Mixed With A Reactant Containing A Single 1,2-epoxy Group Per Mole Or Polymer Derived Therefrom Patents (Class 525/430)
  • Publication number: 20080319145
    Abstract: A thermosetting resin composition for producing a color filter for a CMOS image sensor is provided. The thermosetting resin composition comprises an organic solvent and a self-curing copolymer having structural units represented by Formulae 1, 2, 3 and 4, which are described in the specification.
    Type: Application
    Filed: May 7, 2008
    Publication date: December 25, 2008
    Applicant: CHEIL INDUSTRIES INC.
    Inventors: O Bum Kwon, Kil Sung Lee, Jae Hyun Kim, Jung Hyun Kim
  • Publication number: 20080255320
    Abstract: Polyamidoamine (PAE) resins are prepared from polyamidoamine made with excess amine, which are reacted with a specifically defined amount of difunctional crosslinker. The amount of difunctional crosslinker used is based on the polyamidoamine amine number and reduced specific viscosity (RSV). The PAE resin is prepared by first synthesizing a polyamidoamine from a polyamine and a polycarboxylic acid or polycarboxylic acid derivative, wherein the polyamine is present in a molar excess, said molar excess being from about 1.02 to 2.00, then reacting the polyamidoamine with difunctional crosslinker, wherein the weight % of difunctional crosslinker to polyamidoamine solids is no more than about 0.308(amine number/RSV)—9.18 or 385(amine number/RSV)—5.20, wherein the amine number is expressed as the milliequivalents of amine per gram of polyamidoamine solids and the RSV is the reduced specific viscosity measured at 2% concentration in 1 M NH4Cl expressed in deciliters per gram.
    Type: Application
    Filed: January 18, 2008
    Publication date: October 16, 2008
    Applicant: Hercules Inc.
    Inventor: Anthony J. Allen
  • Patent number: 7425594
    Abstract: A copolymer and a process of making the copolymer are disclosed. The copolymer is produced from reacting a glycidyl ester and/or ether with a polyol comprising a functionality of at least 2 wherein at least 50% by weight of the copolymer comprises a minimum of 3n+X repeating units, wherein n is a monomer unit and X is a monomer unit and/or other reactant. The copolymer may also include less than 50% of the polymeric units having the same molecular weight. The present invention is further directed to processes for preparing the copolymer and to coating compositions employing the copolymer.
    Type: Grant
    Filed: November 23, 2005
    Date of Patent: September 16, 2008
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Jonathan T. Martz, Stephen J. Thomas
  • Patent number: 7390497
    Abstract: Provided herein is a PEA polymer blend and coatings or implantable devices formed therefrom. The PEA polymer blend is formed of a PEA polymer and a material capable of hydrogen bonding with the PEA. The PEA polymer blend can form a coating on an implantable device, one example of which is a stent. The coating can optionally include a biobeneficial material and/or optionally with a bioactive agent. The implantable device can be used to treat or prevent a disorder such as one of atherosclerosis, thrombosis, restenosis, hemorrhage, vascular dissection or perforation, vascular aneurysm, vulnerable plaque, chronic total occlusion, claudication, anastomotic proliferation for vein and artificial grafts, bile duct obstruction, ureter obstruction, tumor obstruction, and combinations thereof.
    Type: Grant
    Filed: October 29, 2004
    Date of Patent: June 24, 2008
    Assignee: Advanced Cardiovascular Systems, Inc.
    Inventors: Jessica Renee DesNoyer, Stephen Dirk Pacetti, Syed Faiyaz Shmed Hossainy, Lothar Kleiner, Yiwen Tang, Gina Zhang
  • Patent number: 7368169
    Abstract: Compounds exhibiting angiogenic properties incorporating the structure of Formula I: R3—NH—NH—C(?O)—R2—P—R1 ??(I) wherein P is a water-soluble, biodegradable polymer, R1 is hydrogen, lower alkyl, lower alkoxy or —R2—C(?O)—NH—NH—R3; each R2 is independently —CH2—, —NH— or O; and each R3 is independently hydrogen or a residue of a naturally occurring alpha-L-amino acid or dipeptide thereof. Polymer networks crosslinked with hydrazide compounds are also disclosed, together with implantable medical devices incorporating the compounds and crosslinked polymers, and angiogenesis-promoting treatment methods, including wound-treatment methods.
    Type: Grant
    Filed: December 1, 2004
    Date of Patent: May 6, 2008
    Assignee: Rutgers, The State University of New Jersey
    Inventors: Joachim B. Kohn, Kristen S. Labazzo, Durgadas Bolikal
  • Patent number: 7339009
    Abstract: A cross-linked polyimide is disclosed. The cross-linked polyimide includes a polyimide and at least one oxygenated hydrocarbon. The oxygenated hydrocarbon cross-links the polyimide. A porous cross-linked membrane is also disclosed. The porous cross-linked membrane includes a support structure and a cross-linked polyimide disposed on the support structure. The cross-linked polyimide includes a polyimide; and at least one oxygenated hydrocarbon cross-linking the polyimide. Also disclosed are methods of making the cross-linked polyimide and the porous cross-linked membrane.
    Type: Grant
    Filed: December 16, 2004
    Date of Patent: March 4, 2008
    Assignee: General Electric Company
    Inventor: Gary William Yeager
  • Patent number: 7312263
    Abstract: The present invention relates to thermoplastic polyamide moulding compositions which contain at least one copolyamide with at least 20% by weight polyamide 12 components and at least one aprotic compound selected from the group of N-alkylated, cyclic carboxylic acid amides with 5 to 7 ring elements and/or of urea derivatives, the alkyl rests of which are linear at the nitrogen or which form a linking of the two N-atoms, and a process for production of the moulding compositions. The thermoplastic polyamide moulding compositions are distinguished by the fact that no solid deposits are formed during thermoplastic conversion.
    Type: Grant
    Filed: December 29, 2004
    Date of Patent: December 25, 2007
    Assignee: EMS-Chemie AG
    Inventors: Eduard Schmid, Ornulf Rexin
  • Patent number: 7241832
    Abstract: Biodegradable polymer blends suitable for laminate coatings, wraps and other packaging materials are manufactured from at least one “hard” biopolymer and at least one “soft” biopolymer. “Hard” biopolymers tend to be more brittle and rigid and typically have a glass transition temperature greater than about 10° C. “Soft” biopolymers tend to be more flexible and pliable and typically have a glass transition temperature less than about 0° C. While hard and soft polymers each possess certain intrinsic benefits, certain blends of hard and soft polymers have been discovered which possess synergistic properties superior to those of either hard or soft polymers by themselves. Biodegradable polymers include polyesters, polyesteramides, polyesterurethanes, thermoplastic starch, and other natural polymers. The polymer blends may optionally include an inorganic filler. Films and sheets made from the polymer blends may be textured so as to increase the bulk hand feel.
    Type: Grant
    Filed: March 1, 2002
    Date of Patent: July 10, 2007
    Assignee: bio-tec Biologische Naturverpackungen GmbH & Co., KG
    Inventors: Kishan Khemani, Harald Schmidt, Simon K. Hodson
  • Patent number: 7232864
    Abstract: The present invention is a coupled radial anionic polymer comprising a polyhedral oligosilsesquioxane [POSS] of the formula [R—SiO3/2]n. POSS compounds having R=vinyl, glycidyldimethyl silyl, and isobutyl have been found effective in coupling anionic living polymers to yield radial polymers having 2 to 10 arms. Radial polymers of the present invention have been formed using POSS octamers and mixtures of POSS octamers, decamers and dodecamers. The present invention also relates to a process for coupling living anionic polymers with POSS compounds.
    Type: Grant
    Filed: October 14, 2004
    Date of Patent: June 19, 2007
    Inventor: Robert C. Bening
  • Patent number: 7214414
    Abstract: Biodegradable polymer blends suitable for laminate coatings, wraps and other packaging materials are manufactured from a blend of suitable biodegradable polymers, such as at least one “hard” biopolymer and at least one “soft” biopolymer. “Hard” biopolymers tend to be more brittle and rigid and typically have a glass transition temperature greater than about 10° C. “Soft” biopolymers tend to be more flexible and pliable and typically have a glass transition temperature less than about 0° C. While hard and soft polymers each possess certain intrinsic benefits, certain blends of hard and soft polymers have been discovered which possess synergistic properties superior to those of either hard or soft polymers by themselves. Biodegradable polymers include polyesters, polyesteramides, polyesterurethanes, thermoplastic starch, and other natural polymers. The polymer blends may optionally include an inorganic filler. Films and sheets made from the polymer blends may be textured so as to increase the bulk hand feel.
    Type: Grant
    Filed: April 12, 2005
    Date of Patent: May 8, 2007
    Assignee: biotec Biologische Naturverpackungen Gmb
    Inventors: Kishan Khemani, Harald Schmidt, Simon Hodson
  • Patent number: 7208447
    Abstract: The invention relates to a novel process that makes it possible to epoxidize ?,?-unsaturated enones or ?,?-unsaturated sulfones with high conversions and enantiomeric excesses in a two-phase system without addition of water in the presence of an organic solvent, a base, an oxidant, a diastereomer- and enantiomer-enriched homo-polyamino acid that has not been separately preactivated as catalyst, and a specific phase-transfer catalyst as cocatalyst.
    Type: Grant
    Filed: August 25, 2004
    Date of Patent: April 24, 2007
    Assignee: Lanxess Deutschland GmbH
    Inventors: Thomas Geller, Christa Maria Krüger, Hans-Christian Militzer
  • Patent number: 7030208
    Abstract: The present invention relates to fluorinated biopolymer and polymer derivatives useful as imaging probes, diagnostic agents and contrast agents and to imaging methods employing the fluorinated biopolymers and polymers.
    Type: Grant
    Filed: April 11, 2003
    Date of Patent: April 18, 2006
    Assignee: CarboMer, Inc.
    Inventor: Manssur Yalpani
  • Patent number: 6956086
    Abstract: A amidoamine composition containing oligomeric amidoamine compounds having the structure: the average of x based on the amidoamine composition is at least 0.2, and Z is the residue of a polyoxyalkylene polyether polycarboxylic acid compound, and the amidoamine composition is the reaction product of primary polyamine compounds with polyoxyalkylene polyether polycarboxylic acid compounds at a corresponding equivalent weight ratio of at least 4.0:1 under oligomeric reaction conditions effective to increase the amine nitrogen equivalent weight of the amidoamine composition by at least 10% over the average acid equivalent weight of said polyoxyalkylene polyether polyacid composition. There is also provided glycidated amidoamine compositions used as epoxy functional surfactants, and the aqueous epoxy resin dispersions thereof, and the curable epoxy resin compositions thereof.
    Type: Grant
    Filed: September 24, 2003
    Date of Patent: October 18, 2005
    Assignee: Resolution Performance Products, LLC
    Inventors: Gayle Edward Back, Pen-Chung Wang, Larry Steven Corley, Jimmy D. Elmore
  • Patent number: 6946527
    Abstract: AGE precursors can be removed from blood, plasma or PBS buffer using a modified polymeric shaped body that can be produced by reaction of diaminoguanidine and/or triaminoguannidine with a staring polymeric shaped body carrying R—X residues, where R is an alkylene group that may or may not be substituted with a hydroxyl group and contains from 1 to 3 carbon atom, and X is a group that is substituted during the reaction by carrying residues Y, on to with diaminoguanidine, or with a starting polymeric shaped body during the reaction which diaminoguanidine and/or triaminoguannidine are added during the reaction.
    Type: Grant
    Filed: July 5, 2001
    Date of Patent: September 20, 2005
    Assignee: Membrana GmbH
    Inventors: Horst Dieter Lemke, Arne Gehlen
  • Patent number: 6908983
    Abstract: The present invention contemplates a process for forming polyaminoamide polymers formed by the reaction of a dibasic acid/ester with excess amounts of an amine; the intermediate polymer resulting therefrom; a process for synthesizing effective, high solids resins resulting from the reaction of intermediate polymers with an epihalohydrin; and the resultant high, solids resin. These resins may be used as wet strength resins in the papermaking industry.
    Type: Grant
    Filed: April 1, 2003
    Date of Patent: June 21, 2005
    Assignee: Hercules Corporation
    Inventor: William W. Maslanka
  • Patent number: 6887967
    Abstract: A thermosetting polyimide resin composition is provided which comprises a polyimide resin and an epoxy resin, which has excellent heat resistance, low dielectric constant and low dielectric loss tangent and also yields a cured article having good mechanical properties such as tensile strength and tensile elongation. Also, a process for producing a polyimide resin used in the polyimide resin composition is provided. The thermosetting polyimide resin composition comprises a polyimide resin (X), which has a carboxyl group and a linear hydrocarbon structure having a number-average molecular weight of 300 to 6,000, and an epoxy resin (Y).
    Type: Grant
    Filed: January 23, 2003
    Date of Patent: May 3, 2005
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Eiju Ichinose, Yohzoh Yamashina, Hidenobu Ishikawa
  • Patent number: 6861479
    Abstract: Production of a porous layer includes using a composition which includes a first polymer component and a second polymer component, the first polymer component being polyhydroxyamide and/or polybenzoxazole and stable at a temperature at which the second polymer component decomposes and volatilizes. If the composition is heated to the decomposition temperature of the second polymer component, the second component volatilizes and a porous layer that contains the first component remains.
    Type: Grant
    Filed: June 26, 2002
    Date of Patent: March 1, 2005
    Assignee: Infineon Technologies AG
    Inventor: Recai Sezi
  • Patent number: 6822053
    Abstract: The invention relates to a novel process that makes it possible to epoxidize &agr;,&bgr;-unsaturated enones or &agr;,&bgr;-unsaturated sulfones with high conversions and enantiomeric excesses in a two-phase system without addition of water in the presence of an organic solvent, a base, an oxidant, a diastereomer- and enantiomer-enriched homo-polyamino acid that has not been separately preactivated as catalyst, and a specific phase-transfer catalyst as cocatalyst.
    Type: Grant
    Filed: July 24, 2002
    Date of Patent: November 23, 2004
    Assignee: Bayer Aktiengesellschaft
    Inventors: Thomas Geller, Christa Maria Krüger, Hans-Christian Militzer
  • Patent number: 6808819
    Abstract: A resin composition comprising the associated product of a polyimide resin having acid anhydride groups in the skeleton with an epoxy resin-curing catalyst, an epoxy resin, and optionally, an epoxy resin-curing agent has excellent adhesion, heat resistance, shelf stability and solvent resistance. An adhesive film comprising the resin composition is useful as an adhesive or sealant for printed circuit boards and semiconductor packages.
    Type: Grant
    Filed: February 14, 2003
    Date of Patent: October 26, 2004
    Assignee: Shin Etsu Chemical Co., Ltd.
    Inventors: Nobuhiro Ichiroku, Toshio Shiobara
  • Patent number: 6784275
    Abstract: Disclosed is an active energy ray-curable polyimide resin composition which comprises a polymerizable polyimide resin (I) having an isocyanurate ring, an alicyclic structure, an imide ring and a (meth)acryloyl group and being capable of patterning with a dilute alkali aqueous solution.
    Type: Grant
    Filed: June 27, 2002
    Date of Patent: August 31, 2004
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Eiju Ichinose, Yohzoh Yamashina, Hidenobu Ishikawa
  • Publication number: 20040092671
    Abstract: Polyaminoamides in which at least some of the amine nitrogen atoms have been alkoxylated, amidated, or alkylated are suitable for hydrophilicizing surfaces, in particular of linear or sheet-like textile structures made from synthetic fibers, or structures in the form of their plastics film or of a plastics molding. The hydrophilicized linear or sheet-like textile structures are particularly used in hygiene items.
    Type: Application
    Filed: September 29, 2003
    Publication date: May 13, 2004
    Inventors: Cordula Mock-Knoblauch, Michael Zirnstein, Helmut Meffert
  • Publication number: 20040087734
    Abstract: The invention relates to polyamide compositions having improved antistatic behaviour and/or improved hydrophilicity. These compositions are particularly suitable for the manufacture of polyamide-based yarns, fibres and filaments. The compositions comprise polyamide and a modifier containing polyether units, which modifies the antistatic and/or hydrophilic properties.
    Type: Application
    Filed: December 22, 2003
    Publication date: May 6, 2004
    Inventors: Jean- Pierre Bianchi, Bertrand Bordes, Olivier Chaubet, Sandrine Rochat, Eric Roche
  • Patent number: 6710106
    Abstract: A molding composition comprising an aggregate [Component (A)], a linear unsaturated polyester [Component (B)] and/or linear unsaturated polyester polyamide [Component (C)], and a radical generator [Component [D]), characterized in that each of Component (B) and Component (C) comprises a specific alkylene oxide adduct of bisphenol A in an amount of from 3 to 50 mol % based on the total amount of constituent monomers of each of Component (B) and Component (C) and a molded article obtained by molding the composition.
    Type: Grant
    Filed: February 2, 2001
    Date of Patent: March 23, 2004
    Assignee: Kao Corporation
    Inventors: Takashi Yamaguchi, Katsutoshi Aoki, Kuniyasu Kawabe
  • Patent number: 6677427
    Abstract: A polyamide, the enzymatic reaction product of at least one polyamine and diester, and processes for preparing and using the same. In addition, processes for preparing and using the enzymatic reaction product as creping adhesives and wet strength resins to make cellulose products.
    Type: Grant
    Filed: June 13, 2000
    Date of Patent: January 13, 2004
    Assignee: Hercules Incorporated
    Inventors: Huai N. Cheng, Qu-Ming Gu, William W. Maslanka
  • Patent number: 6667384
    Abstract: The present invention contemplates poly(aminoamide) pre-polymers, polyamide polymers, a multi-step process for the synthesis of these pre-polymers and polymers using acrylates and at least one monomer containing at least two primary amines, and the resins resulting from the reaction of the polymers with an epihalohydrin. These resins may be used as wet strength resins and creping aids in the papermaking industry as well as surface additives for wool.
    Type: Grant
    Filed: December 27, 2001
    Date of Patent: December 23, 2003
    Assignee: Hercules Incorporated
    Inventors: Qu-Ming Gu, Armin Michel, Huai Nan Cheng, William W. Maslanka, Ronald R. Staib
  • Patent number: 6586512
    Abstract: A composition comprising a superabsorbent polymer and a hydroxy-functionalized polyether.
    Type: Grant
    Filed: September 28, 2000
    Date of Patent: July 1, 2003
    Assignee: The Dow Chemical Company
    Inventors: Charles D. Dukes, Donna G. Shaffer
  • Patent number: 6576687
    Abstract: The invention relates to a novel process for the preparation of polycondensate solutions based on polyamidoamine/epichlorohydrin resins that gives products having a very low content of organic chlorine compounds, in particular a 1,3-dichlorophenol-2-propanol content of <0.1%, in combination with high activity and good shelf-life.
    Type: Grant
    Filed: July 2, 2001
    Date of Patent: June 10, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl-Rudolf Gassen, Joachim König, Karlheinrich Meisel, Fritz Puchner, Jürgen Reiners, Horst Zwick
  • Patent number: 6515048
    Abstract: An adhesive powder for bonding flat, closed, or porous substrates, the adhesive powder being applied in the first step to a first substrate, an intermediate product that is non-adhesive at room temperature and stable in storage being produced, and the first substrate being bonded to a second substrate in a second step by applying an increased temperature and pressure, as a combination of the following components: i) a thermoplastic polymer having a proportion of 25 to 95% by weight; and ii) at least one epoxy resin that is solid at room temperature and has a proportion of 5 to 75% by weight; and, if desired, iii) at least one pre-adduct of epoxy resins and polyamines that is solid at room temperature and has a proportion of at most 25% by weight, a physical bonding taking place when the adhesive powder is applied to the first substrate in the first step, and the two substrates being bonded in the second step by the powder components being chemically cross-linked or post-cross-linked among one another, and bei
    Type: Grant
    Filed: June 6, 2001
    Date of Patent: February 4, 2003
    Assignee: Firma Carl Freudenberg
    Inventors: Michael Kalbe, Silke Wagener, Peter S. Grynaeus
  • Publication number: 20030023007
    Abstract: A benzoxazine polymer having improved thermal properties. The properties are improved by inserting aromatic polyamines into the monomer, such as phenylenediamine, methylenedianiline, oxydianiline, diaminodiphenylsulfone, 2,2-bis(4-[aminophenoxy]phenyl)propane, 4,4′-oxydianiline, 4,4′-diaminodiphenyl sulfone, and diaminobenzanilide, to introduce internal benzoxazine groups that are crosslinking sites. The improved polymers can be converted into molding compounds, towpregs, and prepregs by being compounded with reinforcing fibers.
    Type: Application
    Filed: February 15, 2002
    Publication date: January 30, 2003
    Applicant: HyComp, Inc.
    Inventor: Joseph P. Reardon
  • Patent number: 6498217
    Abstract: A branched polyamide and a process for its preparation are disclosed. Aliphatic or aromatic esters of carbonic acid are used as branching agents in an optionally catalyzed reaction with crystalline polyamide to produce resins having good flow properties, high degree of crystallinity and excellent mechanical properties. Amorphous polyamides that are branched in accordance with the inventive process have improved flow properties.
    Type: Grant
    Filed: August 10, 2000
    Date of Patent: December 24, 2002
    Assignee: Bayer Aktiengesellshaft
    Inventors: Miroslav Marek, Friedrich-Karl Bruder, Konstadinos Douzinas
  • Patent number: 6479588
    Abstract: A graft copolymer comprising a polyamide to which is grafted a glycidyl group-containing acrylate copolymer. The graft copolymer can be prepared by dispersing in an organic solvent a polyamide and a material which will react with the polyamide to form the graft copolymer of the polyamide and the acrylate copolymer and reacting the polyamide and the material so as to form said graft copolymer. The graft copolymer can exhibit improved toughness and reduced friability and can be used to form molded articles and in coating compositions, especially powder coating compositions. The coatings can exhibit transparency, reduced brittleness and increased chip resistance. The powder coatings can further exhibit high gloss and smoothness due to superior flow characteristics thereby enabling thinner coatings to be used that provide acceptable appearance.
    Type: Grant
    Filed: August 21, 2000
    Date of Patent: November 12, 2002
    Assignee: Anderson Development Co.
    Inventors: Szu-Ping Lu, Paul J. Prucnal, Hiram A. Norton
  • Patent number: 6458897
    Abstract: An aqueous dispersion composition which comprises an ionomer resin (A) neutralized with a divalent metal, and water, sufficiently answers high level of requirement performances in various uses, and in particular, is particularly suitable as a heat sealing agent for aluminum foil, film, paper or the like, a metal coating agent, a modifier for various emulsions, a paint, an adhesive, a rust-preventive treating agent, and the like; a method which can produce the aqueous dispersion composition in high yield; a rust-preventive treating agent for a metal surface, which contains the aqueous dispersion composition, has excellent corrosion resistance, and can form a rust-preventive layer showing excellent coating adhesion to a over coat paint; a rust-preventive treatment method using the rust-preventive treating agent; and a rust-preventive treated metal product.
    Type: Grant
    Filed: February 19, 1999
    Date of Patent: October 1, 2002
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Suguru Tokita, Shigenobu Otsubo, Yoshiyuki Harada, Makoto Nakazawa
  • Patent number: 6429267
    Abstract: Process for reducing the AOX content of wet-strength resins, such as polyaminopolyamide-epi or polyalkylene polyamine-epi resins, by treatment with base, e.g. sodium hydroxide, while maintaining the wet-strength effectiveness of the resin.
    Type: Grant
    Filed: December 22, 1998
    Date of Patent: August 6, 2002
    Assignee: Hercules Incorporated
    Inventor: Richard James Riehle
  • Patent number: 6403757
    Abstract: A reaction between epoxy-terminated polyamide and an acid anhydride compound can yield a modified polyamide resin, into resin skeleton of which carboxy groups to react with epoxy resin are introduced. An adhesive agent having excellent heat-resistance can be provided by the use of a composition of this modified polyamide resin and epoxy resin. Furthermore, an adhesive tape for a semiconductor device having excellent properties can be produced by laminating the adhesive agent and the protective layer on one surface of an organic insulated film.
    Type: Grant
    Filed: January 7, 2000
    Date of Patent: June 11, 2002
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisah
    Inventors: Katsunori Yabuta, Kiyokazu Akahori, Yasushi Nishikawa
  • Patent number: 6352613
    Abstract: wherein R1 is substituted or unsubstituted alkyl; R2 is substituted or unsubstituted alkyl; R3 is substituted or unsubstituted alkyl; Z is halogen selected from F, Cl, Br and I; x is from about 5 to about 45 mole %; and y is from about 55 to about 95 mole % are useful as wet strength resins and creping adhesives. Methods of producing such resins, and the use of such resins in wet strength and creping applications, as well as compositions suitable for such applications, and combinations of cellulosic product and such resins are also disclosed.
    Type: Grant
    Filed: March 14, 2000
    Date of Patent: March 5, 2002
    Assignee: Hercules Incorporated
    Inventor: William W. Maslanka
  • Patent number: 6353059
    Abstract: The present invention relates to nonlinear-optically active copolymers which are composed of a chromophore acrylate, a glycidyl-functional acrylate, and a further acrylate unit, and to polyadducts produced from them by crosslinking with a carboxyl-functional polyester. The nonlinear-optical copolymers of the present invention, and the polyadducts prepared from them, possess an orientation stability in the crosslinked state, and a thermal stability, which makes them highly suitable for producing electrooptical and photonic components.
    Type: Grant
    Filed: November 30, 2000
    Date of Patent: March 5, 2002
    Assignee: Siemens Aktiengesellschaft
    Inventors: Andreas Kanitz, Horst Hartmann, Christian Fricke, Karsten Kuhne
  • Publication number: 20010034406
    Abstract: A water-soluble thermosetting resin giving high wet-strength of paper and excellent preservation stability which comprises 20% by weight or less of components having a molecular weight of 10,000 or less; and a water-soluble thermosetting resin giving high wet-strength of paper in which, in a reverse mutation test carried out for the resin as the object to be tested using histidine-requiring Salmonella typhimurium TA1535 strain, the number of reversant colonies generated is less than twice the number of reversant colonies in the solvent control, treated only the solvent as a reference liquid are provided; and a process for producing an aqueous cationic thermosetting resin solution giving excellent preservation stability of the solution which comprises a step of reacting polyamidepolyamine and epihalohydrin, and a step wherein the solution obtained by reacting polyamidepolyamine and epihalohydrin is held at a temperature of about 30 to about 70° C. for a period, while adjusting the pH to about 2 to about 3.
    Type: Application
    Filed: December 20, 2000
    Publication date: October 25, 2001
    Inventors: Satoshi Yamamoto, Yoshifumi Yoshida, Masahiko Kurumatani, Mika Ota, Satoshi Asano
  • Patent number: 6294645
    Abstract: The invention relates to resin systems useful for imparting dry-strength to paper without substantially increasing the paper's wet-strength wherein the resin system comprises a cationic component and an anionic component. The invention also relates to the process for incorporating these resin systems into paper and the paper produced containing the resin systems.
    Type: Grant
    Filed: July 25, 1997
    Date of Patent: September 25, 2001
    Assignee: Hercules Incorporated
    Inventors: Anthony J. Allen, Elliott Echt, William W. Maslanka, Jeffrey C. Peters
  • Patent number: 6239205
    Abstract: A silicone rubber composition comprising about 0.05 to 10 wt % cerium oxide powder having a BET specific surface area not less than 80 m2/g and a pH value measured of a 3 wt % aqueous dispersion thereof of about pH 2 to 5.5.
    Type: Grant
    Filed: December 15, 1999
    Date of Patent: May 29, 2001
    Assignee: Dow Corning Toray Silicone Co.
    Inventors: Chiichiro Hasegawa, Junsuke Tokimatsu, Kazuhito Fujiwara
  • Patent number: 6222006
    Abstract: An aqueous formulation of a high solid content fully functional thermosettable wet strength resin designed for use in the manufacture of paper products is disclosed. The wet strength resin is the product of reaction of an epihalohydrin and an end-capped polyaminamide polymer. The thermosetting wet strength resins are useful in the manufacture of improved absorbent paper products such as bathroom tissues, facial tissues, napkins, towels, and paperboard products such as dairy cartons and bag paper.
    Type: Grant
    Filed: August 5, 1998
    Date of Patent: April 24, 2001
    Assignee: Fort James Corporation
    Inventors: Bruce Jerome Kokko, Elroy Wayne Post
  • Patent number: 6211249
    Abstract: The present invention relates to novel bioabsorbable polymeric compositions based upon AB polyester polyether or related diblocks and triblocks. Compositions according to the present invention may be used in medical applications, for example, for reducing or preventing adhesion formation subsequent to medical procedures such as surgery, for producing surgical articles including stents and grafts, as coatings, sealants, lubricants, as transient barriers in the body, for materials which control the release of bioactive agents in the body, for wound and bum dressings and producing biodegradable articles, among numerous others.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: April 3, 2001
    Assignee: Life Medical Sciences, Inc.
    Inventors: Daniel Cohn, Theodor Stern, Avraham Levi
  • Patent number: 6203872
    Abstract: Proposed is a process for sealing the seams of a water vapour permeable lining comprising a laminate of a textile material and a waterproof, but water vapour permeable film in which sections of said laminate with the textile sides facing one another are bonded together along the contours of the material to be lined, after which the lining is dipped in a solution of a hydrophilic polymer in an organic solvent which acts as a swelling agent for the waterproof film of the laminate, followed by evaporation of the solvent. The water vapour permeable film in the laminate preferably is made of a hydrophilic copolyetherester or copolyetheramide, while the hydrophilic polymer soluble in an organic solvent preferably is a copolyetherester.
    Type: Grant
    Filed: July 23, 1998
    Date of Patent: March 20, 2001
    Assignee: Akzo Nobel NV
    Inventor: Dennis W Hannon
  • Patent number: 6187856
    Abstract: An antistatic composition containing a crosslinked thermosetting resin formed by reacting, in the presence of a water-soluble solvent, (a) a polyaminoamide having unreacted primary and secondary amine groups and (b) a polychlorohydrin derivative.
    Type: Grant
    Filed: March 18, 1998
    Date of Patent: February 13, 2001
    Assignee: Henkel Corporation
    Inventors: Michael J. Incorvia, Stephen A. Fischer
  • Patent number: 6180727
    Abstract: There is provided a curing agent composition, a method for making a curing agent composition, two component curable epoxy resin compositions, methods of their manufacture, and the different cured products thereof. The curing agent comprises the reaction product of a a) phenolic acid substituted with at least one carboxyl group and at least one hydrocarbyl group having at least 1 carbon atom; b) a polyepoxide compound; c) a polyamine compound having at least two primary amine groups; and d) a monoglycidyl capping agent. The curing agents contain secondary amine groups, yet are reactive enough to cure epoxy resins without the necessity for external catalysts/accelerators, at a wide range of curing temperatures and are immediately compatible with a standard diglycidyl ether of Bisphenol-A epoxy resins.
    Type: Grant
    Filed: December 31, 1997
    Date of Patent: January 30, 2001
    Assignee: Shell Oil Company
    Inventor: Kalyan Ghosh
  • Patent number: 6174961
    Abstract: The present invention relates to nonlinear-optically active copolymers which are composed of a chromophore acrylate, a glycidyl-functional acrylate, and a further acrylate unit, and to polyadducts produced from them by crosslinking with a carboxyl-functional polyester. The nonlinear-optical copolymers of the present invention, and the polyadducts prepared from them, possess an orientation stability in the crosslinked state, and a thermal stability, which makes them highly suitable for producing electrooptical and photonic components.
    Type: Grant
    Filed: March 9, 1999
    Date of Patent: January 16, 2001
    Assignee: Siemens Aktiengesellschaft
    Inventors: Andreas Kanitz, Horst Hartmann, Christian Fricke, Karsten Kuhne
  • Patent number: 6166137
    Abstract: The present invention is directed to a unique poly(arylene ether)/polyetherimide composition having improved impact strength, as well as other improved mechanical and physical properties. This composition comprises: about 40 to about 90 pbw of a polyetherimide resin; about 8 to about 60 pbw of a functionalized poly(arylene ether) resin having a base titratable functionality level of at least 30 .mu.eq/g; and about 0.2 to about 35 pbw of a copolymer of an olefin and an epoxy-functionalized monomer; and may further include catalysts, gloss improvers, stabilizers, and other additives.
    Type: Grant
    Filed: December 10, 1998
    Date of Patent: December 26, 2000
    Assignee: General Electric Company
    Inventors: Sterling Bruce Brown, Brenda A. Giles, Yimin Jin, Darryl Nazareth, Steven Thomas Rice, Robert Puyenbroek, Barbara J. McKinley
  • Patent number: 6165322
    Abstract: Compositions suitable for use as dry strength additives comprising water soluble polyamidoamine/epchlorohydrin resin bearing polyol sidechains wherein the weight fraction of the polyol in the resin is less than 50 percent by weight and the polyol sidechain is attached to the polyamidoamine/epichlorohydrin resin by carbon-nitrogen bond, such as amide bond or secondary or tertiary amine bonds.
    Type: Grant
    Filed: July 29, 1997
    Date of Patent: December 26, 2000
    Assignee: Hercules Incorporated
    Inventor: Barton K. Bower
  • Patent number: 6111032
    Abstract: A process for preparing a tertiary amine polyamidoamine-epihalohydrin polymer having a low level of epihalohydrin byproducts. In this process a tertiary amine polyamidoamine prepolymer is reacted with an epihalohydrin; the molar ratio, of epihalohydrin to tertiary amine groups in the polyamidoamine prepolymer, is less than 1.0 to 1.0. The reaction is further conducted at a pH of from about 7.5 to less than about 9.0, in the presence of a nonhalide acid, and at a temperature of not more than about 35.degree. C.
    Type: Grant
    Filed: May 4, 1998
    Date of Patent: August 29, 2000
    Assignee: Hercules Incorporated
    Inventor: Barton K. Bower
  • Patent number: 6077500
    Abstract: Higher generation radially layered copolymeric dendrimers having a hydrophilic poly(amidoamine) or a hydrophilic poly(propyleneimine) interior and a hydrophobic organosilicon exterior are prepared by first reacting a hydrophilic dendrimer having --NH.sub.2 surface groups with an organosilicon compound, and then hydrosilating the resulting copolymeric dendrimer with another organosilicon compound in the presence of a noble metal catalyst. In an alternate embodiment, the radially layered copolymeric dendrimers are prepared by reacting a hydrophilic dendrimer having --NH.sub.2 surface groups directly with an organosilicon dendron or organosilicon hyperbranched polymer.
    Type: Grant
    Filed: March 18, 1999
    Date of Patent: June 20, 2000
    Assignees: Dow Corning Corporation, Dendritech, Incorporated
    Inventors: Petar R. Dvornic, Agnes M. deLeuze-Jallouli, Michael James Owen, Susan Victoria Perz
  • Patent number: 5998545
    Abstract: The present invention relates to a mixture of polymers (A) having polyamide blocks and copolymers (B) comprising vinylaromatic units and unsaturated carboxylic anhydride units, the quantity of (B) being sufficient for the melt index (or melt flow index, MFI) of the mixture of (A) and (B) to be less than the melt index of (A) alone.It also relates to masterbatches of (A) and (B).
    Type: Grant
    Filed: January 22, 1998
    Date of Patent: December 7, 1999
    Assignee: Elf Atochem S.A.
    Inventors: Denis Melot, Alain Bouilloux, Benoit Ernst