Abstract: Resin particles include mother particles containing a biodegradable resin and a plasticizer, in which an amount of a metal element having an ionic valence of 2 or more, obtained by fluorescent X-ray analysis, is 0.002% by mass or more and 2.0% by mass or less with respect to a total amount of the resin particles.

Abstract: The patent application discloses a degradable polymers compounds. The polymer compounds comprises product of blends of polyglycolic acid and polylactic acid in a weight ratio of from about 99/1 to about 50/50 in mixture with a compatibilizer poly(lactic-co-glycolic acid), wherein the compounded product has a tensile strength of at least about 12,000 psi.

Abstract: A polyester elastomer resin composition for resin belt materials contains 80-92.99% by weight of a thermoplastic polyester elastomer (A), 7-19.99% by weight of glass fibers (B) and 0.01-5.0% by weight of a crystal nucleator (C), and which is also characterized in that: the thermoplastic polyester elastomer (A) is a polyester block copolymer which contains 40-70% by weight of a high melting point crystalline polymer segment (a1) that is composed of a crystalline aromatic polyester unit and 30-60% by weight of a low melting point polymer segment (a2) that is composed of an aliphatic polyether unit; and the melt flow rate as determined in accordance with ASTM D1238 at 230° C. under a load of 2,160 g is 1.0 g/10 min or more but less than 10.0 g/10 min.

Abstract: Resin particles include mother particles containing a biodegradable resin, in which an alkali metal atomic weight A present on a resin particle surface with respect to a total atomic weight present on the resin particle surface, which is measured by an X-ray photoelectron spectroscopy, and an alkali metal atomic weight B present in the resin particles with respect to the total atomic weight present on the resin particles, which is measured by a fluorescent X-ray spectroscopy, satisfy a relationship of 0?(A/B)<0.15 and 0.005 atomic %?B?0.5 atomic %.

Abstract: The present invention provides: a piezoelectric substrate which includes a first piezoelectric body having an elongated shape and helically wound in one direction, and which does not include a core material, in which the first piezoelectric body includes a helical chiral polymer (A) having an optical activity; in which the length direction of the first piezoelectric body is substantially parallel to the main direction of orientation of the helical chiral polymer (A) included in the first piezoelectric body; and in which the first piezoelectric body has a degree of orientation F, as measured by X-ray diffraction according to the following Equation (a), within the range of 0.5 or more but less than 1.0: degree of orientation F=(180°??)/180°??(a) (in which ? represents the half-value width of the peak derived from the orientation).

Abstract: A thermosetting coating composition includes a hydroxyl group-containing resin (A), a blocked polyisocyanate curing agent (B), and an amine compound (C) represented by the formula (1). In the formula (1), R1 to R5 each independently represents a hydrogen atom or an organic group having one or more carbon atoms. The organic group may contain one or more atoms selected from the group consisting of oxygen atoms, nitrogen atoms, sulfur atoms, and halogen atoms.

Abstract: The invention is directed to biomedical polyurethanes. The invention is particularly directed to biomedical polyurethanes with improved biodegradability and to an improved preparation of the biomedical polyurethanes. In particular the present invention provides a biomedical polyurethane having the formula (A-B-C-B)n, wherein A denotes a polyol, B denotes a diisocyanate moiety, C denotes a diol component and n denotes the number of recurring units, and wherein the B-C-B segment is bioresorbable.

Abstract: The invention relates to a continuous process for producing an aliphatic polyester constructed from aliphatic dicarboxylic acids and aliphatic diols comprising the steps of a) esterification, b) polycondensation and optionally c) chain extension, characterized in that during step b) in which the polycondenser functions as a degassing apparatus (B) and/or b?) after the polycondensation in an additional degassing apparatus (B?) the crude polyester is degassed at a pressure of 0.01 to 5 mbar in the presence of 1% to 7% by weight, based on the total weight of the crude polyester of water, introduced into the gas space of the degassing apparatus B and/or B? as an entraining agent.

Abstract: A novel polymer is provided by polymerization of xylitol and dodecanedioic acid. The polymer, poly(xylitol-dodecanedioic acid) or PXDDA, shows high elasticity. PXDDA significantly improves cell adhesion and promotes cell proliferation compared to an FDA-approved polymer, poly(lactic acid), and tissue-culture plates. PXDDA can be synthesized by a simple melt condensation polymerization without the use of any toxic catalysts.

Abstract: The invention relates to the field of analgesics. According to the invention, a kit or composition, particularly a pharmaceutical composition or a pharmaceutical kit, is provided, comprising a nanocarrier which is a hyperbranched polymer, such as a dendritic polymer or dendrimer, preferably having a molecular weight of 1,000-100,000 g/mol, and an analgesic which, when administered without nanocarrier, has both peripheral and central analgesic effect, preferably an opioid such as nalbuphine. According to the invention, the analgesic in this composition mainly or exclusively has a peripheral effect and thus reduces side effects triggered by the activation of central or intestinal opioid receptors. It is used for the treatment of peripheral pain and/or inflammation. The invention also relates to particularly suitable nanocarriers.

Abstract: Described herein is a feasible, significantly simplified production method that avoids challenging lactonization steps and converts a low molecular weight aliphatic polyester, consisting of hydroxy acids and a comonomer, whose molecular weight has been increased by step-growth polymerization reactions. The molecular weight of the aliphatic polyester, based on comparison of initial and final weight average molecular weights (Mw,1/Mw,2), increased significantly at a rate which permits the use of reactive extrusion to produce high molecular weight aliphatic polyesters in a simple, economically feasible manner.

Abstract: The invention relates to a method of manufacturing a diffractive grating. The method comprises providing a first substrate and manufacturing onto the first substrate a first surface profile using temporary grating material. Next, the first surface profile is covered entirely by a layer of final grating material and a second substrate is bonded onto the final grating material. Finally, the first substrate and the temporary grating material are removed for producing on the final grating material a second surface profile, which is a negative of the first surface profile. The invention allows for conveniently producing high quality gratings using e.g. inorganic materials and height and/or fill factor modulation for diffraction efficiency control.

Abstract: Water-soluble, fluorescent particles and compositions, kits, and methods of making and using such particles are disclosed. Processes for preparing fluorescent particles and for controlling the size, polydispersity and optical properties of such particles also are provided.

Abstract: A composition for a protective film for electroconductive patterns, including: (A) a polyurethane containing a carboxyl group; (B) an epoxy compound; (C) a curing accelerator; and (D) a solvent, wherein the percentage of the solvent (D) contained is from 95.0% to 99.9% by mass, and the solvent (D) contains (D1) a solvent containing a hydroxyl group and having a boiling point in excess of 100° C., and (D2) a solvent having a boiling point that does not exceed 100° C., wherein the content of the solvent (D2) having a boiling point that does not exceed 100° C. is 30% to less than 70% by mass of total solvent in total. The composition can be cured by heating at a temperature not exceeding 100° C. for a heating time not exceeding 10 minutes.

Abstract: A polyamideimide copolymer which is an imide of a polyamic acid resulting from copolymerizing an aromatic diamine monomer, an aromatic dianhydride monomer, and an aromatic dicarbonyl monomer and a colorless and transparent polyamideimide film including the polyamideimide copolymer. The polyamideimide copolymer according to the present disclosure makes it possible to provide a polyamideimide film exhibiting excellent scratch resistance while being colorless and transparent.

Abstract: This invention relates to biodegradable films characterised by high resistance to processes of the photodegradative type, mainly activated by the ultraviolet component of sunlight, which are particularly suitable for use in the mulch film sector. These films comprise a composition containing at least one polyphenol of plant origin.

Abstract: Embodiments of poly-lactide compositions are disclosed herein. The compositions may comprise at least one first polymer selected from polylactide-polybutadiene (PLA-PB) block copolymer, polylactide-urethane-polybutadiene block copolymer, or a mixture thereof; and at least one second polymer selected from polylactide, polylactide-urethane, or a mixture thereof. The composition may also comprise from 20% to 50% by weight of said first polymer based on the total weight of the composition and from 50% to 80% by weight of said second polymer based on the total weight of the composition. Embodiments of the present invention also relate to a process for preparing the poly-lactide compositions and articles comprising the poly-lactide compositions.

Abstract: Controlled biodegradable smart responsive scaffold (SRS) materials enhance attachment and viability of cells, i.e. actively guiding their expansion, proliferation and in some cases differentiation, while increasing their biomechanical functionality is an important key issue for tissue regeneration. Chemically build-in functionality in these biodegradable SRS materials is achieved by varying structural functionalization with biocompatible liquid crystal motifs and general polymer composition allowing for regulation and alteration of tensile strength, surface ordering, bioadhesion and biodegradability, bulk liquid crystal phase behavior, porosity, and cell response to external stimuli. Liquid crystal modification of such polymeric scaffolds is an ideal tool to induce macroscopic ordering events through external stimuli.

Abstract: A method of forming anti-rust or anti-bacterial film includes mixing a predetermined liquid and a film-forming composition which contains a tannic acid derivative in which hydrogen atoms in at least 10% of hydroxyl groups of tannic acid are substituted by a chain hydrocarbon group having 10 to 16 carbon atoms, and removing the liquid.

Abstract: The present invention relates to a method for preparing polylactic acid. According to the method for preparing polylactic acid, high quality polylactic acid can be provided by effectively removing residual monomers while minimizing property changes of the polylactic acid.

Abstract: The present invention is directed to a polymer blend comprising at least one polyalkylencarbonate (PAC) and at least one polyhydroxyalkanoate (PHA) with low crystallinity. The invention also describes processes to prepare the blends of the invention and articles made of said blends.

Abstract: A two-component coating composition contains (1) a paint base component comprising (A) at least one polycarbonate diol, (B) at least one hydroxyl-containing acrylate resin, polyester resin and/or polyester acrylate resin having a hydroxyl number of 75 to 500 mg KOH/g, and (C) at least one filler modified with at least one organosilane, and (2) a hardener component comprising (D) at least one organic polyisocyanate, where the coating composition has a viscosity of 50 to 2000 mPa·s at a shear stress of 1000 l/s and a temperature of 23° C. and a proportion of organic solvents of 100 to 350 g/L.

Abstract: A shape-memory self-healing polymeric network (SMSHP) is useful as a molded part, a coating, or as a matrix for a composite that can be repaired by heating to a controlled temperature. The SMSHP has thermally reversible repeating units where a thermally reversible adduct is situated between two common linking units formed during a polymerization process between thermally reversible monomers and cross-linking monomers. Optionally, other repeating units can be present from other monomers. Shape-memory results when the SMSHP is warmed to a temperature in excess of its glass transition temperature and self-healing then proceeds when a higher temperature is achieved where thermally reversible adducts dissociates to complementary groups that subsequently reform the adduct without distortion of the memorized shape. The thermally reversible adducts can be Diels-Alder (DA) adducts in a polyurethane, poly urea, or amine epoxy SMSHP network.

Abstract: Methods and apparatuses for selectively depositing silicon-containing dielectric or metal-containing dielectric material on silicon or metal surfaces selective to silicon oxide or silicon nitride materials are provided herein. Methods involve exposing the substrate to an acyl chloride which is reactive with the silicon oxide or silicon nitride material where deposition is not desired to form a ketone structure that blocks deposition on the silicon oxide or silicon nitride material. Exposure to the acyl chloride is performed prior to deposition of the desired silicon-containing dielectric material or metal-containing dielectric material.

Abstract: The present invention provides a silicone skeleton-containing polymer compound containing a repeating unit shown by the general formula (1). There can be provided a silicone skeleton-containing polymer compound suitable used as a base resin of a chemically amplified negative resist composition that can remedy the problem of delamination generated on a metal wiring such as Cu and Al, an electrode, and a substrate, especially on a substrate such as SiN, and can form a fine pattern without generating a scum and a footing profile in the pattern bottom and on the substrate.

Abstract: Embodiments of polylactide based compositions are disclosed herein. The compositions may comprise at least one first polymer selected from polylactide-polybutadiene (PLA-PB) block copolymer, polylactide-urethane-polybutadiene block copolymer, or a mixture thereof; and at least one second polymer selected from polylactide, polylactide-urethane, or a mixture thereof. The composition may also comprise from 20% to 50% by weight of said first polymer based on the total weight of the composition and from 50% to 80% by weight of said second polymer based on the total weight of the composition. Embodiments of the present invention also relate to a process for preparing the polylactide based compositions and articles comprising the polylactide compositions.

Abstract: Polyester compositions are disclosed herein, as well as methods of making and using such polyesters. In some embodiments, the polyesters are formed from monomers derived from natural oils. In some embodiments, the polyesters have lower glass transition temperatures than polyesters of comparable molecular weight.

Abstract: A process for the manufacture of a block copolymer includes a reaction of a lactide monomers in the presence of a catalyst with a polymer to form the block copolymer having a lactic acid chain, wherein a polymer selected from polypropylene, polyethylene, polysiloxane, polybutylene succinate, polytrimethylene carbonate, polyester, polyether, polystyrene, polyisoprene, polycarbonate, polyalkylenecarbonate, polyvinyl alcohol, polyurethane, or polyacrylate; and wherein the polymer contains n number of OH and/or NH2 group(s), n is an integer greater than or equal to 1 and Moles ? ? of ? ? Lactide ( Moles ? ? of ? ? Compound * n ) ? 70 , and the reaction is performed at a temperature of at least 70° C. The process includes step of quenching of the reaction in order to form the lactic acid chains consisting of 70 or less of the lactide monomers, and the quenching agent is an acid chloride having a formula of Cl—CO—R9, wherein R9 is 1-pentenyl or aminoethyl.

Abstract: A method for producing a lactide block copolymer, to a lactide block copolymer and to an article including the lactide block copolymer. In particular, the instant invention relates to an improved lactide block copolymer which may be obtained by providing a polymer of a first lactide monomer including a residual amount of the first monomer, adding and polymerizing a first amount of a second monomer of opposite chirality and subsequently adding and polymerizing a second amount of the second monomer. The resulting lactide block copolymer generally has a high melting point (e.g. from 190 to 250° C.).

Abstract: The invention relates to a method for manufacturing polylactide, comprising the steps of mixing lactide and a metal-coordination compound as polymerization catalyst to obtain a reaction mixture, polymerizing the lactide in liquid phase at a temperature of at least 150° C. to form polylactide in liquid phase and allowing the polylactide to solidify, characterized in that the polymerization catalyst comprises a metal-ligand coordination compound whereby the parent ligand answers the formula (I), whereby R represents an H atom, an aliphatic group, a halide atom or a nitro group and the metal is at least one of Zr and Hf. The invented catalysts show kinetics which is comparable to the kinetics of the known Sn-octoate catalyst.

Abstract: The present invention relates to a method for preparing a stereoblock polylactide, comprising: a step of obtaining a first reaction mixture with a monomer conversion rate of 80 to 95% by adding a catalyst to a D-lactide and growing a PDLA chain; a step of obtaining a second reaction mixture with a monomer conversion rate of 80 to 95% by adding an L-lactide to the first reaction mixture and growing a racemic PDLLA chain at the end of the PDLA chain; and a step of further adding an L-lactide to the second reaction mixture and growing a PLLA chain at the end of the PDLLA chain through a polymerization reaction.

Abstract: Described herein are aqueous soluble polymersomes that encapsulate one or more hydrophobic fluorescent polymers and methods of their preparation and use.

Abstract: An ophthalmic lens material includes dopamine methacrylamide, a hydrophilic monomer, a cross-linking agent, and a photoinitiator. The dopamine methacrylamide has a mass percentage of about 0.5% to about 10% of a total mass of the ophthalmic lens material. The hydrophilic monomer has a mass percentage of about 88.95% to about 99.494% of a total mass of the ophthalmic lens material. The cross-linking agent has a mass percentage of about 0.001% to about 1% of a total mass of the ophthalmic lens material. The photoinitiator has a mass percentage of about 0.005% to about 0.05% of a total mass of the ophthalmic lens material.

Abstract: A method for making an ophthalmic lens includes following steps of mixing dopamine methacrylamide, a hydrophilic monomer, a cross-linking agent, and a photoinitiator to form a mixture; feeding the mixture into a mold and exposing the mixture to ultraviolet radiation, to cause the dopamine methacrylamide, the hydrophilic monomer, the photoinitiator, and the cross-linking agent to undergo a polymerization reaction. The disclosure also provides an ophthalmic lens made by above method, and an ophthalmic lens material making for the ophthalmic lens.

Abstract: Biodegradable particles for medical use and a vascular embolization material have improved flexibility, cause less aggregation among particles, and have improved particle shape-recovering ability after passing through a catheter or the like. The biodegradable particles for medical use are composed of an A1-B-A2 type triblock copolymer, wherein A1 and A2 are each a block of biodegradable copolymer constituted of monomers including glycolic acid, lactic acid and 6-hydroxycaproic acid, and B is a block of water-soluble polymer.

Abstract: A variety of thermochromic build materials are disclosed for use in color-controlled three-dimensional printing. By providing materials that exhibit a final color dependent upon heat applied during a melt or extrusion process, objects can be fabricated having a user-controlled color that varies from object to object, or within a single object.

Abstract: A process for copolymerizing selectively i) ethylene carbonate with ii) one or more cyclic esters can include contacting the ethylene carbonate with the one or more cyclic esters in the presence of a catalyst. The catalyst can be a Zn-complex with a diaminophenolate ligand (NNO) or a ?-diiminate ligand (BDI).

Abstract: Poly(carbonate-urethane) or poly(ester-urethane) may be characterized in that of carbonate soft segments have molecular weights Mn ranging between 10,000 and 250,000 g/mol. The segments' length may be monitored by the ring-opening polymerization condition. The process of preparing the poly(carbonate-urethane) or poly(ester-urethane) may include immortal ring-opening polymerization of a cyclic carbonate or of a cyclic ester or diester monomers in the presence of a first catalyst system and diols or polyols. The process may include chemical modification of the hydroxyl chain-end groups into carboxylic groups in the presence of a second catalyst system. The process may include a coupling reaction with at least 2 equivalents of a second cyclic carbonate, enabling coupling with the carboxylic moiety in the presence of a third catalyst system.

Abstract: Provided is a polylactic acid resin composition which has excellent flexibility and heat resistance without decreasing a biomass degree. The polylactic acid resin composition includes a polylactic acid and a branched polylactic acid having at least three branched chains composed of a polylactic acid in the molecule can be obtained. This polylactic acid resin composition is very superior due to the following reasons: the resin composition has excellent flexibility because plasticization is accelerated; the resin composition has excellent heat resistance because crystallization is accelerated; and the resin composition is effective in protection of the global environment and measures against fossil resource depletion because the resin composition is derived from a recyclable resource.

Abstract: Quantum-dot binding ligands with easy to synthesize alkyl-acids are provided. The quantum-dot binding ligands include a multiplicity of carboxy binding ligands in combination with an alkyl backbone, and optionally a solubilizing group. The ligands and coated nanostructures of the present invention are useful for close packed nanostructure compositions, which can have improved quantum confinement and/or reduced cross-talk between nanostructures.

Abstract: A primary object of the present invention is to provide a polylactic acid decomposition method that efficiently decomposes polylactic acid so that the polylactic acid can readily undergo degradation by a biological treatment such as methane fermentation. Specifically, the present invention provides a polylactic acid decomposition method involving a step of impregnating a polylactic acid-containing organic material with a treatment solution containing an organic acid salt and/or inorganic acid salt of an amine compound.

Abstract: A bioderived plasticizer for biopolymers includes a compatibilizing unit and a polyester plasticizing unit. The plasticizer improves the flexibility of biopolymers while not adversely affecting the modulus of the biopolymer. The compatibilizing unit renders the plasticizer more miscible with the desired base biopolymer, and may increase crystallization and includes a lower alkyl (C3 to C7) organic acid including enantiomeric isomers of the base polymer. The polyester plasticizing unit is formed from monomers comprising a multifunctional alcohol and an aliphatic anhydride or its equivalent dicarboxylic acid and ester derivatives. The polyester plasticizing unit may optionally include one or more difunctional alcohols in combination with the multifunctional alcohol. The resulting bioderived plasticizer lowers glass transition temperature (Tg), can improve brittleness, may increases heat deflection temperature and improves melt viscosity.

Abstract: The invention is directed towards methods and compositions for preventing dusting problems in mineral supplement. The method involves treating the mineral supplement or a dust releasing material with a composition comprising polymerized organic acid.

Abstract: A hyperbranched polymer based on one or more repeating units of an ABx type monomer, wherein A and B are functional groups and x is greater than or equal to 2, wherein A reacts with, or substantially reacts with, B, wherein B is fractionally functionlized with a plurality of functional groups comprising a first functional group comprising a C6-C30 alkyl chain attached to the repeating unit through a carbonyl group (C?O) via an ester linkage, a second functional group comprising a partially fluorinated or perfluorinated C20 alkyl chain attached to the repeating unit through a carbonyl group (C?O) via an ester linkage, and a third functional group comprising substantially one of a stabilized radical source attached to the repeating unit via a C0-C6 tether, or a 5 to 8 member chloroamide heterocycle of carbon and nitrogen that is attached to the repeating unit via a C2-C6 tether.

Abstract: The present disclosure relates to an apparatus and process for forming medical devices from an injectable composition. The apparatus includes a supply assembly configured to maintain and selective dispense a first precursor and a second precursor, a mixing assembly configured to mix the first and second precursors, and at least one catalyzing element including a transition metal ion to aid in the polymerization of the first and second precursors. The process includes dispensing a volume of the first precursor and a volume of the second precursor into a mixing assembly and mixing the first and second precursors. The first and second precursors each possess a core and at least one functional group known to have click reactivity with each other. The mixed precursors are contacted with a transition metal catalyst to produce a flowable composition for use as a medical device.

Abstract: A thermally degradable polymeric sheet, comprising: a poly(hydroxyalkanoate); and a metal selected from the group consisting of an alkali earth metal and a transition metal; where the volume fraction of the metal in the sheet is at least 0.1 vol %.

Abstract: Branched PHA compositions, and related methods and articles are disclosed.

Abstract: Compositions of biobased polymer blends of polymers and a polyhydroxyalkanoate copolymer are described. In certain embodiments, the copolymer is a multiphase copolymer blend having one phase a glass transition temperature of about ?5° C. to about ?50° C. Methods of making the compositions of the invention are also described. Also articles, films and laminates made from the compositions are described.

Abstract: Disclosed herein is a method for preparing a polycondensation resin. The method includes preparing a low degree condensate; and solid phase polymerizing the low degree condensate, wherein a granular molded article is introduced into the solid phase polymerization. The method enables efficient manufacture of high quality resins without problems such as agglomeration or scaling of a low degree condensate in pipes.

Abstract: A hyperbranched polymer based on one or more repeating units of an ABx type monomer, wherein A and B are functional groups and x is greater than or equal to 2, wherein A reacts with, or substantially reacts with, B, wherein B is fractionally functionlized with a plurality of functional groups comprising a first functional group comprising a C6-C30 alkyl chain attached to the repeating unit through a carbonyl group (C?O) via an ester linkage, a second functional group comprising a partially fluorinated or perfluorinated C3-C20 alkyl chain attached to the repeating unit through a carbonyl group (C?O) via an ester linkage, and a third functional group comprising substantially one of a stabilized radical source attached to the repeating unit via a C0-C6 tether, or a 5 to 8 member chloroamide heterocycle of carbon and nitrogen that is attached to the repeating unit via a C2-C6 tether.