Solid Polymer Derived From -n=c=x Reactant And Polyhydroxy Reactant Patents (Class 525/453)
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Patent number: 12152342Abstract: The present invention provides ink and coating compositions for printing on non-woven substrates or fabrics. Advantageously, the compositions of the invention can be used either as one component (1K) or two component (2K) ink systems. The compositions of the invention exhibit improved properties, such as ink adhesion ratings, as shown by a rub test, compared to commercially available inks designed to be printed on non-woven substrates.Type: GrantFiled: April 22, 2021Date of Patent: November 26, 2024Assignee: Sun Chemical CorporationInventors: Alex Chudolij, Richard Bianchi, Arnold Gibaldi
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Patent number: 12006455Abstract: The present invention relates to an adhesive printing form attachment layer comprising a support, and a permanently sticky layer suitable for receiving a printing form and fixing a printing form during a printing operation provided on the support, wherein the permanently sticky layer comprises a crosslinked structure obtained by crosslinking a crosslinkable composition comprising at least one polyurethane-based polymeric compound that has two or more crosslinkable groups, which are preferably ethylenically unsaturated groups, and two or more —NHC(O)O— linkages. A method of preparing the adhesive printing form attachment layer and of operating a printing machine using the adhesive printing form attachment layer are also disclosed.Type: GrantFiled: January 8, 2021Date of Patent: June 11, 2024Assignee: tesa SEInventor: Nils Thebud
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Patent number: 11993000Abstract: The present invention relates to systems and methods for solid freeform fabrication, especially fused deposition modeling, as well as various articles made using the same, where the systems and methods utilize certain thermoplastic polyurethanes which are particularly suited for such processing. The useful thermoplastic polyurethanes are derived from (a) a polyisocyanate component, (b) a polyol component, and (c) an optional chain extender component where the resulting thermoplastic polyurethane has a crystallization temperature above 80° C. and retains more than 20% of its shear storage modulus at 100° C. relative to its shear storage modulus at 20° C.Type: GrantFiled: May 17, 2021Date of Patent: May 28, 2024Assignee: Lubrizol Advanced Materials, Inc.Inventors: John M. Cox, Joseph J. Vontorcik, Jr., Edward W. Ault
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Patent number: 11866648Abstract: A process for producing a polymerizable composition for optical materials of the present invention includes a step A of mixing together a polyisocyanate compound (i), a polymer (ii) represented by General Formula (ii), a photochromic compound (iii), and an internal release agent (iv), a step B of mixing a mixed solution obtained by the step A with a polythiol compound (v), and a step C of further mixing a mixed solution obtained by the step B with a polymerization catalyst (vi) so as to obtain a polymerizable composition for optical materials, wherein in the step A, the internal release agent (iv) is added so that a content thereof in the polymerizable composition for optical materials is 500 to 3,000 ppm, and in the step C, the polymerization catalyst (vi) is added so that a content thereof in the polymerizable composition for optical materials is 120 to 500 ppm. R1A1—R2—A2—R3]n??(ii).Type: GrantFiled: January 29, 2020Date of Patent: January 9, 2024Assignee: MITSUI CHEMICALS, INC.Inventors: Yuuki Kasori, Nobuo Kawato
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Patent number: 11859109Abstract: Disclosed are polyurethane adhesive compositions which include (a) one or more urethane prepolymers having isocyanate moieties; (b) a catalytic amount of one or more catalysts; (c) one or more fillers; (d) one or more silane adhesion promoters; and (e) one or more monofunctional polyalkylene glycols.Type: GrantFiled: June 14, 2019Date of Patent: January 2, 2024Assignee: DDP SPECIALTY ELECTRONIC MATERIALS US, LLCInventors: Dietmar Golombowski, Sergio Grunder
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Patent number: 11834548Abstract: Method of making a golf ball comprising the steps of: providing a subassembly; forming about the subassembly at least one layer comprised of a thermoset polyurethane which is prepared by mixing as the essential ingredients: (i) at least one long chain soft segment polyol and/or polyamine; (ii) at least one short chain-extending-type species; (iii) at least one isocyanate; and (iv) at least one additional chain-extending-type species; wherein essential ingredients (i) and (ii) are combined (reacted/mixed) to form a first sub-mixture; followed by combining/mixing the first sub-mixture and essential ingredient (iii) to form a prepolymer second sub-mixture; followed by combining (reacting/mixing) the prepolymer second sub-mixture with essential ingredient (iv) to form the thermoset polyurethane.Type: GrantFiled: March 1, 2021Date of Patent: December 5, 2023Assignee: Acushnet CompanyInventor: Michael Michalewich
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Patent number: 11820890Abstract: The present disclosure is directed to pulverulent thermoplastic polymer blends comminuted to a particle size of less than 300 ?m. The pulverulent thermoplastic polymer blends can include a first thermoplastic polyurethane and a second thermoplastic polyurethane at a weight ratio of from about 90:10 to about 30:70 first thermoplastic polyurethane to second thermoplastic polyurethane. The first thermoplastic polyurethane can include a reaction product of a first reaction mixture consisting of or consisting essentially of an aliphatic diisocyanate having a number average molecular weight of from 140 g/mol to 170 g/mol and an aliphatic diol having a number average molecular weight of from 62 g/mol to 120 g/mol.Type: GrantFiled: April 1, 2021Date of Patent: November 21, 2023Inventors: Liang Chen, Chen Xu, Leslie J. Vescio, Bruce D. Lawrey
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Patent number: 11697282Abstract: The method for the production of curved furniture components comprises: an overlapping step of a first panel of wooden, plastic or metal material, of at least one intermediate separating layer and of a second panel of wooden, plastic or metal material for obtaining a flat semi-finished product having a perimeter edge; an interposition step of a polyurethane type adhesive between the intermediate layer and the first panel and second panel by hot dispensing of said adhesive on the surfaces of the first and the second panels which are adapted to be associated with the intermediate layer or by hot dispensing of the adhesive on the surfaces of the intermediate layer which are adapted to be associated with said first panel and second panel; a cold shaping step of the semi-finished product for obtaining a curved component; and a spraying step of a water-based auxiliary substance between the intermediate layer and at least one of the first panel and the second panel, subsequent to the interposition of the adhesiveType: GrantFiled: August 2, 2018Date of Patent: July 11, 2023Assignee: Technoform S.p.a.Inventor: Alessandro Rossodivita
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Patent number: 11628408Abstract: A bilayer electrospun membranes for treating hydraulic fracking wastewater via membrane distillation, and more particularly to bilayer electrospun membranes having an omniphobic layer to prevent low-surface tension solution wicking and an oleophobic antifouling surface to prevent foulant depositing on the membrane. Nanoparticles are decorated on the omniphobic surface through electrochemical interaction, which is coated with a fluorine monomer on the nanoparticles. A zwitterionic co-polymer is grafted using self-assembly between hydroxy groups on the antifouling surface generated by alkaline treatment and anchor segment epoxy groups on zwitterionic co-polymer.Type: GrantFiled: June 8, 2021Date of Patent: April 18, 2023Assignee: Board of Trustees of the University of ArkansasInventors: Jorge Almodovar, Ranil Wickramasinghe, Yu-Hsuan Chiao, David Alfonso Castilla-Casadiego
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Patent number: 11535707Abstract: The present invention is directed to a process for preparing light curable energetic polymeric binders. The process for preparing such binder comprises the steps of mixing a pre-polymer such as PGN or GAP having a terminal hydroxyl group with a solvent and adding reactants wherein the reactant has a light curable moiety and a pre-polymer reactive moiety. Catalysts such as carbodiimide and DMAP may be further added to the mixture.Type: GrantFiled: August 14, 2019Date of Patent: December 27, 2022Assignee: United States of America as Represented by the Secretary of the ArmyInventors: Alexander Paraskos, Edward D. Cooke, Eric R. Beckel
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Patent number: 11525069Abstract: Durable, anti-fouling, crosslinked zwitterionic coatings that are grafted to the surface of a substrate through covalent bonding are disclosed. When exposed to a light source, zwitterionic monomers react with a crosslinker and with activated radicals at the surface of the substrate, simultaneously forming the crosslinked zwitterionic coating and anchoring it to the surface of the substrate. Photomasking techniques can be used to micropattern the zwitterionic coatings. The zwitterionic coatings can be applied to a variety of substrates, including medical devices and systems.Type: GrantFiled: June 24, 2017Date of Patent: December 13, 2022Assignee: UNIVERSITY OF IOWA RESEARCH FOUNDATIONInventors: Elise Lin Cheng, C. Allan Guymon, Marian R. Hansen, Braden Leigh
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Patent number: 11365281Abstract: A coating composition includes a blocked urethane elastomer (A) containing a terminal isocyanate group blocked with an oxime compound and having a number average molecular weight of 800 to 5,000, an aromatic diamine compound (B) containing an electron-donating group, and an amide compound (C). An equivalent ratio (amino group/isocyanate group) of the amino group of the aromatic diamine compound (B) to the isocyanate group of the blocked urethane elastomer (A) is within a range of 1.0 to 2.0. A solid content of the amide compound (C) is within a range of 0.5 mass % to 5 mass % based on a total solid content of the blocked urethane elastomer (A) and the aromatic diamine compound (B).Type: GrantFiled: October 11, 2019Date of Patent: June 21, 2022Assignee: KANSAI PAINT CO.. LTD.Inventors: Mayu Kawagishi, Katsuto Komura
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Patent number: 11091638Abstract: The present invention relates to a shock-absorbing nanostructured polymer alloy, comprising: a (meth)acrylic polymer matrix comprising one or more (meth)acrylic polymer(s), said (meth)acrylic polymer matrix forming a (meth)acrylic network, and, at least one polyborodimethylsiloxane (PBDMS) distributed in the (meth)acrylic polymer matrix, the polyborodimethylsiloxane forming a network, the polyborodimethylsiloxane network and the (meth)acrylic network being intertwined. The invention also relates to a chemical composition for the manufacture of such an alloy as well as a process for manufacturing a part made of such an alloy.Type: GrantFiled: December 18, 2017Date of Patent: August 17, 2021Assignees: RHEONOVA, Centre National de la Recherche Scientifique (CNRS)Inventors: Jérémy Patarin, Guillaume Darsy, Yahya Rharbi
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Patent number: 10982035Abstract: A polyurethane resin having an anionic group and a polyalkylene oxide in a side chain thereof is obtainable by reacting a polyester polyol, a polyether diol, a polyol containing an anionic group, and a polyisocyanate, and the polyester polyol is obtained by reacting an aromatic polycarboxylic acid and a polyol. The polyurethane resin can be used as binder in an ink jet ink and provides excellent scratch and solvent resistance of printed images.Type: GrantFiled: October 12, 2017Date of Patent: April 20, 2021Assignee: AGFA NVInventors: Hubertus Van Aert, Ellen Bertels, Johan Loccufier
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Patent number: 10947430Abstract: Disclosed is a tire with reduced cavity noise including an adhesive agent layer applied to an inside of an inner liner and a sound absorber layer attached to the adhesive agent layer, wherein the adhesive agent layer includes poly(ether-urethane) containing alkoxysilane at both ends thereof. The tire with reduced cavity noise is stable without causing separation of a sound absorber even upon heating and deformation during driving.Type: GrantFiled: March 11, 2018Date of Patent: March 16, 2021Inventors: Byeong Ho Seo, Ju Geon Park, Chang Hwan Kang, Hak Joo Kim
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Patent number: 10669370Abstract: Compositions and curing agents comprising a benzylated Mannich base composition. The benzylated Mannich base composition includes a reaction product of (a) a substituted phenolic compound having at least one substituent of formula (I): wherein R1 is each independently a linear or branched alkyl group having 1 to 4 carbon atoms, and R2 is hydrogen, methyl, ethyl or phenyl, with (b) a benzylated polyalkylene polyamine (II): wherein RA is substituted or unsubstituted benzyl; RB is each independently RA, or a hydrogen atom, or a group selected from C1-C16 linear, cyclic, and branched alkyl, alkenyl, and alkaryl groups; X, Y, and Z are independently selected from C2-C10 alkylene, and cycloalkylene groups; y is an integer from 0 to 7, and z is an integer from 0 to 4; and, optionally, (c) a multifunctional amine. Amine-epoxy compositions and articles produced from these compositions are also disclosed.Type: GrantFiled: February 22, 2017Date of Patent: June 2, 2020Assignee: Evonik Operations GmbHInventors: Shiying Zheng, Gamini Ananda Vedage, Marcelo Rufo, Daniel Iliev Totev, Michael Cook
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Patent number: 10633568Abstract: Disclosed is an adhesive for laminated sheets comprising a urethane resin obtained by blending: (A) an acrylic polyol; (B) at least one component selected from carboxylic acids and carboxylic anhydrides; and (C) an isocyanate compound. The acrylic polyol (A) is obtained by polymerization of a polymerizable monomer, has a glass transition temperature of from ?35 ° C. to 20° C., and has a hydroxyl value of from 0.5 to 40 mgKOH/g. The adhesive for laminated sheets is excellent in initial adhesion to a film, peel strength after aging and hydrolysis resistance for a long time under high temperature when a laminated sheet is produced, and wherein the adhesive does not impart an adverse effect to the appearance of the laminated sheet and the lamination process of films while improving the curability. The laminated sheet is suitably prepared using the adhesive for laminated sheets. An article comprising the laminated sheet can be prepared using the laminated sheet.Type: GrantFiled: June 2, 2017Date of Patent: April 28, 2020Assignee: Henkel AG & Co. KGaAInventors: Shoko Ito, Noriyoshi Kamai, Yasushi Yamada, Hitoshi Ikeda
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Patent number: 10519287Abstract: The invention relates to compositions comprising a fiber material and a specific thermoplastic binder. The thermoplastic binder comprises at least one thermoplastic polyurethane polymer, wherein said thermoplastic polyurethane polymer comprises a reaction product of (i) at least one semi-crystalline polyester polyol, and (ii) at least one polyisocyanate. The molar ratio of the NCO groups of said polyisocyanate (ii) to the sum of OH groups of said polyester polyol (i) is less than 1.00:1 and the thermoplastic polyurethane polymer has (a) a melting enthalpy of at least 20 J/g, (b) a melting point (Tm) of >70° C., and (c) an average number molecular weight (Mn) of 5,000 to 80,000 g/mol. Furthermore, the present invention relates to a fiber-reinforced composite comprising a cured thermosetting polyurethane polymer matrix reinforced by the composition according to the present invention.Type: GrantFiled: June 14, 2019Date of Patent: December 31, 2019Assignee: Henkel AG & Co. KGaAInventors: Andreas Niegemeier, Andreas Ferencz, Tamara Schmidt, Wolfgang Lupp, Tim Maeling
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Patent number: 10464187Abstract: A CMP polishing pad for polishing a semiconductor substrate is provided containing a polishing layer that comprises a polyurethane reaction product of a reaction mixture comprising a (i) curative of from 15 to 30 wt. % of an amine initiated polyol having an average of from 3 to less than 5 hydroxyl groups and a number average molecular weight of 150 to 400, and from 70 to 85 wt. % of an aromatic diamine and a (ii) polyisocyanate prepolymer having a number average molecular weight of from 600 to 5,000 and having an unreacted isocyanate content ranging from 6.5 to 11%. The CMP polishing pad has a tunable tan-delta peak temperature at from 50 to 80° C. which has a value of from 0.2 to 0.8 at the tan-delta peak temperature and is useful for polishing a variety of substrates.Type: GrantFiled: December 1, 2017Date of Patent: November 5, 2019Assignee: Rohm and Haas Electronic Materials CMP Holdings, Inc.Inventors: Bainian Qian, Kancharla-Arun K. Reddy, George C. Jacob, Marty W. DeGroot
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Patent number: 10385167Abstract: The present invention relates to polyoxazolidinone compounds, a method for the production of polyoxazolidinone compounds, comprising the step of reacting a biscarbamate compound with a bisepoxide compound in the presence of a mono-carbamate, a mono-isocyanate and/or a mono-epoxide compound as chain regulator and a suitable base having a pKb value of ?9 as catalyst. The invention further relates to the use of polyoxazolidinone compounds with high thermal stability.Type: GrantFiled: February 9, 2016Date of Patent: August 20, 2019Assignee: Covestro Deutschland AGInventors: Thomas Ernst Müller, Christoph Gürtler, Susmit Basu, Claudine Rangheard, David Rivillo, Walter Leitner, Burkhard Köhler
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Patent number: 10259904Abstract: A binder for capacitive deionization electrode is provided, which is formed by reacting a polyether polyol, a diisocyanate, and a diol having a hydrophobic side chain. The binder may bind an electrode material and to form a capacitive deionization electrode. The electrode material and the binder may have a weight ratio of 90:5 to 90:25.Type: GrantFiled: December 29, 2015Date of Patent: April 16, 2019Assignee: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Po-I Liu, Li-Ching Chung, Teh-Ming Liang, Ren-Yang Horng, Hsin Shao, Ruei-Shin Chen, Hsu-Tzu Fan, Chih-Hsiang Fang, Min-Chao Chang
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Patent number: 10106660Abstract: Disclosed is a film composed of a resin having a thiourethane bond, wherein the molar ratio (S/N) of sulfur to nitrogen contained in the resin is equal to or more than 0.8 and less than 3. A method for manufacturing a film is also disclosed. The disclosed film is excellent in a balance among high refractive index, low birefringence and light transmittance, and further excellent in a balance of mechanical characteristics such as toughness, hardness and dimensional stability, so that effects of deformation and the like during processing are very small, and the film is further excellent in solvent resistance as well.Type: GrantFiled: May 20, 2016Date of Patent: October 23, 2018Assignee: MITSUI CHEMICALS, INC.Inventors: Hisako Ishikawa, Toshinori Matsuda, Yosuke Ono, Kazuo Yagi, Akifumi Kagayama
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Patent number: 9822290Abstract: A composition comprising: a one part adhesive composition comprising a) one or more isocyanate components; b) one or more catalysts for the reaction of isocyanate groups with active hydrogen containing groups; c) one or more fillers which do not enhance the formation of voids during curing; d) one or more fillers having basic character; and a cure accelerator comprising: e) one or more liquid carriers; f) water; and g) one or more paste forming agents. The one part adhesive composition may be used alone where ambient temperature and humidities afford reasonably rapid cure rates. The cure accelerator may be used when temperatures and/or humidities are sufficiently low such that the cure rate of the adhesive alone is not acceptable for a particular use.Type: GrantFiled: July 22, 2016Date of Patent: November 21, 2017Assignee: DOW GLOBAL TECHNOLOGIES LLCInventors: Huide D. Zhu, Daniel P. Sophiea, Matthew B. Feldpausch
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Patent number: 9781836Abstract: A thermosetting resin composition which contains a polyurethane resin and a curing agent, the polyurethane resin including a constitutional unit derived from an alicyclic diol and having an acid value of 10 to 35 mgKOH/g.Type: GrantFiled: October 5, 2010Date of Patent: October 3, 2017Assignee: HITACHI CHEMICAL COMPANY, LTD.Inventors: Iori Hukushima, Tomohiro Hirata, Hidekazu Kondou, Susumu Kaneko, Satoshi Uehara, Yuki Miyamoto
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Patent number: 9617390Abstract: The present invention is directed to binder based on an alkoxy- and/or silanol-functional polysiloxane A), one or more dicarboxylic or polycarboxylic acids B), one or more di- or polyols C), one or more di- or polyisocyanates and one or more aminosilanes D1) or one or more isocyanatosilanes D2), the constituents A) to D1) or D2) being present condensed with one another in the binder.Type: GrantFiled: August 25, 2014Date of Patent: April 11, 2017Assignee: Evonik Degussa GmbHInventors: Dirk Hinzmann, Barbel Wolff, Thomas Klotzbach, Jessica Leyers, Sascha Herrwerth
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Patent number: 9428678Abstract: A composition comprising: a one part adhesive composition comprising a) one or more isocyanate functional components; b) one or more catalysts for the reaction of isocyanate groups with active hydrogen containing groups; c) one or more fillers which do not enhance the formation of voids during curing; d) one or more fillers having basic character; and a cure accelerator comprising: e) one or more liquid carriers; f) water; and g) one or more paste forming agents. The one part adhesive composition may be used alone where ambient temperature and humidities afford reasonably rapid cure rates. The cure accelerator may be used when temperatures and/or humidities are sufficiently low such that the cure rate of the adhesive alone is not acceptable for a particular use.Type: GrantFiled: March 4, 2013Date of Patent: August 30, 2016Assignee: DOW GLOBAL TECHNOLOGIES LLCInventors: Huide D. Zhu, Daniel P. Sophiea, Matthew B. Feldpausch
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Patent number: 9376574Abstract: The present invention relates to a method for producing a multilayer coating film, which comprises steps of applying a waterborne intermediate coating composition on an electrodeposited coating film to form an intermediate coating film; applying a waterborne base coating composition on the intermediate coating film to form a base coating film; applying a clear coating composition on the base coating film to form a clear coating film; and simultaneously baking and curing the intermediate coating film, the base coating film applied thereon, and the clear coating film further applied thereon in order to form a multilayer coating film, wherein the waterborne intermediate coating composition comprises an emulsion of a hydroxyl group-containing acrylic resin comprising 27 to 65% by weight of a styrene monomer, wherein the emulsion has a water-tolerance within a range of from 0.Type: GrantFiled: April 21, 2009Date of Patent: June 28, 2016Assignees: NIPPON PAINT CO., LTD., TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Kouki Hayashi, Daichi Kato, Junya Ogawa
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Patent number: 9221984Abstract: The present disclosure provides an aqueous dispersion containing a colorant and a polyurethane dispersant, wherein the polyurethane dispersant is a polymer having a cross-linkable moiety, wherein the cross-linkable moiety is cross-linked, with a cross-linking agent.Type: GrantFiled: July 13, 2011Date of Patent: December 29, 2015Assignee: E I DU PONT DE NEMOURS AND COMPANYInventors: Xiaoqing Li, Charles T Berge, Christian Jackson, C Chad Roberts, Tristan Williams
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Patent number: 9156981Abstract: Moisture-curable compositions are provided which comprises a moisture-curable silylated resin, a flexibilizer and at least one curing catalyst. The cured compositions possess enhanced elongation and tear properties, and are highly suitable for applications such as adhesives, sealants, coatings, gaskets, industrial rubber goods, and the like.Type: GrantFiled: July 24, 2013Date of Patent: October 13, 2015Assignee: Momentive Performance Materials Inc.Inventors: Thomas Fay-Oy Lim, Vikram Kumar, Martin Wusik
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Publication number: 20150144486Abstract: A polymeric film composition and a non-enzymatic glucose sensor including the functional polymeric film are provided. The polymeric film composition includes polyurethane and perfluorosulfonic acid polymer.Type: ApplicationFiled: November 26, 2014Publication date: May 28, 2015Applicants: INSTITUTE FOR RESEARCH & INDUSTRY COOPERATION, PNU, SAMSUNG ELECTRONICS CO., LTD.Inventors: Chulho CHO, Yoon-Bo SHIM, Jaehong KIM, Suntae JUNG, Seongje CHO, Jaegeol CHO
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Patent number: 9037069Abstract: In a method for producing a cleaning blade, a first composition obtained by causing a reaction of diphenylmethane diisocyanate and a first aliphatic polyester polyol which has a number-average molecular weight of 2000 to 3500 and is used in an amount of 20 to 40 mol % relative to the diphenylmethane diisocyanate and a second composition containing a urethane rubber-synthesizing catalyst and a second aliphatic polyester polyol which has a number-average molecular weight of 2000 to 3500 and is the same as or different from the first aliphatic polyester polyol are mixed so that a relationship between a number of moles (MNCO [mol]) of an NCO group in the first composition and a number of moles (MOH [mol]) of an OH group in the second composition satisfies 0.05?MOH/MNCO?0.20.Type: GrantFiled: April 28, 2014Date of Patent: May 19, 2015Assignee: Canon Kabushiki KaishaInventors: Masahiro Watabe, Masaya Kawada, Tomohiro Tanoue
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Publication number: 20150132248Abstract: Antimicrobial quaternized polyurethane materials and methods of forming and using the materials are disclosed. The quaternized polyurethane antimicrobial materials may be synthesized from one or more diisocyanates and one or more diols or triols. The quaternized polyurethane materials may be stand alone or coated onto other surfaces, such as medical devices, table tops, air/water filters, or the like to provided desired antimicrobial devices and surfaces.Type: ApplicationFiled: May 1, 2013Publication date: May 14, 2015Inventor: Daewon Park
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Patent number: 9028343Abstract: The present invention provides a golf ball comprising a spherical core and at least one cover layer covering the spherical core, wherein the cover is formed from a polyurethane composition containing a polyurethane elastomer as a resin component, the polyurethane composition satisfying properties of rebound resilience of 54% or more and a shear loss modulus G? of 5.03×106 Pa or less when measured in a shear mode using a dynamic viscoelasticity measuring apparatus at the conditions of the temperature of 0° C., and the oscillation frequency of 10 Hz, and the spherical core has a hardness distribution that R2 of a linear approximate curve determined by a least-squares method is 0.95 or more, when plotting JIS-C hardness measured at a center, a surface and at intervals of 2.5 mm from the center of the spherical core, versus distances from the center of the spherical core.Type: GrantFiled: August 30, 2012Date of Patent: May 12, 2015Assignee: Dunlop Sports Co., Ltd.Inventors: Toshiyuki Tarao, Kazuyoshi Shiga, Chiemi Mikura, Kazuhisa Fushihara
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Patent number: 9018317Abstract: A method for producing a pigment dispersion composition having excellent image density, dispersibility, and storage stability, has high resolubility, and forms an ink film having excellent marker resistance and scratch resistance. The method includes bringing a pigment (I) having a surface acidic group and a basic compound (II) having two or more ammo groups selected from a primary amino group and a secondary amino group in its molecule, into contact with each other in an aqueous medium to prepare a pigment having an unreacted surface amino group, bringing the pigment into contact with a polyisocyanate polyurethane resin (III) having two or more isocyanate end groups so that the pigment and the polyisocyanate polyurethane resin are bonded via a urea bond to prepare a dispersion of a polyurethane resin-bonded pigment (A), and heating the dispersion of the polyurethane resin-bonded pigment (A) at 40 to 100° C. for 1 to 30 days.Type: GrantFiled: February 7, 2012Date of Patent: April 28, 2015Assignee: Tokai Carbon Co., Ltd.Inventors: Asami Takenaka, Shigehiro Tanaka, Yukari Ishibashi
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Patent number: 9018319Abstract: A radical-curable hot-melt urethane resin composition includes 100 parts by mass of a hot-melt urethane (X) having a (meth)acryloyl group and 0.5 to 5.0 parts by mass of a radical polymerization initiator (Y), wherein the hot-melt urethane (X) is obtained by introducing, using a (meth)acrylate compound (D) having an active-hydrogen-containing group, a (meth)acryloyl group into a hot-melt urethane prepolymer (C) that has isocyanate groups at its terminals and is obtained by a reaction of a polyol (A) and an alicyclic polyisocyanate (B), the polyol (A) containing an aliphatic polycarbonate polyol (a1), an alicyclic polycarbonate polyol (a2), or an aliphatic polyether polyol (a3), in an amount of more than 50 mol % and 100 mol % or less of the total number of isocyanate groups of the urethane prepolymer (C).Type: GrantFiled: December 21, 2011Date of Patent: April 28, 2015Assignee: DIC CorporationInventors: Yoshinori Kanagawa, Daichi Higuchi, Tamotsu Sakamoto
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Patent number: 9012575Abstract: The present invention relates to epoxy group-terminated polymers of the formula (I). Said epoxy group-terminated polymers are suited extremely well as impact resistance modifiers, particularly in epoxy resin compositions. They are particularly suited for use in heat-curing epoxy resin adhesives. It has been found that such epoxy resin compositions not only have excellent mechanical properties and high glass transition temperatures, but also above all improved impact resistance properties, both at room temperature and at low temperatures.Type: GrantFiled: March 20, 2008Date of Patent: April 21, 2015Assignee: Sika Technology AGInventors: Jürgen Finter, Andreas Kramer
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Publication number: 20150105602Abstract: A polymeric radiation-source with customized geometries to maximize receipt of radiation into treatment areas that is formed from either radioisotopes molecularly bonded to a polymer or radioisotopes encased within a polymer.Type: ApplicationFiled: April 2, 2014Publication date: April 16, 2015Applicant: IP LIBERTY VISION CORPORATIONInventors: Paul T. FINGER, Toby WELLES, Jaime SIMON
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Patent number: 9006375Abstract: A method for preparing a polyurethane elastomer, the method comprising mixing an isocyanate terminated prepolymer and a nitrogen-containing organic salt to form a prepolymer mixture and reacting the prepolymer in the prepolymer mixture with a methylenedianiline metal salt coordination complex chain extender to form the polyurethane elastome. The nitrogen-containing organic salt is selected from the group consisting of an ammonium salt, an imidazolium salt, a pyridinium salt, a pyrrolidinium salt, a piperidinium salt, and a morpholinium salt.Type: GrantFiled: March 10, 2014Date of Patent: April 14, 2015Assignee: Chemtura CorporationInventors: Thomas R. Doyle, Mark P. Ferrandino, Ronald O. Rosenberg
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Publication number: 20150083326Abstract: The present invention encompasses polyurethane adhesive compositions comprising aliphatic polycarbonate chains. In one aspect, the present invention encompasses polyurethane adhesives derived from aliphatic polycarbonate polyols and polyisocyanates wherein the polyol chains contain a primary repeating unit having a structure. In another aspect, the invention provides articles comprising the inventive polyurethane compositions as well as methods of making such compositions.Type: ApplicationFiled: April 16, 2013Publication date: March 26, 2015Inventors: Scott D. Allen, Vahid Sendijarevic, James O'Connor
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Patent number: 8987374Abstract: The present invention provides a non-aqueous composition containing a particulate solid, an organic medium and a polyurethane dispersant having an essentially linear backbone and laterally attached solvent-solubilizing side chains of a polyester, a polyether, a polyacrylate or a polyolefin including mixtures of such side chains.Type: GrantFiled: May 3, 2010Date of Patent: March 24, 2015Assignee: The Lubrizol CorporationInventors: Stuart Nicholas Richards, Andrew James Shooter
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Patent number: 8987405Abstract: A golf ball having an over-indexed thermoplastic polyurethane elastomer cover that may be cross-linked. The golf ball may have an outer cover layer and an inner cover layer. The 100% modulus of the outer cover layer is less than that of the inner cover layer providing a soft feeling when hit.Type: GrantFiled: April 30, 2012Date of Patent: March 24, 2015Assignee: NIKE, Inc.Inventors: Yasushi Ichikawa, Thomas J. Kennedy, III, Chen-Tai Liu, Chien-Hsin Chou, Hui-Kai Liao
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Patent number: 8981005Abstract: Disclosed are coating compositions comprising polycarbodiimides having onium salt groups, as well as relating methods and coated substrates.Type: GrantFiled: February 12, 2009Date of Patent: March 17, 2015Assignee: PPG Industries Ohio, Inc.Inventors: Anthony M. Chasser, Lawrence J. Fitzgerald, Venkateshwarlu Kalsani
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Patent number: 8980155Abstract: An over-indexed, optionally cross-linked thermoplastic polyurethane elastomer. Also, the method of making the elastomer, and articles, including golf balls, comprising the elastomer.Type: GrantFiled: January 3, 2012Date of Patent: March 17, 2015Assignee: NIKE, Inc.Inventors: Yasushi Ichikawa, Thomas J. Kennedy, III
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Publication number: 20150064382Abstract: A composition includes 50 to 95 weight percent of a thermoplastic polyurethane, and 5 to 50 weight percent of a particulate engineering plastic. The particulate engineering plastic has a glass transition temperature or a crystalline melting point greater than or equal to 200° C. and includes a polyarylsulfone, a polyimide, a poly(phenylene sulfide), a semi-crystalline polyamide, or a combination thereof. Incorporation of the particulate engineering plastic into the thermoplastic polyurethane improves one or more of tensile strength, heat resistance, hardness, and char formation.Type: ApplicationFiled: August 30, 2013Publication date: March 5, 2015Inventor: Edward Norman Peters
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Publication number: 20150064500Abstract: An aspect of the present invention relates to a composition, which is a composition for a magnetic recording medium and comprises an isocyanate compound in the form of an adduct of a polyhydroxyl compound having one or more aromatic carbon rings and three or more hydroxyl groups per molecule with a polyisocyanate having two or more isocyanate groups per molecule.Type: ApplicationFiled: August 29, 2014Publication date: March 5, 2015Applicant: FUJIFILM CorporationInventors: Toshihide AOSHIMA, Kazutoshi KATAYAMA
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Patent number: 8962771Abstract: Elastomer composites are prepared by wetting particles of a natural or synthetic rubber with a liquid one-component moisture-curable resin composition and then exposing the wetted particles to moisture to cure the resin composition. The moisture-curable resin composition comprises (a) an isocyanate-terminated polyurethane prepolymer having an isocyanate content of from 0.5 to 12% by weight and (b) from 1 to 30%, based on the combined weight of components (a) and (b), of an epoxide or lactone compound having a molecular weight of from about 70 to about 1000 and which is miscible in the prepolymer at the relative proportions thereof that are present. In addition, the composition contains no more than 0.1% by weight of compounds having a primary or secondary amino group.Type: GrantFiled: May 26, 2011Date of Patent: February 24, 2015Assignee: Dow Global Technologies LLCInventors: Blndu Radhakrishnan, William Aaron Koonce
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Publication number: 20150044458Abstract: Disclosed is a semi-hardened pressure sensitive adhesive film to be used in the semi-hardened state and having excellent printing step absorption properties. The adhesive film according to the present invention contains a radial polymer composition and a cationic polymer composition, and the radial polymer composition is primarily cross-linked to maintain the semi-hardened state. When applied onto a substrate through a printing step, the present invention has excellent step absorption properties and adhesion properties and excellent durability even under high-temperature and high-humidity conditions.Type: ApplicationFiled: April 8, 2013Publication date: February 12, 2015Inventors: Min-Seok Song, Chan-Oh Yoon, Eun-Kyung Park, Bu-Gi Jung, Jang-Soon Kim
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Publication number: 20150025197Abstract: A process for preparing a reinforced and reactive thermoplastic composition having a continuous phase based on a thermoplastic polymer and dispersed therein is a discontinuous phase based on a reactive reinforcing agent that may be immiscible with the thermoplastic polymer is provided. A composition obtained by this process is also provided. The reinforcing agent is selected from the group consisting of epoxy resins, polyorganosiloxanes having SiH functional group(s), diisocyanates or polyisocyanates and mixtures thereof, comprises a grafting, a branching and/or a crosslinking, that are carried out in situ, by reactive compounding of these phases with a shear rate greater than 102 s?1, of the reinforcing agent onto the chain of the thermoplastic polymer, so that the discontinuous phase is dispersed homogeneously in the continuous phase in the form of nodules having a number-average size of less than 5 ?m.Type: ApplicationFiled: April 4, 2014Publication date: January 22, 2015Applicant: HutchinsonInventors: Nicolas Garois, Philippe Sonntag, Gregory Martin, Matthieu Vatan, Jacques Drouvroy
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Publication number: 20150025198Abstract: The invention relates to surface modifying macromolecules (SMMs) having high degradation temperatures and their use in the manufacture of articles made from base polymers which require high temperature processing. The surface modifier is admixed with the base polymer to impart alcohol and water repellency properties.Type: ApplicationFiled: February 24, 2014Publication date: January 22, 2015Applicant: Interface Biologics Inc.Inventors: Sanjoy MULLICK, Weilun CHANG, Alexandra PIOTROWICZ, Jeannette HO, Richard WITMEYER
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Patent number: 8936744Abstract: There are provided a fluorine-containing photocurable resin composition and a method of preparing a mold comprising the same and more particularly, a photocurable resin composition having chemical resistance, mechanical properties and high transmittance, etc. as well as being easily wetted with and released from thermosetting or photocurable resins for pattern formation regardless of additional surface treatment, as opposed to the existing polymer resin materials used for resin molds, and a method of preparing a resin mold using the same.Type: GrantFiled: July 7, 2010Date of Patent: January 20, 2015Assignee: Dongjin Semichem Co., Ltd.Inventors: Jae-won Yoo, Byung-uk Kim, Un-yong Kim, Eun-jin Kwak