Abstract: Phosphorus-containing compounds useful for flame retardant epoxy resins are disclosed. The flame retardant epoxy resins may be used to make electrical laminates. This invention is particularly useful in end use applications in which a low bromine or low halogen content is required or desired.

Abstract: The instant invention provides crosslinkable compositions, and method of producing the same. The non-aqueous single phase crosslinkable composition comprises: (a) a polyol having an average of 2 or more hydroxyl functional groups; (b) polyaldehyde, or acetal or hemiacetal thereof; and (c) an acid catalyst having pK of less than 6; and (d) optionally one or more organic solvents.

Abstract: Hyperbranched polycarbonates having stabilizing groups, prepared by reaction of (a) at least one compound having at least three alcoholic hydroxyl groups per molecule with (b) at least one reagent of the general formula I (c) and at least one reagent of the general formula X3-(A1)m-X4, where the variables are defined as follows: X1, X2 are identical or different and are selected from among halogen, C1-C10-alkoxy, C6-C10-aryloxy and O—C(?O)-halogen, X3 is a functional group selected from among OH, SH, NH2, NH—C1-C4-alkyl, iso-cyanate, epoxy, COOH, COOR12, C(?O)—O—C(?O), C(?O)—Cl, R12 is C1-C4-alkyl or C6-C10-aryl, A1 is a spacer or a single bond, m is zero or one. X4 is a group selected from among phenol groups, benzophenones, aromatic amines and nitrogen-comprising heterocycles, in each case substituted or unsubstituted.

Abstract: Phosphorus-containing compounds useful for flame retardant epoxy resins are disclosed. The flame retardant epoxy resins may be used to make electrical laminates. This invention is particularly useful in end use applications in which a low bromine or low halogen content is required or desired.

Abstract: The thermosetting, non-polymeric coating composition includes at least one monomeric material having a plurality of carbamate and/or urea groups, at least one crosslinker reactive with the at least one monomeric material, and a sag control agent that is a crystalline reaction product of an amine and an isocyanate.

Abstract: Phosphorus-containing compounds useful for flame retardant epoxy resins are disclosed. The flame retardant epoxy resins may be used to make electrical laminates. This invention is particularly useful in end use applications in which a low bromine or low halogen content is required or desired.

Abstract: Phosphorus-containing compounds useful for flame retardant epoxy resins are disclosed. The flame retardant epoxy resins may be used to make electrical laminates. This invention is particularly useful in end use applications in which a low bromine or low halogen content is required or desired.

Abstract: Phosphorus-containing compounds useful for flame retardant epoxy resins are disclosed. The flame retardant epoxy resins may be used to make electrical laminates. This invention is particularly useful in end use applications in which a low bromine or low halogen content is required or desired.

Abstract: Phosphorus-containing compounds useful for flame retardant epoxy resins are disclosed. The flame retardant epoxy resins may be used to make electrical laminates. This invention is particularly useful in end use applications in which a low bromine or low halogen content is required or desired.

Abstract: Phosphorus-containing compounds useful for flame retardant epoxy resins are disclosed. The flame retardant epoxy resins may be used to make electrical laminates. This invention is particularly useful in end use applications in which a low bromine or low halogen content is required or desired.

Abstract: Phosphorus-containing compounds are disclosed which are obtainable by reacting: (A) at least one organophosphorus compound having a group selected from the group H—P?O; the group P—H and the group P—OH; and (B) at least one compound having the following Formula (I): [R?(Y)m?]m(X—O—R?)n??Formula (I) wherein R? is an organic group; Y is a functional group selected from the group consisting of hydroxy, carboxylic acid, and amine; X is a hydrocarbylene group; R? is hydrogen or a hydrocarbyl group having from 1 to 8 carbon atoms, R is alkyl or aryl group having from 1 to 12 carbon atoms; m?, m and n are, independently, numbers equal to or greater than 1; and (C) a thermosetting or thermoplastic composition.

Abstract: Phosphorus-containing compounds useful for flame retardant epoxy resins are disclosed. The flame retardant epoxy resins may be used to make electrical laminates. This invention is particularly useful in end use applications in which a low bromine or low halogen content is required or desired.

Abstract: Multiblock copolymers are described and contain the structural unit of formula I -A-O—R1—O—CO—(R2—CO—)m—X-D-X—(CO—R2)m—CO—X—??(I), where A is a radical derived from a homo- or copolyoxymethylene, R1 is an alkylene radical-having at least two carbon atoms or a cycloalkylene radical, R2 is a direct carbon-carbon bond, or an alkylene, cycloalkylene, arylene, or aralkylene radical, X is selected from —O—, —S—, or —NH—, D is a divalent radical B which is a radical of a hydroxy-terminated, mercaptan-terminated, or amino-terminated polymer which derives from polyalkylene glycols, polyvinyl ethers, polyvinyl ether-alkene copolymers, polyvinyl esters, polyvinyl ester-alkene copolymers, polyvinyl alcohols, polyvinyl alcohol-alkene copolymers, polyvinylaromatics, polyacrylates, polymethacrylates, polyacetals, polycarbonates, polyesters, polyamides, polyimines, polyetherester elastomers, polyetheramide elastomers, polyalkadienes, polyurethanes, polyureas, polysiloxanes, or a triblock copolymer radical -PAO-B-PAO-, wh

Abstract: Film-forming materials include nonionic metal coordinating structures. Nonionic metal coordinating structures can coordinate metals, such as metal catalysts and metal substrates. Example film-forming materials can be the product of a poly-functional epoxide and a nucleophilic ligand having a nonionic metal coordinating structure, or the product of a poly-functional alcohol and an electrophilic ligand having a nonionic metal coordinating structure.

Abstract: A polymer blend consisting essentially of at least one thermoplastic polymer, and a polymer comprising structural units derived from a 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine is disclosed.

Abstract: A crosslinking agent which is an ungelled reaction product of (a) at least one aminoplast resin, (b) at least one polyfunctional polymer having functional groups reactive with aminoplast resin (a) and having a glass transition temperature of at least 15° C.; and (c) at least one compound different from (b) having active hydrogen groups reactive with aminoplast resin (a) is provided. Also provided is a method for preparing the crosslinking agent. Further provided is a powder coating composition which includes the crosslinking agent. Additionally provided is a multi-layer composite coating composition having a base coat layer and a top coat over the base coat deposited from the previously described powder coating composition. Coated substrates are also provided.

Abstract: This invention discloses a flame retarding thermoplastic resin composition, which is comprised of (i) a thermoplastic resin and (ii) a phenolic resin compound as a flame retardant, wherein the phenolic resin compound contains a nitrogen-containing heterocycle and phosphorus. Since the flame retarding thermoplastic resin composition of this invention does not contain halogen, and has excellent flame retardant properties and high heat resistance, it is useful in producing parts and products in the fields of electronics, electricity and automobile.

Abstract: A polycarbonate resin composition according to the present invention is suited to be used for medical supplies or appliances and shows a very low yellow discoloration when exposed to an ionizing radiation for sterilization. The polycarbonate resin composition comprises 100 parts by weight of a polycarbonate resin; 0.01 to 5 parts by weight of an aromatic compound containing oxy group or carbonyl group; and 0.01 to 5 parts by weight of at least one compound selected from the group consisting of: (A) a compound containing cyclic acetal group; (B) a sulfone compound; (C) a sulfoxide compound; (D) polyalkylene glycol, an ether of polyalkylene glycol or an ester of polyalkylene glycol; (E) a compound containing sulfonate group; and (F) an aromatic hydrocarbon-aldehyde resin.

Abstract: A lactone chain-extended polyester polyol of the present invention comprises the reaction product of a lactone and a previously chain-extended phenolic-based hydroxyl compound. The previously chain-extended phenolic-based hydroxyl compound may comprise the reaction product of (i) a lactone or an alkoxylating agent selected from the group consisting of alkylene oxides and alkylene carbonates, and (ii) a phenolic aralkylation polymer comprising the reaction product of a phenolic monomer having at least two free reactive positions; a styrene derivative; and a coupling agent. The previously chain-extended phenolic-based hydroxyl compound also may be chain-extended by reacting with a lactam to produce a lactam chain-extended polyester polyamide. The polyols and polyamides of the present invention provide unique combinations of hard and soft functionalities, which translates into materials exhibiting a unique combination of toughness and hardness.

Abstract: A resin matrix with resistances to alkali and acid such as a fluorene-containing epoxy acrylate and/or a benzocyclobutene resin includes at least any one of insulative organic particles and insulative composite particles having an organic component and an inorganic component with the total amount of these particles being in the range of 5-50% by volume, wherein the insulative organic particles and the organic component of the insulative composite particles are allowed to be corroded by either alkali or acid, and wherein not less than 90% by volume of the insulative organic particles and insulative composite particles have a particle diameter in the range of 1-20 micrometers.

Abstract: A lactone chain-extended polyester polyol of the present invention comprises the reaction product of a lactone and a previously chain-extended phenolic-based hydroxyl compound. The previously chain-extended phenolic-based hydroxyl compound may comprise the reaction product of (i) a lactone or an alkoxylating agent selected from the group consisting of alkylene oxides and alkylene carbonates, and (ii) a phenolic aralkylation polymer comprising the reaction product of a phenolic monomer having at least two free reactive positions; a styrene derivative; and a coupling agent. The previously chain-extended phenolic-based hydroxyl compound also may be chain-extended by reacting with a lactam to produce a lactam chain-extended polyester polyamide. The polyols and polyamides of the present invention provide unique combinations of hard and soft functionalities, which translates into materials exhibiting a unique combination of toughness and hardness.

Abstract: The objective of the invention is to produce a thermoplastic resin capable of producing a casting with a superior granular surface appearance like marble while maintaining the impact strength and other properties of the base resin. The present invention pertains to a thermoplastic composition with a granular surface appearance like marble produced by mixing and dispersing 0.001-10 parts by weight of thermosetting resin with 100 parts by weight of thermoplastic resin.

Abstract: The objective of the invention is to produce a thermoplastic resin capable of producing a casting with a superior granular surface appearance like marble while maintaining the impact strength and other properties of the base resin.The present invention pertains to a thermoplastic composition with a granular surface appearance like marble produced by mixing and dispersing 0.001-10 parts by weight of thermosetting resin with 100 parts by weight of thermoplastic resin.

Abstract: The invention relates to a process for preparing a composition contains a polymer and a crosslinking agent which comprises mixing a polymer that is solid at room temperature with a crosslinking agent, the polymer and the crosslinker having complementary reactive groups, at a temperature at which the viscosity of the polymer (measured according to Emila) is less than 5000 dpas, in a means for achieving a homogeneous composition in such a short time that less than 20% of the reactive groups of one of either the polymer or crosslinking agent has reacted, and subsequently cooling and comminuting the composition.The mixing is preferably effected in a static mixer at a temperature higher than 140.degree. C.

Abstract: A curable coating composition is described comprising(A) a compound comprising a plurality of functional crosslinking groups, at least one of which is a carbamate or urea functional group, which compound also includes at least one carbonate group having the structure: ##STR1## and (B) a curing agent comprising a plurality of groups that are reactive with the functional groups on compound (A).

Abstract: The invention pertains to a non-linear optically active (NLO) side chain polycarbonate and to NLO active waveguides containing said polycarbonate. Waveguides containing this NLO polycarbonate have a low loss of signal. Polycarbonates based on bischloroformates of hexafluorobisphenol A, hexafluorotetrabromobisphenol A and bisphenol S or deuterated bisphenol A or sulphonylbiphenol are especially preferred within the framework of the invention: they were found to give an exceptionally low loss of signal. The invention further pertains to cross-linkable and already cross-linked polycarbonates. Especially preferred polycarbonates according to the invention are those where the diol comprises a rigid donor group. These polycarbonates have a high Tg, which renders them thermally stable.

Abstract: The objective of the invention is to produce a thermoplastic resin capable of producing a casting with a superior granular surface appearance like marble while maintaining the impact strength and other properties of the base resin.The present invention pertains to a thermoplastic composition with a granular surface appearance like marble produced by mixing and dispersing 0.001-10 parts by weight of thermosetting resin with 100 parts by weight of thermoplastic resin.

Abstract: The present invention provides for amino-crosslinkable coating formulations based on a mixture of a di or polyhydroxy functional polymeric component selected from the group consisting of diesters, polyesters, alkyd polymers, acrylic polymers and polycarbonate polymers, a methylol (alkoxymethyl) amino crosslinking agent and a bis-aromatic polyhydric phenol component having the structure of formula I: ##STR1## wherein X is selected from the group consisting of carbon to carbon covalent bond, oxygen, sulfur, --S--S--, --CO--, --SO--, --SO.sub.2 -- and a divalent organic radical having a molecular weight less than about 400, and wherein Y is independently selected from the group consisting of hydrogen, halogen, C.sub.1 to C.sub.4 alkyl and C.sub.1 to C.sub.4 alkoxy.

Abstract: Disclosed is a coating composition comprising:(1) a polycarbonate polyol having an average molecular weight of 400-10,000 and a hydroxyl value of 50-350, and(2) a melamine resin curing agent, wherein polyhydric alcohols constituting said polycarbonate polyol comprises at least 10 mol % of branched diols, at least 10 mol % of tri- or higher-hydric alcohols and the balance of the other polyhydric alcohols, and a ratio of component (1) / component (2) is within the range of 90/10-50/50 based on solid weight.

Abstract: The objective of the invention is to produce a thermoplastic resin capable of producing a casting with a superior granular surface appearance like marble while maintaining the impact strength and other properties of the base resin.The present invention pertains to a thermoplastic composition with a granular surface appearance like marble produced by mixing and dispersing 0.001-10 parts by weight of thermosetting resin with 100 parts by weight of thermoplastic resin.

Abstract: Polyester polymers having pendant carbamate groups are disclosed. The polymers are prepared by:(a) reacting a hydroxyalkyl cyclic carbonate with ammonia, ammonium hydroxide, or a primary amine to form a dihydric alcohol having a carbamate group appended thereto,(b) reacting the dihydric alcohol from (a) and a cyclic anhydride to form a half-ester diacid having a carbamate group appended thereto, and(c) reacting a mixture comprising the half-ester diacid from step (b) and a polyol to form a polyester having carbamate groups appended thereto.

Abstract: A smear resistant thermally reactive material for use in a one-coat system, the thermally reactive material being applied to a receiver stock and consisting essentially of: about 55-75% wax; a binder of about 0.5-11% ethylene vinyl acetate; a pigment of about 6-26% color pigment; a dye of about 0.5-14% color forming dye; and a reactant of about 5-15% epoxy resin. The smear resistant thermally reactive material has a cohesive strength that inhibits smearing of data that is thermally transferred from an ink ribbon to the receiver stock. A crosslinking polymer for use in a two-coat system is also disclosed. The crosslinking polymer has a first coating consisting of a catalyst of 100% organosilane and a second coating consisting essentially of: about 55-75% wax; a binder of about 0.5-11% ethylene vinyl acetate; a pigment of about 6-26% color pigment; a dye of about 0.5-14% color forming dye; and a reactant of about 5-15% organosiloxane.

Abstract: Provided are light-absorbing polymers which contain backbone unsaturations and which are produced by knoevenagel condensation and which are useful for imparting color and/or ultraviolet light screening properties to thermoplastic resins. The polymeric colorants or UV absorbers may be added during the formation of the uncolored thermoplastic polymer or melt or solution blended with other thermoplastic polymers.

Abstract: a composition comprising a polymer phase in dispersion in a non-aqueous continuous diluent in which the polymer phase comprises a crystallizable polymer, selected from polyesters, polyamides and polycarbonates, in intimate admixture with a curable solvent for the crystallizable polymer, a stabilizer and, optionally, an auxiliary solvent.

Abstract: Blends of aromatic polycarbonate, alkylnaphthalene-formaldehyde condensation product and an impact modifier produce easy-flow, tough, stiff thermoplastics. The thermoplastics can be used to injection mold thin-walled housings for electronic circuits.

Abstract: An improved resinous blend having good impact properties and solvent resistance comprising an aromatic carbonate polymer, a polyacetal and a thermoplastic polyurethane.

Abstract: A coating composition has as its principal constituents(i) an isocyanate terminated urethane containing material; and(ii) a phosphatized polyepoxide essentially free of oxirane groups.The coating composition has excellent elongation and is particularly useful as a coating applied directly to metal. The coating composition is also useful as a primer in the preparation of multilayer coatings having good flexibility.

Abstract: A coating composition is composed of a material or mixture of materials adapted to provide a source of:(i) carbonate moieties;(ii) isocyanate groups; and(iii) phosphatized polyepoxide essentially free of oxirane groups.The coating composition has excellent elongation and is particularly useful as a coating applied directly to metal. The coating composition is also useful as a primer in the preparation of multilayer coatings having good flexibility.

Abstract: Method for manufacturing a conductive plastic of a defined conductivity by forming a polymer alloy. A polar or nonpolar insulating polymer and a polar or nonpolar conductive polymer are used for forming the polymer alloy. The two polymers are mixed together and they are homogeneously distributed within the polymer alloy.

Abstract: A coating composition comprising as resinous vehicle, a melamine resin, and a crosslink curable type resin having functional groups capable of reacting with the melamine resin, which is characterized in that the melamine resin has a weight-average molecular weight by Gel Permeation Chromatography of 6000 to 12000 and bears as functional groups, imino, methylol and alkoxymethylol groups, the sum of imino and methylol groups being, when expressed in terms of average number per triazine nucleus, 2.0 to 2.5, the number of alkoxymethylol groups being 2.0 or more, and the ratio of methylol groups to imino groups being 1.0 to 2.5.The coating composition is characterized by having, inter alia, a low temperature curing property and excellent intercoat adhesion.

Abstract: A resinous composition for coating use comprising a resin obtained by the reaction of base resin having as essential groups, both carboxyl groups derived from a polycarboxylic acid whose titration midpoint potential in non-aqueous potentiometric titration is more than -300 mV in a state capable of developing a resinous acid value and a functional group reactive with a crosslinking agent, and an alkyleneimine compound in an amount equivalent to resinous acid value of 0.01 to 50, the resinous acid value based on said polycarboxylic acid in the final composition being 2 to 50.This is useful for the preparation of a coating composition having improved curing property, storage stability and time color stability.

Abstract: An acetal resin composition comprising an acetal resin and a low molecular weight polycarbonate compound having an intrinsic viscosity of 0.2 dl/g or less in methylene chloride at 25.degree. C. and, optionally, an organic or inorganic filler is disclosed. Said composition has improved surface gloss and weather resistance.

Abstract: A resin composition comprising(I) a granular or powdery resin which is a condensation product of a phenol, an aldehyde and optionally a nitrogen-containing compound having at least two active hydrogens and is characterized by (A) containing spherical primary particles and their secondary agglomerated particles each having a particle diameter of 0.1 to 150 microns, (B) having such a size that at least 50% by weight thereof can pass through a 100 Tyler mesh sieve, and (C) having a free phenol content, determined by liquid chromatography, of not more than 500 ppm, and(II) at least one member selected from the group consisting of (1) a rubbery elastic material, (2) a thermoplastic resin and (3) a curable reisn other than said granular or powdery resin (I) and/or a filler material other than said granular or powdery resin (I).

Abstract: A process for producing polycarbonate is described, comprising reacting a chloroformate group-containing polycarbonate oligomer with an aqueous alkaline solution of a compound containing at least three functional groups and, thereafter, interfacial polycondensing the above-obtained reaction product with an aqueous alkaline solution of a dihydric phenol compound. The thus-produced polycarbonate has good melt characteristics compared with conventional polycarbonates, and the dependence of melt viscosity on a rate of shear is large. Thus, the polycarbonate of the invention is suitable for extrusion molding, particularly for blow molding using an extrusion molding machine, and can provide good quality sheets or molds.

Abstract: There are described liquid compositions of a hemiformal of phenol and/or a hemiformal of a methylolated phenol with a miscible polymers such as phenol-formaldehyde resoles, phenol-formaldehyde, novolacs, aromatic polyesters, unsaturated polyesters, poly(aryl-ethers), aromatic polycarbonates urea-formaldehyde resins, or melamine-formaldehyde resins. The compositions are useful for forming thermoset plastic materials.

Abstract: A method of making grinding wheel mounts by molding a central hub onto a thermoset plastic abrasive disc is provided. An aromatic polycarbonate thermoplastic resin is molded to form a hub on a cured thermoset plastic abrasive disc. It is believed that the polycarbonate forms both a mechanical and chemical bond with the thermoset plastic to provide an efficient method of producing grinding wheels.

Abstract: A polymer composite material which comprises a first rigid polymeric material composed substantially of rigid molecular chains having an average chain length of 50 A or more, and a second polymeric material composed substantially of flexible molecular chains, wherein said first rigid polymeric material is present in an amount of 20% or less based on the total weight of polymeric material in said composite and said first material is uniformly dispersed in said second polymeric material in a microscopic region of 1 .mu.m or less.

Abstract: Improved copoly(carbonate/phosphonate) compositions formed by reaction of a dihydric phenol, a carbonate precursor, and an organophosphorus dihalide are disclosed. The inherent viscosity and melting point of such compositions is increased by the presence of an effective amount of a chain branching agent, optionally in the additional presence of a chain terminating agent.

Abstract: Aliphatic or cycloaliphatic polycarbonate-triols having a molecular weight of not more than 3,000, which contain hydrophobic segments and are liquid at room temperature are obtained by transesterifying an aryl carbonate with a primary aliphatic triol and a mixture of two diols, HOAOH and HOBOH, at least one of the radicals A or B being a hydrophobic radical, the proportion of the primary aliphatic triol is such that there is statistically one molecule of the said triol per polymer chain in the product, and the ratio of the diols being such that the polycarbonate-triol obtained is equivalent to a mixture of a% by weight of a polycarbonate derived from the triol and the diol HOAOH alone, and of b% by weight of a polycarbonate derived from the triol and the diol HOBOH alone, the percentages a and b corresponding to the following two conditions:30%.ltoreq.a%.ltoreq.70%a%+b%=100%.Modified aminoplast resins can be obtained by reacting such polycarbonate-triols with etherified melamine-formaldehyde condensates.