Mixed With Ethylenically Unsaturated Reactant Or Polymer Therefrom Patents (Class 525/468)
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Patent number: 11767426Abstract: The invention relates to a composition for producing a thermoplastic moulding material, wherein the composition contains the following constituents: A) at least one polymer selected from the group consisting of aromatic polycarbonate, aromatic polyestercarbonate and polyester, B) at least one anhydride-functionalized ethylene-?-olefin copolymer or ethylene-?-olefin terpolymer having a weight-average molecular weight Mw of 50000 to 500000 g/mol determined by high-temperature gel permeation chromatography using ortho-dichlorobenzene as solvent against polystyrene standards, C) glass fibres, and also to a process for producing the moulding material, to the moulding material itself, to the use of the composition or of the moulding material for producing moulded articles and to the moulded articles themselves.Type: GrantFiled: November 8, 2018Date of Patent: September 26, 2023Assignee: Covestro Deutschland AGInventor: Derk Erich Wandner
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Patent number: 10941291Abstract: The disclosed relates to a polyalkylene carbonate resin composition, and more specifically, to a polyalkylene carbonate resin composition containing polyalkylene carbonate and polyketone. The polyalkylene carbonate resin composition particularly exhibits excellent thermal stability, while having excellent transparency and flexibility, oxygen barrier properties, and mechanical and chemical properties.Type: GrantFiled: December 27, 2017Date of Patent: March 9, 2021Assignee: LG Chem, Ltd.Inventors: Seung Young Park, Sung-Kyoung Kim
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Patent number: 10844220Abstract: The present invention relates to a polyketone resin composition and a polyketone resin molded article produced by using the composition, and particularly to a polyketone resin and a polyketone resin molding which comprise a predetermined content of polyketone and polyalkylene carbonate and thus have enhanced melt stability of polyketone.Type: GrantFiled: December 27, 2017Date of Patent: November 24, 2020Assignee: LG Chem, Ltd.Inventors: Seung Young Park, Sung-Kyoung Kim
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Patent number: 9051246Abstract: A compound represented by a formula 1 shown below. In the formula 1, each of R1 and R2 independently represents a group selected from the group consisting of a hydrogen atom and substituents composed of C, H and/or X (wherein X represents a hetero atom), and each of Z1 and Z2 independently represents a group selected from the group consisting of aromatic substituents composed of C and H, aromatic substituents composed of C, H and X (wherein X represents a hetero atom), groups containing an aromatic ring and a double-bonded and/or triple-bonded conjugated structure composed of C and H, and groups containing an aromatic ring and a double-bonded and/or triple-bonded conjugated structure composed of C, H and/or X (wherein X represents a hetero atom).Type: GrantFiled: January 28, 2011Date of Patent: June 9, 2015Assignee: HITACHI CHEMICAL COMPANY, LTD.Inventors: Shigeaki Funyuu, Kenichi Ishitsuka, Hideo Nakako, Sentaro Okamoto
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Patent number: 9006351Abstract: The invention is to provide a polycarbonate resin composition and a molded polycarbonate resin article which combine excellent transparency and strength and which are suitable for use in the field of building materials, electrical/electronic field, automotive field, field of optical parts, etc. The invention relates to a polycarbonate resin composition containing a polycarbonate resin and an impact strength modifier, the polycarbonate resin containing structural units which are derived from a dihydroxy compound that has the portion represented by the following general formula (1) as part of the structure thereof and having a glass transition temperature lower than 145° C. and a molded polycarbonate resin article obtained by molding the composition. The polycarbonate resin composition gives a molded object having a thickness of 3 mm which has a total light transmittance of 60% or higher.Type: GrantFiled: January 14, 2013Date of Patent: April 14, 2015Assignees: Mitsubishi Chemical Corporation, Mitsubishi Plastics, Inc.Inventors: Masashi Yokogi, Kazuya Tanaka, Haruo Sasaki, Akira Kosuge
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Patent number: 8975346Abstract: In one aspect, the invention relates to relates to copolymer compositions comprising domains of polycarbonate and polyacrylate, and to methods of preparing the copolymers, wherein the method comprises reacting a polycarbonate macroinitator with a vinyl monomer by atom transfer radical polymerization. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.Type: GrantFiled: May 18, 2012Date of Patent: March 10, 2015Assignee: SABIC Global Technologies B.V.Inventors: Meghna Markanday, Balakrishnan Ganesan, Theo Hoeks, Jan Henk Kamps
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Publication number: 20150056879Abstract: A composite material comprises a reinforcing material carried in a polymer matrix material which is the polymerization product of a polymerizable composition comprising a di-activated vinyl compound, with the proviso that the di-activated vinyl compound is not a cyanoacrylate. The reinforcing materials may be a wide variety of substrates including thermally sensitive materials. Exemplary composites can be molded and cured at ambient temperatures. Also disclosed are laminate materials having layered materials adhered by curing a di-activated vinyl polymerizable composition.Type: ApplicationFiled: March 29, 2013Publication date: February 26, 2015Inventors: Bernard M. Malofsky, Adam G. Malofsky, Matthew M. Ellison
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Publication number: 20140316078Abstract: An unsaturated polycarbonate diol (A) comprising terminal hydroxyl groups, at least one repeating unit of formula (Ia) and at least one repeating unit selected from units of formula (Ib) and units of formula (II), wherein R1a is selected from the group consisting of C2-C20 acyclic alkylene group, C2-C20 ether group and C3-C20 ester group, R1b represents and C2-C20 acyclic alkenylene group, and R2 represents a C2-C20 acyclic alkenylene group; the unsaturated polycarbonate diol (A) comprising at least one unsaturated carbon-carbon bond; and procedures to obtain such an unsaturated polycarbonate diol (A):Type: ApplicationFiled: March 31, 2014Publication date: October 23, 2014Applicant: UBE CHEMICAL EUROPE, S.A.Inventors: Andres NOHALES PIQUERAS, Victor Ignacio COSTA VAYA
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Patent number: 8802197Abstract: The invention relates to a method of producing an article comprising an interpenetrating polymer network (IPN) and an IPN comprising article e.g. obtainable by this method. The method comprises providing a polymer substrate e.g. shaped to provide the desired article and applying it in a reaction chamber, providing at least one monomer for an interpenetrating polymer, exposing said polymer substrate in said reaction chamber to said at least one monomer in the presence of an impregnation solvent comprising CO2 under conditions wherein said CO2 is in its liquid or supercritical state and polymerizing and optionally cross linking said at least one monomer to form an interpenetrating polymer in the presence of a polymerization solvent under conditions wherein at least a part of said at least one monomer is dissolved in said polymerization solvent.Type: GrantFiled: November 5, 2007Date of Patent: August 12, 2014Assignee: PTT Holding APSInventors: Martin Alm, Maike Benter, Anne Marie Jensen, Joachim Karthäuser, Kjeld Schaumburg
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Patent number: 8703869Abstract: The invention relates to impact-modified polycarbonate compositions which are distinguished by high heat resistance and good melt flow behavior. In addition, the moldings produced from the compositions according to the invention in an injection-molding process can be metallised, the resulting metallised moldings having a surface with a particularly high and, in particular, homogeneous gloss. The invention thus also provides the metallised moldings produced from the compositions according to the invention.Type: GrantFiled: March 23, 2010Date of Patent: April 22, 2014Assignee: Bayer Materialscience AGInventors: Andreas Seidel, Eckhard Wenz, Hans-Jü{umlaut over ( )}rgen Klankers
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Patent number: 8623960Abstract: Provided are a resin composition including an acryl-based copolymer resin including an alkyl(meth)acrylate-based monomer and an imide-based monomer, additionally copolymerizable with a styrene-based monomer, and a polycarbonate-based resin having a melt index (MI) of 30 g/10 min or more under conditions of a load of 1.2 kg and a temperature of 300° C., a polarizer protective film including the resin composition, and a liquid crystal display including the polarizer protective film. The polarizer protective film according to the present invention has excellent heat resistance, transparency, and optical properties.Type: GrantFiled: January 20, 2012Date of Patent: January 7, 2014Assignee: LG Chem, Ltd.Inventors: Eun-Jung Choi, Byoung-Il Kang, Chang-Hun Han, Jae-Bum Seo
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Patent number: 8536275Abstract: The present invention relates to acryl-based copolymers including an alkyl(meth)acrylate-based monomer; a (meth)acrylate-based monomer containing an aromatic ring; and a maleimide-based monomer, a resin composition including the same, and an optical film prepared by using the same.Type: GrantFiled: June 13, 2011Date of Patent: September 17, 2013Assignee: LG Chem, Ltd.Inventors: Byung-Il Kang, Chang-Hun Han, Dae-Woo Lee, Eun-Jung Choi
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Patent number: 8445581Abstract: The present invention provides a biocompatible prepolymer comprising hydrophilic and hydrophobic segments, wherein the hydrophobic segments have at least one ethylenically unsaturated functional group and at least 5% of the segments have two or more ethylenically unsaturated functional groups and water. The invention further provides a biocompatible prepolymer composition comprising hydrophilic and hydrophobic prepolymers, wherein at least one of the hydrophobic prepolymers has at least one ethylenically unsaturated functional group and at least 5% of the prepolymers have two or more ethylenically unsaturated functional groups and water. The invention further provides use of the prepolymer or prepolymer compositions of the invention in biomedical applications such as tissue engineering, as bone substitutes or scaffolds, and in wound treatment.Type: GrantFiled: August 2, 2007Date of Patent: May 21, 2013Assignee: Polynovo Biomaterials Pty LimitedInventors: Pathiraja Arachchillage Gunatillake, Roshan Tyrrel Anton Mayadunne, Raju Adhikari, Heng Chy Taing, Tam Phuong Thi Le, Jerome Anthony Werkmeister, John Alan Maurice Ramshaw, Jacinta Frances White, Tracy Ann Tebb
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Patent number: 8426532Abstract: Methods of forming polycarbonate graft copolymers are provided. In particular, a polycarbonate polymer or copolymer containing allyl groups provides the backbone for the graft copolymer, and pendant chains are attached to the copolymer through the allyl groups. The graft copolymers exhibit a combination of high transparency, good graft levels, good scratch resistance, and/or good anti-fog properties.Type: GrantFiled: September 17, 2010Date of Patent: April 23, 2013Assignee: SABIC Innovative Plastics IP B.V.Inventors: Rubin Huang, Andre van Zyl, Jan Pleun Lens, Theodorus Lambertus Hoeks, Hans-Peter Brack, Jan Henk Kamps
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Publication number: 20120322953Abstract: Functionalized prepolymers and biocompatible polymer networks are disclosed, especially biodegradable polymer networks obtainable by polymerization of the functionalized prepolymers by the example ultraviolet (UV), redox, and/or heat radical polymerization. Functionalized prepolymers (macromers) are obtainable by reaction of a prepolymer comprising at least one alcohol, amine, and/or sulfhydril group, with an unsaturated mono-esterified dicarbonic acid, especially fumanic acid mono-ethyl ester.Type: ApplicationFiled: March 13, 2012Publication date: December 20, 2012Applicant: DSM IP ASSETS B.V.Inventors: Dirk Wybe GRIJPMA, Qingpu Hou, Jan Feijen
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Patent number: 8324318Abstract: A thermoplastic composition including a combination of a polycarbonate, an impact modifier, an aromatic vinyl copolymer, and a polyester carbonate and/or a polycarbonate polysiloxane copolymer having excellent thermal and mechanical properties as well as good adhesion to both a polymer superstrate and certain types substrates is disclosed. Also disclosed are articles and multilayer films including the tie layer composition.Type: GrantFiled: July 10, 2009Date of Patent: December 4, 2012Assignee: Sabic Innovative Plastics IP B.V.Inventor: James DeRudder
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Patent number: 8198366Abstract: The present invention provides a thermoplastic resin composition containing (A) a resin mixture including (a-1) a polycarbonate resin in an amount of 45 to 97% by mass and (a-2) a fatty acid polyester in an amount of 55 to 3 % by mass, and (B) a rubber-like elastomer in an amount of 0.5 to 20 parts by mass per 100 parts by mass of the resin mixture, wherein component (B) is dispersed in an interface between ingredient (a-1) and ingredient (a-2) or in domains of ingredient (a-2). The composition has high impact characteristics and high fluidity and overcomes appearance defects such as pearl-like gloss and jetting marks.Type: GrantFiled: October 25, 2005Date of Patent: June 12, 2012Assignee: Idemitsu Kosan Co., Ltd.Inventors: Yusuke Hayata, Akio Nodera
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Patent number: 8173720Abstract: A transparent gel is disclosed which has an interpenetrating polymer network of a copolymer containing a polysiloxane structure and a polycarbonate structure and a hydrophilic polymer obtained by polymerizing a hydrophilic monomer. The transparent gel is useful as a cultivation substrate, a container for storage and an ophthalmic material, comprising an easily synthesizable and purifiable silicon-containing resin, wherein a gel strength, transparency, oxygen permeability, birefringence and other characteristics are excellent.Type: GrantFiled: January 13, 2006Date of Patent: May 8, 2012Assignees: Mitsubishi Gas Chemical Company, Inc., Menicon Co., Ltd.Inventors: Kazuhiko Nakada, Takahito Nakase, Takahiro Adachi, Akira Yamamoto, Masahiko Minemura
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Publication number: 20120068115Abstract: Disclosed are random copoly(phosphonate carbonate)s with the high molecular weight and narrow molecular weight distribution exhibiting a superior combination of properties compared to prior art.Type: ApplicationFiled: September 16, 2011Publication date: March 22, 2012Applicants: BAYER MATERIAL SCIENCE AG, FRX POLYMERS, INC.Inventors: Dieter FREITAG, Pin GO, Lawino KAGUMBA, Stephan KONRAD, Helmut-Werner HEUER, Berit KRAUTER, Pieter OOMS, Michael PREIN, Johann RECHNER
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Patent number: 8133943Abstract: Disclosed is a polylactic acid/polycarbonate resin composition including (A) about 100 parts by weight of a mixed resin including: (a1)) about 10 to about 90 wt % of a polycarbonate resin and (a2) about 10 to about 90 wt % of a polylactic acid resin; (B) about 1 to about 50 parts by weight of a flame retardant based on about 100 parts by weight of the mixed resin; (C) about 1 to about 30 parts by weight of an acryl-based copolymer based on about 100 parts by weight of the mixed resin; and (D) about 1 to about 20 parts by weight of an impact-reinforcing agent based on about 100 parts by weight of the mixed resin.Type: GrantFiled: November 18, 2009Date of Patent: March 13, 2012Assignee: Cheil Industries Inc.Inventors: Jin-Kyung Cho, Hyung-Tak Lee, Doo-Han Ha, Chang-Do Jung
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Patent number: 8053534Abstract: Disclosed is a thermoplastic resin composition that includes: (A) about 55 to about 95 wt % of a polycarbonate resin; (B) about 1 to about 40 wt % of a polyalkyl(meth)acrylate resin having a weight average molecular weight of about 1,000,000 g/mol or more; and (C) about 0.001 to about 10 wt % of a polysiloxane resin, and a molded product made using the same.Type: GrantFiled: December 2, 2009Date of Patent: November 8, 2011Assignee: Cheil Industries, Inc.Inventors: Byung-Choon Lee, Tae-Uk Kim, Doo-Han Ha
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Patent number: 8044143Abstract: Disclosed are a polyester/polycarbonate alloy resin composition that includes: (A) a mixed resin including (A-1) a polycarbonate resin having a weight average molecular weight ranging from about 30,000 to about 200,000 g/mol and (A-2) a polyester resin having an intrinsic viscosity of about 0.85 to about 1.52 dl/g; (B) an acryl-based resin; and (C) an impact-reinforcing agent, and a molded product made using the polyester/polycarbonate alloy resin composition.Type: GrantFiled: December 18, 2009Date of Patent: October 25, 2011Assignee: Cheil Industries Inc.Inventors: Jung-Eun Park, Bang-Duk Kim, In-Sik Shim, Doo-Han Ha
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Patent number: 7772334Abstract: A crosslinker for polymerizing a film-forming material including an alkyl or aromatic compound comprising at least two functional groups reactive with a film-forming resin and at least one pendent group having a nonionic metal coordinating structure. Coating compositions can include a film-forming material and the crosslinker. The coating compositions can be used to coat a substrate, such as a metal substrate. Applied coating layers on substrates can be cured to form coating films.Type: GrantFiled: October 26, 2006Date of Patent: August 10, 2010Assignee: BASF Coatings GmbHInventors: Timothy S. December, Sergio Gonzalez, Günther Ott, Karl-Heinz Grosse-Brinkhaus
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Patent number: 7759436Abstract: Film-forming materials include nonionic metal coordinating structures. Nonionic metal coordinating structures can coordinate metals, such as metal catalysts and metal substrates. Example film-forming materials can be the product of a poly-functional epoxide and a nucleophilic ligand having a nonionic metal coordinating structure, or the product of a poly-functional alcohol and an electrophilic ligand having a nonionic metal coordinating structure.Type: GrantFiled: October 26, 2006Date of Patent: July 20, 2010Assignee: BASF Coatings GmbHInventors: Timothy S. December, Sergio Gonzalez, Günther Ott, Karl-Heinz Grosse-Brinkhaus
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Patent number: 7550527Abstract: The present invention relates to aqueous copolymer dispersions containing A) one or more hydroxy-functional copolymers synthesized from a) one or more OH-free (meth)acrylic esters and/or vinylaromatics, b) one or more hydroxy-functional (meth)acrylic esters, c) one or more ionic and/or potential ionic monomers capable of free-radical copolymerization, and d) one or more optionally monomers other than components a) to c) that are capable of free-radical copolymerization, and B) one or more hydroxy-functional polycarbonate polyols as reactive diluent. The present invention also relates to a process for preparing these aqueous copolymer dispersions and to their use in coating compositions.Type: GrantFiled: March 6, 2006Date of Patent: June 23, 2009Assignee: Bayer MaterialScience AGInventors: Steffen Hofacker, Markus Mechtel, Thomas Münzmay, Nusret Yuva, Rolf Gertzmann
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Patent number: 7547749Abstract: In various embodiments the present invention comprises 2,4,6-trisubstituted-1,3,5-triazine capping agents comprising one, two, or three leaving groups as substituents with any remaining substituents being essentially inert to reaction with a nucleophilic group on a polymer or monomer, or reactive with a nucleophilic group on a polymer or monomer at a slower rate than any leaving group. The invention also comprises polymers or monomers with nucleophilic groups capped with a triazine moiety. Still other embodiments of the invention comprise processes for capping nucleophilic groups in a polymer or monomer which comprises combining and reacting the polymer or monomer with a triazine-comprising capping agent.Type: GrantFiled: June 21, 2007Date of Patent: June 16, 2009Assignee: SABIC Innovative Platics IP B.V.Inventors: Sterling Bruce Brown, Hans-Peter Brack, James Anthony Cella, Dennis Karlik
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Patent number: 7514478Abstract: Powder coating binders having a glass temperature of ?35° C. containing at least one polymer and one or more radiation-curing reactive thinners, a process for the production of these powder coating binders and their use as a component of powder coatings.Type: GrantFiled: November 22, 2004Date of Patent: April 7, 2009Assignee: Bayer MaterialScience AGInventors: Thomas Fäcke, Jan Weikard, Peter Thometzek
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Patent number: 7390857Abstract: Crosslinkable polymeric materials are disclosed useful for the temporal stabilization of a poling-induced noncentrosymmetric host lattice containing guest nonlinear optical chromophores. The materials are also suitable as crosslinkable coatings in the absence of chromophores. Also disclosed is a method of crosslinking such polymeric material.Type: GrantFiled: August 27, 2004Date of Patent: June 24, 2008Assignee: General Electric CompanyInventors: James Anthony Cella, Daniel Gerard Colombo, Christopher James Kapusta
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Patent number: 7329711Abstract: The present invention relates to molding compositions comprising A) from 40 to 99% by weight of at least one epoxy resin, B) from 1 to 60% by weight of at least one polyarylene ether sulfone containing side- or end-groups selected from the group consisting of carboxy groups and anhydride groups, C) from 0 to 60% by weight of at least one polyarylene ether sulfone containing essentially no side- or end-groups selected from the group consisting of carboxy and anhydride groups, D) from 0 to 60% by weight of at least one filler, and E) from 0 to 40% by weight of one or more various additives, where the percentages by weight of components A to E together give 100%, and also to a process for preparing these molding compositions, and to their use, and to moldings obtainable therefrom.Type: GrantFiled: October 29, 2002Date of Patent: February 12, 2008Assignee: BASF AktiengesellschaftInventors: Ingo Alig, Marco Holst, Martin Weber
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Patent number: 7297370Abstract: An encapsulant for encapsulating electronic components and a method of making and/or using the encapsulant may be provided. An electronic device that includes the encapsulant may be provided. The curable encapsulant composition may include a mixture of a functionalized polymer and at least one reactive monomer composition. The reactive monomer composition may include a reactive monomer component that may be a low temperature solid and may be present in an amount in the reactive monomer composition a range of greater than about 20 weight percent based on the total weight of reactive monomer composition. The mixture, at about low temperature, may be solid or tack-free, or both solid and tack-free.Type: GrantFiled: June 24, 2005Date of Patent: November 20, 2007Assignee: General Electric CompanyInventors: Michael Alan Vallance, John Robert Campbell, Kenneth Paul Zarnoch, Prameela Susarla, Bryan Patrick Duffey, Gary William Yeager, Michael Joseph O'Brien
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Patent number: 7288608Abstract: A thiol-ene polymeric material is disclosed. The material is produced by the photopolymerization of reactants having thiol and olefin moieties. The material can incorporate encapsulated components, including cells. Additionally, the material can be derivatized by reacting the polymeric material with components such as proteins.Type: GrantFiled: October 10, 2002Date of Patent: October 30, 2007Assignee: Regents of the University of ColoradoInventors: Christopher Bowman, Kristi Anseth, Bilge Hacioglu, Charlie Nuttelman
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Patent number: 7235611Abstract: In various embodiments the present invention comprises 2,4,6-trisubstituted-1,3,5-triazine capping agents comprising one, two, or three leaving groups as substituents with any remaining substituents being essentially inert to reaction with a nucleophilic group on a polymer or monomer, or reactive with a nucleophilic group on a polymer or monomer at a slower rate than any leaving group. The invention also comprises polymers or monomers with nucleophilic groups capped with a triazine moiety. Still other embodiments of the invention comprise processes for capping nucleophilic groups in a polymer or monomer which comprises combining and reacting the polymer or monomer with a triazine-comprising capping agent.Type: GrantFiled: September 26, 2003Date of Patent: June 26, 2007Assignee: General Electric CompanyInventors: Sterling Bruce Brown, Hans Peter Brack, James Anthony Cella, Dennis Karlik
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Patent number: 7230066Abstract: The present invention provides novel block copolycarbonates comprising residues from a hydroxy terminated polyetherimide or polyimide, residues from a dihydroxy compound, and residues from an activated carbonate. In a preferred embodiment of the present invention the polyetherimide or polyimide blocks exhibit high Mw while the resulting block copolycarbonate exhibits a single Tg. The novel block copolycarbonates of the present invention are produced under melt polymerization conditions in the presence an activated carbonate source.Type: GrantFiled: December 16, 2004Date of Patent: June 12, 2007Assignee: General Electric CompanyInventors: Farid Khouri, Julia Lee, Sheldon Shafer
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Patent number: 7009001Abstract: Provided is an aromatic polycarbonate resin composition which comprises 100 parts by mass of an aromatic polycarbonate resin and from 0.001 to 1 part by mass of an additional thermoplastic resin that differs from the aromatic polycarbonate resin in the refractive index by at least 0.001 and which is so designed that the ratio (X)/(Y) is at least 0.5 wherein (X) indicates the spectral transmittance at 320 nm through a sample plate of the resin composition having a thickness of 2 mm and (Y) indicates the spectral transmittance at 633 nm through it. Having realized further increase in the transparency of aromatic polycarbonate resin, the resin composition gives moldings of which the transparency is comparable to that of acrylic resin for optical use, and the resin moldings have good impact resistance and heat resistance.Type: GrantFiled: August 9, 2001Date of Patent: March 7, 2006Assignee: Idemitsu Kosan Co., Ltd.Inventors: Hiroshi Kawato, Shigeki Kuze
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Patent number: 6890991Abstract: The present invention relates to a thermoplastic resin composition which has an improved impact resistance while maintaining mechanical properties such as strength and rigidity. In the present invention, a thermoplastic resin (A) is mixed with a polytetrafluoroethylene-containing mixed powder (B) consisting of a polytetrafluoroethylene (b1) having a particle diameter of 10 ?m or less and an organic polymer (b2). In this case, the polytetrafluoroethylene-containing mixed powder (B) is mixed so that the amount of a polytetrafluoroethylene component is from 0.0001 to 20 parts by weight based on 100 parts by weight of the thermoplastic resin (A), and a polymer having an epoxy group was used as the organic polymer (b2). The thermoplastic resin composition of the present invention can be widely used in the fields of automotive parts, electric and electronic parts, and precision instrument parts.Type: GrantFiled: March 21, 2001Date of Patent: May 10, 2005Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Hideyuki Fujimoto, Atsunori Koshirai
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Publication number: 20040176548Abstract: A thermoplastic elastomer. It is produced by impregnating a heat resistant polycondenzation copolymer containing soft segments with acrylate monomers and radical initiators and polymerizing the monomers inside the pellets. By incorporating a cross-linked polyacrylate phase into a block-elastomer based on an engineering polymer, such as polyester, polyamide or polyurethane, softer compounds having excellent heat and oil resistance are obtained.Type: ApplicationFiled: December 24, 2003Publication date: September 9, 2004Inventors: Tomi Heiskanen, Christer Bergstrom, Johanna Lampinen, Ville Nurminen
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Patent number: 6670428Abstract: An object of the present invention is to substantially improve the compatibility between a radical copolymerizable unsaturated resin and an addition polymerized polymer (thermoplastic resin) which is added for the purpose of low profile and improvement of physical properties. The present invention provides a compatibilizing agent for compatibilizing a radical copolymerizable unsaturated resin with an addition polymerized polymer, characterized in that said compatibilizing agent is a graft copolymer (A) which contains a styrene monomer as a principal component, and has a principal chain (A1) consisting of a copolymer with a (meth)acrylate monomer and a side chain (A2) selected from a ring-opening polymerized polyether side chain consisting of a polyoxyalkylene ether, a polyester side chain, and a polycarbonate side chain, the side chain (A2) being bonded to the principal chain.Type: GrantFiled: November 15, 2000Date of Patent: December 30, 2003Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Takashi Yasumura, Akira Takano
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Patent number: 6649691Abstract: The reaction of unsaturated carbonates such as vinyl ethylene carbonate with N-aminoethylimidazolidone (TAM) under mild conditions generates a mixture of two vinyl and hydroxy functional imidazolidone carbamates which polymerize readily into acrylate or vinyl acetate based emulsion polymers. The polymers show enhanced wet adhesion (wet scrubbability) in latex paints and coatings.Type: GrantFiled: December 12, 2002Date of Patent: November 18, 2003Assignee: Air Products Polymers, L.P.Inventors: Robert Krantz Pinschmidt, Jr., Khalil Yacoub, Christian Leonard Daniels, Kien Van Phung
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Patent number: 6642322Abstract: A method of making telechelic oligomers comprises reacting a substrate compound selected from the group consisting of relatively high molecular weight polymers with a chain transfer agent in the presence of an alkali metal catalyst. The telechelic oligomers thus produced may then be reacted with monomers according to known polymerization techniques in order to produce block copolymers.Type: GrantFiled: September 27, 2001Date of Patent: November 4, 2003Assignee: The University of North Carolina at Chapel HillInventors: Michel R. Gagné, Michael R. Korn
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Patent number: 6583257Abstract: The invention relates to thermoplastic copolycarbonate compositions and moulded parts containing the latter having improved stress cracking resistance and thermal stability.Type: GrantFiled: September 24, 2001Date of Patent: June 24, 2003Assignee: Bayer AktiengesellschaftInventors: Holger Warth, Thomas Eckel, Dieter Wittmann, Silke Kratschmer
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Patent number: 6359081Abstract: A functional block copolymer useful as a compatibilizing agent for a blend of a condensation polymer and vinyl polymer comprises segments of a condensation polymer and a vinyl polymer derived from a reactive functional group-containing monomer or a functions-imparting monomer such as ultraviolet absorption or flame retardant functions. The block copolymer can further include a segment of a lower cohesive energy polymer. The condensation or vinyl polymer segment, or the lower cohesive energy polymer segment contains azo or peroxide groups which act as a polymerization initiator for the copolymerization of the vinyl monomer forming the vinyl polymer segment.Type: GrantFiled: April 19, 2000Date of Patent: March 19, 2002Assignees: Takiron Co., Ltd., Osaka Municipal GovernmentInventors: Masayuki Shimada, Yasuyuki Agari, Yoichiro Makimura
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Patent number: 6232398Abstract: A resin matrix with resistances to alkali and acid such as a fluorene-containing epoxy acrylate and/or a benzocyclobutene resin includes at least any one of insulative organic particles and insulative composite particles having an organic component and an inorganic component with the total amount of these particles being in the range of 5-50% by volume, wherein the insulative organic particles and the organic component of the insulative composite particles are allowed to be corroded by either alkali or acid, and wherein not less than 90% by volume of the insulative organic particles and insulative composite particles have a particle diameter in the range of 1-20 micrometers.Type: GrantFiled: December 5, 1997Date of Patent: May 15, 2001Assignee: NEC CorporationInventors: Yoshitsugu Funada, Koji Matsui
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Patent number: 6221940Abstract: A thermoplastic resin composition containing a polyetherimide resin, a glycidyl ester impact modifier and a organometallic compound exhibits improved impact strength and ductility.Type: GrantFiled: December 23, 1997Date of Patent: April 24, 2001Assignee: General Electric CompanyInventors: Robert Puyenbroek, James Fishburn
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Patent number: 6172142Abstract: There is provided by the present invention a thermal transfer ribbon which employs reactive binder components that increase in molecular weight when heated during transfer to provide images with high scratch and smear resistance. The reactive components comprise an epoxy resin binder and crosslinker for the epoxy resin binder which are maintained in separate phases within the thermal transfer layer until exposed to a thermal print head through the use of a coating formulation solvent which does not solubilize either the crosslinker or the epoxy resin binder or both.Type: GrantFiled: April 7, 1999Date of Patent: January 9, 2001Assignee: NCR CorporationInventors: Michael A. Lorenz, Joseph D. Roth
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Patent number: 6107436Abstract: Polyfunctional ethylenically unsaturated polyureas, polythiocarbamateureas, and polyurethaneureas comprise (a) at least one segment derived from an aspartic ester polyamine; and (b) at least one polycarbonate, polyether, or polyester segment. The polyfunctional polymers are useful in preparing curable coatings, films, and articles.Type: GrantFiled: October 5, 1998Date of Patent: August 22, 2000Assignee: 3M Innovative Properties CompanyInventors: Siegfried Rainer Goeb, Anja Christina Rohmann
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Patent number: 6008293Abstract: A composition comprising 20-80 weight percent of a styrene polymer with mainly syndiotactic configuration, and 20-80 weight percent of a polycarbonate, and optionally an inorganic filler.Type: GrantFiled: June 5, 1995Date of Patent: December 28, 1999Assignee: Idemitsu Kosan Co., Ltd.Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
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Patent number: 6005025Abstract: A method for dispersing solid forms of additives in polymers involves adding dispersions or solutions of additive(s) to a solution of polymer in a tubular mixer (preferably in the presence of a stationary mixer). The mixer leads to a steam precipitation step wherein all fluid ingredients in the mixture are volatilized leaving the solid additive and resin in the desired ratio. This results in a uniform dispersion of the additives in the polymer matrix. As a result of the high dispersion, physical properties of a thermoplastic resin, to which the polymer matrix has been added are preserved. In one illustration, PTFE as a drip inhibitor additive, is added to polycarbonate to obtain a highly dispersed PTFE concentrate of improved drip-inhibition without loss of mechanical properties when added to a thermoplastic molding resin.Type: GrantFiled: January 5, 1998Date of Patent: December 21, 1999Assignee: General Electric CompanyInventors: Qamar S. Bhatia, Paul Buckley, Gary Davis, Robert L. Howe, Wie-Hin Pan, Elliott Shanklin
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Patent number: 5981661Abstract: A flame retarded resin molding compositions with enhanced weatherable properties, which comprise a polyester and polycarbonate blend modified with an organopolysiloxane-polycarbonate and a glycidyl ester impact modifier for enhancing weatherablity and a flame retarding amount of a halogenated flame retardant.Type: GrantFiled: August 29, 1997Date of Patent: November 9, 1999Assignee: General Electric CompanyInventors: Jun Liao, Luca Pietro Fontana, Kevin Mitchell Snow
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Patent number: 5849845Abstract: Blends ofA) 80 to 99 wt. % of high molecular weight, thermoplastic, aromatic polycarbonate with a molecular weight M.sub.w (weight average) of at least 10,000, which contains bifunctional carbonate structural units of the formula (I), ##STR1## in which R.sup.1 and R.sup.2 mutually independently mean hydrogen, halogen, C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.6 cycloalkyl, C.sub.6 -C.sub.10 aryl, preferably phenyl, and C.sub.7 -C.sub.12 aralkyl,m means an integer from 4 to 7, preferably 4 or 5,R.sup.3 and R.sup.4 individually selectably for each X, mutually independently mean hydrogen or C.sub.1 -C.sub.6 alkyl andX means carbon,providing that on at least one atom X, R.sup.3 and R.sup.4 simultaneously mean alkyl,B) 1 to 20 wt. % of a terpolymer prepared from 60 to 70 wt. % of ethylene, 37 to 20 wt. % of an acrylic acid ester of a C.sub.2 -C.sub.12 alcohol and 3 to 10 wt. % of a monomer with epoxy groups.Type: GrantFiled: January 11, 1996Date of Patent: December 15, 1998Assignee: Bayer AktiengesellschaftInventors: Burkhard Kohler, Peter Bier
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Patent number: 5807932Abstract: The invention relates to a process for increasing the molecular weight of polycondensates, which comprises heating a polycondensate in the temperature range below the melting point and above the glass transition temperature in the solid phase of the polymer with additionof at least one sterically hindered hydroxyphenylalkylphosphonic ester or monoester.Type: GrantFiled: April 9, 1997Date of Patent: September 15, 1998Assignee: Ciba Specialty Chemicals CorporationInventors: Rudolf Pfaendner, Kurt Hoffmann, Heinz Herbst