Solid Polymer Derived From O-c(=o)-o- Or Hal-c(=o)- And Polyhydroxy Reactant Derived From At Least Two Polyhydroxy Reactants Patents (Class 525/469)
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Patent number: 12247122Abstract: The present invention relates to a moulding compound containing: A) at least one polymer selected from the group consisting of polycarbonate and polyester carbonate; B) a polymer containing B1) at least one rubber-modified vinyl(co)polymer containing B1.1) 80 to 95 wt. %, based on B1, of at least one vinyl monomer and B1.2) 5 to 20 wt. %, based on B1, of one or more rubber-elastic polybutadiene-containing graft foundations, wherein B1 contains polybutadiene-containing rubber particles, which are grafted with the vinyl monomers B1.1 and contain inclusions of vinyl(co)polymer consisting of the vinyl monomers B1.1, and a vinyl(co)polymer matrix which consists of the vinyl monomers B1.1 and is not bonded to these rubber particles and not enclosed in rubber particles, and optionally B2) further rubber particles, grafted with vinyl monomers, from B2.1) 5 to 75 wt. %, based on B.2, of at least one vinyl monomer grafted onto B2.2) 25 to 95 wt.Type: GrantFiled: May 11, 2021Date of Patent: March 11, 2025Assignee: Covestro Deutschland AGInventor: Kristina Pupovac
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Patent number: 11414540Abstract: Provided is a method of modifying a blend of polycarbonate and acrylonitrile/butadiene/styrene copolymer comprising adding composite particles to the blend, wherein the composite particles comprise (I) a partially crosslinked polyolefin core and (II) a full or partial shell comprising polymerized units of one or more vinyl monomer, and the resulting modified blend.Type: GrantFiled: December 4, 2018Date of Patent: August 16, 2022Assignees: Dow Global Technologies LLC, Rohm and Haas CompanyInventors: Liang Chen, Carlos A. Cruz, Yannick Saint-Gerard, Jessica Ye Huang, Matthew J. Crimmins, Douglas J. Hasso
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Patent number: 11034811Abstract: Provided are resin composition and a molded article produced therefrom, the resin composition comprising: a polycarbonate resin; a rubber-modified aromatic vinyl-based copolymer resin; a conductive additive including a carbon fiber and a carbon nanotube; talc; and a foaming agent, wherein the carbon fiber and the carbon nanotube are contained in a weight ratio of 1:0.1 to 1:0.4.Type: GrantFiled: November 22, 2017Date of Patent: June 15, 2021Assignee: Lotte Advanced Materials Co., Ltd.Inventors: Kihong Choi, Taegon Kang, Seungshik Shin, Dongin Ha
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Patent number: 9976023Abstract: A composition comprising: at least one conjugated polymer, at least one second polymer comprising repeat units represented by: (I) optionally, —[CH2—CH(Ph-OH)]— and (II) —[CH2—CH(Ph-OR)]— wherein Ph is a phenyl ring and R comprises a fluorinated group, an alkyl group, an alkylsulfonic acid group, an alkylene oxide group, or a combination thereof is described. Other polymers can be used as second polymer including polymers comprising modified naphthol side groups. Used in hole injection and hole transport layers for organic electronic devices. Increased lifetime and better processability can be achieved. Versatility with useful OLED emitters can be achieved. Ink formulations can be adapted for ink jet printing. The conjugated polymer can be a polythiophene. Applications include OLEDs and OPVs.Type: GrantFiled: June 13, 2014Date of Patent: May 22, 2018Assignee: NISSAN CHEMICAL INDUSTRIES, LTD.Inventors: Venkataramanan Seshadri, Christopher T. Brown, Brian E. Woodworth, Edward S. Yang
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Publication number: 20150141577Abstract: The present invention relates to a transparent film obtained by molding a polycarbonate resin composition comprising a specific weight of (A) a polycarbonate resin containing (a) a specific structural unit and (b) a specific structural unit, and a specific weight of (B) a resin having a composition different from that of the polycarbonate resin (A), with a specific absolute value of the difference in the glass transition temperature between the resin (B) and the polycarbonate resin (A) and a specific absolute value of the difference in the refractive index, wherein in the transparent film, the ratio of the retardation measured at a wavelength of 450 nm to the retardation measured at a wavelength of 550 nm satisfies a specific formula.Type: ApplicationFiled: January 30, 2015Publication date: May 21, 2015Applicant: MITSUBISHI CHEMICAL CORPORATIONInventors: Shingo NAMIKI, Hiroyuki TAJIMA, Masashi YOKOGI, Tomohiko TANAKA, Akira KOSUGE
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Publication number: 20150038615Abstract: A polycarbonate resin of the present invention is characterized by comprising repeating units represented by Formula 1, Formula 2, Formula 3 and Formula 4, respectively.Type: ApplicationFiled: December 13, 2011Publication date: February 5, 2015Applicant: Cheil Industries Inc.Inventors: Jun Ho Chi, O Sung Kwon, Jong Chan Hur, Hyuck Man Kwon, Bok Nam Jang
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Patent number: 8916270Abstract: Disclosed are compositions, glass filled compositions, articles made therefrom, and processes for making articles therefrom. In an embodiment, a composition can comprise: one or more polycarbonates wherein at least one of the polycarbonates is a polyester-polycarbonate having at least one unit derived from sebacic acid and has a biocontent of at least 5 weight % based upon a total weight of the polyester-polycarbonate, determined according ASTM-D6866; a glass content of 10 weight % or greater based upon a total weight of the composition; and an epoxy resin. The composition has a melt volume rate of greater than 10.5 cm3/10 minutes at 300° C./1.2 kg according to ASTM-D1238-10. A part molded having a 0.8 mm thickness molded from the composition has a gloss value of 89 or higher at 60°, according to ASTM-D523.Type: GrantFiled: August 2, 2012Date of Patent: December 23, 2014Assignee: Sabic Global Technologies B.V.Inventors: Jon Michael Malinoski, Thomas L. Evans
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Publication number: 20140329169Abstract: Provided are a hydroxyl group-containing sulfonated polyethersulfone copolymer, a method for preparing the same, a polymer electrolyte membrane for fuel cell, and a membrane electrode assembly including the same. More particularly, provided are a hydroxyl group-containing sulfonated polyethersulfone electrolyte membrane and a membrane electrode assembly including the same, which are applied to a fuel cell to provide significantly higher ion conductivity as compared to the sulfonated polymer electrolyte membranes according to the related art. The hydroxyl group-containing sulfonated polyethersulfone copolymer electrolyte membrane shows significantly higher ion conductivity under various temperature and humidity conditions as compared to the sulfonated polymer electrolyte membranes according to the related art. Therefore, it is expected that the hydroxyl group-containing sulfonated polyethersulfone copolymer substitutes for expensive fluoropolymer electrolyte membranes such as Nafion.Type: ApplicationFiled: April 28, 2014Publication date: November 6, 2014Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGYInventors: Hyoung-Juhn KIM, Yeon Hye KWON, Jun Young HAN, Hyung Chul HAM, Jong Hyun JANG, Suk Woo NAM, Eun Ae CHO, Sung Jong YOO, Chang Won YOON
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Patent number: 8853331Abstract: Hyperbranched polycarbonates having stabilizing groups, prepared by reaction of (a) at least one compound having at least three alcoholic hydroxyl groups per molecule with (b) at least one reagent of the general formula I (c) and at least one reagent of the general formula X3-(A1)m-X4, where the variables are defined as follows: X1, X2 are identical or different and are selected from among halogen, C1-C10-alkoxy, C6-C10-aryloxy and O—C(?O)-halogen, X3 is a functional group selected from among OH, SH, NH2, NH—C1-C4-alkyl, iso-cyanate, epoxy, COOH, COOR12, C(?O)—O—C(?O), C(?O)—Cl, R12 is C1-C4-alkyl or C6-C10-aryl, A1 is a spacer or a single bond, m is zero or one. X4 is a group selected from among phenol groups, benzophenones, aromatic amines and nitrogen-comprising heterocycles, in each case substituted or unsubstituted.Type: GrantFiled: September 9, 2011Date of Patent: October 7, 2014Assignee: BASF SEInventors: Bernd Bruchmann, Jens Aβmann, Claudius Schwittay, Harald Schäfer
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Patent number: 8846818Abstract: Thermoplastic polymer particles directly cross-linked together or cross-linked via a separate and independent polymer network to form an inter-penetrating network are disclosed herein, along with methods of manufacturing and use as interleaf tougheners of pre-pregs and composite articles.Type: GrantFiled: May 26, 2010Date of Patent: September 30, 2014Assignee: Cytec Technology Corp.Inventors: Yi Wei, Alexandre A. Baidak, James Senger
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Publication number: 20140275321Abstract: Photoactive additives, such as cross-linkable polycarbonate resins, are disclosed. The additive is formed from the reaction of a monohydroxybenzophenone, a dihydroxybenzophenone, a diol chain extender, and one or more linker moieties having functional groups that react with the phenolic groups on the other ingredients. If desired, a secondary linker moiety and/or an end-capping agent can be used. When added to a base polymeric resin, the photoactive additive permits crosslinking when exposed to ultraviolet light.Type: ApplicationFiled: March 13, 2014Publication date: September 18, 2014Applicant: SABIC Innovative Plastics IP B.V.Inventors: Jean-Francois Morizur, Paul Dean Sybert
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Patent number: 8742057Abstract: A polycarbonate resin composition (X), comprises: (A) a polycarbonate resin containing (a) a structural unit derived from a dihydroxy compound having a moiety represented by the following formula (1) in a part of a structure; and (B) an aromatic polycarbonate resin, wherein a reduced viscosity of the aromatic polycarbonate resin (B) is 0.55 dl/g or less, a proportion of the aromatic polycarbonate resin (B) in the polycarbonate resin composition (X) is 30 wt % or more, and a total light transmittance of the polycarbonate resin composition (X) is 90% or less: CH2—O??(1).Type: GrantFiled: August 19, 2013Date of Patent: June 3, 2014Assignee: Mitsubishi Chemical CorporationInventors: Masashi Yokogi, Haruo Sasaki
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Patent number: 8686107Abstract: A polycarbonate diol comprising repeating units represented by the following formula (A) and a terminal hydroxy group, 60-100 mol % of the repeating units represented by the formula (A) being repeating units represented by the following formula (B) or (C). The amount of the repeating units represented by the formula (B) is 60-100 mol % based on the total amount of the repeating units represented by the formula (A). The polycarbonate diol has a terminal primary OH ratio of 95% or higher. (A) (In the formula, R represents a C2-12 divalent aliphatic or alicyclic hydrocarbon.Type: GrantFiled: November 4, 2008Date of Patent: April 1, 2014Assignee: Asahi Kasei Chemicals CorporationInventors: Tetsuo Masubuchi, Eizaburo Ueno
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Publication number: 20140061533Abstract: Disclosed herein are indane bisphenol monomer units, and polymers derived from such monomer units. Also disclosed herein are blends including such polymers, articles made from such polymers and blends, methods of using such monomers, polymers, and blends, and processes for preparing such monomers, polymers, and blends.Type: ApplicationFiled: September 5, 2012Publication date: March 6, 2014Inventors: Laura G. Schultz Hume, S/shri. Shubashree Swaminathan, Ganapathy Bhotla Venkata Ramanarayanan
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Patent number: 8609786Abstract: A method of making a thermoplastic composition comprises melt blending a reaction mixture comprising a first polycarbonate comprising repeat units derived from monoaryl monomers (II) and (III) and a diaryl monomer (IV), wherein the sum of the mole percent of the repeat units derived from monomers (II) and (III) is greater than or equal to 30 mole percent, and the mole percent of the repeat units derived from monomer (IV) is 5 to 70 mole percent, each based on the total moles the repeat units derived from monomers (II), (III), and (IV), and the total weight of the repeat units derived from monomers (II), (III), and (IV) is greater than or equal to 90 wt. % of the first polycarbonate; and an additional polycarbonate, comprising 50 to 100 mole percent of repeat units derived from a bisphenol cyclohexane.Type: GrantFiled: December 18, 2008Date of Patent: December 17, 2013Assignee: Sabic Innovative Plastics IP B.V.Inventors: Johannes Martinus Dina Goossens, Hendrik Theodorus van de Grampel, Jan-Pleun Lens, Lina Prada, Sandeep Tripathi, André van Zyl
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Publication number: 20130331527Abstract: A polycarbonate resin composition (X), comprises: (A) a polycarbonate resin containing (a) a structural unit derived from a dihydroxy compound having a moiety represented by the following formula (1) in a part of a structure; and (B) an aromatic polycarbonate resin, wherein a reduced viscosity of the aromatic polycarbonate resin (B) is 0.55 dl/g or less, a proportion of the aromatic polycarbonate resin (B) in the polycarbonate resin composition (X) is 30 wt % or more, and a total light transmittance of the polycarbonate resin composition (X) is 90% or less: ?CH2—O???(1).Type: ApplicationFiled: August 19, 2013Publication date: December 12, 2013Applicant: MITSUBISHI CHEMICAL CORPORATIONInventors: Masashi YOKOGI, Haruo Sasaki
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Publication number: 20130317182Abstract: [Problem] To provide a process for manufacturing, easily and using a conventional branching agent, a branched aromatic polycarbonate resin which has both a sufficiently high molecular weight and a desired degree of branching. [Solution] A branched aromatic polycarbonate resin having a degree of branching (N value) controlled within a specific range is manufactured by subjecting an aromatic polycarbonate prepolymer that has a branched structure introduced using a specific amount of a branching agent to molecular-weight-increasing linking reaction with an aliphatic diol compound in the presence of a transesterification catalyst under the condition of a reduced pressure. The amount (A) of the branching agent used in adjusted on the basis of the correlation between the amount (A) of the branching agent used and the N value of the branched aromatic polycarbonate resin.Type: ApplicationFiled: February 9, 2012Publication date: November 28, 2013Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Yoshinori Isahaya, Atsushi Hirashima, Hidefumi Harada, Maki Ito, Jun-ya Hayakawa, Takehiko Isobe, Taichi Tokutake, Yousuke Shinkai
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Patent number: 8426531Abstract: The present invention relates to an improved process for online measurement of monomer concentration, specifically bisphenol A, in an interfacial polycarbonate manufacturing process. Wherein the measurement is obtained by vibrational spectroscopy for the purpose of improving process control, specifically, controlling the carbonate polymer molecular weight.Type: GrantFiled: February 24, 2010Date of Patent: April 23, 2013Assignee: Styron Europe GmbHInventors: Jean P. Chauvel, Jr., John O. Osby, Wenzel P. Bartlett, Serena K. Stephenson, John S. Hanson, Jeffery S. Bradley, Walter D. Leatherwood, Rajesh P. Paradkar, Thoi H. Ho
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Patent number: 8426532Abstract: Methods of forming polycarbonate graft copolymers are provided. In particular, a polycarbonate polymer or copolymer containing allyl groups provides the backbone for the graft copolymer, and pendant chains are attached to the copolymer through the allyl groups. The graft copolymers exhibit a combination of high transparency, good graft levels, good scratch resistance, and/or good anti-fog properties.Type: GrantFiled: September 17, 2010Date of Patent: April 23, 2013Assignee: SABIC Innovative Plastics IP B.V.Inventors: Rubin Huang, Andre van Zyl, Jan Pleun Lens, Theodorus Lambertus Hoeks, Hans-Peter Brack, Jan Henk Kamps
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Publication number: 20130035441Abstract: In some embodiments, a composition comprises a bisphenol-A polycarbonate, wherein a molded article of the composition has transmission level greater than or equal to 90.0% at 2.5 mm thickness as measured by ASTM D1003-00 and a yellow index (YI) less than or equal to 1.5 as measured by ASTM D1925.Type: ApplicationFiled: August 2, 2012Publication date: February 7, 2013Applicant: SABIC INNOVATIVE PLASTICS IP B.V.Inventors: Johannes de Brouwer, Paulus Johannes Maria Eijsbouts, Hatem Abdallah Belfadhel, Jos Arie van den Bogerd
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Patent number: 8222349Abstract: A bioabsorbable material which is flexible and degradable at a controlled rate, and an in-vivo indwelling device made thereof. The bioabsorbable material is a copolymer composed of an aromatic compound having an ?,?-unsaturated carboxylic group and at least one hydroxyl group as substituents on the aromatic ring, and a polycarbonate or a monomer constituting polycarbonate. Alternatively, it is a copolymer composed of, as the first component, an aromatic compound having an ?,?-unsaturated carboxylic group and at least one hydroxyl group as substituents on the aromatic ring, as the second component, an aromatic compound having an ?,?-unsaturated carboxylic group and at least two hydroxyl groups as substituents on the aromatic ring, and, as the third component, a polycarbonate or a monomer constituting polycarbonate.Type: GrantFiled: September 21, 2010Date of Patent: July 17, 2012Assignee: Terumo Kabushiki KaishaInventors: Mitsuru Akashi, Michiya Matsusaki, Yotaro Fujita, Makoto Onishi
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Publication number: 20120178886Abstract: To provide a polycarbonate resin composition excellent in low-birefringence and strength. Disclosed is a polycarbonate resin composition prepared by blending a polycarbonate resin (A) prepared by forming carbonate bonds in a 95-5% by mole of dihydroxy compound represented by formula (1) and a 5-95% by mole of dihydroxy compound represented by formula (2) with a diester carbonate, and a polycarbonate resin (B) prepared by forming carbonate bonds in dihydroxy compound represented by formula (3) with a diester carbonate or phosgene in a 45-85% ratio by weight of (100×(A))/((A)+(B)). (in the formula, R1 and R2 represent a hydrogen atom or methyl respectively.Type: ApplicationFiled: July 12, 2010Publication date: July 12, 2012Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Noriyuki Kato, Hiroki Furuhashi, Shu Yoshida, Kazuaki Kaneko, Keiichi Kameyama
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Patent number: 8193290Abstract: A modified polyurethane including a lipid substituent from at least one urethane nitrogen and/or at least carbon atom of the modified polyurethane.Type: GrantFiled: June 20, 2008Date of Patent: June 5, 2012Assignee: The Children's Hospital of PhiladelphiaInventors: Robert J. Levy, Ivan Alferiev, Stanley J. Stachelek
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Publication number: 20120004375Abstract: The present invention relates to copolycarbonates with improved surface hardness, processes for producing the same, and use of the same for producing blends, moldings, and extrudates, foil (layers), foil laminates, and cards.Type: ApplicationFiled: March 12, 2010Publication date: January 5, 2012Applicant: Bayer MaterialScience AGInventors: Helmut Werner Heuer, Rolf Wehrmann
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Patent number: 8058384Abstract: The invention relates to a method for producing a thermoplastic resin, comprising using a composition at least comprising a fluorene-containing dihydroxy compound represented by the following formula (1) and a fluorene-containing hydroxy compound represented by the following formula (2) in an amount of from 0.5 parts by weight to 1.5 parts by weight relative to 100 parts by weight of the fluorene-containing dihydroxy compound of formula (1).Type: GrantFiled: October 26, 2009Date of Patent: November 15, 2011Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Noriyuki Kato, Toshiaki Yamada, Shu Yoshida, Jun Hagiwara, Hiroki Furuhashi, Kazuaki Kaneko, Keiichi Kameyama
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Publication number: 20110190457Abstract: The present invention relates to polymeric materials having enhanced properties. In some cases, the materials may comprise polymers having shape-persistent portions which may enhance the mechanical properties of the material. The materials may exhibit higher stiffness or strength and ductility values, resulting in higher energy absorption and enhanced protection, as well as longer lifetimes for product usage. In some cases, the materials may be optically transparent and lightweight, making them suitable for in various applications including protective materials.Type: ApplicationFiled: March 7, 2008Publication date: August 4, 2011Applicant: Massachusetts Institute of TechnologyInventors: Nicholas T. Tsui, Edwin L. Thomas, Timothy M. Swager
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Publication number: 20100305239Abstract: Thermoplastic polymer particles directly cross-linked together or cross-linked via a separate and independent polymer network to form an inter-penetrating network are disclosed herein, along with methods of manufacturing and use as interleaf tougheners of pre-pregs and composite articles.Type: ApplicationFiled: May 26, 2010Publication date: December 2, 2010Applicant: CYTEC TECHNOLOGY CORP.Inventors: Yi WEI, Alexandre A. BAIDAK, James SENGER
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Patent number: 7816444Abstract: An injection molded article comprising a polycarbonate composition. The polycarbonate composition is scratch resistant, flame retardant, has a low chlorine and bromine content and is dark colored.Type: GrantFiled: September 25, 2006Date of Patent: October 19, 2010Assignee: Sabic Innovative Plastics IP B.V.Inventors: Jan Henk Kamps, Edward Kung, Jan-Pleun Lens, Michael Teruki Takemori, Hendrik Theodorus van de Grampel
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Patent number: 7745548Abstract: Homo- or copolyoxymethylenes are described and contain the repeat structural unit of formula I -A-O—R1—O—CO—(R2—CO—)m—O—??(I), where A is a radical derived from a homo- or copolyoxymethylene, R1 is an alkylene radical having at least two carbon atoms, or a cycloalkylene radical, R2 is a direct carbon-carbon bond, or an alkylene, cycloalkylene, arylene, or aralkylene radical, and m is 0 or 1. These polymers may be prepared by reacting end-group-functionalized homo- or copolyoxymethylenes with selected chain-linking agents. The reaction products can be used to produce moldings.Type: GrantFiled: September 3, 2004Date of Patent: June 29, 2010Assignee: Ticona GmbHInventors: Dirk Zierer, Jens Schiebisch, Klaus Kurz
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Publication number: 20100160575Abstract: A method of making a thermoplastic composition comprises melt blending a reaction mixture comprising a first polycarbonate comprising repeat units derived from monoaryl monomers (II) and (III) and a diaryl monomer (IV), wherein the sum of the mole percent of the repeat units derived from monomers (II) and (III) is greater than or equal to 30 mole percent, and the mole percent of the repeat units derived from monomer (IV) is 5 to 70 mole percent, each based on the total moles the repeat units derived from monomers (II), (III), and (IV), and the total weight of the repeat units derived from monomers (II), (III), and (IV) is greater than or equal to 90 wt. % of the first polycarbonate; and an additional polycarbonate, comprising 50 to 100 mole percent of repeat units derived from a bisphenol cyclohexane.Type: ApplicationFiled: December 18, 2008Publication date: June 24, 2010Inventors: Johannes Martinus Dina Goossens, Hendrik Theodorus van de Grampel, Jan-Pleun Lens, Lina Prada, Sandeep Tripathi, Andre van Zyl
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Patent number: 7709581Abstract: A thermoplastic composition comprises a copolycarbonate comprising 25 to 100 mole percent of a first carbonate unit derived from a dihydroxy aromatic compound having the formula wherein Ra? and Rb? are C1-12 alkyl, T is a C5-16 cycloalkylene, a C5-16 cylcloalkylidene, a C1-5 alkylene, a C1-5 alkylidene, a C6-13 arylene, a C7-12 arylalkylene, C7-12 arylalkylidene, a C7-12 alkylarylene, or a C7-12 arylenealkyl, and r and s are each independently 1 to 4, and r and s are 1 to 4; and 0 to 75 mole percent of a second carbonate unit, wherein the first carbonate unit and second carbonate unit are not identical; a polysiloxane-polycarbonate copolymer comprising 0.15 to 30 weight percent of a polysiloxane block comprising siloxane units of the formula wherein E is on average of 4 to 60 units, and 70 to 99.85 weight percent of a third carbonate unit, wherein an article having a thickness of 3.Type: GrantFiled: September 29, 2006Date of Patent: May 4, 2010Assignee: SABIC Innovative Plastics IP B.V.Inventors: Katherine Glasgow, Jan-Pleun Lens, Brian Mullen, Vandita Pai-Paranjape
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Patent number: 7700696Abstract: A thermoplastic composition comprises A) 25 to 95 parts by weight of a first polycarbonate consisting essentially of i) 25 to 100 mole percent of a first carbonate unit comprising an alkyl-substituted bisphenol carbonate unit, ii) 0 to 75 mole percent of a second carbonate unit where the first and second carbonate units are not identical, and the sum of the mole percentages of the first and second carbonate units in the first polycarbonate is 100 mole percent; B) 5 to 75 parts by weight of a polyester-polycarbonate where the molar ratio of carbonate unit to arylate ester unit is 95:5 to 10:90; and C) 0 to 65 parts by weight of a second polycarbonate, where the first polycarbonate and second polycarbonate are not identical, and the sum of the parts by weight of the first polycarbonate, the polyester-polycarbonate, and the second polycarbonate is 100 parts by weight.Type: GrantFiled: June 28, 2006Date of Patent: April 20, 2010Assignee: SABIC Innovative Plastics IP B.V.Inventors: Robert Dirk van de Grampel, Jan-Pleun Lens, Dake Shen
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Patent number: 7687584Abstract: The present invention relates to a miscible transparent polymer blend, specifically, a polycarbonate blend which comprises homopolycarbonates and/or copolycarbonates. In particular, high aspect ratio monomers confer unique miscibility properties on polycarbonates. Miscible, transparent blends have been found to form from polycarbonate mixtures containing as components of the mixture (1) polycarbonates of bisphenol A monomers copolymerized with a variety of bisphenols, and (2) polycarbonates containing high aspect ratio monomers.Type: GrantFiled: July 24, 2006Date of Patent: March 30, 2010Assignee: South Dakota School of Mines and TechnologyInventors: David A. Boyles, John T. Bendler, Tsvetanka Filipova
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Patent number: 7524562Abstract: The invention includes embodiments that relate to a method of improving the abrasion resistance of a plastic article. The method comprises: (a) providing a composition comprising at least one e-beam active thermoplastic polymeric material; (b) forming an article from the composition of step (a); and (c) exposing the article formed in step (b) to an electron beam source. The invention also includes embodiments that relate to an article comprising an abrasion resistant surface.Type: GrantFiled: October 18, 2005Date of Patent: April 28, 2009Assignee: Sabic Innovative Plastics IP B.V.Inventors: Ryo Tamaki, Steven Thomas Rice, Hieu Minh Duong, Xian-Zhi Zhou, Gary Charles Davis, Elliott West Shanklin
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Patent number: 7408014Abstract: A modified polyurethane including a lipid substituent pendant from at least one urethane nitrogen and/or at least one carbon atom of the modified polyurethane, methods of preparing modified polyurethanes and the use thereof as an implantable biomaterial.Type: GrantFiled: July 8, 2004Date of Patent: August 5, 2008Assignee: The Children's Hospital of PhiladelphiaInventors: Robert J. Levy, Ivan Alferiev, Stanley J. Stachelek
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Publication number: 20080171836Abstract: Synthesis methods for creating polymeric compounds comprising dihydroxyphenyl derivatives (DHPD), or DHPp i.e. polymers modified with DHPD, with desired surface active effects are described. The polymer backbone of DHPp has structural or performance features that can be tailored to control physical properties of DHPp, allowing it to be useful for different applications i.e. tissue adhesives or sealants, adhesion promoting coatings, and antifouling coatings.Type: ApplicationFiled: August 6, 2007Publication date: July 17, 2008Inventor: Bruce P. Lee
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Patent number: 7365124Abstract: A polymer blend consisting essentially of at least one thermoplastic polymer, and a polymer comprising structural units derived from a 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine is disclosed.Type: GrantFiled: August 24, 2004Date of Patent: April 29, 2008Assignee: General Electric CompanyInventors: Veeraraghavan Srinivasan, Chandrashekhar Lingannaiah, Anantharaman Dhanabalan
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Patent number: 7166687Abstract: A thermoplastic composition comprising a matrix of a polycarbonate polymer in which are embedded polysiloxane domains with an average domain size between 20 and 45 nanometers. Said compositions can be obtained by combining a first polycarbonate/poly(diorganosiloxane) copolymer; with a second polycarbonate/poly(diorganosiloxane) copolymer. A range of translucencies are obtainable by varying the relative amounts of the two copolymers without substantial loss in impact properties.Type: GrantFiled: February 20, 2004Date of Patent: January 23, 2007Assignee: General Electric CompanyInventors: Robert W. Venderbosch, Jan-Willem Goedmakers, Jeremy D. Hurst
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Patent number: 6897265Abstract: A coil coating composition producing a coil coating with excellent properties at a lower peak metal temperature includes (a) a first, branched polyester prepared by condensation of a polyol component consisting essentially of a flexibilizing diol, 2-methyl-1,3-propanediol, and a polyol having at least three hydroxyl groups and an acid component consisting essentially of isophthalic acid; (b) a second, essentially linear polyester prepared by condensation of a polyol component consisting essentially of a flexibilizing diol and 2-methyl-1,3-propanediol and an acid component consisting essentially of isophthalic acid; and (c) a crosslinking agent.Type: GrantFiled: October 29, 2002Date of Patent: May 24, 2005Assignee: BASF CorporationInventors: Donald J. Algrim, Daniel Calimente, Andrew Dell, David E. Lindow
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Patent number: 6800697Abstract: In the present invention, a retardation film is produced by adjusting the mixing ratio of at least two kinds of mutually compatible polymers A and B and by forming the resulting mixture into the film. The polymers A and B are copolymers comprising respective two common repeating units and different in copolymerization composition. According to the present invention, the retardation film having the desired wavelength dispersion can industrially and simply be produced. Furthermore, there can be provided the high-quality retardation film capable of controlling the wavelength dispersion of the retardation at a high level.Type: GrantFiled: December 18, 2001Date of Patent: October 5, 2004Assignee: Teijin LimitedInventors: Akihiko Uchiyama, Masakazu Tsujikura, Takashi Kushida
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Patent number: 6740714Abstract: A thermoplastic molding composition suitable for making articles having good combination of properties is disclosed. The composition contains (A) a copolycarbonate derived from compounds of formula (I) wherein R1 to R4 independently of one another represent H, C1-C4-alkyl, phenyl, substituted phenyl or halogen, and compounds of formula (II) wherein R5 to R8 independently of the others denote H, CH3, Cl or Br and X is C1-C5-alkylene, C2-C5-alkylidene, C5-C6-cycloalkylene, C5-C10-cycloalkylidene, and (B) a homopolycarbonate derived from bisphenol A. The composition that features resistance to stress cracking and good low-temperature properties is suitable for automotive construction and exterior applications.Type: GrantFiled: July 17, 2002Date of Patent: May 25, 2004Assignee: Bayer AktiengesellschaftInventors: Silke Kratschmer, Klaus Horn, Michael Erkelenz
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Publication number: 20040097662Abstract: Disclosed is a transparent/translucent molding composition and process for making prepared from an impact modifier and a resin blend of polycarbonate and a cycloaliphatic polyester having a matching index of refraction.Type: ApplicationFiled: February 24, 2003Publication date: May 20, 2004Inventors: Satish Kumar Gaggar, Johannes Jacobus de Moor, Paul Honigfort, Gabrie Hoogland, Mark van Heeringen, Eelco M.S. van Hamersveld
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Patent number: 6730748Abstract: A thermoplastic molding composition that features improved low-temperature properties and is thus suitable for application in exterior automotive parts is disclosed. The composition contains (A) 80 to 60 percent of a copolycarbonate wherein 65 to 75 mole percent of its structural units are derived from compounds of formula (I) wherein R1, R2, R3 and R4 independently of one another represents H, C1-C4-alkyl, phenyl, substituted phenyl or halogen, and wherein 25 to 35 mole percent of its structural units are derived from compounds of formula (II) where R5, R6, R7 and R8 independently one of the others denote H, CH3, Cl or Br and X is C1-C5-alkylene, C2-C5-alkylidene, C5-C6-cycloalkylene, C5-C10-cycloalkylidene and (B) 20 to 40 percent of a homopolycarbonate of bisphenol A having a melt flow rate, determined in accordance with ASTM D-1238 under 1.2 kg loading at 300° C. of 3 to 12 gm/10 minutes.Type: GrantFiled: July 9, 2002Date of Patent: May 4, 2004Assignees: Bayer Polymers LLC, Bayer AktiengesellschaftInventors: James Y. J. Chung, Winfried G. Paul, Michael Erkelenz, Melanie Moethrath, Klaus Horn
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Patent number: 6716957Abstract: A bioabsorbable material such as a terpolymer of poly-(L-lactide/D-lactide/glycolide). The material may consist of 85 molar percent L-lactide, 5 molar percent D-lactide, and 10 molar percent glycolide. The material may have a heat of fusion of about 15-25 J/G, tensile strength retention at 26 weeks of incubation of at least about 50%, and tensile strength retention at 52 weeks of incubation of at most about 25%. The material may be used in implantable devices such as bone fixation devices.Type: GrantFiled: January 8, 2001Date of Patent: April 6, 2004Assignee: Stryker Technologies CorporationInventor: Deger C. Tunc
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Publication number: 20030040586Abstract: A thermoplastic molding composition suitable for making articles having good combination of properties is disclosed.Type: ApplicationFiled: July 17, 2002Publication date: February 27, 2003Inventors: Silke Kratschmer, Klaus Horn, Michael Erkelenz
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Patent number: 6462146Abstract: Copolymers of BPA and menthane bisphenols such as BPT1 and BPT2 can be used as a compatabilizer to allow the formation of homogeneous blends of BPA with menthane bisphenol polycarbonates such as poly-BPT1 or poly-BPT2 or copolymers thereof. Thus, a compatible polycarbonate blend is made by combining a bisphenol A polycarbonate, a menthane bisphenol polycarbonate and a BPA/menthane bisphenol copolymer compatabilizer, and mixing the combined materials to form a blend. The compatabilizer may contain one or more species of menthane bisphenol. In a specific example, BPT1 and BPT2 are used in the compatabilizer in a ratio, BPT1/BPT2, in the range of 70/30 to 10/90, preferably less than or equal to 1/1, for example around 30/70. By adjusting the relative amounts and the properties of the bisphenol A polycarbonate and the menthane bisphenol polycarbonate, the glass transition temperature and the toughness of the blend can be selected.Type: GrantFiled: March 27, 2001Date of Patent: October 8, 2002Assignee: General Electric CompanyInventor: James Mahood
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Patent number: 6037437Abstract: A method for producing an aromatic polycarbonate which comprises subjecting to a transesterification polymerization reaction at least one polymerizable material selected from a molten monomer mixture of an aromatic dihydroxy compound and a diaryl carbonate, and a molten prepolymer obtained from the monomer mixture, wherein the transesterification reaction is performed in one or more polymerizers which is or are connected through a pipeline system toward an outlet for a final aromatic polycarbonate product, wherein the pipeline system comprises one or more pipes through which a molten aromatic polycarbonate having a number average molecular weight increased by the transesterification polymerization reaction is passed while contacting an inner wall of the pipe or pipes, and wherein a molten aromatic polycarbonate having a number average molecular weight of less than 2,500 is passed through the pipe or pipes at a velocity of 0.05 m/sec.Type: GrantFiled: December 9, 1997Date of Patent: March 14, 2000Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Kyosuke Komiya, Kazumi Hasegawa
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Patent number: 5936047Abstract: The weight average molecular weight of a polycarbonate resin is predictably reduced by reaction with a multifunctional aliphatic compound at a temperature of 250 C. to 350 C.Type: GrantFiled: August 18, 1997Date of Patent: August 10, 1999Assignee: General Electric CompanyInventors: Johannes J. De Bont, Theodorus L. Hoeks
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Patent number: 5863992Abstract: Branched polycarbonates having properties suitable for blow molding are prepared by equilibrating a linear or branched aromatic polycarbonate with certain tetraphenols, especially 2,2,5,5-tetrakis (4-hydroxyphenyl)hexane and ?1,1-bis(p-hydroxyphenyl)ethyl!-phenyl ether.Type: GrantFiled: December 17, 1996Date of Patent: January 26, 1999Assignee: General Electric CompanyInventors: Patrick Joseph McCloskey, David Michel Dardaris, YeGang Lin, Pin-Pin Wu, Jimmy Lynn Webb
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Patent number: 5854378Abstract: This invention an aspartic acid copolymer obtained by copolymerizing a monomer mixture comprising (1) aspartic acid, maleamic acid and/or a reaction product of maleic acid and ammonia as a main monomer, (2) fumaric acid, and (3) succinic acid and containing 0.005 to 3% by weight, based on the total monomers, of ammonia in the form of an ammonium salt and hydrolyzing the resulting copolymer partially or completely; and a process for producing the same.Type: GrantFiled: December 12, 1996Date of Patent: December 29, 1998Assignee: Mitsubishi Chemical CorporationInventors: Masayuki Tomida, Masako Yoshikawa, Takeshi Nakato