Utilizing A Tubular Or Loop Reactor Patents (Class 525/52)
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Patent number: 11618795Abstract: The present invention relates to a multimodal ethylene copolymer composition having a density of 920 to 949 kg/m3 and a flexural modulus, wherein said flexural modulus is following the equation: Flexural modulus [MPa]<21.35·density [kg/m3]?19585 [1]. The multimodal ethylene copolymer composition according to the invention can be used in a highly flexible cable jacket, preferably a power cable jacket.Type: GrantFiled: April 21, 2021Date of Patent: April 4, 2023Assignee: BOREALIS AGInventors: Anna Hjärtfors, Yi Liu, Ravindra Tupe, Victor Sumerin
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Patent number: 11555116Abstract: Provided herein is a copolymer of ethylene and acrylate(s) having a melt flow index (MFI) greater than or equal to 50 g/10 minutes, obtained by free-radical copolymerisation under high pressure carried out in a tubular reactor, and methods of using the same. Also provided herein is a thermoplastic composition, particularly intended to be extruded or injection moulded, having one or more copolymers of ethylene and acrylate(s) at a content ranging from 0.1 to 20 wt. %, and one or more thermoplastic polymers.Type: GrantFiled: March 26, 2019Date of Patent: January 17, 2023Assignee: SK Global Chemical Co., Ltd.Inventors: Paul Coupillaud, Sebastien Quinebeche, Alain Bouilloux
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Patent number: 10974223Abstract: [Object] To provide a method for producing a water-absorbent resin in powder form or particle form, which has excellent physical properties such as water absorption performance and the like, at high productivity. [Solution] A method for producing a water-absorbent resin includes: a polymerization step of polymerizing a monomer, which is a raw material of the water-absorbent resin, to obtain a hydrous gel crosslinked polymer dispersed in an organic solvent; and a separation step of separating the organic solvent and the hydrous gel crosslinked polymer. The separation step includes transfer, compression, and discharge of the hydrous gel crosslinked polymer.Type: GrantFiled: December 28, 2016Date of Patent: April 13, 2021Assignee: NIPPON SHOKUBAI CO., LTD.Inventors: Tokio Shuto, Motohiro Imura, Shin-Ichi Fujino, Koji Honda, Ryota Wakabayashi
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Patent number: 10759936Abstract: The present invention relates to a thermoplastic ABS composition reinforced with natural fibres, which comprises an ABS polymer, natural fibres, a compatibilizing polymer, and processing aids comprising a lubricant and titanium dioxide. It relates also to a moulded article prepared from the thermoplastic composition and to its use in extrusion, injection, compression moulding and 3D printing.Type: GrantFiled: November 17, 2016Date of Patent: September 1, 2020Assignee: ELIX POLYMERS, S.L.Inventors: Ramon Malet Murillo, Marc Perez Fernandez, Ignacio Buezas Sierra, Antonio Prunera Casellas, David Castaneda Garrido
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Patent number: 10604643Abstract: The pipe articles with excellent stress crack resistance can be achieved by providing ethylene copolymer composition comprises ethylene and a C6-C10 ?-olefin comonomer; the ethylene copolymer having a total density of 0.945-0.980 g/cm3 and a MFR5 of 0.10-0.50 g/10 min; and the ethylene copolymer having a comonomer content of 1-5% wt. The ethylene copolymer has Mx/My in the range of not less than 14.0; gpcBR in the range of from 0.20 to 0.80; and strain hardening modulus <Gp> in the range of not less than 53.4.Type: GrantFiled: November 15, 2016Date of Patent: March 31, 2020Assignees: SCG Chemicals Co., Ltd., Mitsui Chemicals, Inc.Inventors: Natthaporn Suchao-in, Kenji Iwamasa, Eiji Shiba, Warachad Klomkamol, Patcharin Samphawamontri, Watcharee Cheevasrirungruang, Shinichi Kojoh, Yasunori Kaneko, Takashi Fukawa, Thipphaya Pathaweeisariyakul
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Patent number: 10599132Abstract: An automated fastener insert installation system for composite panels is provided. A first module receives and secures a composite panel with respect to an origin of a first coordinate system, wherein the composite panel has opposed major surfaces and defines an insert-receiving orifice extending through one of the major surfaces, and is secured such that one of the major surfaces is externally accessible. A second module engages each of a plurality of fastener inserts with an installation aide. Third module determines a configuration of the orifice defined by the composite panel, selects a corresponding one of the fastener inserts engaged with the installation aide, inserts the selected fastener insert into the orifice, and dispenses an adhesive material through the installation aide and into the orifice about selected fastener insert such that the adhesive material secures the selected fastener insert within the orifice. Associated systems are also provided.Type: GrantFiled: February 11, 2019Date of Patent: March 24, 2020Assignee: The Boeing CompanyInventors: Aaron Coon, Chris G. McInelly, Bret Hoeksema, Ryan Lillibridge, Tom Allen, Steve Solack, Kevin Bowe, Gary K. Allen
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Patent number: 9976017Abstract: Polyethylene composition having a density of 950-960 kg/m3, a SHI(1,100) of 4-12, a melt index MI2 between 0.2 and 2 g/10 min, and a relationship between spiral flow ‘SF’ (measured in mm at 250° C./1000 bar/100 mm/s) and ESCR ‘E’ (measured in hours) of E>200?SF. The composition contains 48-62 wt % of an ethylene polymer (A) and 38-52 wt % of an ethylene copolymer (B). Copolymer (B) has a higher weight average molecular weight than polymer (A), and both of fractions (A) and (B) have a reverse comonomer distribution such that comonomer content increases with increasing molecular weight in the individual fraction.Type: GrantFiled: January 5, 2015Date of Patent: May 22, 2018Assignee: INEOS EUROPE AGInventors: Benoit Koch, Christophe Moineau
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Patent number: 9796806Abstract: The invention relates to dioxomolybdenum (VI) complex compounds of the formula MoO2(L)x(Y)2-x, where the ligand L has the formula (I). Such complex compounds are suitable in particular as catalysts for one- and two-component polyurethane compositions. The invention also relates to two-component polyurethane compositions including at least one polyisocyanate as the first component, at least one polyol as the second component, and at least one such dioxomolybdenum (VI) complex compound as the catalyst. The invention further relates to one-component polyurethane compositions comprising at least one polyurethane prepolymer with isocyanate groups, which are made from at least one polyisocyanate with at least one polyol, and comprising such a dioxomolybdenum (VI) complex compound as the catalyst. The invention additionally relates to different uses of said polyurethane compositions.Type: GrantFiled: July 20, 2016Date of Patent: October 24, 2017Assignee: SIKA TECHNOLOGY AGInventors: Urs Burckhardt, Rita Cannas
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Patent number: 9745397Abstract: A process for polymerizing propylene in the presence of a polymerization catalyst by copolymerizing propylene with a comonomer selected from the group of ethylene and C4-C10 alpha-olefins in three polymerization stages. The polymer produced in the first polymerization stage has the highest melt flow rate and the lowest content of comonomer. The polymer produced in the last polymerization stage has the lowest melt flow rate and the highest content of comonomer. The polymer composition produced by the process has good mechanical properties and can be used for making pipes. The process has a good productivity.Type: GrantFiled: April 22, 2014Date of Patent: August 29, 2017Assignees: Borealis AG, Abu Dhabi Polymers Co. Ltd (Borouge) L.L.C.Inventors: Kauno Alastalo, Pauli Leskinen, Cristian Hedesiu, Johanna Lilja
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Patent number: 9605088Abstract: This invention relates to novel catalyst compositions based on Ruthenium- or Osmium-based complex catalysts and to a process for selectively hydrogenating nitrile rubbers in the presence of such catalyst compositions.Type: GrantFiled: October 19, 2012Date of Patent: March 28, 2017Assignee: ARLANXEO Deutschland GmbHInventors: Qingchun Liu, Zhenli Wei
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Patent number: 9587044Abstract: Polypropylene having a melt flow rate MFR2 (230° C.) of at least 20 g/10 min; and a Mw/Mn ratio of at least 15.0.Type: GrantFiled: June 10, 2014Date of Patent: March 7, 2017Assignee: Borealis AGInventors: Norbert Hafner, Klaus Bernreitner, Marcus Gahleitner
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Patent number: 9567416Abstract: The present invention relates to an apparatus and process for polymerizing olefins. One embodiment comprises polymerizing at least one monomer in a first loop reactor in the presence of a catalyst to produce a first polyolefin fraction. A portion of the first polyolefin fraction is transferred to a second loop reactor, connected in series with the first loop reactor. The process further comprises polymerizing in the second loop reactor at least one monomer in the presence of a catalyst to produce a second polyolefin fraction in addition to the first polyolefin fraction. The combination of the first and second polyolefin fractions can produce a polymer resin fluff having bimodal molecular weight distribution.Type: GrantFiled: December 22, 2015Date of Patent: February 14, 2017Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Louis Fouarge, Eric Damme, Olivier Miserque, Daniel Siraux, Philippe Bodart, Andre Lewalle, Marc Van der Auwera, Frans Van den Brande, Giacomo Conti, Hugo Vandaele, Mark Verleysen, Carl Van Camp, Etienne Laurent, Philippe Marechal, Marc Moers, Leopold D'Hooghe, Marjan Sillis, Kai Hortman, Pascal Folie, Renaud Oreins
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Patent number: 9260541Abstract: A method comprising preparing a multi-component catalyst system comprising a catalyst and a cocatalyst, and adjusting the level of at least one component of the catalyst system to maintain a user-desired level of catalyst activity throughout a process, wherein the component comprises a catalyst activator and wherein the catalyst activator comprises the catalyst or the cocatalyst. A method comprising contacting a polymerization catalyst system comprising a Ziegler-Natta catalyst and a cocatalyst with a catalyst activator at least twice during a polymerization process, wherein the polymerization process is carried out in a reactor system comprising multiple reactor types.Type: GrantFiled: May 19, 2010Date of Patent: February 16, 2016Assignee: FINA TECHNOLOGY, INC.Inventors: Kenneth P. Blackmon, David Ribour, Shabbir Malbari, Tim Coffy, Michel Daumerie
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Publication number: 20150025195Abstract: The present disclosure is related to bimodal high-density polyethylene polymer compositions with increased high melt strength and good processability comprising a base resin which has a density of about 945 kg/m3 to about 955 kg/m3, and comprises an ethylene polymer (A) having a density of at least about 968 kg/m3, in an amount ranging from 45% to 55% by weight and an ethylene polymer (B) having a density lower than the density of polymer (A) wherein said composition has a complex viscosity at a shear rate of 0.01 rad/s ranging from about 200 to about 450 kPa·s and a complex viscosity at a shear rate of 100 rad/s ranging from about 1900 to about 2500 Pa·s. The present disclosure also relates to methods of making, and using the present compositions, and to articles made from there composition, and preferably to pipes and fittings.Type: ApplicationFiled: December 21, 2012Publication date: January 22, 2015Applicant: INEOS Olefins & Polymers USA, a division of INEOS USA LLCInventors: Joshua Allen Cottle, Mark Anthony Gessner, Robert Ernest Sander, Luc Dheur
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Publication number: 20140350182Abstract: The invention provides for a process for removing thiocarbonylthio groups from polymer prepared by RAFT polymerisation, the process comprising: introducing into a flow reactor a solution comprising the RAFT polymer in solvent; and promoting a reaction within the flow reactor that removes the thiocarbonylthio groups so as to form a solution that flows out of the reactor comprising the RAFT polymer absent the thiocarbonylthio groups.Type: ApplicationFiled: December 14, 2012Publication date: November 27, 2014Inventors: John Chiefari, Christian Hornung, Almar Postma, Simon Saubern
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Patent number: 8871876Abstract: Ethylene-based interpolymers, e.g., ethylene-acrylic acid copolymers, are made by a process comprising the steps of: A. Injecting a first feed comprising a chain transfer agent system (CTA system) and ethylene into a first autoclave reactor zone to produce a first zone reaction product, the CTA system of the first reactor zone having a transfer activity Z1; and B. (1) Transferring at least part of the first zone reaction product to a second reactor zone selected from a second autoclave reactor zone or a tubular reactor zone, and (2) at least one of transferring or freshly injecting a feed comprising a CTA system into the second reactor zone to produce a second zone reaction product, the CTA system of the second reactor zone having a transfer activity of Z2; and with the proviso that the ratio of Z1:Z2 is greater than 1. The comonomer comprises at least one carboxylic acid group or an anhydride group.Type: GrantFiled: September 21, 2011Date of Patent: October 28, 2014Assignee: Dow Global Technologies LLCInventors: Otto J. Berbee, Roger G. Gagnon, Mark Jasek, Laura Nunez, Bryan Gutermuth
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Patent number: 8759551Abstract: The invention provides a process for continuously producing a urethane (meth)acrylate, containing causing a mixed liquid of a compound (A) having a hydroxyl group and a (meth) acryloyl group and a compound (B) having an isocyanate group to pass continuously and densely through a tubular microchannel formed in a heat-conducting reaction device, and reacting the hydroxyl group of the compound (A) with the isocyanate group of the compound (B).Type: GrantFiled: March 12, 2009Date of Patent: June 24, 2014Assignee: DIC CorporationInventors: Fumihiko Ishiyama, Takeshi Hizawa, Hideki Watanabe
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Patent number: 8722807Abstract: The application relates to a polyethylene composition having a base resin, the base resin comprising (A) a first polyethylene fraction, and (B) a second polyethylene fraction, wherein the melt flow rate MFR5/190° c. of the first fraction is higher than the melt flow rate MFR5/190° c. of the second fraction, the flow rate ratio FRR21/5 of the polyethylene composition, defined as the ratio of melt flow rate MFR21-6/190° c. to melt flow rate MFR5/190° c., is within the range of 15-28, and 10 the melt flow rate MFR5/190° c. of the polyethylene composition is within the range of 0.5-1.1 g/10 min.Type: GrantFiled: November 2, 2005Date of Patent: May 13, 2014Assignee: Borealis Technology OyInventors: Mats Bäckman, James McGoldrick, Bo Hovgard, Siegfried Liedauer, David Walton
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Patent number: 8703879Abstract: A continuous process for the multistage drying and postcondensation of polyamide pellets in the solid phase comprises 1) carrying out the predrying process in a continuous drying apparatus which is operated in countercurrent mode or in crossflow mode with inert gas or steam, or with a mixture of inert gas and steam, using a pellet temperature in the range from 70 to 200° C., and 2) Carrying out the subsequent continuous postcondensation process in a separate vertical duct with moving bed at a pellet temperature in the range from 120 to 210° C., where the duct is operated in countercurrent mode with inert gas or steam, or with a mixture of inert gas and steam, the inert gas is introduced at least two sites along the duct, and from 15 to 90% of the inert gas is introduced at the base of the vertical duct and from 10 to 85% of the inert gas is introduced in the upper half below the surface of the pellets.Type: GrantFiled: June 19, 2009Date of Patent: April 22, 2014Assignee: BASF SEInventors: Wolfgang Loth, Faissal-Ali El-Toufaili, Achim Stammer, Gad Kory, Achim Gerstlauer, Jens Becker
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Patent number: 8697808Abstract: A high-temperature solution process for making an ethylene polymer blend having a controlled degree of long-chain branching is disclosed. Ethylene is polymerized in the presence of a first Ziegler-Natta catalyst comprising titanium, magnesium, and aluminum in the absence of hydrogen to produce a first ethylene polymer component having substantial long-chain branching. A second ethylene polymer component having little or no long-chain branching is also prepared. Both polymerizations are performed at a temperature from 140° C. to 250° C. The first and second ethylene polymer components are combined to give a polymer blend. The degree of long-chain branching in the blend is controlled by adjusting the relative amounts of the first and second ethylene polymer components. The invention enables the preparation of valuable products having a pre-determined degree of long-chain branching using readily available Zeigler-Natta catalysts, commercially practiced techniques, and conventional equipment.Type: GrantFiled: November 8, 2010Date of Patent: April 15, 2014Assignee: Equistar Chemicals, LPInventors: Michael W. Lynch, Kenneth J. Klug
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Patent number: 8691354Abstract: This invention is related to the preparation of polyethylene pipe resins suitable for transporting hot and cold water containing chlorine dioxide.Type: GrantFiled: April 26, 2013Date of Patent: April 8, 2014Assignee: Total Research & Technology FeluyInventors: Pierre Belloir, Christine Bertrand
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Publication number: 20140058039Abstract: A process for preparing a homogeneous polyethylene product can include producing a first polyethylene resin in the presence of a metallocene catalyst in a reactor. The first polyethylene resin can have a density of from 0.940 to 0.970 g/cm3. The first polyethylene resin can have a Low Molecular Weight (LMW) with an MI2 of between 2 and 250 g/10 min. The process can include separately producing a second polyethylene resin in the presence of a Ziegler-Natta catalyst in a reactor. The second polyethylene resin can have a High Molecular Weight (HMW) with an MI2 of between 0.01 and 15 g/10 min. The process can include physically blending together the first polyethylene resin and the second polyethylene resin to produce the homogeneous polyethylene product.Type: ApplicationFiled: March 2, 2012Publication date: February 27, 2014Inventors: Daan Dewachter, Eric Damme
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Publication number: 20140045994Abstract: Reactor grade thermoplastic polyolefins with high flowability and excellent surface quality comprising (A) 40-90 wt % of a propylene homo- or copolymer matrix with an MFR in accordance with ISO 1 133 (230° C., 2.16 kg load) of ?200 g/10 min and (B) 2-30 wt % of an elastomeric ethylene-propylene copolymer having an intrinsic viscosity IV (according to ISO 1628 with decalin as solvent) of ?2.8 dl/g and an ethylene content of >50 to 80 wt % and (C) 8-30 wt % of an elastomeric ethylene-propylene copolymer having an intrinsic viscosity IV (according to ISO 1628 with decalin as solvent) of 3.0-6.Type: ApplicationFiled: October 18, 2013Publication date: February 13, 2014Applicant: Borealis AGInventors: Christelle Grein, Klaus Bernreitner
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Publication number: 20130345360Abstract: A process for preparing a homogeneous polyethylene product can include producing a first polyethylene resin in the presence of a metallocene catalyst in a reactor. The first polyethylene resin can have a density of from 0.942 to 0.970 g/cm3 and an HLMI of from 0.5 to 150 g/10 min. The process can include separately producing a second polyethylene resin in the presence of a chromium catalyst in a reactor. The process can include physically blending together the first polyethylene resin and the second polyethylene resin to produce the homogeneous polyethylene product. The homogeneous polyethylene product can include at least 25% by weight of the first polyethylene resin.Type: ApplicationFiled: March 2, 2012Publication date: December 26, 2013Inventors: Daan Dewachter, Eric Damme
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Patent number: 8575267Abstract: A process for the hydrolysis of polymers comprising vinylcarboxamide units by heating polymers comprising vinylcarboxamide units in an aqueous medium in the presence of acids or bases, wherein an aqueous solution or dispersion of a polymer comprising vinylcarboxamide units and an aqueous solution or a base or acid are fed continuously to a tubular reactor at elevated pressure, from 0.05 to less than one equivalent of a base or acid being used per vinylcarboxamide equivalent and the mixture being passed through the tubular reactor at a temperature of >100° C. to 250° C., depressurized and cooled.Type: GrantFiled: November 2, 2009Date of Patent: November 5, 2013Assignee: BASF SEInventors: Manfred Winter, Hagen Weigl, Hans-Joachim Haehnle, Andreas Kramer
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Publication number: 20130289206Abstract: The invention relates to polymers comprising ester/hydroxyl groups, containing repetitive structural units of formulae (I) and (II) in blocks, alternating, or random sequence wherein D represents a direct bond between the polymer backbone and the hydroxyl group, a C1- to C6-alkylene group, a C5- to C12-arylene group, a oxyalkylene group of formula —O—R2—, an ester group of formula —C(O)—O—R2— or an amide group of formula —C(O)—N(R3)R2—, E represents a hydrocarbon group having 1 to 10 C-atoms, R1 represents hydrogen, a hydrocarbon group having 1 to 50 C-atoms or an acyl group of formula —C(O)—R4, R2 represents a C2- to C10-alkylene group, R3 represents hydrogen or a C1- to C10-alkyl group, which can have substituents, R4 represents a hydrocarbon group having 1 to 50 C-atoms, A represents a C2- to C10-alkylene group, k represents a number between 1 and 100, n represents a number from 0 to 4999, m represents a number from 1 to 5000, n+m for a number from 10 to 5000, under the proviso that a) the molar fraction oType: ApplicationFiled: December 8, 2011Publication date: October 31, 2013Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Matthias Krull, Roman Morschhaeuser, Hans Juergen Scholz, Jochen Stock
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Patent number: 8563109Abstract: A pressureless polymer pipe, a composition therefore, and a process of preparing the composition are described. The pipe is characterized in that the polymer comprises a propylene polymer composition where the propylene base polymer is a heterophasic propylene copolymer having a matrix of a propylene homopolymer and a dispersed phase of an elastomeric copolymer of propylene and at least one olefin comonomer; has a comonomer content of 2-7% by weight, based on the weight of the heterophasic propylene copolymer; has a melt flow rate MFR (2/230), determined according to ISO 1133 C4, of 0.1-2.0 g/10 min; has a broad molecular weight distribution as defined by its rheology shear thinning index, SHI0/50, measured at 200° C. of 9-30; has a tensile modulus, determined according to ISO 527-2/1B at 1 mm/min and 23° C. of at least 1800 MPa; has an impact strength, determined according to ISO 179/1 eA of at least 6 kJ/m2 at 0° C. and at least 2 kJ/m2 at ?20° C. The composition is a polymer composition as defined above.Type: GrantFiled: August 30, 2005Date of Patent: October 22, 2013Assignee: Borealis Technology OyInventors: Carl-Gustaf Ek, Bo Malm, Olli Tuominen
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Patent number: 8557920Abstract: The present invention relates to a polymer composition, comprising (i) a polypropylene homopolymer, (ii) a polypropylene random copolymer, prepared by copolymerization of propylene with an olefin comonomer and having an amount of olefin comonomer units of 0.2 to 5 wt %, and (iii) an elastomeric copolymer of propylene and at least one olefin comonomer, the polymer composition having a tensile modulus, determined according to ISO 527-2/1 B at 1 mm/min. and 230 C, of at least 1200 MPa.Type: GrantFiled: May 11, 2006Date of Patent: October 15, 2013Assignee: Borealis Technology OyInventors: Kauno Alastalo, Carl-Gustaf Ek, Bo Malm, Ulf Torgersen, Olli Tuominen
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Publication number: 20130253089Abstract: The invention relates to a continuous process for the preparation of amphiphilic graft polymers, wherein a vinyl ester component (B) composed of vinyl acetate and/or vinyl propionate (B1) and, if desired, a further ethylenically unsaturated monomer (B2), is polymerized in the presence of a polyalkylene oxide (A), a free radical-forming initiator (C) and, if desired, an additive (D), at a mean polymerization temperature at which the initiator (C) has a decomposition half-time of from 1 to 500 min, in at least one tubular reactor segment with a feed side and an outlet side, through which the reaction mixture comprising at least a part of component (A) to (C), and if desired (D), streams, a tubular reactor segment and the use of the inventive amphiphilic graft polymer. The invention further relates to an inventive amphiphilic graft polymer and the use thereof.Type: ApplicationFiled: March 7, 2013Publication date: September 26, 2013Applicant: BASF SEInventors: Faissal-Ali El-Toufaili, Michaela Heussler, Christian Schwede, Aaron Flores-Figueroa, Rainer Dobrawa, Dieter Boeckh, Wolfgang Loth, Gerd Konrad
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Publication number: 20130203931Abstract: Propylene copolymer composition (P) comprising (a) a propylene copolymer (A) having a comonomer content of at least 1.0 wt.-%, the comomers are C5 to C12 a-olefins, and (b) a propylene copolymer (B) having a comonomer content of 4.0 to 20.0 wt.-%, the comomers are C5 to C12 a-olefins, wherein further (i) the comonomer content in the propylene copolymer (A) is lower compared to the comonomer content in the propylene copolymer (B), (ii) the propylene copolymer composition (P) has a comonomer content of 2.0 to 10.0 wt.-%, the comomers are C5 to C12 a-olefins, (iii) the weight ratio of the propylene copolymer (A) to the propylene copolymer (B) is the range of 30/70 to 80/20.Type: ApplicationFiled: April 18, 2011Publication date: August 8, 2013Applicant: BOREALIS AGInventors: Juha Paavilainen, Petar Doshev, Kristin Reichelt
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Patent number: 8324328Abstract: An apparatus defined as a set of loop reactors suitable for the polymerization process of a monomer, preferably ethylene and optionally an olefin co-monomer, comprising for each of said reactors: a plurality of interconnected pipes P defining a flow path for a polymer slurry, said slurry consisting essentially of ethylene, optionally a co-monomer, a polymerization catalyst, liquid diluent and solid olefin polymer particles, means for feeding monomer, optionally a co-monomer, diluent and optionally hydrogen in the reactor, means for feeding a polymerization catalyst in the reactor, a pump suitable for maintaining the polymer slurry in circulation in such reactor, one or more settling legs connected to the pipes P of such reactor for settling of polymer slurry, one or more control valves connected to the outlet of such settling legs, and one or more flash lines for discharging settled polymer slurry out of the reactor characterized in that each of said loop reactors comprises a three-or-more-way valve definiType: GrantFiled: August 22, 2011Date of Patent: December 4, 2012Assignee: Total Petrochemicals Research FeluyInventors: Louis Fouarge, Carl Van Camp
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Patent number: 8304049Abstract: Polypropylene composition comprising a propylene homopolymer (A) and a random propylene-butene copolymer (B) or a random propylene-ethylene copolymer (B?) wherein the polypropylene composition is ?-nucleated.Type: GrantFiled: June 30, 2008Date of Patent: November 6, 2012Assignee: Borealis Technology OyInventors: Doris Machl, Bo Malm, Franz Ruemer, Klaus Bernreitner
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Patent number: 8148478Abstract: A process for the polymerization of olefins carried out in a gas-phase reactor having interconnected polymerization zones, where the growing polymer particles flow upward through a first polymerization zone (riser) under fast fluidization or transport conditions, leave said riser and enter a second polymerization zone (downcomer) through which they flow downward under the action of gravity, leave said downcomer and are reintroduced into the riser, a gas recycle stream being withdrawn from said first polymerization zone, subjected to cooling below its dew point and then returned to said first polymerization zone, the process being characterized in that said gas recycle stream is cooled at a temperature Tc ranging from 0.05° C. to 3° C. below its dew point.Type: GrantFiled: May 15, 2009Date of Patent: April 3, 2012Assignee: Basell Poliolefine Italia s.r.l.Inventors: Riccardo Rinaldi, Antonio Mazzucco, Enrico Balestra, Giuseppe Penzo, Maurizio Dorini, Gabriele Mei
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Patent number: 8143352Abstract: A process for fluid phase in-line blending of polymers.Type: GrantFiled: December 17, 2007Date of Patent: March 27, 2012Assignee: ExxonMobil Research and Engineering CompanyInventors: Gabor Kiss, Patrick Brant, Robert Patrick Reynolds, Jr., Robert Charles Portnoy, David B. Dunaway
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Publication number: 20120065328Abstract: Hyperbranched polycarbonates having stabilizing groups, prepared by reaction of (a) at least one compound having at least three alcoholic hydroxyl groups per molecule with (b) at least one reagent of the general formula I (c) and at least one reagent of the general formula X3-(A1)m-X4, where the variables are defined as follows: X1, X2 are identical or different and are selected from among halogen, C1-C10-alkoxy, C6-C10-aryloxy and O—C(?O)-halogen, X3 is a functional group selected from among OH, SH, NH2, NH—C1-C4-alkyl, iso-cyanate, epoxy, COOH, COOR12, C(?O)—O—C(?O), C(?O)—Cl, R12 is C1-C4-alkyl or C6-C10-aryl, A1 is a spacer or a single bond, m is zero or one. X4 is a group selected from among phenol groups, benzophenones, aromatic amines and nitrogen-comprising heterocycles, in each case substituted or unsubstituted.Type: ApplicationFiled: September 9, 2011Publication date: March 15, 2012Applicant: BASF SEInventors: Bernd BRUCHMANN, Jens Aßmann, Claudius Schwittay, Harald Schäfer
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Publication number: 20120010362Abstract: The present invention relates to a method for preparing and extruding a bimodal polyethylene product, which comprises a first polyethylene fraction and a second polyethylene fraction having a different molecular weight than the first polyethylene fraction. More specifically, the present invention relates to a method for controlling the specific energy applied on said bimodal polyethylene product by regulating the amount of the polyethylene fraction having the higher molecular weight in said bimodal polyethylene product. According to the present invention regulation of the amount of said polyethylene fraction having the higher molecular weight in said bimodal polyethylene product is obtained by regulating the polymerization conditions for preparing the bimodal polyethylene product, and in particular by adjusting ethylene monomer feed during the polymerization process.Type: ApplicationFiled: March 31, 2010Publication date: January 12, 2012Applicant: TOTAL PETROCHEMICALS RESEARCH FELUYInventor: Mieke Dams
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Publication number: 20110253418Abstract: The present invention relates to a cable comprising a conductor surrounded by one or more layers, wherein at least one layer comprises a polymer composition comprising a copolymer of ethylene with one or more comonomers, to a process for producing the cable and to a polymer composition suitable as a cable layer material.Type: ApplicationFiled: October 12, 2009Publication date: October 20, 2011Applicant: BOREALIS AGInventors: Carl-Gustav Ek, Anneli Pakkanen, Albrecht Dix, Thomas Steffl, Andrey Buryak
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Patent number: 8025847Abstract: Reactor systems suitable for the polymerization of an olefin monomer including first and second loop reactors effective for the polymerization of an olefin monomer and polymers formed therefrom are described herein.Type: GrantFiled: May 11, 2010Date of Patent: September 27, 2011Assignee: Total Petrochemicals Research FeluyInventors: Louis Fouarge, Carl VanCamp
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Publication number: 20110207882Abstract: A process for the hydrolysis of polymers comprising vinylcarboxamide units by heating polymers comprising vinylcarboxamide units in an aqueous medium in the presence of acids or bases, wherein an aqueous solution or dispersion of a polymer comprising vinylcarboxamide units and an aqueous solution or a base or acid are fed continuously to a tubular reactor at elevated pressure, from 0.05 to less than one equivalent of a base or acid being used per vinylcarboxamide equivalent and the mixture being passed through the tubular reactor at a temperature of >100° C. to 250° C., depressurized and cooled.Type: ApplicationFiled: November 2, 2009Publication date: August 25, 2011Applicant: BASF SEInventors: Manfred Winter, Hagen Weigl, Hans-Joachim Haehnle, Andreas Kramer
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Publication number: 20110196093Abstract: A method polymerizes a monomer to form a polyamide having a reagent incorporated therein. In the method, a masterbatch is formed that includes the reagent. The masterbatch and the monomer are introduced into a reactor, and the monomer is polymerized in the presence of the reagent to form the polyamide having the reagent incorporated therein. The monomer may be a caprolactam monomer that may be polymerized in a VK tube reactor to form polyamide 6 having at least one free acid site. The reagent may be present in an amount of from 1 to 10 parts by weight per 100 parts by weight of the masterbatch. Additionally, the masterbatch and caprolactam may be introduced into the top of the VK tube reactor.Type: ApplicationFiled: February 11, 2011Publication date: August 11, 2011Applicant: BASF SEInventors: Cesar G. Ortiz, William E. Grant
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Patent number: 7994264Abstract: Process comprising polymerizing in a loop reactor of a continuous tubular construction an olefin monomer optionally together with an olefin comonomer in the presence of a polymerization catalyst in a diluent to produce a slurry comprising solid particulate olefin polymer and the diluent, wherein the average internal diameter of at least 50% of the total length of the continuous tubular loop reactor is at least 700 mm wherein the HMW polymer is produced in a reactor upstream of the LMW polymer reactor and the ratio of the average internal diameter of the HMW reactor to the average internal diameter of the LMW reactor is between 0.8 and 1.4.Type: GrantFiled: November 20, 2009Date of Patent: August 9, 2011Assignee: Ineos Manufacturing Belgium NVInventors: Stephen Kevin Lee, Daniel Marissal, Brent R. Walworth
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Patent number: 7989551Abstract: A process for the polymerization of one or more addition polymerizable monomers to form a copolymer comprising multiple regions or segments of differentiated polymer composition or properties comprising contacting an addition polymerizable monomer or mixture of monomers under addition polymerization conditions with a composition comprising at least one olefin polymerization catalyst, a cocatalyst and a chain shuttling agent, said process being characterized by formation of at least some of the growing polymer chains under differentiated process conditions such that two or more blocks or segments formed within at least some of the resulting polymer are chemically or physically distinguishable.Type: GrantFiled: January 30, 2006Date of Patent: August 2, 2011Assignee: Dow Global Technologies LLCInventors: Daniel J. Arriola, Edmund M. Carnahan, Marilyn Bokota, Phillip D. Hustad, Roger L. Kuhlman, Timothy T. Wenzel, Pamela J. Stirn
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Patent number: 7985813Abstract: A process comprising polymerising in a loop reactor of a continuous tubular construction an olefin monomer optionally together with an olefin comonomer in the presence of a polymerisation catalyst in a diluent to produce a slurry comprising solid particulate olefin polymer and the diluent wherein the average internal diameter of at least 50% of the total length of the reactor is at least 650 millimeters, the solids concentration in the reactor is at least 15 volume % and having a particle size distribution such that (D90?D10)/D50 is less than 2.Type: GrantFiled: November 20, 2009Date of Patent: July 26, 2011Assignee: Ineos Manufacturing Belgium NVInventors: Stephen Kevin Lee, Daniel Marissal, Brent R. Walworth
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Patent number: 7981983Abstract: A process for controlling a slurry phase (co-) polymerisation process in the presence of a polymerisation catalyst, which comprises maintaining the density SPAN of the polymer powder particles (defined as the absolute value of the density difference in g/cm3 between the average density of the polymer particles exiting the reactor with particle size above D90 and the average density of the material with particle size below D10) below 0.005, preferably below 0.003, more preferably below 0.0026, most preferably below 0.0023.Type: GrantFiled: November 20, 2009Date of Patent: July 19, 2011Assignee: Ineos Manufacturing Belgium NVInventors: Stephen Kevin Lee, Daniel Marissal, Brent R. Walworth
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Publication number: 20110151161Abstract: The present invention relates to a heterophasic polymer composition which comprises (i) a matrix comprising a propylene homopolymer and/or a propylene copolymer having an amount of comonomer units of less than 1.0 wt %, and (ii) an elastomeric polypropylene which is dispersed within the matrix and comprises comonomer units derived from ethylene and/or a C4 to C12 alpha-olefin; and wherein the heterophasic polymer composition has an amorphous fraction AM in an amount of 2.0 to 7.5 wt %, and the amorphous fraction AM has an amount of ethylene- and/or C4 to C12 alpha-olefin-derived comonomer units of 20 to 45 wt %.Type: ApplicationFiled: July 7, 2009Publication date: June 23, 2011Applicant: Borealis AGInventors: Bo Malm, Franz Ruemer, Andreas Wolf, Tua Sundholm
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Publication number: 20110123745Abstract: A pressureless polymer pipe, a composition therefore, and a process of preparing the composition are described. The pipe is characterised in that the polymer comprises a propylene polymer composition where the propylene base polymer is a heterophasic propylene copolymer having a matrix of a propylene homopolymer and a dispersed phase of an elastomeric copolymer of propylene and at least one olefin comonomer; has a comonomer content of 2-7% by weight, based on the weight of the heterophasic propylene copolymer; has a melt flow rate MFR (2/230), determined according to ISO 1133 C4, of 0.1-2.0 g/10 min; has a broad molecular weight distribution as defined by its rheology shear thinning index, SHI0/50, measured at 200° C. of 9-30; has a tensile modulus, determined according to ISO 527-2/1B at 1 mm/min and 23° C. of at least 1800 MPa; has an impact strength, determined according to ISO 179/1 eA of at least 6 kJ/m2 at 0° C. and at least 2 kJ/m2 at ?20° C. The composition is a polymer composition as defined above.Type: ApplicationFiled: August 30, 2005Publication date: May 26, 2011Applicant: Borealis Technology OyInventors: Carl-Gustaf Ek, Bo Malm, Olli Tuominen
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Patent number: 7943699Abstract: Disclosed are films, tapes, and melt-spun fibers prepared from a composition comprising (a) at least one polyester polymer and (b) from about 1 to 30 weight % of at least one ethylene copolymer such as ethylene/vinyl acetate dipolymers, ethylene/vinyl acetate terpolymers, ethylene/alkyl (meth)acrylate dipolymers, ethylene/alkyl (meth)acrylate terpolymers, functionalized ethylene copolymers, ethylene/acid copolymers, and salts thereof. The films, tapes and fibers exhibit improved tensile properties such as tensile strength and elongation at break compared to non-modified polyester compositions. Also disclosed are textiles and articles prepared from the fibers described.Type: GrantFiled: October 20, 2004Date of Patent: May 17, 2011Assignee: E. I. du Pont de Nemours and CompanyInventors: Loic Pierre Rolland, Sam Louis Samuels
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Publication number: 20110086970Abstract: Reactor grade thermoplastic polyolefins with high flowability and excellent surface quality comprising (A) 40-90 wt % of a propylene homo- or copolymer matrix with an MFR in accordance with ISO 1 133 (230° C., 2.16 kg load) of >200 g/10 min and (B) 2-30 wt % of an elastomeric ethylene-propylene copolymer having an intrinsic viscosity IV (according to ISO 1628 with decalin as solvent) of ?2.8 dl/g and an ethylene content of >50 to 80 wt % and (C) 8-30 wt % of an elastomeric ethylene-propylene copolymer having an intrinsic viscosity IV (according to ISO 1628 with decalin as solvent) of 3.0-6.Type: ApplicationFiled: June 12, 2009Publication date: April 14, 2011Applicant: Borealis AGInventors: Christelle Grein, Klaus Bernreitner
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Publication number: 20110077353Abstract: A reactor system operable to facilitate a chemical reaction in a reaction medium flowing therethrough. The reactor system includes a heat exchanger for heating the reaction medium and a disengagement vessel for disengaging vapor from the heated reaction medium.Type: ApplicationFiled: December 9, 2010Publication date: March 31, 2011Applicant: EASTMAN CHEMICAL COMPANYInventors: Bruce Roger DeBruin, Thomas Lloyd Yount, Larry Cates Windes, Wesley Thomas Moyer
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Patent number: 7906581Abstract: Methods, apparatuses, and systems for manufacturing a hot melt adhesive containing an adhesion promoter in a continuous mode include supplying a melted, hot melt adhesive to a mixing device at a first predetermined rate while simultaneously supplying an adhesion promoter to the same mixing device at a second predetermined rate to form a homogeneous admixture containing the hot melt adhesive and adhesion promoter. The hot melt adhesive/adhesion promoter mixture is subsequently reacted in at least one tubular reactor at a predetermined temperature for a predetermined residence time to allow the adhesion promoter to chemically bond with the hot melt adhesive and form an adhesive-promoter-treated hot melt adhesive. The adhesion-promoter-treated hot melt adhesive is collected in a product receiver and may be further processed.Type: GrantFiled: September 5, 2007Date of Patent: March 15, 2011Assignee: Xerox CorporationInventors: Frank Ping-Hay Lee, Tie Hwee Ng, Sheau Van Kao, Guiqin Song