Mixture Contains Solid Polymer Derived From Reactants Containing An Atom Other Than C, H, O, N, Or Chlorine Patents (Class 525/72)
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Patent number: 6150462Abstract: Golf ball compositions, which contain olefinic polymers produced by use of single-site catalysts. Such polymers can be functionalized with a post-polymerization reaction. The single-site catalyzed polymers may be blended with ionomers, other grafted or non-grafted single-site catalyzed polymers, thermoplastics, non-single-site polymers, or other non-ionomeric polymers. The compositions can be foamed or unfoamed. Golf balls that employ at least one layer of these compositions in any of the golf ball cover, core, or a mantle situated between the cover and the core provide ball properties and performance similar to and in some cases better than the state of the art ionomer based golf balls.Type: GrantFiled: December 21, 1998Date of Patent: November 21, 2000Assignee: Acushnet CompanyInventors: Murali Rajagopalan, Kevin M. Harris
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Patent number: 6121374Abstract: The invention relates to a thermoplastic composition comprising at least one polymer (M) forming a matrix in which are dispersed at least one polymer (S) and at least one polymer (K) and such that its tensile strength is greater than that of a composition comprising only (M) and (S), the proportion by weight of (M) being the same.Type: GrantFiled: May 27, 1998Date of Patent: September 19, 2000Assignee: Elf Atochem SAInventors: Thibaut Montanari, Chrystelle Guibouin, Marius Hert, Patrice Perret, Jacques Thomasset, Didier Roumilhac
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Patent number: 6096827Abstract: The present invention relates to a fluorine-containing graft copolymer and its manufacturing method. In particular, the fluorine-containing graft copolymer synthesized by copolymerization of copolymerizable perfluoroalkyl compound as a main chain and macromonomer having copolymerizable vinyl group at one end as branched chains, respectively. Thus the graft copolymer has the remarkable affinity to the substrates designed for the surface modification and superior performance than random copolymers, when it is employed as various types of surface modifiers of fluorine-containing compounds (e.g., water and oil repellent, soil release agents, mold-releasing agents, etc.).Type: GrantFiled: October 8, 1998Date of Patent: August 1, 2000Assignee: Korea Research Institute of Chemica TechnologyInventors: Soo Bok Lee, Dong Kwon Kim, Kwang Won Lee, Kwang Je Kim, In Jun Park
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Patent number: 6025436Abstract: The invention provides a thermoplastic fluorine-containing resin composition intended to be passed between at least two rollers of a calender to be thinned into a sheet or film. This composition includes: 100 parts by weight of a mixture containing 10-90 wt % of a fluorine-containing elastomeric polymer having a glass transition temperature below room temperature and 90-10 wt % of a fluorine-containing crystalline resin having a melting point not higher than 300.degree. C.; and 0.05-2.0 parts by weight of an agent for releasing the composition from the at least two rollers. The composition has a good melt characteristic and a good elasticity for calendering of the composition, and a good releasibility from a calender roller in calendering of the composition.Type: GrantFiled: May 23, 1997Date of Patent: February 15, 2000Assignee: Central Glass Company, LimitedInventors: Chikashi Kawashima, Katunori Kawamura, Seiiti Minegishi
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Patent number: 6013726Abstract: A polystyrene-based resin composition containing a styrene-based resin with mainly syndiotactic configuration, a polyamide, and a rubber polymer as main components.Type: GrantFiled: June 5, 1995Date of Patent: January 11, 2000Assignee: Idemitsu Kosan Co., Ltd.Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
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Patent number: 6013727Abstract: A thermoplastic composition which may be unvulcanized or vulcanized is provided which comprises a polymer blend of an elastomeric thermoplastic engineering resin and a halogen-containing copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a para-alkylstyrene. A process for preparing a dynamically vulcanized composition is also provided.Type: GrantFiled: January 31, 1991Date of Patent: January 11, 2000Assignee: Exxon Chemical Patents, Inc.Inventors: Narayanaswami Raja Dharmarajan, Robert Chester Puydak, Hsien Chang Wang, Kenneth William Powers, Thomas Chen-Chi Yu, Donald Ross Hazelton
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Patent number: 6011088Abstract: Novel organic silicon compounds of formula (1) are provided. ##STR1## R.sup.1 is a monovalent C.sub.1 -C.sub.4 hydrocarbon group, R.sup.2 is a divalent C.sub.2 -C.sub.3 hydrocarbon group, R.sup.3 is a monovalent C.sub.1 -C.sub.2 hydrocarbon group, m is an integer of 3-10, n is equal to 0, 1 or 2, p is equal to 0 or 1, and the sum of n+p is equal to 0, 1 or 2. Inorganic fillers are surface treated with the organic silicon compounds. Compositions comprising EPR and/or EPDM in admixture with the treated inorganic fillers are electrically insulating and have improved oil resistance and mechanical strength.Type: GrantFiled: February 3, 1998Date of Patent: January 4, 2000Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Hideyoshi Yanagisawa, Shoji Ichinohe
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Patent number: 6008297Abstract: A polyamide resin composition superior in the shock resitance, especially low temperature shock resistence, in the rigidity and in the water absorption resistance, which comprises(A) 98-50 % by weight of a polyamide,(B) 1-40 % by weight of a modified ethylene/.alpha.-olefin copolymer having an MFR (190.degree. C.) of 0.05-50 g/10 min., obtained by a graft-copolymerization of 100 parts by weight of an ethylene/.alpha.-olefin copolymer (B-1) having an ethylene content of 40-93 mole % and a density of lower than 0.900 g/cm.sup.3, with, grafted thereon, 0.01-5 parts by weight of an unsaturated dicarboxylic acid or its derivative (B-2), and(C) 1-40 % by weight of at least one ethylenic copolymer selected from the group consisting of an ethylene/.alpha.-olefin copolymer (C-1) having an .alpha.-olefin content of 10 mole % or less, an Mw/Mn of 2.5 or lower and an MFR (190.degree. C.) of 0.05-50 g/10 min. and a modified ethylen/.alpha.Type: GrantFiled: May 15, 1998Date of Patent: December 28, 1999Assignee: Mitsui Chemicals, Inc.Inventors: Yasuo Tanaka, Youji Hayakawa
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Patent number: 5997855Abstract: A multicomponent homogeneous polymer of (a) from about 30 to about 90 wt. % of a N-vinyl lactam, (b) from about 5 to about 30 wt. % of a quaternized and/or non-quaternized aminoalkylacrylic -ester and/or -amide, (c) from about 0.5 to about 30 wt. % of an unsaturated monomer selected from the group consisting of an acrylic ester or amide having a C.sub.4 to C.sub.22 alkyl group, a C.sub.4 to C.sub.22 .alpha.-olefin, a C.sub.4 to C.sub.22 vinyl ether (VE) and a vinyl ester of a C.sub.2 to C.sub.22 carboxylic acid and (d) from about 1 to about 30 wt. % of an unsubstituted acrylic or methacrylic acid and/or an unsubstituted amide of said acrylic or methacrylic acid and optionally, (e) up to 20 wt.Type: GrantFiled: January 28, 1998Date of Patent: December 7, 1999Assignee: ISP Investments Inc.Inventor: Kou-Chang Liu
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Patent number: 5985998Abstract: A novel class of interpenetrating polymer networks which are dispersible in conventional coating solvents is disclosed. Such dispersions are useful in preparing protective and/or decorative film coatings and are particularly useful in photosensitive or imaging formulations such as photoresists, solder masks and the like. These polymer networks are comprised of at least two interpenetrating crosslinked polymers. At least one of the polymer networks is formed by polymerization in a solvent. In one embodiment of this invention, at least one polymer network is prepared from macromers to produce a polymer system having functionalized branch or graft linear segments. The solvent dispersible interpenetrating networks of this invention are particularly useful as binders in addition polymerizable photosensitive compositions containing crosslinking monomers such as solder masks. Upon exposure to actinic radiation and suitable thermal curing, solder mask coatings of such photosensitive compositions form multiple, e.g.Type: GrantFiled: February 11, 1999Date of Patent: November 16, 1999Assignee: E. I. du Pont de Nemours and CompanyInventors: Eugene G. Sommerfeld, Frank Schadt, III
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Patent number: 5981658Abstract: The disclosed invention provides novel golf ball compositions which contain non-ionic olefinic copolymers produced by use of metallocene catalysts, wherein the metallocene catalyzed polymers have been functionalized with a post-polymerization reaction. The grafted metallocene catalyzed polymers may be blended with ionomers, non-grafted metallocene catalyzed polymers, or other non-ionomeric polymers. These compositions exhibit improved mechanical properties such as tensile and flexural properties, and can be foamed or unfoamed. Golf balls that employ at least one layer of these compositions in any of the golf ball cover, core, or a mantle situated between the cover and the core provide ball properties and performance similar to and in some cases better than the state of the art ionomer based golf balls.Type: GrantFiled: October 14, 1997Date of Patent: November 9, 1999Assignee: Acushnet CompanyInventors: Murali Rajagopalan, Kevin M. Harris
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Patent number: 5962587Abstract: A thermoplastic resin composition includes a rubber modified thermoplastic resin and from 2 parts by weight to 20 parts by weight of a fluoropolymer, based on 100 parts by weight of the resin composition, imparts a high tensile modulus, ductility and a low friction surface to articles molded therefrom.Type: GrantFiled: October 23, 1997Date of Patent: October 5, 1999Assignee: General Electric CompanyInventors: Satish Kumar Gaggar, Marshall Dewey Moore
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Patent number: 5952426Abstract: A method for preparing molded articles of a crosslinked polyolefin is here disclosed which comprises the steps of mixing polyolefin granules comprising polyolefin granules containing a hydrosilylation catalyst, polyolefin granules containing the copolymer of an alkenylsilane and an olefin, and if necessary, polyolefin granules containing neither the hydrosilylation catalyst nor the copolymer of the alkenylsilane and the olefin, and then heating, melting and molding the mixture in a molding machine.According to the present invention, the molded articles of the crosslinked polyolefin containing no residual crosslinking agent and having improved heat resistance and mechanical strength can be obtained by the easy method which comprises mixing the above-mentioned respective granules, and then heating, melting and molding the mixture.Type: GrantFiled: June 11, 1993Date of Patent: September 14, 1999Assignee: Mitsui Chemicals, Inc.Inventors: Tadashi Asanuma, Kazuhiko Yamamoto, Kaoru Kawanishi
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Patent number: 5919862Abstract: A golf ball and a method of making a golf ball, having a cover and a core, wherein the golf ball has at least one layer formed of a compatibilized blend of about 4 percent to 95 percent of at least one ionomer resin; about 95 percent to 4 percent of at least one non-ionic polymer; and about 1 to 15 phr, based on 100 parts ionomer resin and non-ionic polymer, of at least one compatibilizer of a functionalized block and graft polymers and oligomers, wherein the compatibilizer is free of any monomers containing an .alpha.,.beta.-ethylenically unsaturated carboxylic acid, and wherein at least one portion of the non-carboxylic acid compatibilizer is miscible with the at least one ionomer and at least one portion of the non-carboxylic acid compatibilizer is miscible with the at least one non-ionic polymer.Type: GrantFiled: January 21, 1997Date of Patent: July 6, 1999Assignee: Acushnet CompanyInventor: Murali Rajagopalan
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Patent number: 5902859Abstract: The invention relates to an elastic fluorohydrocarbon resin. This resin is obtained by graft copolymerization of a first segment which is one of fluorine-containing elastomeric and crystalline polymers with a second segment which is the other of these polymers. The first segment is prepared by copolymerizing at least one first unsaturated monomer that has peroxy bond with at least one second fluorine-containing monomer. When the first monomer is dissolved in a first solvent prior to the copolymerization, the copolymerization can be safely conducted with higher yield. This first solvent is selected from a carboxylic ester of t-butanol, methylene chloride, 1,1,1-trichloroethane, and first, second, third and fourth compounds which are respectively represented by R.sup.1 COOR.sup.2, C.sub.2 H.sub.x Cl.sub.y F.sub.z, C.sub.3 H.sub.x Cl.sub.y F.sub.z, and C.sub.4 H.sub.x Cl.sub.y F.sub.z.Type: GrantFiled: June 23, 1997Date of Patent: May 11, 1999Assignee: Central Glass Company, LimitedInventors: Chikashi Kawashima, Akira Ishihara, Katunori Kawamura, Seiiti Minegishi
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Patent number: 5898051Abstract: The invention provides a fluorine-containing resin blend. This resin blend includes 100 parts by weight of a first resin and 1-50 parts by weight of a second resin. The first resin is one of an elastic fluorohydrocarbon resin and a vinylidene fluoride based resin. The second resin is a graft copolymer prepared by graft copolymerization of a rubber-like polymer with a first monomer and an optional second monomer. The first monomer is at least one of an acrylic ester and a methacrylic acid ester. The optional second monomer is at least one copolymerizable monomer other than the first monomer. When the elastic fluorohydrocarbon resin is used as the first resin, the resin blend is improved in extensibility upon molding in a melted condition and lowered in modulus of elasticity under a condition that the resin blend is strained by up to 20%, without impairing the elastic fluorohydrocarbon in its heat resistance, low-temperature characteristics and the like.Type: GrantFiled: January 31, 1996Date of Patent: April 27, 1999Assignee: Central Glass Company, LimitedInventors: Chikashi Kawashima, Fumiyoshi Yoshikawa, Seiiti Minegishi
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Patent number: 5863657Abstract: An adhesive for bonding together a first substrate made of vinylidene fluoride resin and a second substrate comprises an elastic fluorohydrocarbon resin, a polyisocyanate, and an organic solvent. This elastic fluorohydrocarbon resin is obtained by graft copolymerization of a fluorine-containing copolymer with a vinylidene fluoride monomer. This copolymer is prepared by copolymerizing at least one first fluorine-containing monomer with at least one unsaturated monomer that has peroxy bond. The adhesive itself is superior in durability, and bond strength between the first and second substrates is also superior.Type: GrantFiled: December 27, 1995Date of Patent: January 26, 1999Assignee: Central Glass Company, LimitedInventors: Chikashi Kawashima, Katunori Kawamura
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Patent number: 5852116Abstract: Crosslinkable polyolefin compositions, articles prepared from such compositions, and processes for making such compositions are described that possess both good processability and fast cure rates. The crosslinkable polyolefin compositions are bidisperse blends of ethylene polymers of the same polymer family having differing number average molecular weights as obtained by deconvolution in which M.sub.n1 /M.sub.n2 >7, M.sub.n2 >3000 and 0.7.gtoreq.(A.sub.1 /(A.sub.1 +A.sub.2)).gtoreq.0.15 wherein M.sub.n1 represents the number average molecular weight of the first deconvoluted component, M.sub.n2 represents the number average molecular weight of the second deconvoluted component, and A.sub.1 and A.sub.2 are the relative proportions of the first and second components.Type: GrantFiled: August 26, 1996Date of Patent: December 22, 1998Assignee: The Dow Chemical CompanyInventors: Stephen H. Cree, John Penfold, Line F. Fanichet, Craig A. Wilson
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Patent number: 5852115Abstract: A polymeric blend formed from recycled carpet scrap and selected compatibilizing agents and/or a poly(ethylene-co-omylacetate) and the products produced from such blend.Type: GrantFiled: July 14, 1995Date of Patent: December 22, 1998Assignee: Lear CorporationInventors: Dennis C. Young, Stanley J. Chlystek, Robert Malloy, Ivan Rios
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Patent number: 5840802Abstract: Low temperature ductile and impact resistant compositions are provided which comprise a polycarbonate resin and a dual graft multi-stage polyorganosiloxane/polyvinyl-based graft polymer composition. Also provided are thermally stabilized multi-stage polyorganosiloxane/polyvinyl-based graft polymers which have improved color-imparting and impact resistance-imparting properties and thermoplastic compositions containing the same.Type: GrantFiled: October 11, 1991Date of Patent: November 24, 1998Assignee: General Electric CompanyInventors: James Louis DeRudder, I-Chung Wayne Wang
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Patent number: 5837773Abstract: A blend and a process for producing that blend in which a high ethylene content ethylene-propylene polymer and a lower ethylene content ethylene-propylene polymer are subjected to simultaneous blending and shearing to reduce their molecular weights and molecular weight distribution. The sheared blend of polymers can function as a shear stable dispersant viscosity index improver with improved lower temperature properties or the hydrocarbon base for multifunctional for viscosity index improvers, motor fuel additives or polymeric dispersants.Type: GrantFiled: March 12, 1997Date of Patent: November 17, 1998Assignee: DSM Copolymer, Inc.Inventors: Errol J. Olivier, Robert T. Patterson, Peter N. Nugara
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Patent number: 5824740Abstract: Disclosed is a golf ball having good shot feel and controllability as well as satisfactory flight performance and cut resistance. The golf ball has a core and a cover for covering the core, wherein said cover has a stiffness modulus of 100 to 250 MPa and comprises a heated mixture of an ionomer resin and a glycidyl group-modified styrene-based block copolymer having a JIS-A hardness of 30 to 90 as base resin, and optionally a maleic anhydride-modified olefin copolymer.Type: GrantFiled: December 28, 1995Date of Patent: October 20, 1998Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Yoshikazu Yabuki, Yoshinori Sano, Hiroaki Tanaka
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Patent number: 5811479Abstract: The present invention relates to a sulfur-vulcanizable rubber composition mprising, by way of reinforcing filler, carbon black or a mixture of carbon black and silica, at least one functionalized diene polymer bearing at the chain end a silanol function or a polysiloxane block having a silanol end, or modified along the chain by silanol functions and at least one organosilane compound comprising an amine or imine function, which can be used for the manufacture of tires having, in particular, improved hysteresis properties.Type: GrantFiled: January 23, 1997Date of Patent: September 22, 1998Assignee: Compagnie Generale des Etablissements Micheline - Michelin & CieInventor: Gerard Labauze
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Patent number: 5804654Abstract: A tetrafluoroethylene-containing powder contains free flowing particles of a tetrafluoroethylene polymer at least partially encapsulated by a polymer or copolymer selected from polystyrene, poly-.alpha.-alkylstyrenes, styrene-acrylonitrile copolymers, .alpha.-alkylstyrene-acrylonitrile copolymers, acrylonitrile-butadiene-styrene copolymers, styrene-butadiene rubbers and their mixtures. The powder is obtained by emulsion polymerization of one or more monomers in the presence of a tetrafluoroethylene polymer and is useful as an additive in polymer compositions and in making molded articles.Type: GrantFiled: October 6, 1995Date of Patent: September 8, 1998Assignee: General Electric CompanyInventors: Fai Lo, Fran.cedilla.ois Serge Mazeres, Ronald van der Wal
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Patent number: 5795654Abstract: The invention provides an adhesive for bonding together a first substrate made of a polyvinylidene fluoride resin and a second substrate. This adhesive includes an elastic fluorohydrocarbon resin, an acrylic resin, a polyvinylidene fluoride resin, a polyisocyanate, and an organic solvent. This elastic fluorohydrocarbon resin is obtained by graft copolymerization of a fluorine-containing copolymer with a vinylidene fluoride monomer. This copolymer is prepared by copolymerizing at least one first fluorine-containing monomer with at least one unsaturated monomer that has peroxy bond. The adhesive itself is superior in durability, and bond strength between the first and second substrates is also superior.Type: GrantFiled: December 4, 1996Date of Patent: August 18, 1998Assignee: Central Glass Company, Ltd.Inventors: Toshio Koishi, Katsunori Kawamura, Seiiti Minegishi
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Patent number: 5773145Abstract: A power cable is disclosed, which comprises a conductor having thereon an insulating layer which comprises a composition comprising from 25 to 35% by weight based on the total amount of the composition of an ethylene-vinyl acetate copolymer resin having a vinyl acetate content of from 25 to 33% by weight, and from 65 to 75% by weight based on the total amount of the composition of polyethylene, the polyethylene containing in the molecule thereof vinyltrimethoxysilane by copolymerization or graft polymerization, the composition containing an organo heavy metal compound as a cross-linking catalyst, the insulating layer is cross-linked by the cross-linking reaction of trimethoxysilane groups in the polyethylene in the presence of water.Type: GrantFiled: September 22, 1997Date of Patent: June 30, 1998Assignee: Sumitomo Electric Industries, Ltd.Inventors: Yoshiyuki Inoue, Mineya Kuno, Takeshi Fukui, Shigeki Ohsawa
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Patent number: 5741854Abstract: A thermoplastic resin composition is provided exhibiting enhanced levels of dart impact strength. The composition contains a vinyl aromatic resin, an increased tetrafluoroethylene polymer and a reduced level of metal salt of a fatty acid. The tetrafluoroethylene polymer is introduced into the composition in the form of a preblend of tetrafluoroethylene polymeric powder and a carrier material. The compositions are useful for making molded articles such as business machine housings. A method for making the composition is also provided.Type: GrantFiled: July 31, 1996Date of Patent: April 21, 1998Assignee: General Electric CompanyInventor: Jianing Huang
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Patent number: 5733974Abstract: The present invention provides a golf ball which exhibits a soft hit feeling and a high impact resilience. The golf ball comprises a core made of an elastomer and a cover covering said core wherein said cover is made of a thermoplastic material comprising a rubber powder and a thermoplastic elastomer, said rubber powder being present in an amount of 5 to 40 parts by weight based on 100 parts by weight of said thermoplastic elastomer.Type: GrantFiled: August 18, 1995Date of Patent: March 31, 1998Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Mikio Yamada, Keiji Moriyama
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Patent number: 5731371Abstract: The invention provides golf balls formed from the reaction product of compositions comprising an ester grafted hydrogenated nitrile butadiene rubber such as zinc dimethacrylate grafted hydrogenated nitrile butadiene rubber elastomer. The compositions may further include polybutadiene rubber. Balls made of these compositions are especially suited for use in restricted land spaces such as driving ranges.Type: GrantFiled: December 18, 1995Date of Patent: March 24, 1998Assignee: Lisco, Inc.Inventors: Robert Dennis Nesbitt, Michael J. Sullivan
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Patent number: 5723526Abstract: A resin composition consisting essentially of (a) an aromatic polycarbonate resin, (b) a thermoplastic graft copolymer obtained by grafting a diene rubber component with a vinyl cyanide compound and an aromatic vinyl compound, (c) a phosphoric acid ester, (d) a polytetrafluoroethylene, (e) a talc, and (f) a composite rubber having a network structure in which a polyorganosiloxane rubber component and a polyalkyl (meth)acrylate rubber component interpenetrate each other, each in a specified amount. This resin composition has excellent fluidity and allows easy mold- processing. The molded article made therefrom is excellent in flame retardancy, stiffness, heat-resistance, impact strength and appearance.Type: GrantFiled: April 1, 1996Date of Patent: March 3, 1998Assignee: Teijin Chemicals LtdInventor: Masashi Nagasawa
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Patent number: 5712340Abstract: The present invention relates to an aqueous dispersion of a polymer composition comprising (A) a copolymer which comprises (a.sub.1) a unit derived from a vinyl monomer having a hydrolyzable silyl group and (a.sub.2) a unit derived from another vinyl monomer copolymerizable with (a.sub.1), and (B) a water-soluble polymer having an amineimide group. The aqueous dispersion of the present invention has good polymerization stability, mechanical stability and storage stability, and is useful in various applications such as coating materials, paints, adhesives, primers and binders.Type: GrantFiled: February 26, 1996Date of Patent: January 27, 1998Assignee: Sanyo Chemical Industries, Ltd.Inventors: Hiroaki Gyotoku, Satoshi Kuriyama, Kaoru Murata, Tatsuya Ohsumi
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Patent number: 5705553Abstract: Copolymers containing carboxyl groups in aqueous dispersion form or redispersible powder form and their water-soluble salts, based on ethylenically unsaturated and copolymerizable monomers, the macro-molecules of which contain at least 24% by weight of monomer units carrying carboxyl groups prepared, by emulsion copolymerization initiated by free radicals in the presence of polyvinyl alcohol (PVA) or polyvinylpyrrolidone (PVP) dissolved in the aqueous phase and isolation of the copolymers in aqueous dispersion form, and optionally subsequent removal of water by spray drying to obtain redispersible copolymer powders and processes for their preparation and their use as thickeners in aqueous formulations which copolymers, by conversion into their water-soluble salt forms, are useful as thickening agents having a surprisingly advantageous rheology-modifying action in aqueous systems.Type: GrantFiled: November 13, 1995Date of Patent: January 6, 1998Assignee: Hoechst AktiengesellschaftInventor: Rolf Kuropka
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Patent number: 5681875Abstract: A process is provided for making a flame composition. The process involves (a) mechanically dry blending (i) a tetrafluoroethylene polymer, preferably in powder form, and (ii) a first thermoplastic resin, preferably a vinyl aromatic resin to form a preblend composition and (b) admixing the preblend composition with a thermoplastic resin and a flame retardant to form the thermoplastic resin. The process provides enhanced levels of falling dart impact strength in articles molded from the thermoplastic composition.Type: GrantFiled: January 22, 1996Date of Patent: October 28, 1997Assignee: General Electric CompanyInventors: Jianing Huang, Fuh-Sheng Fred Chen, Jacobus Johannes Maria Brasser
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Patent number: 5681889Abstract: The present invention provides hydrophilic crosslinked polymer fine particles made of a copolymer composed of:2-50% by weight of (a) a monoethylenic monomer having a polyoxyalkylene or polyvinylpyrrolidone chain,20-97% by weight of (b) a (meth)acrylamide type monoethylenic monomer,1-30% by weight of (c) a crosslinkable unsaturated monomer selected from the group consisting of compounds having, in the molecule, at least two polymerizable double bonds, and compounds having, in the molecule, at least one functional group selected from hydrolyzable silyl groups and 1,2-epoxy groups and one polymerizable double bond, and0-50% by weight of (d) other monoethylenic monomer. Said polymer fine particles are superior in polymerization stability as well as in dispersion stability during storage, undergoes no adverse effect by dispersion stabilizer owing to no use of said stabilizer, and are suitably used for formation of a hydrophilic film.Type: GrantFiled: December 15, 1995Date of Patent: October 28, 1997Assignee: Kansai Paint Co., LtdInventors: Masahiro Kondo, Hiroshi Inoue
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Patent number: 5679741Abstract: Use of a polymer blend based on a polymerizate of groups of tetrafluoroethylene derivatives as a processing aid for polyvinyl chloride resins, chlorinated polyvinyl chloride resins, polyolefins and styrene-based resins.Use of a polymer blend as a processing aid for polyvinyl chloride resins, chlorinated polyvinyl chloride resins, polyolefins and styrene-based resins and their mixtures, the polymer blend comprising particles of tetrafluoroethylene polymerizate, these particles being totally or partially encapsulated by a styrene-acrylonitrile copolymer, the amount of the said blend used being such that the tetrafluoroethylane polymerizate represents between 0.05 parts by weight and 20 parts by weight per 100 parts by weight of resins and/or polymers processed.Type: GrantFiled: October 12, 1995Date of Patent: October 21, 1997Assignee: General Electric CompanyInventors: Fran.cedilla.ois Jean-Marie Breton, Yves Lecomte
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Patent number: 5641834Abstract: A composition that includes an olefinic-terminated polyalkadiene that includes carboxy ester linking groups and at least one nascent secondary hydroxyl group that is capped with a monoisocyanate. The composition also includes a free radical-polymerizable monomer such as an olefinic monomer and, optionally, a second polymeric material. In a preferred embodiment the composition is an adhesive that also includes a phosphorus-containing compound and an ambient temperature-active redox catalyst system.Type: GrantFiled: December 11, 1995Date of Patent: June 24, 1997Assignee: Lord CorporationInventors: Kirk Joseph Abbey, Ian Christopher Quarmby
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Patent number: 5639525Abstract: The invention relates to a polymer compound for the production of sealing elements for vessel or container closures, which sealing elements when closed have a barrier effect preventing the penetration of gaseous or vaporous substances such as oxygen or aromatic compounds, in particular benzenes, phenyl ethers and suchlike into the vessel and/or show an excess pressure valve effect at interior vessel pressures of between approx. 3 and 10 bar and may be produced by mechanical forming of the unshaped thermally plastified polymer compound and its subsequent hardening directly on or in the vessel closure ("in shell" moulding), comprising a mixture of butyl and/or acrylate rubber and a polymer of an .alpha.-oleflnic unsaturated monomer as well as, if appropriate, one or several further polymer components and common additives such as glide enhancers, pigment, talcum and stabilizers. The invention further relates to a sealing element of this kind and a corresponding vessel or container closure.Type: GrantFiled: March 11, 1992Date of Patent: June 17, 1997Assignee: DS-Chemie GmbHInventors: Tino Kuhn, Georg Schlenk
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Patent number: 5633321Abstract: Method for producing a compatabilized rubber composition comprising blending a hydroxy alkylamine or a hydroxy alkylthioether functionalized polymer of a C.sub.4 -C.sub.7 isoolein and para-alkylstyrene with a dissimilar polymer.Type: GrantFiled: March 28, 1995Date of Patent: May 27, 1997Assignee: Exxon Chemical Patents Inc.Inventor: Palanisamy Arjunan
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Patent number: 5633318Abstract: A polystyrene based composition is provided having high impact strength and gloss. The gloss is particularly noted when the resin is molded into plastic articles, especially at relatively cooler temperatures, such as 80.degree. F. to 100.degree. F. The composition contains three resins. The first resin comprises polystyrene and rubber particles smaller than 1.0 micron, such as 0.2 to 0.6 microns. The second resin comprises polystyrene and rubber particles larger than 1.0 micron. The third resin preferably is a block copolymer of styrene and butadiene. Unexpectedly, the third resin improves the gloss achieved by the overall composition.Type: GrantFiled: October 8, 1996Date of Patent: May 27, 1997Assignee: Chevron Chemical CompanyInventor: Kenneth E. Bowen
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Patent number: 5625001Abstract: Acrylic impact modifiers for polar thermoplastics such as poly(methyl methacrylate), polyamides, and poly(vinyl chloride) are prepared from emulsion polymer particles with hard methacrylate-rich domains in a continuous polyacrylate network.Type: GrantFiled: June 9, 1995Date of Patent: April 29, 1997Assignee: Rohm and Haas CompanyInventors: Samuel J. Makower, Richard M. Kopchik, Wen-Long Liu, Alan D. Stein
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Patent number: 5589540Abstract: Three new types of chelating resins containing nitrogen and sulfur or oxygen atoms as coordination atom were synthesized by the reaction of a polymer bearing amino (--NH.sub.2) or imino (.dbd.NH) groups as reaction sites with a substitutive derivative of epithiopropane or epoxypropane. These resins exhibited excellent adsorption properties for noble metals.Type: GrantFiled: January 30, 1995Date of Patent: December 31, 1996Inventor: Dong Shihua
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Patent number: 5583180Abstract: Compositions of stabilized stereoregular polymers of branched higher alpha-olefins, grafting compounds, free radical generators, glass and epoxy resins and/or epoxy-functional silanes and/or hydroxy functional compounds are provided as well as methods for making these compounds and articles thereof.Type: GrantFiled: March 8, 1995Date of Patent: December 10, 1996Assignee: Phillips Petroleum CompanyInventors: Edwin Boudreaux, Jr., Howard F. Efner, Mary J. Hagenson
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Patent number: 5574100Abstract: A polymer composition comprising [A] a polymer selected from a copolymer of .alpha.-olefin having at least 2 carbon atoms and a specific cyclic olefin, a ring-opening polymer of said specific cyclic olefin and a hydroganted, ring-opening polymer thereof and [B] a core-shell elastomer containing 40 to 85 parts of weight of a core component which comprises a styrene-butadiene copolymer and 15 to 60 parts by weight of a shell component which comprises a copolymer of an acrylate or methacrylate having a specific cyclic structure, a monovinyl aromatic monomer, other monovinyl monomer and a plyfunctional monomer. This polymer composition is excellent in transparency and impact resistance.Type: GrantFiled: March 9, 1995Date of Patent: November 12, 1996Assignees: Mitsui Petrochemical Industries, Ltd., Hoechst AktiengesellschaftInventors: Toshihiro Sagane, Masayuki Okabe, Masahiro Kishine
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Patent number: 5567769Abstract: Homogeneous polymer blends are prepared from otherwise thermodynamically immiscible polymers, especially including block copolymers. Thus, polymers such as polystyrene/poly(methyl methacrylate) block copolymer or polystyrene/poly(1,2-butadiene) block copolymer are dissolved under pressure in supercritical fluid solvents such as chlorodifluoromethane and n-butane, respectively, and expanded through a fine nozzle. As the SCF solvent evaporates, the polymer deposits as a substantially homogeneous material.Type: GrantFiled: January 30, 1995Date of Patent: October 22, 1996Assignees: The Procter & Gamble Company, The Univ. of DelawareInventors: Annette D. Shine, Steven D. Smith, Isao Noda
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Patent number: 5548023Abstract: A method of compatibilizing a blend of at least a hydrocarbon polymer with at least one other polymer which is incompatible with the hydrocarbon polymer, said method comprising adding to the polymer blend a compatibilizer which is an isoolefin/para-alkylstyrene copolymer represented by the formula ##STR1## in which R and R' can be hydrogen, alkyl, and the primary and secondary alkyl halides, "a" ranges from about 14 to about 70,000, "b" ranges from 0 to about 70,000, "c" ranges from 0 to about 70,000, "d" ranges from about 1 to about 70,000, X is a halogen, and Nu is a nucleophilic residue provided by a polymeric nucleophile.Type: GrantFiled: March 13, 1995Date of Patent: August 20, 1996Assignee: Exxon Chemical Patents, Inc.Inventors: Kenneth W. Powers, Hsien-Chang Wang, T-C. Chung, Anthony J. Dias, Joseph A. Olkusz
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Conveyor belts derived from compositions comprising vinyl aromatic-conjugated diene block copolymers
Patent number: 5540983Abstract: Conveyor belt, obtainable by application of a block copolymer composition, comprising at least an optionally modified block copolymer, containing at least two terminal poly(vinylaromatic) blocks and at least one internal poly(conjugated diene) block, a non-aromatic plasticizing oil, and a terminal block compatible resin on at least one side of a fabric having from 5 to 25 threads per cm and process for the manufacture of it, while the threads in said fabric have a thickness in the range of from 2.mu. to 300.mu..Type: GrantFiled: August 1, 1995Date of Patent: July 30, 1996Assignee: Shell Oil CompanyInventors: Catherine A. L. Maris, Peter Migchels, Hans F. Vermeire -
Patent number: 5516578Abstract: The invention relates to a water and oil repellency imparting composition which comprises:(a) a fluoroaliphatic radical-containing agent; and(b) a polymer comprising cyclic carboxylic anhydride groups.Additionally, the composition may comprise:(c) a softener and/or a plasticizer. The composition provides water and oil repellent properties to fibrous and other substrates treated therewith and it shows high compatibility with the commonly used softeners.Type: GrantFiled: October 14, 1994Date of Patent: May 14, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventor: Dirk M. Coppens
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Patent number: 5504155Abstract: There is a need for polymers which are utilized in automotive interiors which offer increased heat and ultraviolet light resistance. It is particularly critical for polymers which are utilized in making skin compounds for automotive instrument and door panels to display excellent heat and ultraviolet light resistance. This invention discloses a rubbery polymer which can be blended with polyvinyl chloride to make leathery compositions having good heat and ultraviolet light resistance, said rubbery polymer being comprised of repeat units which are comprised of (a) butyl acrylate, or optionally a mixture of butyl acrylate and 2-ethylhexyl acrylate containing up to about 40% 2-ethylhexyl acrylate, (b) at least one member selected from the group consisting of methyl methacrylate, ethyl methacrylate, methyl acrylate, and ethyl acrylate, (c) acrylonitrile, (d) styrene, (e) a half ester maleate soap, and (f) a crosslinking agent.Type: GrantFiled: May 15, 1995Date of Patent: April 2, 1996Assignee: The Goodyear Tire & Rubber CompanyInventors: Hung D. Ngoc, Mariano Salazar
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Patent number: 5492760Abstract: A cross-linkable polymer composition containing a cross-linkable polymer having at least one hydrolysable silane group, a silanol condensation catalyst and a polybutadiene. The composition provides a cross-linked polymer having good water tree resistance properties, for use as insulation in electrical cables.Type: GrantFiled: December 5, 1994Date of Patent: February 20, 1996Assignee: AT Plastics Inc.Inventors: Haridoss Sarma, Alexander Shaikevitch
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Patent number: 5484839Abstract: Flame retardant latex compositions are disclosed which include natural or synthetic latex grafted with ring-halogenated, ethylenically unsaturated aromatic monomers. The graft latex is used alone or in combination with non-grafted natural or synthetic latex. The compositions are useful as coatings for a wide variety of applications, including fabric backcoatings, carpetings, paints, adhesives, sealants, caulks, non-woven binders and so on.Type: GrantFiled: May 18, 1994Date of Patent: January 16, 1996Assignee: Great Lakes Chemical Corp.Inventors: Jin-liang Wang, Nicolai A. Favstritsky