Mixture Contains Solid Polymer Derived From Reactant Containing Nitrogen Other Than From (meth)acrylonitrile Patents (Class 525/77)
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Patent number: 10717859Abstract: The present invention relates to a composition for preparing a SAN copolymer, a SAN copolymer, a preparation method therefor, a heat-resistant ABS resin blend comprising the same, and heat-resistant ABS pellets. Specifically, the present invention provides a composition for preparing a SAN copolymer, the composition comprising a monomer mixture, and ethylene glycol dimethacrylate as a chain extender, wherein the monomer mixture comprises 60 to 75 wt % of an ?-methylstyrene monomer and 25 to 40 wt % of an acrylonitrile-based monomer based on the total weight of the monomer mixture; and the ethylene glycol dimethacrylate is contained in an amount of 0.001 to 0.15 parts by weight based on 100 parts by weight of the monomer mixture.Type: GrantFiled: November 16, 2017Date of Patent: July 21, 2020Assignee: LG CHEM, LTD.Inventors: Gyu Sun Kim, Chang Hun Han, Dae Woo Lee, Jae Bum Seo, Jung Tae Park, Eun Jung Choi, Byoung Il Kang, Da Eun Sung
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Patent number: 10355310Abstract: Multi-functional additives containing at least one solid electrolyte interface (SEI) forming group and at least one SEI modifying group are advantageously employed in electrolyte compositions for electrochemical devices. The SEI forming group may comprise an organic carbonate moiety and the SEI modifying group may comprise a heteroatom functional group such as a sulfur containing organic moiety. The electrochemical devices include lithium ion batteries.Type: GrantFiled: May 13, 2016Date of Patent: July 16, 2019Assignee: SHENZHEN CAPCHEM TECHNOLOGY CO., LTD.Inventor: Wentao Li
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Patent number: 9815927Abstract: A copolymer includes a fumaronitrile residue represented by following General Formula I and an aromatic vinyl monomer residue represented by following General Formula II: wherein, in General-Formula II, R1 is a hydrogen atom, a methyl-group or a phenyl-group, and R2 is a hydrogen atom or a substituted or unsubstituted aryl-group having 6 to 12 carbon atoms, and each of R3, R4, R5, R6 and R7 independently represents a hydrogen atom, a halogen atom, a hydroxy-group, an alkoxy-group having 1 to 4 carbon atoms, an acyloxy-group having 2 to 5 carbon atoms, a cyanomethyl-group, or an alkyl-group having 1 to 8 carbon atoms, and at least two of R2, R3 and R4 may be bonded to form a ring, and at least two of arbitrary substituents of R3, R4, R5, R6 and R7 may be bonded to form a ring.Type: GrantFiled: October 15, 2015Date of Patent: November 14, 2017Assignee: FUJIFILM CORPORATIONInventors: Yutaka Nozoe, Ryosuke Takada
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Patent number: 9249290Abstract: The invention relates to a thermoplastic molding compound containing: a) 50 to 85 parts of one or more terpolymers based on acrylnitril, alpha-methylstyrene, and styrene as component A, said terpolymers consisting of: 5 to 30 wt. % styrene, 15 to 35 wt. % acrylnitril, 50 to 70 wt. % alpha-methylstyrene, and 0 to 5 wt. % additional copolymerizable monomers, b) 15 to 50 parts of one or more impact-modifying graft rubbers with an olefinic double bond in the rubber phase as component B, c) 0 to 45 parts of one or more copolymers based on styrene and acrylnitril as component C, said copolymers consisting of: 71 to 81 wt. % styrene, 29 to 19 wt. % acrylnitril, and 0 to 5 wt. % additional copolymerizable monomers, and optionally additives and fibrous and/or particulate fillers. The thermoplastic molding compound leads to a reduced yellowing of the produced molded body.Type: GrantFiled: December 28, 2012Date of Patent: February 2, 2016Assignee: STYROLUTION EUROPE GMBHInventors: Peter Ittemann, Rolf Minkwitz, Pascal Hesse, Bernd Niedermaier
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Patent number: 9187580Abstract: The present invention provides a resin particle having many recesses on the surface thereof, which has solvent resistance and heat resistance. More specifically, the present invention provides a resin particle having many recesses on the surface thereof which is obtained by using a seed particle, wherein a seed particle component in the resin particle has a crosslinked structure.Type: GrantFiled: May 11, 2009Date of Patent: November 17, 2015Assignee: SUMITOMO SEIKA CHEMICALS CO., LTD.Inventors: Shigeki Hamamoto, Hirotsugu Kawata, Kiyoshi Yamaguchi, Masayoshi Okubo
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Publication number: 20150017451Abstract: There is described a polymer blend of a first and second polymer comprising: a) a first polymer of: vinyl (co)polymer; alkyd; urethane acrylic copolymer; polyurethane and/or polyester; b) a second copolymer from: b1) optionally at least 10 wt-% of one or derivatives of itaconic acid and/or isomers thereof; b2) up to 20 wt-% of one or more acid functional (or potentially acid functional) monomer(s) and b3) vinyl monomer(s) where wt % of each monomer (b1 to b3) is based on total (b) and where at least one of the first and second polymer is obtained from an itacon-functional monomer such as itaconic acid and/or its derivatives.Type: ApplicationFiled: February 4, 2013Publication date: January 15, 2015Inventors: Tijs Nabuurs, Jeffrey Stubbs, Matthew Stewart Gebhard, Gerardus Cornelis Overbeek
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Publication number: 20140187719Abstract: Disclosed is a thermoplastic resin composition including: (A) a polycarbonate resin; (B) an acrylate-styrene-acrylonitrile (ASA) graft copolymer; (C) a random copolymer of an alkyl(meth)acrylate, an aromatic vinyl compound, and a vinyl cyanide compound; and (D) a copolymer of an aromatic methacrylate and a monofunctional unsaturated monomer.Type: ApplicationFiled: December 20, 2013Publication date: July 3, 2014Applicant: Cheil Industries Inc.Inventors: In-Chol KIM, Chang-Min HONG, Ja-Yoon KIM, Ji-Eun PARK
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Publication number: 20140148551Abstract: The present invention is directed to a polymer blend comprising a first polymer and a second polymer, the first polymer comprising: a polymeric backbone chain derived from a monomer comprising at least one conjugated diene monomer and optionally at least one vinyl aromatic monomer; and polymeric sidechains bonded to the backbone chain, the sidechains comprising a polymer immiscible with the backbone; the second polymer consisting of a polymer miscible with the polymeric sidechains.Type: ApplicationFiled: November 27, 2012Publication date: May 29, 2014Applicant: THE GOODYEAR TIRE & RUBBER COMPANYInventors: Alexandra Hermann, Robert Fokko Roskamp, Ralf Mruk, Liqing Ma, Frank James Feher, Rudolf Wilhelm Zentel, Bruce Raymond Hahn
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Publication number: 20140088254Abstract: The present invention generally relates to polyamide compositions having improved anti-delamination. More specifically, the present invention relates to novel polyamide compositions demonstrating improved anti-delamination, which can have at least one low purity polyamide.Type: ApplicationFiled: March 15, 2013Publication date: March 27, 2014Applicant: E I DU PONT DE NEMOURS AND COMPANYInventor: Avelino F. Lima
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Publication number: 20140011898Abstract: A thermoplastic elastomer compound is blended from styrenic block copolymer, thermoplastic vulcanizate, thermoplastic polyurethane, a compatibilizer, and a masterbatch containing silicone, which is added to provide a qualitative silky feel on surfaces of plastic articles made from the compound.Type: ApplicationFiled: March 11, 2013Publication date: January 9, 2014Applicant: POLYONE CORPORATIONInventors: Guoqiang QIAN, Krishna VENKATASWAMY, Malar SHETTY
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Publication number: 20130345353Abstract: The invention relates to thermoplastic molding compounds, containing a) 3 to 91.9 wt % of one or more styrene copolymers as component A, b) 3 to 91 wt % of one or more polyamides as component B, c) 3 to 50 wt % of one or more graft natural rubbers as component C, d) 0.1 to 25 wt % of one or more compatibilizers as component D, and e) 2 to 30 wt % of ethylene-1-octene copolymer having functional groups as component E, said thermoplastic molding compounds having improved low-temperature toughness.Type: ApplicationFiled: December 19, 2011Publication date: December 26, 2013Applicant: BASF SEInventors: Martin Weber, Marko Blinzler
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Patent number: 8592035Abstract: To provide a pressure-sensitive adhesive composition for a removable pressure-sensitive adhesive tape which can be, after attaching to an adherend, easily removed from the adherend by stretching the pressure-sensitive adhesive tape and does not cause adhesive transfer on the adherend or damage of the adherend. A pressure-sensitive adhesive composition comprises a cohesive component comprising a styrene-based block copolymer, and a basic component.Type: GrantFiled: November 14, 2005Date of Patent: November 26, 2013Assignee: 3M Innovative Properties CompanyInventors: Aizoh Sakurai, Eiji Mizuno
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Publication number: 20130172470Abstract: Disclosed is a composition comprising a polyamide composition comprising nylon-66 or nylon 66/6T, and optionally nylon-6, nylon-610, nylon-612, nylon-11, nylon-12, an ionomer composition comprising at least one ethylene acid copolymer wherein 30 to 90% of the total acid functionalities are neutralized to salts with a mixture of zinc cations and sodium or lithium cations, wherein the salts comprise from 20 to 90% equivalents of zinc; and optionally reinforcing filler. Articles prepared from the composition exhibit improved calcium chloride salt stress crack resistance over polyamide compositions not containing the ionomer.Type: ApplicationFiled: December 13, 2012Publication date: July 4, 2013Applicant: E I DU PONT DE NEMOURS AND COMPANYInventor: E I Du Pont De Nemours and Company
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Publication number: 20130137822Abstract: Modified carbon nanotubes are provided having carbon nanotube core covalently bound through C—C bonds to a polymer shell surrounding the carbon nanotube core. The polymer shell is a polymer having functional groups pointing outwardly from the shell. The functional groups are compatible with or able to covalently connect to another polymer. Such modified carbon nanotubes are more readily dispersed in a homogeneous manner in another polymer and may be used as a reinforcing filler in a polymer matrix. The modified carbon nanotubes with a core-shell structure in which the core has a substantially unidirectional orientation within the shell are produced by reacting neutral carbon nanotubes with 4-vinylaniline through a diazonium reaction in presence of one or more types of multifunctional monomers carrying a vinyl moiety and one or more functional groups for compatibilization with or connection to another polymer.Type: ApplicationFiled: June 10, 2011Publication date: May 30, 2013Applicant: NATIONAL RESEARCH COUNCIL OF CANADAInventors: Jingwen Guan, Robin Fraser, Benoit Simard
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Patent number: 8389628Abstract: The present invention provides a thermoplastic resin composition that can have excellent impact resistance, chemical resistance, fluidity and high gloss, which comprises about 1 to about 80 parts by weight of a styrene-acrylonitrile resin (A) including one or more functional groups capable of reacting with polyester; about 1 to about 98 parts by weight of an acrylonitrile-butadiene-styrene resin (B) including about 5 to about 40% by weight of a graft polymerized acrylonitrile-butadiene-styrene resin (B1) and about 60 to about 95% by weight of a styrene-acrylonitrile resin (B2) and including about 20% by weight or less of acrylonitrile; and about 1 to about 98 parts by weight of a polyester resin (C), wherein the resin composition comprises acrylonitrile in a total amount of about 1 to about 13% by weight.Type: GrantFiled: December 28, 2009Date of Patent: March 5, 2013Assignee: Cheil Industries Inc.Inventors: Jee Kwon Park, Jin Hwan Choi, Kang Yeol Park, Jun Myung Kim, Jae Won Lee
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Patent number: 8367755Abstract: There are provided a thermoplastic resin composition excellent in a balance between fluidity and low outgassing, and a molded product and a sheet including the thermoplastic resin composition. The thermoplastic resin composition may include from 70 to 99% by mass of (A) a polyphenylene ether, from 1 to 30% by mass of (B) a copolymer including an aromatic vinyl compound and an unsaturated dicarboximide derivative as constituent monomers, and from 0 to 20% by mass of (C) a copolymer including an aromatic vinyl compound and a cyanided vinyl compound as constituent monomers, based on 100% by mass of the total of the (A) component, the (B) component and the (C) component, wherein the (B) component has a weight-average molecular weight of from 70,000 to 250,000.Type: GrantFiled: November 6, 2008Date of Patent: February 5, 2013Assignee: Asahi Kasei Chemicals CorporationInventor: Kazunori Terada
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Patent number: 8344043Abstract: The present invention provides a thermoplastic resin composition that can have improved scratch resistance comprising: (A) about 10 to about 20% by weight of a rubber modified aromatic vinyl graft copolymer resin; (B) about 30 to about 50% by weight of polymethylmethacrylate (PMMA) resin; and (C) about 40 to about 60% by weight of an aromatic vinyl copolymer resin including about 5 to about 50% by weight of a (meth)acrylate alkyl ester. The thermoplastic resin composition of the present invention can have a good balance of various properties such as scratch resistance, impact strength, colorability, gloss, and injection molding properties.Type: GrantFiled: December 17, 2010Date of Patent: January 1, 2013Assignee: Cheil Industries Inc.Inventors: Sung Hun Jin, Chang Min Hong, Dong Hui Chu, Tae Woog Jang, In Chol Kim, Yu Ho Kim, Don Keun Lee
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Publication number: 20120322945Abstract: A thermoplastic resin composition for vehicle lamp housings, includes: 5 to 80 parts by weight of a graft copolymer (A) obtained by graft polymerizing at least one monomer (a-2) selected from the group consisting of aromatic vinyl-based monomers, vinyl cyanide-based monomers, and (meth)acrylic ester-based monomers and maleimide-based monomers, under the presence of an acrylic ester-based rubbery polymer (a-1) having a weight average particle size of 100 to 400 nm; and 20 to 95 parts by weight of a (co)polymer (B) in which at least one monomer (a-2) selected from the group consisting of aromatic vinyl-based monomers, vinyl cyanide-based monomers, (meth)acrylic ester-based monomers and maleimide-based monomers is polymerized, in which a content of total volatiles at 260° C. is no more than 0.7% by weight of the composition overall, and a content of oligomer component having a weight average molecular weight of 200 to 1000 is no more than 0.3% by weight of the composition overall.Type: ApplicationFiled: February 28, 2011Publication date: December 20, 2012Applicant: NIPPON A&L INC.Inventors: Hajime Tomita, Takayoshi Fujiwara, Shunsaku Kubota, Suguru Koba
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Patent number: 8227543Abstract: The invention relates to a flexible thermoplastic composition resistant to the ageing effects of oil, said composition comprising a grafted copolymer containing polyamide blocks and consisting of a polyolefin backbone and at least one polyamide graft. According to the invention, the grafts are attached to the core by the residues of an unsaturated monomer (X) having a function that can react with a polyamide comprising an amine end or a carboxylic acid end; the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerization from the double bond thereof; and the composition comprises between 40 to 90 wt % of the polyolefin core comprising the unsaturated monomer (X); between 5 to 40 wt % of polyamide grafts; and between 5 to 40% of at least one polymer selected from a saponified ethylene/vinyl acetate copolymer and a polyamide.Type: GrantFiled: February 6, 2008Date of Patent: July 24, 2012Assignee: Arkema FranceInventors: Stephane Bizet, Jean-Jacques Flat
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Patent number: 8076393Abstract: An ink composition includes (A) at least one polymerizable compound selected from the group consisting of a monofunctional radically polymerizable monomer having an aliphatic cyclic structure, an N-vinyllactam, and an aromatic monofunctional radically polymerizable monomer, (B) a radical polymerization initiator, (C) a pigment, and (D) a graft copolymer having a repeating unit represented by the formula below in a graft chain: wherein R denotes a hydrogen atom or a methyl group, X denotes a single bond, —O—, —CO—, —COO—, —CONR1—, —OCO—, or a phenylene group, R1 denotes a hydrogen atom, an alkyl group, an aryl group, or an aralkyl group, L denotes a single bond or a divalent linking group, Z denotes —NR2R3, R2 and R3 independently denote a hydrogen atom, an alkyl group, an aryl group, or an aralkyl group, and R2 and R3 may be bonded to each other to form a ring.Type: GrantFiled: August 26, 2008Date of Patent: December 13, 2011Assignee: FUJIFILM CorporationInventors: Kaoru Tojo, Norihide Shimohara
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Patent number: 8022146Abstract: A thermoplastic copolymer prepared from acrylonitrile and para-alpha-dimethylstyrene via bulk or solution polymerization has an improved heat distortion temperature and can be used together with graft copolymers and further components for the preparation of thermoplastic moldings.Type: GrantFiled: November 11, 2008Date of Patent: September 20, 2011Assignee: BASF SEInventors: Gerrit Luinstra, Florian Becker, Matthias Müller, Dirk Meckelnburg, Jens Assmann
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Patent number: 8007919Abstract: The invention concerns a coextrusion binder comprising a mixture of at least one ethylene homo- or copolymer (A1) of density ranging between 0.940 and 0.980 g/cm3 with at least one propylene homo- or copolymer (B), said mixture being grafted by at least one functional monomer and optionally diluted in at least one non-grafted ethylene homo- or copolymer (A2) of density ranging between 0.940 and 0.980 g/cm3; the grafting rate of said coextrusion binder being less than 0.5% wt. % based on the total weight of said binder; the density of said tie ranging between 0.940 and 0.980 g/cm3. The invention also concerns a structure comprising said type of binder as well as its use.Type: GrantFiled: May 23, 2006Date of Patent: August 30, 2011Assignee: Arkema FranceInventors: Jerome Chauveau, Fabrice Chopinez, Arnaud Gerbaulet, Jean-Laurent Pradel
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Publication number: 20110152402Abstract: The present invention provides a thermoplastic resin composition that can have improved scratch resistance comprising: (A) about 10 to about 20% by weight of a rubber modified aromatic vinyl graft copolymer resin; (B) about 30 to about 50% by weight of polymethylmethacrylate (PMMA) resin; and (C) about 40 to about 60% by weight of an aromatic vinyl copolymer resin including about 5 to about 50% by weight of a (meth)acrylate alkyl ester. The thermoplastic resin composition of the present invention can have a good balance of various properties such as scratch resistance, impact strength, colorability, gloss, and injection molding properties.Type: ApplicationFiled: December 17, 2010Publication date: June 23, 2011Applicant: CHEIL INDUSTRIES INC.Inventors: Sung Hun Jin, Chang Min Hong, Dong Hui Chu, Tae Woog Jang, In Chol Kim, Yu Ho Kim, Don Keun Lee
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Publication number: 20110082256Abstract: A polyolefin compound including: A) at least one thermoplastic olefin copolymer including the reaction product of olefin 1 and olefin 2, wherein: olefin 1 is a C2 based olefin and olefin 2 is a C3 to C8 ?-olefin or olefin 1 is a C3 based olefin and olefin 2 is a C4 to C8 ?-olefin; B) at least one functional polymer, the functional polymer content in the polyolefin compound being between 1 and 75 weight percent of the combined components A and B; wherein the thermoplastic olefin copolymer and the functional polymer form a co-continuous phase; wherein: a) an 12 melt index of the polyolefin compound is from about 1 to about 15 as measured using ASTM D 1238; b) a Shore A hardness of the polyolefin compound is from about 55 to about 100 as measured using ASTM D2240; c) a flexural modulus of the polyolefin compound is from about 0.8 to about 30 kpsi as measured using ASTM D790.Type: ApplicationFiled: May 29, 2009Publication date: April 7, 2011Applicant: DOW GLOBAL TECHNOLOGIES INC.Inventors: Felipe Martinez, Pankaj Gupta, Ashish Batra
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Publication number: 20100331475Abstract: Disclosed herein is a low gloss thermoplastic resin composition with a soft touch surface comprising (A) about 10 to about 80% by weight of a soft rubbery aromatic vinyl copolymer resin which comprises rubber particles with a graft ratio of about 40 to about 90% and an average particle diameter of about 6 to about 20 ?m as a dispersed phase; (B) about 4 to about 60% by weight of a rubber-modified aromatic vinyl copolymer resin; and (C) about 5 to about 80% by weight of an aromatic vinyl-vinyl cyanide copolymer resin. The molded article molded from the thermoplastic resin composition can have a soft touch surface as well as excellent low gloss and impact strength.Type: ApplicationFiled: June 30, 2010Publication date: December 30, 2010Applicant: CHEIL INDUSTRIES INC.Inventors: Jae Keun Hong, Hwan Seok Park, Byeong Do Lee, Young Sub Jin, Ho Ryong Sun, Sung Kwan Kim, Young Don Yoo
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Publication number: 20100324188Abstract: The present invention relates to a fiber reinforced nylon composition, wherein the composition includes (A) 25 to 75 parts by weight of a polyarylamide resin, (B) 25 to 75 parts by weight of a reinforcing fiber having a cross-sectional aspect ratio of 1.5 or more, and (C) an impact modifier, and the impact modifier is included in an amount of 1 to 10 parts by weight based on 100 parts by weight of a mixture of the polyarylamide resin and the reinforced fiber. According to the present invention, the fiber reinforced nylonresin composition may exhibit minimal or no warpage, can have excellent fluidity and impact resistance, and can provide high whiteness and a glossy-coating due to minimal or no surface change after dipping in boiling water.Type: ApplicationFiled: June 28, 2010Publication date: December 23, 2010Applicant: CHEIL INDUSTRIES INC.Inventors: Bum-Seok YOUN, Chang-Min HONG, Tae-Uk KIM, Young-Jun LEE
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Publication number: 20100266837Abstract: The invention relates to multiphase compositions of matter comprising at least an acrylic phase and a hydrocarbon phase, and more specifically to pressure sensitive adhesive compositions of matter of an acrylic-hydrocarbon polymer and an additional hydrocarbon component which has a molecular weight of at least 1,000 and may include one or both of an oligomeric hydrocarbon and a polymeric hydrocarbon.Type: ApplicationFiled: February 12, 2010Publication date: October 21, 2010Applicant: AVERY DENNISON CORPORATIONInventors: Nagarajan SRIVATSAN, Prakash MALLYA, Daniel L. HOLGUIN, Dominique WOUTERS, Eric L. BARTHOLOMEW, Liza P. LOFTON
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Publication number: 20100261831Abstract: A thermoplastic copolymer prepared from acrylonitrile and para-alpha-dimethylstyrene via bulk or solution polymerization has an improved heat distortion temperature and can be used together with graft copolymers and further components for the preparation of thermoplastic moldings.Type: ApplicationFiled: November 11, 2008Publication date: October 14, 2010Applicant: BASF SEInventors: Gerrit Luinstra, Florian Becker, Matthias Müller, Dirk Meckelnburg, Jens Assmann
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Publication number: 20100240813Abstract: There are provided a thermoplastic resin composition excellent in a balance between fluidity and low outgassing, and a molded product and a sheet including the thermoplastic resin composition. The thermoplastic resin composition may include from 70 to 99% by mass of (A) a polyphenylene ether, from 1 to 30% by mass of (B) a copolymer including an aromatic vinyl compound and an unsaturated dicarboximide derivative as constituent monomers, and from 0 to 20% by mass of (C) a copolymer including an aromatic vinyl compound and a cyanided vinyl compound as constituent monomers, based on 100% by mass of the total of the (A) component, the (B) component and the (C) component, wherein the (B) component has a weight-average molecular weight of from 70,000 to 250,000.Type: ApplicationFiled: November 6, 2008Publication date: September 23, 2010Applicant: ASAHI KASEI CHEMICALS CORPORATIONInventor: Kazunori Terada
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Publication number: 20100202050Abstract: The present invention provides an optical film that includes i) an acryl resin, and ii) 20 to 65 parts by weight of a core-shell type graft copolymer that includes a core having a rubber component and a shell including a polymer having a weight average molecular weight that is the same as or higher than a weight average molecular weight of a polymer constituting the i) acryl resin based on 100 parts by weight of the acryl resin, a retardation film, and an electronic device including the same.Type: ApplicationFiled: September 19, 2008Publication date: August 12, 2010Applicant: LG CHEM, LTD.Inventors: Byoung-II Kang, Chang-Hun Han, Dae-Woo Lee, Jae-Bum Seo, Jung-A Yoo, Song-Taek Oh
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Publication number: 20100168315Abstract: The present invention provides a thermoplastic resin composition that can have excellent impact resistance, chemical resistance, fluidity and high gloss, which comprises about 1 to about 80 parts by weight of a styrene-acrylonitrile resin (A) including one or more functional groups capable of reacting with polyester; about 1 to about 98 parts by weight of an acrylonitrile-butadiene-styrene resin (B) including about 5 to about 40% by weight of a graft polymerized acrylonitrile-butadiene-styrene resin (B1) and about 60 to about 95% by weight of a styrene-acrylonitrile resin (B2) and including about 20% by weight or less of acrylonitrile; and about 1 to about 98 parts by weight of a polyester resin (C), wherein the resin composition comprises acrylonitrile in a total amount of about 1 to about 13% by weight.Type: ApplicationFiled: December 28, 2009Publication date: July 1, 2010Inventors: Jee Kwon PARK, Jin Hwan CHOI, Kang Yeol PARK, Jun Myung KIM, Jae Won LEE
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Patent number: 7670523Abstract: Regrind is mixed with at least one low density metallocene polyethylene to increase the amount of regrind that can be used in a thermoformed article.Type: GrantFiled: January 25, 2007Date of Patent: March 2, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Anthony Poloso, Allen T Mika
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Patent number: 7671127Abstract: The invention relates to thermoplastic molding compositions, comprising A) from 35 to 95% by weight of at least one graft copolymer A), which is obtainable via reaction of A1) from 5 to 95% by weight of a polymer A1), which is obtained from at least one dicarboxylic anhydride a11) and from at least one vinylaromatic comonomer a12), and A2) from 5 to 95% by weight of a polyamide A2), B) from 5 to 40% by weight of at least one ungrafted or grafted, non-particulate rubber without core-shell structure B), which has functional groups which can react with the end groups of component A), C) from 0 to 50% by weight of at least one particulate or fibrous filler or particulate or fibrous reinforcing material C), D) from 0 to 60% by weight of at least one copolymer D) composed of vinyl aromatic monomers d1) and of comonomers d2), and E) from 0 to 40% by weight of at least one other additive E), where the entirety of components A) to E) gives 100% by weight, and also to processes for preparation of the thermoplastiType: GrantFiled: December 3, 2005Date of Patent: March 2, 2010Assignee: BASF SEInventors: Martin Weber, Frank Rittig, Werner Haensel, Walter Heckmann, Hans Hönl, Peter Ittemann, Bangaru Sampath
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Patent number: 7655726Abstract: The present invention relates to novel molding compositions based on semicrystalline engineering thermoplastics which, in conventional processing techniques, give moldings with reduced surface gloss. A feature of the molding compositions is that they comprise, in a polymer matrix, if appropriate with the usual additives, polymer particles with a median size d50 of from 0.1 ?m to 100 ?m, and comprise at least one other incompatible or semicompatible polymer which has not been chemically crosslinked, and also, if appropriate, comprise salt-like additives. The invention further relates to moldings which are produced by means of conventional processing techniques, in particular via injection molding, from these matt-effect molding compositions.Type: GrantFiled: March 28, 2008Date of Patent: February 2, 2010Assignee: Ticona GmbHInventors: Joachim Clauss, Christine Kostler, Arnold Schneller, Klaus Kurz
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Patent number: 7569628Abstract: The present invention relates to a styrenic thermoplastic resin composition, and more particularly to a styrenic thermoplastic resin composition comprising a non-halogen flame-retardant having superior flame-retarding properties and impact strength. The present invention provides a flame-retarding styrenic thermoplastic resin composition comprising a) 100 weight parts of a base resin comprising i) 10 to 50 weight parts of a rubber-modified styrene-containing graft copolymer, ii) 5 to 20 weight parts of phenol novolac resin, and iii) 20 to 70 weight parts of a styrene-containing copolymer; and b) 5 to 20 weight parts of an aromatic phosphate. In addition, the a) base resin may further comprise iv) 10 to 40 weight parts of a thermoplastic polyurethane resin.Type: GrantFiled: June 25, 2007Date of Patent: August 4, 2009Assignee: LG Chem, Ltd.Inventors: Sung-Ho Lee, Chan-Hong Lee, Yong-Yeon Hwang, Ki-Young Nam, Tae-Hak Kim
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Publication number: 20090156717Abstract: Disclosed are a synthetic resin composition for use as building materials such as window frames, as well as a product manufactured using the same. More particularly, the synthetic resin composition comprises a tetrapolymer of acrylic rubber-styrene monomer-butadiene rubber-vinyl cyanide monomer and a styrene-vinyl cyanide copolymer having a high molecular weight and a high degree of dispersion. Unlike products manufactured using prior polyvinyl chloride (PVC), building material such as window frames manufactured using the synthetic resin composition are recyclable, and thus can contribute to a reduction in the generation of hormone-disrupting chemical dioxin, which is released in the burning thereof. Also, the resin composition can be manufactured into products having excellent properties of weather resistance and colorability without using environmental pollutants such as cadmium stearate or lead stearate, which are used as thermal stabilizers.Type: ApplicationFiled: May 12, 2006Publication date: June 18, 2009Inventors: Jang Hyun Choi, Joo Yub Ho, Seung Kyu Lee, Yun Hwan Kim
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Patent number: 7528194Abstract: The present invention relates to the modification of copolymers, in particular of grafted copolymers into comb copolymers. The modification comprises the steps (i) of controlled radical polymerization of a polymer or copolymer bearing a epoxide group at one end resulting from the initiation step, and (ii) a heating step of the polymer prepared under (i) and a copolymer bearing a functional group either in the backbone or attached to a side chain, which is able to react with the epxide group. The result is a comb copolymer with well controlled chain length of the grafted side arms expressed for example by a low polydispersity.Type: GrantFiled: February 2, 2004Date of Patent: May 5, 2009Assignee: Ciba Specialty Chemicals Corp.Inventors: Jochen Fink, Michael Roth, Rudolf Pfaendner
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Publication number: 20090111942Abstract: Disclosed are methods for making a surface modified biomedical device involving (a) exposing a biomedical device having a plurality of biomedical device surface functional groups to one or more ethylenically unsaturated-containing organic compounds having a reactive group that is co-reactive to the biomedical device surface functional groups of the biomedical device; and (b) graft polymerizing a hydrophilic reactive monomer having a complementary reactive functionality with the ethylenically unsaturated functionalities of the ethylenically unsaturated-containing organic compounds on or near the surface of the biomedical device thus forming a biocompatible surface on the biomedical device. The methods disclosed are two-step methods and do not include any additional surface treatment steps.Type: ApplicationFiled: October 25, 2007Publication date: April 30, 2009Applicant: BAUSCH & LOMB INCORPORATEDInventors: Weihong Lang, Yu-Chin Lai, Daniel J. Hook
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Publication number: 20090086319Abstract: The present invention provides an optical film that includes i) a (meth)acrylic resin, and 5 to 45 parts by weight of ii) a graft copolymer, prepared by grafting a (meth)acrylic resin onto a copolymer of (meth)acrylic rubber and aromatic vinyl compound, based on 100 parts by weight of the i) (meth)acrylic resin, and an electronic device including the optical film.Type: ApplicationFiled: October 1, 2008Publication date: April 2, 2009Applicant: LG Chem, Ltd.Inventors: Tae-Bin Ahn, Yong-Yeon Hwang, Min-Jung Kim, Jae-Hyun Jeong, Ki-Heon Song
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Publication number: 20090043047Abstract: A resin composition having good scratch resistance includes about 5 to about 50 parts by weight of core-shell graft resin (A) and about 95 to about 50 parts by weight of resin (B) which includes about 40 to about 100% by weight of (meth)acrylic acid alkyl ester. The outer shell of the core-shell graft resin (A) comprises (meth)acrylic acid alkyl ester.Type: ApplicationFiled: October 17, 2008Publication date: February 12, 2009Applicant: Cheil Industries Inc.Inventors: Doo Han HA, Bong Jae JEONG
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Publication number: 20090005507Abstract: To provide a gap-filling member for vehicles using an olefinic thermoplastic elastomer, which has a wide range for regulating a gloss value representing gloss, can provide a high initial gloss value and is excellent also in mechanical properties such as scratch resistance, chemical resistance and adhesion, and recycling properties. A gap-filling member for vehicles to be mounted on a peripheral portion of a plate-like body for vehicle windows, to fill a gap between the plate-like body for vehicle windows and an opening of a vehicle body, said gap-filling member being made of an olefinic thermoplastic elastomer which comprises: an olefinic graft copolymer comprising an olefinic polymer or olefinic copolymer segment formed from an ?-olefin monomer, and a vinyl copolymer segment, wherein particles of one segment are dispersed in the other segment, and the particles have an average diameter of from 0.Type: ApplicationFiled: September 3, 2008Publication date: January 1, 2009Applicants: ASAHI GLASS COMPANY, LIMITED, NOF CORPORATIONInventors: Yuuji MASAKI, Toshihiro Atsumi, Satoshi Usami, Toru Tamura, Motoyuki Sugiura
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Publication number: 20080311332Abstract: To provide a pressure-sensitive adhesive composition for a removable pressure-sensitive adhesive tape which can be, after attaching to an adherend, easily removed from the adherend by stretching the pressure-sensitive adhesive tape and does not cause adhesive transfer on the adherend or damage of the adherend. A pressure-sensitive adhesive composition comprises a cohesive component comprising a styrene-based block copolymer, and a basic component.Type: ApplicationFiled: November 14, 2005Publication date: December 18, 2008Inventors: Aizoh Sakurai, Eiji Mizuno
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Publication number: 20080108750Abstract: An object of the present invention is to propose a novel thermoplastic resin composition having high impact resistance without degrading weather resistance even when the content of an impact modifier is small. A thermoplastic resin composition includes 100 parts by weight of a thermoplastic resin (a) and 0.5 to 20 parts by weight of an impact modifier (b) containing a graft copolymer (b-1) containing at least one (meth)acrylate flexible polymer phase and a rigid polymer phase serving as the outermost part of the graft copolymer, a water-soluble polymer compound (b-2) having a physical gel-forming property, and a gelling agent (b-3). In the thermoplastic resin composition, the content of the water-soluble polymer compound (b-2) having the physical gel-forming property is 0.01 to 3.0 parts by weight relative to 100 parts by weight of the graft copolymer (b-1) and the content of the rigid polymer phase serving as the outermost part in the graft copolymer (b-1) is 0.5 to 10 percent by weight.Type: ApplicationFiled: December 13, 2005Publication date: May 8, 2008Inventors: Toru Terada, Shinya Hongo, Hirotsugu Yamada, Takashi Ueda
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Patent number: 7235597Abstract: The present invention relates to a styrenic thermoplastic resin composition, and more particularly to a styrenic thermoplastic resin composition comprising a non-halogen flame-retardant having superior flame-retarding properties and impact strength. The present invention provides a flame-retarding styrenic thermoplastic resin composition comprising a) 100 weight parts of a base resin comprising i) 10 to 50 weight parts of a rubber-modified styrenic-containing graft copolymer, ii) 5 to 20 weight parts of phenol novolac resin, and iii) 20 to 70 weight parts of a styrene-containing copolymer; and b) 5 to 20 weight parts of an aromatic phosphate. In addition, the a) base resin may further comprise iv) 10 to 40 weight parts of a thermoplastic polyurethane resin.Type: GrantFiled: September 5, 2002Date of Patent: June 26, 2007Assignee: LG Chem, Ltd.Inventors: Sung-Ho Lee, Chan-Hong Lee, Yong-Yeon Hwang, Ki-Young Nam, Tae-Hak Kim
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Patent number: 7217763Abstract: The present invention relates to acrylonitrile-butadiene-styrene copolymer transparent resin having superior chemical resistance and transparency and preparation thereof, and particularly to acrylonitrile-butadiene-styrene copolymer transparent resin having superior chemical resistance and transparency by graft-copolymerzing on a) conjugated diene rubber latex, b) methacrylate alkylester or acrylate alkylester compound, c) aromatic vinyl compound and d) vinyl cyanide compound, and preparation thereof. In addition, according to the present invention, chemical resistance and ESCR can be further improved by further adding e) polyester-amide copolymer to the acrylonitrile-butadiene-styrene copolymer transparent resin.Type: GrantFiled: October 24, 2002Date of Patent: May 15, 2007Assignee: LG Chem, Ltd.Inventors: Jeong-Su Choi, Sung-Hee Kim, Hyoung-Min Bahn, Keun-Hoon Yoo
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Patent number: 7179882Abstract: The present invention relates to low viscosity polymer polyols and to a process for the preparation of these low viscosity polymer polyols. These polymer polyols comprise the free-radical polymerization product of (A) a base polyol, (B) a pre-formed stabilizer, and (C) at least one ethylenically unsaturated monomer, in the presence of (D) at least one free-radical polymerization initiator, and (E) at least one polymer control agent. The total amount of polymer control agent present in the polymer polyols of the present invention ranges from greater than about 5.0% up to about 20% by weight, based on 100% by weight of the polymer polyol.Type: GrantFiled: August 2, 2004Date of Patent: February 20, 2007Assignee: Bayer Materialscience LLCInventors: Rick L. Adkins, Scott A. Guelcher, James R. Charron, John E. Hayes
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Patent number: 7134466Abstract: The present invention relates to crosslinked rubber particles modified by secondary amino-(meth)-acrylate groups, a process for their production, their use for the production of rubber vulcanizates or rubber molded bodies of all kinds and also the rubber vulcanizates or rubber molded bodies that can be obtained from the rubber particles.Type: GrantFiled: February 13, 2004Date of Patent: November 14, 2006Assignee: Bayer AktiengesellschaftInventors: Werner Obrecht, Burkhard Köhler, Winfried Jeske
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Patent number: 7056979Abstract: A reaction product is prepared by reacting a first polymer having pendant or terminal carboxyl or anhydride groups with a second polymer (e.g. elastomer) having an amine containing terminal group. The second polymer is anionically polymerized. The second polymer is functionalized by reacting the growing anionic chain end with an imine. Then a protic terminating agent terminates the growing chain end. The first and second polymers are reacted by mixing (desirably above their softening temperatures) and forming a blend with improved physical properties over a blend of similar polymers lacking a reactive amine group.Type: GrantFiled: June 12, 1998Date of Patent: June 6, 2006Assignee: Bridgestone CorporationInventors: James A. Krom, Xiaorong Wang
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Patent number: 6924013Abstract: The present invention relates to a coextrusion binder useful for petrol tanks of HDPE/binder/EVOH or PA/binder/HDPE structure.Type: GrantFiled: April 6, 2000Date of Patent: August 2, 2005Assignee: Arkema (formerly ATOFINA)Inventors: Jean-Claude Jammet, Christophe Le Roy, Xavier Marical, Jérôme Pascal
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Patent number: 6893593Abstract: A resin molded article is produced by performing extrusion molding of a thermoplastic amorphous resin containing a dispersion phase, and then rolling it. According to a molecular orientation associated with an elongation of the dispersion phase in the rolling direction, it is possible to provide the resin molded article having an increased elastic modulus and a reduced coefficient of linear expansion.Type: GrantFiled: June 24, 2002Date of Patent: May 17, 2005Assignee: Matsushita Electric Works, Ltd.Inventors: Sadao Yabu, Takashi Nakai, Kazushige Uchida, Hidemi Ibi