Mixture Contains Solid Polymer Derived From Reactant Containing Carboxylic Acid Group Patents (Class 525/78)
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Patent number: 6448343Abstract: The formation of thermoplastic vulcanates may be accomplished with two polymers, wherein one polymer is grafted, or copolymerized with a carboxylic acid anhydride, which acid anhydride grafted polymer then is reacted with an amino silane, which reacts with the acid anhydride and then cross links.Type: GrantFiled: February 15, 2000Date of Patent: September 10, 2002Assignee: Crompton CorporationInventors: Jacques F. Schombourg, Peter Kraxner, Willy Furrer, Abdellatif Adberrazig
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Patent number: 6448332Abstract: Compositions which have substantial weatherability and impact resistance include a substantially uniform blend of an acrylonitrile/styrene/acrylic polymeric material and a component selected from (A) polymeric materials including units derived from ethylene, carbon monoxide and copolymerizable ethylenically unsaturated organic compounds, (B) graft polymer components including ethylene-propylene-non-conjugated diene terpolymers grafted with styrene and acrylonitrile monomers, and mixtures thereof. Methods for making such compositions include forming a substantially uniform physical mixture of such polymeric material and component.Type: GrantFiled: January 20, 2000Date of Patent: September 10, 2002Assignee: Hughes Processing, Inc.Inventor: Roderick E. Hughes
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Patent number: 6448335Abstract: Mixtures of C2-C10 olefin polymers functionalized with carboxylic acids which are neutralized from 1 to 100% with metallic ions The mixtures comprise (by weight): (1) 100 parts of a heterophasic polyolefin composition comprising crystalline polypropylene and an elastomeric fraction of an ethylene/propylene or superior ethylene/&agr;-olefin copolymer where the ethylene content is less than 40%; and (II) 0-250 parts of an elastomeric polymer selected from: a) ethylene/C3-C10 &agr;-olefin copolymers containing at least 20% of a C3-C10 &agr;-olefin; b) ethylene/methyl acrylate copolymers containing from 15 to 30% of recurrent units of methyl acrylate, and having a MFR ranging from 1 to 10 g/10 min; and c) polyisobutylenes; d) atactic propylene homopolymers and amorphous ethylene/C3-C10 &agr;-olefins copolymers produced with metallocenic catalysts; and e) styrene block copolymers containing butadiene and isoprene as comonomer.Type: GrantFiled: March 22, 2000Date of Patent: September 10, 2002Assignee: Basell Poliolefine Italia S.p.A.Inventors: Vittorio Braga, Roberto Bonari
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Patent number: 6433091Abstract: A methacrylate ester or acrylate ester two-part reactive adhesive composition including vinyl-terminated liquid rubber and polymeric elastomer. The vinyl-terminated liquid rubber is preferably methacrylate-terminated or acrylate-terminated polybutadiene; the polymeric elastomer is preferably polychloroprene, core shell polymer and/or block copolymer rubber.Type: GrantFiled: May 10, 2001Date of Patent: August 13, 2002Assignee: Henkel Loctite CorporationInventor: Haitao Cheng
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Patent number: 6420482Abstract: This invention concerns a composition comprising a blend of polyolefin with the reaction of a functionalized polyolefin and polyetheramine in which the polyetheramine is grafted into the functionalized polyolefin in a customary mixing apparatus. A process for producing the reaction product of functionalized polypropylene and polyetheramine by melting with polypropylene in a customary mixing apparatus is also disclosed. Blends of the present invention are advantageously useful to prepare paintable automotive body parts. This invention further includes dyeable polyolefin compositions containing the reaction product of functionalized polyolefin and polyetheramine. Dyeable polyolefin fibers, including polypropylene fibers, are disclosed, which may be made by melt spinning, and which may be employed to make woven. and non-woven fabric.Type: GrantFiled: September 26, 2000Date of Patent: July 16, 2002Assignee: Huntsman Petrochemical CorporationInventors: Richard Joseph Gilbert Dominguez, Christopher S. Henkee, Wheeler C. Crawford, Gerald W. Cummings, Kevin John Hess, Richard James Clark, Randall Keith Evans
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Patent number: 6416834Abstract: Adhesion promoting compositions comprising mixtures of carboxylated unsaturated polymers and a) amines; b) amine derivatives; or c) mixtures of hydroxy compounds and quaternary phosphonium salt accelerators or quaternary ammonium salt accelerators are useful as components of curable elastomer compositions. The curable compositions exhibit excellent adhesion to fluoropolymers.Type: GrantFiled: March 15, 2000Date of Patent: July 9, 2002Assignee: E. I. du Pont de Nemours and CompanyInventor: Robert Earl Fuller
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Patent number: 6414082Abstract: The disclosed invention provides a golf ball comprising a core and a cover, wherein at least one of the cover or the core is formed from a polymer blend comprising at least one grafted metallocene-catalyzed polymer, at least one ionomer, and at least one non-ionomer having improved melt flow characteristics.Type: GrantFiled: June 15, 2000Date of Patent: July 2, 2002Assignee: Acushnet CompanyInventors: Murali Rajagopalan, Kevin M. Harris
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Publication number: 20020082347Abstract: A resin composition comprising, in admixture, (A) a specific thermoplastic resin composition and (B) a comb-like graft copolymer comprising (b-1) a non-ionomer thermoplastic elastomer as backbone component and (b-2) a polymeric chain containing a non-olefinic monomer as side chain component wherein the weight ratio of (A):(B) is from 99:1 to 40:60 is improved in flow and moldability and thus suitable to form a layer of a golf ball which exhibits improved rebound and durability.Type: ApplicationFiled: May 21, 2001Publication date: June 27, 2002Applicant: BRIDGESTONE SPORTS CO., LTD.Inventors: Rinya Takesue, Yasushi Ichikawa
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Patent number: 6399704Abstract: Multiple component polymer compositions for fabrication into articles. In particular, polymeric compositions comprising a heat resistant polymer; a radio frequency (“RF”) susceptible polymer; and a compatibilizing polymer.Type: GrantFiled: June 5, 1995Date of Patent: June 4, 2002Assignee: Baxter International Inc.Inventors: Dean Laurin, Angeles Lillian Buan, Lecon Woo, Michael T. K. Ling, Yuan Pang Samuel Ding, William Anderson, Larry A. Rosenbaum, Denise S. Hayward, Joseph P. Hoppesch, Gregg Nebgen, Stanley Westphal
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Patent number: 6384136Abstract: The disclosed invention provides novel golf ball compositions which contain non-ionic olefinic copolymers produced by use of metallocene catalysts, wherein the metallocene catalyzed polymers have been functionalized with a post-polymerization reaction. The grafted metallocene catalyzed polymers may be blended with ionomers, non-grafted metallocene catalyzed polymers, or other non-ionomeric polymers. These compositions exhibit improved mechanical properties such as tensile and flexural properties, and can be foamed or unfoamed. Golf balls that employ at least one layer of these compositions in any of the golf ball cover, core, or a mantle situated between the cover and the core provide ball properties and performance similar to and in some cases better than the state of the art ionomer based golf balls.Type: GrantFiled: November 9, 1999Date of Patent: May 7, 2002Assignee: Acushnet CompanyInventors: Murali Rajagopalan, Kevin M. Harris
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Patent number: 6376575Abstract: An aqueous coating composition comprising a mixture of 90 to 99 wt. % of a filmforming binder composition comprising an alkali non-swellable core-shell addition polymer dispersion (I), and 1-10 wt. % of a rheology modifying addition polymer dispersion (II). It is required that the total amount of (meth)acrylic acid in 100 parts of the total addition polymer (I) is less than 1.75 wt. %. The aqueous coating composition of the present invention can be advantageously used as a base coat in a base coat/clear coat system. This use shows a decrease in strike-in effect compared to previous known base coat/clear coat systems.Type: GrantFiled: December 21, 2000Date of Patent: April 23, 2002Assignee: Akzo Nobel N.V.Inventors: Roelof Buter, Andreas Henricus J. Roelofs
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Patent number: 6372850Abstract: Melt processable, flushable polymer fibers and methods of making melt processable, flushable polymer fibers are disclosed. The fibers comprise poly(ethylene oxide). Preferably, the poly(ethylene oxide) is modified by grafting polar vinyl monomers, such as poly(ethylene glycol) methacrylate and 2-hydroxyethyl methacrylate, onto poly(ethylene oxide). The modified poly(ethylene oxide) has improved melt processability and can be used to melt process poly(ethylene oxide) fibers of thinner diameters.Type: GrantFiled: December 31, 1997Date of Patent: April 16, 2002Assignee: Kimberly-Clark Worldwide, Inc.Inventors: James Hongxue Wang, David Michael Schertz
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Patent number: 6362274Abstract: The invention relates to grafted copolymers comprising at least three sequences of distinct chemical nature, among which one or more sequence(s) for anchoring on solid particles, one or more sequence(s) of hydrophobic character and one or more sequence(s) of hydrophilic character. The invention also concerns their process of preparation, the compositions containing them, their use as agent for dispersing, stabilizing solid particles and/or emulsifying in an aqueous and/or organic medium, as well as use thereof for preparing pigmentary dispersions in aqueous and/or organic medium.Type: GrantFiled: February 23, 1999Date of Patent: March 26, 2002Assignee: Les Peintures JefcoInventors: Pierre Legrand, Gerard Riess, Jean-Phillipe Lerch, Daniel Lefevre
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Publication number: 20020010265Abstract: A combination of a low flexural modulus and low crystallinity polyolefin and a functionalized polyolefin were found to result in an olefin composition with excellent adhesion to metals and polar polymers (e.g. polyesters, polyamides, etc) especially fibers therefrom. When these two polyolefins were added to a thermoplastic vulcanizate (e.g. used to partially or fully replace the semicrystalline polyolefin of a thermoplastic vulcanizate), the thermoplastic vulcanizate was found to have the necessary adhesion to form fiber reinforced thermoplastic vulcanizate.Type: ApplicationFiled: December 22, 1998Publication date: January 24, 2002Inventors: JIM JOHNSON, MARVIN HILL
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Publication number: 20020004571Abstract: Synthetic polymers having moieties capable of covalent or hydrogen bonding to cellulose and one or more amphiphilic moieties are disclosed. These polymers are capable of providing two distinct properties to paper products, such as tissues, which properties heretofore have been imparted through the use of at least two different molecules. The backbone of these synthetic polymers is based on modified vinyl polymers, such as polyvinyl alcohol, polyacrylamides and polyacrylic acids.Type: ApplicationFiled: May 14, 2001Publication date: January 10, 2002Inventors: Wen Zyo Schroeder, Daniel Arthur Clarahan, Mike Thomas Goulet, Thomas Gerard Shannon
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Publication number: 20010051689Abstract: A polymeric film composition, which can readily be applied to a sheet-configured substrate and which resists creep at room temperature, even when the sheet/film combination is stored as a roll, is disclosed.Type: ApplicationFiled: June 26, 2001Publication date: December 13, 2001Inventors: Thomas Kevin Foreman, Mark Robert McKeever
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Patent number: 6306975Abstract: Methods for irradiation induced graft polymerization of a monomers, such as styrenes, onto fluoropolymers are provided. The methods, which involve either the use of acids, preferably mineral acids, or creating a rough surface on the fluoropolymer, provide higher levels of grafting of the copolymer than grafting in the absence of the acid or of the rough surface on the fluoropolymer. Also provided are grafted copolymers produced by the methods. Methods for increasing the performance of solid phase assays, such as scintillation proximity assays, are also provided.Type: GrantFiled: January 22, 1998Date of Patent: October 23, 2001Assignee: IroriInventors: Chanfeng Zhao, John E. Lillig, Robert Neeper, Gordon W. Hudson, Anthony W. Czarnik, Zahra Parandoosh, Gary S. David, Xiao-Yi Xiao
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Patent number: 6306964Abstract: A compound comprising a blend of polypropylene with the reaction of a functionalized polypropylene and polyether amine in which the polyetheramine is grafted into the functionalized polypropylene in a customary mixing apparatus is disclosed. The blend may include an elastomer such as EP rubber and/or a filler such as glass. A process for producing the reaction product of the functionalized polypropylene and the polyether amine by melting with polypropylene in a customary mixing apparatus is also disclosed. Blends of the present invention are advantageously useful to prepare paintable automotive body parts.Type: GrantFiled: August 3, 1999Date of Patent: October 23, 2001Assignee: Huntsman Petrochemical CorporationInventors: Randall Keith Evans, Richard J. G. Dominguez, Richard J. Clark
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Patent number: 6300412Abstract: This invention relates to a process for preparing rubber-modified aromatic vinyl resin compositions by polymerizing a raw material solution containing 3 to 20% by weight of rubbery polymer, 50 to 97% by weight of an aromatic vinyl monomer, and 0 to 30% by weight of a solvent until the conversion of said aromatic vinyl monomer falls in the range from 30 to 70%, adding a (meth)acrylate monomer or its mixture with other monomers to the reaction mixture so that the ratio by weight of the aromatic vinyl monomer in the reaction mixture to the (meth)acrylate monomer becomes 85/15 to 50/50, continuing the polymerization, and devolatilizing to remove the unreacted monomers, solvent, and the like. It is possible by this process to prepare easily and economically rubber-modified aromatic vinyl resin compositions of easy processability, good surface properties in respect to appearance and scratch resistance, and good balance between impact resistance and rigidity.Type: GrantFiled: January 7, 2000Date of Patent: October 9, 2001Assignee: Nippon Steel Chemical Co., Ltd.Inventors: Yasuji Shichijo, Masanari Fujita
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Patent number: 6281297Abstract: Isobutylene rubber particles comprising a finely divided isobutylene polymer, and isobutylene-based graft copolymer particles comprising the isobutylene rubber particles and a vinyl monomer graft-polymerized onto the particles, which are useful as an impact modifier having excellent weatherability and thermal stability for thermoplastic resins and provide a thermoplastic resin composition having an improved impact resistance.Type: GrantFiled: November 3, 1998Date of Patent: August 28, 2001Assignee: Kaneka CorporationInventors: Taizo Aoyama, Katsuhiko Kimura
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Patent number: 6268427Abstract: A method for increasing the damping properties of tire rubber comprising the steps of adding a saturated damping additive to a vulcanizable composition of matter, and processing the vulcanizable composition of matter containing the damping additive into tire rubber.Type: GrantFiled: February 18, 1999Date of Patent: July 31, 2001Assignee: Bridgestone CorporationInventors: Xiaorong Wang, Victor J. Foltz, Michael W. Hayes
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Patent number: 6255387Abstract: A derivatized blend and a process for producing that blend in which a high ethylene content ethylene-propylene polymer and a lower ethylene content ethylene-propylene polymer are subjected to simultaneous blending and shearing to reduce their molecular weights and molecular weight distribution and then reacted with an organic compound to derivatize the blend. The sheared derivatized blend of polymers can function as a shear stable multifunctional viscosity index improver with improved low temperature properties and, in some cases, dispersancy antioxidant and anti-wear properties.Type: GrantFiled: January 8, 1998Date of Patent: July 3, 2001Assignee: Ethyl Additives CorporationInventors: Errol J. Olivier, Robert T. Patterson, Peter N. Nugara
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Patent number: 6248825Abstract: The present invention teaches a method for enabling the formation of a high damping, soft polymer gel. The method includes: reacting a poly(alkenyl benzene-co-maleimide) polymer with a maleated polyalkylene and an alkyl diamine under substantially dry conditions sufficient to form a polyalkylene grafted poly(alkenyl benzene-co-maleimide) polymer product; and, dispersing the polyalkylene grafted poly(alkenyl benzene-co-maleimide) polymer product with an extender oil sufficient to form the gel. The present invention also contemplates a polymer gel composition, a polymer composition and an article manufactured from the polymer gel composition.Type: GrantFiled: May 6, 1998Date of Patent: June 19, 2001Assignee: Bridgestone CorporationInventors: Xiaorong Wang, Victor J. Foltz, Takahiro Matsuse, Naruhiko Mashita, Shinichi Toyosawa
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Patent number: 6239215Abstract: A powder coating composition comprising a multilayer polymer particle, in which at least one inner layer is a polymer layer having a glass transition temperature (Tg) of not over 20° C. and the outermost layer is a polymer layer having a Tg of not less than 60° C. and, the monomer components forming the polymer layer having a Tg of not over 20° C. are those having an unsaturated double bond in the molecule, and among the monomer components, a crosslinking monomer and a grafting monomer are used, respectively, within the ranges of 0.3 to 5 weight % and of 1 to 10 weight %, is dispersed in an amount of 1 to 30 parts by weight per 100 parts by weight of the total components other than the multilayer polymer particle can show excellent dispersibility to various powder coatings and can improve workability and impact resistance of a coat film while maintaining inherent characteristics of a powder coating such as appearance of a coat film and an anti-blocking property.Type: GrantFiled: March 23, 1999Date of Patent: May 29, 2001Assignee: Takeda Chemical Industries, Ltd.Inventors: Hirokazu Morita, Tatsuo Fujii, Hiroyuki Shiraki
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Patent number: 6228939Abstract: The present invention relates to the use of polymers near their gelation point as additives to hydrogenated block copolymers to form thermoreversible gels. More particularly, the compositions of this invention are elastomeric and exhibit improved damping capabilities over a wide temperature range and frequency range due to the addition of a novel near-gelation polymer damping additive.Type: GrantFiled: May 19, 1999Date of Patent: May 8, 2001Assignee: Bridgestone CorporationInventors: Xiaorong Wang, Victor J. Foltz
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Patent number: 6225404Abstract: A thermoplastic compound comprising at least one linear or branched thermoplastic polymer or copolymer, having at least one reactive or graftable site (F1), which polymer is compounded with at least one hyperbranched dendritic polyester macromolecule being composed of a monomeric or polymeric nucleus and one or more monomeric or polymeric branching or spacing chain extenders. The macromolecule is optionally chain terminated and/or functionalized, whereby terminal chain extender functions, chain termination and/or functionalization provides the macromolecule with at least one reactive or graftable site (F2) being reactive to or graftable onto said reactive or graftable site (F1). In a further aspect, the invention relates to a thermoplastic composition comprising two or more components, whereby at least one is said thermoplastic compound. In yet a further aspect, the invention relates to a thermoplastic article made of one or more thermoplastic compounds, whereby at least one is said thermoplastic compound.Type: GrantFiled: March 4, 1999Date of Patent: May 1, 2001Assignee: Perstorp ABInventors: Kent Sorensen, Bo Pettersson, Louis Boogh, Jan-Anders Edvin Mansson
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Patent number: 6214426Abstract: A multilayered article and vessel, which are superior in the properties, such as shock resistance, rigidity, an ability to barrier against gasoline and interlayer adhesion, and are permissible of being recycled for reuse, comprising a base layer (A1) comprising a polyetylene resin (a1) having an MFR (ASTM D 1238, 190° C., 2160 g) of 0.001 to 0.5 g/10 min. and a density of 0.945 to 0.980 g/cm3, an adhesive layer (A2) comprising a modified etylene/&agr;-olefin copolymer (a2) which is modified by having grafted thereon an unsaturated carboxylic acid or its derivative and has a density of 0.900 to 0.940 and a barriering layer (B) comprising an ethylene/vinyl alcohol copolymer (b), wherein the Izod impact strength (with notch) (ASTM D 256, −40° C.Type: GrantFiled: April 23, 1998Date of Patent: April 10, 2001Assignee: Mitsui Chemicals, Inc.Inventors: Hideshi Kawachi, Hiromi Shigemoto, Yuichiro Terashi
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Patent number: 6214914Abstract: A compound comprising a blend of polypropylene with the reaction of a functionalized polypropylene and polyether amine in which the polyether amine is grafted into the functionalized polypropylene in a customary mixing apparatus is disclosed. The blend may include an elastomer such as EP rubber and/or a filler such as glass. A process for producing the reaction product of the functonalized polypropylene and the polyether amine by melting with polypropylene in a customary mixing apparatus is also disclosed. Blends of the present invention are advantageously useful to prepare paintable automotive body parts. A polyether monoamine that contains from about 36 to about 44 ethylene units and from about 1 to about 6 propylene units, and processes and blends using same.Type: GrantFiled: August 3, 1999Date of Patent: April 10, 2001Assignee: Huntsman Petrochemical CorporationInventors: Randall Keith Evans, Richard J. G. Dominguez, Richard J. Clark
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Patent number: 6211290Abstract: A polyolefin modified to contain a pendant polar chain structure of at least 200 molecular weight and which has at least one ester group and at least one hydroxyl and/or oxirane group is a useful adhesion-promoting modifier for polyolefin resins.Type: GrantFiled: July 7, 1999Date of Patent: April 3, 2001Assignee: GX Associates, IncInventors: Han Xiong Xiao, Mohammad Hailat
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Patent number: 6207761Abstract: A thermoplastic ionomer blend or alloy exhibiting advantageous properties upon molding or extrusion and/or thermoforming, consisting essentially of the following components: A. about 15 to 85 parts by weight of a thermoplastic copolymer containing about 91 to 80 weight percent of alpha-olefin units and about 9 to 20 weight percent of alpha, beta-ethylenically unsaturated carboxylic acid units said carboxylic acid units being about 20 to 90 percent neutralized with metal ions, preferably zinc, B. about 10 to 80 parts by weight of a rubber, preferably a thermoplastic elastomer selected from the group consisting of (a) crosslinked ethylene-propylene-diene copolymers and equivalent polyolefin copolymers such as ethylene-butene, hexene, or octene, (b) acrylonitrile-butadiene copolymers, (c) styrene-butadiene copolymers, and (d) styrene acrylonitrile graft-crosslinked butadiene rubbers, and C.Type: GrantFiled: March 18, 1999Date of Patent: March 27, 2001Assignee: A. Schulman, Inc.Inventors: Dennis C. Smith, Anita Shah, Alain C. Adam, Roy H. Kinsey, Brian D. Fairchild
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Patent number: 6191218Abstract: The invention is directed towards a method for improving hot tack in blown polyethylene films. Accordingly, a nucleating agent and polyethylene are combined to form a melt from which the film is blown. The method comprises forming a melt of polyethylene and a nucleating agent selected from the group consisting of dibenzylidene sorbitol, paramethyldibenzylidene sorbitol, dimethyldibenzylidene sorbitol, ethylene copolymers containing grafted maleic anhydride, ethylene copolymers containing grafted acrylic acid, and mixtures thereof. Polyethylene films having increased hot tack can be blown therefrom.Type: GrantFiled: July 14, 1998Date of Patent: February 20, 2001Assignee: Exxon Research and Engineering CompanyInventor: Arnold Lustiger
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Patent number: 6183863Abstract: An adhesive ethylene copolymer resin composition blend of a modified ethylene/&agr;-olefin copolymer obtained by graft-modifying an unmodified linear ethylene/&agr;-olefin copolymer comprising ethylene and an a-olefin of 3 to 20 carbon atoms with an unsaturated carboxylic acid or its derivative, or the unmodified ethylene/&agr;-olefin copolymer and the modified ethylene/&agr;-olefin copolymer and an olefin elastomer (F) The linear ethylene/&agr;-olefin copolymer being prepared by the use of an olefin polymerization catalyst including a Group IV transition metal compound (a) containing a ligand having cyclopentadienyl skeleton and an organoaluminum oxy-compound (b). The adhesive ethylene copolymer resin composition can be used as a layer to form a laminate with a layer of a polar material or a layer of a metal. The polar material layer can be a layer of an ethylene/vinyl alcohol copolymer, a layer of a polyamide or a layer of a polyester.Type: GrantFiled: May 12, 1997Date of Patent: February 6, 2001Assignee: Mitsui Chemical IncInventors: Hideshi Kawachi, Yuji Sawada, Haruhiko Tanaka
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Patent number: 6180251Abstract: A thermoplastic resin having such a sufficient heat shock resistance that it is unbroken by common temperature changes and also exhibiting an excellent flame resistance when applied to an insert molded article, which is obtained by blending a thermoplastic polyester resin (A) with 1-25% by weight to the total amount of the composition of an impact resistance giving agent (B), 1-50% by weight to the total amount of the composition of an inorganic filler (C), 1-25% by weight to the total amount of the composition of a flame retardant (D) and 0.1-10% by weight to the total amount of the composition of an aromatic polyvalent carboxylate (E).Type: GrantFiled: March 22, 2000Date of Patent: January 30, 2001Assignee: Polyplastics Co. Ltd.Inventors: Hiroyuki Kanai, Kei Aoki, Toru Katsumata
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Patent number: 6177515Abstract: A polymer composition with improved scratch and mar resistance contains (1) a graft copolymer comprising a backbone of a propylene polymer material having graft polymerized thereto at least one vinyl monomer capable of being polymerized by free radicals, and (2) an additive selected from the group consisting of (a) about 0.5% to about 10% of at least one low molecular weight ethylene polymer or a functionalized derivative thereof, and (b) a combination of (i) about 0.5% to about 10% of at least one of the low molecular weight ethylene polymers in (a) and (ii) about 0.5% to about 10% of inorganic microspheres, based on the total weight of the composition. Optionally the composition can also contain a compatibilizing agent such as an unsaturated carboxylic acid-functionalized propylene polymer material.Type: GrantFiled: December 17, 1998Date of Patent: January 23, 2001Assignee: Montell Technology Company BVInventors: Jeanine A. Smith, Dominic A. Berta, Nitya P. Khasat, Jay S. Rosenthal
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Patent number: 6166132Abstract: Directly paintable polymer compositions contain (1) a thermoplastic olefin, (2) a maleic anhydride-grafted propylene homopolymer or random copolymer, (3) a maleic anhydride-grafted olefin polymer material, (4) a functionalized polymer that reacts with the maleic anhydride groups of the grafted polymers, and, optionally, (5) a maleic anhydride-grafted ethylene polymer. The amount of (2)+(3) or (2)+(3)+(5) is at least 16 parts but less than 27 parts per hundred parts of the thermoplastic olefin.Type: GrantFiled: July 2, 1999Date of Patent: December 26, 2000Assignee: Montell North America Inc.Inventor: Dominic A. Berta
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Patent number: 6162852Abstract: A hot alkaline liquid soluble or dispersable composition made from a first polymer of an ethylene-acrylic acid copolymer having an acrylic acid portion, an ethylene-methacrylic acid copolymer having a methacrylic acid portion, or a mixture thereof, where the acrylic acid portion and the methacrylic acid portion each, independently, comprise from 10 to 30 wt. % of the total copolymer weight and also including an Ionomer-type copolymer having an acrylic acid portion, a methacrylic acid portion, or a combination thereof, comprising from 10 to 30 wt. % of the total Ionomer copolymer weight. Methods of making articles from such compositions. Methods of disposal of such compositions in hot liquid and alkaline conditions.Type: GrantFiled: September 4, 1997Date of Patent: December 19, 2000Assignee: Isolyser Company, Inc.Inventors: Travis W. Honeycutt, Baosheng Lee, Feng Qin, Robert S. Woody
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Patent number: 6156841Abstract: The present invention relates to 4-methyl-1-pentene polymer compositions. Specifically, the present invention relates to adhesive compositions comprising the 4-methyl-1-pentene polymers used in bonding a 4-methyl-1-pentene polymer layer and a polar-group-containing resin layer, and laminates obtained by using such compositions. The 4-methyl-1-pentene polymer compositions as these adhesive compositions comprise a 4-methyl-1-pentene polymer (A); and a modified polyolefin resin (B) comprising a mixture of an unsaturated carboxylic acid-modified .alpha.-olefin polymer (B-1) whose .alpha.-olefin is selected from a group of propylene, butene-1 and 4-methyl-1-pentene and an unsaturated carboxylic acid-modified ethylene/.alpha.-olefin copolymer (B-2). In these compositions, an unsaturated carboxylic acid-modified 4-methyl-1-pentene polymer (A') showing a particular modification rate and a particular melt flow rate may be used in place of (A) and (B-1).Type: GrantFiled: August 7, 1998Date of Patent: December 5, 2000Assignee: Mitsui Chemicals, Inc.Inventors: Katsumi Noritomi, Toshimasa Takata
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Patent number: 6153307Abstract: The present invention relates to compatibilizers useful to laminate a layer of a vinyl aromatic polymer such as polystyrene and a polyester such as PET. The compatibilizer comprises a mixture comprising 5-95 weight % of a polyester, 95-5 weight % of an impact modified polymer of a vinyl aromatic monomer such as high impact polystyrene (HIPS) and from 5 to 20 weight % of a hydrogenated block polymer of a vinyl aromatic monomer and a conjugated diolefin sometimes called SEBS.Type: GrantFiled: July 30, 1998Date of Patent: November 28, 2000Assignee: Nova Chemicals Inc.Inventor: Beth Ann Baran
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Patent number: 6143825Abstract: An adhesive composition suitable for coating onto a substrate, containing a blend of the following components:(a) a propylene polymer;(b) a high melt strength propylene polymer having a branching index of less than 0.9 or a melt tension of 3 to 28 cN; and(c) a modified propylene polymer grafted with an unsaturated compound having a polar group. Also disclosed is a coated article including (a) a primer-coated substrate, and (b) a layer of the composition applied to the primer surface of the primer-coated substrate.Type: GrantFiled: May 14, 1999Date of Patent: November 7, 2000Assignee: Montell Technology Company BVInventors: James R. Beren, Edward M. Phillips
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Patent number: 6140416Abstract: A compound comprising a blend of polypropylene with the reaction of a functionalized polypropylene and polyether amine in which the polyetheramine is grafted into the functionalized polypropylene in a customary mixing apparatus is disclosed. The blend may include an elastomer such as EP rubber and/or a filler such as glass. A process for producing the reaction product of the functionalized polypropylene and the polyether amine by melting with polypropylene in a customary mixing apparatus is also disclosed. Blends of the present invention are advantageously useful to prepare paintable automotive body parts.Type: GrantFiled: August 3, 1999Date of Patent: October 31, 2000Assignee: Huntsman Petrochemical CorporationInventors: Randall Keith Evans, Richard J. G. Dominguez, Richard J. Clark
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Patent number: 6136200Abstract: A composition for the detackification and clarification of acid and alkaline paint and lacquer waste waters and paint spray booth wastes, comprising:an inorganic-organic and/or organic adduct alloy polymer composition having the formula:A.multidot.B.sup.+ .multidot.D.sup.+wherein: A=[(SiO.sub.2 /Me.sup.I.sub.2 O).sub.u Me.sup.II.sub.m Me.sub.m.sup.III(OH).sbsp.p.sup.(SO.sbsp.4.sup.).sbsp.y.sup.(Aci) (2m+3n)-p-2y].sub.rwhere r=1 to 98% bw; u=0 to 10% bw; ##STR1## where: x=0 to 98% bw; Z is a divalent substituted or unsubstituted aliphatic, cycloaliphatic, heterocyclic or aromatic radicalD.sup.+ =(PQAM).sub.wwherew=2 to 98% b.w. of polyquaternized polymer (PQAM)Me.sub.m.sup.II is selected from the divalent cationic group comprising: Mg, Zn, Ca, and Fe.sup.2+m=0 to 5Me.sub.n.sup.III is a tri-or more valent metal selected from the group comprising: Fe, Al, and Al--Zn complexes;n=1 to 20Aci is selected from the monovalent anionic group comprising Cl.sup.-, Br.sup.-, I.sup.-, NO.sub.3 --, H.sub.2 PO.sub.4 --, CH.Type: GrantFiled: March 11, 1994Date of Patent: October 24, 2000Assignee: Polymer Research CorporationInventor: John J. Waldmann
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Patent number: 6136918Abstract: A rubber latex with its particles grown through cohesion by adding 100 weight parts of (B) a rubber latex (solid), 0.1-15 weight parts (solid) of (A) an acid group-containing latex having an average particle size of 50-500 nm prepared by polymerizing a monomer mixture comprising (a), (b), (c) and (d) [wherein (a)+(b)+(c)+(d)=100 weight %]: (a) 5-25 weight % of at least one of unsaturated acids selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid and crotonic acid, (b) 20-95 weight % of at least one of alkyl methacrylates with its alkyl group 1-12 in carbon number, (c) 0-30 weight % of at least one of alkyl acrylates with its alkyl group 1-12 in carbon number, (d) 0-40 weight % of at least one selected from the group consisting of aromatic vinyls, compounds having at least two polymerizable functional groups in a molecule and vinyl cyanides, copolymerizable with the aforementioned (a), (b) and (c) is provided.Type: GrantFiled: April 30, 1998Date of Patent: October 24, 2000Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Ikuhiro Mishima, Norito Doi, Youichi Matsumura, Shigemi Matsumoto, Shinobu Ochikoshi, Kazuhito Wada, Hiroki Yoshino
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Patent number: 6133349Abstract: Compositions which have substantial weatherability and impact resistance include a substantially uniform blend of (1) a physical mixture of an uncross-linked acrylonitrile/styrene copolymer and a cross-linked alkyl acrylate/graft (meth)acrylate copolymer; and (2) a filler component, preferably wood, in an amount effective as a filler in the composition. Methods for making such compositions include forming a substantially uniform physical blend of such copolymers and filler component. The compositions preferably are substantially free of cross-linked acrylonitrile/styrene copolymer.Type: GrantFiled: September 29, 1998Date of Patent: October 17, 2000Assignee: Hughes Processing, Inc.Inventor: Roderick E. Hughes
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Patent number: 6127480Abstract: This invention concerns a composition comprising a blend of polyolefin with the reaction of a functionalized polyolefin and polyetheramine in which the polyetheramine is grafted into the functionalized polyolefin in a customary mixing apparatus. A process for producing the reaction product of functionalized polypropylene and polyetheramine by melting with polypropylene in a customary mixing apparatus is also disclosed. Blends of the present invention are advantageously useful to prepare paintable automotive body parts. This invention further includes dyeable polyolefin compositions containing the reaction product of functionalized polyolefin and polyetheramine. Dyeable polyolefin fibers, including polypropylene fibers, are disclosed, which may be made by melt spinning, and which may be employed to make woven and non-woven fabric.Type: GrantFiled: October 19, 1999Date of Patent: October 3, 2000Assignee: Huntsman Petrochemical CorporationInventors: Richard Joseph Gilbert Dominguez, Christopher S. Henkee, Wheeler C. Crawford, Gerald W. Cummings, Kevin John Hess, Richard James Clark, Randall Keith Evans
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Patent number: 6114442Abstract: Disclosed is a chemical and heat-resistant styrene-based resin composition which uses the following as the primary resin: (A) a graft copolymer of a diene rubber component and at least two compounds selected from vinyl compounds, cyanide vinyl compounds, and maleic anhydrides; (B) a graft copolymer of an alkyl acrylate rubber component and at least two compounds selected from aromatic vinyl compounds, cyanide vinyl compounds, and maleic anhydride compounds; (C) a copolymer of styrene and a cyanide vinyl compound; (D) a copolymer of styrene, .alpha.-methylstyrene, and a cyanide vinyl compound; and (E) a copolymer of styrene, a cyanide vinyl compound, and a maleimide compound. An oil component, a lubricant, a thermal stabilizer, and an antioxidant are added at suitable ratios to the above primary resin.Type: GrantFiled: August 28, 1998Date of Patent: September 5, 2000Assignee: Hyundai Motor CompanyInventor: Soon-joon Jung
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Patent number: 6111024Abstract: Rubber-modified molding materials having improved impact strength in combination with good flow behavior can be prepared by special graft polymerization of monomers forming hard graft shells, such as styrene and acrylonitrile, in the presence of an elastomeric acrylate macromonomer copolymer dissolved or swollen in these monomers, the graft polymerization being carried out, to a conversion of more than 15% by weight of the monomers, by thermal or free radical mass or solution polymerization.Type: GrantFiled: October 8, 1998Date of Patent: August 29, 2000Assignee: BASF AktiengesellschaftInventors: Graham Edmund McKee, Bernhard Rosenau
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Patent number: 6107385Abstract: A flame-retardant resin composition, which comprises 100 parts by weight of a synthetic resin having 70 to 100% by weight of metallocene LLDPE, 20 to 100 parts by weight of a magnesium hydroxide having a BET specific surface area of 20 m.sup.2 /g or less, an average secondary particle diameter of 5 .mu.m or less, measured according to a laser diffraction scattering method, and a water-soluble sodium salt content of 500 ppm or less as a sodium, 1 to 20 parts by weight of red phosphorus having an average secondary particle diameter of 30 .mu.m or less and 0.1 to 20 parts by weight of a carbon powder, the total of the magnesium hydroxide, the red phosphorus and the carbon powder being 120 parts by weight or less.Type: GrantFiled: April 27, 1999Date of Patent: August 22, 2000Assignee: Kyowa Chemical Industry Co., Ltd.Inventor: Takeshi Imahashi
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Patent number: 6103829Abstract: Molding materials (F) which are suitable for the production of shaped articles having reduced surface gloss and are based on polymers or polymer blends (P), preferably ASA polymers and/or styrene/acrylonitrile copolymers, contain a sufficient amount of a dull graft copolymer (A) admixed as dulling agent, which was prepared by one-stage or multistage graft copolymerization of monomers forming the hard shell onto an elastomeric acrylate polymer, the graft copolymerization being carried out to a conversion of more than 15% by thermal or free radical mass or solution polymerization.Type: GrantFiled: October 8, 1998Date of Patent: August 15, 2000Assignee: BASF AktiengesellschaftInventors: Graham Edmund Mc Kee, Bernhard Rosenau, Walter Heckmann
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Patent number: 6100345Abstract: The present invention provides a thermally resistant resin composition containing PS and PPO, wherein at least one of PS and PPO has an acid group and the acid group is neutralized with a basic metal compound containing a metal element of the group 2B, 3B, 4B or 5B of the periodic table; thermally resistant PS and PPO each with an acid group which is also neutralized in the same manner as described above; and a method for miscible preparation of PS and PPO, wherein at least one of PS and PPO has an acid group and the acid group is neutralized similarly.Type: GrantFiled: October 29, 1998Date of Patent: August 8, 2000Assignee: Sony CorporationInventors: Yasuhito Inagaki, Tsutomu Noguchi, Hidemi Tomita
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Patent number: 6093773Abstract: A compound comprising a blend of polypropylene with the reaction product of a functionalized polypropylene and polyether amine in which the polyether amine is grafted onto the functionalized polypropylene in a customary mixing apparatus is disclosed. A process for producing the reaction product of the functionalized polypropylene and the polyether amine by melting with polypropylene in a customary mixing apparatus is also disclosed.Type: GrantFiled: August 3, 1999Date of Patent: July 25, 2000Assignee: Huntsman Petrochemical CorporationInventors: Randall Keith Evans, Richard Joseph Gilbert Dominguez, Richard James Clark