Mixture Contains Solid Polymer Derived From Reactant Containing Ether Or Hydroxyl Group Patents (Class 525/79)
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Publication number: 20150147550Abstract: Disclosed herein is a non-birefringent resin material that is very small in both orientation birefringence and photoelastic birefringence, has high transparency, and is capable of providing a molded article having few foreign matter defects and a film made of such a material. The non-birefringent resin material contains a resin (A) and a polymer (B) and has an orientation birefringence of ?1.7×10?4 to 1.7×10?4 and a photoelastic constant of ?4×10?12 to 4×10?12 Pa?1.Type: ApplicationFiled: June 26, 2013Publication date: May 28, 2015Inventors: Fuminobu Kitayama, Nobuyoshi Maizuru, Keisuke Hatano
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Patent number: 8851084Abstract: The present invention relates to compositions comprising a blend of cellulose acetate and a water soluble polymer. In some embodiments, the composition is water dispersive and/or biodegradable. Embodiments of the invention also relate to processes for preparing such compositions, and to materials and products including such compositions.Type: GrantFiled: July 18, 2012Date of Patent: October 7, 2014Assignee: British American Tobacco (Investments) LimitedInventors: Yahia Lemmouchi, Robert Quintana, Olivier Persenaire, Leila Bonnaud, Philippe Dubois
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Patent number: 8835526Abstract: The present invention provides optic portions, intraocular lenses, and polymers for use in manufacturing optic portions and intraocular lenses. The optic portions include a polymer that comprises (a) one or more alkoxyalkyl methacrylate monomers and/or one or more alkoxyalkyl acrylate monomers that are incorporated in the polymer; (b) one or more hydroxyalkyl methacrylate monomers and/or one or more hydroxyalkyl acrylate monomers that are incorporated in the polymer; and (c) optionally, one or more crosslinking agents that are incorporated in the polymer.Type: GrantFiled: November 19, 2012Date of Patent: September 16, 2014Assignee: Benz Research and Development CorporationInventors: Patrick H. Benz, Jose A. Ors
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Patent number: 8816005Abstract: The present invention provides a method for making a composition comprising an amphiphilic polymeric material which comprises a straight or branched chain carbon-carbon backbone and a multiplicity of side chains attached to the backbone; wherein in the method, backbone precursors comprising acylating groups are mixed with side chain precursors which comprise a nucleophilic group at at least one terminus, to form a reaction mixture; the backbone precursors, side chain precursors and/or the reaction mixture are heated; the reaction mixture is stirred; and the nucleophilic groups react with the acylating groups to form the amphiphilic polymeric material wherein the side chains are linked to the backbone via acyl linkages; characterized in that the reaction mixture does not comprise organic solvent.Type: GrantFiled: October 15, 2008Date of Patent: August 26, 2014Assignee: Revolymer LimitedInventors: Terence Cosgrove, Roger Pettman, Erol Hasan
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Patent number: 8703293Abstract: Provided herein re a composition and a coating or a device (e.g., absorbable stent) that includes a PEGylated hyaluronic acid and a PEGylated non-hyaluronic acid biocompatible polymer and the methods of use thereof.Type: GrantFiled: April 1, 2010Date of Patent: April 22, 2014Assignee: Advanced Cardiovascular Systems, Inc.Inventors: Lothar W. Kleiner, Connie S. Kwok
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Patent number: 8703869Abstract: The invention relates to impact-modified polycarbonate compositions which are distinguished by high heat resistance and good melt flow behavior. In addition, the moldings produced from the compositions according to the invention in an injection-molding process can be metallised, the resulting metallised moldings having a surface with a particularly high and, in particular, homogeneous gloss. The invention thus also provides the metallised moldings produced from the compositions according to the invention.Type: GrantFiled: March 23, 2010Date of Patent: April 22, 2014Assignee: Bayer Materialscience AGInventors: Andreas Seidel, Eckhard Wenz, Hans-Jü{umlaut over ( )}rgen Klankers
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Publication number: 20130289198Abstract: The present invention relates to a rubber-modified vinyl-based graft copolymer to which acrylic monomers containing a phenyl or phenoxy group are grafted in order to increase compatibility with a polycarbonate resin, and also relates to a thermoplastic resin composition including the rubber-modified vinyl-based graft copolymer. The thermoplastic resin composition according to the present invention can significantly improve appearance and high fluidity and can have high flowability and chemical resistance.Type: ApplicationFiled: June 26, 2013Publication date: October 31, 2013Inventors: Ki Bo CHANG, Jun Hwan AHN, Sung Il MYUNG
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Patent number: 8562836Abstract: The present invention relates to synthetic methods for grafting hydrophilic chains onto polymers, particularly hydrophobic polymers such as poly(vinyl chloride) (PVC), poly(vinylidene fluoride) (PVDF), and chlorinated polypropylene (cPP). Resulting polymers include comb polymers which can have a microphase-separated structure of hydrophilic domains provided by the hydrophilic chains. Articles prepared from these comb polymers, particularly derived from PVDF, include membranes for water filtration in which the hydrophilic domains provide a pathway for water transport. PVC can be plasticized by grafting the PVC with hydrophilic chains. In addition, such articles, particularly articles having biomedical applications, can display anti-thrombogenic properties.Type: GrantFiled: November 30, 2010Date of Patent: October 22, 2013Assignee: Massachusetts Institute of TechnologyInventors: Jonathan F. Hester, Pallab Banerjee, Ariya Akthakul, Glenn C. Mailand
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Patent number: 8557920Abstract: The present invention relates to a polymer composition, comprising (i) a polypropylene homopolymer, (ii) a polypropylene random copolymer, prepared by copolymerization of propylene with an olefin comonomer and having an amount of olefin comonomer units of 0.2 to 5 wt %, and (iii) an elastomeric copolymer of propylene and at least one olefin comonomer, the polymer composition having a tensile modulus, determined according to ISO 527-2/1 B at 1 mm/min. and 230 C, of at least 1200 MPa.Type: GrantFiled: May 11, 2006Date of Patent: October 15, 2013Assignee: Borealis Technology OyInventors: Kauno Alastalo, Carl-Gustaf Ek, Bo Malm, Ulf Torgersen, Olli Tuominen
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Patent number: 8552112Abstract: The present invention provides a weather resistant thermoplastic resin with low gloss and a method of preparing the same. The thermoplastic resin of the present invention comprises a (meth)acrylic acid alkyl ester-based polymer (A) and a (meth)acrylic acid alkyl ester-based oligomeric prepolymer (B), and an aromatic vinyl-cyanide vinyl based copolymer (C), wherein the (meth)acrylic acid alkyl ester-based polymer (A) and the (meth)acrylic acid alkyl ester-based oligomeric prepolymer (B) form a network-shaped disperse phase and the aromatic vinyl-cyanide vinyl based copolymer (C) forms a continuous phase.Type: GrantFiled: December 29, 2010Date of Patent: October 8, 2013Assignee: Cheil Industries Inc.Inventors: So Young Kwon, Young Sub Jin, Sung Kwan Kim, Byeong Do Lee
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Patent number: 8541502Abstract: A polyolefin compound including: A) at least one thermoplastic olefin copolymer including the reaction product of olefin 1 and olefin 2, wherein: olefin 1 is a C2 based olefin and olefin 2 is a C3 to C8 ?-olefin or olefin 1 is a C3 based olefin and olefin 2 is a C4 to C8 ?-olefin; B) at least one functional polymer, the functional polymer content in the polyolefin compound being between 1 and 75 weight percent of the combined components A and B; wherein the thermoplastic olefin copolymer and the functional polymer form a co-continuous phase; wherein: a) an 12 melt index of the polyolefin compound is from about 1 to about 15 as measured using ASTM D 1238; b) a Shore A hardness of the polyolefin compound is from about 55 to about 100 as measured using ASTM D2240; c) a flexural modulus of the polyolefin compound is from about 0.8 to about 30 kpsi as measured using ASTM D790.Type: GrantFiled: May 29, 2009Date of Patent: September 24, 2013Assignee: Dow Global Technologies LLCInventors: Felipe Martinez, Pankaj Gupta, Ashish Batra
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Patent number: 8513355Abstract: Disclosed is a graft copolymer highly improving the adhesion resistance and impact strength, a method of preparing the same, and PVC composition containing the same, wherein the graft copolymer comprises i) 55 to 85 wt % of a conjugated diene-based rubber core; and ii) 15 to 45 wt % of a graft shell surrounding the rubber core, and formed by comprising a (meth)acrylate-based monomer, and at least one selected from the group consisting of a vinyl-based monomer having a polyalkylene oxide group represented by the following Formula 1; in which the graft copolymer includes 0.1 to 5 wt % of the vinyl-based monomer having the polyalkylene oxide group represented by the following Formula 1: wherein R is independently hydrogen, or C1 to C4 alkyl group, and n is independently 3 to 14.Type: GrantFiled: August 27, 2010Date of Patent: August 20, 2013Assignee: LG Chem, Ltd.Inventors: Yoon Ho Kim, Geon Soo Kim, Yeon Hwa Wi, Ki Hyun Yoo, Chan Hong Lee
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Patent number: 8420736Abstract: An object of the present invention is to provide a thermoplastic resin composition capable of improving impact resistance and surface gloss of a molded article, and a molded article thereof. A thermoplastic resin composition of the present invention is comprising 100 parts by weight of a thermoplastic resin (a) and 0.5 to 30 parts by weight of a core-shell polymer composition (b), wherein the core-shell polymer composition (b) is obtained by polymerizing the shell-constituting components in the presence of a core obtained by polymerizing a monomer mixture (100% by weight in total) of 70% to 99.95% by weight of an alkyl acrylate having an alkyl group of 2 to 18 carbon atoms, 0.05% to 10% by weight of a polyfunctional monomer, and 0% to 20% by weight of a monomer copolymerizable with the alkyl acrylate and the polyfunctional monomer, and the polyfunctional monomers contains at least a compound having a plurality of same radically polymerizable functional groups in the molecule thereof.Type: GrantFiled: June 25, 2010Date of Patent: April 16, 2013Assignee: Kaneka CorporationInventors: Fuminobu Kitayama, Kouhei Fujimoto, Yuya Manabe
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Patent number: 8389628Abstract: The present invention provides a thermoplastic resin composition that can have excellent impact resistance, chemical resistance, fluidity and high gloss, which comprises about 1 to about 80 parts by weight of a styrene-acrylonitrile resin (A) including one or more functional groups capable of reacting with polyester; about 1 to about 98 parts by weight of an acrylonitrile-butadiene-styrene resin (B) including about 5 to about 40% by weight of a graft polymerized acrylonitrile-butadiene-styrene resin (B1) and about 60 to about 95% by weight of a styrene-acrylonitrile resin (B2) and including about 20% by weight or less of acrylonitrile; and about 1 to about 98 parts by weight of a polyester resin (C), wherein the resin composition comprises acrylonitrile in a total amount of about 1 to about 13% by weight.Type: GrantFiled: December 28, 2009Date of Patent: March 5, 2013Assignee: Cheil Industries Inc.Inventors: Jee Kwon Park, Jin Hwan Choi, Kang Yeol Park, Jun Myung Kim, Jae Won Lee
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Patent number: 8367766Abstract: A tire with a rubber containing component compound of a copolymer rubber having pendant hydroxyl groups; and a non-sulfur containing silane.Type: GrantFiled: December 11, 2008Date of Patent: February 5, 2013Inventors: Georges Marcel Victor Thielen, Frank Schmitz
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Patent number: 8349949Abstract: Non cross-linked modifiers for thermoplastic alloys comprising from 20 to 80% by weight based on the modifier of an interpolymer of ethylene and an alpha-olefin having from 4 to 12 carbon atoms grafted with an acid functionality, preferably maleic anhydride, having a Melt Index of from 0.3 to 100 and a density of 0.85 to 0.91 prior to being grafted and from 80 to 20% by weight of an ungrafted diene containing interpolymer derived from ethylene and an alpha-olefin having from 3 to 12 carbon atoms and an amount of a cross-linking component effective to provide cross-linking during subsequent melt blending with a condensation polymer having a melting point of at least 150° C.Type: GrantFiled: May 18, 2005Date of Patent: January 8, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Jean-Roch Schauder, Guy Joseph Wouters
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Patent number: 8318832Abstract: The present invention provides optic portions, intraocular lenses, and polymers for use in manufacturing optic portions and intraocular lenses. The optic portions include a polymer that comprises (a) one or more alkoxyalkyl methacrylate monomers and/or one or more alkoxyalkyl acrylate monomers that are incorporated in the polymer; (b) one or more hydroxyalkyl methacrylate monomers and/or one or more hydroxyalkyl acrylate monomers that are incorporated in the polymer; and (c) optionally, one or more crosslinking agents that are incorporated in the polymer.Type: GrantFiled: May 23, 2008Date of Patent: November 27, 2012Assignee: Benz Research and Development CorporationInventors: Patrick H. Benz, Jose A. Ors
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Patent number: 8211977Abstract: Polymer compositions with adhesive properties comprising: (1) at least one fluoropolymer (A) grafted by at least one compound (a), wherein the compound (a) contains at least one functional group (f1) capable of conferring adhesion properties on the fluoropolymer; (2) at least one olefin polymer (B) grafted by at least one compound (b), wherein the compound (b) contains at least one functional group (f2) capable of conferring adhesion properties on the olefin polymer and of reacting with the functional group (f1) contained in the compound (a); and (3) at least one polymer (C) chosen from polyesters and polyamides.Type: GrantFiled: June 26, 2007Date of Patent: July 3, 2012Assignee: Solvay (Societe Anonyme)Inventors: Henri Wautier, Fernand Gauthy
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Publication number: 20110082256Abstract: A polyolefin compound including: A) at least one thermoplastic olefin copolymer including the reaction product of olefin 1 and olefin 2, wherein: olefin 1 is a C2 based olefin and olefin 2 is a C3 to C8 ?-olefin or olefin 1 is a C3 based olefin and olefin 2 is a C4 to C8 ?-olefin; B) at least one functional polymer, the functional polymer content in the polyolefin compound being between 1 and 75 weight percent of the combined components A and B; wherein the thermoplastic olefin copolymer and the functional polymer form a co-continuous phase; wherein: a) an 12 melt index of the polyolefin compound is from about 1 to about 15 as measured using ASTM D 1238; b) a Shore A hardness of the polyolefin compound is from about 55 to about 100 as measured using ASTM D2240; c) a flexural modulus of the polyolefin compound is from about 0.8 to about 30 kpsi as measured using ASTM D790.Type: ApplicationFiled: May 29, 2009Publication date: April 7, 2011Applicant: DOW GLOBAL TECHNOLOGIES INC.Inventors: Felipe Martinez, Pankaj Gupta, Ashish Batra
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Patent number: 7897654Abstract: In one aspect, the invention relates to silicone prepolymer compositions comprising a silicone prepolymer and a solvent. A soluble silicone prepolymer can be provided having increased average silicon content, thereby attaining a desired oxygen permeability. A solvent can be provided with a desired balance between hydrophilicity and hydrophobicity by selection and modification of the solvent molecular structure, resulting in molded polymer films and articles that exhibit minimal or nonexistent eye irritation and exhibit highly transparent products. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.Type: GrantFiled: April 1, 2008Date of Patent: March 1, 2011Assignees: Johnson & Johnson Vision Care Inc., Toray Industries Inc.Inventors: Kazuhiko Fujisawa, Mitsuru Yokota, Masataka Nakamura
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Patent number: 7893165Abstract: There are provided in accordance with embodiments of the invention metal-containing inorganic block copolymers, structures formed by self-assembly of such copolymers, and metal-containing ceramics which may be formed from such copolymers and/or structure. Methods for making such copolymers, structures and ceramics are also provided. Other embodiments are also disclosed.Type: GrantFiled: August 11, 2006Date of Patent: February 22, 2011Assignee: General Electric CompanyInventors: Patrick Roland Lucien Malenfant, Andrea Peters, Julin Wan
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Patent number: 7847021Abstract: A modified polyolefin resin comprising a copolymer having a structure that a propylene-based polyolefin segment (a) and a segment (b) containing a lactic acid as a constituent are bonded in a block state and/or a graft state through a vinyl monomer having a hydroxyl group, wherein a number average molecular weight of the propylene-based polyolefin segment (a) is from 1,000 to 100,000, a number average molecular weight of the segment (b) containing lactic acid as a constituent is from 1,000 to 200,000, and a weight composition of the propylene-based polyolefin segment (a) and the segment (b) containing lactic acid as a constituent is from 10/90 to 90/10. The modified polyolefin resin can be used in a resin composition containing an aliphatic polyester resin (A), a polyolefin resin (B) and the modified polyolefin resin (C). The composition can exhibit excellent heat resistance and impact resistance and can be used for molding various parts.Type: GrantFiled: February 9, 2005Date of Patent: December 7, 2010Assignee: Mitsui Chemicals, Inc.Inventors: Hosei Shinoda, Takeshi Kashima, Masahiro Enna, Shinichi Kojoh, Hideyuki Kaneko, Shingo Matsuo, Nobuo Kawahara, Tomoaki Matsugi, Yuichi Matsuda, Takayuki Onogi, Fumio Kageyama
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Patent number: 7838156Abstract: A thickener for use in an alkaline battery provides a gel viscosity ratio (N1h/N12h) of 0.7 to 1.3, the gel viscosity ratio (N1h/N12h) being a ratio of a viscosity (N1h) of a gel after being left to stand for one hour to a viscosity (N12h) of the gel after being left to stand for twelve hours (where the gel viscosity is a viscosity of a gel composed of 2.0 parts by weight of the thickener, 200 parts by weight of zinc powder, and 100 parts by weight of 37 wt % aqueous solution of potassium hydroxide, measured at 40° C. according to JIS K7117-1: 1999). An alkaline battery having a negative electrode gel in which the thickener of the present invention is used is provided. The alkaline battery exhibits improved long-term retention of discharge characteristics (discharge amount and discharge time), and improved impact resistance.Type: GrantFiled: September 6, 2005Date of Patent: November 23, 2010Assignee: Sanyo Chemical Industries, Ltd.Inventors: Kazuya Ohtani, Takeaki Yamaguchi
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Publication number: 20100266837Abstract: The invention relates to multiphase compositions of matter comprising at least an acrylic phase and a hydrocarbon phase, and more specifically to pressure sensitive adhesive compositions of matter of an acrylic-hydrocarbon polymer and an additional hydrocarbon component which has a molecular weight of at least 1,000 and may include one or both of an oligomeric hydrocarbon and a polymeric hydrocarbon.Type: ApplicationFiled: February 12, 2010Publication date: October 21, 2010Applicant: AVERY DENNISON CORPORATIONInventors: Nagarajan SRIVATSAN, Prakash MALLYA, Daniel L. HOLGUIN, Dominique WOUTERS, Eric L. BARTHOLOMEW, Liza P. LOFTON
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Patent number: 7745362Abstract: There are provided in accordance with embodiments of the invention metal-containing inorganic block copolymers, structures formed by self-assembly of such copolymers, and metal-containing ceramics which may be formed from such copolymers and/or structure. Methods for making such copolymers, structures and ceramics are also provided. Other embodiments are also disclosed.Type: GrantFiled: August 11, 2006Date of Patent: June 29, 2010Assignee: General Electric CompanyInventors: Patrick Roland Lucien Malenfant, Andrea Peters, Julin Wan
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Patent number: 7723434Abstract: An olefinic thermoplastic elastomer with improved properties can be obtained by melting and kneading a graft copolymer, acrylic rubber, a crosslinking agent, and a co-crosslinking agent. The graft copolymer is composed of an olefin polymer segment formed from a nonpolar ?-olefin monomer and a vinyl polymer segment formed from a vinyl monomer, with particles of one segment being dispersed in the other segment. The particle diameter is 0.01 to 1 ?m. The acrylic rubber can be obtained by polymerizing a monomer mixture containing methoxyethyl acrylate.Type: GrantFiled: March 27, 2003Date of Patent: May 25, 2010Assignee: Nof CorporationInventors: Motoyuki Sugiura, Toru Tamura, Takamitsu Kano, Toru Kato
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Patent number: 7709574Abstract: The present invention is generally directed to methods of making ceramics with nanoscale/microscale structure involving self-assembly of precursor materials such as, but not limited to, inorganic-based block co-polymers, inorganic-/organic-based hybrid block co-polymers, and other similar materials, and to the structures made by such methods. Where such precursor materials are themselves novel, the present invention is also generally directed to those materials and their synthesis.Type: GrantFiled: July 18, 2006Date of Patent: May 4, 2010Assignee: General Electric CompanyInventors: Julin Wan, Patrick Roland Lucien Malenfant, Mohan Manoharan
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Patent number: 7674855Abstract: A thermoplastic molding composition having improved melt flow and chemical resistance is disclosed. The composition contains A) at least one member selected from the group consisting of aromatic polycarbonate and polyester carbonate, B) a graft polymer of at least one vinyl monomer on at least one rubber having a glass transition temperature of <10° C. as graft base and C) vinyl (co)polymer having weight-average molecular weight of 1500 to 5000 g/mol and glass transition temperature of >40° C. The composition may optionally further contain D) a phosphorus-based flame retardant and E) an anti-dripping agent.Type: GrantFiled: June 18, 2004Date of Patent: March 9, 2010Assignee: Bayer MaterialScience AGInventors: Andreas Seidel, Thomas Eckel, Marc Vathauer
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Patent number: 7662538Abstract: A process for preparing a blocked derivatized poly(4-hydroxystryrene)-DPHS having a novolak type structure which comprises the steps of (i) supplying a solution of methanol containing 4-hydroxyphenylmethylcarbinol, (ii) subjecting said solution to an acid catalyzed displacement reaction for a sufficient period of time and under suitable conditions of temperature and pressure to convert substantially all of said carbinol to 4-hydroxyphenylmethylcarbinol methyl ether in solution, (iii) polymerizing said ether containing solution in the presence of a suitable acid catalyst for a sufficient period of time and under suitable conditions of temperature and pressure to form a novolak type polymer; and (iv) reacting said polymer with a vinyl ether, a dialkyl dicarbonate, or a mixture of vinyl ether and a dialkyl dicarbonate to form the blocked DPHS.Type: GrantFiled: October 13, 2005Date of Patent: February 16, 2010Assignee: Du Pont Electronic Polymers L.P.Inventors: Michael T. Sheehan, Edward G. Zey, Hiroshi Okazaki
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Patent number: 7534846Abstract: Onium-modified polymers, such as polyethers and alkylimidazolium-modified polymers are provided. The polymers have desirable properties such as moisture absorbing capability, low volatile organic compounds (VOCs) emission, and enhanced electrical conductivity. A method to prepare the polymers is also provided, in which green solvents such as ionic liquids are utilized as both reaction media and reactants.Type: GrantFiled: May 11, 2005Date of Patent: May 19, 2009Assignee: Bridgestone CorporationInventors: Xiaorong Wang, Victor J. Foltz, David F. Lawson
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Patent number: 7528194Abstract: The present invention relates to the modification of copolymers, in particular of grafted copolymers into comb copolymers. The modification comprises the steps (i) of controlled radical polymerization of a polymer or copolymer bearing a epoxide group at one end resulting from the initiation step, and (ii) a heating step of the polymer prepared under (i) and a copolymer bearing a functional group either in the backbone or attached to a side chain, which is able to react with the epxide group. The result is a comb copolymer with well controlled chain length of the grafted side arms expressed for example by a low polydispersity.Type: GrantFiled: February 2, 2004Date of Patent: May 5, 2009Assignee: Ciba Specialty Chemicals Corp.Inventors: Jochen Fink, Michael Roth, Rudolf Pfaendner
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Publication number: 20090086319Abstract: The present invention provides an optical film that includes i) a (meth)acrylic resin, and 5 to 45 parts by weight of ii) a graft copolymer, prepared by grafting a (meth)acrylic resin onto a copolymer of (meth)acrylic rubber and aromatic vinyl compound, based on 100 parts by weight of the i) (meth)acrylic resin, and an electronic device including the optical film.Type: ApplicationFiled: October 1, 2008Publication date: April 2, 2009Applicant: LG Chem, Ltd.Inventors: Tae-Bin Ahn, Yong-Yeon Hwang, Min-Jung Kim, Jae-Hyun Jeong, Ki-Heon Song
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Patent number: 7488775Abstract: A thermoplastic resin composition comprising 10 to 98 parts by weight of a graft polymer (1A) containing a rubber-like polymer (1G) having a diene unit content of 50% by weight or less, 2 to 50 parts by weight of a hydroxyl group-containing acrylic copolymer (1B) and 0 to 80 parts by weight of other thermoplastic resin (1F), wherein the rubber-like polymer (1G) is at least one selected from the group consisting of a diene-based rubber, a polyorganosiloxane-based rubber and an olefin-based rubber; and, a graft copolymer (2A) obtained by grafting a vinyl-based polymer to a (meth)acrylate-based rubber-like polymer (2G) expansion-treated with an acid group-containing copolymer latex (2K) wherein the (meth)acrylate-based rubber-like polymer contains two or more poly-functional monomer units.Type: GrantFiled: December 21, 2001Date of Patent: February 10, 2009Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Yoshihiro Nakai, Hideyuki Shigemitsu
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Patent number: 7476708Abstract: A tire with a rubber containing component compound of a copolymer rubber having pendant hydroxyl groups; and a non-sulfur containing silane.Type: GrantFiled: December 21, 2006Date of Patent: January 13, 2009Assignee: The Goodyear Tire & Rubber CompanyInventors: Georges Marcel Victor Thielen, Frank Schmitz
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Publication number: 20080289850Abstract: An electrical wire and a method of making an electrical wire are disclosed. The electrical wire comprises a conductor and a covering. The covering comprises a thermoplastic composition comprising a poly(arylene ether), a polyolefin and a polymeric compatibilizer. The thermoplastic composition may further comprise a flame retardant.Type: ApplicationFiled: November 29, 2005Publication date: November 27, 2008Applicant: GENERAL ELECTRIC COMPANYInventors: Vijay R. Mhetar, Vijay Rajamani, Kristopher Rexius, Sho Sato, Xiangyang Tai
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Patent number: 7425322Abstract: A responsive polymeric system including a responsive polymeric component capable of undergoing a transition that results in a sharp increase in viscosity in response to a triggering effected at a predetermined body site. The system includes a solid non-ceramic reinforcing component which reinforces the polymeric component, and an aqueous-based solvent wherein the viscosity of the responsive polymeric component increases by at least about 2 times upon exposure to a predetermined trigger.Type: GrantFiled: September 24, 2004Date of Patent: September 16, 2008Assignee: Yissum Research Development Company of the Hebrew University of JerusalemInventors: Daniel Cohn, Alejandro Sosnik
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Publication number: 20080188821Abstract: Water-absorbing polymeric particles are produced by spray polymerization of a monomer solution in a process wherein the monomer solution is spray dispensed and at least one crosslinker accumulates in the region of the droplet surface, and are useful in hygiene articles.Type: ApplicationFiled: January 14, 2006Publication date: August 7, 2008Applicant: Basf AktiengesellschaftInventors: Dennis Losch, Volker Seidl, Uwe Stueven
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Patent number: 7295376Abstract: A pseudo cross-link type resin composition made of one of resins or a mixture of the resins; wherein the resin is obtained by mixing a polymer molecule that has an atomic group capable of forming an intermolecular hydrogen bond at least in a molecular side chain or at a molecular tail end of the polymer molecule, and a polymer molecule that has an atomic group capable of forming an intermolecular hydrogen bond at lest in a molecular side chain or in a molecular skeleton of the polymer molecule; wherein the polymer molecule having an atomic group capable of forming an intermolecular hydrogen bond at least in a molecular side chain or at a molecular tail end is a vinylic polymer or a copolymer thereof that has a carboxyl group or a hydroxyl group at least in a molecular side chain or at a molecular tail end, and the polymer molecule that has an atomic group capable of forming an intermolecular hydrogen bond at least in a molecular side chain or in a molecular skeleton is a vinylic polymer or a copolymer thereofType: GrantFiled: January 22, 2004Date of Patent: November 13, 2007Assignee: Hitachi Chemical Company, Ltd.Inventors: Tetsuro Yamanaka, Yukihiko Yamashita, Kenji Kanemaru
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Patent number: 7135529Abstract: The invention provides golf balls with a core and with one or more layers, preferably cover layers, formed of a saturated rubber/ionomer block copolymer comprising one or more neutral thermoplastic polymer blocks and one or more ionomeric blocks. The saturated rubber block is preferably polyisobutylene, and the ionomer block may be a cationomer block or an anionomer block. Various block cationomers comprising polyisobutylene (PIB) and poly(2-dimethylamino)ethyl methacrylate) (PDMAEMA) are preferred. The golf balls of the present invention have been found to provide improved scuff resistance while providing a greater coefficient of friction for improved spin and feel properties.Type: GrantFiled: August 9, 2004Date of Patent: November 14, 2006Assignee: Acushnet CompanyInventor: Michael J. Sullivan
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Patent number: 7022765Abstract: A poly(arylene ether)-polyolefin composition is prepared by melt-blending a poly(arylene ether) and a compatibilizer to form a first blend, and melt-blending the first blend and a polyolefin to form a second blend. The composition lacks an unhydrogenated block copolymer, a poly(alkenyl aromatic) resin, or both. Multiple mixing elements, low throughput, and high extruder rotations per minute may be used to achieve high energy mixing of the first and second blends. Compositions prepared by the method exhibit an improved balance of impact strength, stiffness, and heat resistance, as well as reduced variability of physical properties.Type: GrantFiled: January 9, 2004Date of Patent: April 4, 2006Assignee: General ElectricInventors: Adeyinka Adedeji, Thomas J. Hartle
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Patent number: 6923986Abstract: Gel-forming macromers including at least four polymeric blocks, at least two of which are hydrophobic and at least one of which is hydrophilic, and including a crosslinkable group are provided. The macromers can be covalently crosslinked to form a gel on a tissue surface in vivo. The gels formed from the macromers have a combination of properties including thermosensitivity and lipophilicity, and are useful in a variety of medical applications including drug delivery and tissue coating.Type: GrantFiled: August 27, 2003Date of Patent: August 2, 2005Assignee: Genzyme CorporationInventors: Chandrashekhar P. Pathak, Shikha P. Barman, C. Michael Philbrook, Amarpreet S. Sawhney, Arthur J. Coury, Luis Z. Avila, Mark T. Kieras
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Patent number: 6872776Abstract: A vinyl chloride resin composition having excellent weatherability and impact resistance which comprises (a) a vinyl chloride resin, (b) a graft copolymer which is obtained by graft-polymerizing (b2) a graft monomer component composed of 40 to 100% by weight of methyl methacrylate and 0 to 60% by weight of at least one monomer selected from the group consisting of an alkyl acrylate, an alkyl methacrylate, an unsaturated nitrile and an aromatic vinyl compound onto (b1) a crosslinked elastomeric polymer composed mainly of an alkyl acrylate, the methyl ethyl ketone-soluble portion of the graft copolymer having an ?sp/c of 1 to 5 measured at 30° C. with respect to its 0.2 g/100 cc acetone solution, and (c) calcium carbonate; and molded articles having a multilayer structure wherein a layer molded from the above composition is used as the surface layer or the inner layer.Type: GrantFiled: May 31, 1999Date of Patent: March 29, 2005Assignee: Kaneka CorporationInventors: Hirokazu Iguchi, Kazunori Saegusa, Satoshi Mizunuma, Akira Takaki
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Patent number: 6872775Abstract: A compound for a composite body having a hard and a soft component, and to a process for producing such a composite body is provided. The compound comprises a hard component (a) of a polyoxymethylene and a soft component (b) of one or more hydrogenated styrene block copolymers, molded directly onto component (a). The styrene block copolymers are from the group of poly-isoprene/butadiene polymer (SEEPS), poly-isoprene polymer (SEPS); poly-butadiene polymer (SEBS), and combinations thereof. The styrene block copolymer is adhesion-modified by the addition of a compound selected from styrene/butadiene copolymer (SBS); ethylene/vinyl acetate copolymer (EVA); olefinic polymers, polystyrene (PS), and combinations thereof.Type: GrantFiled: January 15, 2002Date of Patent: March 29, 2005Assignees: E.I. du Pont de Nemours and Company, Plastolen GmbHInventors: Stefan Greulich, Karl-Wilhelm Kirberg, Norbert Eickhoff, Olaf Stelzer
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Publication number: 20040186233Abstract: A thermoplastic molding composition comprising (A) 89 to 99 wt. % of a copolycarbonate and (B) 11 to 1 wt. % of a modifier is disclosed. The structure of the copolycarbonate contains 0.Type: ApplicationFiled: March 3, 2004Publication date: September 23, 2004Inventors: Melanie Moethrath, Michael Erkelenz, Klaus Horn
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Patent number: 6790874Abstract: The invention relates to thermoplastic polyolefin compositions having enhanced surface durability and products thereof which include a thermoplastic polyolefin base component at least one radiation-crosslinkable component present in an amount sufficient to enhance the surface durability of the thermoplastic polyolefin component when radiation-cured and at least one photoinitiator present in an amount sufficient to initiate crosslinking of the radiation-crosslinkable component upon exposure of the thermoplastic polyolefin composition to radiation.Type: GrantFiled: July 31, 2002Date of Patent: September 14, 2004Assignees: Solvay Engineered Polymers, Ciba Specialty Chemicals CorporationInventors: Edmund K. Lau, Satchit Srinivasan, Peter J. Perron, Peter S. Solera, Anthony DeBellis, Chia-Hu Chang, Gerald Capocci, Joseph Puglisi, Douglas Horsey
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Patent number: 6767967Abstract: A pseudo cross-link type resin composition made of one of resins or a mixture of the resins; wherein the resin is obtained by mixing a polymer molecule that has an atomic group capable of forming an intermolecular hydrogen bond at least in a molecular side chain or at a molecular tail end of the polymer molecule, and a polymer molecule that has an atomic group capable of forming an intermolecular hydrogen bond at lest in a molecular side chain or in a molecular skeleton of the polymer molecule; wherein the polymer molecule having an atomic group capable of forming an intermolecular hydrogen bond at least in a molecular side chain or at a molecular tail end is a vinylic polymer or a copolymer thereof that has a carboxyl group or a hydroxyl group at least in a molecular side chain or at a molecular tail end, and the polymer molecule that has an atomic group capable of forming an intermolecular hydrogen bond at least in a molecular side chain or in a molecular skeleton is a vinylic polymer or a copolymer thereType: GrantFiled: June 17, 2002Date of Patent: July 27, 2004Assignee: Hitachi Chemical Co., Ltd.Inventors: Tetsuro Yamanaka, Yukihiko Yamashita, Kenji Kanemaru
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Patent number: 6759480Abstract: The invention relates to thermoplastic compositions comprising: −40 to 97 parts of a thermoplastic polymer (M) forming a matrix, chosen from polyamides, polyamide block copolymers, fluoro polymers, polycarbonate, styrene resins, PMMA, thermoplastic polyurethanes (TPU), copolymers containing polyester blocks and polyether blocks, polycarbonate-polyester alloys, polyketones, PVC and ethylene-vinyl alcohol copolymers (EVOH), −60 to 3 parts of (B) comprising: either an ethylene-alkyl (meth)acrylate copolymer (B1), the alkyl having at least 5 carbon atoms, which copolymer (B1) carries a functional group or a blend of an ethylene-alkyl (meth)acrylate copolymer (B2), the alkyl having at least 5 carbon atoms, which copolymer (B2) does not carry a functional group, and of an impact modifier which carries a functional group.Type: GrantFiled: September 26, 2000Date of Patent: July 6, 2004Assignee: AtofinaInventors: Alain Bouilloux, Christophe Lacroix, Jean-Marc Le Blevec, Thibaut Montanari
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Publication number: 20030232923Abstract: A pseudo cross-link type resin composition made of one of resins or a mixture of the resins;Type: ApplicationFiled: June 17, 2002Publication date: December 18, 2003Inventors: Tetsuro Yamanaka, Yukihiko Yamashita, Kenji Kanemaru
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Patent number: 6657005Abstract: A thermoplastic resin composition is formed by mixing (A) 30-84.9 wt. % of a crystalline thermoplastic resin, (B) 15-65 wt. % of a graft copolymer obtained by graft-polymerizing an ethylenically unsaturated monomer onto a rubber trunk polymer having an alkylene oxide group and (C) 0.1-5 wt. % of an anionic surfactant. As a result, it is possible to obtain a non-black thermoplastic resin composition which shows an antistatic property at a level suitable for use as an ESD (electrical static dissipative) and can be colored into arbitrary hues.Type: GrantFiled: October 18, 2001Date of Patent: December 2, 2003Assignee: Kureha Kagaku Kogyo Kabushiki KaishaInventors: Naomitsu Nishihata, Shiro Arai, Chikau Onodera, Masahito Tada
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Patent number: 6639014Abstract: Gel-forming macromers including at least four polymeric blocks, at least two of which are hydrophobic and at least one of which is hydrophilic, and including a crosslinkable group are provided. The macromers can be covalently crosslinked to form a gel on a tissue surface in vivo. The gels formed from the macromers have a combination of properties including thermosensitivity and lipophilicity, and are useful in a variety of medical applications including drug delivery and tissue coating.Type: GrantFiled: April 2, 2002Date of Patent: October 28, 2003Assignee: Focal, Inc.Inventors: Chandrashekhar P. Pathak, Shikha P. Barman, C. Michael Philbrook, Amarpreet S. Sawhney, Arthur J. Coury, Luis Z. Avila, Mark T. Kieras