Polymer Substrate Derived From Hydrocarbon Reactants Only Patents (Class 525/84)
  • Patent number: 6653404
    Abstract: A rubber composition having satisfactory processability and dimension stability, exhibits excellent tensile strength and wearing resistance when vulcanized and comprises (1) a crosslinked rubber particle containing as repeating units (a) 39.89 to 79.89% by weight of a conjugated diene unit such as 1,3-butadiene or the like, (b) 20 to 60% by weight of an aromatic vinyl unit such as styrene, (c) 0.01 to 10% by weight of a monomer unit having at least two polymerizable unsaturated group such as divinylbenzene, and the like, and (d) 0.1 to 30% by weight of a monomer unit having one polymerizable unsaturated group and an amino group such as vinylbenzylmethylamine, and the like and (2) a conjugated diene/aromatic vinyl copolymeric rubber such as styrene-butadiene copolymeric rubber and the like.
    Type: Grant
    Filed: April 30, 2001
    Date of Patent: November 25, 2003
    Assignee: JSR Corporation
    Inventors: Tomohisa Konno, Toshihiro Tadaki, Yoshiyuki Udagawa, Hiroshi Akema
  • Patent number: 6630535
    Abstract: A composition comprising an elastomer, a filler, and a comb-like polymer, the comb-like polymer comprising a backbone and a plurality of side chains, the backbone having a length greater than or equal to the entanglement length, the side chains having a length greater than about 33% of the entanglement length, the backbone including at least one side chain per entanglement length, and the comb-like polymer having a Tg of less than −5° C.
    Type: Grant
    Filed: August 18, 2000
    Date of Patent: October 7, 2003
    Assignee: Bridgestone Corporation
    Inventors: Terrence E. Hogan, James A. Krom, James E. Hall, Xiaorong Wang, Peyman Pakdel, William L. Hergenrother
  • Patent number: 6620883
    Abstract: The invention relates to a process for the preparation of graft rubber polymers of the ABS type by emulsion polymerization according to the so-called fed batch process, in which latexes having markedly reduced residual monomer contents are obtained, and to compositions containing the mentioned graft rubber polymers.
    Type: Grant
    Filed: September 26, 2001
    Date of Patent: September 16, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Erich Gasche, Herbert Eichenauer, Pierre Vanhoorne, Ulrich Jansen, Eckhard Wenz, Stefan Moss
  • Patent number: 6583221
    Abstract: This invention is related to a vinyl chloride resin as obtainable by graft-copolymerizing an acrylic copolymer (a) having a mean particle diameter of 60 to 250 nm with a vinyl monomer (b) predominantly composed of vinyl chloride, said acrylic copolymer (a) being obtainable by graft-copolymerizing 40 to 90 weight % of a copolymer (a−1) with 10 to 60 weight % of a mixture monomer (a−2), said copolymer (a−1) being composed of 100 weight parts of a radical-polymerizable monomer which gives a homopolymer having a glass transition point of not lower than −140° C. but lower than −60° C. and 0.1 to 1 weight part of a polyfunctional monomer, and said mixture monomer (a−2) comprising 100 weight parts of a radical-polymerizable monomer predominantly comprised of a (meth) acrylate which gives a homopolymer having a glass transition point of not lower than −55° C. but lower than −10° C. and 1.5 to 10 weight parts of a polyfunctional monomer.
    Type: Grant
    Filed: July 13, 2001
    Date of Patent: June 24, 2003
    Assignee: Sekisui Chemical Co., Ltd.
    Inventors: Takahiro Omura, Noriki Fujii
  • Patent number: 6566436
    Abstract: The use of a thermoplastic molding composition which is not ABS, comprising, based on the total of the amounts of components A, B, C, and, where appropriate, D, this total being 100% by weight, a: as component A, from 1 to 48% by weight of at least one particulate emulsion polymer which has one or more phases and has a glass transition temperature below 0° C. in at least one phase, and has a median particle size from 50 to 1000 nm, b: as component B, from 1 to 48% by weight of at least one amorphous or semicrystalline polymer, c: as component C, from 51 to 90% by weight of polycarbonates, and d: as component D, from 0 to 47% by weight of conventional addictives and/or fibrous or particulate fillers, or a mixture of these, for producing moldings, or corresponding semifinished products, for the garden sector or animal-keeping sector.
    Type: Grant
    Filed: April 5, 2001
    Date of Patent: May 20, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Norbert Güntherberg, Heiner Görrissen, Graham Edmund Mc Kee, Norbert Niessner, Martin Weber
  • Patent number: 6559219
    Abstract: A rubber composition of the invention comprises [1] a cross inked rubber particle component whose toluene-insolubles is 50% by weight or more and whose number mean particle size is 3 to 1000 nm and [2] a non-crosslinked rubber component whose toluene-insolubles is less than 20% by weight. This crosslinked rubber particle component is a polymer comprising at least one selected from (1) a conjugated diene unit, (2) a conjugated diene unit and an &agr;,&bgr;-unsaturated nitrile unit and (3) a conjugated diene unit and an acrylate unit as well as a monomer unit having at least 2 polymerizable unsaturated groups. The non-crosslinked rubber component described above is a polymer co rising at least one selected from (a) a conjugated diene unit, (b) (a) plus an aromatic vinyl unit, (c) (a) plus an &agr;,&bgr;-unsaturated nitrile unit, (d) (a) plus an acrylate unit and (e) an ethylene unit and an &agr;-olefin unit having 3 to 12 carbon atoms.
    Type: Grant
    Filed: April 27, 2001
    Date of Patent: May 6, 2003
    Assignee: JSR Corporation
    Inventors: Toshihiro Tadaki, Tomohisa Konno, Yoshiyuki Udagawa, Hiroshi Akema
  • Patent number: 6472487
    Abstract: Synthetic polymers having moieties capable of covalent or hydrogen bonding to cellulose and one or more amphiphilic moieties are disclosed. These polymers are capable of providing two distinct properties to paper products, such as tissues, which properties heretofore have been imparted through the use of at least two different molecules. The backbone of these synthetic polymers is based on modified vinyl polymers, such as polyvinyl alcohol, polyacrylamides and polyacrylic acids.
    Type: Grant
    Filed: May 14, 2001
    Date of Patent: October 29, 2002
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Wen Zyo Schroeder, Daniel Arthur Clarahan, Mike Thomas Goulet, Thomas Gerard Shannon
  • Patent number: 6391950
    Abstract: Disclosed is a PVC pipe cement composition that comprises a polymeric material of a methyl methacrylate homopolymer or copolymer, a styrene-acrylonitrile polymer, and a rubber grafted with at least a methacrylic acid ester of a C1 to C8 alkanol; and at least about 10% by weight solvent.
    Type: Grant
    Filed: October 1, 1997
    Date of Patent: May 21, 2002
    Assignee: BASF Corporation
    Inventor: Mark Waldrop
  • Patent number: 6380308
    Abstract: The invention relates to a binder composition containing A) 50-90 parts by wt. of OH-functional graft copolymer resins prepared from a) 0.1 to 10 parts by wt. of polybutadiene, b) 5 to 60 parts by wt. of an unsaturated aromatic monomer, c) 10 to 50 parts by wt. of a hydroxyalkyl ester of (meth)acrylic acid, d) 5 to 70 parts by wt. of a cycloaliphatic ester of (meth)acrylic acid, e) 5 to 50 parts by wt. of an aliphatic ester of (meth)acrylic acid, f) 0.1 to 5 parts by wt. of a mono-olifinically unsaturated mono- or dicarboxylic acid and/or maleic or fumaric acid half esters, B) 0.1 to 5 parts by wt. of a polyfunctional crosslinking agent.
    Type: Grant
    Filed: November 13, 2000
    Date of Patent: April 30, 2002
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Wamprecht, Michael Sonntag, Holger Mundstock
  • Publication number: 20020007011
    Abstract: An objective of the invention is to provide a rubber composition which has satisfactory processability and dimension stability, and the like, gives a vulcanized rubber exhibiting excellent wearing resistance and tensile strength, and the like, and thus is useful in a belt, a hose and a tire and the like, as well as a crosslinked rubber particle for obtaining such rubber composition. A rubber composition of the invention comprises [1] a crosslinked rubber particle comprising as repeating units (a) 30 to 94.89% by weight of a conjugated diene unit, (b) 5 to 69.89% by weight of an aromatic vinyl unit, (c) 0.01 to 10% by weight of a monomer unit having at least two polymerizable unsaturated group, (d) one polymerizable unsaturated group and an amino group, a hydroxyl group and an epoxy group and (e) 0.
    Type: Application
    Filed: April 26, 2001
    Publication date: January 17, 2002
    Applicant: JSR CORPORATION
    Inventors: Tomohisa Konno, Toshihiro Tadaki, Yoshiyuki Udagawa, Hiroshi Akema
  • Patent number: 6310148
    Abstract: A styrene resin composition excellent in luster, rigidity and surface impact strength is provided. A mixed solution of (b1) a homopolymer of a diene monomer or (b2) a copolymer of a styrene monomer and a diene monomer, the copolymer having 15% or less on a weight basis of the styrene structure units, (b3) a copolymer of a styrene monomer and a diene monomer, the copolymer having 20 to 50% on a weight basis of the styrene structure units, (a1) a styrene monomer, and (a2) a (meth)acrylic acid alkyl ester is continuously bulk polymerized in a continuous bulk polymerization line having incorporated therein a tubular reactor with a plurality of mixing elements that have no mobile part fixed inside thereof.
    Type: Grant
    Filed: March 28, 2000
    Date of Patent: October 30, 2001
    Assignee: Dainippon Ink and Chemicals, Ltd.
    Inventors: Tsuyoshi Morita, Mamoru Fujihira, Jiro Matsuo
  • Patent number: 6300412
    Abstract: This invention relates to a process for preparing rubber-modified aromatic vinyl resin compositions by polymerizing a raw material solution containing 3 to 20% by weight of rubbery polymer, 50 to 97% by weight of an aromatic vinyl monomer, and 0 to 30% by weight of a solvent until the conversion of said aromatic vinyl monomer falls in the range from 30 to 70%, adding a (meth)acrylate monomer or its mixture with other monomers to the reaction mixture so that the ratio by weight of the aromatic vinyl monomer in the reaction mixture to the (meth)acrylate monomer becomes 85/15 to 50/50, continuing the polymerization, and devolatilizing to remove the unreacted monomers, solvent, and the like. It is possible by this process to prepare easily and economically rubber-modified aromatic vinyl resin compositions of easy processability, good surface properties in respect to appearance and scratch resistance, and good balance between impact resistance and rigidity.
    Type: Grant
    Filed: January 7, 2000
    Date of Patent: October 9, 2001
    Assignee: Nippon Steel Chemical Co., Ltd.
    Inventors: Yasuji Shichijo, Masanari Fujita
  • Patent number: 6288167
    Abstract: The present invention is directed to blends of two grafted rubber substrates and a matrix polymer wherein one of the grafted rubber substrates uses a core/shell rubber such as a styrene/butyl acrylate rubber in order to obtain a lower contrast ratio in the blends and better colorability as well as good impact strength.
    Type: Grant
    Filed: May 26, 1999
    Date of Patent: September 11, 2001
    Assignee: Bayer Antwerpen S.A./N.V.
    Inventors: Chuan-Ju Chen, Fred Ming-sheng Peng
  • Patent number: 6277913
    Abstract: There is provided a thermoplastic resin composition and interior or exterior parts for vehicle using thereof, which is excellent in flexibility, surface appearance, heat deformation property at heating and has low tackiness at a high temperature. The thermoplastic resin composition comprises 25 to 90 parts by weight of a (meth)acrylic ester copolymer (X), which is prepared by polymerizing 40 to 95% by weight of a (meth)acrylic ester, 0 to 40% by weight of a vinyl cyanide compound, not more than 60% by weight of an aromatic vinyl compound and 0 to 40% by weight of a monomer copolymerizable therewith, and has a glass transition temperature of not more than 20° C. and a gel content of not more than 50% by weight, 5 to 75 parts by weight of a copolymer (Y), which has a glass transition temperature or a melting point not less than 50° C.
    Type: Grant
    Filed: May 21, 1999
    Date of Patent: August 21, 2001
    Assignee: Kaneka Corporation
    Inventors: Ikuhiro Mishima, Kazuhito Wada
  • Patent number: 6255388
    Abstract: A shrink film is provided which is superior in glossiness, mechanical strength, and rigidity, and which is also provided with a property of preventing natural shrinkage. The shrink film with excellent properties is produced by using a resin composition which is obtained by graft polymerization of copolymers of styrene and butadiene with styrene, methylmethacrylate, and butylacrylate. The thus obtained resin composition is extruded after melting and kneading, and drawn into a film in two directions, and exposed at a temperature within a temperature range for the thermal setting so as to obtain the orientation according to ASTM D1504 of the shrink film in range of 1.5 to 5.0 MPa.
    Type: Grant
    Filed: February 22, 1999
    Date of Patent: July 3, 2001
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Hirofumi Yamada, Yoshiaki Murata, Hidetsugu Sawada, Kosuke Arai
  • Patent number: 6255387
    Abstract: A derivatized blend and a process for producing that blend in which a high ethylene content ethylene-propylene polymer and a lower ethylene content ethylene-propylene polymer are subjected to simultaneous blending and shearing to reduce their molecular weights and molecular weight distribution and then reacted with an organic compound to derivatize the blend. The sheared derivatized blend of polymers can function as a shear stable multifunctional viscosity index improver with improved low temperature properties and, in some cases, dispersancy antioxidant and anti-wear properties.
    Type: Grant
    Filed: January 8, 1998
    Date of Patent: July 3, 2001
    Assignee: Ethyl Additives Corporation
    Inventors: Errol J. Olivier, Robert T. Patterson, Peter N. Nugara
  • Patent number: 6228938
    Abstract: Thermoplastic materials containing A) 5 to 80 parts by weight of a thermoplastic co- or terpolymer made from the monomers styrene, &agr;-methylstyrene, methyl methacrylate, acrylonitrile with an average molecular weight ({overscore (M)}w) of 70,000 to 119,000, B) 1 to 30 parts by weight of a thermoplastic copolymer made from 60 to 95% by weight of styrene and/or &agr;-methylstyrene and 40 to 5% by weight of acrylonitrile with an average molecular weight ({overscore (M)}w) of 25,000 to 49,500, C) 0.1 to 10 parts by weight of a thermoplastic co- or terpolymer made from the monomers styrene, &agr;-methylstyrene, methyl methacrylate, acrylonitrile with an average molecular weight ({overscore (M)}w) of 1,500 to 6,000 and D) 0.5 to 50 parts by weight of a particulate rafted rubber with a glass transition temperature ≦10° C. and an average particle diameter (d50) of 0.05 to 0.
    Type: Grant
    Filed: June 20, 1994
    Date of Patent: May 8, 2001
    Assignee: Bayer AG
    Inventors: Herbert Eichenauer, Karl-Heinz Ott, Dieter Wittmann, Alfred Pischtschan
  • Patent number: 6225404
    Abstract: A thermoplastic compound comprising at least one linear or branched thermoplastic polymer or copolymer, having at least one reactive or graftable site (F1), which polymer is compounded with at least one hyperbranched dendritic polyester macromolecule being composed of a monomeric or polymeric nucleus and one or more monomeric or polymeric branching or spacing chain extenders. The macromolecule is optionally chain terminated and/or functionalized, whereby terminal chain extender functions, chain termination and/or functionalization provides the macromolecule with at least one reactive or graftable site (F2) being reactive to or graftable onto said reactive or graftable site (F1). In a further aspect, the invention relates to a thermoplastic composition comprising two or more components, whereby at least one is said thermoplastic compound. In yet a further aspect, the invention relates to a thermoplastic article made of one or more thermoplastic compounds, whereby at least one is said thermoplastic compound.
    Type: Grant
    Filed: March 4, 1999
    Date of Patent: May 1, 2001
    Assignee: Perstorp AB
    Inventors: Kent Sorensen, Bo Pettersson, Louis Boogh, Jan-Anders Edvin Mansson
  • Patent number: 6221969
    Abstract: Disclosed is a method for producing a rubber-modified styrenic resin. The method includes the steps of (a) producing a rubber solution by dissolving a rubber polymer in a vinyl monomer; (b) producing a rubber composition by continuously supplying the above rubber solution in a first reactor to polymerize the rubber polymer with the vinyl monomer at a reaction temperature of 120°-145° C. to perform phase inversion of the rubber polymer, thereby producing the polymer of conversion ratio of 10-40 wt %, and realized through 50-99% of rubber particles having an average particle diameter of 0.1-0.
    Type: Grant
    Filed: March 22, 1999
    Date of Patent: April 24, 2001
    Assignee: LG Chemical, Ltd.
    Inventors: Oh-jin Kwon, Yong-jun Kim, Hyung-sub Lee
  • Patent number: 6191226
    Abstract: The invention relates to polybutadiene rubber wherein a molecular weight distribution curve of the rubber as determined by gel permeation chromatography (GPC) has 2 peaks attributable to a high molecular weight component and a low molecular weight component, a peak top molecular weight of the high molecular weight component and a peak top molecular weight of the low molecular weight component fall within ranges of from 100,000 to 1,500,000 and from 10,000 to 50,000, respectively, a ratio of the weight average molecular weight (Mw) to the number average molecular weight (Mn), Mw/Mn, falls within a range of from 4.5 to 14.5, and the content of a cis-1,4 structure is at least 80 wt. %, a high-impact aromatic vinyl resin composition comprising the polybutadiene rubber, and a preparation process of the resin composition.
    Type: Grant
    Filed: February 19, 1999
    Date of Patent: February 20, 2001
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Hiroaki Matsuda, Kohkichi Noguchi
  • Patent number: 6187862
    Abstract: A thermoplastic molding composition comprising a grafted rubber and a copolymeric matrix is disclosed. The composition is characterized in that its grafted rubber includes a substrate, a first grafted phase and a subsequent grafted phase which are sequentially grafted to said substrate. The substrate which contains a crosslinked elastomer is grafted with a first grafted phase and with a subsequent grafted phase, both phases containing copolymers of at least one vinylaromatic monomer and at least one member selected from the group consisting of (meth)acrylonitrile and alkyl (meth)acrylate. The relative ratios of the monomers making up the copolymerized phases differ one from the other. The grafted rubber is present in particulate form having a weight average particle size of about 0.1 to 1.0 microns. The composition features improved impact strength and reduced opacity.
    Type: Grant
    Filed: May 1, 1998
    Date of Patent: February 13, 2001
    Assignee: Bayer Corporation
    Inventors: Moh Ching Oliver Chang, Richard M. Auclair, Robert A. Sanocki
  • Patent number: 6180693
    Abstract: Core/shell particles comprising a core comprising an elastomer having a TG value of <0° C., onto which a shell of a crosslinked copolymer is grafted, where the proportion of the crosslinking component in the copolymer of the shell is from 5 to 90% by weight, based on the total amount of the comonomers of the shell copolymer, are suitable as toughening agents for epoxy resins, with which they have good compatibility.
    Type: Grant
    Filed: September 3, 1999
    Date of Patent: January 30, 2001
    Assignee: Vantico Inc.
    Inventors: Qian Tang, Martin Roth, Dean Tallak Behm, Carl Walter Mayer, Klaus Petschel, Sameer Hosam Eldin
  • Patent number: 6177517
    Abstract: Thermoplastic molding masses made of thermoplastic polymers obtained by mixed graft polymerization and having a glass transition temperature above 20 C., and of special rubber-elastic block copolymers, are characterized by a balanced spectrum of properties.
    Type: Grant
    Filed: June 18, 1997
    Date of Patent: January 23, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Norbert G{umlaut over (u)}ntherberg, Martin Weber, Konrad Knoll
  • Patent number: 6153307
    Abstract: The present invention relates to compatibilizers useful to laminate a layer of a vinyl aromatic polymer such as polystyrene and a polyester such as PET. The compatibilizer comprises a mixture comprising 5-95 weight % of a polyester, 95-5 weight % of an impact modified polymer of a vinyl aromatic monomer such as high impact polystyrene (HIPS) and from 5 to 20 weight % of a hydrogenated block polymer of a vinyl aromatic monomer and a conjugated diolefin sometimes called SEBS.
    Type: Grant
    Filed: July 30, 1998
    Date of Patent: November 28, 2000
    Assignee: Nova Chemicals Inc.
    Inventor: Beth Ann Baran
  • Patent number: 6140417
    Abstract: A vinyl chloride resin composition having a greatly improved processability without lowering the transparency wherein the gelation property of a vinyl chloride resin is improved with greatly decreased generation of ungelled substance; which comprises a vinyl chloride resin and 0.
    Type: Grant
    Filed: December 2, 1998
    Date of Patent: October 31, 2000
    Assignees: Kaneka Corporation, Kaneka Belgium N.V.
    Inventors: Yasushi Nakanishi, Mamoru Kadokura, Karin Janssen, Akira Takaki, Yasuhiro Miki
  • Patent number: 6103829
    Abstract: Molding materials (F) which are suitable for the production of shaped articles having reduced surface gloss and are based on polymers or polymer blends (P), preferably ASA polymers and/or styrene/acrylonitrile copolymers, contain a sufficient amount of a dull graft copolymer (A) admixed as dulling agent, which was prepared by one-stage or multistage graft copolymerization of monomers forming the hard shell onto an elastomeric acrylate polymer, the graft copolymerization being carried out to a conversion of more than 15% by thermal or free radical mass or solution polymerization.
    Type: Grant
    Filed: October 8, 1998
    Date of Patent: August 15, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Graham Edmund Mc Kee, Bernhard Rosenau, Walter Heckmann
  • Patent number: 6087435
    Abstract: A polystyrene-based resin composition, comprising (A) a styrene-based resin with a mainly syndiotactic configuration, (B) a polyolefin, and (C) rubber polymer particles as main components, exhibits excellent heat resistance and impact resistance.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: July 11, 2000
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
  • Patent number: 6080815
    Abstract: The present invention relates to a process for producing a thermoplastic resin having high impact strength and good surface gloss, which comprises graft copolymerizing at least a vinyl cyanide compound and at least an aromatic vinyl compound for a short period of less than about 3 hours in the presence of rubber latex having high gel content. The rubber latex can be a mixture of two or more rubber latices having different particle size. The graft copolymer has the characteristics such that the degree of the inner occlusion into the resin is decreased and the degree of surface grafting is increased. Thereby, the resulted thermoplastic resin has a very high impact strength and good surface gloss, and the processability is greatly improved. In addition, when the graft copolymer is polymerized the level of coagulum formation is greatly decreased.
    Type: Grant
    Filed: June 10, 1998
    Date of Patent: June 27, 2000
    Assignee: LG Chemical Limited
    Inventors: Chang-Hong Lee, Young-Min Kim, Jin-Nyoung Yoo
  • Patent number: 6063868
    Abstract: The use of a thermoplastic molding composition differing from ABS and comprising, based on a total of 100% by weight of amounts of components A and B, and, if desired, C and/or D,a: as component A, from 1 to 99% by weight, preferably from 15 to 60% by weight, in particular from 25 to 50% by weight, of a particulate emulsion polymer with a glass transition temperature of below 0.degree. C. and with a median particle size of from 50 to 1000 nm, preferably from 50 to 500 nmb: as component B, from 1 to 99% by weight, preferably from 40 to 85% by weight, in particular from 50 to 75% by weight, of at least one amorphous or partly crystalline polymer,c: as component C, from 0 to 50% by weight of polycarbonates, andd: as component D, from 0 to 50% by weight of fibrous or particulate fillers or mixtures of thesefor producing housings for security equipment.
    Type: Grant
    Filed: January 22, 1999
    Date of Patent: May 16, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Herbert Naarmann, Graham Edmund McKee, Alfred Pirker, Hans-Josef Sterzel, Franz Brandstetter, Bernd-Steffen von Bernstorff, Bernhard Rosenau, Ulrich Endemann, Burkhard Straube
  • Patent number: 6063870
    Abstract: The rigid vinyl chloride resin composition comprises 100 parts by weight of a vinyl chloride resin having an average degree of polymerization of 350 to 600, 5 to 30 parts by weight of an impact-resistant improver, and 5 to 20 parts by weight of an acrylonitrile-styrene copolymer having a weight ratio acrylonitrile and styrene of 1/99 to 9/91. This composition has good impact strength and fluidity.
    Type: Grant
    Filed: August 5, 1998
    Date of Patent: May 16, 2000
    Assignee: Shin-Etsu Chemical, Co., Ltd.
    Inventors: Yuji Tokushige, Osamu Sodeyama
  • Patent number: 6063854
    Abstract: The use of a thermoplastic molding composition differing from ABS and comprising, based on a total of 100% by weight of amounts of components A and B, and, if desired, C and/or D,a: as component A, from 1 to 99% by weight, preferably from 15 to 60% by weight, in particular from 25 to 50% by weight, of a particulate emulsion polymer with a glass transition temperature of below 0.degree. C. and with a median particle size of from 50 to 1000 nm, preferably from 50 to 500 nmb: as component B, from 1 to 99% by weight, preferably from 40 to 85% by weight, in particular from 50 to 75% by weight, of at least one amorphous or partly crystalline polymer,c: as component C, from 0 to 50% by weight of polycarbonates, andd: as component D, from 0 to 50% by weight of fibrous or particulate fillers or mixtures of thesefor producing moldings for sanitary and bathroom fittings.
    Type: Grant
    Filed: January 25, 1999
    Date of Patent: May 16, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Herbert Naarmann, Graham Edmund Mc Kee, Alfred Pirker, Hans-Josef Sterzel, Franz Brandstetter, Bernd-Steffen von Bernstorff, Bernhard Rosenau, Ulrich Endemann, Burkhard Straube
  • Patent number: 6051655
    Abstract: A composition amenable to injection molding and extrusion comprises a syndiotactic styrene resin, a thermoplastic resin such as a polyolefin and an inorganic filler optionally contains a rubber.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: April 18, 2000
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
  • Patent number: 6031047
    Abstract: Poly(vinyl chloride), when impact modified with a core/shell acrylic impact modifier whose shell is predominantly formed from 50-90 parts of polymerized units of methyl methacrylate and 10-50 parts of polymeric units of a C.sub.2 -C.sub.8 alkyl acrylate and whose core is a crosslinked copolymer mainly of polymeric units of butyl acrylate, exhibits improved fusion behavior, allowing conversion to an intimate, fused, processable blend at lower temperatures and faster rates, than when the shell of the impact modifier is substantially formed from methyl methacrylate alone.
    Type: Grant
    Filed: December 30, 1997
    Date of Patent: February 29, 2000
    Assignee: Rohm and Haas Company
    Inventors: Jean Marie Brady, Steven Richard Rapacki
  • Patent number: 6020428
    Abstract: A rubber-modified styrenic resin composition comprising (A) 100 wt. parts of a rubber-modified styrenic resin which contains 10 to 35 wt. % of soft component particles having an average particle size of 0.1 to 0.5 .mu.m, where said soft component particles have a single occlusion structure comprising a core part which consists of a single continuous phase of a styrenic resin and a shell part which comprises a rubber polymer and occludes said core part, and (B) 0.1 to 10 wt. parts of a polymer having a solubility parameter (SP) of 8.45 to 8.70 and having no aromatic vinyl compound unit therein. This composition has excellent plane impact strength and gloss properties as well as moldability and other physical properties, and satisfies properties required for exterior materials, wrapping materials and molded foam articles.
    Type: Grant
    Filed: May 24, 1996
    Date of Patent: February 1, 2000
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Shuji Yoshimi, Hayato Kihara, Takahiro Ishii
  • Patent number: 6013726
    Abstract: A polystyrene-based resin composition containing a styrene-based resin with mainly syndiotactic configuration, a polyamide, and a rubber polymer as main components.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: January 11, 2000
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
  • Patent number: 6008298
    Abstract: Polymer alloy comprising a) one or more cycloolefin copolymers and b) one or more types of core/shell particles having a diameter of 0.01 to 0.7 micrometer.
    Type: Grant
    Filed: January 22, 1998
    Date of Patent: December 28, 1999
    Assignees: Hoechst Aktiengesellschaft, Mitsui Petrochemical Ind., Ltd.
    Inventors: Wilfried Hatke, Frank Osan, Otto Herrmann-Schonherr
  • Patent number: 5994464
    Abstract: According to the present invention there is provided a cyanoacrylate adhesive composition having high shear bond strength, peeling bond strength and impact bond strength and superior particularly in hot-cold cycle resistance and heat resistance. The cyanoacrylate adhesive composition contains (a) a cyanoacrylate monomer, (b) an elastomer miscible or compatible with the cyanoacrylate monomer, and (c) a core-shell polymer having a core of a rubbery polymer and a shell of a glassy polymer, the core-shell polymer being compatible but not miscible with the cyanoacrylate monomer.
    Type: Grant
    Filed: May 30, 1997
    Date of Patent: November 30, 1999
    Assignee: Three Bond., Ltd.
    Inventors: Nobuo Ohsawa, Hiroyuki Mikuni, Tatsuo Fujii, Hiroshi Takeuchi
  • Patent number: 5977254
    Abstract: A molding material contains, based on the sum of the components A and B, and, if required, C, D and/or E,A: 1-99% by weight of a particulate microemulsion polymer having a glass transition temperature below 0.degree. C. and a median particle size of less than 50 nm,B: 1-99% by weight of a semicrystalline polymer B, in particular selected from at least one polymer from semicrystalline polyamides, partly aromatic copolyamides, polyolefins, ionomers, polyesters, polyetherketones, polyoxyalkylenes and polyarylene sulfides,C: 0-50% by weight of a polymer selected from a particulate graft copolymer having a median particle size of from 60 to 10,000 nm, a thermoplastic polyurethane, a thermoplastic elastomer and an acrylate, diene, EP, EPDM or silicone rubber,D: 0-50% by weight of polycarbonates andE: 0-50% by weight of fibrous or particulate fillers or of a mixture thereof.
    Type: Grant
    Filed: April 7, 1997
    Date of Patent: November 2, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Graham Edmund Mc Kee, Norbert Niessner, Herbert Fisch
  • Patent number: 5969042
    Abstract: Thermoplastic molding materials contain a mixture of(A) a methacrylate polymer,(B) a copolymer of vinylaromatic monomers and vinyl cyanide,(C) a graft copolymer comprising a core and a graft shell and(D) a further graft copolymer comprising a core and a graft shell,the average particle size (d.sub.50)-C of the graft copolymer (C) being from 25 to 60 nm and that of the graft copolymer (D) being from 90 to 300 nm and the ratio of the average particle size (d.sub.50)-C to (d.sub.50)-D being kept in the range from 2:1 to 5:1.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: October 19, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Kristin Tiefensee, Norbert Guntherberg
  • Patent number: 5955541
    Abstract: A thermoplastic resin composition which has low rigidity such as bending strength, bending modulus and tensile strength, high impact resistance, and further low stress and large energy absorption at the time of impact, high heat deformation resistance and excellent moldability and comprises 5 to 65 by weight of the copolymer (I) having Tg (glass transition temperature) of not more than 20.degree. C., 20 to 80 parts by weight of the maleimide copolymer (II) and 15 to 75 part by weight of the graft copolymer (III) having a graft ratio of 10 to 70% so that the total amount of the copolymers (I), (II) and (III) becomes 100 parts by weight, can be obtained.
    Type: Grant
    Filed: December 4, 1997
    Date of Patent: September 21, 1999
    Assignee: Kaneka Corporation
    Inventors: Kazuhito Wada, Ikuhiro Mishima, Shigemi Matsumoto
  • Patent number: 5936036
    Abstract: There is provided a rubber-modified styrenic resin composition comprising a rubber-modified styrenic resin containing soft component particles of a salami structure and a polymer having a predetermined solubility parameter, which is much more improved in both of plane impact resistance and Izod impact resistance, while retaining a high level of other properties such as rigidity, gloss and moldability.
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: August 10, 1999
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hayato Kihara, Takahiro Ishii, Kenji Atarashi
  • Patent number: 5910538
    Abstract: A thermoplastic molding composition containing a blend of polycarbonate, vinyl copolymer, such as SAN, and a graft polymer, such as ABS is disclosed. The invention resides in the finding that the incorporation of a compatibilizing agent which comprises a polymeric resin having a number average molecular weight of at least about 21,000 and which is miscible with the grafted phase of the graft polymer and which contains secondary amine reactive groups in its structure yields stable compositions having improved mechanical properties especially at low temperatures.
    Type: Grant
    Filed: April 24, 1998
    Date of Patent: June 8, 1999
    Assignee: Bayer Corporation
    Inventors: Allen R. Padwa, Venkatarayaloo Janarthanan
  • Patent number: 5889113
    Abstract: A resin composition, excellent in a physical property balance between chemical resistance and impact strength, obtained by mixing at least one graft copolymer selected from the group consisting of a graft copolymer in which a copolymer rubber of an alkyl acrylate and a conjugated diene is used, a graft copolymer in which a rubber prepared by seed rubber polymerizing an alkyl acrylate with a conjugated diene rubber is used and a graft copolymer in which a rubber prepared by seed rubber polymerizing an alkyl acrylate with a polyorganosiloxane rubber is used, with a graft copolymer in which a conjugated diene rubber is used, and optionally with a rigid thermoplastic resin.
    Type: Grant
    Filed: July 28, 1997
    Date of Patent: March 30, 1999
    Assignee: Mitsubishi Rayon Company Ltd.
    Inventors: Hiroshi Mori, Seizo Fujii
  • Patent number: 5883190
    Abstract: Thermoplastic moulding compositions containingI) At least one graft polymer which is obtainable by emulsion polymerisation of for example styrene and acrylonitrile under special conditions,II) At least one graft polymer that can be obtained by solution, bulk or suspension polymerisation of for example styrene and acrylonitrile in the presence of a rubber,III) At least one rubber-free copolymer of for example styrene and acrylonitrile,and their use for producing mouldings.
    Type: Grant
    Filed: November 21, 1997
    Date of Patent: March 16, 1999
    Assignee: Bayer AG
    Inventor: Herbert Eichenauer
  • Patent number: 5883189
    Abstract: Thermoplastic moulding compositions of the ABS type, containingI) at least one graft polymer, obtainable by emulsion polymerisation of resin-forming monomers in the presence of a mixture comprising a butadiene polymer latex (A) having a particle diameter d.sub.50 of .ltoreq.320 nm, a particle diameter distribution of 30 to 100 nm in width and a gel content of .ltoreq.70 wt. % and a butadiene polymer latex (B) having a particle diameter d.sub.50 of .gtoreq.370 nm, a particle diameter distribution of 50 to 500 nm in width and a gel content of .gtoreq.270 wt. %,II) at least one graft polymer, obtainable by emulsion polymerisation of resin-forming monomers in the presence of a butadiene polymer latex (C) having a particle diameter d.sub.50 of from 110 to 150 nm, a particle diameter distribution of 20 to 50 nm in width and a gel content of from 80 to 98 wt. %, andIII) at least one rubber-free copolymer composed of resin-forming monomersand the use of the moulding compositions for the production of mouldings.
    Type: Grant
    Filed: November 21, 1997
    Date of Patent: March 16, 1999
    Assignee: Bayer AG
    Inventors: Herbert Eichenauer, Edgar Leitz
  • Patent number: 5872184
    Abstract: A resin composition, excellent in a physical property balance between chemical resistance and impact strength, obtained by mixing at least one graft copolymer selected from the group consisting of a graft copolymer in which a copolymer rubber of an alkyl acrylate and a conjugated diene is used, a graft copolymer in which a rubber prepared by seed rubber polymerizing an alkyl acrylate with a conjugated diene rubber is used and a graft copolymer in which a rubber prepared by seed rubber polymerizing an alkyl acrylate with a polyorganosiloxane rubber is used, with a graft copolymer in which a conjugated diene rubber is used, and optionally with a rigid thermoplastic resin.
    Type: Grant
    Filed: October 20, 1997
    Date of Patent: February 16, 1999
    Assignee: Mitsubishi Rayon Company Ltd.
    Inventors: Hiroshi Mori, Seizo Fujii
  • Patent number: 5869154
    Abstract: Metal sparkles having one or more colors dispersed throughout a translucent resin at a concentration which eliminates the appearance of scratches and scuff marks on the resin surface. A pigment may be used in the translucent resin to yield a variety of decorative colors to create matching containers and utensils. The metal sparkle concentration in the translucent resin contains on an average 11/2%-3% metal sparkles by weight and 0.25%-1% color by weight. The sparkle concentration may be used at a letdown ratio of 4% resulting in a composition having an average of 0.06%-0.12% sparkles by weight and 0.01%-0.04% color by weight. The sparkles are random cuts of multi-colored aluminum having an average size of 1/64" (0.015) and are manufactured from the thinnest standard sheets of aluminum which are polished to a mirror-like surface of brilliant reflectivity.
    Type: Grant
    Filed: March 21, 1996
    Date of Patent: February 9, 1999
    Assignee: Fort James Corporation
    Inventor: Julie M. Benson
  • Patent number: 5849843
    Abstract: Multiple component polymer compositions for fabrication into articles. In particular, polymeric compositions comprising a heat resistant polymer; a radio frequency ("RF") susceptible polymer; a compatibilizing polymer; the composition having physical properties within the range a<40,000 psi; b>=70%; c<30%; d>1.0; e<0.1%; f<0.1%; g>=0.05; h<=60%; i=0; wherein: a is the mechanical modulus of the composition measured according to ASTM D-882; b is the percent recovery in length of the composition after an initial 20% deformation; c is the optical haze of the composition being 9 mils in thickness according to ASTM D-1003; d is the loss tangent of the composition at 1 Hz measured at melt processing temperatures; e is the elemental halogen content by weight of the composition; f is the low molecular weight water soluble fraction of the composition; g is the dielectric loss between 1 and 60 MHz and over temperatures of 25.degree. to 250.degree. C.
    Type: Grant
    Filed: November 16, 1993
    Date of Patent: December 15, 1998
    Assignee: Baxter International Inc.
    Inventors: Dean Laurin, Angeles Lillian Buan, Lecon Woo, Michael T. K. Ling, Yuan Pang Samuel Ding, William Anderson, Larry A. Rosenbaum, Denise S. Hayward, Joseph P. Hoppesch, Gregg Nebgen, Stanley Westphal
  • Patent number: 5847050
    Abstract: A method for particles agglomeration and enlargement of a diene type polymer rubber latex, which comprises subjecting a diene type polymer rubber latex produced by emulsion polymerization, to particles agglomeration and enlargement to obtain a particles-enlarged diene type polymer rubber latex (A), wherein the particles enlargement is allowed to take place by agglomeration based mainly on Brownian coagulation; a graft copolymer (B) of a particles-enlarged diene type polymer rubber latex (A) obtained by the above method; and a thermoplastic resin composition comprising said graft copolymer (B).
    Type: Grant
    Filed: March 3, 1997
    Date of Patent: December 8, 1998
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Akihiro Toritani, Koichi Shishido, Masahiro Osuka, Akira Nakata
  • Patent number: 5837773
    Abstract: A blend and a process for producing that blend in which a high ethylene content ethylene-propylene polymer and a lower ethylene content ethylene-propylene polymer are subjected to simultaneous blending and shearing to reduce their molecular weights and molecular weight distribution. The sheared blend of polymers can function as a shear stable dispersant viscosity index improver with improved lower temperature properties or the hydrocarbon base for multifunctional for viscosity index improvers, motor fuel additives or polymeric dispersants.
    Type: Grant
    Filed: March 12, 1997
    Date of Patent: November 17, 1998
    Assignee: DSM Copolymer, Inc.
    Inventors: Errol J. Olivier, Robert T. Patterson, Peter N. Nugara