Solid Polymer Other Than Graft Or Graft-type Derived From Nonaromatic Plural Ethylenically Unsaturated Reactant Patents (Class 525/87)
  • Patent number: 8822597
    Abstract: A process for producing rubber modified polymers having an increased rubber phase volume, including feeding a vinyl aromatic monomer and an elastomer to a polymerization reactor to form a reaction mixture, polymerizing the reaction mixture, combining a copolymer to the polymerized reaction mixture to form a combined mixture, subjecting the combined mixture to further polymerization, and obtaining a rubber modified polymer product from the further polymerization.
    Type: Grant
    Filed: April 28, 2011
    Date of Patent: September 2, 2014
    Assignee: Fina Technology, Inc.
    Inventors: Carlos DeAnda, Graciela Morales, Jose M. Sosa, David Knoeppel
  • Patent number: 8742015
    Abstract: The objective of the present invention is to provide a thermoplastic resin composition having an excellent balance of chemical resistance, heat resistance and impact resistance and a molded article comprising this thermoplastic resin composition. The present thermoplastic resin composition comprises a rubber-reinforced resin, an ethylene•(meth)acrylic acid ester•carbon monoxide copolymer, and polytetrafluoroethylene, and contents of ethylene•(meth)acrylic acid ester•carbon monoxide copolymer and polytetrafluoroethylene are respectively from 0.5 to 20 parts by weight and from 0.01 to 5 parts by weight, with respect to 100 parts by weight of the rubber-reinforced resin. A modified polyolefin resin may be contained.
    Type: Grant
    Filed: July 11, 2007
    Date of Patent: June 3, 2014
    Assignee: Techno Polymer Co., Ltd.
    Inventors: Keigo Higaki, Yasuhiko Itou
  • Patent number: 8685539
    Abstract: A tie layer adhesive composition for multilayer structures made up of graft composition compounded with a base resin, such as linear low density polyethylene (LLDPE), and a polyethylene having long chain branching, such as low density polyethylene (LDPE), and optionally one or more additives. The graft composition can be made up of a blend of a grafted polyolefin and an olefin elastomer and/or the reaction product of a live, grafted polyolefin and an olefin elastomer.
    Type: Grant
    Filed: August 26, 2011
    Date of Patent: April 1, 2014
    Assignee: Equistar Chemicals, LP
    Inventor: Maged G. Botros
  • Publication number: 20130337263
    Abstract: A fine polymer particle production method includes producing an emulsion in a liquid prepared by dissolving and mixing a polymer A and a polymer B in organic solvents in which a solution phase composed primarily of the polymer A and a solution phase composed primarily of the polymer B are formed as separate phases, and bringing it into contact with a poor solvent for the polymer A to precipitate the polymer A. This method serves for easy synthesis of fine polymer particles with a narrow particle size distribution and the method can be effectively applied to production of highly heat-resistant polymers that have been difficult to produce with the conventional methods.
    Type: Application
    Filed: August 8, 2013
    Publication date: December 19, 2013
    Applicant: Toray Industries, Inc.
    Inventors: Itaru Asano, Yuji Echigo, Hiroshi Takezaki
  • Publication number: 20130052471
    Abstract: A tie layer adhesive composition for multilayer structures made up of graft composition compounded with a base resin, such as linear low density polyethylene (LLDPE), and a polyethylene having long chain branching, such as low density polyethylene (LDPE), and optionally one or more additives. The graft composition can be made up of a blend of a grafted polyolefin and an olefin elastomer and/or the reaction product of a live, grafted polyolefin and an olefin elastomer.
    Type: Application
    Filed: August 26, 2011
    Publication date: February 28, 2013
    Applicant: Equistar Chemicals, LP
    Inventor: Maged G. Botros
  • Publication number: 20120142862
    Abstract: A rubber-modified polystyrene resin composition is for making an electroplatable article which has a sectioned layer defining a unit area. The rubber-modified polystyrene resin composition includes a resin matrix, occlusion rubber particles dispersed in the resin matrix, and non-occlusion rubber particles dispersed in the resin matrix. A total sectional area ratio of the occlusion rubber particles to the non-occlusion rubber particles in the unit area ranges from 1.1 to 14.
    Type: Application
    Filed: November 17, 2011
    Publication date: June 7, 2012
    Inventors: Chien-Chung WU, Chun-Ting KUO, Wen-Yi SU, Chen-Hsiang FANG
  • Patent number: 8119736
    Abstract: Branched polymers including multi-branched polymers, functionalized branched polymers, star-branched polymers, and dendigraft polymers. Methods for the synthesis of branched polymers and method for the use of branched polymers in tire components are also included.
    Type: Grant
    Filed: October 5, 2007
    Date of Patent: February 21, 2012
    Assignee: Bridgestone Corporation
    Inventors: Christopher G. Robertson, Sandra Warren, James Hall, Georg G. A. Böhm, Mark Arigo, Noriko Mori
  • Patent number: 8048947
    Abstract: The present invention provides a nanocomposite of a star branched elastomer and a clay. The nanocomposite can be a mixture of a halogenated star branched elastomer and a clay, desirably an exfoliated clay, suitable for use as an air barrier. The halogenated star-branched elastomer can be the primary halogenated elastomer in the blend, and a ratio of the star-branched elastomer to clay can be from 2:1 to 500:1.
    Type: Grant
    Filed: November 8, 2005
    Date of Patent: November 1, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Caiguo Gong, Carmen Neagu, Beverly Jean Poole, Anthony Jay Dias, Kriss Randall Karp, Molly Westermann Johnston
  • Patent number: 8034875
    Abstract: Compositions including a thermoplastic elastomer or thermoplastic vulcanizate derived from a styrenic block copolymer having a reactive or crosslinkable hard block including aromatic vinyl repeat units and also preferably a crosslinkable soft block, and a non-olefin thermoplastic polymer or copolymer and preferably a compatibilizer such as the reaction product of a non-olefin thermoplastic polymer and a functionalized polymer such as a maleic anhydride functionalized styrenic block copolymer that is compatible with the styrenic block copolymer having a reactive or crosslinkable hard block, and optionally a linking compound. The vulcanizates are prepared by crosslinking the styrenic block copolymer in the presence of the non-olefin thermoplastic polymer and a suitable crosslinking agent, and optionally the compatibilizer, preferably utilizing dynamic vulcanization.
    Type: Grant
    Filed: October 25, 2010
    Date of Patent: October 11, 2011
    Assignee: Teknor Apex Company
    Inventors: Darnell C. Worley, II, Elliot ByungHwa Lee, Raman Patel, Jushik Yun
  • Publication number: 20110244240
    Abstract: Disclosed is a graft copolymer highly improving the adhesion resistance and impact strength, a method of preparing the same, and PVC composition containing the same, wherein the graft copolymer comprises i) 55 to 85 wt % of a conjugated diene-based rubber core; and ii) 15 to 45 wt % of a graft shell surrounding the rubber core, and formed by comprising a (meth)acrylate-based monomer, and at least one selected from the group consisting of a vinyl-based monomer having a polyalkylene oxide group represented by the following Formula 1; in which the graft copolymer includes 0.1 to 5 wt % of the vinyl-based monomer having the polyalkylene oxide group represented by the following Formula 1: wherein R is independently hydrogen, or C1 to C4 alkyl group, and n is independently 3 to 14.
    Type: Application
    Filed: August 27, 2010
    Publication date: October 6, 2011
    Inventors: Yoon Ho Kim, Geon Soo Kim, Yeon Hwa Wi, Ki Hyun Yoo, Chan Hong Lee
  • Patent number: 7847024
    Abstract: Compositions including a thermoplastic elastomer or thermoplastic vulcanizate derived from a styrenic block copolymer having a reactive or crosslinkable hard block including aromatic vinyl repeat units and also preferably a crosslinkable soft block, and a non-olefin thermoplastic polymer or copolymer and preferably a compatibilizer such as the reaction product of a non-olefin thermoplastic polymer and a functionalized polymer such as a maleic anhydride functionalized styrenic block copolymer that is compatible with the styrenic block copolymer having a reactive or crosslinkable hard block, and optionally a linking compound. The vulcanizates are prepared by crosslinking the styrenic block copolymer in the presence of the non-olefin thermoplastic polymer and a suitable crosslinking agent, and optionally the compatibilizer, preferably utilizing dynamic vulcanization.
    Type: Grant
    Filed: February 23, 2007
    Date of Patent: December 7, 2010
    Assignee: Teknor Apex Company
    Inventors: Darnell C. Worley, II, Elliot ByungHwa Lee, Raman Patel, Jushik Yun
  • Patent number: 7812092
    Abstract: This invention discloses a process for synthesizing a hairy polymer particle which comprises the steps of (1) polymerizing a vinyl aromatic monomer by emulsion polymerization in an aqueous medium to produce core particles, (2) recovering the core particles from the aqueous medium, (3) dispersing the core particles in an organic solvent, (4) adding an organo-lithium compound to the dried core particles in the organic solvent to produce the hairless core initiator, and (5) utilizing the hairless core initiator to initiate the anionic polymerization of a conjugated diolefin monomer in an organic solvent to produce a solution of the hairy polymer particles. The hairy polymer nanoparticles can then be recovered from the organic solvent. These hairy polymer particles are comprised of (1) a core which is comprised of a polymer of a vinyl aromatic monomer and (2) hairs which are polymer chains of a conjugated diolefin monomer, wherein the hairs are covalently bonded to the core.
    Type: Grant
    Filed: June 10, 2008
    Date of Patent: October 12, 2010
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Lei Zheng, Eric Sean Castner, Thierry Florent Edme Materne
  • Publication number: 20100227965
    Abstract: A thermoplastic molding composition having reduced gloss sensitivity and no unpleasant odor is produced from a graft copolymer and a thermoplastic polymer. The graft copolymer is produced from a soft elastomeric particulate graft base obtained by emulsion polymerization of a conjugated diene alone or with a small amount of a monoethylenically unsaturated monomer, using an inorganic radical generating substance and a limited amount of chain transfer agent, upon which is grafted a vinyl aromatic monomer and acrylonitrile and optionally another monoethylenically unsaturated monomer using an inorganic radical generating substance while the use of a chain transfer agent is excluded. The thermoplastic polymer is a copolymer of a vinyl aromatic monomer and acrylonitrile and optionally an additional monoethylenically unsaturated monomer. The thermoplastic molding composition has a low level of unpleasant odor coupled with reduced gloss sensitivity and good mechanical properties.
    Type: Application
    Filed: August 3, 2006
    Publication date: September 9, 2010
    Applicant: BASF Aktiengesellschaft
    Inventors: Wil Duijzings, Davy Roger Suwier, Bernhard Czauderna, Norbert Niebner, Alexander Sauer, Michel Peper
  • Patent number: 7776963
    Abstract: Adhesive formulations having acrylate monomer or methacrylate monomer, or mixtures thereof, and having a reducing agent and an initiator (e.g., peroxide). The formulations may include a chelating agent solution to improve storage stability and other properties. Further, the mole ratio of the initiator to the reducing agent may be adjusted to control weight loss of the adhesives during cure. Polyvinyl acetate or its derivatives may also be employed in the adhesive formulations to reduce weight loss during cure. Moreover, certain embodiments of the formulations include a toughening-agent copolymer having a glass transition temperature (of at least one domain) that is lower than ?50° C. (?58° F.). These toughening-agent copolymers may be added to the adhesive formulations to improve impact strength and other properties of the cured adhesives at lower temperatures, e.g., ?40° C. (?40° F.), while maintaining performance of the cured adhesives at higher temperatures, e.g., 82° C. (180° F.).
    Type: Grant
    Filed: May 3, 2005
    Date of Patent: August 17, 2010
    Assignee: Illinois Tool Works Inc.
    Inventors: Xiaobin Wang, Daniel K. Doe, Patricia M. Savory, Kenneth A. Lambert
  • Patent number: 7723434
    Abstract: An olefinic thermoplastic elastomer with improved properties can be obtained by melting and kneading a graft copolymer, acrylic rubber, a crosslinking agent, and a co-crosslinking agent. The graft copolymer is composed of an olefin polymer segment formed from a nonpolar ?-olefin monomer and a vinyl polymer segment formed from a vinyl monomer, with particles of one segment being dispersed in the other segment. The particle diameter is 0.01 to 1 ?m. The acrylic rubber can be obtained by polymerizing a monomer mixture containing methoxyethyl acrylate.
    Type: Grant
    Filed: March 27, 2003
    Date of Patent: May 25, 2010
    Assignee: Nof Corporation
    Inventors: Motoyuki Sugiura, Toru Tamura, Takamitsu Kano, Toru Kato
  • Publication number: 20100010160
    Abstract: The present invention provides a polymer particle and a method of preparing the same. More precisely, the invention provides a polymer particle having optimum impact strength and improved elastic recovery rate by forming the brush having softness on the surface of the monodisperse polymer particle by the anion dispersion polymerization using a conjugated diene monomer.
    Type: Application
    Filed: November 19, 2007
    Publication date: January 14, 2010
    Applicant: LG CHEM, LTD.
    Inventors: Bo-ryeong Han, Moon-seok Chun, Do-yeon Park, Su-kyung Kim, Chong-min Koo, Bum-jae Lee, Choel-han Gang
  • Patent number: 7538157
    Abstract: The present invention provides a series of baroplastic materials, and systems and methods of making and using such baroplastic materials. In one aspect of the invention, polymeric particles are provided that can be used to produce baroplastic materials under certain pressures and/or below certain temperatures. In one set of embodiments, the polymeric particles include an inner “core” region and an outer “shell” region. In some cases, more than one “shell” region may be present. In another arrangement the particles can include materials, or domains, in nanoscale proximity with each other. Non-particulate materials can also be processed in accordance with the invention. In another aspect of the invention, the invention provides for polymeric particles that can be processed and/or recycled multiple times, without causing significant degradation or alteration in the physical and/or chemical properties of the polymer.
    Type: Grant
    Filed: June 29, 2005
    Date of Patent: May 26, 2009
    Assignee: Massachusetts Institute of Technology
    Inventors: Anne M. Mayes, Sang-Woog Ryu, Metin H. Acar, Juan A. Gonzalez
  • Patent number: 7514502
    Abstract: The present invention relates to an acrylonitrile (ASA) type thermoplastic resin composition with excellent weatherability and appearance properties, and more particularly, to an acrylate-styrene-acrylonitrile type thermoplastic resin composition comprising a) an acrylate-styrene-acrylonitrile graft copolymer; b) a butadienc-acrylonitrile methylmethacrylate graft copolymer; c) a copolymer of aromatic vinyl compound and vinylcyanide compound; and d) an alkyl acrylate copolymer, which has remarkably improved appearance properties such as scratch resistance, color (color stability) and gloss as well as excellent basic properties and weatherability.
    Type: Grant
    Filed: November 6, 2003
    Date of Patent: April 7, 2009
    Assignee: LG Chem, Ltd.
    Inventors: Dong-sung Kim, Chan-hong Lee, Seong-lyong Kim, Han-jong You
  • Patent number: 7510764
    Abstract: A pressure-sensitive adhesive composition comprising polymers and/or copolymers based at least predominantly on (meth)acrylic acid and/or derivatives thereof, wherein said composition possesses an outgassing level of not more than 50 ?g/g in total, preferably less than 10 ?g/g, when said composition is measured by the tesa method.
    Type: Grant
    Filed: February 15, 2002
    Date of Patent: March 31, 2009
    Assignee: tesa AG
    Inventors: Marc Husemann, Stephan Zöllner, Heiko Thiede, Reinhard Storbeck
  • Publication number: 20090022888
    Abstract: The invention is based on the recognition that known antimicrobial compounds, such as nisin or other lantibiotics, can be made to form a long lasting antimicrobial surface coating by linking the peptide with a block polymer, such as PLURONIC® F108 or an end group activated polymer (EGAP) in a manner to form a flexible tether and/or entrap the peptide. The entrapped peptide provides antimicrobial action by early release from entrapment while the tethered peptide provides longer lasting antimicrobial protection. Antimicrobial gels and foams may be prepared using the antimicrobial peptide containing block copolymers.
    Type: Application
    Filed: July 11, 2008
    Publication date: January 22, 2009
    Applicants: ALLVIVO VASCULAR, INC., State Univ.
    Inventors: Jennifer A. Neff, Joseph McGuire, Pranav R. Joshi
  • Patent number: 7314893
    Abstract: This invention relates to a core/shell impact modifier having as a core a copolymer or terpolymer having from 25 to 75 percent by weight of 2-ethylhexyl acrylate (2-EHA) monomer units with from 25 and 75 percent by weight of n-octyl acrylate (n-OA) monomer units. This core-shell impact modifier is used in performance polymers to improve low temperature impact performance.
    Type: Grant
    Filed: June 6, 2005
    Date of Patent: January 1, 2008
    Assignee: Arkema Inc.
    Inventors: Sheng Hong, Claude Granel
  • Patent number: 7294399
    Abstract: Disclosed is an improved weatherable thermoplastic composition. The composition is comprised of a copolymer of an alkyl acrylate or alkyl methacrylate and (methyl)methacrylate and a multi-stage, sequentially-polymerized impact modifier polymer. The copolymer is characterized by greater than 15 weight percent alkyl acrylate content. The multi-stage, sequentially-polymerized impact modifier is characterized by an elastomer stage, which is 55 percent by weight or greater of the impact modifier composition and is minimally crosslinked. The thermoplastic composition can be used in a wide range of film, sheet, or molded applications.
    Type: Grant
    Filed: March 24, 2003
    Date of Patent: November 13, 2007
    Assignee: Arkema France
    Inventors: Robert A. Wanat, Charles C. Crabb, Dennis J. Labanoski
  • Patent number: 7268186
    Abstract: The present invention relates to a sheet for a carrier tape, having at least one layer comprising (I) a block copolymer comprising a vinyl aromatic hydrocarbon and a conjugated diene, (II) a non-rubber-modified vinyl aromatic type hydrocarbon polymer, and (III) a rubber-modified vinyl aromatic type hydrocarbon polymer, wherein the peak molecular weight of the vinyl aromatic hydrocarbon polymer block in the block copolymer (I) is from 30,000 to 80,000, the half-width in the molecular weight distribution curve of the vinyl aromatic hydrocarbon block is from 1.3 to 2.8, the vinyl aromatic hydrocarbon content in the sheet for a carrier tape is from 75 to 95 wt %, and the content of the vinyl aromatic hydrocarbon polymer component is from 65 to 85 wt %.
    Type: Grant
    Filed: August 20, 2004
    Date of Patent: September 11, 2007
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Susumu Hoshi, Fumio Sugeno
  • Patent number: 7193013
    Abstract: The present invention provides a polyolefin-based resin composition, comprising (A) a polyolefin I produced from at least one monomer selected from the group consisting of ?-olefins, cyclic olefins and styrenes; (B) a polyolefin II produced from said at least one monomer, which differs in composition or properties from said polyolefin I; and (C) a graft copolymer produced by bonding said polyolefins I and II to each other through a polyene, wherein (a) a ratio [(1/R1)/(1/R1)0] of a relaxation velocity (1/R1) of a long-term relaxation component measured by a solid 1H-NMR method about the composition to a relaxation velocity (1/R1)0 of a long-term relaxation component measured by a solid 1H-NMR method about a resin mixture of only the components (A) and (B) is 1.01 or higher; and (b) an intrinsic viscosity [?] of the composition is in the range of 0.1 to 10 deciliter/g as measured in decalin at 135° C.
    Type: Grant
    Filed: February 6, 2002
    Date of Patent: March 20, 2007
    Assignee: Idemitsu Kosan Co. Ltd.
    Inventors: Shuji Machida, Kazuo Sato
  • Patent number: 7160946
    Abstract: A method for improving the cohesive strength at elevated temperature of a die attach adhesive formulation of a liquid curable resin, initiator, and filler, comprises adding to the adhesive formulation an aromatic bismaleimide resin powder that does not dissolve in the curable resin.
    Type: Grant
    Filed: April 1, 2004
    Date of Patent: January 9, 2007
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventor: Tadashi Takano
  • Patent number: 7119146
    Abstract: Compatibilized blends of an isoolefin polymer and an unsaturated diene polymer are prepared by utilizing a compatibilizing agent comprising a block/graft copolymer containing poly- or copoly-isoolefin segments and C4 to C6 alkyl-substituted styrene polymer segments, such as poly(t-butylstyrene) segments.
    Type: Grant
    Filed: August 19, 2002
    Date of Patent: October 10, 2006
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Mun Fu Tse, Hsien Chang Wang, Ramanan Krishnamoorti, Andy H. Tsou
  • Patent number: 7071246
    Abstract: This invention relates to a tread rubber composition for tires with the addition of crosslinked resinous nanoparticles having a high glass transition temperature (Tg) into elastomeric base polymers. The invention demonstrates greatly improved handling performance without deteriorating controllability and stability during high-speed running. The present invention discloses a rubber composition comprising: (1) a rubbery polymer and (2) from 1 to 30 parts per hundred parts of rubber by weight (phr) of pre-crosslinked polymer particles, wherein the pre-crosslinked polymer particles have a particle size which is within the range of 30 nm to 500 nm, wherein the pre-crosslinked polymer is comprised of repeat units that are derived from at least one monomer selected from the group consisting of acrylate monomers, vinyl aromatic monomers, acrylonitrile monomer, and vinyl halide monomers, and wherein the pre-crosslinked polymer has a glass transition temperature which is within the range of 30° C. to 200° C.
    Type: Grant
    Filed: April 13, 2004
    Date of Patent: July 4, 2006
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Feng Anne Xie, Lei Zheng, Eric Sean Castner
  • Patent number: 7071259
    Abstract: Functionalized propylene polymer compositions useful as coupling/compatibilizing agents are provided. The compositions are a mixture of two different functionalized propylene polymers. Polypropylene composites containing fillers and/or non-compatible resins and formulated using the mixed functionalized coupling/compatibilizing agents are also provided.
    Type: Grant
    Filed: July 27, 2004
    Date of Patent: July 4, 2006
    Assignee: Equistar Chemicals, LP
    Inventor: Maged G. Botros
  • Patent number: 7022763
    Abstract: A branched olefin copolymer demonstrating excellent performance in various uses, comprising a building block (A) represented by formula (1) below and a building block (B) represented by formula (2) below, obtained by e.g.
    Type: Grant
    Filed: October 9, 2003
    Date of Patent: April 4, 2006
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Tomoaki Matsugi, Nobuo Kawahara, Hideyuki Kaneko, Shingo Matsuo, Shin-ichi Kojoh, Norio Kashiwa
  • Patent number: 7012117
    Abstract: The present invention provides a water-dispersant resin composition for perforating a printed wiring board excellent in preciseness of the processing position and plating throwing power when perforating, a sheet for perforating using the composition, a process for perforating a printed wiring board using the sheet. More specifically, the present invention provides a water-dispersant resin composition for perforating a printed wiring board comprising a water-soluble polymer (A) and a polymer compound (B) containing the compound represented by the following formula (1) as a copolymer component, a sheet for perforating using the composition, and a process for perforating a printed wiring board using the sheet. (wherein, R represents hydrogen or a methyl group, and n represents an integer of 10 to 22).
    Type: Grant
    Filed: July 16, 2002
    Date of Patent: March 14, 2006
    Assignee: The Nippon Synthetic Chemical Industry Co., Ltd.
    Inventors: Tsukasa Izumi, Hiroaki Satoh
  • Patent number: 6878775
    Abstract: A pressure-sensitive adhesive composition based on (co)polymers of acrylic acid and/or methacrylic acid and/or derivatives thereof which has an at least two-phase domain structure and also an outgassing level of less than 10 ?g/g, based on the weight of the composition, when measured by the tesa method.
    Type: Grant
    Filed: February 12, 2002
    Date of Patent: April 12, 2005
    Assignee: tesa AG
    Inventors: Marc Husemann, Stephan Zöllner
  • Patent number: 6852799
    Abstract: Product, method and use of a copolymer AB as a compatibilizing agent between a polar thermoplastic polymer C and a polyolefine D. The method of making AB comprise the steps of: a) melting a copolymer (A) comprising a larger amount of methylmethacrylate units and a smaller amount of functional vinyl or (meth)acrylate units wherein functional moiety is selected in the group consisting of (a hydroxyl, a carboxylic, a glycidyl or an amine functional group); together with maleic anhydride grafted polypropylene (B) allowing condensation reaction to occur between the functions under “A” and the anhydride under “B”; b) the condensation copolymer obtained under a) is further melt together with the two polymers C and D to be homogenized, or melt processed as an interlayer between the two molten polymers.
    Type: Grant
    Filed: September 10, 2001
    Date of Patent: February 8, 2005
    Assignee: Universite de Liege
    Inventors: Alexandre Baidak, Christine Brassine, Jean-Marie Liegeois, Trazollah Ouhadi
  • Patent number: 6849689
    Abstract: Rubber-reinforced thermoplastic resins containing a copolymer resin (A1) obtained by polymerizing a vinyl monomer (b1) in the presence of an acrylic rubber-like polymer (a), or a mixture of copolymer resin (A1) and a (co)polymer (A2) of a vinyl monomer (b2). Acrylic rubber-like polymer (a) contains 50 to 98% by weight of acrylic rubber-like polymer particles (a1) which have a particle size of less than 350 nm and 2 to 50% by weight of acrylic rubber-like polymer particles (a2) which have a particle size of not less than 350 nm. The amount of the acrylic rubber-like polymer (a) is 5 to 80% by weight based on the rubber-reinforced thermoplastic resin.
    Type: Grant
    Filed: March 26, 2002
    Date of Patent: February 1, 2005
    Assignee: Techno Polymer Co., Ltd.
    Inventors: Gou Yamada, Hiromu Akatsuka, Takashi Kurata
  • Patent number: 6849687
    Abstract: A thermoplastic molding composition comprising a grafted acrylate rubber (ASA) and a gloss reducing agent and a process for making the same are disclosed. The gloss reducing agent is the reaction product of (i) an epoxidized grafted rubber having two or more epoxy groups in its graft phase and (ii) a compound having two or more terminal primary amine groups per molecule The gloss reducing agent may be either incorporated in ASA as the reaction product of (i) and (ii) or, in the altemative, formed upon the reaction of (i) with (ii) in the course of the thermal processing of the a blend containing ASA, (i) and (ii).
    Type: Grant
    Filed: August 1, 2002
    Date of Patent: February 1, 2005
    Assignee: Bayer Polymers LLC
    Inventors: Moh-Ching Oliver Chang, Allen R. Padwa, Norma I. Santiago
  • Patent number: 6812283
    Abstract: A process for the agglomeration of at least one rubber (A), dispersed in an aqueous phase, by the addition of a dispersion of at least one agglomerating polymer (B) in aqueous phase, in which the agglomerating polymer B used is one containing substantially no free acid groups and the agglomeration is carried out in the presence of at least one basic electrolyte.
    Type: Grant
    Filed: January 22, 2003
    Date of Patent: November 2, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Wil Duijzings, Sabine Oepen, Norbert Niessner, Michael Breulmann, Hardy Korb
  • Patent number: 6767962
    Abstract: A thermoplastic molding composition that contains a plurality of graft rubbers is disclosed. A first graft rubber is a product of emulsion polymerization of a mixture containing styrene and acrylonitrile in the presence of butadiene polymer latex (A) having an average particle diameter (d50) of 80 to 220 nm. An additional graft rubber is a product of emulsion polymerization of a mixture containing styrene and acrylonitrile in the presence of butadiene polymer latex (B) having an average particle diameter (d50) of 350 to 650 nm. The butadiene polymer latex (A) is the product of seed polymerization in which seed is butadiene polymer latex having a median particle diameter of 10 to 100 nm, and the butadiene polymer latex (B) is the product of agglomeration in which butadiene polymer latex (A) is the starting latex.
    Type: Grant
    Filed: July 26, 2002
    Date of Patent: July 27, 2004
    Assignee: Bayer Aktiengesellschaft
    Inventors: Herbert Eichenauer, Vera Buchholz, Eckhard Wenz
  • Patent number: 6737476
    Abstract: A brominated butyl rubber and a polymer based on a conjugated diolefin monomer are grafted by mixing the solid polymer at a temperature greater than 50° C. for a time sufficient to cause grafting. The grafted copolymer is useful especially in tire tread compositions.
    Type: Grant
    Filed: January 28, 2002
    Date of Patent: May 18, 2004
    Assignee: Bayer Inc.
    Inventor: William Hopkins
  • Patent number: 6734257
    Abstract: The block copolymers according to the invention which are based on conjugated diolefins and polar monomers and are prepared in the presence of catalysts based on the rare earth metals have a high cis-1,4 content in the polydiene block and, because of their polar polymer part and their non-polar diene polymer part, can be used as agents which impart compatibility in the preparation of vulcanizates with a filler content for the production of tires and tire component in the preparation of thermoplastic elastomers or in the modification of thermoplastics.
    Type: Grant
    Filed: March 21, 2002
    Date of Patent: May 11, 2004
    Assignee: Bayer Aktiengesellschaft
    Inventors: Heike Windisch, Werner Obrecht, Cristina Stere, Thomas Scholl, Oskar Nuyken, Lars Friebe, Mario Vierle
  • Patent number: 6730736
    Abstract: An alicyclic structure-containing resin composition comprising an alicyclic structure-containing resin (A) having a polar group in a proportion of 3 to 50 mol % based on the whole repeating unit in the resin, and a soft polymer (B), a varnish containing the resin composition, a sheet formed of the resin composition, and an insulating film formed of the resin composition.
    Type: Grant
    Filed: October 2, 2000
    Date of Patent: May 4, 2004
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Shojiro Kaita, Takashi Iga, Yasuhiro Wakizaka, Yasuo Tsunogae
  • Patent number: 6720386
    Abstract: Rubber modified weatherable styrenic blends with improved transparency and colorability are disclosed. A matrix phase of poly(alkyl alkylacrylate) and vinyl carboxylic acid ester-vinyl aromatic-vinyl cyanide terpolymer is combined with a rubbery graft phase of a poly(alkyl acrylate) rubber substrate grafted with a vinyl aromatic-vinyl cyanide superstrate copolymer to provide acrylate-styrene-acrylonitrile type (ASA) compositions.
    Type: Grant
    Filed: February 28, 2002
    Date of Patent: April 13, 2004
    Assignee: General Electric Company
    Inventors: Satish Kumar Gaggar, Kwan Hongladarom
  • Patent number: 6716917
    Abstract: A rubber-reinforced styrene transparent resin composition contains a styrene copolymer reinforced with a rubber polymer, wherein the monomer composition of an acetone soluble resin component contained in the resin composition contains 5 to 70% by weight of aromatic vinyl monomer (a1), 30 to 95% by weight of unsaturated carboxylic acid alkyl ester monomer (a2), 0 to 50% by weight of vinyl cyanide monomer (a3), and 0 to 50% by weight of another monomer copolymerizable with these monomers, and the acid value of the acetone soluble resin component is 0.01 to 1 mgKOH/g.
    Type: Grant
    Filed: July 26, 2001
    Date of Patent: April 6, 2004
    Assignee: Toray Industries, Inc.
    Inventors: Ryota Kido, Hiroshi Shibata, Hajime Takamura, Akihiro Ohmura, Yoshiyuki Yamamoto
  • Publication number: 20040024122
    Abstract: A thermoplastic molding composition comprising a grafted acrylate rubber (ASA) and a gloss reducing agent and a process for making the same are disclosed. The gloss reducing agent is the reaction product of (i) an epoxidized grafted rubber having two or more epoxy groups in its graft phase and (ii) a compound having two or more terminal primary amine groups per molecule The gloss reducing agent may be either incorporated in ASA as the reaction product of (i) and (ii) or, in the alternative, formed upon the reaction of (i) with (ii) in the course of the thermal processing of the a blend containing ASA, (i) and (ii).
    Type: Application
    Filed: August 1, 2002
    Publication date: February 5, 2004
    Inventors: Moh-Ching Oliver Chang, Allen R. Padwa, Norma I. Santiago
  • Patent number: 6673867
    Abstract: A heat-resistant engineering-plastic composition that satisfies a soldering-heat resistance of 260° C. for 10 to 60 secs., that is less costly, that is free of problems in injection molding process, and that is excellent in heat-aging resistance. A heat-resistant molded product made with the heat-resistant engineering-plastic composition, such as a connector mounted on printed circuit board. The heat-resistant molded product is produced by (a) melt-kneading (a1) an engineering plastic either having or introduced an active site for reacting with a specific functional group and (a2) either an organic compound that has both the said specific functional group and a polymerizing functional group in the same molecule or polyolefin that has the said specific functional group described in (a1) to obtain a resin composition, (b) melt-molding the resin composition comprising of (a), and (c) irradiating the melt-molded resin composition with ionizing radiation.
    Type: Grant
    Filed: November 13, 2001
    Date of Patent: January 6, 2004
    Assignee: Sumitomo Electric Fine Polymer, Inc.
    Inventors: Hiroshi Hayami, Shinya Nishikawa
  • Patent number: 6670419
    Abstract: A method of forming a toughened article from a blend of a thermoplastic polymer and a comb copolymer is disclosed, along with the toughened article produced thereby. Compositions such as solids blends and melt blends, including a thermoplastic polymer and a comb copolymer, are also disclosed.
    Type: Grant
    Filed: September 13, 2001
    Date of Patent: December 30, 2003
    Assignee: Rohm and Haas Company
    Inventors: Willie Lau, Paul Ralph Van Rheenen
  • Patent number: 6653401
    Abstract: Disclosed is a thermoplastic elastomer composition which comprises (A) a thermoplastic resin containing a polystyrene resin, (B) a rubber-like polymer obtained by partially or completely crosslinking an ethylene-&agr;-olefin copolymer and (C) a compatibilizing agent, the amount of the component (B) being 40-90 parts by weight and the amount of the component (C) being 0.1-40 parts by weight based on 100 parts by weight of the components (A), (B) and (C) in total. According to the present invention, an elastomer composition excellent in abrasion resistance can be provided.
    Type: Grant
    Filed: March 2, 2001
    Date of Patent: November 25, 2003
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Hideo Kinoshita, Ikuji Ohtani, Takeshi Yasui
  • Patent number: 6646047
    Abstract: The invention provides a process for the preparation of a thermoplastic elastomeric resin composition comprising melt kneading (a) 100 parts by weight of a block copolymer consisting of at least two polymeric blocks (A) composed mainly of a vinyl aromatic compound and at least one polymeric block (B) composed mainly of a conjugated diene compound, and/or a hydrogenated block copolymer obtained by hydrogenating said block copolymer, (b) 20 to 300 parts by weight of a non-aromatic softening agent for rubber, (c) 1 to 150 parts by weight of a peroxide-crosslinking type olefinic resin and/or a copolymeric rubber containing said resin, and (d) 10 to 150 parts by weight of a peroxide-decomposing type olefinic resin and/or a copolymer containing said resin, characterized in that the process comprises a step of heat-processing component (a), component (b), at least a part of component (c), at least a part of component (d) and at least a part of 1.
    Type: Grant
    Filed: April 30, 1999
    Date of Patent: November 11, 2003
    Assignee: Riken Technos Corporation
    Inventors: Michihisa Tasaka, Akihiro Tamura, Tetsuya Sawai
  • Patent number: 6630535
    Abstract: A composition comprising an elastomer, a filler, and a comb-like polymer, the comb-like polymer comprising a backbone and a plurality of side chains, the backbone having a length greater than or equal to the entanglement length, the side chains having a length greater than about 33% of the entanglement length, the backbone including at least one side chain per entanglement length, and the comb-like polymer having a Tg of less than −5° C.
    Type: Grant
    Filed: August 18, 2000
    Date of Patent: October 7, 2003
    Assignee: Bridgestone Corporation
    Inventors: Terrence E. Hogan, James A. Krom, James E. Hall, Xiaorong Wang, Peyman Pakdel, William L. Hergenrother
  • Patent number: 6620883
    Abstract: The invention relates to a process for the preparation of graft rubber polymers of the ABS type by emulsion polymerization according to the so-called fed batch process, in which latexes having markedly reduced residual monomer contents are obtained, and to compositions containing the mentioned graft rubber polymers.
    Type: Grant
    Filed: September 26, 2001
    Date of Patent: September 16, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Erich Gasche, Herbert Eichenauer, Pierre Vanhoorne, Ulrich Jansen, Eckhard Wenz, Stefan Moss
  • Patent number: 6586533
    Abstract: Articles are formed from a thermosetting composition based on polybutadiene or polyisoprene resins which are subjected to a high temperature cure step of greater than 250° C. The thermosetting compositions may include fillers such as particulate ceramic fillers and may also include woven webs for improved dimensional stability and decreased brittleness. The formation process of this invention is particularly well suited for making electrical circuit substrates for microwave and digital circuits, typically in the form of the thermosetting composition being laminated on one or both opposed surfaces to metal conductive foil (e.g., copper).
    Type: Grant
    Filed: May 4, 1994
    Date of Patent: July 1, 2003
    Assignee: World Properties, Inc.
    Inventors: Vincent R. Landi, J. Mark Mersereau, Walter A. Robbins, Michael E. St. Lawrence
  • Patent number: 6518361
    Abstract: Thermoplastic molding compositions are made from A) from 20 to 98% by weight of a particulate graft polymer and a non-elastomeric graft shell B) from 0.5 to 78.5% by weight of a thermoplastic styrene polymer or copolymer C) from 1 to 79% by weight of a second styrene copolymer and D) from 0.5 to 30% by weight of an isobutene polymer.
    Type: Grant
    Filed: October 3, 2000
    Date of Patent: February 11, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Norbert Güntherberg, Martin Weber, Gerhard Lindenschmidt, Hans Peter Rath