Radial Block Patents (Class 525/901)
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Patent number: 9845374Abstract: The present invention relates to novel block copolymers comprising at least one mono vinyl aromatic monomer (also referred to as mono vinylarene) and at least one conjugated diene monomer, in particular to styrene butadiene block copolymers (SBC), with a defined block structure. The invention further relates to polymer blends which comprise at least one block copolymer and at least one mono vinylarene acrylate copolymer, in particular a styrene-methyl methacrylate copolymer. Related methods for preparation and articles prepared from the polymer blends are also provided.Type: GrantFiled: July 7, 2014Date of Patent: December 19, 2017Assignee: INEOS STYROLUTION GROUP GMBHInventors: Norbert Niessner, Christof Mehler, Konrad Knoll, Thomas W. Cochran
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Patent number: 8895645Abstract: A modified-asphalt composition prepared by introducing a diene end-capped block copolymer with a molten asphalt composition, where the block copolymer is defined by the formula ?-(D-V-d)x where each D is independently a polydiene block, each V is independently a vinyl aromatic block, each d is a polydiene end cap, ? is a coupling moiety, and x is an integer from 2 to 10.Type: GrantFiled: November 8, 2013Date of Patent: November 25, 2014Assignees: Firestone Polymers, LLC, Heritage Research GroupInventors: Christine Rademacher, Timothy Reece, Herb Wissel, Daniel Graves, Peter Boerner
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Patent number: 8883927Abstract: A process for making a radial multi-block copolymer, comprising: (a) anionically polymerizing styrene monomer A1, at least one monovinylarene monomer A2 other than styrene and at least one conjugated diene monomer B using a lithium-based initiator to form block copolymer chains; (b) adding a metal alkyl compound other than the lithium-based initiator after initiating anionic polymerization in step (a), wherein the molar ratio of the metal alkyl compound to lithium is greater than about 2.0; and (c) adding a coupling agent having more than two functional groups to form the radial multi-block copolymer, wherein the radial multi-block copolymer comprises a residue Z derived from the coupling agent and block copolymer chains from step (b) coupled to the residue Z.Type: GrantFiled: November 25, 2008Date of Patent: November 11, 2014Assignee: Dynasol Elastómeros, S.A. de C.V.Inventors: José Manuel Rojas García, Gerardo Gutiérrez Cruz, Norma Alicia Hernández Beltrán
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Patent number: 8580874Abstract: A modified-asphalt composition prepared by introducing a diene end-capped block copolymer with a molten asphalt composition.Type: GrantFiled: April 18, 2008Date of Patent: November 12, 2013Assignees: Firestone Polymers, LLC, Heritage Research GroupInventors: Herb Wissel, Peter Boerner, Daniel Graves, Christine Rademacher, Timothy Reece
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Patent number: 8552114Abstract: The present invention provides a block copolymer composition and method of making the same having the structures (A2-B)n-X-(A1) or (A2-B2)n-X-(B1A1), where A1 and A2 are each a polymer block of a monoalkenyl arene and B, B1, and B2 are each a polymer block of one or more conjugated dienes or a hydrogenated diene polymer, n is an integer from 2 to 30 and X is the residue of a coupling agent.Type: GrantFiled: November 30, 2012Date of Patent: October 8, 2013Assignee: Kraton Polymers U.S. LLCInventors: Dale Lee Handlin, Jr., Peter Pasman, Glenn H. Fredrickson, Carl L. Willis, Robert C. Bening
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Patent number: 8324309Abstract: The present invention provides a low viscosity block copolymer for non-wovens construction adhesives of the formula [A?(A/B)]nX, wherein A represents an aromatic vinyl compound and (A/B) represents a polymer block obtained by random copolymerization of a mixture of a aromatic vinyl compound and butadiene in a weight ratio in the range of from 2:98 to 30:70, wherein n is an integer in the range of from 1 to 5, and wherein X is the remainder of the coupling agent.Type: GrantFiled: April 27, 2010Date of Patent: December 4, 2012Assignee: Kraton Polymers US LLCInventor: Donn Dubois
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Patent number: 8188192Abstract: Elastomeric films which are both soft and thermally, UV and oxidatively stable are provided. The films are composed of coupled, selectively hydrogenated block copolymers having a relatively high molecular weight and high vinyl content. In addition to the block copolymer other components may be present in formulated films such as other block copolymers, hydrocarbon resins, polyolefins, metallocene polyolefins, homopolystyrene or mineral oils. The softness of the films is determined by the stress at 100% tensile elongation where the films with suitable softness have a 100% stress of about 100 psi or less. While soft, the films also are strong with tensile strengths of 1000 psi or more and suitable hysteresis properties. The elastomeric films are useful as integral components of personal hygiene articles such as gloves, diapers, incontinence products, disposable swimwear and disposable undergarments.Type: GrantFiled: December 19, 2008Date of Patent: May 29, 2012Assignee: Kraton Polymers U.S. LLCInventors: Dale Lee Handlin, Jr., Phillip Doerpinghaus, Sandra Horton, legal representative, Keith Eiden, Margaret Clawson
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Patent number: 8147974Abstract: A composition comprising: a)one or more film forming resins having at least one functional group capable of polymerization; b) one or more adhesion promoters comprising compounds containing one or more unsaturated groups capable of free radical polymerization and one or more trialkoxy silane groups; c) one or more fillers capable of imparting abrasion resistance to the composition; d) one or more compounds which is reactive with the film forming resin which also contains an acidic moiety; and e) one or more compounds comprising a siloxane backbone and one or more active hydrogen groups capable of reacting with the functional groups on a glass bonding adhesive: one or more second adhesion promoters comprising one or more silicon, titanium, zirconium, aluminum, or metal containing compounds; organic materials having reactive groups reactive with reactive groups on the surface of substrates or adhesives; or mixtures thereof.Type: GrantFiled: December 18, 2008Date of Patent: April 3, 2012Assignee: Dow Global Technologies LLCInventors: Kiran Baikerikar, Syed Z. Mahdi, Ben W. Schaefer
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Patent number: 8124693Abstract: Various novel block cationomers comprising polyisobutylene (PIB) and poly(2-dimethylamino)ethyl methacrylate) (PDMAEMA) segments have been synthesized and characterized. The specific targets were various molecular weight diblocks (PDMAEMA+) and triblocks (PDMAEMA+-b-PIB-b-PDMAEMA+) with the PIB blocks in the DPn=50-200 (Mn=3,000-9,000 g/mol) range connected to blocks of PDMAEMA+ cations in the DPn=5-20 range. The overall synthetic strategy for the preparation of these block cationomers comprised four steps: 1) Synthesis by living cationic polymerization of mono- and di-allyltelechelic polyisobutylenes, 2) End group transformation to obtain PIBs fitted with termini capable of mediating the atom transfer radical polymerization (ATRP) of DMAEMA, 3) ATRP of DMAEMA and 4) Quaternization of PDMAEMA to PDMAEMA+I? by CH3I. Kinetic and model experiments provided guidance to develop convenient synthesis methods.Type: GrantFiled: November 28, 2006Date of Patent: February 28, 2012Assignee: The University of AkronInventors: Joseph P. Kennedy, Zheng Fang
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Patent number: 7001956Abstract: The present invention relates to articles prepared from novel anionic block copolymers of mono alkenyl arenes and conjugated dienes, and to blends of such block copolymers with other polymers. The block copolymers are selectively hydrogenated and have mono alkenyl arene end blocks and conjugated diene mid blocks. The block copolymer may be blended with at least one other polymer selected from the group consisting of olefin polymers, styrene polymers, amorphous resins and engineering thermoplastic resins.Type: GrantFiled: June 4, 2003Date of Patent: February 21, 2006Assignee: Kraton Polymers U.S. LLCInventors: Dale Lee Handlin, Jr., Carl Lesley Willis, Hendrik de Groot, Margaret Ann Burns Clawson, Gert Joly, Catherine Maris, Lie Djiauw
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Patent number: 6933005Abstract: A method for repairing a basecoat/clearcoat finish or coating comprised of a fluorinated organosilane topcoat. A fluorourethane star polyester additive is added to the fluorinated organosilane topcoat composition to improve recoat adhesion with the repair basecoat.Type: GrantFiled: September 22, 2003Date of Patent: August 23, 2005Assignee: E. I. du Pont de Nemours and CompanyInventors: William F. Graham, Douglas Robert Anton, Jeffery W. Johnson, Michael Joseph Michalczyk, Sape Kwesi Quashie
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Patent number: 6890991Abstract: The present invention relates to a thermoplastic resin composition which has an improved impact resistance while maintaining mechanical properties such as strength and rigidity. In the present invention, a thermoplastic resin (A) is mixed with a polytetrafluoroethylene-containing mixed powder (B) consisting of a polytetrafluoroethylene (b1) having a particle diameter of 10 ?m or less and an organic polymer (b2). In this case, the polytetrafluoroethylene-containing mixed powder (B) is mixed so that the amount of a polytetrafluoroethylene component is from 0.0001 to 20 parts by weight based on 100 parts by weight of the thermoplastic resin (A), and a polymer having an epoxy group was used as the organic polymer (b2). The thermoplastic resin composition of the present invention can be widely used in the fields of automotive parts, electric and electronic parts, and precision instrument parts.Type: GrantFiled: March 21, 2001Date of Patent: May 10, 2005Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Hideyuki Fujimoto, Atsunori Koshirai
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Patent number: 6747095Abstract: An objective of the invention is to provide a rubber composition which has satisfactory processability and dimension stability, and the like, gives a vulcanized rubber exhibiting excellent wearing resistance and tensile strength, and the like, and thus is useful in a belt, a hose and a tire and the like, as well as a crosslinked rubber particle for obtaining such rubber composition. A rubber composition of the invention comprises [1] a crosslinked rubber particle comprising as repeating units (a) 30 to 94.89% by weight of a conjugated diene unit, (b) 5 to 69.89% by weight of an aromatic vinyl unit, (c) 0.01 to 10% by weight of a monomer unit having at least two polymerizable unsaturated group, (d) one polymerizable unsaturated group and an amino group, a hydroxyl group and an epoxy group and (e) 0.Type: GrantFiled: April 26, 2001Date of Patent: June 8, 2004Assignee: JSR CorporationInventors: Tomohisa Konno, Toshihiro Tadaki, Yoshiyuki Udagawa, Hiroshi Akema
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Patent number: 6492449Abstract: The present invention concerns polymers obtained by anionic initiation and bearing functions that can be activated by cationic initiations that are not reactive in the presence of anionic polymerization initiators. The presence of such cationic initiation functions allow an efficient cross-linking of the polymer after moulding, particularly in the form of a thin film. It is thus possible to obtain polymers with well-defined properties in terms of molecular weight and cross-linking density. The polymers of the present invention are capable of dissolving ionic compounds inducing a conductivity for the preparation of solid electrolytes.Type: GrantFiled: May 7, 2002Date of Patent: December 10, 2002Assignee: Hydro-QuebecInventors: Christophe Michot, Alain Vallée, Paul-Étienne Harvey, Michel Gauthier, Michel Armand
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Patent number: 6462137Abstract: The present invention relates to star-block interpolymers having the following structure (X-Y)n-C, wherein X represents a random copolymer block derived from conjugated diene and monovinyl aromatic monomer; Y represents a polyconjugated diene block; C represents a residue derived from a multifunctional lithium based initiator; and n represents the functionality of the initiator and has a value of not less than 3; and preparation of the same. The star-block interpolymers according to the present invention have in the same molecule both a random copolymer block derived from conjugated diene and monovinyl aromatic monomer and a rubber block selected from the group consisting of a homopolymer block derived from conjugated diene, a tapered copolymer block derived from conjugated dienes, a random copolymer block derived from conjugated dienes and combinations thereof, and hence possess excellent properties of the both kinds of rubbers, and can be used widely as elastomeric materials.Type: GrantFiled: October 18, 2001Date of Patent: October 8, 2002Assignees: China Petroleum and Chemical Corporation, Research Institute of Beijing Yanshan Petrochemical Co., Ltd.Inventors: Yang Li, Hongde Xu, Yurong Wang, Dingyi Hong, Mingchu Gu, Mei Wang, Zhanxia Lü, Aili Xu
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Patent number: 5733979Abstract: Catalytic solids based on titanium trichloride complex, usable for the stereospecific polymerisation of alpha-olefins, obtained by heat treatment, in the presence of a halogenated activating agent, of the liquid material resulting from bringing TiCl.sub.4, pretreated with an electron-donor compound, into contact with a composition (C) corresponding to the general formulaAlR.sub.p (Y).sub.q X.sub.3-(p+q)in whichR represents a hydrocarbon radical or a hydrogen atom;Y represents a group chosen from --OR', --SR' and --NR'R", in which R' and R" each represent a hydrocarbon radical or a hydrogen atom;X represents a halogen;p is an arbitrary number such that 0<p<3; andq is an arbitrary number such that 0<q<3;the sum (p+q) being such that 0<(p+q).ltoreq.3.These catalytic solids of controllable porosity permit the production of a wide range of propylene polymers, in particular the propylene and ethylene copolymers known as "block" copolymers.Type: GrantFiled: February 18, 1993Date of Patent: March 31, 1998Assignee: Solvay (Societe Anonyme)Inventors: Jean-Louis Costa, Sabine Pamart
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Patent number: 5723511Abstract: A process for the preparation of branched thermoplastic resins comprising: heating a mixture of a free radical initiator, at least one first free radical reactive monomer, at least one free radical reactive branching agent compound, and at least one stable free radical agent, to produce a linear or unbranched polymer product with a free radical initator fragment at one end and a covalently bonded stable free radical agent at the other end of the polymerized chain of monomers; and irradiating the unbranched polymer product in the presence of a reactive compound selected from the group consisting of a free radical reactive monomer, a branching agent compound, and mixtures thereof to form a branched polymeric product.Type: GrantFiled: June 17, 1996Date of Patent: March 3, 1998Assignee: Xerox CorporationInventors: Peter M. Kazmaier, Barkev Keoshkerian, Karen A. Moffat, Michael K. Georges, Gordon K. Hamer, Richard P. N. Veregin
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Patent number: 5721316Abstract: A process for incorporation of epoxidized polydienes into aromatic epoxy resins which comprises (a) blending the epoxidized polydiene into a curing agent in a ratio of 1:20 to 1:4, (b) reacting the epoxidized polydiene and a curing agent at a temperature of from 100.degree. to 150.degree. C. over a time from 10 to 100 minutes, (c) mixing the pre-reacted epoxidized polydiene and curing agent with the aromatic epoxy resin and accelerator, and (d) curing the aromatic epoxy resin by heating the full mixture of paragraph (c) to a temperature of from 110.degree. to 170.degree. C. for from 2 to 6 hours.Type: GrantFiled: July 3, 1996Date of Patent: February 24, 1998Assignee: Shell Oil CompanyInventors: Michael Alan Masse, Kailash Dangayach, James Robert Erickson
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Patent number: 5635543Abstract: Disclosed is an expanded foamed bead of a rubber-modified styrene polymer, comprising a plurality of closed cells defined by cell walls which constitute a matrix for the bead, wherein each of the cell walls comprises two surfaces separated by a distance equal to the thickness of the cell wall.Type: GrantFiled: June 11, 1996Date of Patent: June 3, 1997Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Masamichi Kaneko, Isao Kiba
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Patent number: 5585441Abstract: A thermoplastic composition comprising a crystalline propylene polymer and as a modifying elastomer, a hydrogenated butadiene polymer which is either an essentially linear hydrogenated butadiene homopolymer or a star-branched polymer, the arms of which are an essentially linear hydrogenated butadiene homopolymer, such hydrogenated butadiene polymer containing from about 20 to about 90% of polymerized butadiene units with the 1,2-microstructure and having a polydispersity index (P.I.) of about 1.01 to 1.50. The compositions have a superior combination of processing and mechanical properties such as flexural strength, impact resistance, and melt flow.Type: GrantFiled: May 22, 1995Date of Patent: December 17, 1996Assignee: Mobil Oil CorporationInventors: Ellen B. Brandes, Margaret D. Monahan, Steven L. Schafer
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Patent number: 5525639Abstract: Disclosed is an expanded foamed bead of a rubber-modified styrene polymer, comprising a plurality of closed cells defined by cell walls which constitute a matrix for the bead, wherein each of the cell walls comprises two surfaces separated by a distance equal to the thickness of the cell wall.Type: GrantFiled: November 2, 1994Date of Patent: June 11, 1996Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Masamichi Keneko, Isao Kiba
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Patent number: 5512626Abstract: Rubber composition for a base tread, which is obtainable by blending, per 100 parts by weight of a rubber component, 30 to 55% by weight of a carbon black having an iodine adsorption value of from 40 to 100 g/kg, wherein the rubber component comprises (A) 20 to 55% by weight of a star shaped solution-polymerized butadiene rubber and (B) 45 to 80% by weight of a natural rubber or a natural rubber containing a diene rubber other than a star shaped solution-polymerized rubber in an amount of not more than 50% by weight. When using the above-mentioned rubber composition for the base tread of a base portion of a tread having a cap/base two-layer structure, it is possible to save fuel consumption of the tire because of small deformation and uniform shape.Type: GrantFiled: October 7, 1994Date of Patent: April 30, 1996Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Toshiro Matsuo, Naohiko Kikuchi
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Patent number: 5504156Abstract: A thermoplastic elastomer composition which comprises (I) 99 to 1% by weight of a hydrogenated diene copolymer having a number average molecular weight of 50000 to 700,000 in which 80% or more of the double bonds of the conjugated diene portion of the conjugated diene polymer have been saturated, (II) 1 to 99% by weight of an ionomer resin having an .alpha.-olefin unit having 2 to 8 carbon atoms and an .alpha.,.beta.-unsaturated carboxylic acid unit, at least part of the carboxyl group of said unsaturated carboxylic acid unit having been neutralized with a metal ion, and (III) 0 to 70% by weight of a polyolefin resin, provided that (I)+(II)+(III)=100% by weight. Said composition is excellent in moldability and gives a molded article excellent in transparency, flexibility, mechanical strength, heat resistance and impact resilience.Type: GrantFiled: December 14, 1994Date of Patent: April 2, 1996Assignee: Japan Synthetic Rubber Co., Ltd.Inventors: Yoshiyuki Takezaki, Junji Kojina, Kazumi Nejigaki, Yoshihisa Fujinaga
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Patent number: 5458791Abstract: The present invention includes star polymers which can be used as viscosity index improvers in oil compositions formulated for high performance engines. The star polymers have triblock copolymer arms of hydrogenated polyisoprene and polystyrene wherein the polystyrene is placed near the core of the star polymer to provide excellent low temperature performance and finishability as a polymer crumb.Type: GrantFiled: July 1, 1994Date of Patent: October 17, 1995Assignee: Shell Oil CompanyInventors: Robert B. Rhodes, Craig A. Stevens
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Patent number: 5432232Abstract: A rubber composition satisfying wear resistance and fracture properties as well as wet skid resistance, ice skid resistance and dry gripping property is provided by including at least 30% by weight of a rubber ingredient which consists of 100 parts by weight of a particular branched styrene-butadiene copolymer (A) and 15-100 parts by weight of a particular low molecular weight butadiene polymer (B) and has a Mooney viscosity of 30-100.Type: GrantFiled: August 12, 1993Date of Patent: July 11, 1995Assignees: Japan Synthetic Rubber Co., Ltd., Bridgestone CorporationInventors: Iwakazu Hattori, Toshihiro Tadaki, Tatsuro Hamada, Fuji Yamanaka
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Patent number: 5429826Abstract: There is provided copolymer particles wherein the particles are derived from chemically fixed micelles that comprise a copolymer. The copolymer is an amphiphilic block or graft copolymer comprising a water soluble component and an oleophilic component that can be crosslinked in an aqueous environment; and the oleophilic component is crosslinked. The particles can be dispersed in an aqueous continuous phase. The particles can contain other materials associated with the oleophilic component such as biochemical agents or other materials such as photographic materials such as couplers and dyes.Type: GrantFiled: October 18, 1993Date of Patent: July 4, 1995Assignee: Eastman Kodak CompanyInventors: Mridula Nair, Youngtai Yoo
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Patent number: 5428114Abstract: An epoxidized diene star polymer having greater than 4 arms and comprising from 0.05 to 5 Meq of di-, tri- and tetra-substituted olefinic epoxides and the molecular weights of the arms are from 1,500 to 15,000.Type: GrantFiled: May 3, 1994Date of Patent: June 27, 1995Assignee: Shell Oil CompanyInventors: James R. Erickson, Steven H. Dillman, Dale L. Handlin, Jr., Carl L. Willis, Robert J. Sutherland
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Patent number: 5409972Abstract: This invention relates to a process for the preparation of self-crosslinking cationic paint binders which can be diluted with water after protonation and are based on modified aminoalkylation products of phenols; to the binders prepared by this process and to their use for formulating water-dilutable paints, in particular electrodeposition paints which can be deposited cathodically. The process is characterized in that an aminoalkylation product of a phenol containing at least one secondary amino group is reacted with epoxide compounds, and after temperature treatment, the reaction product is reacted with partly blocked isocyanate compounds. The process permits the use of blocking agents which allow stoving temperatures in the range of 130 to 150.degree. C.Type: GrantFiled: May 7, 1992Date of Patent: April 25, 1995Assignee: Vianova Kunstharz, A.G.Inventors: Roland Feola, Willibald Paar, Georg Pampouchidis, Johann Gmoser, Helmut Honig
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Patent number: 5266648Abstract: A symmetric star block copolymer having and exhibiting one phase melt behavior comprising from about 3 to 30 arms, wherein each of said arm has a molecular weight of from about 20,000 to 35,000; said arms coupled with a suitable coupling agent; and wherein said arms comprises monomers of monoalkenyl aromatic hydrocarbon and conjugated diolefins; and wherein said monoalkenyl aromatic hydrocarbon is present in an amount of from about 20 to 40 wt % of the star block copolymer. Also disclosed is a process for preparing these one phase melt block copolymers.Type: GrantFiled: September 27, 1991Date of Patent: November 30, 1993Assignee: Shell Oil CompanyInventor: Michael A. Masse
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Patent number: 5247026Abstract: An epoxidized diene star polymer having greater than 4 arms and comprising from 0.05 to 5 Meq of di-, tri- and tetra-substituted olefinic epoxides and the molecular weights of the arms are from 1,500 to 15,000.Type: GrantFiled: June 19, 1992Date of Patent: September 21, 1993Assignee: Shell Oil CompanyInventors: James R. Erickson, Steven H. Dillman, Dale L. Handlin, Jr., Carl L. Willis, Robert J. Sutherland
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Patent number: 5019628Abstract: Acrylic star polymers containing polysiloxanylalkyl ester groups in their arms and terminal organo groups containing a polymerizable carbon-carbon double bond are useful for improving polymer compositions for contact lenses.Type: GrantFiled: April 10, 1990Date of Patent: May 28, 1991Assignee: E. I. du Pont de Nemours and CompanyInventor: Harry J. Spinelli
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Patent number: 5003007Abstract: Novel copolymer blends comprising (a) a copolymer of alkenyl aromatic monomers containing from about 10 to about 70 percent by weight of an isopropenyl aromatic monomer, (b) a block copolymer of polystyrene blocks and conjugated diene blocks containing from about 50 to about 80 weight percent conjugated diene, and (c) 15 to 50 weight percent of a semicrystalline polyolefin.Type: GrantFiled: May 19, 1989Date of Patent: March 26, 1991Assignee: The Dow Chemical CompanyInventors: John F. Vitkuske, Corwin J. Bredeweg
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Patent number: 4956415Abstract: Block copolymers are prepared by providing an initial anionically polymerizable monomer portion; anionically polymerizing the initial monomer portion to provide polymer chains with living ends, and contacting the polymer chains with m-bis(phenylethenyl)benzene (PEB), a coupling agent, to bring about substantial coupling. In preferred embodiments the polymer chain living ends are capped with an .alpha.-alkylstyrene or a ring-alkyl substituted .alpha.-alkylstyrene, wherein the .alpha.-alkyl groups contain between about 1 to about 20 carbon atoms, and the ring-alkyl groups have at least 2 carbon atoms. The coupling agents employed with the capped polymer chain living ends include PEB, p-dibromoxylene, terephthaloyl chloride, 1,4-dibromobutene; and the multifunctional epoxides, multifunctional isocyanates, multifunctional aziridines, multifunctional aldehydes, multifunctional ketones, multifunctional anhydrides, multifunctional esters, and polyhalides.Type: GrantFiled: November 7, 1989Date of Patent: September 11, 1990Assignee: The Dow Chemical CompanyInventor: Kent S. Dennis
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Patent number: 4885343Abstract: Block copolymers are prepared by providing an initial anionically polymerizable monomer portion; anionically polymerizing the initial monomer portion to provide polymer chains with living ends, and contacting the polymer chains with m-bis(phenyletheynl)benzene (PEB), a coupling agent, to bring about substantial coupling. In preferred embodiments the polymer chain living ends are capped with an .alpha.-alkylstyrene or a ring-alkyl substituted .alpha.-alkylstyrene, wherein the .alpha.-alkyl groups contain between about 1 to about 20 carbon atoms. and the ring-alkyl groups have at least 2 carbon atoms. The coupling agents employed with the capped polymer chain living ends include PEB, p-dibromoxylene, terephthaloyl chloride, 1,4-dibromobutene; and the multifunctional epoxides, multifunctional isocyanates, multifunctional aziridines, multifunctional aldehydes, multifunctional ketones, multifunctional anhydrides, multifunctional esters, and polyhalides.Type: GrantFiled: March 3, 1989Date of Patent: December 5, 1989Assignee: The Dow Chemical CompanyInventor: Kent S. Dennis
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Patent number: 4839430Abstract: Block copolymers are prepared by providing an initial anionically polymerizable monomer portion; anionically polymerizing the initial monomer portion to provide polymer chains with living ends, and contacting the polymer chains with m-bis(phenylethenyl)benzene (PEB), a coupling agent, to bring about substantial coupling. In preferred embodiments the polymer chain living ends are capped with an .alpha.-alkylstyrene or a ring-alkyl substituted .alpha.-alkylstyrene, wherein the .alpha.-alkyl groups contain between about 1 to about 20 carbon atoms, and the ring-alkyl groups have at least 2 carbon atoms. The coupling agents employed with the capped polymer chain living ends include PEB, p-dibromoxylene, terephthaloyl chloride, 1,4-dibromobutene; and the multifunctional epoxides, multifunctional isocyanates, multifunctional aziridines, multifunctional aldehydes, multifunctional ketones, multifunctional anhydrides, multifunctional esters, and polyhalides.Type: GrantFiled: April 1, 1987Date of Patent: June 13, 1989Assignee: The Dow Chemical CompanyInventor: Kent S. Dennis
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Patent number: 4760122Abstract: Novel polyorganosiloxane polymers having at least one terminal cyclic diorganosiloxane moiety containing a plurality of acrylic units of the formula ##STR1## wherein R.sup.1 is H or lower alkyl; X is O, NH or S; and Y is a divalent linking group.Type: GrantFiled: January 6, 1986Date of Patent: July 26, 1988Assignee: Loctite CorporationInventors: Steven T. Nakos, Samuel Q. Lin
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Patent number: 4737545Abstract: A composition comprisinga. a major amount of an aromatic carbonate polymer;b. a minor amount of an aromatic carbonate polymer impact modifying composition comprising(i) a linear, sequential, or radial teleblock copolymer resin of a vinyl aromatic compound (A).sub.n and (A').sub.n and an olefinic elastomer (B), of the A--B--A'; A--(B--A--B).sub.n --A; A(--BA).sub.n B; B(A).sub.4 B; B(A).sub.4 ; or B((AB).sub.n B).sub.4 type, wherein n is an integer of from 1 to 10;(ii) an olefin alkylacrylate wherein the alkyl is one to six carbon atoms and the olefin is two to about five carbon atoms, inclusive, the olefin being from about 55 to 75 weight percent and the alkylacrylate from about 25 to 45 weight percent of the olefin alkylacrylate, said olefin alkylacrylate bringing about increased resistance of the composition comprising a and b to environmental stress crazing and cracking caused by gasoline.Type: GrantFiled: December 16, 1986Date of Patent: April 12, 1988Assignee: General Electric CompanyInventors: Ping Y. Liu, Toshio Ishihara
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Patent number: 4638033Abstract: A resin composition comprising:(i) a blend of at least one aromatic carbonate resin and at least one grafted derivative of an ethylene-propylene-diene terpolymer; and(ii) an amount at least effective to improve the impact properties and resistance to organic solvents of said blend of at least one polymer selected from(a) a polyolefin,(b) an olefin-acrylate or methacrylate copolymer, or(c) at least one selectively hydrogenated linear, sequential or radial teleblock copolymer of a vinyl aromatic compound and an olefin elastomer.Type: GrantFiled: December 23, 1985Date of Patent: January 20, 1987Assignee: General Electric CompanyInventors: Omar M. Boutni, Ping Y. Liu
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Patent number: 4617345Abstract: The invention relates to polymer mixtures which comprise an aromatic polycarbonate resin, a block copolymer, and a graft copolymer. The polymer mixtures according to the invention have a good impact strength, in particular at low temperatures, and do not show any delamination phenomena when injection molded.Type: GrantFiled: July 31, 1985Date of Patent: October 14, 1986Assignee: General Electric CompanyInventor: Willem L. Sederel
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Patent number: 4611030Abstract: A composition for pneumatic tires including more than 30% of star shaped styrene-butadiene copolymers by solution polymerization with or without one or more types of natural rubbers or diene series synthetic rubbers. The composition value X of the solution polymerization star shaped SBR is obtained by the following equation. ##EQU1## wherein BR is the butadiene component and the vinyl content is the content of 1, 2 bonded butadiene in butadiene component. The value X falls in the range of the lower limit of 26 to the upper limit of 39. And the coupling efficiency of the solution polymerization star shaped SBR is more than 40%.Type: GrantFiled: March 25, 1985Date of Patent: September 9, 1986Assignee: Toyo Tire and Rubber Co., Ltd.Inventors: Masanori Kan, Hideo Fujiwara
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Patent number: 4598123Abstract: A clear, cast acrylic sheet of improved impact strength may be prepared by dispersing or dissolving 8-14% of an ABA block copolymer, (where A is styrene, B is a hydrogenated butadiene, containing a large 1-2 butadiene fraction) in a methyl methacrylate casting mixture which contains 0.1- 20% styrene, and polymerizing in sheet form by heating with free-radical initiators.Type: GrantFiled: May 1, 1985Date of Patent: July 1, 1986Assignee: Unites States Steel CorporationInventor: Louis A. Cutter
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Patent number: 4579903Abstract: Copolyester-carbonate composition exhibiting improved resistance to organic solvents comprising, in admixture:(i) at least one aromatic copolyester-carbonate resin;(ii) at least one aromatic polycarbonate resin;(iii) at least one selectively hydrogenated block copolymer of a vinyl aromatic compound and an olefinic elastomer; and(iv) at least one polymer selected from an olefin acrylate copolymer, an olefin diene terpolymer, or mixtures thereof. The instant composition also exhibits improved impact properties and relatively high heat resistance.Type: GrantFiled: December 19, 1984Date of Patent: April 1, 1986Assignee: General Electric CompanyInventors: Ping Y. Liu, Edward L. Belfoure
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Patent number: 4564655Abstract: Polycarbonate composition exhibiting improved resistance to organic solvents comprised of, in admixture:(i) at least one high molecular weight thermoplastic aromatic polycarbonate resin;(ii) at least one selectively hydrogenated linear, sequential or radial teleblock copolymer resin of a vinyl aromatic compound (A).sub.n and (A').sub.n and an olefinic elastomer (B), of the A--B--A', A--(B--A--B).sub.n, A(BA).sub.n B, (A).sub.4 B, B(A).sub.4 or B((AB).sub.n B).sub.4 type wherein n is an integer of from 1 to 10; and(iii) at least one olefin-rubbery diene terpolymer; components (ii) and (iii) being present in amounts effective to improve the organic solvent resistance of said composition.The instant composition is useful in the production of extruded sheets and films, and injection or blow molded articles.Type: GrantFiled: December 10, 1984Date of Patent: January 14, 1986Assignee: General Electric CompanyInventor: Ping Y. Liu
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Patent number: 4553578Abstract: A tire having a tread exhibiting substantial low rolling resistance, traction and wear comprises a cured compounded carbon black reinforced blend of (A) a star-shaped substantially random vinyl containing rubbery solution polymerized polymer selected from the group consisting of polybutadienes, polyisoprenes, butadiene-styrene copolymers, butadiene-isoprene copolymers, isoprene-styrene copolymers, butadiene-isoprene-styrene copolymers and mixtures of the same and (B) at least one other rubbery diene polymer.Type: GrantFiled: January 30, 1985Date of Patent: November 19, 1985Assignee: GenCorp Inc.Inventors: Francis J. Vitus, Ivan G. Hargis, Russell A. Livigni, Sundar L. Aggarwal
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Patent number: 4540744Abstract: A butadiene-base polymer containing a branched polymer through tin-carbon bond and a process for producing the same are disclosed. The butadiene-base polymer is produced by polymerizing 1,3-butadiene alone or 1,3-butadiene and aromatic vinyl compound in a hydrocarbon solvent in the presence of a Lewis base using an organolithium compound as an initiator and then coupling with a tin halide, and satisfies the following requirements:(1) a content of a bound aromatic vinyl compound in the butadiene-base polymer is 0-40% by weight;(2) a ratio of vinyl bond-containing butadiene unit in the toal butadiene unit of the butadiene-base polymer is 30-90%;(3) a ratio of the branched polymer in the butadiene-base polymer is at least 30% by weight; and(4) a ratio of a component having a molecular weight of less than 100,000 as polystyrene in the molecular weight distribution as measured by a gel permeation chromatography is 10-20% by weight.Type: GrantFiled: February 12, 1985Date of Patent: September 10, 1985Assignees: Bridgestone Tire Company Limited, Japan Synthetic Rubber Co., Ltd.Inventors: Noboru Oshima, Isamu Shimizu, Yoshito Yoshimura
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Patent number: 4517343Abstract: A cathodic electrocoating binder comprises a mixture of(A) from 50 to 95 percent by weight of one or more polyadducts, polymers and/or polycondensates which possess basic nitrogen groups and(B) from 50 to 5 percent by weight of one or more amide-amines obtained by reacting monocarboxylic and/or dicarboxylic acids, or their esters, with diamines which possess one primary and one secondary amino group per molecule, the secondary amino group carrying a .beta.Type: GrantFiled: November 15, 1982Date of Patent: May 14, 1985Assignee: BASF AktiengesellschaftInventors: Eberhard Schupp, Fritz E. Kempter
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Patent number: 4514588Abstract: Electronic components are encapsulated with a poly(arylene sulfide) composition containing hydrogenated conjugated diene/monovinyl-substituted aromatic copolymer. The invention also includes certain encapsulation compositions containing poly(arylene sulfide), hydrogenated conjugated diene/monovinyl-substituted aromatic copolymer, reinforcement and filler.Type: GrantFiled: December 28, 1982Date of Patent: April 30, 1985Assignee: Phillips Petroleum CompanyInventors: William H. Beever, Robert S. Shue, Clifford W. Childers
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Patent number: 4499238Abstract: Various resin products having beautiful pearl-like pattern or luster and excellent mechanical strength such as impact strength and hinging properties are produced by molding a mixture of styrene-butadiene block copolymer containing 10 to 35 wt % butadiene and 65 to 90 wt % styrene, showing resinous properties, and having a specific block form and crystalline polypropylene (content of the former copolymer: 25 to 95 wt %).Type: GrantFiled: January 24, 1983Date of Patent: February 12, 1985Assignees: Nippon Steel Chemical Co., Ltd., Sumitomo Chemical Company, LimitedInventors: Nobutoshi Iwata, Kiyoshi Fukushima, Shinji Fujino, Takeshiro Yamada, Hideyuki Hao, Shigeo Tanaka, Tatsuyuki Mitsuno
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Patent number: 4493922Abstract: An impact-resistant thermoplastic molding material, containing polystyrene as the matrix, and, dispersed therein, two elastomeric polymers or copolymers I and II composed entirely or predominantly of 1,3-dienes and containing particles of different mean size, namely, in I, particles from 0.2 to 0.6 .mu.m in size and having capsule particle morphology, and, in II, particles from 2 to 8 .mu.m in size, having cell particle or coil particle morphology.Type: GrantFiled: January 25, 1984Date of Patent: January 15, 1985Assignee: BASF AktiengesellschaftInventors: Adolf Echte, Hermann Gausepohl
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Patent number: H1597Abstract: An epoxidized diene block polymer comprising at least interior and exterior diene blocks wherein the exterior diene blocks contain a greater concentration of di-, tri- and tetrasubstituted olefinic epoxides than the interior blocks and wherein the exterior blocks contain from 0.2 to 10 Meq of olefinic epoxides per gram of exterior blocks and the molecular weights of the exterior blocks are from 3000 to 50,000 and the molecular weights of the interior blocks are from 15,000 to 200,000.Type: GrantFiled: April 18, 1995Date of Patent: September 3, 1996Assignee: Shell Oil CompanyInventor: James R. Erickson