Abstract: The invention teaches an encapsulated curable adhesive composition especially adapted for use as a structural adhesive. The adhesive composition enables formation of a thin layer reactive composition of microcapsules and a two-part curative. The adhesive composition comprises a first population of microcapsules encasing a monomer and a first-part curative comprising an initiator. The adhesive composition further comprises a second-part curative. The second-part curative comprises an activator and a catalyst. At least the activator of the second-part curative is preferably encapsulated in a second population of microcapsules. The catalyst and the second population of microcapsules can be dispersed in a binder material, along with the first population of microcapsules. The first population of microcapsules contain encapsulated within the core a monomer having a Tg 35° C. or less and the first-part curative. The first population microcapsules contain encapsulated within the core a monomer having a Tg 35° C.

Abstract: It is an object of the present invention to provide a base coating composition for decorated moldings containing silver plating layer and a top clear coating composition for decorated moldings containing silver plating layer, and decorated moldings obtainable by using these compositions; the compositions and moldings are to be excellent in silver deposition tendency, basecoat film smoothness, adhesion and/or film appearance.

Abstract: The invention relates to a modular system for the production of coating compositions for coating plastics comprising the following component modules: A) at least one base module containing at least one binder, extenders and/or pigments, optionally together with conventional coating additives, water and/or organic solvents, B) at least one adhesion module containing at least one adhesion-promoting component optionally together with binders, conventional coating additives, extenders, organic solvents and/or water, C) at least one elasticity module containing at least one elasticising component optionally together with conventional coating additives, extenders, organic solvents and/or water and D) at least one binder module containing at least one binder optionally together with additives, organic solvents and/or water.

Abstract: The invention relates to preparations with improved curing behavior, which are characterized in that they contain 0.0005 to 50 wt. % of soluble and/or fine-particle organic and/or inorganic alkaline earth and/or alkali metal compounds. The preparations according to the invention may be used for bonding, sealing, casting and coating substrates, also in medical dental and technical dental preparations, and for making impressions of articles and, more particularly, for making dental impressions.

Abstract: Curable epoxy resin compositions, which are obtainable by heating a composition containing at least one epoxy compound, which contains on average at least one, preferably more than one, 1,2-epoxy group and optionally also one or several hydroxyl groups in the molecule, in the presence of at least one Lewis acid as catalyst, wherein the Lewis acid is a salt of trifluoromethanesulfonic acid or of perchloric acid, the counterion of which carries a 2- to 6-fold positive charge, until the epoxy value, measured in equivalent epoxy/kg (Eq/kg) of the starting material, has been reduced by 1 to 60 percent, preferably by 5 to 50 percent; a process for their preparation, and their use for the preparation of fully cured moulded compositions or coatings.

Abstract: An emulsion of a copolymer of carbon monoxide with an olefinically unsaturated compound dispersed in an aqueous diluent; a curable resin composition in the form of an oil-in-water emulsion comprising a copolymer of carbon monoxide with an olefinically unsaturated compound and a curing agent; and a process for producing a laminated wood composite comprising applying said curable resin composition onto wood parts of the composite, bringing the wood parts of the composite together such that curable resin composition is positioned between adjacent wood parts, and curing the curable resin such that after curing cured resin adheres adjacent wood parts to one another.

Abstract: A free radical curable composition that includes a free radical curable and a vinyl aromatic compound that is chemically different than the free radical curable component, wherein the vinyl aromatic compound is present in an amount sufficient to decelerate the cure rate of the free radical composition without adversely effecting completion of cure and the properties of the curable composition after it has cured. The composition is particularly useful as a two part adhesive that includes a free radical catalyst system and a diene elastomer.

Abstract: A two-pack aqueous adhesive, which comprises (A) an adhesive component comprising (a) a polycarbonate-urethane aqueous dispersion having a pH 5.0-8.5, which is prepared by self-emulsifying a carboxyl group-containing, hydroxy-terminated polyurethane polymer obtained from a polycarbonate diol, a carboxyl group-containing chain extender and a polyisocyanate compound in water in the presence of a tertiary amine, and (b) a conventional aqueous emulsion of a synthetic resin or a synthetic rubber, and (B) a curing component comprising a polyisocyanate compound, which can be cured even at a low temperature and is suitable for dry lamination of a product having complicated shape.

Abstract: A fast-curing sealant composition is made from generally liquid oligomers and has good tensile strength, one hundred percent modulus, Shore-A Hardness, and good insensitivity to water. One part of the sealant composition is generally a polyester or polyether oligomer having acetoacetate end groups or functionalities thereon, whereas the second part is also generally a polyester of polyether oligomer generally containing primary amine end groups or functions. The oligomers are generally of a low molecular weight, as from about 500 to about 10,000, and are modified by compounding with various additives such as carbon black, antioxidants, ultraviolet light inhibitors, and the like. Polyfunctional acetoacetate-terminated molecules having 3 or more functional end groups or polyfunctional primary amine-terminated molecules having 3 or more functional end groups serve to increase the crosslink density and modulus of the compositions. The sealant can be used as a coating or as a caulking type compound.

Abstract: A two-part initiator system useful in acrylic adhesive compositions comprising in one part a stable organoboron amine complex and in the second part an aldehyde destabilizer or activator. This initiator is particularly useful in elastomeric acrylic adhesive compositions and provides room temperature, relatively slow curing systems with good adhesive properties making them useful in applications where longer open times are required.

Abstract: The present invention relates to acid-curing aqueous coating compositions, in particular for the coating of finish sheeting and continuous edging, which contain aminoplast resin and hydroxyl-containing polyesters, wherein the polyester is prepared froma) 33 to 55 mol % of a dicarboxylic acid component obtained froma.sub.1) 50 to 100 mol % of olefinically unsaturated aliphatic dicarboxylic acidsa.sub.2) 0 to 50 mol % of saturated aliphatic dicarboxylic acidsa.sub.3) 0 to 50 mol % of saturated aliphatic dicarboxylic acids andb) 67 to 45 mol % of a polyol component obtained fromb.sub.1) 20 to 90 mol % of at least one monomeric and/or oligomeric glycol having 2 to 4 carbon atoms per glycol segment and number average molecular weights smaller than 200b.sub.2) 5 to 30 mol % of at least one polymeric glycol having 2 to 4 carbon atoms per glycol segment and a number average molecular weight between 300 and 1000 andb.sub.

Abstract: A method for the production of water absorbent polymer beads which retain a bead like shape after the absorption of water, wherein the absorbent beads are used in the manufacturing of concrete/mortar.

Abstract: The present invention is directed to a two package coating composition, comprising:(A) (a1) an acrylic resin having acid and hydroxy groups; and (a.sub.2) additives selected from the group consisting of solvents,UV-stabilizers, antioxidants, catalysts, flow agents, hindered amine light stabilizers and mixtures thereof; and(B) (b.sub.1) a polycarbodiimide;(b.sub.2) optionally a crosslinker selected from the group consisting of polyisocyanates, aminoplasts, and mixtures thereof; and(b.sub.3) additives selected from the group consisting of solvents, flow agents, findered amine light stabilizers, UV-absorbers, and mixtures thereof;a method of coating an article therewith and the coated article. The coating composition is used as a clearcoat with improved rheology control and no striking in which forms films with excellent appearance and sag resistance.

Abstract: The present invention relates to a homogeneous accelerator system for epoxy resins and to a method of curing such epoxy resins, wherein the system comprises (a) an inorganic salt which contains a nitrate ion, (b) aliphatic hydroxy compound selected from monohydric alcohols containing 1 to 10 carbon atoms in the molecule, polyhydric alcohols containing 2 to 10 carbon atoms and 2 to 4 hydroxy groups in the molecule, and poly (C.sub.2-5 alkylene) glycols and (c) an aminophenol.

Abstract: A polyurethane polyanhydride oligomer is disclosed as well as a process for its preparation. The process involves the following steps:(a) reacting a hydroxyl functional 2,4-dienoate ester with a polyisocyanate under conditions sufficient to react essentially all of the isocyanate groups to form a polyurethane polyene; and(b) reacting by Diels Alder addition the unsaturated double bonds of the polyurethane polyene with an unsaturated polycarboxylic acid anhydride containing material. Also disclosed is a curable composition containing hydroxyl functional material and the aforedescribed polyurethane polyanhydride oligomer.

Abstract: The invention consists of a system for storing, initiating curing of and dispensing a multicomponent curable material. One of the component materials is in the form of a multiplicity of discrete units surrounded by respective destructible layers of a substance which is nonreactive with the components. The system includes a device for rupturing the destructible layers while the components are being dispensed. This device may include a screen, roller pair, or heating element.

Abstract: The two-solution acrylic adhesive composition of this invention is composed of a solution A which has as its necessary ingredients (1) a chlorosulfonated polyethylene, (2) a (meth)acrylate monomer, and (3) an organic peroxide, and a solution B which has as its necessary ingredients (4) a butadiene-acrylonitrile copolymer elastomer (NBR), (5) a (meth)acrylate monomer, and (6) an aminealdehyde condensate.

Abstract: A package comprised of (A) compounding ingredients for unvulcanized rubber packaged in (B) a film comprised of syndiotactic-1,2-polybutadiene, sulfur, accelerator and retarder. The invention further relates to a compounded rubber comprised of a mixture of such package and sulfur curable rubber. The film may also contain additional selected rubbers.

Abstract: System for thermoplastic cross-linking adhesive, preparation thereof and corresponding method of gluing.This system for thermoplastic adhesives includes (A) a first composition without anhydride groups, containing: (a) at least one polymer chosen from the thermoplastic polymers and the synthetic rubbers; (b) at least one compound containing at least one group which can react with anhydride groups; (c) at least one tackifying resin; and (d) if desired, at least one plasticizer; (B) a second composition containing constituents Ba, Bc and Bd which are respectively analogous to the constituents Aa, Ac and Ad, and (b) at least one polymer containing anhydride goups; and (C) at least one activator of the reaction between the reactive groups of Ab and the anhydride functions of Bb. Advantageously the activatior (C) is wholly incorporated in the composition A and/or in the composition B, so as to form a two-component system.

Abstract: A two-component epoxy resin composition of improved cure rate is provided through the mixture of:A. an epoxy resin component, andB. a hardener component of curing Component A comprising a mixture of a ketimine and an amine-terminated butadiene/acrylonitrile copolymer rubber in a weight ratio of ketimine to said copolymer rubber of 47.1 to 12.5:52.9 to 87.5.

Abstract: Isocyanate functional polymers useful as crosslinking agents or as moisture curing polymers, which comprise the addition polymerization reaction product of:(a) 1 to 100% by weight of at least one isocyanate functional ethylenically unsaturated monomer which comprises the reaction product obtained by the gradual addition of an ethylenically unsaturated monomer having a single active hydrogen to a diisocyanate selected from the group consisting of isophorone diisocyanate and 2,4 toluene diisocyanate wherein the final molar ratio of active hydrogen containing monomer to diisocyanate is essentially 1 to 1; and(b) 0 to 99% by weight of at least one ethylenically unsaturated monomer which is free of active hydrogen functionality and which is copolymerizable with the ethylenically unsaturated isocyanate functional monomer.

Abstract: A grouting composition for sealing structures to inhibit water leakage therethrough and for stabilizing soil is provided. The composition is provided as a two-part system. Part A is an aqueous solution of a hydrophililc, water soluble prepolymer having a polyether backbone and terminal active olefinic groups, the olefinic groups being connected to the polyether backbone by linking groups selected from --NH--, --CONH--, --OCONH--, and --NHCONH--, and tertiary amine catalyst. Part B is an aqueous solution of a initiator. Parts A and B are mixed and react to form a gel.

Abstract: A coating composition contains an organic polyol, a polyepoxide, a polyisocyanate crosslinking agent, and a phenolic resin. The composition is flexible, having an elongation of at least 10 percent when cured. This coating composition is particularly suitable as a primer in preparing substrates with a multilayer coating having good flexibility.

Abstract: Composition for preparing a polymer concrete, a method of protecting or reconditioning surfaces by treatment with the composition, the protected or reconditioned surfaces thus-treated, and multi-package systems for bringing the components of the composition to an application site, wherein the composition comprises a substantially non-aqueous slurry of (1) an aggregate material and (2) a monomer binder system effective to bind the aggregate, upon curing, into a polymer concrete, the binder system comprising (a) a liquid comonomer component, (b) a solid, thermoplastic macromonomer component dissolved in the comonomer and comprising a linear polymer terminated at one or both ends with a polymerizable end group, and (c) a polymerization catalyst.

Abstract: A coating composition contains an organic polyol, a polyepoxide, a polyisocyanate crosslinking agent, and a phenolic resin. The composition is flexible, having an elongation of at least 10 percent when cured. This coating composition is particularly suitable as a primer in preparing substrates with a multilayer coating having good flexibility.

Abstract: A coating composition contains an organic polyol, a polyepoxide, a blocked polyisocyanate crosslinking agent, and a phenolic resin. The coating composition also can be formulated as a two package coating composition with a free polyisocyanate crosslinking agent. The composition is flexible, having an elongation of at least 10 percent when cured. This coating composition is particularly suitable as a primer in preparing substrates with a multilayer coating having good flexibility.

Abstract: A gelled dielectric encapsulant material and process therefor for use in reenterable and nonreenterable communication cable splices as well as applications relating to encapsulation of electronic components comprises a plasticizer which does not stress crack polycarbonate, an aliphatic or aromatic carboxylic acid, and a basic oxide or hydroxide.

Abstract: This invention relates to radically hardening adhesives, which contain polymerisable isocyanates and which are distinguished by high adhesive capacity on plastics materials.

Abstract: A two part type acrylic adhesive composed of liquid I comprising an acrylate ester monomer, a polymer soluble in the acrylate ester monomer, and an organic peroxide and liquid II containing a hardening accelerator capable of hardening said liquid I by polymerization at a temperature lower than room temperature, wherein at least liquid I contains 0.005 to 0.1% by weight polyphosphoric acid.

Abstract: There is provided a novel acrylic two-part adhesive suitable for structural uses composed of a liquid I comprising an acrylic monomer and an organic peroxide and a liquid II comprising an acrylic monomer and a curing accelerator. At least one of the liquid I and II further contains a diene-elastomer, and the liquid I or both the liquids further contain an ion-containing unsaturated polyester. The unsaturated polyester is further characterized in that it has one or more polymerizable or copolymerizable double bonds and its remaining carboxylic group is neutralized with a metal compound, ammonia or an amine.

Abstract: A solventless, fluid epoxy resin composition is storage-stable against separation of phases for at least one year, and when cured provides adhesive bonds of improved peel strength at room and low temperatures without loss of lap shear strength at room and elevated temperatures. The composition comprises an epoxide group-containing compound having in situ polymerized, elastomeric particles colloidally dispersed therein, and as curing agent a poly(oxyhydrocarbolene)diamine compound and optionally, and preferably, a cure accelerator.

Abstract: A low temperature curing coating composition containing 10-80% by weight of binder and 20-90% by weight of an organic solvent in which the binder is(1) an acrylic polymer containing monomers having reactive groups such as acrylamide, methacrylamide, methacrylic acid, acrylic acid and glycidyl methacrylate,(2) an epoxy resin,(3) a polyamine curing agent,(4) phenol and(5) a bicyclic amindine;The composition is used as a primer or topcoating for metal substrates and curings at temperatures of 0.degree. C. to ambient temperatures and provides a primer that has excellent adhesion to the substrate and provides a durable, corrosion resistant finish.

Abstract: A method for preparing a polyurethane wherein the components thereof have a long shelf life. The formulation is made by separately preparing a prepolymer solution, a crosslinking solution, and a cement solution. Upon utilization, the solutions are mixed together and applied. The urethane has very good fuel resistance and can be used as a coating in fuel tanks as well as to form integral fuel tanks.

Abstract: The present invention provides a method for preparing a precious metal catalyzed, heat curable silicon release coating composition. Also, there is provided an article of manufacture for packaging the ingredients necessary to practice the method of the invention.

Abstract: Adhesives and coatings, especially two-component epoxy laminating adhesives, are prepared so as to be flame-resistant in the so-called part B or polyamide component thereof by including in that component a chlorinated hydrocarbon solvent together with an adduct of a polyamide and an aromatic hydroxy or epoxy compound. By this approach, the amine is tied up and is rendered resistant to premature reaction with the chlorinated hydrocarbon solvent within the part B component, which premature reaction would lead to the formation of undesirable crystals within the part B component and reduce its pot life. When the part B component is blended with an epoxy-containing part B component, the polyamine adduct gradually disassociates in order to free the polyamine to catalyze setting of the two-component system, particularly the epoxy resin of the part A component.

Abstract: A new composition of matter comprises the product of the amassment of two or more arrays of glass roving or other suitable filaments, each of which array has been coated or impregnated with one of two complementary resin systems, preferably thermosetting polyester resin systems. Each such complementary resin system comprises substantially the same or functionally similar resin and each further comprises a curing agent, for example, in the case of polyester resin an organic peroxide, which curing agent differs from the curing agent in the other resin system. The resin system of each array further comprises suitable accelerator which is substantially ineffective to promote the curing agent of the resin system in which it is incorporated, but which does effectively promote the curing agent of the other, complementary resin system. Upon amassment of the separate arrays the two accelerators act synergisticly in the combined resin system.

Abstract: This invention provides a two-component coating composition wherein:Component A contains a polyglycidyl ether of a bisphenol having an epoxy equivalent weight between about 170 and about 200 diluted with between about 10 weight percent and about 20 weight percent of butyl glycidyl ether; an organic thixotropic agent; a liquid polyglycidyl ether of a bisphenol having an epoxy equivalent weight between about 170 and about 210; a coumarone-indene resin having a softening point between about 40.degree. F. and about 60.degree. F.; a urea-formaldehyde resin; leafing aluminum paste; and 2-nitropropane; andComponent B contains a polyamide having a base number between about 300 and about 360; N-oleyl-1,3-propylenediamine oleate; a coumarone-indene resin having a softening point between about 40.degree. F. and about 60.degree. F.; microcrystalline silica; and 2,4,6-tris-(dimethylaminomethyl) phenol.

Abstract: Ungelled amidation reaction products of a polycarboxyl-containing material and a polyamine having at least one ether group are produced. The ungelled products can be mixed with a crosslinking resin to provide a coating composition having good durability and stain-resistance.

Abstract: Improved composition for a fingernail coating having an acrylic binder, a peroxide catalyst, a tertiary amine accelerator, and a polymeric filler at least partially soluble in the coating. The acrylic binder contains a monoethylenically unsaturated monomer comprising at least a major proportion of methoxyethyl methacrylate. A polyfunctional monomer may be present that copolymerizes with the monoethylenically unsaturated monomer, for crosslinking and toughening.

Abstract: The present invention is directed to a two component industrial maintenance coating. The first component is a polyamine terminated epoxy resin which is end capped with a monoepoxide. The second component is a low molecular weight polyepoxide crosslinker. When salted with an acid, the adduct can be dissolved or dispersed in water. The polyepoxide crosslinker can then be microemulsified in the system. When coated on a substrate, the two component mixture cures at room temperature producing coatings having excellent balance of chemical and physical properties.

Abstract: The present invention provides a method for preparing a precious metal catalyzed, heat curable silicon release coating composition. Also, there is provided an article of manufacture for packaging the ingredients necessary to practice the method of the invention.