Material Contains Water And A Hydrocarbon Patents (Class 526/207)
  • Patent number: 10391474
    Abstract: The present disclosure provides a process for preparing a hydrocarbon fuel from waste rubber. The process involves admixing, in a reaction vessel, at least one fluid medium with the waste rubber to obtain a slurry; wherein the concentration of the waste rubber in the slurry ranges from 45% to 70%. A reactor is charged with the slurry and a predetermined amount of at least one catalyst composition to obtain a mixture, followed by introduction of hydrogen to the reactor to attain a predetermined pressure and heating the mixture at a predetermined temperature, to attain an autogenously generated pressure, and for a predetermined time period to obtain a reaction mass comprising the hydrocarbon fuel. This reaction mass comprising the hydrocarbon fuel is then cooled to obtain a cooled reaction mass. The hydrocarbon fuel is then separated from the cooled reaction mass.
    Type: Grant
    Filed: May 16, 2017
    Date of Patent: August 27, 2019
    Assignee: Reliance Industries Limited
    Inventors: Kshudiram Mantri, Mandan Chidambaram, Ramesh Bhujade, Nagesh Sharma, Raksh Vir Jasra
  • Patent number: 9320660
    Abstract: The present invention provides a method for producing water-absorbing resin particles having high equilibrium swelling capacity, a high water-absorption rate or high initial swelling capacity, and an appropriate particle size that achieves good handling performance; water-absorbing resin particles obtained by the method; and a water blocking material and an absorbent article which include the water-absorbing resin particles. The present invention is a method for producing water-absorbing resin particles, which comprises: preparing a hydrogel polymer by reversed-phase suspension polymerization of a water-soluble ethylenically unsaturated monomer in a hydrocarbon solvent in the absence of an internal crosslinking agent but in the presence of a surfactant with an HLB of 8 to 12; carrying out a post-crosslinking reaction of the hydrogel polymer whose moisture content is adjusted to 30 to 110 mass % based on a water-soluble ethylenically unsaturated monomer component that composes the hydrogel polymer.
    Type: Grant
    Filed: November 24, 2010
    Date of Patent: April 26, 2016
    Assignee: Sumitomo Seika Chemicals Co., Ltd.
    Inventors: Sachi Kikuno, Atsushi Heguri, Masayoshi Handa, Nobuhiro Maeda
  • Patent number: 9115221
    Abstract: A method for producing polymer particles includes a suspension step of suspending a first liquid mixture containing an oily olefin monomer and a radical polymerization initiator in a second liquid mixture containing water, an iodide ion, and an iodine molecule, to prepare a suspension in which an oil droplet containing the oily olefin monomer and the radical polymerization initiator is dispersed in the water containing the iodide ion and the iodine molecule, a synthesis step of synthesizing an iodine compound by allowing a radical generated by cleavage of the radical polymerization initiator to react with the iodine molecule in the oil droplet, and a polymerization step of polymerizing the oily olefin monomer in the oil droplet.
    Type: Grant
    Filed: October 22, 2013
    Date of Patent: August 25, 2015
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takayuki Hiratani, Shinnosuke Koji, Kazumichi Nakahama
  • Patent number: 8993695
    Abstract: Heat aging of the composition comprising melt-fabricable tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer, the alkyl containing 1 to 5 carbon atoms and melt flowable polytetrafluoroethylene is effective to cause thermal transformation of the composition in the solid state, which is epitaxial co-crystallization of the polymer components of the composition, and other valuable changes, such as increased continuous use temperature.
    Type: Grant
    Filed: January 23, 2014
    Date of Patent: March 31, 2015
    Assignee: E I du Pont de Nemours and Company
    Inventor: Jacob Lahijani
  • Patent number: 8975302
    Abstract: The disclosure relates to methods of making polymer particles, said methods including the steps of: making an aqueous gel reaction mixture; forming an emulsion having dispersed aqueous phase micelles of gel reaction mixture in a continuous phase; adding an initiator oil comprising at least one polymerization initiator to the continuous phase; and performing a polymerization reaction in the micelles. Further, the initiator oil is present in a volume % relative to a volume of the aqueous gel reaction mixture of between about 1 vol % to about 20 vol %. The disclosure also relates to methods of making nucleic acid polymer particles having the same method steps and wherein the aqueous gel reaction mixture includes a nucleic acid fragment, such as a primer.
    Type: Grant
    Filed: July 6, 2012
    Date of Patent: March 10, 2015
    Assignee: Life Technologies Corporation
    Inventors: David Light, Barnett Rosenblum
  • Publication number: 20140243478
    Abstract: There is disclosed a method for producing water-absorbent resin particles, comprising a polymerization step that includes mixing an oily liquid comprising a hydrocarbon dispersing medium and a surfactant, and an aqueous liquid comprising an aqueous solvent and a water-soluble ethylenically unsaturated monomer, forming a suspension comprising an oily liquid and an aqueous liquid dispersed in the oily liquid, and polymerizing the water-soluble ethylenically unsaturated monomer in the suspension. The HLB of the surfactant is 6 or greater, and the temperature of the suspension is kept at 35° C. or higher during the period from initial mixing of the oily liquid and aqueous liquid until complete mixing of the entire amounts.
    Type: Application
    Filed: September 24, 2012
    Publication date: August 28, 2014
    Inventors: Atsushi Heguri, Kenji Tanimura, Yuichi Onoda, Masayoshi Handa
  • Patent number: 8785580
    Abstract: The invention relates to a polyvinylidene fluoride polymer having an ultra-high molecular weight, and unexpected physical properties. The ultra-high molecular weight polymer is clear, has a lower melting point, reduced crystallinity, excellent impact resistance, and a high elongation at the yield point. The ultra-high molecular weight polyvinylidene fluoride can be alone, or blended with other polymers, in final applications and articles.
    Type: Grant
    Filed: June 26, 2007
    Date of Patent: July 22, 2014
    Assignee: Arkema Inc.
    Inventor: Ramin Amin-Sanayei
  • Publication number: 20140179886
    Abstract: A method is disclosed for producing a water-absorbent resin by a reversed-phase suspension polymerization method, wherein an odor originating from a raw material component, in particular, a petroleum hydrocarbon dispersion medium, is further reduced as compared with a water-absorbent resin obtained by a conventional method, and a water-absorbent resin obtained by the method. More specifically, a method is disclosed for producing a water-absorbent resin by performing a reversed-phase suspension polymerization of a water-soluble ethylenically unsaturated monomer in a petroleum hydrocarbon dispersion medium, comprising adding and dispersing an aqueous solution of a water-soluble ethylenically unsaturated monomer containing a hydrophilic polymeric dispersion agent to a petroleum hydrocarbon dispersion medium in the presence of a surfactant under stirring, and performing a reversed-phase suspension polymerization using a radical polymerization initiator, and a water-absorbent resin obtained by the method.
    Type: Application
    Filed: July 20, 2011
    Publication date: June 26, 2014
    Applicant: SUMITOMO SEIKA CHEMICALS CO., LTD.
    Inventors: Hideki Yokoyama, Atsushi Heguri, Nobuhiro Maeda
  • Publication number: 20140127510
    Abstract: Disclosed is a water-absorbent resin particle in which the water-absorption rate of physiological saline is 1 second to 15 seconds, the median particle size is 100 ?m to 600 ?m, and the residual volatile component content is 1.5% by weight or less.
    Type: Application
    Filed: July 23, 2012
    Publication date: May 8, 2014
    Applicant: SUMITOMO SEIKA CHEMICALS CO., LTD.
    Inventors: Masayoshi Handa, Kenji Tanimura, Atsushi Heguri, Yuichi Onoda
  • Patent number: 8470942
    Abstract: The claimed invention relates to a method for producing a melt-moldable tetrafluoroethylene copolymer containing repeating units (a) based on tetrafluoroethylene and repeating units (b) based on another fluoromonomer, wherein the amount of the repeating units (a), based on the total mass of the repeating units (a) and the repeating units (b), is from 97.3 to 99.5 mass %, and the volume flow rate of the copolymer is from 0.1 to 1000 mm3/s; the process including radical suspension-polymerization of tetrafluoroethylene and the fluoromonomer in an aqueous medium in the presence of a radical polymerization initiator and at least one chain transfer agent selected from the group consisting of methane, ethane, a hydrochlorocarbon, a hydrofluorocarbon and a hydrochlorofluorocarbon.
    Type: Grant
    Filed: March 11, 2009
    Date of Patent: June 25, 2013
    Assignee: Asahi Glass Company, Limited
    Inventors: Atsushi Funaki, Shigeki Kobayashi, Hiroki Nagai
  • Publication number: 20120116015
    Abstract: A polymerization process is provided, comprising polymerizing fluoromonomer in an aqueous medium to form a dispersion of fluoropolymer particles in the aqueous medium, said polymerizing being carried out in the presence of (i) polymerization initiator, and (ii) hydrocarbon-containing surfactant stabilizing the dispersion of fluoropolymer particles, the hydrocarbon-containing surfactant being passivated to reduce its the telogenic behavior.
    Type: Application
    Filed: November 9, 2011
    Publication date: May 10, 2012
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Paul Douglas Brothers, Subhash Vishnu Gangal, Dipti Dilip Khasnis
  • Publication number: 20120052316
    Abstract: Described is an aqueous polymer dispersion comprising a chain growth addition polymer obtainable by free-radically initiated emulsion polymerization of ethylenically unsaturated, free-radically polymerizable monomers, wherein the polymerization of the monomers is effected in the presence of a certain molecular weight regulator composition. The molecular weight regulator composition comprises at least one mercaptoalkylcarboxylic ester of a C2- to C4-carboxylic acid and at least one oligomeric compound of the formula R1—X-(A-S—)n-A-Y—R2, where R1 and R2 are each H or CH3—(CH2)0-2—C(?O)—, X and Y are each an oxygen atom or a sulfur atom, A is a divalent C1- to C18-alkylene group and n is from 1 to 8. Also described is a process for preparing the aqueous polymer dispersion. The polymer dispersion is useful as a binder, an adhesive, a sizing agent for fibers, in the manufacture of coatings or in the manufacture of paper coating slips.
    Type: Application
    Filed: August 24, 2011
    Publication date: March 1, 2012
    Applicant: BASF SE
    Inventors: Elitsa Evstatieva, Dirk Lawrenz, Johannes Jan-Bessel Minderhoud, Florian Garlichs, Peter Bassler, Jens Baldamus
  • Patent number: 7999050
    Abstract: A method of making a composition comprising reacting, in a reactor, a non-halogenated acetoacetate group containing monomer, at least one additional monomer, and a base, wherein at least a portion of the base is fed to the reactor during reaction. Also, a composition comprising an aqueous polymer dispersion that is a product of a method comprising reacting a non-halogenated acetoacetate moiety containing monomer, at least one additional monomer, and a base, wherein the base is fed to the reaction during reaction, wherein the composition has a lower viscosity than a second composition, wherein the second composition is prepared from the same materials as the composition, and the second composition is made by a method wherein the base is added to the second composition after a reaction to form the second composition.
    Type: Grant
    Filed: August 10, 2006
    Date of Patent: August 16, 2011
    Assignee: BASF SE
    Inventor: Cheng-Le Zhao
  • Patent number: 7956128
    Abstract: A thermoplastic resin composition for a refrigerator according to the present invention can include (A) about 20 to about 40 parts by weight of an acrylonitrile-butadiene-styrene graft copolymer resin prepared by grafting in emulsion polymerization about 60 to about 30% by weight of a monomer mixture comprising a cyanide vinyl compound and an aromatic vinyl compound to about 40 to about 70% by weight of a rubber polymer having an average particle size of about 0.1 to about 0.4 ?m; (B) about 1 to about 20 parts by weight of a styrenic copolymer comprising (b1) about 0 to about 75% by weight of a styrenic copolymer prepared by copolymerizing about 5 to about 20% by weight of a rubber polymer having an average particle size of about 0.
    Type: Grant
    Filed: June 28, 2007
    Date of Patent: June 7, 2011
    Assignee: Cheil Industries Inc.
    Inventors: Kang Yeol Park, Hee Jung Park, Jae Hyung Lee
  • Publication number: 20110130534
    Abstract: The invention relates to a polyHIPE material provided with high mechanical strength, which material comprises at least one N-alkenyltriazole monomer and a cross-linking monomer in a weight ratio of cross-linking monomer/N-alkenyltriazole monomer of 1/100 to 60/100. It also relates to a process and an emulsion allowing this emulsion to be prepared, and to an article formed in whole or in part of this material, and notably a catalyst support for heterogeneous catalysis, a particle filter, metal ion adsorbent, or gas sensor.
    Type: Application
    Filed: June 8, 2009
    Publication date: June 2, 2011
    Applicant: Commissariat A L'Energie Atomique
    Inventors: Oliver Besnard, Eric Pasquinet, Herve Deleuze, Marc Birot, Fabrice Audouin
  • Patent number: 7709052
    Abstract: Alkyldiketene-containing aqueous polymer dispersions which are obtainable by miniemulsion polymerization of hydrophobic monoethylenically unsaturated monomers in the presence of alkyldiketenes, processes for the preparation of such polymer dispersions and the use of the thus obtainable dispersions as sizes for paper or as water repellents for leather, natural and/or manmade fibers and textiles.
    Type: Grant
    Filed: October 9, 2003
    Date of Patent: May 4, 2010
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Dyllick-Brenzinger, Roland Ettl, Franca Tiarks, Ulrich Riebeling
  • Publication number: 20080194708
    Abstract: The present invention relates to the use of a water-soluble or water-dispersible crosslinked polymer obtainable by the polymerization of a mixture comprising 99.99 to 10% by weight of at least one ?,?-ethylenically unsaturated compound having at least one cationogenic and/or cationic group per molecule, 0 to 90% by weight of at least one monoethylenically unsaturated compound containing amide groups which differs from a), and 0.01 to 5% by weight of a crosslinking agent for modifying the rheology of aqueous compositions.
    Type: Application
    Filed: March 16, 2006
    Publication date: August 14, 2008
    Applicant: BASF Aktiengesellschaft
    Inventors: Peter Hossel, Klemens Mathauer, Claudia Wood, Matthias Laubender, Wolfgang Jahnel, Ivette Garcia Castro, Volker Wendel, Karl Kolter
  • Patent number: 7282547
    Abstract: A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M containing from 40 to 80% by weight of styrene as monomer M1, from 20 to 60% by weight of butadiene as monomer M2, and from 0 to 40% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers M3 other than styrene and butadiene by a monomer feed technique in the presence of from 0.05 to 0.5% by weight, based on 100% by weight of monomers, of at least one hydrocarbon HC selected from compounds having 6 to 20 carbon atoms which on abstraction of a hydrogen atom form a pentadienyl radical or a 1-phenylallyl radical and from ?-methylstyrene dimer comprises supplying the monomers to be polymerized to the polymerization reaction over the course of 3 hours.
    Type: Grant
    Filed: September 30, 2002
    Date of Patent: October 16, 2007
    Assignee: BASF Aktiengesellschaft
    Inventors: Lambertus Manders, Thomas Wirth, Wolfgang Gaschler, Hubertus Kroener
  • Patent number: 7282545
    Abstract: A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M containing from 40 to 80% by weight of styrene as monomer M1, from 20 to 60% by weight of butadiene as monomer M2, and from 0 to 40% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers M3 other than styrene and butadiene by a monomer feed technique in the presence of from 0.05 to 0.5% by weight, based on 100% by weight of monomers, of at least one hydrocarbon HC having 6 to 20 carbon atoms, which is selected from compounds which on abstraction of a hydrogen atom form a pentadienyl radical or a 1-phenylallyl radical and from ?-methylstyrene dimer comprises including at least 30% of the hydrocarbon HC in the initial charge to the polymerization vessel and supplying the remainder of the hydrocarbon HC to the polymerization reaction in the course of that reaction.
    Type: Grant
    Filed: September 30, 2002
    Date of Patent: October 16, 2007
    Assignee: BASF Aktiengesellschaft
    Inventors: Wolfgang Gaschler, Volker Schaedler, Lambertus Manders, Thomas Wirth, Hubertus Kroener
  • Patent number: 7196146
    Abstract: A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M containing from 40 to 80% by weight of styrene as monomer M1, from 20 to 60% by weight of butadiene as monomer M2, and from 0 to 40% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers M3 other than styrene and butadiene by a monomer feed technique in the presence of from 0.05 to 0.5% by weight, based on 100% by weight of monomers, of at least one hydrocarbon HC having 6 to 20 carbon atoms selected from compounds which on abstraction of a hydrogen atom form a pentadienyl radical or a 1-phenylallyl radical and ?-methylstyrene dimer comprises raising, at a point in time when at least 70% of the monomers to be polymerized have been supplied to the polymerization reaction, the concentration of butadiene in the monomer feed for a period of at least 1% of the total feed time by at least 10% by weight, based on monomers in the feed.
    Type: Grant
    Filed: September 30, 2002
    Date of Patent: March 27, 2007
    Assignee: BASF Aktiengesellschaft
    Inventors: Lambertus Manders, Thomas Wirth, Wolfgang Gaschler, Hubertus Kroener
  • Publication number: 20040171778
    Abstract: Low color, aromatic modified C5 hydrocarbon resins are disclosed. The resins are predominantly an aromatic modified piperylene resin. The resins are useful as tackifies in hot melt adhesives and hot melt pressure sensitive adhesives.
    Type: Application
    Filed: November 13, 2002
    Publication date: September 2, 2004
    Inventors: Chretien Pieter Louis C. Donker, Elisabeth E.C.G. Gielens, Gerard A. Verrijzer
  • Patent number: 6762248
    Abstract: An epoxy group-containing acrylic resin for a powder coating is prepared by suspension polymerization at a temperature of at least 80° C. and a pressure of at least 2 kg/cm2 with a vinyl monomer mixture comprising from 10-60% by weight of epoxy group-containing vinyl monomers, from 10-60% by weight of alkyl (meth)acrylate(s), and other vinyl monomer(s). The epoxy group-containing acrylic resin particles possess the following characteristics: i) a weight average molecular weight of from 3000-20,000; ii) an epoxy equivalent of from 350-1200 g/eq; iii) 1000 ppm or less of volatile components; iv) a mean particle diameter of from 80-800 &mgr;m; v) at least 95% by weight of the particles having a long diameter R:short diameter r ratio within the parameters 1<R/r<1.2; and vi) 5% by weight or less of the particles having a long diameter R of less than 62 &mgr;m and 5% by weight or less of particles having a short diameter r of more than 1000 &mgr;m.
    Type: Grant
    Filed: November 22, 2002
    Date of Patent: July 13, 2004
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Yoko Harada, Motoshi Inagaki, Koji Shimizu, Noriyuki Tajiri
  • Patent number: 6673861
    Abstract: Composition comprising an oil phase, an aqueous phase, at least one emulsifying agent of water-in-oil (W/O) type and at least one emulsifying agent of oil-in-water (O/W) type in the form of a self-invertible inverse latex comprising from 20% to 70% by weight, and preferably from 25% to 50% by weight of a branched or crosslinked polyelectrolyte, characterized in that the said polyelectrolyte is either a homopolymer based on a monomer having a partially or completely salified strong acid functional group or a copolymer based on at least one monomer having a partially or completely salified strong acid functional group copolymerized with acrylamide and characterized in that the constituent solvent of the oil phase is chosen from white mineral oils, squalane, hydrogenated polyisobutene, isohexadecane or isododecane. Cosmetic, dermocosmetic, dermopharmaceutical or pharmaceutical composition comprising them.
    Type: Grant
    Filed: May 7, 2001
    Date of Patent: January 6, 2004
    Assignee: Societe d'Exploitation de Produits pour les Industries Chimiques Seppic
    Inventors: Guy Tabacchi, Jean-Pierre Boiteux, Chantal Almaric, Nelly Michel, Paul Mallo
  • Patent number: 6667365
    Abstract: The present invention relates to a method of manufacturing polymer nano particle having two-photon absorption compound at its central portion. The method of manufacturing polymer nano particle comprises the steps of dispersing a monomer for forming polymer nano particle and two-photon absorption compound into a solvent; supplying a given gas while stirring the solvent in which the monomer and the two-photon absorption compound are dispersed at a given temperature, in order to remove the dissolved oxygen contained in the solvent; supplying polymerization initiators into the solvent while stirring the solvent in which the monomer and the two-photon absorption compound are dispersed at a given temperature; and polymerizing the monomer for a given period of time while stirring the solvent in which the monomer and the two-photon absorption compound are dispersed at a given temperature.
    Type: Grant
    Filed: June 27, 2002
    Date of Patent: December 23, 2003
    Assignee: Electronics and Telecommunications Research Institute
    Inventors: Myung Ae Chung, Sang Don Jung
  • Patent number: 6646078
    Abstract: A method of producing a paraffin wax for aqueous dispersion polymerization of TFE which allows high speed aqueous dispersion polymerization of TFE with excellent polymerization behavior such as excellent dispersion stability and consistent production of PTFE having excellent physical properties, and a method of producing PTFE using the paraffin wax. Aqueous dispersion polymerization of tetrafluoroethylene (hereinafter referred to as TFE) is conducted in the presence of a paraffin wax, a polymerization initiator and an emulsifier at least once and then the paraffin wax is recovered. The recovered paraffin wax is used for aqueous dispersion polymerization of TFE in the presence of a polymerization initiator and an emulsifier.
    Type: Grant
    Filed: December 20, 2001
    Date of Patent: November 11, 2003
    Assignees: Asahi Glass Company, Limited, Asahi Glass Fluoropolymers Co., Ltd.
    Inventors: Shigeki Kobayashi, Jun Hoshikawa, Kazuo Kato, Hiroki Kamiya, Hiroyuki Hirai
  • Patent number: 6605680
    Abstract: Low color, aromatic modified C5 hydrocarbon resins are disclosed. The resins are predominantly an aromatic modified piperylene resin. The resins are useful as tackifiers in hot melt adhesives and hot melt pressure sensitive adhesives.
    Type: Grant
    Filed: April 7, 2000
    Date of Patent: August 12, 2003
    Assignee: Eastman Chemical Resins, Inc.
    Inventors: Chretien P. L. C. Donker, Ester E. C.G. Gielens, Gerard A. Verrijzer
  • Publication number: 20030130454
    Abstract: A process for producing polymers which comprises polymerizing an amphipathic monomer or copolymerizing an amphipathic monomer and another monomer which is copolymerizable therewith, wherein a polymerization solvent, a nonionic chain transfer agent and 1,1′-azobis(cyclohexane-1-carbonitrile) as a polymerization initiator are used together with the monomer. It is thereby possible to produce polymers with high hydrate formation and dissociation-controlling performance, and to produce polymers of low molecular weight with low residual monomer contents using the same amounts of polymerization initiators.
    Type: Application
    Filed: November 7, 2002
    Publication date: July 10, 2003
    Applicant: Mitsubishi Rayon Co., Ltd.
    Inventors: Masaaki Seya, Masayuki Tooyama
  • Patent number: 6586546
    Abstract: Aqueous copolymerization of TFE and PAVE in the presence of a small amount of terpene enables the manufacture of a more uniform melt-fabricable copolymer with a narrower molecular weight distribution. The copolymer exhibits improved flex life.
    Type: Grant
    Filed: June 14, 2001
    Date of Patent: July 1, 2003
    Assignee: DuPont-Mitsui Fluorochemicals Co. Ltd.
    Inventors: Takahiko Iwasaki, Masahiro Kino
  • Patent number: 6566549
    Abstract: A continuous process for oligomers which do not contain, as polymerized units, carboxylic acid-containing monomers and their salts, including the steps of: (1) forming a reaction mixture, substantially free of carboxylic acid-containing monomers and their salts, containing: (i) 0.5 to 99.95% by weight of the reaction mixture of at least one ethylenically unsaturated monomer; and (ii) 0.05 to 25% by weight, based on the weight of the ethylenically unsaturated monomer, of at least one free-radical initiator; and (2) continuously passing the reaction mixture through a heated zone wherein the reaction mixture is maintained at a temperature of at least 150° C. and a pressure of at least 30 bars for from 0.1 seconds to 4 minutes to form terminally-unsaturated oligomers. In addition, processes for forming oligomers of vinyl acetate and oligomers of vinyl alcohol are disclosed. Mixtures of fully saturated and terminally unsaturated oligomers are also disclosed.
    Type: Grant
    Filed: December 15, 1998
    Date of Patent: May 20, 2003
    Assignee: Rohm and Haas Company
    Inventors: Gary David Greenblatt, Barry Clifford Lange, Michael Damian Bowe, Richard Foster Merritt, Robert Wilczynski, Gary Robert Larson, Lori Marie Petrovich, David William Whitman
  • Patent number: 6555640
    Abstract: Process that is capable of synthesizing a metal-containing resin having a good antifouling property in a short period of time without having such problems associated with the synthesis as gelation. The process for producing a metal-containing resin by conducting a copolymerization reaction of a monomer mixture (A) comprising 1 to 50% by weight of a carboxyl group-containing polymerizable unsaturated monomer (a) and 50 to 99% by weight of other polymerizable unsaturated monomer (b) in an organic solvent in the presence of water and an oxide or hydroxide of a metal having a valency of at least 2, wherein the amount of water is 1 to 30 parts by weight based on 100 parts by weight of the monomer mixture (A), and the formation of a metal carboxylate bond occurs together with the copolymerization of the monomer mixture (A); and an antifouling coating composition containing, as an active constituent, a metal-containing resin obtained by the production process.
    Type: Grant
    Filed: September 21, 2000
    Date of Patent: April 29, 2003
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Kei Ito, Chikara Kawamura
  • Patent number: 6531557
    Abstract: A modified polytetrafluoroethylene fine powder containing agglomerates of colloidal particles with an average particle size of from 0.05 to 0.5 &mgr;m which comprise a copolymer of tetrafluoroethylene and an olefin-monomer represented by X(CF2)nOCF═CF2 in which X is a hydrogen atom, a fluorine atom or a chlorine atom, and n is an integer of 1 to 6, and/or C3F7(OCF2CF2CF2)m[OCF(CF3)CF2]pOCF═CF2 in which m and p are independently an integer of 0 to 4, provided that the sum of m and p is not 0 (zero), a content of the olefin monomer being from 0.02 to 0.3 wt. %, wherein the copolymer has a molecular weight distribution Mw/Mn of from 1.5 to 4.5 and a standard specific gravity of from 2.135 to 2.175. This modified polytetrafluoroethylene has good paste extrudability, and provides molded articles having good mechanical properties, in particular, pressure resistance.
    Type: Grant
    Filed: March 12, 1999
    Date of Patent: March 11, 2003
    Assignee: Daikin Industries Ltd.
    Inventors: Kazutaka Hosokawa, Yoshinori Nanba, Takahisa Aoyama, Tetsuo Shimizu
  • Publication number: 20030022987
    Abstract: Novel water soluble polymers in solution or water-in-oil emulsion form are disclosed containing quaternary ammonium monomers; and optionally (meth)acrylic acid or 2-(meth)acrylamido-2-methylpropane sulfonic acid; methylene bis-acryamide and the like; and a C1-C3 alkyl (meth)acrylate acrylamide or methacrylamide and the use thereof in hair, skin and nail conditioning; papermaking; and subterranean well drilling and well cementing operations.
    Type: Application
    Filed: September 13, 2002
    Publication date: January 30, 2003
    Inventors: Gary F. Matz, Randy J. Loeffler, Shih-Ruey T. Chen, Allan L. Melby, Nicholas F. Vozza
  • Patent number: 6509420
    Abstract: An epoxy group-containing acrylic resin for a powder coating composition is a copolymer, having a weight-average molecular weight of 3000 to 20000, of a vinyl monomer mixture comprising 10 to 60% by weight of alkyl ester(s) of (meth)acrylic acid, 10 to 60% by weight of epoxy group-containing vinyl monomer(s) and other vinyl monomer(s), said epoxy group-containing acrylic resin having a mean particle diameter in the range of 80 to 800 &mgr;m, including 95% by weight or more of particles satisfying the relation of 1≦R/r≦1.2 wherein R is a long diameter and r is a short diameter of each particle, and including 1000 ppm or less of volatile components, the amount of the particles having long diameters R of less than 62 &mgr;m being 5% by weight or less, that of the particles having short diameters r of more than 1000 &mgr;m being 5% by weight or less.
    Type: Grant
    Filed: September 5, 2000
    Date of Patent: January 21, 2003
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Yoko Harada, Motoshi Inagaki, Koji Shimizu, Noriyuki Tajiri
  • Publication number: 20020132942
    Abstract: A humidification system (A) for humidifying a dry hydrocarbon stream includes a column (10) which defines an interior cavity (20). The cavity is partially filled with a bed (12) of a packing material (40) and a layer of water (20), leaving a headspace above the water. An inlet (52) adjacent a lower end of the cavity receives a dry hydrocarbon stream which is broken up by the packing material and dissolves water as it passes therethrough. Entrained water droplets fall out of the wet blend in a disengagement zone (70) above the water layer leaving the hydrocarbon stream humidified yet substantially free of liquid water in an upper region (72) of the column.
    Type: Application
    Filed: March 14, 2001
    Publication date: September 19, 2002
    Inventors: David M. Roggeman, James Oziomek, Timothy L. Tartamella
  • Publication number: 20020082343
    Abstract: A method of producing a paraffin wax for aqueous dispersion polymerization of TFE which allows high speed aqueous dispersion polymerization of TFE with excellent polymerization behavior such as excellent dispersion stability and consistent production of PTFE having excellent physical properties, and a method of producing PTFE using the paraffin wax. Aqueous dispersion polymerization of tetrafluoroethylene (hereinafter referred to as TFE) is conducted in the presence of a paraffin wax, a polymerization initiator and an emulsifier at least once and then the paraffin wax is recovered. The recovered paraffin wax is used for aqueous dispersion polymerization of TFE in the presence of a polymerization initiator and an emulsifier.
    Type: Application
    Filed: December 20, 2001
    Publication date: June 27, 2002
    Applicant: ASAHI GLASS COMPANY LIMITED
    Inventors: Shigeki Kobayashi, Jun Hoshikawa, Kazuo Kato, Hiroki Kamiya, Hiroyuki Hirai
  • Patent number: 6407186
    Abstract: A process for preparing low molecular weight, highly reactive polyisobutylene having an average molecular weight Mn of from 500 to 5000 Dalton and a terminal double bond content of more than 80 mol % by polymerization in the liquid phase of isobutene or hydrocarbon streams comprising isobutane [sic] with the aid of a boron trifluoride complex catalyst at from −40 to 20° C. and at from 1 to 20 bar comprises a) polymerizing until the residual isobutene content of the reaction mixture is less than 2% by weight, based on isobutene introduced, or removing residual isobutene towards the end of the polymerization until the residual isobutene content is less than 2% by weight, b) enriching the boron trifluoride complex catalyst which is obtained in the form of droplets in the disperse and/or coherent phase, c) recycling the complex-enriched phases to the polymerization and d) compensating for catalyst losses by adding boron trifluoride and, if necessary, complexing agents.
    Type: Grant
    Filed: June 12, 2000
    Date of Patent: June 18, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans Peter Rath, Ulrich Kanne, Frans van Deyck
  • Publication number: 20020040109
    Abstract: The present invention provides a method to improve the efficiency of ROMP-hydrogenation and ROMP-hydrogenolysis processes. Thus the invention provides a means for increasing the rate of reaction of the hydrogenation step of the ROMP-hydrogenation process via the addition of non-inert solvent such as methanol. The present invention permits multiple cycles of ROMP-hydrogenation-ROMP and ROMP-hydrogenolysis-ROMP without additional catalyst, thus allowing the formation of tailored polymer blends in a ‘one-pot’ reaction. Moreover, the ROMP-hydrogenation reactions of the present invention may be carried out at pressures as low as atmospheric pressure.
    Type: Application
    Filed: March 26, 2001
    Publication date: April 4, 2002
    Inventors: Deryn Elizabeth Fogg, Samantha Dawn Drouin, Fojan Zamanian
  • Patent number: 6340733
    Abstract: The present invention describes a process for the making of a copolymer of the general formula (I) wherein A is a residue of at least one (meth)acrylate monomeric species, B is a residue of at least one monomeric species copolymerizable with A, R is a (meth)acrylate functionalized pendant ester group, X1 and X2 are terminal groups which may be the same or different, n and p are both at least one and are chosen such that the copolymer has a number average molecular weight of more than 2000.
    Type: Grant
    Filed: November 30, 2000
    Date of Patent: January 22, 2002
    Assignee: Imperial Chemical Industries PLC
    Inventors: Andrew Trevithick Slark, Michael Stephen Chisholm, Helen Harte
  • Publication number: 20010037006
    Abstract: A method for the preparation of gel-free poly 2-hydroxyethyl methacrylate substantially in the absence of a chain transfer agent, comprising introducing monomeric 2-hydroxyethyl methacrylate containing ethylene glycol dimethacrylate impurities in the range of about 0.05 to 0.1% by weight into a solution of alcohol and water and polymerizing. The present invention also provides a method for the preparation of gel-free homopolymer of 4-hydroxybutyl acrylate substantially in the absence of a chain transfer agent in an alcohol or in solution of alcohol and water. The present invention also provides a method for the preparation of gel-free copolymer of 2-hydroxyethyl methacrylate and 4-hydroxybutyl acrylate substantially in the absence of a chain transfer agent, comprising introducing monomeric 2-hydroxyethyl methacrylate containing ethylene glycol dimethacrylate impurities in the range of about 0.05 to 0.1 % by weight with monomeric 4-hydroxybutyl acrylate into a solution of alcohol and water.
    Type: Application
    Filed: January 10, 2001
    Publication date: November 1, 2001
    Inventor: Daniel L. Holguin
  • Publication number: 20010007009
    Abstract: Polymers based on monomers having a C-C double bond and/or C-C triple bond are prepared by polymerization of these monomers in the presence of a catalyst system comprising as active constituents
    Type: Application
    Filed: December 5, 2000
    Publication date: July 5, 2001
    Inventors: Lambertus Manders, Marc Oliver Kristen, Alexander Haunschild, Michael Geprags
  • Patent number: 6238486
    Abstract: The invention provides novel cationic flocculant dispersion polymers that can be utilized in the methods disclosed herein. This invention also provides methods for detecting cationic flocculants wherein said flocculants may be made via a dispersion process, a latex process or a dry polymer process. The flocculants are used to flocculate solids from liquid components of an industrial food process. The detection method involves the use of monoclonal antibodies to determine the presence or concentration of the cationic flocculants in the liquids.
    Type: Grant
    Filed: March 10, 1999
    Date of Patent: May 29, 2001
    Assignee: Nalco Chemical Company
    Inventors: Andrew J. Dunham, Cathy C. Johnson, Kristine S. Salmen, John W. Sparapany, Anthony G. Sommese
  • Patent number: 6191242
    Abstract: Unsheared, water-soluble, branched, high molecular weight, anionic, polymeric flocculants are produced by polymerizing ethylenically unsaturated anionic, and optionally non-ionic, monomers and a branching agent in the presence of a chain-transfer agent. They are useful as flocculating agents for releasing water from dispersions of suspended solids.
    Type: Grant
    Filed: November 27, 1996
    Date of Patent: February 20, 2001
    Assignee: Cytec Technology Corp.
    Inventors: Roderick Glyn Ryles, Roger Edgar Neff, Joseph Jacinto Pellon
  • Patent number: 6160061
    Abstract: A process for preparing an aqueous emulsion with a narrow droplet size distribution of an oily material comprising one or more highly water insoluble substances, wherein the oily material is homogenized in a hydrophilic phase in which the oily material is more soluble than in water, but still so insoluble that an emulsion is formed by the homogenization, and the emulsion is subsequently diluted with a high proportion of water to form a stable emulsion of the oily material having the desired narrow size distribution. The stable emulsion may be mixed with an excess of a partly water soluble material which becomes absorbed by the droplets of the oily material. Said partly water soluble material may comprise a polymerizable monomer, and polymerization is subsequently effected to prepare a dispersion of polymer particles, and if desired, the polymer particles are recovered from said dispersion.
    Type: Grant
    Filed: March 4, 1999
    Date of Patent: December 12, 2000
    Assignee: Nyfotek A/S
    Inventors: Arvid Berge, Kari-Anne Leth-Olsen, John Ugelstad deceased, Anne Dalager Dyrli, Steinar Pedersen
  • Patent number: 6075090
    Abstract: The present invention is a method of making a stable colloidal non-aqueous wax particle dispersion. The method includes the steps of forming a mixture of a first vinyl monomer of a polymerizable mono-alpha, beta-ethylenically unsaturated compound free of ionic charge groups and capable of addition polymerization and a second vinyl monomer capable of addition polymerization and wax particle in a aqueous medum. The mixture is polymerized using an azo or diazo initiator to form an aqueous dispersion of composite wax particles. The wax particles are redispersed in an organic solvent.
    Type: Grant
    Filed: December 28, 1998
    Date of Patent: June 13, 2000
    Assignee: Eastman Kodak Company
    Inventors: Yongcai Wang, James L. Bello, David E. Decker, Dennis E. Smith
  • Patent number: 5994419
    Abstract: Rapidly dissolving/absorbing free-flowing powders of hydrophilic/superabsorbent (co)polymers, having irregular nonspherical morphology and a particle size distribution ranging from 100 .mu.m to 800 .mu.
    Type: Grant
    Filed: November 14, 1997
    Date of Patent: November 30, 1999
    Assignee: Elf Atochem S.A.
    Inventors: Christian Collette, Manuel Hidalgo, Jean-Marc Corpart, Andre Kowalik, Paul Mallo
  • Patent number: 5925714
    Abstract: Improved water soluble vinyl addition polymers for use as thickening and flocculating agents in water purification treatment, paper manufacture and waste water treatment are prepared using alkoxylated castor oil as an activation release agent. The release agent is biodegradable thereby making the overall product process more environmentally friendly.
    Type: Grant
    Filed: March 4, 1994
    Date of Patent: July 20, 1999
    Assignee: SNF S.A.
    Inventors: Eric H. Larson, Manilal Dahanayake, William R. Busler
  • Patent number: 5880240
    Abstract: An alkyl-containing porous resin with a specific surface area of 50 to 600 m.sup.2 /g, the resin being prepared by polymerizing a monomer mixture of, based on the total weight of the monomers, 15 to 97% by weight of divinylbenzene, 0 to 82% by weight of at least one aromatic monovinyl monomer selected from the group consisting of styrene, methylstyrene and ethylvinylbenzene and 3 to 50% by weight of a vinylbenzyloxyalkane derivative represented by the formula ##STR1## wherein n is an integer of 1 to 18, a process for its preparation and its use.The porous resin of the invention is capable of fully exhibit its modified functions based on the variations of chemical and structural environments on the surface of resin, the functions being modified by introducing alkyl groups having varying chain lengths.
    Type: Grant
    Filed: November 26, 1997
    Date of Patent: March 9, 1999
    Assignee: Arakawa Chemical Industries, Ltd.
    Inventor: Takaharu Tsuno
  • Patent number: 5780564
    Abstract: The invention relates to a homo- or copolymer of vinyl chloride. The polymer contains 0.01-50% of an oligomer of a C.sub.4 -C.sub.20 .alpha.-olefin or of an internal olefin or of their mixtures.
    Type: Grant
    Filed: March 7, 1996
    Date of Patent: July 14, 1998
    Assignee: Topvin Oy
    Inventor: Hannu Harjuhahto
  • Patent number: 5739221
    Abstract: Expandable styrene resin beads are described, which, when expanded to a bulk density of 20 g/l, give pre-expanded beads in which the number of cells present along those surface parts of radii which range from the bead surface to a depth of 0.2 mm from the surface is from 3 to 20 per mm and to the bead center is 10 or larger per mm, the number of the number of cells present along those inner parts of the radii which range from a depth of 1 mm from the bead surface to the bead center is 10 or larger per mm, the number of cells present along said surface parts being smaller than the number of cells present along said inner parts.
    Type: Grant
    Filed: May 3, 1996
    Date of Patent: April 14, 1998
    Assignee: Mitsubishi Chemical BASF Company Limited
    Inventors: Hiroki Shinozaki, Masayuki Tanaka, Yonezo Ueda
  • Patent number: 5731395
    Abstract: A functional group-containing porous resin prepared by polymerization of a monomer mixture of, based on 100% by weight of the total amount of the monomers, 15 to 97% by weight of divinylbenzene, 0 to 82% by weight of at least one aromatic monovinyl monomer selected from the group consisting of styrene, methylstyrene and ethylvinylbenzene and 3 to 30% by weight of a vinylbenzyloxyalkyl derivative represented by the formula ##STR1## wherein n is an integer of 2 to 16 and A represents a hydroxyl group or a halogen atom, and a process for preparing the same. The above-mentioned porous resin of the invention can fully exhibit its function due to the marked presence of a functional group on the surface of the resin and/or in the neighborhood thereof.
    Type: Grant
    Filed: November 13, 1996
    Date of Patent: March 24, 1998
    Assignee: Arakawa Chemical Industries, Ltd.
    Inventor: Takaharu Tsuno