Material Contains Water And A Hydrocarbon Patents (Class 526/207)
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Patent number: 10391474Abstract: The present disclosure provides a process for preparing a hydrocarbon fuel from waste rubber. The process involves admixing, in a reaction vessel, at least one fluid medium with the waste rubber to obtain a slurry; wherein the concentration of the waste rubber in the slurry ranges from 45% to 70%. A reactor is charged with the slurry and a predetermined amount of at least one catalyst composition to obtain a mixture, followed by introduction of hydrogen to the reactor to attain a predetermined pressure and heating the mixture at a predetermined temperature, to attain an autogenously generated pressure, and for a predetermined time period to obtain a reaction mass comprising the hydrocarbon fuel. This reaction mass comprising the hydrocarbon fuel is then cooled to obtain a cooled reaction mass. The hydrocarbon fuel is then separated from the cooled reaction mass.Type: GrantFiled: May 16, 2017Date of Patent: August 27, 2019Assignee: Reliance Industries LimitedInventors: Kshudiram Mantri, Mandan Chidambaram, Ramesh Bhujade, Nagesh Sharma, Raksh Vir Jasra
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Patent number: 9320660Abstract: The present invention provides a method for producing water-absorbing resin particles having high equilibrium swelling capacity, a high water-absorption rate or high initial swelling capacity, and an appropriate particle size that achieves good handling performance; water-absorbing resin particles obtained by the method; and a water blocking material and an absorbent article which include the water-absorbing resin particles. The present invention is a method for producing water-absorbing resin particles, which comprises: preparing a hydrogel polymer by reversed-phase suspension polymerization of a water-soluble ethylenically unsaturated monomer in a hydrocarbon solvent in the absence of an internal crosslinking agent but in the presence of a surfactant with an HLB of 8 to 12; carrying out a post-crosslinking reaction of the hydrogel polymer whose moisture content is adjusted to 30 to 110 mass % based on a water-soluble ethylenically unsaturated monomer component that composes the hydrogel polymer.Type: GrantFiled: November 24, 2010Date of Patent: April 26, 2016Assignee: Sumitomo Seika Chemicals Co., Ltd.Inventors: Sachi Kikuno, Atsushi Heguri, Masayoshi Handa, Nobuhiro Maeda
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Patent number: 9115221Abstract: A method for producing polymer particles includes a suspension step of suspending a first liquid mixture containing an oily olefin monomer and a radical polymerization initiator in a second liquid mixture containing water, an iodide ion, and an iodine molecule, to prepare a suspension in which an oil droplet containing the oily olefin monomer and the radical polymerization initiator is dispersed in the water containing the iodide ion and the iodine molecule, a synthesis step of synthesizing an iodine compound by allowing a radical generated by cleavage of the radical polymerization initiator to react with the iodine molecule in the oil droplet, and a polymerization step of polymerizing the oily olefin monomer in the oil droplet.Type: GrantFiled: October 22, 2013Date of Patent: August 25, 2015Assignee: Canon Kabushiki KaishaInventors: Takayuki Hiratani, Shinnosuke Koji, Kazumichi Nakahama
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Patent number: 8993695Abstract: Heat aging of the composition comprising melt-fabricable tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer, the alkyl containing 1 to 5 carbon atoms and melt flowable polytetrafluoroethylene is effective to cause thermal transformation of the composition in the solid state, which is epitaxial co-crystallization of the polymer components of the composition, and other valuable changes, such as increased continuous use temperature.Type: GrantFiled: January 23, 2014Date of Patent: March 31, 2015Assignee: E I du Pont de Nemours and CompanyInventor: Jacob Lahijani
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Patent number: 8975302Abstract: The disclosure relates to methods of making polymer particles, said methods including the steps of: making an aqueous gel reaction mixture; forming an emulsion having dispersed aqueous phase micelles of gel reaction mixture in a continuous phase; adding an initiator oil comprising at least one polymerization initiator to the continuous phase; and performing a polymerization reaction in the micelles. Further, the initiator oil is present in a volume % relative to a volume of the aqueous gel reaction mixture of between about 1 vol % to about 20 vol %. The disclosure also relates to methods of making nucleic acid polymer particles having the same method steps and wherein the aqueous gel reaction mixture includes a nucleic acid fragment, such as a primer.Type: GrantFiled: July 6, 2012Date of Patent: March 10, 2015Assignee: Life Technologies CorporationInventors: David Light, Barnett Rosenblum
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Publication number: 20140243478Abstract: There is disclosed a method for producing water-absorbent resin particles, comprising a polymerization step that includes mixing an oily liquid comprising a hydrocarbon dispersing medium and a surfactant, and an aqueous liquid comprising an aqueous solvent and a water-soluble ethylenically unsaturated monomer, forming a suspension comprising an oily liquid and an aqueous liquid dispersed in the oily liquid, and polymerizing the water-soluble ethylenically unsaturated monomer in the suspension. The HLB of the surfactant is 6 or greater, and the temperature of the suspension is kept at 35° C. or higher during the period from initial mixing of the oily liquid and aqueous liquid until complete mixing of the entire amounts.Type: ApplicationFiled: September 24, 2012Publication date: August 28, 2014Inventors: Atsushi Heguri, Kenji Tanimura, Yuichi Onoda, Masayoshi Handa
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Patent number: 8785580Abstract: The invention relates to a polyvinylidene fluoride polymer having an ultra-high molecular weight, and unexpected physical properties. The ultra-high molecular weight polymer is clear, has a lower melting point, reduced crystallinity, excellent impact resistance, and a high elongation at the yield point. The ultra-high molecular weight polyvinylidene fluoride can be alone, or blended with other polymers, in final applications and articles.Type: GrantFiled: June 26, 2007Date of Patent: July 22, 2014Assignee: Arkema Inc.Inventor: Ramin Amin-Sanayei
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Publication number: 20140179886Abstract: A method is disclosed for producing a water-absorbent resin by a reversed-phase suspension polymerization method, wherein an odor originating from a raw material component, in particular, a petroleum hydrocarbon dispersion medium, is further reduced as compared with a water-absorbent resin obtained by a conventional method, and a water-absorbent resin obtained by the method. More specifically, a method is disclosed for producing a water-absorbent resin by performing a reversed-phase suspension polymerization of a water-soluble ethylenically unsaturated monomer in a petroleum hydrocarbon dispersion medium, comprising adding and dispersing an aqueous solution of a water-soluble ethylenically unsaturated monomer containing a hydrophilic polymeric dispersion agent to a petroleum hydrocarbon dispersion medium in the presence of a surfactant under stirring, and performing a reversed-phase suspension polymerization using a radical polymerization initiator, and a water-absorbent resin obtained by the method.Type: ApplicationFiled: July 20, 2011Publication date: June 26, 2014Applicant: SUMITOMO SEIKA CHEMICALS CO., LTD.Inventors: Hideki Yokoyama, Atsushi Heguri, Nobuhiro Maeda
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Publication number: 20140127510Abstract: Disclosed is a water-absorbent resin particle in which the water-absorption rate of physiological saline is 1 second to 15 seconds, the median particle size is 100 ?m to 600 ?m, and the residual volatile component content is 1.5% by weight or less.Type: ApplicationFiled: July 23, 2012Publication date: May 8, 2014Applicant: SUMITOMO SEIKA CHEMICALS CO., LTD.Inventors: Masayoshi Handa, Kenji Tanimura, Atsushi Heguri, Yuichi Onoda
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Patent number: 8470942Abstract: The claimed invention relates to a method for producing a melt-moldable tetrafluoroethylene copolymer containing repeating units (a) based on tetrafluoroethylene and repeating units (b) based on another fluoromonomer, wherein the amount of the repeating units (a), based on the total mass of the repeating units (a) and the repeating units (b), is from 97.3 to 99.5 mass %, and the volume flow rate of the copolymer is from 0.1 to 1000 mm3/s; the process including radical suspension-polymerization of tetrafluoroethylene and the fluoromonomer in an aqueous medium in the presence of a radical polymerization initiator and at least one chain transfer agent selected from the group consisting of methane, ethane, a hydrochlorocarbon, a hydrofluorocarbon and a hydrochlorofluorocarbon.Type: GrantFiled: March 11, 2009Date of Patent: June 25, 2013Assignee: Asahi Glass Company, LimitedInventors: Atsushi Funaki, Shigeki Kobayashi, Hiroki Nagai
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Publication number: 20120116015Abstract: A polymerization process is provided, comprising polymerizing fluoromonomer in an aqueous medium to form a dispersion of fluoropolymer particles in the aqueous medium, said polymerizing being carried out in the presence of (i) polymerization initiator, and (ii) hydrocarbon-containing surfactant stabilizing the dispersion of fluoropolymer particles, the hydrocarbon-containing surfactant being passivated to reduce its the telogenic behavior.Type: ApplicationFiled: November 9, 2011Publication date: May 10, 2012Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventors: Paul Douglas Brothers, Subhash Vishnu Gangal, Dipti Dilip Khasnis
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Publication number: 20120052316Abstract: Described is an aqueous polymer dispersion comprising a chain growth addition polymer obtainable by free-radically initiated emulsion polymerization of ethylenically unsaturated, free-radically polymerizable monomers, wherein the polymerization of the monomers is effected in the presence of a certain molecular weight regulator composition. The molecular weight regulator composition comprises at least one mercaptoalkylcarboxylic ester of a C2- to C4-carboxylic acid and at least one oligomeric compound of the formula R1—X-(A-S—)n-A-Y—R2, where R1 and R2 are each H or CH3—(CH2)0-2—C(?O)—, X and Y are each an oxygen atom or a sulfur atom, A is a divalent C1- to C18-alkylene group and n is from 1 to 8. Also described is a process for preparing the aqueous polymer dispersion. The polymer dispersion is useful as a binder, an adhesive, a sizing agent for fibers, in the manufacture of coatings or in the manufacture of paper coating slips.Type: ApplicationFiled: August 24, 2011Publication date: March 1, 2012Applicant: BASF SEInventors: Elitsa Evstatieva, Dirk Lawrenz, Johannes Jan-Bessel Minderhoud, Florian Garlichs, Peter Bassler, Jens Baldamus
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Patent number: 7999050Abstract: A method of making a composition comprising reacting, in a reactor, a non-halogenated acetoacetate group containing monomer, at least one additional monomer, and a base, wherein at least a portion of the base is fed to the reactor during reaction. Also, a composition comprising an aqueous polymer dispersion that is a product of a method comprising reacting a non-halogenated acetoacetate moiety containing monomer, at least one additional monomer, and a base, wherein the base is fed to the reaction during reaction, wherein the composition has a lower viscosity than a second composition, wherein the second composition is prepared from the same materials as the composition, and the second composition is made by a method wherein the base is added to the second composition after a reaction to form the second composition.Type: GrantFiled: August 10, 2006Date of Patent: August 16, 2011Assignee: BASF SEInventor: Cheng-Le Zhao
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Patent number: 7956128Abstract: A thermoplastic resin composition for a refrigerator according to the present invention can include (A) about 20 to about 40 parts by weight of an acrylonitrile-butadiene-styrene graft copolymer resin prepared by grafting in emulsion polymerization about 60 to about 30% by weight of a monomer mixture comprising a cyanide vinyl compound and an aromatic vinyl compound to about 40 to about 70% by weight of a rubber polymer having an average particle size of about 0.1 to about 0.4 ?m; (B) about 1 to about 20 parts by weight of a styrenic copolymer comprising (b1) about 0 to about 75% by weight of a styrenic copolymer prepared by copolymerizing about 5 to about 20% by weight of a rubber polymer having an average particle size of about 0.Type: GrantFiled: June 28, 2007Date of Patent: June 7, 2011Assignee: Cheil Industries Inc.Inventors: Kang Yeol Park, Hee Jung Park, Jae Hyung Lee
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Publication number: 20110130534Abstract: The invention relates to a polyHIPE material provided with high mechanical strength, which material comprises at least one N-alkenyltriazole monomer and a cross-linking monomer in a weight ratio of cross-linking monomer/N-alkenyltriazole monomer of 1/100 to 60/100. It also relates to a process and an emulsion allowing this emulsion to be prepared, and to an article formed in whole or in part of this material, and notably a catalyst support for heterogeneous catalysis, a particle filter, metal ion adsorbent, or gas sensor.Type: ApplicationFiled: June 8, 2009Publication date: June 2, 2011Applicant: Commissariat A L'Energie AtomiqueInventors: Oliver Besnard, Eric Pasquinet, Herve Deleuze, Marc Birot, Fabrice Audouin
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Patent number: 7709052Abstract: Alkyldiketene-containing aqueous polymer dispersions which are obtainable by miniemulsion polymerization of hydrophobic monoethylenically unsaturated monomers in the presence of alkyldiketenes, processes for the preparation of such polymer dispersions and the use of the thus obtainable dispersions as sizes for paper or as water repellents for leather, natural and/or manmade fibers and textiles.Type: GrantFiled: October 9, 2003Date of Patent: May 4, 2010Assignee: BASF AktiengesellschaftInventors: Rainer Dyllick-Brenzinger, Roland Ettl, Franca Tiarks, Ulrich Riebeling
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Publication number: 20080194708Abstract: The present invention relates to the use of a water-soluble or water-dispersible crosslinked polymer obtainable by the polymerization of a mixture comprising 99.99 to 10% by weight of at least one ?,?-ethylenically unsaturated compound having at least one cationogenic and/or cationic group per molecule, 0 to 90% by weight of at least one monoethylenically unsaturated compound containing amide groups which differs from a), and 0.01 to 5% by weight of a crosslinking agent for modifying the rheology of aqueous compositions.Type: ApplicationFiled: March 16, 2006Publication date: August 14, 2008Applicant: BASF AktiengesellschaftInventors: Peter Hossel, Klemens Mathauer, Claudia Wood, Matthias Laubender, Wolfgang Jahnel, Ivette Garcia Castro, Volker Wendel, Karl Kolter
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Patent number: 7282547Abstract: A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M containing from 40 to 80% by weight of styrene as monomer M1, from 20 to 60% by weight of butadiene as monomer M2, and from 0 to 40% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers M3 other than styrene and butadiene by a monomer feed technique in the presence of from 0.05 to 0.5% by weight, based on 100% by weight of monomers, of at least one hydrocarbon HC selected from compounds having 6 to 20 carbon atoms which on abstraction of a hydrogen atom form a pentadienyl radical or a 1-phenylallyl radical and from ?-methylstyrene dimer comprises supplying the monomers to be polymerized to the polymerization reaction over the course of 3 hours.Type: GrantFiled: September 30, 2002Date of Patent: October 16, 2007Assignee: BASF AktiengesellschaftInventors: Lambertus Manders, Thomas Wirth, Wolfgang Gaschler, Hubertus Kroener
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Patent number: 7282545Abstract: A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M containing from 40 to 80% by weight of styrene as monomer M1, from 20 to 60% by weight of butadiene as monomer M2, and from 0 to 40% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers M3 other than styrene and butadiene by a monomer feed technique in the presence of from 0.05 to 0.5% by weight, based on 100% by weight of monomers, of at least one hydrocarbon HC having 6 to 20 carbon atoms, which is selected from compounds which on abstraction of a hydrogen atom form a pentadienyl radical or a 1-phenylallyl radical and from ?-methylstyrene dimer comprises including at least 30% of the hydrocarbon HC in the initial charge to the polymerization vessel and supplying the remainder of the hydrocarbon HC to the polymerization reaction in the course of that reaction.Type: GrantFiled: September 30, 2002Date of Patent: October 16, 2007Assignee: BASF AktiengesellschaftInventors: Wolfgang Gaschler, Volker Schaedler, Lambertus Manders, Thomas Wirth, Hubertus Kroener
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Patent number: 7196146Abstract: A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M containing from 40 to 80% by weight of styrene as monomer M1, from 20 to 60% by weight of butadiene as monomer M2, and from 0 to 40% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers M3 other than styrene and butadiene by a monomer feed technique in the presence of from 0.05 to 0.5% by weight, based on 100% by weight of monomers, of at least one hydrocarbon HC having 6 to 20 carbon atoms selected from compounds which on abstraction of a hydrogen atom form a pentadienyl radical or a 1-phenylallyl radical and ?-methylstyrene dimer comprises raising, at a point in time when at least 70% of the monomers to be polymerized have been supplied to the polymerization reaction, the concentration of butadiene in the monomer feed for a period of at least 1% of the total feed time by at least 10% by weight, based on monomers in the feed.Type: GrantFiled: September 30, 2002Date of Patent: March 27, 2007Assignee: BASF AktiengesellschaftInventors: Lambertus Manders, Thomas Wirth, Wolfgang Gaschler, Hubertus Kroener
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Publication number: 20040171778Abstract: Low color, aromatic modified C5 hydrocarbon resins are disclosed. The resins are predominantly an aromatic modified piperylene resin. The resins are useful as tackifies in hot melt adhesives and hot melt pressure sensitive adhesives.Type: ApplicationFiled: November 13, 2002Publication date: September 2, 2004Inventors: Chretien Pieter Louis C. Donker, Elisabeth E.C.G. Gielens, Gerard A. Verrijzer
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Patent number: 6762248Abstract: An epoxy group-containing acrylic resin for a powder coating is prepared by suspension polymerization at a temperature of at least 80° C. and a pressure of at least 2 kg/cm2 with a vinyl monomer mixture comprising from 10-60% by weight of epoxy group-containing vinyl monomers, from 10-60% by weight of alkyl (meth)acrylate(s), and other vinyl monomer(s). The epoxy group-containing acrylic resin particles possess the following characteristics: i) a weight average molecular weight of from 3000-20,000; ii) an epoxy equivalent of from 350-1200 g/eq; iii) 1000 ppm or less of volatile components; iv) a mean particle diameter of from 80-800 &mgr;m; v) at least 95% by weight of the particles having a long diameter R:short diameter r ratio within the parameters 1<R/r<1.2; and vi) 5% by weight or less of the particles having a long diameter R of less than 62 &mgr;m and 5% by weight or less of particles having a short diameter r of more than 1000 &mgr;m.Type: GrantFiled: November 22, 2002Date of Patent: July 13, 2004Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Yoko Harada, Motoshi Inagaki, Koji Shimizu, Noriyuki Tajiri
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Patent number: 6673861Abstract: Composition comprising an oil phase, an aqueous phase, at least one emulsifying agent of water-in-oil (W/O) type and at least one emulsifying agent of oil-in-water (O/W) type in the form of a self-invertible inverse latex comprising from 20% to 70% by weight, and preferably from 25% to 50% by weight of a branched or crosslinked polyelectrolyte, characterized in that the said polyelectrolyte is either a homopolymer based on a monomer having a partially or completely salified strong acid functional group or a copolymer based on at least one monomer having a partially or completely salified strong acid functional group copolymerized with acrylamide and characterized in that the constituent solvent of the oil phase is chosen from white mineral oils, squalane, hydrogenated polyisobutene, isohexadecane or isododecane. Cosmetic, dermocosmetic, dermopharmaceutical or pharmaceutical composition comprising them.Type: GrantFiled: May 7, 2001Date of Patent: January 6, 2004Assignee: Societe d'Exploitation de Produits pour les Industries Chimiques SeppicInventors: Guy Tabacchi, Jean-Pierre Boiteux, Chantal Almaric, Nelly Michel, Paul Mallo
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Patent number: 6667365Abstract: The present invention relates to a method of manufacturing polymer nano particle having two-photon absorption compound at its central portion. The method of manufacturing polymer nano particle comprises the steps of dispersing a monomer for forming polymer nano particle and two-photon absorption compound into a solvent; supplying a given gas while stirring the solvent in which the monomer and the two-photon absorption compound are dispersed at a given temperature, in order to remove the dissolved oxygen contained in the solvent; supplying polymerization initiators into the solvent while stirring the solvent in which the monomer and the two-photon absorption compound are dispersed at a given temperature; and polymerizing the monomer for a given period of time while stirring the solvent in which the monomer and the two-photon absorption compound are dispersed at a given temperature.Type: GrantFiled: June 27, 2002Date of Patent: December 23, 2003Assignee: Electronics and Telecommunications Research InstituteInventors: Myung Ae Chung, Sang Don Jung
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Patent number: 6646078Abstract: A method of producing a paraffin wax for aqueous dispersion polymerization of TFE which allows high speed aqueous dispersion polymerization of TFE with excellent polymerization behavior such as excellent dispersion stability and consistent production of PTFE having excellent physical properties, and a method of producing PTFE using the paraffin wax. Aqueous dispersion polymerization of tetrafluoroethylene (hereinafter referred to as TFE) is conducted in the presence of a paraffin wax, a polymerization initiator and an emulsifier at least once and then the paraffin wax is recovered. The recovered paraffin wax is used for aqueous dispersion polymerization of TFE in the presence of a polymerization initiator and an emulsifier.Type: GrantFiled: December 20, 2001Date of Patent: November 11, 2003Assignees: Asahi Glass Company, Limited, Asahi Glass Fluoropolymers Co., Ltd.Inventors: Shigeki Kobayashi, Jun Hoshikawa, Kazuo Kato, Hiroki Kamiya, Hiroyuki Hirai
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Patent number: 6605680Abstract: Low color, aromatic modified C5 hydrocarbon resins are disclosed. The resins are predominantly an aromatic modified piperylene resin. The resins are useful as tackifiers in hot melt adhesives and hot melt pressure sensitive adhesives.Type: GrantFiled: April 7, 2000Date of Patent: August 12, 2003Assignee: Eastman Chemical Resins, Inc.Inventors: Chretien P. L. C. Donker, Ester E. C.G. Gielens, Gerard A. Verrijzer
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Publication number: 20030130454Abstract: A process for producing polymers which comprises polymerizing an amphipathic monomer or copolymerizing an amphipathic monomer and another monomer which is copolymerizable therewith, wherein a polymerization solvent, a nonionic chain transfer agent and 1,1′-azobis(cyclohexane-1-carbonitrile) as a polymerization initiator are used together with the monomer. It is thereby possible to produce polymers with high hydrate formation and dissociation-controlling performance, and to produce polymers of low molecular weight with low residual monomer contents using the same amounts of polymerization initiators.Type: ApplicationFiled: November 7, 2002Publication date: July 10, 2003Applicant: Mitsubishi Rayon Co., Ltd.Inventors: Masaaki Seya, Masayuki Tooyama
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Patent number: 6586546Abstract: Aqueous copolymerization of TFE and PAVE in the presence of a small amount of terpene enables the manufacture of a more uniform melt-fabricable copolymer with a narrower molecular weight distribution. The copolymer exhibits improved flex life.Type: GrantFiled: June 14, 2001Date of Patent: July 1, 2003Assignee: DuPont-Mitsui Fluorochemicals Co. Ltd.Inventors: Takahiko Iwasaki, Masahiro Kino
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Patent number: 6566549Abstract: A continuous process for oligomers which do not contain, as polymerized units, carboxylic acid-containing monomers and their salts, including the steps of: (1) forming a reaction mixture, substantially free of carboxylic acid-containing monomers and their salts, containing: (i) 0.5 to 99.95% by weight of the reaction mixture of at least one ethylenically unsaturated monomer; and (ii) 0.05 to 25% by weight, based on the weight of the ethylenically unsaturated monomer, of at least one free-radical initiator; and (2) continuously passing the reaction mixture through a heated zone wherein the reaction mixture is maintained at a temperature of at least 150° C. and a pressure of at least 30 bars for from 0.1 seconds to 4 minutes to form terminally-unsaturated oligomers. In addition, processes for forming oligomers of vinyl acetate and oligomers of vinyl alcohol are disclosed. Mixtures of fully saturated and terminally unsaturated oligomers are also disclosed.Type: GrantFiled: December 15, 1998Date of Patent: May 20, 2003Assignee: Rohm and Haas CompanyInventors: Gary David Greenblatt, Barry Clifford Lange, Michael Damian Bowe, Richard Foster Merritt, Robert Wilczynski, Gary Robert Larson, Lori Marie Petrovich, David William Whitman
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Patent number: 6555640Abstract: Process that is capable of synthesizing a metal-containing resin having a good antifouling property in a short period of time without having such problems associated with the synthesis as gelation. The process for producing a metal-containing resin by conducting a copolymerization reaction of a monomer mixture (A) comprising 1 to 50% by weight of a carboxyl group-containing polymerizable unsaturated monomer (a) and 50 to 99% by weight of other polymerizable unsaturated monomer (b) in an organic solvent in the presence of water and an oxide or hydroxide of a metal having a valency of at least 2, wherein the amount of water is 1 to 30 parts by weight based on 100 parts by weight of the monomer mixture (A), and the formation of a metal carboxylate bond occurs together with the copolymerization of the monomer mixture (A); and an antifouling coating composition containing, as an active constituent, a metal-containing resin obtained by the production process.Type: GrantFiled: September 21, 2000Date of Patent: April 29, 2003Assignee: Kansai Paint Co., Ltd.Inventors: Kei Ito, Chikara Kawamura
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Patent number: 6531557Abstract: A modified polytetrafluoroethylene fine powder containing agglomerates of colloidal particles with an average particle size of from 0.05 to 0.5 &mgr;m which comprise a copolymer of tetrafluoroethylene and an olefin-monomer represented by X(CF2)nOCF═CF2 in which X is a hydrogen atom, a fluorine atom or a chlorine atom, and n is an integer of 1 to 6, and/or C3F7(OCF2CF2CF2)m[OCF(CF3)CF2]pOCF═CF2 in which m and p are independently an integer of 0 to 4, provided that the sum of m and p is not 0 (zero), a content of the olefin monomer being from 0.02 to 0.3 wt. %, wherein the copolymer has a molecular weight distribution Mw/Mn of from 1.5 to 4.5 and a standard specific gravity of from 2.135 to 2.175. This modified polytetrafluoroethylene has good paste extrudability, and provides molded articles having good mechanical properties, in particular, pressure resistance.Type: GrantFiled: March 12, 1999Date of Patent: March 11, 2003Assignee: Daikin Industries Ltd.Inventors: Kazutaka Hosokawa, Yoshinori Nanba, Takahisa Aoyama, Tetsuo Shimizu
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Publication number: 20030022987Abstract: Novel water soluble polymers in solution or water-in-oil emulsion form are disclosed containing quaternary ammonium monomers; and optionally (meth)acrylic acid or 2-(meth)acrylamido-2-methylpropane sulfonic acid; methylene bis-acryamide and the like; and a C1-C3 alkyl (meth)acrylate acrylamide or methacrylamide and the use thereof in hair, skin and nail conditioning; papermaking; and subterranean well drilling and well cementing operations.Type: ApplicationFiled: September 13, 2002Publication date: January 30, 2003Inventors: Gary F. Matz, Randy J. Loeffler, Shih-Ruey T. Chen, Allan L. Melby, Nicholas F. Vozza
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Patent number: 6509420Abstract: An epoxy group-containing acrylic resin for a powder coating composition is a copolymer, having a weight-average molecular weight of 3000 to 20000, of a vinyl monomer mixture comprising 10 to 60% by weight of alkyl ester(s) of (meth)acrylic acid, 10 to 60% by weight of epoxy group-containing vinyl monomer(s) and other vinyl monomer(s), said epoxy group-containing acrylic resin having a mean particle diameter in the range of 80 to 800 &mgr;m, including 95% by weight or more of particles satisfying the relation of 1≦R/r≦1.2 wherein R is a long diameter and r is a short diameter of each particle, and including 1000 ppm or less of volatile components, the amount of the particles having long diameters R of less than 62 &mgr;m being 5% by weight or less, that of the particles having short diameters r of more than 1000 &mgr;m being 5% by weight or less.Type: GrantFiled: September 5, 2000Date of Patent: January 21, 2003Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Yoko Harada, Motoshi Inagaki, Koji Shimizu, Noriyuki Tajiri
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Publication number: 20020132942Abstract: A humidification system (A) for humidifying a dry hydrocarbon stream includes a column (10) which defines an interior cavity (20). The cavity is partially filled with a bed (12) of a packing material (40) and a layer of water (20), leaving a headspace above the water. An inlet (52) adjacent a lower end of the cavity receives a dry hydrocarbon stream which is broken up by the packing material and dissolves water as it passes therethrough. Entrained water droplets fall out of the wet blend in a disengagement zone (70) above the water layer leaving the hydrocarbon stream humidified yet substantially free of liquid water in an upper region (72) of the column.Type: ApplicationFiled: March 14, 2001Publication date: September 19, 2002Inventors: David M. Roggeman, James Oziomek, Timothy L. Tartamella
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Publication number: 20020082343Abstract: A method of producing a paraffin wax for aqueous dispersion polymerization of TFE which allows high speed aqueous dispersion polymerization of TFE with excellent polymerization behavior such as excellent dispersion stability and consistent production of PTFE having excellent physical properties, and a method of producing PTFE using the paraffin wax. Aqueous dispersion polymerization of tetrafluoroethylene (hereinafter referred to as TFE) is conducted in the presence of a paraffin wax, a polymerization initiator and an emulsifier at least once and then the paraffin wax is recovered. The recovered paraffin wax is used for aqueous dispersion polymerization of TFE in the presence of a polymerization initiator and an emulsifier.Type: ApplicationFiled: December 20, 2001Publication date: June 27, 2002Applicant: ASAHI GLASS COMPANY LIMITEDInventors: Shigeki Kobayashi, Jun Hoshikawa, Kazuo Kato, Hiroki Kamiya, Hiroyuki Hirai
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Patent number: 6407186Abstract: A process for preparing low molecular weight, highly reactive polyisobutylene having an average molecular weight Mn of from 500 to 5000 Dalton and a terminal double bond content of more than 80 mol % by polymerization in the liquid phase of isobutene or hydrocarbon streams comprising isobutane [sic] with the aid of a boron trifluoride complex catalyst at from −40 to 20° C. and at from 1 to 20 bar comprises a) polymerizing until the residual isobutene content of the reaction mixture is less than 2% by weight, based on isobutene introduced, or removing residual isobutene towards the end of the polymerization until the residual isobutene content is less than 2% by weight, b) enriching the boron trifluoride complex catalyst which is obtained in the form of droplets in the disperse and/or coherent phase, c) recycling the complex-enriched phases to the polymerization and d) compensating for catalyst losses by adding boron trifluoride and, if necessary, complexing agents.Type: GrantFiled: June 12, 2000Date of Patent: June 18, 2002Assignee: BASF AktiengesellschaftInventors: Hans Peter Rath, Ulrich Kanne, Frans van Deyck
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Publication number: 20020040109Abstract: The present invention provides a method to improve the efficiency of ROMP-hydrogenation and ROMP-hydrogenolysis processes. Thus the invention provides a means for increasing the rate of reaction of the hydrogenation step of the ROMP-hydrogenation process via the addition of non-inert solvent such as methanol. The present invention permits multiple cycles of ROMP-hydrogenation-ROMP and ROMP-hydrogenolysis-ROMP without additional catalyst, thus allowing the formation of tailored polymer blends in a ‘one-pot’ reaction. Moreover, the ROMP-hydrogenation reactions of the present invention may be carried out at pressures as low as atmospheric pressure.Type: ApplicationFiled: March 26, 2001Publication date: April 4, 2002Inventors: Deryn Elizabeth Fogg, Samantha Dawn Drouin, Fojan Zamanian
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Patent number: 6340733Abstract: The present invention describes a process for the making of a copolymer of the general formula (I) wherein A is a residue of at least one (meth)acrylate monomeric species, B is a residue of at least one monomeric species copolymerizable with A, R is a (meth)acrylate functionalized pendant ester group, X1 and X2 are terminal groups which may be the same or different, n and p are both at least one and are chosen such that the copolymer has a number average molecular weight of more than 2000.Type: GrantFiled: November 30, 2000Date of Patent: January 22, 2002Assignee: Imperial Chemical Industries PLCInventors: Andrew Trevithick Slark, Michael Stephen Chisholm, Helen Harte
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Publication number: 20010037006Abstract: A method for the preparation of gel-free poly 2-hydroxyethyl methacrylate substantially in the absence of a chain transfer agent, comprising introducing monomeric 2-hydroxyethyl methacrylate containing ethylene glycol dimethacrylate impurities in the range of about 0.05 to 0.1% by weight into a solution of alcohol and water and polymerizing. The present invention also provides a method for the preparation of gel-free homopolymer of 4-hydroxybutyl acrylate substantially in the absence of a chain transfer agent in an alcohol or in solution of alcohol and water. The present invention also provides a method for the preparation of gel-free copolymer of 2-hydroxyethyl methacrylate and 4-hydroxybutyl acrylate substantially in the absence of a chain transfer agent, comprising introducing monomeric 2-hydroxyethyl methacrylate containing ethylene glycol dimethacrylate impurities in the range of about 0.05 to 0.1 % by weight with monomeric 4-hydroxybutyl acrylate into a solution of alcohol and water.Type: ApplicationFiled: January 10, 2001Publication date: November 1, 2001Inventor: Daniel L. Holguin
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Publication number: 20010007009Abstract: Polymers based on monomers having a C-C double bond and/or C-C triple bond are prepared by polymerization of these monomers in the presence of a catalyst system comprising as active constituentsType: ApplicationFiled: December 5, 2000Publication date: July 5, 2001Inventors: Lambertus Manders, Marc Oliver Kristen, Alexander Haunschild, Michael Geprags
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Patent number: 6238486Abstract: The invention provides novel cationic flocculant dispersion polymers that can be utilized in the methods disclosed herein. This invention also provides methods for detecting cationic flocculants wherein said flocculants may be made via a dispersion process, a latex process or a dry polymer process. The flocculants are used to flocculate solids from liquid components of an industrial food process. The detection method involves the use of monoclonal antibodies to determine the presence or concentration of the cationic flocculants in the liquids.Type: GrantFiled: March 10, 1999Date of Patent: May 29, 2001Assignee: Nalco Chemical CompanyInventors: Andrew J. Dunham, Cathy C. Johnson, Kristine S. Salmen, John W. Sparapany, Anthony G. Sommese
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Patent number: 6191242Abstract: Unsheared, water-soluble, branched, high molecular weight, anionic, polymeric flocculants are produced by polymerizing ethylenically unsaturated anionic, and optionally non-ionic, monomers and a branching agent in the presence of a chain-transfer agent. They are useful as flocculating agents for releasing water from dispersions of suspended solids.Type: GrantFiled: November 27, 1996Date of Patent: February 20, 2001Assignee: Cytec Technology Corp.Inventors: Roderick Glyn Ryles, Roger Edgar Neff, Joseph Jacinto Pellon
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Patent number: 6160061Abstract: A process for preparing an aqueous emulsion with a narrow droplet size distribution of an oily material comprising one or more highly water insoluble substances, wherein the oily material is homogenized in a hydrophilic phase in which the oily material is more soluble than in water, but still so insoluble that an emulsion is formed by the homogenization, and the emulsion is subsequently diluted with a high proportion of water to form a stable emulsion of the oily material having the desired narrow size distribution. The stable emulsion may be mixed with an excess of a partly water soluble material which becomes absorbed by the droplets of the oily material. Said partly water soluble material may comprise a polymerizable monomer, and polymerization is subsequently effected to prepare a dispersion of polymer particles, and if desired, the polymer particles are recovered from said dispersion.Type: GrantFiled: March 4, 1999Date of Patent: December 12, 2000Assignee: Nyfotek A/SInventors: Arvid Berge, Kari-Anne Leth-Olsen, John Ugelstad deceased, Anne Dalager Dyrli, Steinar Pedersen
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Patent number: 6075090Abstract: The present invention is a method of making a stable colloidal non-aqueous wax particle dispersion. The method includes the steps of forming a mixture of a first vinyl monomer of a polymerizable mono-alpha, beta-ethylenically unsaturated compound free of ionic charge groups and capable of addition polymerization and a second vinyl monomer capable of addition polymerization and wax particle in a aqueous medum. The mixture is polymerized using an azo or diazo initiator to form an aqueous dispersion of composite wax particles. The wax particles are redispersed in an organic solvent.Type: GrantFiled: December 28, 1998Date of Patent: June 13, 2000Assignee: Eastman Kodak CompanyInventors: Yongcai Wang, James L. Bello, David E. Decker, Dennis E. Smith
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Patent number: 5994419Abstract: Rapidly dissolving/absorbing free-flowing powders of hydrophilic/superabsorbent (co)polymers, having irregular nonspherical morphology and a particle size distribution ranging from 100 .mu.m to 800 .mu.Type: GrantFiled: November 14, 1997Date of Patent: November 30, 1999Assignee: Elf Atochem S.A.Inventors: Christian Collette, Manuel Hidalgo, Jean-Marc Corpart, Andre Kowalik, Paul Mallo
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Patent number: 5925714Abstract: Improved water soluble vinyl addition polymers for use as thickening and flocculating agents in water purification treatment, paper manufacture and waste water treatment are prepared using alkoxylated castor oil as an activation release agent. The release agent is biodegradable thereby making the overall product process more environmentally friendly.Type: GrantFiled: March 4, 1994Date of Patent: July 20, 1999Assignee: SNF S.A.Inventors: Eric H. Larson, Manilal Dahanayake, William R. Busler
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Patent number: 5880240Abstract: An alkyl-containing porous resin with a specific surface area of 50 to 600 m.sup.2 /g, the resin being prepared by polymerizing a monomer mixture of, based on the total weight of the monomers, 15 to 97% by weight of divinylbenzene, 0 to 82% by weight of at least one aromatic monovinyl monomer selected from the group consisting of styrene, methylstyrene and ethylvinylbenzene and 3 to 50% by weight of a vinylbenzyloxyalkane derivative represented by the formula ##STR1## wherein n is an integer of 1 to 18, a process for its preparation and its use.The porous resin of the invention is capable of fully exhibit its modified functions based on the variations of chemical and structural environments on the surface of resin, the functions being modified by introducing alkyl groups having varying chain lengths.Type: GrantFiled: November 26, 1997Date of Patent: March 9, 1999Assignee: Arakawa Chemical Industries, Ltd.Inventor: Takaharu Tsuno
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Patent number: 5780564Abstract: The invention relates to a homo- or copolymer of vinyl chloride. The polymer contains 0.01-50% of an oligomer of a C.sub.4 -C.sub.20 .alpha.-olefin or of an internal olefin or of their mixtures.Type: GrantFiled: March 7, 1996Date of Patent: July 14, 1998Assignee: Topvin OyInventor: Hannu Harjuhahto
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Patent number: 5739221Abstract: Expandable styrene resin beads are described, which, when expanded to a bulk density of 20 g/l, give pre-expanded beads in which the number of cells present along those surface parts of radii which range from the bead surface to a depth of 0.2 mm from the surface is from 3 to 20 per mm and to the bead center is 10 or larger per mm, the number of the number of cells present along those inner parts of the radii which range from a depth of 1 mm from the bead surface to the bead center is 10 or larger per mm, the number of cells present along said surface parts being smaller than the number of cells present along said inner parts.Type: GrantFiled: May 3, 1996Date of Patent: April 14, 1998Assignee: Mitsubishi Chemical BASF Company LimitedInventors: Hiroki Shinozaki, Masayuki Tanaka, Yonezo Ueda
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Patent number: 5731395Abstract: A functional group-containing porous resin prepared by polymerization of a monomer mixture of, based on 100% by weight of the total amount of the monomers, 15 to 97% by weight of divinylbenzene, 0 to 82% by weight of at least one aromatic monovinyl monomer selected from the group consisting of styrene, methylstyrene and ethylvinylbenzene and 3 to 30% by weight of a vinylbenzyloxyalkyl derivative represented by the formula ##STR1## wherein n is an integer of 2 to 16 and A represents a hydroxyl group or a halogen atom, and a process for preparing the same. The above-mentioned porous resin of the invention can fully exhibit its function due to the marked presence of a functional group on the surface of the resin and/or in the neighborhood thereof.Type: GrantFiled: November 13, 1996Date of Patent: March 24, 1998Assignee: Arakawa Chemical Industries, Ltd.Inventor: Takaharu Tsuno