Abstract: The present invention resides in the discovery that ethylenically unsaturated organic compounds can be readily photopolymerized by adding to such compounds a catalytic formulation including certain FDA approved food color additives and an amount of an organic amine activator. Particularly improved results are obtained by employing as said food color additive the combination of FD&C red No. 3 dye, with either FD&C red No. 2 dye, FD&C red No. 40 dye, or with both FD&C red No. 2 and FD&C red No. 40 dyes.

Abstract: Ultraviolet polymerization of photopolymerizable binders or vehicles is improved by incorporating thereinto a sensitizer composition comprising an activated halogenated azine compound.

Abstract: Vinyl chloride monomer, or a monomeric mixture comprising vinyl chloride as a main component and other monomers co-polymerizable therewith in an aqueous reaction medium, is polymerized in a polymerization vessel. All of the surfaces of the inside walls of the vessel and the agitator blades, the baffle plates and the like with which the vessel is equipped, are coated prior to the polymerization with at least one of a specific class of nitrogen-containing aromatic heterocyclic compounds. Not only is the deposition of polymer scale surprisingly reduced, but also the polymer thus obtained has good physical and chemical properties.

Abstract: A copolymer derived from a monomeric mixture comprising from 20 to 60 parts of acrylic or methacrylic acid, from 20 to 70 parts of a lower alkyl acrylate or methacrylate, and from 5 to 20 parts of a plasticizing monomer is at least partially neutralized by multivalent cations.

Abstract: Novel alternating copolymers having functional groups are prepared by subjecting to alternating copolymerization at least one olefin, at least one acrylic ester and at least one .alpha.,.beta.-ethylenically unsaturated dicarboxylic acid or its derivative represented by the formula: ##EQU1## wherein Y and Z are independently --O--, --S--, or --NR.sup.3 --, and R.sup.1, R.sup.2 and R.sup.3 are independently hydrogen or hydrocarbon groups having 1 to 20 carbon atoms. Said alternating copolymer consists essentially of a structure in which said olefin is bonded to only said acrylic ester or said .alpha.,.beta.-ethylenically unsaturated dicarboxylic acid or its derivative, and said acrylic ester and said .alpha.,.beta.-ethylenically unsaturated dicarboxylic acid or its derivative are bonded to only said olefin, and has a sufficiently high molecular weight.

Abstract: A method of polymerising a composition comprising an allyl amine salt of a strong acid said allyl amine containing two or more allyl groups which method comprises reacting said composition in the presence of a free radical initiator which yields only uncharged fragments and at a temperature between -20 and 80.degree.C and at a pH between 0 and 5 in the absence of oxygen.

Abstract: Polymerization of vinyl chloride in aqueous suspension in the presence of free-radical initiators of short half-life at pH's below 8. The temperature of the reactor wall must not be more than 20.degree.C above the temperature of the polymerization mixture during the heat-up phase and it must be lower than the temperature of the polymerization mixture during the subsequent polymerization phase. This procedure suppresses the formation of incrustations in the reactor.

Abstract: An amorphous substantially linear atactic alternating copolymer having a glass transition temperature less than about 0.degree.C., and an inherent viscosity of about 1 to about 6, said copolymer having repeating units of -A-B- wherein A is a unit of at least one C.sub.1 -C.sub.8 alkyl acrylate and cure-site monomer if the cure-site monomer is an acrylic, and B is independently selected from ethylene and cure-site monomers if the cure-site monomer is an .alpha.-olefin. These copolymers are prepared by reacting monomers in the presence of boron trifluoride and a free radical initiator and, when cured, are particularly useful as elastomers.

Abstract: Novel crosslinked heteropolymers of vinyl acetate and maleic anhydride are provided which are useful as aqueous thickeners for aqueous formulations such as cosmetics and latex paints. Ester and amide derivatives of the combined maleic anhydride portion of the heteropolymer are also provided. The process for preparing the crosslinked heteropolymers comprises adding a maleic anhydride monomer, and crosslinking agent monomer, and catalyst in controlled amounts to a monomer solution of vinyl acetate.

Abstract: Compounds which contain azo linkages as well as the radical of an ultraviolet light stabilizing group are described. These compounds function as polymerization initiators which cause an ultraviolet light stabilization group to be chemically bound to the polymer.

Abstract: Polymeric compositions having desirable film-forming characteristics and water-barrier properties at substantially neutral pH's and yet solubilizable and thus disposable at substantially non-neutral pH's comprise a silane crosslinked interpolymer of an alkyl acrylate and a monomer interpolymerizable therewith such as, in the preferred alkaline labile embodiment, acrylic acid. The silane crosslinking monomer is preferably 3-(trimethoxysilyl)-propyl methacrylate or 3-(trimethoxysilyl)-propyl acrylate. The resultant pH-sensitive polymeric composition may be used, for example, as a binder for other materials, such as webs of non-woven water-dispersible fibers, or may be used in film form either by itself or preferably laminated to other dispersible materials to produce a variety of products which are completely disposable at selected non-neutral pH's.

Abstract: Polymer or copolymer of vinyl chloride having superior properties can be produced by suspension-polymerizing vinyl chloride or a mixture thereof with another vinyl monomer, at first, in the presence of an oil-soluble radical initiator, and thereafter, when the percentage of polymerization of the resulting polymer has reached about 15% to about 80%, subjecting the polymer to a further polymerization in the presence of a water-soluble radical initiator.The product thus obtained has both the merits resulting from suspension polymerization and emulsion one. It has an extremely high absorptivity of plasticizer, easy processability, and film made therefrom has substantially no fish eye.