Abstract: Aqueous emulsion comprising: —25-70 wt % organic peroxide, based on the weight of the emulsion, —a cyclohexane dicarboxylate ester, and —water. This emulsion is storage stable and can be used for the production of polymers, in particular PVC, that come into contact with food products.

Abstract: The present invention provides a method for producing water-absorbent resin particles which show an excellent water absorption rate and high equilibrium swelling capacity and which have an appropriate particle size to be excellent in handleability, and water-absorbent resin particles obtained by the method.

Abstract: The present invention provides a method for producing water-absorbent resin particles which show an excellent water absorption rate and high equilibrium swelling capacity and which have an appropriate particle size to be excellent in handleability, and water-absorbent resin particles obtained by the method.

Abstract: The invention pertains to a process for manufacturing a fluoroelastomer [fluoroelastomer (A)] having a heat of fusion of less than 5 J/g as measured by ASTM D-3418-08, said method comprising emulsion polymerizing vinylidene fluoride (VDF) in the presence of at least one additional fluorinated monomer, in an aqueous polymerization medium, said method comprising polymerizing VDF and said additional fluorinated monomer(s) in the presence of a redox radical initiator system comprising: —at least one organic oxidizing agent [agent (O)]; —at least one organic reducing agent [agent (R)]; wherein agent (O) is fed to said polymerization medium separately from agent (R), so that agent (O) comes in contact with agent (R) exclusively in said polymerization medium comprising VDF and optional additional monomer(s), to fluoroelastomers having low amount of chain defects and low amount of polar end groups, notably obtainable from said process, and to curable compositions therefrom.

Abstract: The present invention relates to a method for preparing a polymer based on N-vinyl lactam monomer units, which comprises a step (E) for controlled radical polymerization of a composition comprising: monomers containing (and most often consisting of) N-vinyl lactam monomers, either identical or different (and generally identical); an agent for controlling the radical polymerization, for example comprising a thiocarbonylthio group —S(C?S)—; and a radical polymerization initiator which is a redox system comprising a reducing agent (Red) and an oxidizing agent (Ox).

Abstract: Provided is a method for disassembling a bonded body, whereby the bonded body can be easily disassembled and peeled. The method for disassembling a bonded body formed by bonding substrates with an adhesive comprises irradiating light having a wavelength of 280 nm or more such that irradiation energy is 1000-5000000 mJ/cm2 at a wavelength of 365 nm while heating the bonded body to 150° C.-300° C.

Abstract: The present invention relates to cure accelerators useful for anaerobic curable compositions, such as adhesives and sealants.

Abstract: A polyol composition comprising a polyol (a) and resin fine particles (b) dispersed in the polyol (a), and a method for producing the polyol composition are provided, wherein the resin fine particles (b) are particles such that an arithmetic standard deviation by volume of a particle size distribution of the particles, derived from respective values in 85 divisions of a range of 0.020 to 2000 ?m determined by a laser diffraction/scattering particle size distribution analyzer, is not more than 0.6. A resin fine particle-dispersed polyol composition that, even if the resin particles dispersed in the polyol have a small particle diameter, allows the production of a polyurethane resin having an excellent mechanical strength such as elongation at break, and a method for producing the same, are provided.

Abstract: The object of the present invention is to provide a process for producing a high-quality polymer microparticle having uniform particle size of the order of several micrometers to tens of micrometers by inverse suspension polymerization at high productivity while keeping excellent dispersion stability without causing aggregation among particles. The process is one for the production of polymer microparticles by inverse polymerization of a vinyl monomer and is characterized in that the inverse suspension polymerization is conducted dividing at least two steps, an oil-soluble oxidizing agent and a water-soluble reducing agent are used as a polymerization initiator, and the oil-soluble oxidizing agent is fed after the water-soluble reducing agent is fed.

Abstract: The object of the present invention is to provide a process for producing high-quality polymer microparticles having uniform particle size of the order of several micrometers to tens of micrometers by inverse suspension polymerization at high productivity while keeping excellent dispersion stability without causing aggregation among particles. The process is one for the production of polymer microparticles by inverse polymerization of a vinyl monomer and is characterized in that an oil-soluble oxidizing agent and a water-soluble reducing agent are used as a polymerization initiator and the oil-soluble oxidizing agent is fed after the water-soluble reducing agent is fed.

Abstract: Composition which contains polymerizable binder and an initiator according to the following Formula I: R1—X—O—O—[Y—O—O—-]nR2??(Formula I) and having a large through-curing depth and a sufficiently long processing time and which cures without the development of high temperatures.

Abstract: A rubber-modified polymeric composition having predominately core-shell morphology is disclosed. The rubber-modified polymeric composition can be a polystyrene comprising styrene, polybutadiene, and a high-grafting initiator formed by contacting singlet oxygen with an olefin containing an allylic hydrogen or a diene to form a hydroperoxide or peroxide. The singlet oxygen can be formed by contacting ground state oxygen with a photo catalyst, such a photosensitive dye exposed to light.

Abstract: The object of the present invention is to provide a process for producing a high-quality polymer microparticle having uniform particle size of the order of several micrometers to tens of micrometers by inverse suspension polymerization at high productivity while keeping excellent dispersion stability without causing aggregation among particles. The process is one for the production of polymer microparticles by inverse polymerization of a vinyl monomer and is characterized in that the inverse suspension polymerization is conducted dividing at least two steps, an oil-soluble oxidizing agent and a water-soluble reducing agent are used as a polymerization initiator, and the oil-soluble oxidizing agent is fed after the water-soluble reducing agent is fed.

Abstract: Processes and products utilizing (meth)acrylic esters of poly(trimethylene ether) glycol are provided. Products that can be made include ceramic materials, personal care products, inks, coatings, fabrics, and other articles that can be made from reaction products of (meth)acrylic ester of poly(trimethylene ether) glycol with certain monomers.

Abstract: The present invention relates to new cure accelerators for anaerobic curable compositions. These anaerobic cure accelerators are generally sulfonimide derivatives and sulfonamide derivatives.

Abstract: A method is disclosed for producing polyvinyl chloride which includes mixing a vinyl chloride solution with an initiator solution in at least one high shear mixing device comprising at least one rotor/stator set producing a rotor tip speed of at least 5.1 m/sec (1000 ft/min), to form a polymerization mixture; and allowing the mixture to polymerize by free radical polymerization to form polyvinyl chloride. The polymerization mixture may be subjected to free radical polymerization conditions comprising a temperature in the range of about 20° C. to about 230° C. In some embodiments, the high shear mixing device produces a shear rate of at least 20,000 s?1. A system for carrying out the method is also disclosed.

Abstract: There is provided a process for the preparation of a polymerizable composition comprising a cross-linker and a polymerizable monomer of formula (I) comprising (i) contacting a compound of formula (II) with an acid such as an imobilized acid; and (ii) neutralizing product of (i) such that a crosslinker is formed.

Abstract: A process for producing water-absorbing polymer particles by polymerizing droplets of a monomer solution, where the monomer solution comprises at least two initiators, one of the initiators is a peroxide with the exception of persulfate, and the molar ratio of peroxide to further initiator is at least 1:8, the water-absorbing polymer particles themselves, and hygiene articles comprising these water-absorbing polymer particles.

Abstract: The invention relates to a process for preparing polythiophene dispersions or for in situ deposition of polythiophenes. The dispersion is prepared by oxidative polymerizing of a thiophene or thiophene derivative, wherein an oxidizing agent is used and is at least one organic peroxidic compound excluding diacyl peroxide. The invention also relates to the use of specific organic peroxides as oxidizing agents in the oxidative polymerization of thiophenes. The invention further relates to a process to process a conductive layer and the use of the conductive layer.

Abstract: A process for preparing polyvinylpyrrolidones by free-radically initiated polymerization in the presence of an initiator found, which comprises performing the polymerization as a spray or droplet polymerization.

Abstract: Compositions comprising a cross-linked isocyanurate homopolymer or other cross-linked triazine homopolymers in the form of a microbead that is porous or non-porous; methods of making; and methods of using the compositions are disclosed.

Abstract: The invention relates to highly concentrated aqueous emulsions of peroxides comprising an anti-freeze agent, a polyvinyl acetate with a degree of hydrolysis between 45 and 80%, and optionally a non-ionic surfactant with an HLB value greater than 10 selected from alkylene oxide block-copolymers, ethoxylated fatty alcohols, and ethoxyfated fatty acids. The emulsions have a low COD value and are safe, storage stable, and generally applicable.

Abstract: The present invention relates to phenylgycines and derivatives thereof, 1,4-aminobenzoyl compounds, and phenyl pyrazolinones as cure accelerators for anaerobically curable compositions.

Abstract: The present invention relates to new cure accelerators for anaerobic curable compositions. These anaerobic cure accelerators are generally sulfonimide derivatives and sulfonamide derivatives.

Abstract: A method of modifying a polyethylene is disclosed. In the method ethylene or a mixture of ethylene and a C3-C10 ?-olefin is polymerized in an organic solvent with a Ziegler or single-site catalyst to form an initial polyethylene solution. The initial polyethylene solution is then reacted with a free radical initiator to produce a modified polyethylene. The modified polymer has an enhanced melt elasticity and increased long chain branching index, and is essentially free of gel.

Abstract: An acrylic composition includes the reaction product of an acrylic polymer, a carboxylic acid compound, and an alkyl carbamate. The acrylic polymer includes the reaction product of a functionalized monomer, a first compound reactive with the functionalized monomer to form a functionalized intermediate, and a highly branched, polyfunctional core molecule reactive with the functionalized intermediate. The first compound includes vinyl functionality reactive with the functionalized monomer and epoxy functionality. The carboxylic acid compound has carboxylic acid functionality that is reactive with the acrylic polymer. The alkyl carbamate is reactive with the hydroxyl-functional acrylic polymer to form the acrylic composition. The acrylic composition is highly-branched and, when used in coating compositions in combination with a suitable cross-linking agent, enhances recoat adhesion and produces cured films that have optimum scratch, mar, and chip performance, and acid etch resistance.

Abstract: This invention relates to a polymerizable composite material and method of making same including at least one multifunctional acid containing monomer having a concentration ranging from about 10% to about 85%, a non-reactive filler having a concentration ranging from about 1% to about 80%, a polymerization system having a concentration ranging from about 1.5% to about 15%, and water having a concentration ranging from about 0.1% to about 25%.

Abstract: Curable formulations comprising: (a) at least one multifunctional acrylate having a functionality of at least two, (b) at least one mono-acrylate monomer, (c) at least one heteroatom-containing diacrylate, wherein the heteroatom is sulfur or selenium; and (d) a curing agent, have been discovered. The curable formulations show promise as precursors to high refractive index materials suitable for use in light management devices and other optical devices. In addition the novel curable formulations are useful for producing coatings, which may be useful in forming display films, in particular brightness enhancing display films.

Abstract: Liquid rubbers that are ordinarily immiscible in liquid thermoset resins can be made miscible by the addition of at least one non-functional aromatic end-group to the polymer chains of such liquid rubber compositions. Such addition may be initiated by high-temperature peroxides in non-functional aromatic solvents. The liquid rubbers are found to improve the fracture toughness of cured thermoset resins while maintaining dimensional and heat resistance.

Abstract: A two-part self-curing endodontic sealing system comprises a thiourea derivative, such as acetyl thiourea, and a hydroperoxide, such as cumene hydroperoxide. The thiourea derivative is used as a reducing agent and the hydroperoxide is used as an oxidizing agent.

Abstract: An acrylic composition includes the reaction product of an acrylic polymer, a carbamate having anhydride-reactive functionality and carbamate functionality, and a carboxylic acid anhydride that is reactive with the carbamate to form a carboxylic acid carbamate. The acrylic polymer includes the reaction product of a functionalized monomer, a first compound reactive with the functionalized monomer to form a functionalized intermediate, and a highly branched, polyfunctional core molecule reactive with the functionalized intermediate. The first compound includes vinyl functionality reactive with the functionalized monomer and epoxy functionality. The carboxylic acid carbamate has the carbamate functionality and carboxylic acid functionality that is reactive with the acrylic polymer.

Abstract: An acrylic composition includes the reaction product of an acrylic polymer and carbon dioxide. The acrylic polymer includes the reaction product of a functionalized monomer, a first compound reactive with the functionalized monomer to form a functionalized intermediate, and a highly branched, polyfunctional core molecule reactive with the functionalized intermediate. The first compound includes vinyl functionality reactive with the functionalized monomer. The first compound also includes epoxy functionality. The carbon dioxide is reactive with the acrylic polymer to form a carbonate-functional acrylic polymer. The acrylic composition is highly-branched and, when used in coating compositions in combination with a suitable cross-linking agent, enhances recoat adhesion and produces cured films that have optimum scratch, mar, and chip performance, and acid etch resistance.

Abstract: The invention relates to an aqueous organic peroxide emulsion comprising an anti-freeze agent, a protective colloid, and a plasticiser wherein the plasticizer is an ester having a ratio of the number of carbon atoms present in the pasticiser molecule (excluding aromatic carbon atoms) to the number of ester groups in the molecule of higher than 8. These emulsions show a reduced droplet growth as compared to emulsions comprising a conventional plasticizer, i.e. the emulsions of the invention are more stable upon storage than the emulsions of the prior art. The invention emulsions are particularly useful in polymerization processes such as the polymerization of vinyl chloride monomer.

Abstract: An acrylic composition is formed by reacting a functionalized, chain-stopping monomer, a first compound, and a highly-branched, polyfunctional core molecule. The first compound includes vinyl functionality and at least one other functionality that is different from the vinyl functionality, such as epoxy functionality. The first compound, specifically the vinyl functionality of the first compound, reacts with the monomer to form a functionalized intermediate, and the core molecule reacts with this functionalized intermediate to form the acrylic composition.

Abstract: A method of homogeneously polymerizing styrene comprising admixing an ethylenically unsaturated monomer and an initiation system that is soluble in the monomer. This system includes a metal; a peroxide, hydroperoxide or mixture thereof; and a reductant. Under appropriate reaction conditions, the cyclic oxidation and reduction of the metal produces free radicals which initiate homogeneous polymerization of the ethylenically unsaturated monomer. The invention beneficially enables relatively low temperature processing with inexpensive initiation.

Abstract: An aqueous composition including a polymer having polymerized ethylenically unsaturated acid monomer is disclosed. The aqueous composition is prepared in the presence of select organic compounds. As provided is a process to prepare the aqueous composition. The aqueous composition is useful as a dispersant for inorganic particles, a thickener or rheology modifiers for various aqueous formulations, and as a dispersing resin.

Abstract: A process for producing organic peroxide initiators useful in the polymerization of ethylenically unsaturated monomers. The process for making the organic peroxides includes forming an aqueous emulsion of the organic peroxide. The organic peroxide is dispersed as small droplets of from 1 to 10 microns in size in the aqueous emulsion. The organic peroxide may be added to a polymerization reactor containing an ethylenically unsaturated monomer. The organic peroxide functions as a free radical initiator to polymerize the monomer. The organic peroxide may be substantially free of organic solvents and plasticizers. The resulting polymers are of high quality.

Abstract: It has been discovered that certain compounds serve as particle size regulators when employed together with peroxide initiators for the polymerization of vinylaromatic monomers in the presence of diene polymers. Suitable compounds that can control particle size include, but are not necessarily limited to, cobalt naphthenate, zinc naphthenate, iron octoate, calcium octoate, zinc octoate, zinc neodecanoate, potassium octoate, copper naphthenate, calcium versalate, and the like. Use of these metal carboxylates when vinylaromatic monomers are polymerized in the presence of polybutadienes and peroxide initiators results in reduced polybutadiene particles. Grafting and morphology characteristics may also be improved.

Abstract: This invention concerns an acrylate adhesive that cures at room temperature and has excellent dimensional stability. The adhesive may be used in applications such as for fiber optic connectors. The adhesive may be made by curing a two-part system or by use of a primer-based system. The two part system may include an adhesive part A, which may include one or more monofunctional, difunctional, or trifunctional acrylate or methacrylate monomers, a peroxide or hydroperoxide free-radical initiator, an antioxidant, and optionally, additives such as thickeners, thixotropes, and adhesion promoters; and an activator part B, which may contain a N,N-disubstituted aromatic amine, a difunctional methacrylate monomer, an antioxidant, and optionally, additives such as thickeners, thixotropes, and adhesion promoters.

Abstract: A method of free radical polymerization and for cleaving a thio group from the resulting polymer is provided. The method comprises forming a mixture of one or more monomers, at least one free radical source and a control agent, wherein the control agent comprises a thio moiety. The mixture is polymerized, and the resulting polymer is mixed with a free radical source, and optionally an addition fragmentation agent under cleavage conditions. The thio moiety on the polymer is replaced with a group of interest.

Abstract: A process for producing organic peroxide initiators useful in the polymerization of ethylenically unsaturated monomers. The process for making the organic peroxides includes forming an aqueous emulsion of the organic peroxide. The organic peroxide is dispersed as small droplets of from 1 to 10 microns in size in the aqueous emulsion. The organic peroxide may be added to a polymerization reactor containing an ethylenically unsaturated monomer. The organic peroxide functions as a free radical initiator to polymerize the monomer. The organic peroxide may be substantially free of organic solvents and plasticizers. The resulting polymers are of high quality.

Abstract: The present invention relates to new cure accelerators for anaerobic curable compositions. These anaerobic cure accelerators are generally sulfinimides and oxygen and sulfur derivatives thereof, sulfonimides and oxygen and sulfur derivatives thereof, sulfonamides and oxygen and sulfur derivatives thereof, and oxygen and sulfur analogues of sulfimides.

Abstract: A method of free radical polymerization and for cleaving a thio group from the resulting polymer is provided. The method comprises forming a mixture of one or more monomers, at least one free radical source and a chain transfer agent, wherein the chain transfer agent comprises a thio moiety. The mixture is polymerized, and the resulting polymer is mixed with a free radical source, and a monomer having little or no homopolymerizability under cleavage conditions. The thio moiety on the polymer is replaced with a group of interest.

Abstract: The present invention relates to phenyl glycines and derivatives thereof as cure accelerators for anaerobic curable compositions.

Abstract: Disclosed are compositions and processes for preparing polymeric materials having polymerizable units derived from at least one C8 to C30 alkyl (meth)acrylate monomer, and at least one chain branching unit. The presence of the chain branching unit suprisingly results in the polymeric composition having non-gelled polymer chains. The polymeric compositions are useful as additives for improving the melt strength of thermoplastic resins.

Abstract: A method for making hydrophilic homopolymers and copolymers of poly 2-hydroxyethyl methacrylate. Also disclosed are coatings, films, hydrogels, cosmetic compositions, dermatological compositions, pressure sensitive adhesives containing the hydrophilic homopolymers or copolymers of poly 2-hydroxyethylmethacrylate. Further disclosed are methods of coating substrates with the hydrophilic homopolymers and copolymers of poly 2-hydroxyethyl methacrylate and hydrophilic pressure sensitive adhesives.

Abstract: The present invention provides a new class of materials effective as cure accelerators for anaerobic curable compositions. The addition of these materials into anaerobic adhesives as a replacement for conventional curatives, such as acetyl phenyl hydrazine and maleic acid or toluidines, surprisingly provides at least comparable cure speeds and physcial properties for the reaction products formed therefrom.

Abstract: Anaerobic and heat curing polymerizable impregnation compositions for sealing pourous articles are disclosed. The compositions contain glycerol, oxygenated glycerol or (meth)acrylate glycerol to improve the washability of the compositions in aqueous solutions. The compositions may contain other compounds to effect the curing characteristics of the sealants.

Abstract: This invention relates to a polymerizable composite material and method of making at least one multifunctional acid containing monomer having a concentration ranging from about 10% to about 85%, a non-reactive filler having a concentration ranging from about 1% to about 80%, a polymerization system having a concentration ranging from about 1.5% to about 15%, and water having a concentration ranging from about 0.1% to about 25%.

Abstract: The invention discloses a process for the preparation of polymeric absorbents useful for gelling organic liquids. The process comprises mixing one or more monomers with a cross-linking agent, a free radical initiator, an optional solvent, optionally in the presence of a transition metal source and subjecting the mixture so obtained to a conventional polymerisation method. The polymer is removed, crushed to obtain polymer powder, washed with solvent and dried by conventional methods to remove unreacted monomers, followed by swelling in alcohols to obtain the desired product.