From Metal Containing Monomer Patents (Class 526/240)
  • Patent number: 8912298
    Abstract: An apparatus (2) includes: a first tank (4); a line mixer (6); a second tank (8); a cooling jacket (10); a first tube (12); a second tube (14); and a third tube (16). In the first tank (4), (i) sodium persulfate serving as a polymerization initiator and (ii) water are fed so as to obtained an aqueous solution. The aqueous solution is continuously taken out and transferred via the first tube (12) to the line mixer (6). Between the first tank (4) and the line mixer (6), water is injected into the first tube (12). The water and the sodium persulfate aqueous solution are stirred together in the line mixer (6). This stirring decreases a concentration of the aqueous solution. The resulting aqueous solution is continuously fed to the second tank (8) via the second tube (14). The aqueous solution is then continuously taken out via the third tube (16) and is continuously added to an acrylic acid (salt) aqueous solution.
    Type: Grant
    Filed: March 31, 2009
    Date of Patent: December 16, 2014
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Koji Matsumoto, Shuji Kanzaki
  • Publication number: 20140360585
    Abstract: An organic photoelectric conversion element composition including a p-type-and-n-type linked organic semiconductor polymer represented by any one of formulas (1) to (5), a thin film and a photovoltaic cell each containing the same, an organic semiconductor polymer and a compound each for use in these, and a method of producing the polymer: wherein, in formulas, A to A4 represent a group of a p-type organic semiconductor unit, and B to B3 represent a group of an n-type organic semiconductor unit; L1 to L4 represent a divalent or trivalent linking group; herein, in the formulas, at least one bonding hand represented by -* in the structures shown upperward and downward, and in the case of formula (4), L4 and (b), and L1 or L2 and (a), bond directly or through a divalent linking group; l, n, r, t, u and v represent an integer of 1 to 1,000; m and s represent an integer of 1 to 10; and p, q, l? and n? represent an integer of 0 to 1,000; in which p and q do not simultaneously represent 0.
    Type: Application
    Filed: August 18, 2014
    Publication date: December 11, 2014
    Applicant: FUJIFILM Corporation
    Inventors: Hiroki SUGIURA, Hiroshi YAMADA, Naoyuki HANAKI, Yoshihiro NAKAI, Kiyoshi TAKEUCHI
  • Publication number: 20140346407
    Abstract: The invention relates to novel conjugated polymers containing repeating units derived from carbonylsubstituted benzodithiophene and repeating units derived from halogenated benzotriazole, to methods for their preparation and educts or intermediates used therein, to polymer blends, mixtures and formulations containing them, to the use of the polymers, polymer blends, mixtures and formulations as organic semiconductors in organic electronic (OE) devices, especially in organic photovoltaic (OPV) devices and organic photodetectors (OPD), and to OE, OPV and OPD devices comprising these polymers, polymer blends, mixtures or formulations.
    Type: Application
    Filed: August 6, 2014
    Publication date: November 27, 2014
    Inventors: Paul BYRNE, Bram KARSTEN, David P. WALLER
  • Publication number: 20140338750
    Abstract: The present invention has an object to provide an organic photoelectric conversion element exhibiting excellent durability. The present invention is to provide an organic photoelectric conversion element comprising a conjugated polymer compound having a partial structure represented by the following Chemical Formula 1. wherein X independently represents O, S, NR2, or CR3?CR4; W independently represents CH or N; L independently represents a linear or branched alkylene group having 1 to 10 carbon atoms; Y1 and Y2 independently represent O or NR5; Z independently represents C, S, or P; R1 to R5 independently represent H, a linear or branched alkyl group having 1 to 24 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms, or a heteroaryl group having 1 to 20 carbon atoms; and a, b, and c independently represent an integer satisfying the relation: 3?a+b+c?4 and 0?a, b, c?2.
    Type: Application
    Filed: December 10, 2012
    Publication date: November 20, 2014
    Inventors: Takayuki Iijima, Yasushi Okubo, Takamune Hattori
  • Publication number: 20140339477
    Abstract: The invention relates to novel conjugated polymers containing repeating units comprising a halogenated benzene ring, a silolobithiophene moiety, and a benzofused heteroaromatic moiety, to methods for their preparation and educts or intermediates used therein, to polymer blends, mixtures and formulations containing them, to the use of the polymers, polymer blends, mixtures and formulations as organic semiconductors in organic electronic (OE) devices, especially in organic photovoltaic (OPV) devices and organic photodetectors (OPD), and to OE, OPV and OPD devices comprising these polymers, polymer blends, mixtures or formulations.
    Type: Application
    Filed: August 6, 2014
    Publication date: November 20, 2014
    Inventors: David P. Waller, Kap-Soo Cheon
  • Patent number: 8889755
    Abstract: Embodiments of the present invention include a branched aromatic ionomer, and a process of making it, by co-polymerizing a first monomer comprising an aromatic moiety and an unsaturated alkyl moiety and a second monomer represented by the general formula: [R-AZ]y-MX wherein R is a hydrocarbon chain having from 2 to 40 carbons and at least one polymerizable unsaturation; A is an anionic group; M is a cationic group; Z is ?1 or ?2; X is +1, +2, +3, +4, or +5; and y is an integer having a value of from 1 to 4. The branched aromatic ionomer has a melt flow index ranging from 1.0 g/10 min. to 13 g/10 min. Optionally the melt flow index ranges from 1.3 g/10 min. to 1.9 g/10 min.
    Type: Grant
    Filed: December 11, 2013
    Date of Patent: November 18, 2014
    Assignee: Fina Technology, Inc.
    Inventors: John Gaustad, Juan Aguirre, Joe Shuler
  • Publication number: 20140336344
    Abstract: A method for making a polystyrene ionomer comprises: preparing a metallic comonomer within styrene monomer to form a reaction mixture; and placing the reaction mixture under conditions suitable for the formation of a polymer composition. The metallic comonomer can be a metal acrylate, formed by contacting a metal complex and an acrylate precursor.
    Type: Application
    Filed: July 21, 2014
    Publication date: November 13, 2014
    Inventors: Steven D. Gray, Scott Cooper, Jason Clark
  • Patent number: 8883954
    Abstract: A photovoltaic cell is provided that includes a first electrode, a second electrode, and a photoactive layer disposed between the first and second electrodes. The photoactive layer includes a photoactive polymer containing a first monomer repeat unit, which contains a moiety of formula (1): in which A and R are defined in the specification.
    Type: Grant
    Filed: October 9, 2013
    Date of Patent: November 11, 2014
    Assignee: Merck Patent GmbH
    Inventors: Paul Byrne, Li Wen, David P. Waller, Taizoon Canteenwala, Patrick Foyle, Edward Jackson
  • Patent number: 8883961
    Abstract: The invention relates to a process for producing water-absorbing polymer particles, comprising thermal postcrosslinking in a contact dryer having external heated outer surfaces.
    Type: Grant
    Filed: August 26, 2013
    Date of Patent: November 11, 2014
    Assignee: BASF SE
    Inventors: Monte Peterson, Filip Mees, John Perry Guentzel, Justin Martin, Dominicus van Esbroeck, Karl J. Possemiers, Leo Van Miert, Oskar Stephan, Rüdiger Funk, Matthias Weismantel
  • Patent number: 8883946
    Abstract: Here is provided a charge control resin which is prompt in charge rising up, excellent in electrostatic charging propensity and easy in manufacturing. This charge control resin contains a polymer as an active ingredient having a constituent unit represented by following Formula (1) in the Formula (1), R1 is independent of one another, and is a hydrogen atom, a hydroxyl group, a halogen atom, a carboxy-containing group, a straight-chained or branched alkyl group having 1-18 carbon atoms, or a straight-chained or branched alkoxy group having 1-18 carbon atoms; R2 is a hydrogen atom, a hydroxyl group, a halogen atom, a carboxy-containing group, a straight-chained or branched alkyl group having 1-18 carbon atoms, or a straight-chained or branched alkoxy group having 1-18 carbon atoms; g is a number of 1-3; h is a number of 1-3; and M is a hydrogen atom, an alkali metal, a straight-chained or branched alkyl group having 1-18 carbon atoms, an ammonium radical or a mixture of any of these.
    Type: Grant
    Filed: May 17, 2012
    Date of Patent: November 11, 2014
    Assignee: Orient Chemical Industries Co., Ltd.
    Inventors: Masashi Yasumatsu, Kaori Inoue, Satoko Ozaki
  • Publication number: 20140329929
    Abstract: The invention relates to a dental restorative material which comprises a thermolabile or photolabile polymerizable compound of Formula I: [(Z1)m-Q1-X)]k-T-[Y-Q2-(Z2)n]1??Formula I, in which T represents a thermolabile or photolabile group, Z1 and Z2 in each case independently represent a polymerizable group selected from vinyl groups, CH2?CR1—CO—O— and CH2?CR1—CO—NR2— or an adhesive group selected from —Si(OR)3, —COOH, —O—PO(OH)2, —PO(OH)2, —SO2OH and —SH, wherein at least one Z1 or Z2 is a polymerizable group, Q1 in each case independently is missing or represents an (m+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, Q2 in each case independently is missing or represents an (n+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, X and Y in each case independently are missing
    Type: Application
    Filed: September 10, 2012
    Publication date: November 6, 2014
    Applicant: IVOCLAR VIVADENT AG
    Inventors: Norbert Moszner, Iris Lamparth, Thorsten Bock, Urs Karl Fischer, Ulrich Salz, Volker Rheinberger, Robert Liska
  • Patent number: 8871880
    Abstract: The invention relates to a superabsorbent copolymer comprising a reaction product of a reactive optical brightener comonomer. In another embodiment, the superabsorbent copolymer comprises a reaction product of a first monomer and a reactive optical brightener comonomer. The reactive optical brightener comonomer may be selected from various pyrene optical brighteners listed herein. The invention also relates to superabsorbent copolymer having from about 0.1 to 10,000 ppm of a reactive optical brightener comonomer based on the superabsorbent copolymer.
    Type: Grant
    Filed: March 22, 2012
    Date of Patent: October 28, 2014
    Assignee: Evonik Corporation
    Inventors: Matthias Naumann, James S. Wooten, IV
  • Publication number: 20140309386
    Abstract: A method for preparing particles includes a material capable of catalyzing the reduction of oxygen or the oxidation of hydrogen, the particles being functionalized by polymers including at least one repeating unit bearing at least one proton-conducting group, and the particles being covalently bonded to a carbon material. The method includes the following consecutive steps: a) a step of contacting particles, comprising a material capable of catalyzing the reduction of oxygen or the oxidation of hydrogen, with a compound that is an initiator for ATRP polymerization, the compound comprising at least one group capable of being grafted onto the surface of the particles, whereby particles, onto which a radical of the initiator compound is grafted, are obtained; and b) a step of contacting the particles obtained in a) with at least one monomer having at least one proton-conducting group, whereby the polymerization of the monomer from the above-mentioned radicals occurs.
    Type: Application
    Filed: November 5, 2012
    Publication date: October 16, 2014
    Inventors: Pierrick Buvat, Anne-Claire Ferrandez, Steve Baranton, Christophe Coutanceau
  • Patent number: 8859702
    Abstract: The present invention has an object to provide a polymer-containing composition for dispersants for cement which exhibits higher cement dispersibility even when used in a small amount, and can provide high flowability to a cement composition such as mortar and concrete and stably maintain this high flowability for a certain period, and to provide a production method thereof. The polymer-containing composition for dispersants for cement includes a polymer including a repeating unit derived from an unsaturated polyalkylene glycol ether monomer (I) having a specific structure and a repeating unit derived from an unsaturated carboxylic acid monomer (II) having a specific structure, and is prepared by polymerizing an unsaturated polyalkylene glycol ether monomer (I)-containing composition that includes specific amounts of specific components.
    Type: Grant
    Filed: August 10, 2010
    Date of Patent: October 14, 2014
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Hirokatsu Kawakami, Naohiko Itayama
  • Patent number: 8853286
    Abstract: The present invention is directed to compositions useful for use in separators for use in lithium ion batteries, and membranes, separators, and devices derived therefrom.
    Type: Grant
    Filed: September 12, 2013
    Date of Patent: October 7, 2014
    Assignees: Drexel University, The Trustees Of The University Of Pennsylvania
    Inventors: Yossef A. Elabd, Karen I. Winey, Yuesheng Ye, Jae-Hong Choi, Tsen-Shan Sharon Sharick
  • Publication number: 20140275459
    Abstract: The present invention relates to conjugated polymers. In various embodiments, the present invention provides a conjugated polymer including a repeating unit including a benzene ring conjugated with the polymer backbone, wherein the benzene ring is fused to two 5-membered rings, wherein each fused 5-membered ring includes N and at least one of O and S. In various embodiments, the present invention provides semiconductor devices including the polymer, and methods of making the polymer.
    Type: Application
    Filed: March 12, 2014
    Publication date: September 18, 2014
    Applicant: Iowa State University Research Foundation, Inc.
    Inventors: Malika Jeffries-EL, Jeremy J. Intemann, Brian C. Tlach
  • Publication number: 20140252279
    Abstract: The invention relates to novel organic semiconducting compounds containing one or more dithieno[2,3-b:7,8-b?]-s-indaceno[1,2-b:5,6-b?]dithiophene (IDTT) units that are functionalised at the 6,12-positions with electron withdrawing groups and are optionally substituted at the 3,9-positions with solubilising groups, to methods for their preparation and educts or intermediates used therein, to polymers, blends, mixtures and formulations containing them, to the use of the compounds, polymers, polymer blends, mixtures and formulations as semiconductors in organic electronic (OE) devices, especially in organic photovoltaic (OPV) devices and organic photodetectors (OPD), and to OE, OPV and OPD devices comprising these compounds, polymers, polymer blends, mixtures or formulations.
    Type: Application
    Filed: September 24, 2012
    Publication date: September 11, 2014
    Applicant: MERCK PATENT GMBH
    Inventors: Changsheng Wang, Steven Tierney, Mansoor D'Lavari, Lana Nanson
  • Patent number: 8829114
    Abstract: A method for making a polystyrene ionomer comprises: preparing a metallic comonomer within styrene monomer to form a reaction mixture; and placing the reaction mixture under conditions suitable for the formation of a polymer composition. The metallic comonomer can be a metal acrylate, formed by contacting a metal complex and an acrylate precursor.
    Type: Grant
    Filed: November 29, 2011
    Date of Patent: September 9, 2014
    Assignee: Fina Technology, Inc.
    Inventors: Steven D. Gray, Scott Cooper, Jason Clark
  • Patent number: 8829129
    Abstract: The present disclosure relates to compositions comprising a copolymer that includes a first monomer and a second monomer that is different from the first monomer, wherein both the first and second monomer are selected from the group consisting of 3-sulfopropyl acrylate potassium salt, sodium acrylate, N-(tris(hydroxyl methyl)methyl)acrylamide, and 2-acrylamideo-2-methyl-1-propane sulfonic acid. The present disclosure further relates to methods for preparing the copolymer compositions and shaped articles comprising the copolymers.
    Type: Grant
    Filed: November 21, 2011
    Date of Patent: September 9, 2014
    Assignee: Covidien LP
    Inventors: Ahmad R. Hadba, Brian Cuevas, Frank R. Schiretz, Joshua Stopek
  • Patent number: 8822713
    Abstract: Coordination complexes of at least one metal element with at least one aromatic monomer are provided. The at least one aromatic monomer may comprise at least one aromatic ring, which ring comprising at least one ethylenic group, at least one hydroxide group —OH, at least one oxime group and salts thereof. The metal element may be in the form of a metal alkoxide.
    Type: Grant
    Filed: November 17, 2010
    Date of Patent: September 2, 2014
    Assignee: Comissariat a l'Energie Atomique et aux Energies Alternatives
    Inventors: Alexia Balland Longeau, Stéphane Cadra, Jérôme Thibonnet
  • Publication number: 20140243480
    Abstract: An anionic polymerization initiator of formula: in which: Met, which can be borne by the ortho, meta or para position, denotes an alkali metal, R1 and R2, and also R3 and R4, which can be borne by the ortho, meta or para position, denote a hydrogen atom or an alkyl, cycloalkyl, aryl or arylalkyl group, and R5 denotes an alkyl, cycloalkyl, aryl or arylalkyl group or a protective group for the alkyne functional group. The use of such a polymerization initiator makes possible the synthesis of a diene elastomer bearing, at one or each of its chain ends, a group comprising an alkyne functional group with a high degree of functionalization.
    Type: Application
    Filed: October 16, 2012
    Publication date: August 28, 2014
    Applicant: Compagnie Generale des Etablissements Michelin
    Inventors: Rachid Matmour, Nicolas Seeboth
  • Publication number: 20140239284
    Abstract: By using a polymer compound comprising a constituent unit represented by the formula (1) and a constituent unit represented by the formula (2) in an organic layer of an organic photoelectric conversion device, photoelectric conversion efficiency can be enhanced: wherein R1 represents a hydrogen atom; or a substituent; Y1 represents an oxygen atom, a sulfur atom or —N(R3)—; R3 represents a hydrogen atom or a substituent; ring Z1 and ring Z2 represent each independently an optionally substituted aromatic carbocyclic ring or an optionally substituted heterocyclic ring; wherein R2 is different from R1 and represents a hydrogen atom or a substituent; Y2 represents an oxygen atom, a sulfur atom or —N(R3)—; R3 represents a hydrogen atom or a substituent; ring Z3 and ring Z4 represent each independently an optionally substituted aromatic carbocyclic ring or an optionally substituted heterocyclic ring.
    Type: Application
    Filed: September 28, 2012
    Publication date: August 28, 2014
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Ken Yoshimura, Kenichiro Ohya, Takehito Kato
  • Publication number: 20140243488
    Abstract: The invention addresses a problem of obtaining a conjugated polymer having a higher molecular weight through coupling reaction of monomers using a transition metal catalyst. The invention relates to a method for producing a conjugated polymer, which comprises polymerizing one or more monomers through a coupling reaction, wherein the coupling reaction of the monomer is carried out by using one or more kinds of homogeneous transition metal complex catalysts and one or more kinds of heterogeneous transition metal complex catalysts in combination.
    Type: Application
    Filed: May 2, 2014
    Publication date: August 28, 2014
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Wataru SATO, Rieko Fujita, Jyunya Kawai, Kenichi Satake, Mitsunori Furuya
  • Publication number: 20140243492
    Abstract: The invention addresses a problem of purifying a monomer to be a precursor according to a simpler and milder method so as to obtain a polymer having a higher molecular weight. The invention relates to a method for producing a condensed polycyclic aromatic compound having n active groups (wherein n is an integer of 1 or more and 4 or less), which comprises bringing a composition containing the condensed polycyclic aromatic compound and a solvent into contact with zeolite.
    Type: Application
    Filed: May 2, 2014
    Publication date: August 28, 2014
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Rieko FUJITA, Jyunya Kawai, Wataru Sato, Kenichi Satake, Mitsunori Furuya
  • Publication number: 20140231784
    Abstract: A polymer comprises a polymeric chain represented by formula (I) or (II). In formula (I) a, b, d, and n are integers, a from 0 to 3, b from 1 to 5, c from 1 to 3, d from 1 to 5, and n from 2 to 5000; R1 and R2 are side chains; R3 and R4 are each independently H or a side chain; and when a is 0, R3 and R4 are side chains. In formula (II), a, b, c, d, e, and n are integers, a from 1 to 3, b and c being independently 0 or 1, d and e being independently 1 or 2, and n from 2 to 5000; R1 and R2 are side chains except —COOalkyl; and X1, X2 and X3 are independently O, S, or Se. Semiconductors and devices comprising the polymer are also provided.
    Type: Application
    Filed: April 28, 2014
    Publication date: August 21, 2014
    Applicant: Agency for Science, Technology and Research
    Inventors: Zhikuan CHEN, Jun LI, Beng ONG, Samarendra P. SINGH, Hoi Kai Ivy WONG, Kok Haw ONG
  • Publication number: 20140209839
    Abstract: The invention relates to novel polymers containing one or more 4,8-dioxycarbonylalkyl-benzo[1,2-b:4,5-b?]dithiophene repeating units or their thioester derivatives, methods for their preparation and monomers used therein, blends, mixtures and formulations containing them, the use of the polymers, blends, mixtures and formulations as semiconductor in organic electronic (OE) devices, especially in organic photovoltaic (OPV) devices, and to OE and OPV devices comprising these polymers, blends, mixtures or formulations.
    Type: Application
    Filed: August 29, 2012
    Publication date: July 31, 2014
    Applicant: MERCK PATENT GMBH
    Inventors: William Mitchell, Nicolas Blouin, Amy Phillips, Steven Tierney, Miguel Carrasco-Orozco, Toby Cull
  • Publication number: 20140213749
    Abstract: Low molecular weight polymers useful in aggregating mineral components in aqueous mineral slurries to release and separate individual components of the slurry, which may then be recovered from the slurry.
    Type: Application
    Filed: March 31, 2014
    Publication date: July 31, 2014
    Applicant: SORTWELL & CO.
    Inventor: Edwin T. Sortwell
  • Publication number: 20140206791
    Abstract: Provided are a dispersion of a nanoparticulate mixed oxide of SiO2 with at least one further metal oxide in a matrix monomer, methods for preparing such a dispersion, a dental composite producible by curing such a dispersion, and uses of the dispersion as a precursor for dental composites.
    Type: Application
    Filed: January 17, 2014
    Publication date: July 24, 2014
    Applicant: Schott AG
    Inventors: Joerg Schuhmacher, Jochen Herrmann, Hans-Joachim Schmitt, Bastian Schoen, Jens Suffner
  • Publication number: 20140196787
    Abstract: An organic photovoltaic cell, containing a first electrode; a second electrode; and a photoelectric conversion layer between the first electrode and the second electrode, wherein the photoelectric conversion layer contains a polymer having a structural unit represented by formula (I): wherein X represents S, NR2, O, Se or Te; Y represents NR2, O, Te, SO, SO2 or CO; and R1 and R2 represent a hydrogen atom or a substituent.
    Type: Application
    Filed: March 27, 2014
    Publication date: July 17, 2014
    Applicant: FUJIFILM Corporation
    Inventors: Naoyuki HANAKI, Yoshihiro NAKAI, Kiyoshi TAKEUCHI, Hiroki SUGIURA
  • Publication number: 20140187716
    Abstract: Processes for the continuous production of conjugated polymers are disclosed. The processes provide excellent control over reaction parameters and are highly reproducible. The conjugated polymers find use in heterojunction devices.
    Type: Application
    Filed: July 13, 2012
    Publication date: July 3, 2014
    Applicant: The University of Melbourne
    Inventors: David John Jones, Wing Ho Wallace Wong, Andrew Bruce Holmes, Helga Seyler
  • Patent number: 8759413
    Abstract: A process for the preparation of lanthanum containing polyacrylates for optical applications. The process consists in dispersing lanthanum oxide in acrylic acid to form a monomer mixture. An aromatic carboxylic acid is added to the monomer mixture and then a cross linking agent is added thereto. Such a monomer mixture is subjected to the step of polymerization by gamma radiation.
    Type: Grant
    Filed: March 9, 2007
    Date of Patent: June 24, 2014
    Assignee: Shriram Institute for Industrial Research
    Inventors: Rakesh Kumar Khandal, Amita Malik, Geetha Seshadri, Mukti Tyagi
  • Publication number: 20140169879
    Abstract: This invention is in the field of road construction as it relates to improving the quality and lifetime of asphalt roads and pavement surfaces. The invention relates to methods and compositions utilizing co-polymers in combination with soil to form improved subgrade soil binder compositions for supporting asphalt roads and pavement surfaces.
    Type: Application
    Filed: December 10, 2013
    Publication date: June 19, 2014
    Applicant: The Texas A&M University System
    Inventors: Howard J.M. Hanley, Eyad A. Masad, Srinath R. Iyengar, Ana K. Rodriguez, Hassan S. Bazi
  • Publication number: 20140163188
    Abstract: Provided is an organic semiconductor material with good crystallinity and an excellent carrier mobility. The organic semiconductor material comprises a backbone represented by formula 1. In formula 1, R1 is hydrogen, an alkyl group, an alkylcarbonyl group, an alkoxy group, or an alkoxycarbonyl group, m is an integer of 1 or more, Ar is a monocyclic or condensed polycyclic heteroaromatic ring optionally comprising a substituent, and when a plurality of heteroaromatic rings are linked, the same or different heteroaromatic rings are optionally linked.
    Type: Application
    Filed: July 25, 2012
    Publication date: June 12, 2014
    Applicant: National University of Corporation Hiroshima Unive
    Inventors: Itaru Osaka, Kazuo Takimiya
  • Publication number: 20140154616
    Abstract: Disclosed is a coloring composition with satisfactory heat resistance, no discoloration, excellent developability, and no development residues on a substrate and pixels of other colors, providing, a coloring composition for a color filter including (A) a polymer having a dye skeleton and (B) an organic solvent, wherein the content of an unreacted monomer component having the dye skeleton which is capable of forming (A) the polymer having the dye skeleton is less than or equal to 1 mass % with regard to (A) the polymer having the dye skeleton.
    Type: Application
    Filed: February 10, 2014
    Publication date: June 5, 2014
    Applicant: FUJIFILM Corporation
    Inventors: Yuzo NAGATA, Hiroaki IDEI, Atsuyasu NOZAKI, Kenta USHIJIMA, Yushi KANEKO, Yousuke MURAKAMI
  • Publication number: 20140110689
    Abstract: A semi-fluoroalkyl group substituted organic semiconductor polymer and an organic thin film transistor including the same are disclosed. A structure in which hydrogen of only a terminal of an alkyl group is substituted with fluorine exhibits significantly increased hole mobility, and significantly improved properties in terms of thermal stability and chemical stability, as compared to a structure in which all hydrogens coupled to a thiophene ring are substituted with fluorine, or a structure in which hydrogen of the terminal thereof is not substituted with fluorine and only hydrogens of the remaining portion are coupled to the thiophene ring.
    Type: Application
    Filed: October 18, 2013
    Publication date: April 24, 2014
    Applicant: GWANGJU INSTITUTE OF SCIENCE AND TECHNOLOGY
    Inventors: Dong-Yu KIM, Hyung-Gu JEONG, Bogyu LIM
  • Patent number: 8703298
    Abstract: The gas-barrier film of the present invention basically comprises a polymer of a polyvalent metal salt of an unsaturated carboxylic acid compound which gives an infrared absorption spectrum in which the ratio of the absorbance A0 at around 1,700 cm?1 attributable to V C?O of the carboxylic acid group to the absorbance A at around 1,520 cm?1 attributable to V C?O of the carboxylate ion, A0/A, is lower than 0.25, and this gas-barrier film and a gas-barrier layered body having the film can be manufactured by applying a solution of a polyvalent metal salt of an unsaturated carboxylic acid compound having a degree of polymerization lower than 20 to at least one side of a substrate layer and then polymerizing the polyvalent metal salt of the unsaturated carboxylic acid compound.
    Type: Grant
    Filed: May 10, 2005
    Date of Patent: April 22, 2014
    Assignee: Tohcello Co., Ltd.
    Inventors: Osamu Nakamura, Tomoyoshi Hakamata, Akira Nomoto
  • Publication number: 20140106218
    Abstract: A polymer includes a first repeating unit having a cationic group and a second repeating unit having an anionic group. The polymer may further include a third repeating unit having a non-ionic group. The polymer may include first and second polymers, each of which includes a first repeating having a cationic group and a second repeating unit having an anionic group. The cationic group of the first polymer may form an intermolecular bond with the anionic group of the second polymer, and the anionic group of the first polymer may form an intermolecular bond with the cationic group of the second polymer. An electrode for a lithium secondary battery includes the polymer, and a lithium secondary battery employs the electrode.
    Type: Application
    Filed: September 25, 2013
    Publication date: April 17, 2014
    Applicant: SAMSUNG SDI CO., LTD.
    Inventors: Beom-Wook Lee, Bum-Jin Chang, Hye-Sun Jeong, Sam-Jin Park, Kwan-Ku Lee
  • Patent number: 8697824
    Abstract: The present invention is concerned with novel ion-exchange membranes, their method of preparation and their uses. The membranes are made of a polymer obtained from a monomer or a mixture of bifunctional monomers of general formula [T-SO2—Y—SO2-T?]?M+. The polymers are useful in an alkali-chloride electrolysis process, as a separator in an electrochemical preparation of inorganic and organic compounds, as a separator between an aqueous and an organic phase, or as a catalyst for Diels-Alder additions, Friedel-Craft reactions, aldol condensations, cationic polymerizations, esterifications, and acetal formations.
    Type: Grant
    Filed: June 26, 2008
    Date of Patent: April 15, 2014
    Assignee: Hydro Quebec
    Inventors: Christophe Michot, Michel Armand
  • Publication number: 20140080986
    Abstract: A method of regioselectively preparing a pyridine-containing compound is provided. In particular embodiments, the method includes reacting halogen-functionalized pyridal[2,1,3]thiadiazole with organotin-functionalized cyclopenta[2,1-b:3,4-b?]dithiophene or organotin-functionalized indaceno[2,1-b:3,4-b?]dithiophene. Also provided is a method of preparing a polymer. The method includes regioselectively preparing a monomer that includes a pyridal[2,1,3]thiadiazole unit; and reacting the monomer to produce a polymer that includes a regioregular conjugated backbone section, wherein the section includes a repeat unit containing the pyridal[2,1,3]thiadiazole unit. A polymer that includes a regioregular conjugated backbone section, and electronic devices that include the polymer, are also provided.
    Type: Application
    Filed: November 22, 2013
    Publication date: March 20, 2014
    Applicant: The Regents of the University of California
    Inventors: Guillermo C. Bazan, Lei Ying, Ben B.Y. Hsu, Wen Wen, Hsin-Rong Tseng, Gregory C. Welch
  • Publication number: 20140073754
    Abstract: An organic semiconductor compound may be represented by the above Chemical Formula 1 or Chemical Formula 2, and an organic thin film may include the organic semiconductor compound according to Chemical Formula 1 or 2.
    Type: Application
    Filed: November 12, 2013
    Publication date: March 13, 2014
    Applicant: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Bang Lin LEE, Jeong Il PARK, Jong Won CHUNG
  • Publication number: 20140066582
    Abstract: The invention relates to a process for producing water-absorbing polymer particles, comprising thermal postcrosslinking in a contact dryer having external heated outer surfaces.
    Type: Application
    Filed: August 26, 2013
    Publication date: March 6, 2014
    Inventors: Monte Peterson, Filip Mees, John Perry Guentzel, Justin Martin, Dominicus van Esbroeck, Karl J. Possemiers, Leo Van Miert, Oskar Stephen, Rüdiger Funk, Mathhias Welsmantel
  • Publication number: 20140057293
    Abstract: Conjugates of 1,3-bis(1,4,7-triazacyclonon-1-yl)-2-hydroxypropanes with a variety of conjugating members are used in the formation of dinuclear metal complexes which bind to phosphate esters. By virtue of their conjugated forms, the complexes are incorporated into chromatographic media, affinity binding reagents, and dyes, which make the complexes useful in a wide range of assays, separations, and purifications. In addition, dinuclear metal complexes of 1,3-bis(1,4,7-triazacyclonon-1-yl)-2-hydroxypropanes that are not so conjugated are used in the detection of phosphate esters of biological species by either MALDI-TOF mass spectrometry or by dye displacement.
    Type: Application
    Filed: August 22, 2013
    Publication date: February 27, 2014
    Applicant: Bio-Rad Laboratories, Inc.
    Inventors: Thomas R. Berkelman, Lisandra Martin, Rhiannon Jones, John Walker, II
  • Publication number: 20140053905
    Abstract: This disclosure relates to a photovoltaic cell that includes a first electrode, a second electrode, and a photoactive layer disposed between the first and second electrodes. The photoactive layer includes a photoactive polymer containing a first monomer repeat unit, which contains a moiety of formula (1): in which A and R are defined in the specification.
    Type: Application
    Filed: October 9, 2013
    Publication date: February 27, 2014
    Applicant: Merck Patent GmbH
    Inventors: Paul Byrne, Li Wen, David P. Waller, Taizoon Canteenwala, Patrick Foyle, Edward Jackson
  • Patent number: 8653212
    Abstract: Embodiments of the present invention include a branched aromatic ionomer, and a process of making it, by co-polymerizing a first monomer comprising an aromatic moiety and an unsaturated alkyl moiety and a second monomer represented by the general formula: [R-AZ]y-MX wherein R is a hydrocarbon chain having from 2 to 40 carbons and at least one polymerizable unsaturation; A is an anionic group; M is a cationic group; Z is ?1 or ?2; X is +1, +2, +3, +4, or +5; and y is an integer having a value of from 1 to 4. The branched aromatic ionomer has a melt flow index ranging from 1.0 g/10 min. to 13 g/10 min. Optionally the melt flow index ranges from 1.3 g/10 min. to 1.9 g/10 min.
    Type: Grant
    Filed: August 12, 2013
    Date of Patent: February 18, 2014
    Assignee: Fina Technology, Inc.
    Inventors: John Gaustad, Juan Aguirre, Joe Shuler
  • Publication number: 20140042371
    Abstract: The invention relates to novel polymers containing one or more repeating units based on 4,8-bis(1,1-difluoralkyl)-benzo[1,2-b:4,5-b?]dithiophene or derivatives thereof, methods for their preparation and monomers used therein, blends, mixtures and formulations containing them, the use of the polymers, blends, mixtures and formulations as semiconductor in organic electronic (OE) devices, especially in organic photovoltaic (OPV) devices, and to OE and OPV devices comprising these polymers, blends, mixtures or formulations.
    Type: Application
    Filed: March 23, 2012
    Publication date: February 13, 2014
    Applicant: MERCK PATENT GMBH
    Inventors: Nicolas Blouin, William Mitchell, Amy Topley, Steven Tierney
  • Patent number: 8648157
    Abstract: The present invention relates to metal-containing compositions comprising a metal-containing precursor unit (MU), a prepolymer unit (PU), and a catalyst or an initiator capable of inducing a combining reaction of ethylenically unsaturated groups of the metal-containing precursor unit and the prepolymer unit. In another embodiment, the composition comprises MU and a catalyst or initiator capable of inducing a combining reaction of the metal-containing precursor units. Both MU and PU contain additional functional groups, which may be selected to impart compatibility with each other and to produce optically clear films. The metal-containing compositions can be used to produce films or articles having a transmittance of at least 90% and index of refraction in the range of 1.4 to 1.8 in the 400-700 nm range of light and 1.4 to 2.4 in the 150-400 nm range of light.
    Type: Grant
    Filed: December 28, 2010
    Date of Patent: February 11, 2014
    Assignee: Pryog, LLC
    Inventor: Joseph J. Schwab
  • Publication number: 20140020762
    Abstract: An organic semiconductor polymer having a structural unit represented by the following Formula (I), a composition for organic semiconductor material, a photovoltaic cell and a polymer. wherein X represents Si, S or O; R1 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an aryl group, an aromatic heterocyclic group or an oxygen atom; p represents 0, 1 or 2; herein, the bond between X and R1 is such that when X is Si, the bond is a single bond, and when X is S, the bond is a double bond. Furthermore, when X is O, p represents 0.
    Type: Application
    Filed: September 24, 2013
    Publication date: January 23, 2014
    Applicant: FUJIFILM Corporation
    Inventors: Yoshihiro NAKAI, Hiroki SUGIURA, Naoyuki HANAKI, Kiyoshi TAKEUCHI
  • Publication number: 20140023607
    Abstract: The present disclosure relates to novel ethylenic copolymers comprising from 10% to 80% by weight, of at least one monomer of polyethylene glycol (meth)acrylate type, from 20% to 90% by weight, of at least one anionic monomer, and from 0% to 70% by weight, at least one additional nonionic hydrophilic monomer. The disclosure also relates to a composition, such as cosmetic or pharmaceutical compositions, comprising the copolymers and to a method of using the same.
    Type: Application
    Filed: September 27, 2013
    Publication date: January 23, 2014
    Applicant: L'OREAL
    Inventors: Nathalie Mougin, Gwenaelle Jegou
  • Publication number: 20140001411
    Abstract: The invention relates to novel polymers containing one or more pyrrolo[3,2-b]pyrrole-2,5-dione repeating units, methods for their preparation and monomers used therein, blends, mixtures and formulations containing them, the use of the polymers, blends, mixtures and formulations as semiconductor in organic electronic (OE) devices, especially in organic photovoltaic (OPV) devices, and to OE and OPV devices comprising these polymers, blends, mixtures or formulations.
    Type: Application
    Filed: February 15, 2012
    Publication date: January 2, 2014
    Applicant: MERCK PATENT GMBH
    Inventors: Nicolas Blouin, William Mitchell, Amy Topley, Steven Tierney
  • Publication number: 20140000716
    Abstract: A photoelectric conversion element has a structure where a hole transport layer, a photoelectric conversion layer, and an electron transport layer are held between a first electrode and a second electrode. The photoelectric conversion layer is a bulk heterojunction layer, and fullerene or a fullerene derivative is used as an n-type organic semiconductor. As a p-type organic semiconductor, a polymer represented by the following Expression is used. In the Expression, R1, R2, R3, and R4 each independently represent any one of a branched alkyl group, a linear alkyl group, an alkyl ester group, a carboxy alkyl group, and an alkoxy group. Independently, X is any one of S, O, and N.
    Type: Application
    Filed: September 3, 2013
    Publication date: January 2, 2014
    Applicants: National University Corporation of Hiroshima University, JX Nippon Oil & Energy Corporation
    Inventors: Seunghun EU, Tsuyoshi Asano, Itaru Osaka, Kazuo Takimiya