Abstract: Process for the production of 2-dimethylaminoethyl (meth)acrylate in multiple stage batch reactions involving the recycling of the catalyst (DBTO) in subsequent reaction, the addition a certain amount of fresh catalyst to the recycled catalyst, the use of said catalysts in the subsequent reaction, and wherein the volume decrease due to azeotropic distillation is compensate in order to keep the volume constant in the reactor during the reaction by the continuous addition of a composition comprising methyl(meth)acrylate and dimethylaminoethanol.

Abstract: Provided is a contact lens that can exhibit excellent breaking elongation and surface hydrophilicity even when produced using a hydrophobic mold made of polypropylene or the like without performing a surface hydrophilic treatment. Further provided are a monomer composition and a polymer that can be suitably used for obtaining the contact lens. This monomer composition contains (A) a siloxanyl group-containing itaconic acid diester monomer, (B) an amide group-containing monomer, (C) a hydroxy group-containing monomer, (D) a siloxanyl group-containing (meth)acrylate, and (E) a cross-linking agent in a specific ratio.

Abstract: [Object] To provide a negative type photosensitive siloxane composition capable of forming a cured film excellent in heat resistance and critical thickness for cracking [Means] The present invention provides a negative type photosensitive siloxane composition comprising: a polysiloxane containing silanol in a specific content, a particular photo base generator, and a solvent. The content of silanol is measured by FT-IR.

Abstract: A triazine ring-containing polymer including a structural unit represented by General Formula 1: *-[A-B-]-*??General Formula 1 wherein, in General Formula 1, A is represented by General Formula 2, B is represented by General Formula 3, and * indicates a point linked to another group or structural unit: wherein, in General Formula 2 and General Formula 3, L, R1 to R6, m1, n1, and * are the same as defined in the detailed description.

Abstract: The present invention relates to novel chemical solutions suitable for forming polymer brushes on a surface of a solid part. The present invention further relates to methods of forming polymer brushes on the surface of a solid part using the novel chemical solutions as well as solid parts having polymer brushes coated onto the surface and uses of such solid parts.

Abstract: The present invention provides a spectacle lens having low surface resistivity. This spectacle lens includes a spectacle lens base and a hard coat layer. When a primer layer is included between the spectacle lens base material and the hard coat layer, the primer layer and/or the hard coat layer contains at least one type of electroconductive filler selected from the group consisting of ionic liquid-coated nanowires containing metal nanowires and an ionic liquid coating the metal nanowire, and ionic liquid-coated nanoparticles containing metal nanoparticles and an ionic liquid coating the metal nanoparticles. When the primer layer is not included between the spectacle lens base material and the hard coat layer, the hard coat layer contains the at least one type of electroconductive filler selected from the group consisting of the ionic liquid-coated nanowires and ionic liquid-coated nanoparticles.

Abstract: Provided is a method making it possible to ensure a gradual release of polymer chains within a liquid medium, the method comprising bringing the liquid medium into contact with specific solid objects formed by polymer chains soluble in the medium and carrying hydrophobic side groups ensuring physical crosslinking between the polymer chains within the solid objects. The released chains may in particular be used as inhibitors of the formation of inorganic or organic deposits (scale inhibitors) within a liquid medium, typically in the field of oil extraction.

Abstract: Compositions and compounds of nucleoside phosphoramidites and modified oligonucleotides, each comprising one or more charge-neutralizing moieties according to the formula V The nucleoside phosphoramidites permit facile attachment of the neutralizing moieties on the backbones of the modified oligonucleotides. The modified oligonucleotides can be used as therapeutic agents (i.e., oligotherapeutics) for the treatment of cancer, autoimmune disorders, genetic diseases, infectious diseases, neurological diseases, inflammatory diseases, metabolic diseases and others.

Abstract: The present invention relates to the field of oil extraction. More specifically, it relates to a particular polymerization process, which provides access to formulations of polymers that may be used in particular for modifying rheology and fluid loss control during extraction operations and that have a better heat stability.

Abstract: A crosslinked polymer that is in the form of a Mannich polycondensation product including reacted units of a cyclic diaminoalkane, an aldehyde, and bisphenol-S or melamine. Also disclosed is a method for removing heavy metals from an aqueous solution by contacting the aqueous solution having an initial concentration of the heavy metal with the crosslinked polymer to form a mixture, and filtering the mixture to obtain an aqueous solution having a reduced concentration of the heavy metal compared to the initial concentration.

Abstract: Embodiments of the present disclosure are directed to a method of making a reaction inhibiting polymer having a formula of M—CO—NR. The method may comprise reacting PAA with an organic coupling reagent and at least one alicyclic amine to produce the reaction inhibiting polymer. In accordance with another embodiment of the present disclosure, a method of making an acryloyl monomer having a formula of Ra—CO—NR may comprise reacting an acrylic acid with an organic coupling reagent and an alicyclic amine to form the acryloyl monomer. Ra may be an alkylene moiety, M may be a poly(acrylic) acid backbone. NR may be an alicyclic amine moiety coupled to the polymer backbone or coupled to the alkylene moiety.

Abstract: A photopolymerizable composition for forming a photopolymerized nail top coating of a substantially uniform mixture of ethyl cellulose and crosslinked (meth)acrylate polymer is disclosed.

Abstract: Multipart functionalized materials are shown that remove sulfites from beverages and in particular wine. The functionalized materials consist of a solid support material having the ability to link polycarbonyls or polyamines thereto. The polycarbonyls and polyamines remove free and bound sulfites when put in contact with the beverage. The polycarbonyl and polyamine functionalized materials can be used separately or mixed together for accomplishing sulfite removal.

Abstract: A polymer production method whereby: a flow reactor comprising a flow path wherein a plurality of liquids can be mixed is used; and a monomer is anionically polymerized in the presence of an initiator. The flow reactor comprises a mixer for mixing two liquids, said mixer comprising either a joint member having a double pipe therein or a static mixer member.

Abstract: Copolymers having General Formula (I): in which R1 and R3 are chosen from divalent C4-C7 aliphatic groups and divalent C4-C7 heteroaliphatic groups, optionally substituted with one or more C1-C6 aliphatic groups, heteroatoms independently chosen from O, N, and S, or combinations thereof, where the divalent C4-C7 heteroaliphatic groups of R1 and R3 include one or two heteroatoms independently chosen from O, N, and S, and the maximum number of heteroatoms in R1 or R3 is two, R2 is chosen from Q1 and Q2, x is a molar fraction range chosen from 0.1 to 0.9, y is a molar fraction range chosen from 0.1 to 0.9, and z is a molar fraction range chosen from 0 to 0.8, where the summation of x, y, and z equals 1. Methods for inhibiting formation of clathrate hydrates include contacting a fluid with at least one copolymer of General Formula (I).

Abstract: A copolymer which comprises, in copolymerized form, (A) 60 to 99% by weight of at least one monoethylenically unsaturated polyalkylene oxide monomer of the formula I (I) in which the variables have the following meanings: X is —CH2— or —CO—, if Y is —O—; is —CO—, if Y is —NH—; Y is —O— or —NH—; R1 is hydrogen or methyl; R2 are identical or different C2-C6-alkylene radicals, which may be arranged blockwise or randomly; R3 is hydrogen or C1-C4-alkyl; n is an integer from 25 to 75, (B) 1 to 40% by weight of at least one quaternized nitrogen-containing monoethylenically unsaturated monomer selected from the group consisting of monomers of formula Ha to IId (Ha-IId) in which the variables have the following meanings: R is C1-C4-alkyl or benzyl; R? is hydrogen or methyl; Y is —O— or —NH—; A is C1-C6-alkylene; X— is halide, C1-C4-alkyl sulfate, C1-C4-alkylsulfonate and Ci-C4-alkyl carbonate, (C) 0 to 10% by weight of anionic monoethylenically unsaturated monomers, and (D) 0 to 30% by weight of other nonionic monoeth

Abstract: To determine and detect 8-oxo-2?-deoxyguanosine in an aqueous sample solution with high sensitivity and specifically, provided is a polymer including a repetition structure represented by any one of the following general formulae 2 to 5, in which a group represented by any one of the following general formulae 6 to 11 is linked to the repetition structure represented by any one of the following general formulae 2 to 5 through a divalent linking group L.

Abstract: Compositions and compounds of nucleoside phosphoramidites and modified oligonucleotides, each comprising one or more charge-neutralizing moieties according to the formula V wherein represents the point of attachment to the nucleoside phosphoramidite or the oligonucleotide, optionally through a spacer group. The nucleoside phosphoramidites permit facile attachment of the neutralizing moieties on the backbones of the modified oligonucleotides. The modified oligonucleotides can be used as therapeutic agents (i.e., oligotherapeutics) for the treatment of cancer, autoimmune disorders, genetic diseases, infectious diseases, neurological diseases, inflammatory diseases, metabolic diseases and others.

Abstract: Antimicrobial compounds are provided that are polymerizable. The compounds include monomers with antimicrobial properties. The compounds have cross-linking properties. The compounds may be utilized in dental and/or medical applications, including dental composites, dentures, bonding agents, sealants, resins and medical devices.

Abstract: The invention discloses a method of separating a biomolecule from at least one other component in a liquid, comprising a step of contacting said liquid with a separation matrix comprising a solid support and polymer chains bound to said solid support. The polymer chains comprise units derived from a first monomer of structure CH2?CH-L-X, where L is a covalent bond or an alkyl ether or hydroxysubstituted alkyl ether chain comprising 2-6 carbon atoms, and X is a sulfonate or phosphonate group.

Abstract: Antimicrobial compounds are provided that are polymerizable. The compounds include monomers with antimicrobial properties. The compounds have cross-linking properties and are hydrolytically stable. The compounds may be utilized in dental and/or medical applications, including dental composites, dentures, bonding agents, sealants, resins and medical devices.

Abstract: A cationizing agent for cationizing a cloth prior to the firm fixing of water-insoluble particles onto the cloth, said cationizing agent comprising a polymer having a constituent unit (a1) derived from a vinylamine monomer represented by formula (1). (In the formula, R1 represents a hydrogen atom or a methyl group.

Abstract: The invention includes a composition comprising a vinyl sulfone monomer, a thiol monomer, and optionally an isocyanate monomer. The invention further includes a composition comprising a composition comprising the tetra(2-mercapto)silane (SiTSH) monomer and at least one selected from the group consisting of (a) a Michael acceptor, optionally an isocyanate monomer, and optionally at least one catalyst selected from the group consisting of a base, nucleophile, photolabile base, photolabile nucleophile, and mixtures thereof; (b) an ene monomer, and optionally a polymerization photoinitiator. In certain embodiments, once the composition is polymerized, the polymerized system is suitable for use as a dental composite system. In other embodiments, the polymerized system is stable to acidic and basic conditions. In yet other embodiments, the polymerized system forms microparticles. The invention further includes a method of generating a dental polymeric material.

Abstract: Provided is a liquid crystal alignment layer of which a constituent member is a polymer represented by the general formula (I).

Abstract: The invention discloses a method of separating a biomolecule from at least one other component in a liquid, comprising a step of contacting said liquid with a separation matrix comprising a solid support and polymer chains bound to said solid support. The polymer chains comprise units derived from a first monomer of structure CH2?CH-L-X, where L is a covalent bond or an alkyl ether or hydroxysubstituted alkyl ether chain comprising 2-6 carbon atoms, and X is a sulfonate or phosphonate group.

Abstract: The present invention generally relates to methods for resolving water and oil emulsions in the produced fluid of an oil production system comprising adding a reverse emulsion breaker to the produced fluid of the crude oil production system in an amount effective for resolving an oil-in-water emulsion. In particular, these methods for resolving an oil-in-water emulsion can be used in separation processes where the oil and solids in the produced fluid are separated from the produced water in the produced fluid.

Abstract: De-polluting, self-cleaning coating compositions are disclosed which comprise an organic binder having dispersed therein photocatalytic titanium dioxide particles substantially in anatase form which have an average crystallite size between about 1 nm and about 150 nm and which preferably have photocatalytic activity in the presence of visible light. Advantageously, the coatings of the invention do not require pre-activation to achieve high initial photocatalytic activity against pollutants in the air, such as NOx compounds.

Abstract: The present invention generally relates to methods for resolving water and oil emulsions in the produced fluid of an oil production system comprising adding a reverse emulsion breaker to the produced fluid of the crude oil production system in an amount effective for resolving an oil-in-water emulsion. In particular, these methods for resolving an oil-in-water emulsion can be used in separation processes where the oil and solids in the produced fluid are separated from the produced water in the produced fluid.

Abstract: Amphiphilic macromolecules having structural units to adjust molecular weight and molecular weight distribution and charging property effects, high stereo-hindrance structural units, and amphiphilic structural units, are suitable for fields such as oil field well drilling, well cementation fracturing, oil gathering and transfer, sewage treatment, sludge treatment and papermaking, etc., and can be used as an oil-displacing agent for enhanced oil production, a heavy oil viscosity reducer, a fracturing fluid, a clay stabilizing agent, a sewage treatment agent, a papermaking retention and drainage aid or a reinforcing agent, etc.

Abstract: An ink composition with excellent solvent resistance of the recorded image and fixability to a recording medium which may be applicable to an ink jet recording method, and an image forming method using the ink composition are provided. An ink composition which includes a dispersion medium including (a) water, and particles of (b) a polymer compound and (b) the polymer compound includes a repeating unit having a partial structure represented by the following General Formula (1) is provided. In the following General Formula (1), Ra and Rb, each independently, represent an alkyl group having the number of carbon atoms 1 to 4, and Ra and Rb may be bonded to each other to form an alicyclic structure with 4- to 6-membered ring and * represents a bonding site to a main chain or a side chain in the polymer compound.

Abstract: A negative resist composition comprising a polymer comprising recurring units (a) of formula (1) and having a Mw of 1,000-500,000 as base resin is provided. R1 is H or methyl, X is a single bond or —C(?O)—O—R4—, R2 is a single bond or C1-C4 alkylene, R3 is C2-C8 alkylene, R4 is a single bond or C1-C4 alkylene, and 0<a?1.0. The composition exhibits a high resolution due to controlled acid diffusion and forms a resist film which is unsusceptible to swell in the developer and hence to pattern collapse.

Abstract: The invention discloses a method of separating a biomolecule from at least one other component in a liquid, comprising a step of contacting said liquid with a separation matrix comprising a solid support and polymer chains bound to said solid support. The polymer chains comprise units derived from a first monomer of structure CH2?CH-L-X, where L is a covalent bond or an alkyl ether or hydroxysubstituted alkyl ether chain comprising 2-6 carbon atoms, and X is a sulfonate or phosphonate group.

Abstract: A polymer is obtained from a hydroxyphenyl methacrylate monomer having an acid labile group substituted thereon. A positive resist composition comprising the polymer as a base resin has a very high contrast of alkaline dissolution rate before and after exposure, a high resolution, a good profile and minimal line edge roughness of a pattern after exposure, a retarded acid diffusion rate, and good etching resistance.

Abstract: A resist composition including a polymeric compound containing a structural unit derived from a compound represented by general formula (a0-m), and a method of forming a resist pattern using the resist composition. R1 represents a polymerizable group; Y1 represents a hydrocarbon group of 1 to 30 carbon atoms; L1 represents a single bond or a carbonyl group; Y2 represents a divalent linking group, and R2 represents a hydrogen atom or a hydrocarbon group, provided that Y2 and R2 may be mutually bonded to form a ring with the nitrogen atom having Y2 and R2 bonded thereto; R3 represents a hydrogen atom or a hydrocarbon group; Y3 represents a group which forms an aromatic ring together with the two carbon atoms having Y3 bonded thereto, provided that the aromatic ring may have a nitro group or a substituent other than the nitro group bonded to the aromatic ring.

Abstract: The present invention relates to a polymer compound including a dye, and a curable resin composition including the same. The polymer compound including the dye according to the present invention may exhibit characteristics such as excellent heat resistance, solubility, coating uniformity, chemical resistance and the like by introducing a single molecule type dye into a side chain of a polymer binder to be modified into a polymer form and applying the modified polymer to a curable composition.

Abstract: Disclosed is a water and oil resistant agent comprising a fluorine-containing copolymer obtained by copolymerizing a (meth)acrylate monomer having a polyfluoroalkyl group having 1 to 6 carbon atoms, the agent being able to afford a superior water and oil resistance to a paper. The invention also discloses a composition comprising the water and oil resistant agent, a process for treating a paper thereby and a treated paper thereby.

Abstract: A polymerizable monomer represented by the following formula (1) wherein at least one of Ar1 to Ar3 is substituted by a group represented by the following formula (2) and which is substituted by one or more groups comprising a polymerizable functional group. Ar1 to Ar3 are a substituted or unsubstituted aryl group having 6 to 40 ring carbon atoms, Ar6 is a substituted or unsubstituted aryl group having 6 to 40 ring carbon atoms and Ar4 and Ar5 are a substituted or unsubstituted arylene group having 6 to 40 ring carbon atoms.

Abstract: An object is to provide a polymerizable compound having high polymerization reactivity, a high conversion ratio and high solubility in a liquid crystal composition, a polymerizable composition containing the compound, a liquid crystal composite prepared from the composition, and a liquid crystal display device having the composite. A solution is a polymerizable compound represented by formula (1). In the formula, for example, P1 and P2 are —OCO—(CH3)C?CH2; S1 and S2 are a single bond; ring A1, ring A2 and ring A3 are 1,4-phenylene; Z1, Z2 and Z3 are a single bond; two of G is —CH? or —N?; and a is 0 or 1.

Abstract: Provided are a polymer for an organic electroluminescent element, which improves light emission efficiency of the element and is applicable to a wet process, and an organic electroluminescent element, which is obtained using the polymer. The polymer for an organic electroluminescent element includes a repeating unit represented by the following general formula (1) in a repeating unit constituting a main chain. Further, the organic electroluminescent element includes organic layers between an anode and a cathode laminated on a substrate, in which at least one of the organic layers includes the polymer for an organic electroluminescent element, including an indolocarbazole skeleton in the repeating unit constituting a main chain. In the general formula (1), Z represents an N-indolocarbazolyl group, W represents a charge transporting group, m and n represent molar ratios, m represents 0 to 95 mol %, and n represents 5 to 100 mol.

Abstract: In a conductive film forming method using photo sintering, a conductive film having low electric resistance is easily formed. The conductive film forming method is a method in which a conductive film is formed using photo sintering. This method includes the steps of forming a layer made of a sintering promoter on a substrate, forming a liquid film made of a copper particulate dispersion on the layer of the sintering promoter, drying the liquid film to form a copper particulate layer, and subjecting the copper particulate layer to photo sintering. The sintering promoter is a compound which removes copper oxide from metallic copper. Thereby, the sintering promoter removes a surface oxide film of copper particulates in photo sintering.

Abstract: The cross-linked polyzwitterion/anion for the removal of strontium from aqueous solutions is a polyzwitterion having the following structure: and the corresponding anion formed by treating the polyzwitterion with a base, e.g., sodium hydroxide. The cross-linked polyzwitterion/anion (CPZA) was prepared using Butler's cyclopolymerization protocol. The CPZA resin was found to have a very good adsorption capacity for Sr2+ ions at low concentrations. The relatively strong rapid initial adsorption of 83% Sr2+ ions was followed by slower adsorption of the remaining 17%, which was described by an intraparticle diffusion model. The adsorption followed the Lagergren second-order kinetic model, and Temkin as well as Freundlich isotherm models. The negative ?Gs and ?H ensured the spontaneity and the exothermic nature of the adsorption process. The excellent adsorption and desorption efficiencies implied the efficacy of the resin in removing (as well as recovering) the metal ions from aqueous solution.

Abstract: A copolymer that includes for 100 mol %: a) more than 70 mol % and up to 99.9 mol % of hydrophobic monomer units (A) from stearyl methacrylate; and b) 0.1 mol % to 30 mol % of monomer units (B) from at least one monomer of a compound of formula (I) where R1 is a linear or branched alkyl radical comprising 12 to 22 carbon atoms, R2 is a hydrogen atom or a methyl radical, and n is an integer greater than or equal to 0 and lower than or equal to 30, wherein it is understood that said compound of formula (I) is not stearyl methacrylate. The invention also relates to a method for preparing and using same as a modifier of the rheology of the oil phase of a topical cosmetic, dermopharmaceutical, or pharmaceutical composition.

Abstract: A thermal triple-responsive polymer, along with methods of its formation and use, is generally provided. The thermal triple-responsive polymer can comprise poly[(2-(pyridin-2-yldisulfanyl)-co-[poly(ethylene glycol)]-co-[N-isopropyl methacrylamide], which contains both disulfide bonds and ester bonds that are labile to high redox potential and acidic pH, respectively, and temperature sensitive segments. The thermal triple-responsive polymer can be modified with 4-methoxybenzoic acid to endow tumor targeting effect. Nanoparticles and nanogels that include such a thermal triple-responsive polymer are also provided, along with their methods of formation and use.

Abstract: There are described vinyl sequential copolymers (and processes for making them) comprising (a) at least 8. 5 wt-% preferably >=20 wt-% of a higher itaconate diester (preferably dibutyl itaconate—DBI); (b) less than 23 wt-% acid monomer but also sufficient to have an acid value less than 150 mg KOH/g of polymer, (c) optionally with less than 50 wt-% of other itaconate monomers, and (d) optionally less than 77 wt-% of other monomers not (a) to (c). The DBI may be biorenewable. One embodiment is an aqueous dispersion of the vinyl sequential polymer of two phases: A) 40 to 90 wt-% of a vinyl polymer A with Tg from ?50 to 30° C.; and B) 10 to 60 wt-% of a vinyl polymer B with Tg from 50 to 130° C.; where DBI is used to prepare A and/or B and polymer A has from 0.1 to 10 wt-% of at least one acid-functional olefinically unsaturated monomer.

Abstract: The instant disclosure describes methacrylate coated carrier resins with aromatic substituent groups with optionally carbon atoms replaced by heteroatoms such as S, N, and O for charge control and improved RH sensitivity.

Abstract: Disclosed are drug delivery systems comprising drugs admixed with polymers having drug solubility gradients and methods of making the polymers. Also disclosed are medical devices having coatings thereon comprising the drug solubility gradient-containing polymers and at least one drug.

Abstract: Disclosed are a method for producing a polymer by a polymerization of a mixture at a temperature of 210° C. or lower, wherein the mixture comprises 0.01 to 35 mol % of a monomer or a polymer thereof which has a piperidine skeleton represented by formula (1), and a molded body thereof. R1 represents a hydrogen atom or a methyl group, X represents an oxygen atom, an imino group, or a specific oxygen atom containing a hydrocarbon group, and R2 and R3 represent a hydrogen atom, a linear alkyl group with C1 to C8, a branched alkyl group with C1 to C8, an alicyclic hydrocarbon with C6 to C8, or an aryl group, wherein R2 and R3 may also form a cyclic structure.

Abstract: An adhesive composition of the present invention contains, as a main composition, a polymer obtained by copolymerizing a monomer composition containing a monomer having a maleimide group, and further contains a thermal polymerization inhibitor. As a result, it is possible to provide an adhesive composition that allows forming an adhesive layer that is excellently dissolved after the adhesive layer has been subjected to a high-temperature process.

Abstract: An adhesive composition of the present invention contains, as a main composition, a polymer obtained by copolymerizing a monomer composition containing a monomer having a maleimide group, and further contains a thermal polymerization inhibitor. As a result, it is possible to provide an adhesive composition that allows forming an adhesive layer that is excellently dissolved after the adhesive layer has been subjected to a high-temperature process.

Abstract: Disclosed herein is a composition and method of making a polymerizable antibacterial/antimicrobial resin and using such a bioactive resin in formulated dental compositions.