Contains Carbocyclic Ring, E.g., Aryl, Etc. Patents (Class 526/292.5)
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Patent number: 9127157Abstract: The present invention provides a flame-retardant and scratch-resistant polycarbonate resin composition including a (meth)acrylic flame-retardant copolymer.Type: GrantFiled: April 29, 2013Date of Patent: September 8, 2015Assignee: Cheil Industries Inc.Inventors: Jin Hwa Chung, Kee Hae Kwon, Jin Seong Lee, Man Suk Kim, Yong Hee Kang, Kwang Soo Park, Ja Kwan Koo
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Patent number: 9072292Abstract: The present invention relates to compounds and materials that reduce the accumulation of microorganisms on a surface by interfering with the attachment of the organisms to the surface. The compounds and materials of the present invention are thus useful in preventing the formation of biofilms. The compounds of the present invention may be either adhered to a surface or integrated within a polymer. Surfaces coated by the present invention are resistant to biofilm formation, in part due to the smoothness of the surface coated with the present invention.Type: GrantFiled: June 6, 2008Date of Patent: July 7, 2015Inventors: T. Brian Cavitt, Rebecca Ann Herrington Faulkner
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Patent number: 9018324Abstract: The invention relates to a process for preparing pentabromobenzyl acrylate through the reaction of pentahalobenzyl halide with a salt of acrylic acid in water-immiscible solvent, wherein said salt is in aqueous form and the reaction is carried out in the presence of a phase transfer catalyst. A process for polymerizing the pentabromobenzyl acrylate in halogenated aromatic solvent and the poly (pentabromobenzyl acrylate) obtained are also disclosed.Type: GrantFiled: April 5, 2012Date of Patent: April 28, 2015Assignee: Bromine Compounds Ltd.Inventor: Jacob Oren
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Publication number: 20140121338Abstract: The invention relates to a process for preparing pentabromobenzyl acrylate through the reaction of pentahalobenzyl halide with a salt of acrylic acid in water-immiscible solvent, wherein said salt is in aqueous form and the reaction is carried out in the presence of a phase transfer catalyst. A process for polymerizing the pentabromobenzyl acrylate in halogenated aromatic solvent and the poly (pentabromobenzyl acrylate) obtained are also disclosed.Type: ApplicationFiled: April 5, 2012Publication date: May 1, 2014Applicant: BROMINE COMPOUNDS LTD.Inventor: Jacob Oren
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Patent number: 8703383Abstract: A copolymer has formula: wherein R1-R5 are independently H, C1-6 alkyl, or C4-6 aryl, R6 is a fluorinated or non-fluorinated C5-30 acid decomposable group; each Ar is a monocyclic, polycyclic, or fused polycyclic C6-20 aryl group; each R7 and R8 is —OR11 or —C(CF3)2OR11 where each R11 is H, a fluorinated or non-fluorinated C5-30 acid decomposable group, or a combination; each R9 is independently F, a C1-10 alkyl, C1-10 fluoroalkyl, C1-10 alkoxy, or a C1-10 fluoroalkoxy group; R10 is a cation-bound C10-40 photoacid generator-containing group, mole fractions a, b, and d are 0 to 0.80, c is 0.01 to 0.80, e is 0 to 0.50 provided where a, b, and d are 0, e is greater than 0, the sum a+b+c+d+e is 1, l and m are integers of 1 to 4, and n is an integer of 0 to 5. A photoresist and coated substrate, each include the copolymer.Type: GrantFiled: November 17, 2011Date of Patent: April 22, 2014Assignee: Rohm and Haas Electronic Materials LLCInventors: James W. Thackeray, Emad Aqad, Su Jin Kang, Owendi Ongayi
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Patent number: 8426106Abstract: A Photoresist composition comprising a polymer comprising a structural unit derived from a compound represented by the formula (I): wherein R1 represents a hydrogen atom or a methyl group, R2 represents a C6-C12 aromatic hydrocarbon group which can have one or more substituents, R3 represents a cyano group or a C1-C12 hydrocarbon group which can have one or more substituents and which can contain one or more heteroatoms, A1 represents a single bond, —(CH2)g—CO—O—* or —(CH2)h—O—CO—(CH2)i—CO—O—* wherein g, h and i each independently represent an integer of ?1 to 6 and * represents a binding position to the nitrogen atom, a resin having an acid-labile group and being insoluble or poorly soluble in an aqueous alkali solution but becoming soluble in an aqueous alkali solution by the action of an acid, and an acid generator.Type: GrantFiled: October 12, 2010Date of Patent: April 23, 2013Assignee: Sumitomo Chemical Company, LimitedInventors: Tatsuro Masuyama, Kazuhiko Hashimoto, Junji Shigematsu
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Patent number: 8293123Abstract: A method of manufacturing an inkjet printhead, in which a solvent included in a positive photoresist composition or in a non-photosensitive soluble polymer composition which is used to form a sacrificial layer has a different polarity from that of a solvent included in a negative photoresist composition that is used to form at least one of a channel forming layer and a nozzle layer.Type: GrantFiled: June 24, 2008Date of Patent: October 23, 2012Assignee: Samsung Electronics Co., Ltd.Inventors: Jong-jin Park, Su-min Kim, Jin-baek Kim, Yong-ung Ha, Yong-seop Yoon, Byung-ha Park
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Patent number: 8022030Abstract: The present invention relates to the field of perfumery. More particularly, it concerns co-polymers, derived from a maleic anhydride derivative and a ethylenic derivative, comprising at least one ?-oxy or ?-thio carbonyl moiety capable of liberating an active molecule such as, for example, an ?,?-unsaturated ketone, aldehyde or carboxylic ester. The present invention concerns also the use of polymers or co-polymers in perfumery as well as the perfuming compositions or perfumed articles comprising the invention's compounds.Type: GrantFiled: October 5, 2007Date of Patent: September 20, 2011Assignee: Firmenich SAInventors: Damien Berthier, Andreas Herrmann
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Patent number: 8003079Abstract: Nanoparticles having an average particle size of less than 2000 nm, wherein said nanoparticles comprise a polymer having pendant cleavable iodine substituted groups are provided. Processes for preparing the nanoparticles and their use as a contrast agent for X-ray imaging are also described.Type: GrantFiled: April 4, 2006Date of Patent: August 23, 2011Assignee: Bar-Ilan UniversityInventors: Shlomo Margel, Anna Galperin
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Patent number: 7910222Abstract: A polymerizable composition for forming an optical device, which comprises a polymerizable monomer of the following formula (1) and a polymerizable monomer of the following formula (2). Using the composition makes it possible to produce an optical device which has a high light transmittability and keeps a reduced transmission loss even in wet. wherein R1 and R2 each are H or D; R3 is H, D, CH3, CD3 or a halogen atom; R4is an alkyl group having from 2 to 8 carbon atoms and at least partly substituted with a fluorine atom, wherein R1 and R2 each are H or D; R3 is H, D, CH3, CD3 or a halogen atom; X1 to X5 each are H, D, a halogen atom or CF3, and at least one of X1 to X5 is a halogen atom or CF3.Type: GrantFiled: November 4, 2005Date of Patent: March 22, 2011Assignee: FUJIFILM CorporationInventors: Hiroki Sasaki, Masataka Sato, Hirokazu Kyota
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Patent number: 7732549Abstract: The aim of the present invention is to provide a multi-branched polymer, in which branch terminals can be easily modified and which have a high degree of branching and narrow dispersion. By polymerizing a compound having 2 or more polymerization-initiation sites and polymerizable unsaturated bonds with a living radical polymerization method using a metal catalyst, it is possible to produce a multi-branched polymer with narrow dispersion and a high degree of branching and having repeating units represented by the formula (I): wherein R1 to R3 each independently represents hydrogen or a hydrocarbon group, R1 may be bonded to R3 to form a ring; X represents a connecting group having a valence of 3 or higher; Y may be the same or different and each represents a functional group which may have a halogen atom at a terminal thereof; and a is an integer of 2 or larger.Type: GrantFiled: November 25, 2004Date of Patent: June 8, 2010Assignee: Nippon Soda Co., Ltd.Inventors: Koichiro Aoyagi, Takeshi Niitani
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Patent number: 7649065Abstract: To provide a novel fluoroadamantane derivative, a novel polymerizable fluoroadamantane derivative and a novel fluoropolymer, and processes for production thereof. To provide the following compound (3), the following compound (4), a polymer obtained by polymerizing the compound (4) and processes for production thereof: provided that Q represents —CHF— or —CF2— (provided that six Qs may be the same or different), Z represents —H, —F or —CH2OH (provided that three Zs may be the same or different), W represents —H or a C1-10 hydrocarbon group, R represents —H, —F, —CH3 or —CF3, and J represents —H, —F, —CHWOH or —CHWOCOCR?CH2 (provided that three Js may be the same or different).Type: GrantFiled: October 25, 2006Date of Patent: January 19, 2010Assignee: Asahi Glass Company, LimitedInventors: Shu-zhong Wang, Koichi Murata, Kazuya Oharu, Yoshitomi Morizawa, Osamu Yokokoji, Naoko Shirota
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Publication number: 20090311192Abstract: Nanoparticles having an average particle size of less than 2000 nm, wherein said nanoparticles comprise a polymer having pendant cleavable iodine substituted groups are provided. Processes for preparing the nanoparticles and their use as a contrast agent for X-ray imaging are also described.Type: ApplicationFiled: April 4, 2006Publication date: December 17, 2009Applicant: Bar-Ilan UniversityInventors: Shlomo Margel, Anna Galperin
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Patent number: 7625988Abstract: The present invention is directed to novel flame retardant monomers and polymers, wherein the flame retardant properties of the polymers are provided by functionality in pendant groups attached to a polymer backbone (as opposed to the polymer backbone itself possessing flame retardant properties. The present invention is also directed to methods of making such polymers and monomers, and articles of manufacture incorporating such monomers and polymers.Type: GrantFiled: June 18, 2004Date of Patent: December 1, 2009Assignee: William Marsh Rice UniversityInventors: James M. Tour, Joshua L. Jurs, Jason J. Stephenson
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Publication number: 20090061356Abstract: A polymer compound having a structural unit (a0) represented by a general formula (a0-1) shown below, and a structural unit (a1) that is derived from an acrylate ester containing an acid dissociable, dissolution inhibiting group but is not classified as said structural unit (a0). [wherein, R represents a hydrogen atom, a lower alkyl group, or a halogenated lower alkyl group; A represents a divalent aliphatic cyclic group that may have a substituent; B represents a divalent hydrocarbon group that may have a substituent; r represents an integer of 0 or 1; and R1 represents an acid dissociable, dissolution inhibiting group.Type: ApplicationFiled: August 26, 2008Publication date: March 5, 2009Applicant: Tokyo Ohka Kogyo Co., Ltd.Inventors: Takahiro Dazai, Takayoshi Mori, Hiroaki Shimizu, Kyoko Ohshita, Komei Hirahara
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Patent number: 7495061Abstract: A hydrophilic, aromatic-based monomer has an aromatic group substituted with at least one hydrophilic substituent and a reactive functional group. Polymers comprising such a hydrophilic, aromatic-based monomers avoid or reduce the risk of forming vacuoles of absorbed water. Furthermore, such polymers have high refractive index, and, thus, are advantageously used for making ophthalmic devices, such as intraocular lenses, contact lenses, corneal rings, corneal inlays, and keratoprostheses.Type: GrantFiled: May 27, 2005Date of Patent: February 24, 2009Assignee: Bausch + Lomb IncorporatedInventors: Joseph C. Salamone, Jay F. Kunzler, Richard M. Ozark
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Patent number: 7317060Abstract: Suspensions of PBBMA, characterized in that they comprise PBBMA in the form of finely ground particles and contain suspending agents chosen from among xanthene gums, anionic or nonionic purified, sodium modified montmorilonite, naphthalene sulfonic acid-formaldehyde condensate sodium salt, sodium or calcium or ammonium salts of sulfonated lignin, acrylic acids/acrylic acids ester copolymer neutralized-sodium polycarboxyl, and wetting agents chosen from among alkyl ether, alkylaryl ether, fatty acid diester and sorbitan monoester types, polyoxyethylene (POE) compounds.Type: GrantFiled: August 11, 2004Date of Patent: January 8, 2008Assignee: Bromine Compounds Ltd.Inventors: Gad Friedman, Emanuel Buchbinder, Nurit Kornberg
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Patent number: 7297810Abstract: The present invention includes optical coatings containing ultraviolet curable monomers employing a bromine substituted fluorene structure. The fluorene backbone of the monomers of the present invention may also be functionalized with one or more polymerizable or reactive functionalities, and most readily at the 9 position. Compositions of the present invention include the reactive bromosubstituted fluorenes combined with inorganic nanoparticles, particularly nanoparticles with reactive surface modifiers exhibiting polymerizable functionality. Reactive high index nanoparticles such as surface modified zirconia are contemplated.Type: GrantFiled: December 30, 2004Date of Patent: November 20, 2007Assignee: 3M Innovative Properties CompanyInventors: Christopher B. Walker, Jr., Roger A. Mader, Emily S. Goenner, Brant U. Kolb, Sharon Wang, Joan M. Noyola
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Patent number: 6967232Abstract: A high-molecular gelling agent precursor for an electrolyte comprises a copolymer formed of (A) a hydrophobic monomer having a hydrophobic group, which forms a carboxyl group upon saponification, and (B) a hydrophobic polyfunctional monomer. The saponification product of the copolymer has property to gel the electrolyte. A high-molecular gelling agent for the electrolyte is produced by saponifying the precursor with a saponifying agent selected from the group consisting of acids and alkalis while using a reaction medium selected from the group consisting of water and hydrophobic organic solvents.Type: GrantFiled: October 1, 2002Date of Patent: November 22, 2005Assignee: Dainichiseika Color & Chemicals Mfg., Co., Ltd.Inventors: Minoru Takizawa, Seiji Doi, Chiaki Iwakura, Hiroshi Inoue, Naoji Furukawa, Shinji Nohara, Yoshifumi Sugito, Naomi Oguma, Sachio Yoshikawa, Michiei Nakamura
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Patent number: 6815498Abstract: A process for the preparation of a reaction product (A), which comprises the following stage (i): (i) Reaction, under free radical conditions, of a reaction mixture comprising at least one monomer (a), capable of free radical reaction in the presence of at least one free radical initiator and a compound of the formula (I) where R1 to R4, independently of one another, are each hydrogen, an alkyl radical, cycloalkyl radical or aralkyl radical, each of which is unsubstituted or substituted, an unsubstituted or substituted aromatic hydrocarbon radical, with the proviso that at least two of the radicals R1 to R4 are an unsubstituted or substituted aromatic hydrocarbon radical, or R1 and R2 or R3 and R4, in each case in pairs, are a substituted or unsubstituted aromatic hydrocarbon having 6 to 18 carbon atoms and a functional group which, in conjugation with the C—C double bond in the formula I, has a multiple bond between a carbon atom and a heteroatom, 10% by weight or less of wateType: GrantFiled: June 13, 2002Date of Patent: November 9, 2004Assignee: BASF AktiengesellschaftInventors: Roman Benedikt Raether, Bernd Modery, Frank Braun, Susanne Brinkmann-Rengel, David Christie, Sylke Haremza
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Patent number: 6787621Abstract: Vinyl group-containing diarylethene monomers and photochromic polymers made there from. The diarylethene monomers may be suitable for controlled polyermerization. Polymers formed from the diarylethene monomers may have optical properties such as, for example, optical signal control properties, photochromic properties, and/or optical reflectivity properties.Type: GrantFiled: September 19, 2002Date of Patent: September 7, 2004Assignee: Korea Research Institute of Chemical TechnologyInventors: Eunkyoung Kim, Song Yun Cho, Min Ja Yoo, Kwang-Hyun Ahn
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Patent number: 6767979Abstract: A polymer is formed of ethylenically unsaturated monomers including a zwitterionic monomer, an aromatic monomer and a cross-linking monomer. Preferably the crosslinking monomer includes at least one a group containing compound and at least one aliphatic group containing compound. The polymer is water-swellable and a hydrogen has optical and mechanical properties rendering it suitable for use as an intraocular refractive device such as an intraocular lens.Type: GrantFiled: September 20, 2001Date of Patent: July 27, 2004Assignee: Biocompatibles UK LimitedInventors: Andrew Victor Graham Muir, Lee Rowan, Stephen Alister Jones, John Charles Stedman
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Patent number: 6703466Abstract: Foldable intraocular lenses having a reduced risk of posterior capsule opacification are disclosed. The foldable intraocular lenses have optics that are prepared such that their surface is glassy and their bulk is rubbery.Type: GrantFiled: June 12, 2002Date of Patent: March 9, 2004Assignee: Alcon, Inc.Inventors: Mutlu Karakelle, Joseph D. Menczel, Robert A. Scott, Charles Freeman
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Patent number: 6653422Abstract: Disclosed are soft, high refractive index, acrylic materials having an elongation of at least 150%. These materials, especially useful as intraocular lens materials, contain an aryl acrylic hydrophobic monomer as the single principal device-forming monomer. In addition to their use as intraocular lens materials, the present materials are also suitable for use in other ophthalmic or otorhinolaryngological devices, such as contact lenses, keratoprostheses, corneal inlays or rings; otological ventilation tubes and nasal implants.Type: GrantFiled: January 24, 2003Date of Patent: November 25, 2003Assignee: Alcon Universal Ltd.Inventors: Charles Freeman, Douglas C. Schlueter
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Patent number: 6610809Abstract: A photorefractive composition comprising a polymer prepared by living radical polymerization, wherein: the living radical polymerization is carried out using a monomer, a polymerization initiator, transition metal catalyst and a ligand capable of reversibly forming a complex with the transition metal catalyst, and the polymer comprises at least one of a repeat unit including a moiety having charge transport ability and a repeat unit including a moiety having non-linear-optical ability.Type: GrantFiled: March 29, 2002Date of Patent: August 26, 2003Assignees: Nitto Denko Corporation, Arizona Board of Regents on behalf of the University of ArizonaInventors: Michiharu Yamamoto, Seth R. Marder, Bernard Kippelen
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Publication number: 20030130460Abstract: Disclosed are soft, high refractive index, acrylic materials having an elongation of at least 150%. These materials, especially useful as intraocular lens materials, contain an aryl acrylic hydrophobic monomer as the single principal device-forming monomer. In addition to their use as intraocular lens materials, the present materials are also suitable for use in other ophthalmic or otorhinolaryngological devices, such as contact lenses, keratoprostheses, corneal inlays or rings; otological ventilation tubes and nasal implants.Type: ApplicationFiled: January 24, 2003Publication date: July 10, 2003Inventors: Charles Freeman, Douglas C. Schlueter
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Publication number: 20030100693Abstract: A polymerizable composition that includes a monomer of the formula 1Type: ApplicationFiled: November 12, 2002Publication date: May 29, 2003Applicant: 3M Innovative Properties CompanyInventors: David B. Olson, Richard J. Pokorny, Bettie C. Fong
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Patent number: 6528602Abstract: Disclosed are soft, high refractive index, acrylic materials having an elongation of at least 150%. These materials, especially useful as intraocular lens materials, contain an aryl acrylic hydrophobic monomer as the single principal device-forming monomer. In addition to their use as intraocular lens materials, the present materials are also suitable for use in other ophthalmic or otorhinolaryngological devices, such as contact lenses, keratoprostheses, corneal inlays or rings; otological ventilation tubes and nasal implants.Type: GrantFiled: August 23, 2000Date of Patent: March 4, 2003Assignee: Alcon Universal Ltd.Inventors: Charles Freeman, Douglas C. Schlueter
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Patent number: 6506836Abstract: A process for preparing a reaction product (A), comprising the following stage (i): (i) reacting under free-radical conditions a reaction mixture comprising at least one free-radically reactable monomer (a) in the presence of at least one free-radical initiator and of a compound (I) of the formula: in which R1 to R4 each independently of one another are hydrogen, a substituted or unsubstituted alkyl radical, cycloalkyl radical or arakyl radical, or an unsubstituted or a substituted aromatic hydrocarbon radical, with the proviso that at least two of R1 to R4 are an unsubstituted or a substituted aromatic hydrocarbon radical in aqueous phase.Type: GrantFiled: July 30, 2001Date of Patent: January 14, 2003Assignees: BASF Aktiengesellschaft, BASF Coating AGInventors: Wolfgang Bremser, Frank Strickmann, Maximilian Bendix, Wolfgang Paulus, Roman Benedikt Raether, David Christie
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Patent number: 6399731Abstract: A method for making a polymer comprising the step of synthesizing a polymer by employing a chain transfer agent having the formula (II) where X and Y are independently selected from oxygen, sulfur, and fully-substituted nitrogen where R1 and R2 are independently selected from hydrogen, halogen, or an organic group, with the proviso that at least one of R1 or R2 be hydrogen or halogen, R3 is an organic group R4 and R5 are independently selected organic groups, with the proviso that R3 is not hydrogen.Type: GrantFiled: December 2, 1998Date of Patent: June 4, 2002Assignee: The University of AkronInventors: Brian King, H. James Harwood
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Patent number: 6355754Abstract: Described are a polymerizable composition comprising an alkyl-substituted brominated phenolic ester (meth)acrylate monomer having an index of refraction of at least 1.50, and, polymeric materials derived therefrom.Type: GrantFiled: May 9, 1997Date of Patent: March 12, 2002Assignee: 3M Innovative Properties CompanyInventors: David B. Olson, Bettie C. Fong
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Patent number: 6235857Abstract: This invention relates to a process for the production of lower molecular weight polymers by free radical-initiated polymerization of unsaturated species characterized by the use of an unsaturated compound of Formula I as a chain transfer agent: wherein R1 and R2 are the same or different and are selected from the group consisting of hydrogen, optionally substituted alkyl, optionally substituted saturated or aromatic carbocyclic or heterocyclic ring, and halogen; X is selected from the group consisting of chlorine, bromine, optionally substituted alkylsulfonyl, and optionally substituted arylsulfonyl, Y is selected from the group consisting of halogen, a polymer chain, and CR3R4Z, wherein R3 and R4 are the same or different and are selected from the group consisting of hydrogen, optionally substituted alkyl, optionally substituted saturated, unsaturated or aromatic carbocyclic or hetercyclic ring, and halogen; and Z is selected from the group consisting of chlorine, bromine, optionally suType: GrantFiled: April 3, 1998Date of Patent: May 22, 2001Assignees: Commonwealth Scientific and Industrial Research Organisation, E.I. DuPont DeNemours and CompanyInventors: Ezio Rizzardo, San Hoa Thang, Graeme Moad, Yen Kwong Chong