From Monomer Containing A >>n-c(=o)-n<< Or >>n-c(-o)-n<< Group E.g., Urea, Isoureau, Etc. Patents (Class 526/302)
  • Patent number: 5451651
    Abstract: Urea- and urethane-containing monomers for contact lens materials are disclosed.
    Type: Grant
    Filed: December 17, 1993
    Date of Patent: September 19, 1995
    Assignee: Bausch & Lomb Incorporated
    Inventor: Yu-Chin Lai
  • Patent number: 5449729
    Abstract: A novel class of compounds are disclosed which may be used as novel crosslinking agents for acrylic-containing, vinyl-containing and/or styrene-containing hydrophilic monomers to prepare novel UV-curable hydrophilic copolymers suitable for use as biomedical articles, especially contact lenses.
    Type: Grant
    Filed: February 14, 1994
    Date of Patent: September 12, 1995
    Assignee: Bausch & Lomb Incorporated
    Inventor: Yu-Chin Lai
  • Patent number: 5444129
    Abstract: A plurality of substituted styrene monomers, for example, urea substituted, is disclosed as well as polymers and copolymers made therefrom. Various thermoset plastic components can be reacted with the monomers, polymers, or copolymers of these substituted styrenes, as for example epoxy, which form a crosslinked system useful as an adhesive or a fiber reinforced substrate for circuit boards. The monomers are made by reacting aminostyrene type monomers with isocyanate containing molecules.
    Type: Grant
    Filed: January 11, 1995
    Date of Patent: August 22, 1995
    Assignee: Gould Inc.
    Inventor: David W. Kurz
  • Patent number: 5389699
    Abstract: UV-crosslinkable materials based on (meth)acrylate copolymers and containing from 0.01 to 10% by weight, based on the copolymer, of copolymerized monomers of the formula I ##STR1## where x is alkyl of 1 to 3 carbon atoms or is phenyl which is unsubstituted or substituted by n Y groups, Y is --H, --CF.sub.3, --O-- alkyl and/or alkyl-COO--, where alkyl in each case is of 1 to 4 carbon atoms, halogen, --CH, --COOH or a non-ortho --OH group, n is from 0 to 4 and Z is a group of the formula ##STR2## where R is H or C.sub.1 -C.sub.4 -alkyl and A is an alkylene, oxaalkylene or polyoxaalkylene radical of 2 to 12 carbon atoms are used as hotmelt adhesives, for coating sheet-like mineral substrates and as surface coatings.
    Type: Grant
    Filed: July 8, 1993
    Date of Patent: February 14, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerd Rehmer, Andreas Boettcher, Michael Portugall
  • Patent number: 5378734
    Abstract: A UV and moisture-curable organopolysiloxane composition comprising (i) an organopolysiloxane terminated with a radical of formula (1): ##STR1## wherein R.sup.1 is a hydrogen atom or monovalent hydrocarbon radical, each of R.sup.2 and R.sup.3 is a divalent hydrocarbon radical which may contain a NH bond or ether bond, each of R.sup.4 and R.sup.5 is a monovalent hydrocarbon radical which may contain an ether bond, and a is equal to 0 or 1, (ii) a photo-polymerization initiator, and (iii) a curing catalyst. The composition readily cures either upon exposure to UV radiation or upon contact with moisture and from the surface to the deep interior within a short time, yielding cured products having satisfactory physical properties.
    Type: Grant
    Filed: August 27, 1993
    Date of Patent: January 3, 1995
    Assignee: Shin-Etsu Chemical Company, Ltd.
    Inventor: Yoshio Inoue
  • Patent number: 5354495
    Abstract: A physical property-improving reagent which comprises an alkenoylcarbamate compound of the formula: ##STR1## wherein R is a hydrogen atom or a lower alkyl group, X is an oxygen atom (--O--), a sulfur atom (--S--) or a substituted or unsubstituted imino group (--NR'--), R' being a hydrogen atom or a lower alkyl group, and Y is the residue of an active hydrogen atom-containing compound excluding --X--H therefrom dissolved in an organic solvent having a solubility parameter of not less than 8, which can impart excellent physical properties to a polymer produced with the same.
    Type: Grant
    Filed: March 1, 1990
    Date of Patent: October 11, 1994
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Satoshi Urano, Ryuzo Mizuguchi, Noriyuki Tsuboniwa, Kei Aoki, Yuji Suzuki, Takeyasu Itoh
  • Patent number: 5310779
    Abstract: A novel class of compounds are disclosed which may be used as novel crosslinking agents for acrylic-containing, vinyl-containing and/or styrene-containing hydrophilic monomers to prepare novel UV-curable hydrophilic copolymers suitable for use as biomedical articles, especially contact lenses.
    Type: Grant
    Filed: July 30, 1992
    Date of Patent: May 10, 1994
    Assignee: Bausch & Lomb Incorporated
    Inventor: Yu-Chin Lai
  • Patent number: 5274061
    Abstract: The present invention provides novel polymerizable substituted amide compounds which are derived from isocyanate compounds and which are useful in the preparation of nonlinear optical materials. The polymerizable substituted amide compound of the present invention represents by the formula; ##STR1## wherein R and R.sup.1 respectively represent a hydrogen atom or a lower alkyl group, A represents --X--(CH.sub.2).sub.n -- in which X represents an oxygen atom or --NH-- and n is an integer of 1 to 6, and m shows 0 or 1. The present invention also provides a homo- or co-polymer derived from the polymerizable substituted amide compound. The present invention further provides a nonlinear optical composition containing the homo- or co-polymer.
    Type: Grant
    Filed: December 8, 1992
    Date of Patent: December 28, 1993
    Assignees: Nippon Paint Co., Ltd., Matsushita Electric Industrial Co., Ltd.
    Inventors: Satoshi Urano, Noriyuki Tsuboniwa, Tetsuji Kawakami, Katsuya Wakita
  • Patent number: 5270412
    Abstract: Dispersion polymers based on ethylenically unsaturated monomers, the polymers containing at least 1% by weight of specific monomer units of ethylenically unsaturated urea derivatives (see formula I), process for their preparation particularly by free-radical initiated emulsion, suspension or bead polymerization or copolymerization and their use as coating compositions, preferably in the form of aqueous dispersions, particularly as corrosion inhibiting metal coating compounds, moreover as adhesives, molded plastics and as binders, thickeners and auxiliaries in industrial chemical compositions.
    Type: Grant
    Filed: May 27, 1992
    Date of Patent: December 14, 1993
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Karl J. Rauterkus, Hans-Ullrich Huth, Karl-Hans Angelmayer
  • Patent number: 5264533
    Abstract: UV-crosslinkable materials based on (meth)acrylate copolymers and containing special modified unsaturated benzophenone derivatives as copolymerized units are used as hotmelt adhesives, for coating sheet-like mineral substrates and as surface coatings.
    Type: Grant
    Filed: August 1, 1991
    Date of Patent: November 23, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerd Rehmer, Andreas Boettcher, Michael Portugall
  • Patent number: 5242964
    Abstract: A process for the preparation of aqueous dispersions of magnetizable polymer particles with a narrow distribution from aqueous dispersions with a wide distribution. The amount of water in the aqueous dispersion with a wide distribution is adjusted so that the proportion by weight of magnetizable polymer particles is between about 1 and 40% of said dispersion. The surfactant concentration of the dispersion after the water adjustment is increased until two phases are obtained: a so-called liquid phase and a so-called solid phase. After separation of these two phases is accomplished, these steps are repeated as desired. An aqueous dispersion with a narrow size distribution is recovered.
    Type: Grant
    Filed: July 29, 1991
    Date of Patent: September 7, 1993
    Assignee: Rhone-Poulenc Chimie
    Inventors: Jerome Bibette, Dominique Charmot, Gilbert Schorsch
  • Patent number: 5239031
    Abstract: A heterofunctional macromer represented by the formula: ##STR1## in which R.sub.1 is H or C.sub.1 -C.sub.4 alkyl; R.sub.2 is a (poly) lactone or (poly) ether chain; X.sub.1 is --COO--, --COOCH.sub.2 CH.sub.2 OCO--, --CONHCOO--, --COOCH.sub.2 CH.sub.2 NH--COO-- ##STR2## X.sub.2 is --O--, --COO-- or --OCO--NH--R.sub.3 --NHCOO--group; R.sub.3 is C.sub.1 -C.sub.6 alkylene, aromatic or alicyclic group; A is --CH.sub.2 --, --C(CH.sub.3).sub.2 -- or ##STR3## and reactive polymers derived from said macromer.
    Type: Grant
    Filed: December 29, 1992
    Date of Patent: August 24, 1993
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Mitsuo Yamada, Kei Aoki
  • Patent number: 5239032
    Abstract: A heterofunctional macromer represented by the formula: ##STR1## in which R.sub.1 is H or C.sub.1 -C.sub.4 alkyl; R.sub.2 is a (poly) lactone or (poly) ether chain; X.sub.1 is --COO--, --COOCH.sub.2 CH.sub.2 OCO--, --CONHCOO--, --COOCH.sub.2 CH.sub.2 NH--COO-- or ##STR2## X.sub.2 is --O--, --COO-- or --OCO--NH--R.sub.3 --NHCOO-- group; R.sub.3 is C.sub.1 -C.sub.6 alkylene, aromatic or alicyclic group; A is --CH.sub.2 --, --C(CH.sub.3).sub.2 -- or ##STR3## and reactive polymers derived from said macromer.
    Type: Grant
    Filed: December 29, 1992
    Date of Patent: August 24, 1993
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Mitsuo Yamada, Kei Aoki
  • Patent number: 5212271
    Abstract: A process for texturing a coating via exposing a photocurable composition comprising a multifunctional urea compound, an ethylenically unsaturated compound, and an aromatic ketone photosensitizer that functions through a hydrogen abstraction mechanism when exposed to ultraviolet light.
    Type: Grant
    Filed: December 22, 1989
    Date of Patent: May 18, 1993
    Assignee: Texaco Chemical Company
    Inventors: Alison D. Beckett, Joseph V. Koleske, Richard M. Gerkin
  • Patent number: 5179184
    Abstract: The present invention relates to polymerizable cyclic urea derivatives which can be thermally split to give rise to an isocyanate group; and to a polymer having cyclic urea pendant groups, which can be cured by heating without any additional curing agent such as an isocyanate blocked with a volatile lower molecular weight material, so that volatile material is not released in a thermal curing process.
    Type: Grant
    Filed: April 10, 1991
    Date of Patent: January 12, 1993
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Noriyuki Tsuboniwa, Satoshi Urano, Hirotoshi Umemoto, Noriyuki Sakamoto, Kenshiro Tobinaga, Yasuyuki Tsuchiya
  • Patent number: 5151480
    Abstract: The invention relates to a process for the production of mouldings of crosslinked polymers by processing (moulding) of uncrosslinked copolymers of vinyl compounds and polymerisable silane compounds having 1 to 3 hydrolysable groups to give the desired mouldings and crosslinking of the copolymers in the mouldings by aftertreatment of the mouldings with acidic or alkaline aqueous solutions.
    Type: Grant
    Filed: June 3, 1991
    Date of Patent: September 29, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Podszun, Michael Muller, Wilfried Cramer, Bodo Rehbold
  • Patent number: 5149752
    Abstract: Certain novel cationic polyelectrolytes are useful as components of formulations for treating keratinaceous and proteinaceous substrates.
    Type: Grant
    Filed: February 16, 1990
    Date of Patent: September 22, 1992
    Assignee: Clairol Incorporated
    Inventors: Janusz Jachowicz, Chittamuru Ramireddy
  • Patent number: 5128386
    Abstract: UV-crosslinkable materials based on (meth)acrylate copolymers contain copolymerized monomers of the general formula I ##STR1## where R is a certain alkyl radical, an aryl radical or a radical R.sup.1 and R.sup.1 is a radical ##STR2## where R.sup.2 to R.sup.6 are each H, alkyl, a non-ortho OH group, OCH.sub.3, OC.sub.2 H.sub.3, SH, SCH.sub.3, Cl, F, CN, COOH, COO(C.sub.1 -C.sub.3 -alkyl), CF.sub.3, N(CH.sub.3).sub.2, N(C.sub.2 H.sub.5).sub.2, N(CH.sub.3)C.sub.6 H.sub.5, .sup.+ N(CH.sub.3).sub.3 X.sup.- or .sup.+N(CH.sub.3).sub.X X.sup.-, where X.sup.- is an acid anion, and one or more of the radicals R.sup.2 to R.sup.
    Type: Grant
    Filed: December 15, 1989
    Date of Patent: July 7, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerd Rehmer, Andreas Boettchher, Gerhard Auchter
  • Patent number: 5071902
    Abstract: A film-forming, self-crosslinking aqueous synthetic resin dispersion with reduced liberation of formaldehyde contains an emulsion polymer composed of(A) a major portion of an ethylenically unsaturated, free radically polymerizable monomer giving a polymer or copolymer with a glass transition temperature not exceeding 120.degree. C.,(B) N-methylolacrylamide or methacrylamide,(C) optionally further ethylenically unsaturated, free radically polymerizable monomers, and(D) an ethylenically unsaturated, free radically polymerizable monomer carrying a ureido group.
    Type: Grant
    Filed: January 23, 1990
    Date of Patent: December 10, 1991
    Assignee: Rohm GmbH
    Inventors: Klaus Langerbeins, Herbert Fink, Wolfgang Klesse, Dieter Tessmer
  • Patent number: 5070165
    Abstract: For filling and forming teeth, novel (meth)acrylic acid derivatives of triisocyanates of the formula ##STR1## wherein R.sup.1 and R.sup.2 are identical or different and stand for hydrogen or a lower alkyl radical,R.sup.3, R.sup.4 and R.sup.5 are identical or different and denote hydrogen or methyl,y.sup.1 to y.sup.3 are identical or different and denote divalent straight-chain or branched hydrocarbon radicals of 2 to 15 carbon atoms which may optionally include 1 to 3 oxygen bridges and which may be unsubstituted or substituted by 1 to 4 additional (meth)acryloyloxy radicals,X.sup.1 to X.sup.3 are identical or different and denote --NR.sup.1 -- or --O--, at least one of the radicals X.sup.1 to X.sup.3 denoting --NR.sup.1 --, and the ringsA and B are identical or different and may be aromatic or saturated.
    Type: Grant
    Filed: March 1, 1991
    Date of Patent: December 3, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Michael Muller, Wolfgang Podszun, Jens Winkel
  • Patent number: 5045616
    Abstract: Dispersion polymers based on ethylenically unsaturated monomers, the polymers containing at least 1% by weight of specific monomer units of ethylenically unsaturated urea derivatives (see formula I), process for their preparation particularly by free-radical initiated emulsion, suspension or bead polymerization or copolymerization and their use as coating compositions, preferably in the form of aqueous dispersions, particularly as corrosion inhibiting metal coating compounds, moreover as adhesives, molded plastics and as binders, thickeners and auxiliaries in industrial chemical compositions.
    Type: Grant
    Filed: May 19, 1989
    Date of Patent: September 3, 1991
    Assignee: Hoechst AG
    Inventors: Karl J. Rauterkus, Hans-Ullrich Huth, Karl-Hans Angelmayer
  • Patent number: 5037926
    Abstract: For filling and forming teeth, novel (meth)acrylic acid derivatives of triisocyanates of the formula ##STR1## wherein R.sup.1 and R.sup.2 are identical or different and stand for hydrogen or a lower alkyl radical,R.sup.3, R.sup.4 and R.sup.5 are identical or different and denote hydrogen or methyl,Y.sup.1 to Y.sup.3 are identical or different and denote divalent straight-chain or branched hydrocarbon radicals of 2 to 15 carbon atoms which may optionally include 1 to 3 oxygen bridges and which may be unsubstituted or substituted by 1 to 4 additional (meth)acryloyloxy radicals,X.sup.1 to X.sup.3 are identical or different and denote --NR.sup.1 -- or --O--, at least one of the radicals X.sup.1 to X.sup.3 denoting --NR.sup.1 --, and the ringsA and B are identical or different and may be aromatic or saturated.
    Type: Grant
    Filed: November 20, 1990
    Date of Patent: August 6, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Michael Muller, Wolfgang Podszun, Jens Winkel
  • Patent number: 5008436
    Abstract: For filling and forming teeth, novel (meth)acrylic acid derivatives of triisocyanates of the formula ##STR1## wherein R.sup.1 and R.sup.2 are identical or different and stand for hydrogen or a lower alkyl radical,R.sup.3, R.sup.4 and R.sup.5 are identical or different and denote hydrogen or methyl,Y.sup.1 to Y.sup.3 are identical or different and denote divalent straight-chain or branched hydrocarbon radicals of 2 to 15 carbon atoms which may optionally include 1 to 3 oxygen bridges and which may be unsubstituted or substituted by 1 to 4 additional (meth)acryloyloxy radicals,X.sup.1 to X.sup.3 are identical or different and denote --NR.sup.1 -- or --O--, at least one of the radicals X.sup.1 to X.sup.3 denoting --NR.sup.1 --, and the ringsA and B are identical or different and may be aromatic or saturated.
    Type: Grant
    Filed: May 1, 1990
    Date of Patent: April 16, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Michael Muller, Wolfgang Podszun, Jens Winkel
  • Patent number: 4996243
    Abstract: A composition of matter comprising an acrylamido-acyl or methacrylamido-acyl oligomer derived from at least one nucleophilic oligomer having at least one amino-, hydroxyl-, or thiol-substituted polyoxyalkylene, polyalkyleneimine, polyester, polyolefin, polyacrylate, or polysiloxane oligomer, said nucleophilic oliogmer having a molecular weight in the range of 200 to 20,000 is disclosed. Also disclosed are free radially polymerizable monomer-containing compositions containing said oligomers as well as acrylamido- and methacrylamido-acylated polymers which are the thermal or photocured products of said oligomers. In addition, a process is disclosed for providing said acrylamido- and methacrylamido-acylated oligomers which are useful, for example, in coatings, films, printing inks, adhesives, and saturants.
    Type: Grant
    Filed: January 16, 1990
    Date of Patent: February 26, 1991
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Jerald K. Rasmussen, Steven M. Heilmann, Frederick J. Palensky
  • Patent number: 4985522
    Abstract: There is disclosed a family of new vinyl monomers capable of forming polymers by free radical polymerization. The vinyl monomer is of the formula ##STR1## wherein R.sub.1 and R.sub.2 are substituted or unsubstituted hydrocarbons, X is O, NH or NR.sub.3, and R.sub.3 is substituted or unsubstituted hydrocarbon.The intermediates in the synthesis of these monomers are new beta-chloroanaline ureas. The polymers are useful in film and fiber formation and display good toughness. These new vinyl monomers also form a cyclic monomer.
    Type: Grant
    Filed: December 19, 1989
    Date of Patent: January 15, 1991
    Assignee: The University of Southern Mississippi
    Inventors: Lon J. Mathias, David W. Kurz
  • Patent number: 4962168
    Abstract: A flame-retardant TAIC is polymerized in the presence of a polymerization modifier and a polymerization initiator. As the polymerization modifier, 6H-dibenz [c,e] [1,2] oxaphosphorine-6-oxide is used in an amount of 1 to 200% by weight on the basis on the weight of triallyl isocyanurate.
    Type: Grant
    Filed: January 2, 1990
    Date of Patent: October 9, 1990
    Assignee: 501 Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Satoshi Hiratsuna, Hiroshi Hotta, Hayashi Tomomi, Hayashi Tomomi
  • Patent number: 4952622
    Abstract: Polymer particles which carry, implanted on their surface, amphiphilic molecules carrying ion-forming or reactive groups, and dispersions thereof, which may be prepared by contacting a latex of particles of a polymer having a glass transition temperature Tg greater than about 40.degree. C., with an amphiphilic compound having an HLB greater than or equal to 10 and a molecular weight greater than or equal to 400. The contacting is carried out at a temperature within the glass transition zone of the polymer, until enmeshing of the polymer chains and of the hydrophobic blocks of the amphiphilic compound has been achieved. The hydrophilic block of the amphiphilic compound carries at least one ion-forming or reactive group. The particles and their dispersions are useful in biological applications.
    Type: Grant
    Filed: May 6, 1988
    Date of Patent: August 28, 1990
    Assignee: Rhone Poulenc Chimie
    Inventors: Bernard Chauvel, Jean-Claude Daniel, Christian Pusineri
  • Patent number: 4933390
    Abstract: A composition, useful for forming absorbent articles of a carboxylic polyelectrolyte, is prepared by copolymerizing a carboxylic polyelectrolyte monomer, a reactive self-crosslinking monomer and a hydrophobic monomer. The composition in the form of an emulsion or a viscous solution has an extendable shelf life and may be used to produce a superabsorbent material or a substrate impregnated with a superabsorbent material.
    Type: Grant
    Filed: August 17, 1987
    Date of Patent: June 12, 1990
    Inventors: Shmuel Dabi, Jayson C. Vassallo
  • Patent number: 4929662
    Abstract: Polymer particles possessing, implanted on their surface, amphiphilic molecules carrying ion-forming or reactive groups, and dispersions thereof, prepared by diffusing, into a previously prepared aqueous seeding dispersion of polymer particles, an organosoluble polymerization initiator, swelling the particles of the dispersion thus obtained by introducing a monomer composition comprising at least one monomer and at least one amphiphilic compound, and polymerizing the monomer composition.
    Type: Grant
    Filed: May 6, 1988
    Date of Patent: May 29, 1990
    Assignee: Rhone-Poulenc Chimie
    Inventors: Roger Hogenmuller, Bernard Chauvel, Jean-Claude Daniel
  • Patent number: 4920190
    Abstract: The invention relates to fluorinated acrylic monomers of the formula: ##STR1## in which A and W denote divalent linkages, R is a hydrogen atom or a methyl radical, R.sub.F is a perfluoroalkyl radical and Q denotes an oxygen or sulphur atom or the group --NR'--, where R' denotes a hydrogen atom or an alkyl radical. Homo-or copolymers derived from these monomers are useful for the water or oil-repellent treatment of various substrates, particularly leather.
    Type: Grant
    Filed: June 21, 1988
    Date of Patent: April 24, 1990
    Assignee: Atochem
    Inventors: Marie-Jose Lina, Andre Dessaint
  • Patent number: 4906715
    Abstract: The invention relates to crosslinked polymers based on polyvinyl acylate or polyvinyl alcohol and having crosslinking agent units which are derived from crosslinking agents of the general formulae ##STR1## and/or ##STR2## These products, inter alia, are particularly hydrolysis-resistant and can have high crosslinking densities.The invention also relates to a process for preparing these polymers and to their use in chromatography and as carriers for biologically active substances.
    Type: Grant
    Filed: December 8, 1987
    Date of Patent: March 6, 1990
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Otto Mauz, Siegfried Noetzel, Bernhard Neumann
  • Patent number: 4861853
    Abstract: Isocyanate functional polymers useful as crosslinking agents or as moisture curing polymers, which comprise the addition polymerization reaction product of:(a) 1 to 100% by weight of at least one isocyanate functional ethylenically unsaturated monomer which comprises the reaction product obtained by the gradual addition of an ethylenically unsaturated monomer having a single active hydrogen to a diisocyanate selected from the group consisting of isophorone diisocyanate and 2,4 toluene diisocyanate wherein the final molar ratio of active hydrogen containing monomer to diisocyanate is essentially 1 to 1; and(b) 0 to 99% by weight of at least one ethylenically unsaturated monomer which is free of active hydrogen functionality and which is copolymerizable with the ethylenically unsaturated isocyanate functional monomer.
    Type: Grant
    Filed: December 27, 1985
    Date of Patent: August 29, 1989
    Assignee: The Sherwin-Williams Company
    Inventors: Brian C. Petrie, Thomas W. Druetzler, Rodney M. Harris
  • Patent number: 4853478
    Abstract: This invention is directed to the preparation of polymerizable monomers that are prepared from 1-(1-isocyanato-1-methylethyl)-3-(1-methylethenyl) benzene (m-TMI) and 1-(1-isocyanato-1-methylethyl)-4-(1-methylethenyl) benzene (p-TMI). The monomers prepared from m- and p-TMI can contain numerous chemical moieties, and when polymerized, produce polymers that have chemically bonded to the polymeric backbone the functional moiety. More specifically, these TMI derived monomers may contain chain breaking antioxidant moieties, peroxide decomposing antioxidant moieties, ultraviolet stabilizing moieties, triplet quenching moieties, and other chemical moieties that are useful in polymers.
    Type: Grant
    Filed: February 18, 1987
    Date of Patent: August 1, 1989
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Howard A. Colvin, Kirkwood S. Cottman, Dane K. Parker
  • Patent number: 4816537
    Abstract: A blocked isocyanatocarbonyl group-containing polymer which comprises a carbon-carbon backbone chain and at least one blocked isocyanatocarbonyl group and at least one active hydrogen-containing group or an acidic or basic group and has a molecular weight of 1,000 to 100,000, the contents of said blocked isocyanatocarbonyl group and said active hydrogen-containing group or said acidic or basic group being respectively from 1 to 99% by weight and from 0.1 to 90% by weight or from 1 to 90% by weight on the weight of the polymer, which is useful as a resin component in a coating agent, an adhesive agent or the like.
    Type: Grant
    Filed: April 22, 1987
    Date of Patent: March 28, 1989
    Assignee: Nippon Paint Co., LTD.
    Inventors: Noriyuki Tsuboniwa, Satoshi Urano, Ryuzo Mizuguchi
  • Patent number: 4806574
    Abstract: An ultraviolet curing liquid coating composition which, when cured with ultraviolet light in the presence of an appropriate photoinitiator, provides a coating adapted for the coating of optical glass fiber. This coating composition comprises as the essential component, an acrylate-terminated polyurethane oligomer based on a polyfunctional core which is at least trifunctional and which supports one branch for each functionality in the core. Each of the branches leads to an acrylate-functional terminal group, with there being from about 150 to about 2500 units of molecular weight in each branch between the trifunctional core and the acrylate-functional terminal group. Depending primarily upon the molecular weight of the branches, one can provide coating compositions for buffer coat, single coat or topcoat use.
    Type: Grant
    Filed: July 22, 1985
    Date of Patent: February 21, 1989
    Assignee: DeSoto, Inc.
    Inventors: John J. Krajewski, Timothy E. Bishop, Clive J. Coady, John M. Zimmerman, Gerry K. Noren, Christopher E. Fisher
  • Patent number: 4786657
    Abstract: A crosslinkable polyurethane or polyurethane/polyurea comprises the reaction product of a composition comprising a macrodiol or macrodiamine, 2-gl;yceryl acrylate or 2-glyceryl methacrylate, a diisocyanate, and optionally a small glycol or small diamine as chain extender. The performance properties of the polyurethanes and polyurethane/polyureas can be controlled by adjustment of the crosslink level and/or curing parameters.
    Type: Grant
    Filed: July 2, 1987
    Date of Patent: November 22, 1988
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: W. James Hammar, John S. Staral
  • Patent number: 4767620
    Abstract: Crosslinked polymers which are produced from monomers containing glycerol carbonate groups, crosslinking monomers and, where appropriate, other monoethylenically unsaturated monomers are composed of principally spherical porous particles and are very suitable as carrier materials for the immobilization of biologically active substances.
    Type: Grant
    Filed: August 26, 1987
    Date of Patent: August 30, 1988
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Otto Mauz, Siegfried Noetzel, Klaus Sauber
  • Patent number: 4749592
    Abstract: A grouting composition for sealing structures to inhibit water leakage therethrough and for stabilizing soil is provided. The composition is provided as a two-part system. Part A is an aqueous solution of a hydrophililc, water soluble prepolymer having a polyether backbone and terminal active olefinic groups, the olefinic groups being connected to the polyether backbone by linking groups selected from --NH--, --CONH--, --OCONH--, and --NHCONH--, and tertiary amine catalyst. Part B is an aqueous solution of a initiator. Parts A and B are mixed and react to form a gel.
    Type: Grant
    Filed: September 11, 1986
    Date of Patent: June 7, 1988
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Alton J. Gasper, Charles D. Wright
  • Patent number: 4742147
    Abstract: Liquid, solventless, complex polymeric compositions are provided which thermoset at ambient temperatures through addition polymerization. In a preferred embodiment, a two component system includes a first component comprising amine or acrylate terminated polyurethanes, polyurethane-ureas or polyureas and a second component comprising di or polyacrylates. By adding an excess of acrylate, a one component system can be formed which thermosets when exposed to ultraviolet radiation.
    Type: Grant
    Filed: October 11, 1985
    Date of Patent: May 3, 1988
    Inventor: Gus Nichols
  • Patent number: 4727126
    Abstract: Compounds are disclosed having the structure ##STR1## wherein A represents arylene or carboxyl;R represents H or CH.sub.3 ; andR.sub.2 and R.sub.3, each independently, represents alkylene of 2 to 7 carbon atoms.The compounds are useful in making curable polyurethane, polyesters and vinyl polymers.
    Type: Grant
    Filed: November 4, 1986
    Date of Patent: February 23, 1988
    Assignee: Eastman Kodak Company
    Inventor: Tsang J. Chen
  • Patent number: 4722965
    Abstract: A chalk-adhesion polymer latex for exterior coatings especially suitable for blending with an acrylic formulation, such as vinyl acetate/ acrylic copolymers. The polymer is derived from a monomer precursor composition, including an acrylic moiety, such as an acrylate and a methacrylate, together with small amounts of a nitrogen-containing alkyl acrylate, an acrylamide and propylene glycol. The method of preparing the chalk adhesion polymer includes emulsification stages to accomplish the polymerization.
    Type: Grant
    Filed: February 24, 1986
    Date of Patent: February 2, 1988
    Assignee: Reichhold Chemicals, Inc.
    Inventors: Kian C. Wong, Patrick J. McDonald, Stanley J. Gromelski, Jr.
  • Patent number: 4694041
    Abstract: The invention relates to the use of novel N,N-disubstituted arylamines containing polymerizable groups as hardening accelerators for polymerizable compositions based on unsaturated polyester resins, in particular for trowelling and water compositions.
    Type: Grant
    Filed: August 14, 1986
    Date of Patent: September 15, 1987
    Assignee: Bayer Aktiengesellschaft
    Inventors: Helmut-Martin Meier, Rolf Dhein, Jens Winkel, Gerhard Klein, Werner Kloker
  • Patent number: 4690995
    Abstract: Copolymers comprising 0.10 to 50 parts by weight of hindered phenol antioxidant monomer and at least 10 to 60 parts by weight of at least one unsaturated carboxylic acid monomer are prepared, preferably in emulsion polymerization systems.
    Type: Grant
    Filed: June 6, 1985
    Date of Patent: September 1, 1987
    Assignee: The Dow Chemical Company
    Inventors: William H. Keskey, Mark R. Johnson
  • Patent number: 4663409
    Abstract: Inclusion of carbonyl modified amino acid monomers in polymeric compositions for biomedical applications, including contact lenses, increases the water content and oxygen permeability of the polymer without significant changes in other desirable properties of the polymer.
    Type: Grant
    Filed: December 24, 1984
    Date of Patent: May 5, 1987
    Assignee: Bausch & Lomb Incorporated
    Inventors: Gary D. Friends, Richard C. Chromecek, Raymond A. Yourd, III
  • Patent number: 4608420
    Abstract: Process for the preparation of acylurethanes by reacting a urethane with compounds containing hydroxyl groups, which comprises reacting a hydroxy compound (A) with a urethane (B) in the form of an imide of the formula ##STR1## to give an acylurethane containing at least one grouping of the formula --CO--R--CO--NH--COOR.sup.1 (II). In these formulae,R denotes the hydrocarbon radical of an optionally .alpha.,.beta.-ethylenically unsaturated, aliphatic, cycloaliphatic or aromatic dicarboxylic acid or endomethylene derivatives thereof, andR.sup.1 denotes alkyl, alkoxy, alkoxyalkyl, cycloalkyl or benzyl.These acylurethanes are suitable for use as self-crosslinking curing agents or as curing agents for polyhydroxy compounds for the production of shaped articles and/or coatings.
    Type: Grant
    Filed: June 6, 1985
    Date of Patent: August 26, 1986
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Gerhard Brindopke, Gerhard Johannes
  • Patent number: 4604439
    Abstract: This invention is directed to the preparation of polymerizable monomers that are prepared from 1-(1-isocyanato-1-methylethyl)-3-(1-methylethenyl) benzene (m-TMI) and 1-(1-isocyanato-1-methylethyl)-4-(1-methylethenyl) benzene (p-TMI). The monomers prepared from m- and p-TMI can contain numerous chemical moieties, and when polymerized, produce polymers that have chemically bonded to the polymeric backbone the functional moiety. More specifically, these TMI derived monomers may contain chain breaking antioxidant moieties, peroxide decomposing antioxidant moieties, ultraviolet stabilizing moieties, triplet quenching moieties, and other chemical moieties that are useful in polymers.
    Type: Grant
    Filed: May 28, 1985
    Date of Patent: August 5, 1986
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Howard A. Colvin, Kirkwood S. Cottman, Dane K. Parker
  • Patent number: 4571418
    Abstract: The char residue formation of molded compositions, upon combustion, is improved by incorporating into the moldable composition a char-forming polymer containing recurring units of at least one monomer capable of undergoing tautomerization, at least one monomer capable of undergoing a nucleophilic substitution reaction by said monomer capable of undergoing tautomerization and, optionally, at least one additional copolymerizable monomer.
    Type: Grant
    Filed: March 12, 1984
    Date of Patent: February 18, 1986
    Assignee: Atlantic Richfield Company
    Inventor: Usama E. Younes
  • Patent number: 4472019
    Abstract: Radiation-curable coating compositions adapted for application to buffer-coated optical fibers are disclosed. These are intended to apply an adherent topcoat having greater toughness and greater hardness than the buffer coating. The new compositions comprise: (1) from 25% to 70% of diethylenic-terminated polyurethane, which may include urea linkages, the polyurethane being based on a diisocyanate having an average molecular weight of from 400 to 5000; (2) from 5% to 40% of a diethylenically unsaturated ester of a diglycidyl ether of a bisphenol, said ether having a molecular weight up to about 1000; and (3) from 5% to 30% of liquid radiation-curable monoethylenically unsaturated monomer having a T.sub.g above about 55.degree. C., especially N-vinyl pyrrolidone. Ultraviolet cures using acrylates as the ethylenic group are preferred.
    Type: Grant
    Filed: December 28, 1982
    Date of Patent: September 18, 1984
    Assignee: DeSoto, Inc.
    Inventors: Timothy E. Bishop, George Pasternack, Orvid R. Cutler, Jr.
  • Patent number: 4451627
    Abstract: An addition polymerizable adhesive is prepared by using the reaction product of (1) an isocyanate compound (such as 2-isocyanatoethyl methacrylate) and (2) an active hydrogen compound (such as a poly(ethylene glycol)) wherein the reaction between (1) and (2) is catalyzed with a tin (II) organoester (such as stannous octoate). The adhesives of the invention have surprisingly long shelf lives compared to similar adhesives made with other catalysts.
    Type: Grant
    Filed: September 7, 1982
    Date of Patent: May 29, 1984
    Assignee: The Dow Chemical Company
    Inventors: Kurt C. Frisch, Jr., Michele R. Lock, Gregory J. Stuk
  • Patent number: 4429096
    Abstract: A meta- or para-compound of the formula: ##STR1## wherein: X.crclbar. is an anion selected from the group consisting of R.sub.4 OSO.sub.3 .crclbar., Cl.crclbar., Br.crclbar. and I.crclbar.;A is -O- or ##STR2## wherein: n is 2 or 3;R.sub.1, R.sub.2 and R.sub.3 which may be the same or different, are lower alkyl; andR.sub.4 is lower alkyl or allyl.Also disclosed is a method of making the compound by reacting meta- or para-isopropenyl-.alpha.,.alpha.-dimethylbenzyl isocyanate with either an amino alcohol or a dialkylaminoethyleneamine, and quaternzing the reaction product with an alkylating agent. The compound may be polymerized with a co-monomer such as acrylamide to yield water-soluble cationic polymers for use in water clarification, flocculation, and hair spray applications.
    Type: Grant
    Filed: June 1, 1983
    Date of Patent: January 31, 1984
    Assignee: American Cyanamid Company
    Inventor: Frederic C. Schaefer