From Nitrogen Containing Monomer Other Than Acrylonitrile Or Methacrylonitrile Patents (Class 526/310)
  • Patent number: 7332553
    Abstract: The present invention refers to new classes of polymerisable monomers, to molecularly imprinted polymers obtainable by polymerisation of at least one of the monomers and a crosslinking monomer in the presence of a template molecule. The obtained polymers may be used for separation of enantiomers, diastereomers of the template molecule, and also for separation of the template molecule or template molecule analogues from structurally related compounds.
    Type: Grant
    Filed: November 15, 2006
    Date of Patent: February 19, 2008
    Assignee: MIP Technologies AB
    Inventors: Börje Sellergren, Andrew Hall, Karine Chenon, Rohini Karmalkar
  • Patent number: 7309757
    Abstract: Provided is a poly(amino ester) having a polymer backbone comprising at least one secondary amine linkage and at least one tertiary amine linkage in the polymer backbone. Poly(amino ester)s are prepared via the Michael addition of a bis(acrylate ester)monomer to a diamine monomer, wherein the diamine monomer has one primary amino group and one secondary amino group, and can be end-capped by reaction with a suitable reagent. The inventive poly(amino ester)s may be used as vectors for delivery of a bioactive agent, such as DNA, to a cell.
    Type: Grant
    Filed: June 20, 2003
    Date of Patent: December 18, 2007
    Assignee: Agency for Science, Technology and Research
    Inventors: Ye Liu, Shu Wang, Chaobin He
  • Patent number: 7304117
    Abstract: Novel azo-based reactive yellow dyes and a process for manufacturing and using ocular devices having blue light absorption properties. Intraocular lenses so produced block blue light from reaching the retina of an eye implanted with the IOL. By blocking blue light from reaching the retina, the IOL thereby prevents potential damage to the retina.
    Type: Grant
    Filed: June 21, 2006
    Date of Patent: December 4, 2007
    Assignee: Bausch & Lomb Incorporated
    Inventor: Yu-Chin Lai
  • Patent number: 7300990
    Abstract: Polymers may be made from zwitterionic monomers having controlled architectures and molecular weights, using living polymerisations such as group or atom transfer radical polymerisation. For instance polymers may be formed by atom transfer radical polymerisation using a copper chloride catalyst, a ligand which is water soluble, and a water soluble tertiary alkyl halide initiator to form homopolymers having controlled polydispersities of less than 1.5 and block copolymers with other hydrophilic or hydrophobic monomers. One suitable zwitterionic monomer is 2-methacryloyloxy-2?-trimethylammoniumethyl phosphate inner salt. The block copolymers may spontaneously form micelles, believed to have zwitterionic, for instance phosphorylcholine, groups at the external surface, which may be useful as drug delivery systems with improved biocompatibility.
    Type: Grant
    Filed: January 3, 2005
    Date of Patent: November 27, 2007
    Assignee: Biocompatibles UK Limited
    Inventors: Andrew Lennard Lewis, Sean Leo Willis, Steven Peter Armes, Emma Janice Lobb, Yinghua Ma
  • Patent number: 7297463
    Abstract: A photosensitive polymer for forming high-resolution fine circuit patterns with an exposure light source of a short wavelength, and a chemically amplified photoresist composition including the polymer, are disclosed. The photosensitive polymer is represented by the following Formula 1, wherein R1 is a hydrogen atom, R2 is a hydrogen atom, R3 is a chlorine atom, a bromine atom, hydroxy, cyano, t-butoxy, CH2NH2, CONH2, CH?NH, CH(OH)NH2 or C(OH)?NH group, R4 is a hydrogen atom or methyl group, each of 1-x-y-z, x, y and z is a degree of polymerization of each repeating unit constituting the photosensitive polymer, x, y and z are 0.01 to 0.8, respectively, and n is 1 or 2.
    Type: Grant
    Filed: June 2, 2005
    Date of Patent: November 20, 2007
    Assignee: Dongjin Semichem Co., Ltd.
    Inventors: Deog-Bae Kim, Sang-Jeoung Kim, Hwa-Young Kim, Jin Jegal, Jae-Hyun Kim
  • Patent number: 7288613
    Abstract: The present invention relates to selected 1-alkoxy-2,2,6,6 tetramethyl piperidine, 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 dimethyl piperidine derivatives which are substituted in the 4 position by two oxygen atoms forming an open chain or cyclic ketal structure, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) said piperidine derivatives. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-2,2,6,6 tetramethyl piperidine, 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 dimethyl piperidine derivatives which are substituted in the 4 position by two oxygen atoms forming an open chain or cyclic ketal structure for controlled polymerization.
    Type: Grant
    Filed: February 28, 2006
    Date of Patent: October 30, 2007
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Peter Nesvadba, Marie-Odile Zink, Wiebke Wunderlich
  • Patent number: 7285368
    Abstract: Novel ester compounds having a sulfonamide structure are polymerizable into polymers having improved transparency at wavelength of up to 300 nm, especially ArF excimer laser light, and dry etching resistance. Resist compositions comprising the polymers are sensitive to high-energy radiation, have a high resolution, and lend themselves to micropatterning with electron beams or deep-UV rays.
    Type: Grant
    Filed: June 10, 2004
    Date of Patent: October 23, 2007
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Takeru Watanabe, Takeshi Kinsho
  • Patent number: 7279540
    Abstract: A precursor composition capable to form a solid-state electrolyte having good ion conductivity and high heat-resistance, by simple curing procedure, comprising; (A) a polymerizable ion pair compound represented by formula I, (B) a cross-linker having two or more unsaturated groups co-polymerizable with the polymerizable ion pair compound (A), and (C) non-polymerizable ion pair compound. Each of R1, R2, R3, R4, R5 and R6 represents hydrogen atom, alkyl or aryl group having 1-12 carbon atoms; and each of R7 and R8 represents alkyl or aryl group having 1-12 carbon atoms.
    Type: Grant
    Filed: July 18, 2005
    Date of Patent: October 9, 2007
    Assignee: Dai-ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Manabu Kikuta, Akiyoshi Hatakeyama
  • Patent number: 7279505
    Abstract: The present invention provides a radiation-curable prepolymer. The radiation-curable prepolymer of the invention is prepared by reacting an isocyanate-capped polyurethane with an ethylenically unsaturated amine or an ethylenically unsaturated monohydroxy compound or a mixture thereof, wherein the isocyanate-capped polyurethane is a copolymerization production of: (a) at least one polyalkylene glycol; (b) at least one branching agent having at least three hydroxy groups; and (c) at least one di- or polyisocyanate. The radiation-curable prepolymer of the invention can find use in economically producing contact lenses which have durable, highly elastic soft contact lenses with desired physical properties. In addition, the present invention provides method for making a radiation-curable prepolymer of the invention and for making a medical device, preferably an ophthalmic device, more preferably a contact lens.
    Type: Grant
    Filed: October 5, 2005
    Date of Patent: October 9, 2007
    Assignee: Novartis AG
    Inventors: John Christopher Phelan, Michael Hugh Quinn, Joshua Andrew Wallach
  • Patent number: 7270727
    Abstract: Sized paper containing an amphoteric promoter resin that is a polymerization reaction product of a quaternary diallylammonium monomer, optionally a diallylammonium monomer, and an unsaturated organic acid is described. The method of sizing paper with such amphoteric promoter resin compound and a sizing agent provides sized paper with significantly improved sizing property characteristics, and the sized paper exhibits superior retention of brightness due to added optical brighteners.
    Type: Grant
    Filed: April 28, 2003
    Date of Patent: September 18, 2007
    Assignee: Hercules Incorporated
    Inventor: Daniel F. Varnell
  • Patent number: 7267924
    Abstract: Disclosed herein are a top anti-reflective coating polymer used in a photolithography process, which is one of the fabrication processes for a semiconductor device, a method for preparing the anti-reflective coating polymer, and an anti-reflective coating composition comprising the anti-reflective coating polymer. Specifically, the top anti-reflective coating polymer is used in immersion lithography for the fabrication of a sub-50 nm semiconductor device. The top anti-reflective coating polymer is represented by Formula 1 below: wherein R1, R2 and R3 are independently hydrogen or a methyl group; and a, b and c represent the mole fraction of each monomer, and are in the range between about 0.05 and about 0.9. Since a top anti-reflective coating formed using the above anti-reflective coating polymer is not soluble in water, it can be applied to immersion lithography using water as the medium for a light source.
    Type: Grant
    Filed: April 5, 2005
    Date of Patent: September 11, 2007
    Assignee: Hynix Semiconductor Inc.
    Inventor: Jae-chang Jung
  • Patent number: 7264866
    Abstract: The object of the present invention is to provide a laminated film excellent in light resistance, scratch resistance, transparency, dimensional stability and adhesion to a hard coating layer. The present invention is a laminated film comprising a base material layer, an easily adhering layer and a hard coating layer, wherein the easily adhering layer is formed on the base material layer and the hard coating layer is formed on the easily adhering layer, and further wherein (1) the base material layer is formed of a polyester resin formed from naphthalenedicarboxylic acid as a main dicarboxylic acid component and ethylene glycol as a main glycol component, (2) the hard coating layer has an ultraviolet absorbing function and has a pencil hardness of H or higher on the hard coating layer surface, and (3) said laminated film has a variation (?b*) of less than 2.0 between transmittance b* values obtained before and after a 300 hours' xenon arc test of said laminated film.
    Type: Grant
    Filed: January 20, 2004
    Date of Patent: September 4, 2007
    Assignee: Teijin Dupont Films Japan Limited
    Inventors: Katsuyuki Hashimoto, Makoto Handa
  • Publication number: 20070203313
    Abstract: A material which expresses its critical solution temperature even in an aqueous solution containing a buffer or salt, and at the same time, shows small variation width of the critical solution temperature even when concentration of salt or the like contained in water, a buffer liquid or the like is different, interacts with a substance such as a component in the living body and can therefore be used efficiently in the isolation of substances, is provided. A monomer represented by a formula (1) and a thermoresponsive polymer which contains said monomer as a polymerization component.
    Type: Application
    Filed: February 27, 2007
    Publication date: August 30, 2007
    Applicant: CHISSO CORPORATION
    Inventors: Hirokazu NAGAOKA, Noriyuki OHNISHI, Masaru EGUCHI
  • Patent number: 7258932
    Abstract: A polymeric fluorescent substance exhibiting visible fluorescence in the solid state, having polystyrene reduced number average molecular weight of 1×103 to 1×108, and comprising one or more repeating units of following formula (1), wherein Ar1 and Ar2 each independently represent an arylene group or the like; Ar3 represents an aryl group or the like having one or more substituents of formula (2) as nuclear substitution; X represents —CR1?CR2— or —C?C—; and n is 0 or 1, —Y—Ar4 ??(2) wherein Ar4 represents an aryl group or the like; and Y represents —CR3?CR4— or —C?C—. The triarylamine type polymeric fluorescent substance is excellent in quantum yield of fluorescence and in light emitting efficiency when made into a device.
    Type: Grant
    Filed: July 12, 2002
    Date of Patent: August 21, 2007
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Takanobu Noguchi, Shuji Doi
  • Patent number: 7259218
    Abstract: Processes for making temporary wet strength additives, more particularly, processes for oxidizing a homo-crosslinking monomeric unit present in a polymer comprising the homo-crosslinking monomeric unit and a cationic monomeric unit to produce a temporary wet strength additive are provided.
    Type: Grant
    Filed: February 17, 2005
    Date of Patent: August 21, 2007
    Assignee: The Procter + Gamble Company
    Inventors: Robert Lee Barcus, Khosrow Parviz Mohammadi
  • Patent number: 7256245
    Abstract: Provided is a polymeric fluorescent substance showing fluorescence in solid state, which has a specific carrier drift mobility, a specific repeating unit, and specific number-average molecular weight. The polymeric fluorescent substance is excellent in solubility to organic solvents, and has higher efficiency and longer lifetime in applying as a polymer LED.
    Type: Grant
    Filed: June 9, 2003
    Date of Patent: August 14, 2007
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Masato Ueda, Takanobu Noguchi
  • Patent number: 7217776
    Abstract: The present invention provides novel gel forming methacrylic blocking copolymers that exhibit cationic pH-sensitive behavior as well as good water solubility. The copolymers are constructed by polymerization of a tertiary amine methacrylate with either a (poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide) polymer, such as the commercially available Pluronic® polymers, or a poly(ethylene glycol)methyl ether polymer. The polymers may be used for drug and gene delivery, protein separation, as structural supplements, and more.
    Type: Grant
    Filed: February 14, 2003
    Date of Patent: May 15, 2007
    Assignee: Iowa State University Research Foundation
    Inventors: Surya K. Mallapragada, Brian C. Anderson
  • Patent number: 7183369
    Abstract: The present invention provides novel block copolymers as structural supplements for injectible bodily prosthetics employed in medical or cosmetic procedures. The invention also includes the use of such block copolymers as nucleus pulposus replacement materials for the treatment of degenerative disc disorders and spinal injuries. The copolymers are constructed by polymerization of a tertiary amine methacrylate with either a (poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide) polymer, such as the commercially available Pluronic® polymers, or a poly(ethylene glycol) methyl ether polymer.
    Type: Grant
    Filed: February 14, 2003
    Date of Patent: February 27, 2007
    Assignee: Iowa State University Research Foundation, Inc.
    Inventors: Surya K. Mallapragada, Brian C. Anderson
  • Patent number: 7160953
    Abstract: A biocompatibilizing process in which a substrate having a surface which bears substrate pendant functional groups is biocompatibilized by coating it with a coating composition containing a polymer formed from a radical polymerizable monomers including a radical polymerisable zwitterionic monomer and a radical polymerizable monomer containing a reactive group to form a polymer having zwitterionic groups and pendant reactive groups and the said pendant reactive groups are reacted to form covalent bonds with said substrate pendant functional group and thereby form a stable coating of polymer on the said surface.
    Type: Grant
    Filed: March 10, 2004
    Date of Patent: January 9, 2007
    Assignee: Biocompatibles UK Limited
    Inventors: Roderick William Jonathon Bowers, Stephen Alister Jones, Peter William Stratford
  • Patent number: 7160634
    Abstract: An organic electroluminescent device having an organic layer between a pair of electrodes. The organic layer (in particular, a hole-transporting layer) has a polymer of a vinyl compound represented by the following formula (1): wherein R1 and R2 are the same or different, each representing a hydrogen atom, a halogen atom, an alkyl group or an alkoxy group. The glass transition temperature of the polymer is about 200 to 250° C., and the polymer has high heat-resistance. Thus, the use of the polymer improves heat resistance of an organic EL device.
    Type: Grant
    Filed: October 14, 2005
    Date of Patent: January 9, 2007
    Assignees: Daicel Chemical Industries, Ltd.
    Inventors: Yasuhiko Shirota, Yutaka Ohsedo, Kazuyuki Moriwaki, Kenji Okumoto
  • Patent number: 7138471
    Abstract: A hydrophilic ethylenically unsaturated macromonomer is disclosed that is prepared by the addition polymerization of addition polymerizable monomers that include monomers that have hydroxyl or amino functional groups, some of which may be subsequently reacted to provide (meth)acryl ethylenic unsaturation. The macromonomers may be used to form intraocular lenses in situ by polymerization of the macromonomers, and thus treat presbyopia.
    Type: Grant
    Filed: July 22, 2004
    Date of Patent: November 21, 2006
    Assignee: Commonwealth Scientific and Industrial Research Organisation
    Inventors: Anthony Brian Clayton, Timothy Charles Hughes, Peter Agapitos Kambouris, Gordon Francis Meijs
  • Patent number: 7101630
    Abstract: An organic electroluminescent device is provided which has a high degree of adhesion between an anode and a hole transport layer, the device emitting light of high luminance even when driven by low applied voltages. Copolymers useful in hole transport layers in organic electroluminescent devices are also provided. Methods of producing hole transport layers for organic electroluminescent devices which can emit light of high luminance even when driven by low applied voltages are also provided, the hole transport layers having high degrees of adhesion with anode. A copolymer comprises a monomer unit including in its structure an electron-donating N,N-diaryl-substituted amino group such as an N,N-diphenylaminophenyl group, or a group having an N,N-diaryl-substituted amino moiety, and a monomer unit having at least one functional group.
    Type: Grant
    Filed: July 10, 2003
    Date of Patent: September 5, 2006
    Assignee: Kawamura Institute of Chemical Research
    Inventor: Shinji Kato
  • Patent number: 7098283
    Abstract: Novel azo-based reactive yellow dyes and a process for manufacturing and using ocular devices having blue light absorption properties. Intraocular lenses so produced block blue light from reaching the retina of an eye implanted with the IOL. By blocking blue light from reaching the retina, the IOL thereby prevents potential damage to the retina.
    Type: Grant
    Filed: September 8, 2003
    Date of Patent: August 29, 2006
    Assignee: Bausch & Lomb Incorporated
    Inventor: Yu-Chin Lai
  • Patent number: 7094853
    Abstract: It is an object of the present invention to provide a basic crosslinked polymer having excellent ion exchange and catalyst properties with high resistance to thermal degradation which is, therefore, useful for a broad range of application, a method for producing said crosslinked polymer with great ease and high efficiency, and methods of using said crosslinked polymer. A crosslinked polymer having a tertiary amine and/or a quaternary ammonium salt structure, said crosslinked polymer has a tertiary amine structure at either end of at least one crosslink structure.
    Type: Grant
    Filed: October 30, 2002
    Date of Patent: August 22, 2006
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Yoshiaki Hirano, Hiroshi Yamamoto, Takehiko Morita, Takafumi Kubo
  • Patent number: 7091256
    Abstract: A reactive paint to be completely cured in air with binders that bear ethylenically-unsaturated groups, that can be cured by radical polymerization either thermally or both thermally and by UV light or high-energy radiation in a dual-cure method. The paint contains a combined initiator system consisting of thermal initiators and UV initiators and reactive oligomers that are formed from addition compounds of a reactant of formula (4) and a reactant of formula (5) In this formula, X=—CO—CH?CH2 or —CnHm or —CO—CnHm. —CnHm is an aliphatic residue with 1 to 3 C atoms, whereby 0, 1, 2 or 3 X substituents are formed by —CnHm, and Y is a hydrocarbon chain of 3 to 8 atoms that can also contain heteroatoms. Also provided is a method for curing by radical polymerization. The polymerization is first started thermally under air and then is continued either thermally or photoinitiated under air or protective gas, and a use in paint systems, especially in automobile manufacturing or as a binder.
    Type: Grant
    Filed: June 22, 2004
    Date of Patent: August 15, 2006
    Assignee: DaimlerChrysler AG
    Inventors: Markus Bischof, Elisabeth Gemmler, Fritz Mezger, Thomas Raith, Christoph Ruechardt
  • Patent number: 7087675
    Abstract: The ?-hydroxy carbamate, ethylenically unsaturated monomer of the invention can be polymerized as a homopolymer or copolymerized with other monomers. The polymerization can be carried out in an aqueous medium. The ?-hydroxy carbamate monomer is polymerized to form water-soluble homopolymers or, if polymerized as a mixture with one or more comonomers, copolymers that are soluble, emulsifiable, or dispersible in water. The ?-hydroxy carbamate monomer can be used as a replacement monomer for acrylamide.
    Type: Grant
    Filed: March 19, 2003
    Date of Patent: August 8, 2006
    Assignee: BASF Corporation
    Inventors: Walter H. Ohrbom, Patricia A. Herrel
  • Patent number: 7087654
    Abstract: The invention provides ion exchange and electrochemical methods and devices employing anion exchange polymers produced by substantially simultaneous quaternization and polymerization reactions. Anion selective polymers are produced in accordance with the invention by combining, an ethylenic tertiary amine monomer, an alkylating agent having a boiling point temperature of at least about 100° C., and a cross-linking agent in the presence of a polymerizing agent for a time and at a temperature sufficient to form the polymer. The alkylating agent and the cross-linking agent may be the same compound, a cross-linking alkylating agent. The polymers may be produced in the presence of solvents and/or in the presence of diluting monomers which are incorporated into the polymers.
    Type: Grant
    Filed: June 24, 2002
    Date of Patent: August 8, 2006
    Assignee: Ionics, Incorporated
    Inventors: Russell J. MacDonald, James A. Lech
  • Patent number: 7064166
    Abstract: The present invention relates to a polymerization process for the control of the microstructure of polymers and to novel copolymers. An embodiment of the present invention relates a process of polymerizing first and second monomers in the presence of a complex comprising at least one of the monomers. The presence of the complex modifies the relative reactivity, or cross propagation rate constants, of the monomers in copolymerization reactions. Embodiments of the present invention allow the synthesis of polymers with novel stereochemistry and monomer sequence distribution, for example, but not limited to, copolymers with at least one segment of alternating monomers, a controlled molecular weight and narrow molecular weight distribution, or a segment of high concentration of the first monomer.
    Type: Grant
    Filed: October 11, 2002
    Date of Patent: June 20, 2006
    Assignee: Carnegie Mellon University
    Inventors: Krzysztof Matyjaszewski, Betül Kirci, Jean François Lutz, Tomislav Pintauer
  • Patent number: 7037996
    Abstract: The present invention provides an ink composition containing a pigment dispersed uniformly in a solvent and a block polymer having an ionic functional group, an image-forming method and an image-forming apparatus employing the ink composition. The composition comprises a pigment, a solvent and a polymer having an ionic functional group, an acid residue, or a base residue at the terminal. The polymer having an ionic functional group, an acid residue, or a base residue at the terminal is a block polymer of ABX type having A, B, and X segments, wherein A and B are respectively a block segment having a vinyl ether structure as the repeating unit, and X is a terminal segment having an ionic functional group, an acid residue, or an base residue.
    Type: Grant
    Filed: March 6, 2003
    Date of Patent: May 2, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masayuki Ikegami, Koichi Sato, Ikuo Nakazawa, Sakae Suda
  • Patent number: 7026419
    Abstract: An adhesive or sealant composition comprising a compound of formula (I) provided that at least one of (a) R1 and R6 or (b) R2 and R3 or (c) R4 and R5 includes an electron withdrawing group; and where necessary, a polymerisation initiator. Novel compounds of formula (I) are also described and claimed. Adhesive compositions can be used to bond for example glass and metal surfaces. Certain biocompatible adhesives for medical applications are included.
    Type: Grant
    Filed: December 11, 2003
    Date of Patent: April 11, 2006
    Assignee: Qinetiq Limited
    Inventors: Paul E Milne, Keith M Blackwood, Alan W Hall, John W Goodby
  • Patent number: 7001963
    Abstract: The present invention provides a polymer composition for the selective removal of cobalt, a process for the preparation thereof and the process for removal of cobalt, using the said polymer composition. More particularly it relates to a cross-linked polymer composition prepared by the molecular imprinting technique. The preparation of the cross linked polymer involves selection of vinyl monomers bearing functional groups that bind to cobalt, formation of a complex of these monomers with cobalt and subsequent polymerization of the complex in presence of a crosslinker. The process for the removal of cobalt comprises treating the solution containing a mixture of cobalt and other metal ions with the polymer under conditions sufficient for cobalt to form a complex with the polymer and separating the polymer from the cobalt depleted solution.
    Type: Grant
    Filed: November 1, 2004
    Date of Patent: February 21, 2006
    Assignee: Council of Scientific and Industrial Research
    Inventors: Mohan Gopalkrishna Kulkarni, Rohini Nitin Karmalkar
  • Patent number: 6998455
    Abstract: This invention relates to a laminate which changes in dimension to such a small extent as not to cause curling and warpage when the ambient humidity changes and is useful for flexible printed wiring boards. The laminate possesses a polyimide layer or layers of polyimides formed on a conductor by coating and at least one of the polyimide layers is composed of polyimide of low hygroscopic expansion obtained by the reaction of diamines containing 20 mol % or more of 4,4?-diamino-2,2?-dimethylbiphenyl with a tetracarboxylic acid compound and exhibiting a coefficient of linear hygroscopic expansion of 15×10?6/% RH or less.
    Type: Grant
    Filed: October 20, 2000
    Date of Patent: February 14, 2006
    Assignee: Nippon Steel Chemical Co., Ltd.
    Inventors: Takuhei Ohta, Katsufumi Hiraishi, Makoto Shimose, Kazuto Okamura, Naoya Okabayashi, Kazunori Oomizo
  • Patent number: 6995208
    Abstract: The invention provides a clearcoat coating composition containing either one acrylic polymer with secondary hydroxyl functionality and carbamate functionality or two acrylic polymers, the first having secondary hydroxyl functionality and the second having carbamate functionality; a carbamate-functional or urea-functional material that is the reaction product of (1) a compound comprising a primary carbamate or primary urea group and an hydroxyl group and (2) a compound that is reactive with hydroxyl groups on a plurality of molecules of compound (1), but that is not reactive with the carbamate or urea groups on compound (1); and a crosslinking component including an aminoplast crosslinker. A windshield sealant can be applied directly to the clearcoat layer produced from the composition without the need for a special primer layer.
    Type: Grant
    Filed: December 11, 2001
    Date of Patent: February 7, 2006
    Assignee: BASF Corporation
    Inventors: Sanjay Mehta, David J. Santure, John A. Gilbert
  • Patent number: 6994745
    Abstract: This invention provides both a pigment dispersing resin which is a copolymer of: (A) polymerizable unsaturated monomer containing at least one kind of ionic functional group selected from the group consisting of tertiary amino group, quaternary ammonium salt and sulfonic acid group; (B) nonionic polymerizable unsaturated monomer having polyoxyalkylene chain; (C) ultraviolet-absorbing polymerizable unsaturated monomer and/or an ultraviolet-stabilizing polymerizable unsaturated monomer; and (D) other ethylenically unsaturated monomer, and water-based pigment dispersion which comprises said pigment dispersing resin, pigment, aqueous medium and, as circumstances may demand, dispersing agent as well.
    Type: Grant
    Filed: April 5, 2002
    Date of Patent: February 7, 2006
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Yuko Hoshida, Yoshiyuki Yukawa, Isao Kamimori, Akihiko Yamanouchi
  • Patent number: 6995192
    Abstract: The present invention provides a radiation-curable prepolymer. The radiation-curable prepolymer of the invention is prepared by reacting an isocyanate-capped polyurethane with an ethylenically unsaturated amine or an ethylenically unsaturated monohydroxy compound or a mixture thereof, wherein the isocyanate-capped polyurethane is a copolymerization production of: (a) at least one polyalkylene glycol; (b) at least one branching agent having at least three hydroxy groups; and (c) at least one di- or polyisocyanate. The radiation-curable prepolymer of the invention can find use in economically producing contact lenses which have durable, highly elastic soft contact lenses with desired physical properties. In addition, the present invention provides method for making a radiation-curable prepolymer of the invention and for making a medical device, preferably an ophthalmic device, more preferably a contact lens.
    Type: Grant
    Filed: August 13, 2003
    Date of Patent: February 7, 2006
    Assignee: Novartis AG
    Inventors: John Christopher Phelan, Michael Hugh Quinn, Joshua Andrew Wallach
  • Patent number: 6984702
    Abstract: A process for the preparation of amine-functionalized vinyl polymer particles which process comprises suspension polymerizing aminostyrene together with at least one other vinylic monomer and optionally a crosslinking agent.
    Type: Grant
    Filed: March 1, 2001
    Date of Patent: January 10, 2006
    Assignee: Dynal Biotech ASA
    Inventors: Geir Fonnum, Ellen Weng, Elin Marie Aksnes, Rolf Nordal, Preben Cato Mørk, Svein Tøgersen, Julian Cockbain
  • Patent number: 6984705
    Abstract: A composition comprising expandable cross linked polymeric microparticles having an unexpanded volume average particle size diameter of from about 0.05 to about 10 microns and a cross linking agent content of from about 9,000 to about 200,000 ppm of labile cross linkers and from 0 to about 300 ppm of non-labile cross linkers. The composition is used for modifying the permeability of subterranean formations and increasing the mobilization and/or recovery rate of hydrocarbon fluids present in the formations.
    Type: Grant
    Filed: September 3, 2002
    Date of Patent: January 10, 2006
    Assignee: Ondeo Nalco Energy Services, L.P.
    Inventors: Kin-Tai Chang, Harry Frampton, James C. Morgan
  • Patent number: 6936669
    Abstract: This invention discloses a process for synthesizing an amine functionalized monomer that comprises (1) reacting a secondary amine with a 2,3-dihalopropene to produce a vinyl halide containing secondary amine having a structural formula selected from the group consisting of wherein R and R? can be the same or different and represent allyl, alkoxyl or alkyl groups containing from 1 to about 10 carbon atoms, and wherein X represents a halogen atom, and wherein m represents an integer from 4 to about 10, and wherein X represents a halogen atom; and (2) reacting the vinyl halide containing secondary amine with a vinyl magnesium halide to produce the monomer having a structural formula wherein R and R? can be the same or different and represent alkyl, allyl or alkoxyl groups containing from 1 to about 10 carbon atoms, and wherein m represents an integer from about 4 to about 10.
    Type: Grant
    Filed: December 9, 2003
    Date of Patent: August 30, 2005
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Adel Farhan Halasa, Wen-Liang Hsu, Jin-Ping Zhou, Chad Aaron Jasiunas, Corey Stanton Yon
  • Patent number: 6933358
    Abstract: This invention discloses a process for synthesizing an amine functionalized monomer that comprises (1) reacting a secondary amine with a 2,3-dihalopropene to produce a vinyl halide containing secondary amine having a structural formula selected from the group consisting of wherein R and R? can be the same or different and represent allyl, alkoxyl or alkyl groups containing from 1 to about 10 carbon atoms, and wherein X represents a halogen atom, and wherein m represents an integer from 4 to about 10, and wherein X represents a halogen atom; and (2) reacting the vinyl halide containing secondary amine with a vinyl magnesium halide to produce the monomer having a structural formula wherein R and R? can be the same or different and represent alkyl, allyl or alkoxyl groups containing from 1 to about 10 carbon atoms, and wherein m represents an integer from about 4 to about 10.
    Type: Grant
    Filed: March 14, 2003
    Date of Patent: August 23, 2005
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Adel Farhan Halasa, Wen-Liang Hsu, Jin-Ping Zhou, Chad Aaron Jasiunas, Corey Stanton Yon
  • Patent number: 6916537
    Abstract: Described is a photochromic article that includes a substrate and at least a partial coating of an at least partially cured polymerizable composition of a photochromic amount of at least one photochromic compound, at least one material having at least one carbonate group and at least one hydroxyl group, and at least one monoisocyanate containing material having at least one unsaturated group. Also described are photochromic optical elements such as ophthalmic lenses, prepared from an optical element substrate coated with the photochromic polymerizable composition.
    Type: Grant
    Filed: October 16, 2002
    Date of Patent: July 12, 2005
    Assignee: Transitions Optical Inc.
    Inventors: Cletus N. Welch, Eric M. King, Lawrence G. Anderson, Randy E. Daughenbaugh, Kevin J. Stewart
  • Patent number: 6906129
    Abstract: A polymer scale preventive agent for use in the polymerization of a monomer containing an ethylenic double bond is provided. The agent includes (A) a condensation reaction product obtained by reacting an aldehyde compound and a hydroxynaphthalene-based compound in the presence of a reducing agent, and (B) a polymer compound containing a nitrogen atom. This agent is capable of forming a coating with satisfactory scale prevention properties on inner wall surfaces of a polymerization vessel with a single-stage application, enabling the production process time to be shortened and the productivity and quality of polymeric products improved.
    Type: Grant
    Filed: September 3, 2004
    Date of Patent: June 14, 2005
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Mikio Watanabe, Tadashi Amano
  • Patent number: 6903171
    Abstract: Methods for the addition polymerization of cycloolefins using a cationic Group 10 metal complex and a weakly coordinating anion of the formula: [(R?)zM(L?)x(L?)y]b[WCA]d wherein [(R?)zM(L?)x(L?)y] is a cation complex where M represents a Group 10 transition metal; R? represents an anionic hydrocarbyl containing ligand; L? represents a Group 15 neutral electron donor ligand; L? represents a labile neutral electron donor ligand; x is 1 or 2; and y is 0, 1, 2, or 3; and z is 0 or 1, wherein the sum of x, y, and z is 4; and [WCA] represents a weakly coordinating counteranion complex; and b and d are numbers representing the number of times the cation complex and weakly coordinating counteranion complex are taken to balance the electronic charge on the overall catalyst complex.
    Type: Grant
    Filed: October 15, 2002
    Date of Patent: June 7, 2005
    Assignee: Promerus, LLC
    Inventors: Larry Funderburk Rhodes, Andrew Bell, Ramakrishna Ravikiran, John C. Fondran, Saikumar Jayaraman, Brian Leslie Goodall, Richard A. Mimna, John-Henry Lipian
  • Patent number: 6890996
    Abstract: The present invention provides a branched polyvinyl imidazoline acid salt which, when used in waste water treatment, especially sewage treatment, forms flocs and decreases the water content of a dehydrated cake, a polymeric flocculent comprising the branched polyvinyl imidazoline acid salt, and a process for preparing the branched polyvinyl imidazoline acid salt. The branched polyvinyl imidazoline acid salt has a Huggins' constant k? of 0.2 to 1.2 and an intrinsic viscosity [?] of 2 to 20 based on measurements at 30° C. in a 0.1 mol/l aqueous solution of sodium chloride.
    Type: Grant
    Filed: May 16, 2003
    Date of Patent: May 10, 2005
    Assignee: Tosoh Corporation
    Inventors: Toshiya Higashino, Shinji Shimosato
  • Patent number: 6889471
    Abstract: A stable aqueous suspension of water-soluble polyacrylamide particles is in a saturated solution of an ammonium salt. The polyacrylamide particles are characterized by a particle size of about ?150 mesh, and preferably ?270 mesh, with ?400 mesh most preferred. The suspension is at least about 2.5% by weight polyacrylamide. When the ammonium salt is ammonium sulfate, PAM concentrations as high as about 15% by weight can be achieved while still being easily flowable. The suspension is made by stirring the small particle PAM into the saturated ammonium salt solution. The PAM can be quickly dissolved to form a less concentrated PAM solution by adding the suspension to water or to a dilute solution, which can include calcium salts or other soil enhancers.
    Type: Grant
    Filed: April 26, 2001
    Date of Patent: May 10, 2005
    Inventors: Charles A. Arnold, Arthur Wallace
  • Patent number: 6891007
    Abstract: This invention relates to a process for polymerizing polar substituted norbornenes and/or cycloalkenes, optionally, in the presence of another unsaturated compound. The method is characterized in that the polymerization is carried out in the presence of one or more tungsten carbine complexes.
    Type: Grant
    Filed: March 19, 2001
    Date of Patent: May 10, 2005
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl-Heinz Alexsander Ostoja Starzewski, Karin Weiss, Martin Olaf Thüring
  • Patent number: 6870002
    Abstract: A rubber composition, which comprises 100 parts by weight of a rubber mixture consisting of 70-95 wt. % of solid rubber and 30-5 wt. % of liquid rubber reactive on the solid rubber, and 450-1,000 parts by weight of magnetic powder. The rubber composition has an improved processability by adding liquid rubber reactive on solid rubber to the conventional magnetic powder-containing rubber, without any deterioration of physical properties proper to the rubber, while maintaining a high magnetic force proper to the magnetic powder, keeping the lower viscosity of rubber compound and holding distinguished heat resistance and flexibility of moldings.
    Type: Grant
    Filed: December 16, 2002
    Date of Patent: March 22, 2005
    Assignee: NOK Corporation
    Inventors: Katsumi Abe, Hironori Nishina
  • Patent number: 6867241
    Abstract: The present invention relates to a radiation-curable composition which includes a cyanoacrylate component or a cyanoacrylate-containing formulation, a metallocene component, a hydrogen abstraction photoinitiator, and hydrogen donor component to enhance the activity of the hydrogen abstraction photoinitiator.
    Type: Grant
    Filed: January 31, 2002
    Date of Patent: March 15, 2005
    Assignee: Henkel Corporation
    Inventors: Stan Wojciak, Shabbir Attarwala, John T. O'Connor, S. Peter Pappas
  • Patent number: 6864337
    Abstract: It is an object of the present invention to provide a polycarboxylic acid copolymer which improves the water reducing capacity and workability of cement compositions and the like and making them easier to handle when the fluidity and water reducing capacity are at the same levels, a method of producing the copolymer, and a cement additive and a cement composition comprising the copolymer. The present invention is further to provide a polycarboxylic acid copolymer and a cement additive which are capable of improving the strength and durability of hardening products of cement compositions, hence can advantageously be used in ultrahigh strength concrete. The present invention is still further to provide a method of producing polycarboxylic acid copolymers having high water reducing capacity, reducing the viscosity of cement compositions and improving the workability in applying cement.
    Type: Grant
    Filed: December 26, 2001
    Date of Patent: March 8, 2005
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Tsutomu Yuasa, Tomotaka Nishikawa, Noboru Sakamoto, Tsuyoshi Hirata, Hiroko Izukashi, Tomiyasu Ueta, Hiromichi Tanaka, Yoshiyuki Onda, Toru Uno
  • Patent number: 6864314
    Abstract: The present invention relates to a block polymeric material. Typically the block polymer comprises units capable of having an average cationic charge density of about 15 or less, preferably 5 or less, more preferably from about 0.05 to about 5, even more preferably from about 0.05 to about 2.77, even more preferably from about 0.1 to about 2.75, most preferably from about 0.75 to about 2.25 units per 100 daltons molecular weight at a pH of from about 4 to about 12. The polymeric material is a suds enhancer and a suds volume extender for personal care products such as soaps and shampoos. The compositions have increased effectiveness for preventing re-deposition of grease during hand and body washing. The polymers are also effective as a soil release agent in fabric cleaning compositions.
    Type: Grant
    Filed: October 30, 2000
    Date of Patent: March 8, 2005
    Inventors: Dominic Wai-Kwing Yeung, Vance Bergeron, Jean-Francois Bodet, Mark Robert Sivik, Bernard William Kluesener, William Michael Scheper
  • Patent number: 6858681
    Abstract: The process for producing an olefinic polymer comprises introducing a saturated aliphatic hydrocarbon in a liquid phase state and in a vapor phase state into the aforementioned fluidized-bed and (co)polymerizing in the condition that when the inside radius of the cylinder section of the fluidized-bed reactor is defined as a distance of 1, the relationship between the concentration (C1) of the saturated aliphatic hydrocarbon put in a liquid state in the peripheral portion of the cylinder section at a relative distance of 0.7 to 1.0 from the center of the cylinder section as a start point and the concentration (C2) of the saturated aliphatic hydrocarbon put in a liquid state in the center portion of the cylinder section at a relative distance less than 0.7 from the center fulfills the following equation: C1>C2 at a place close to the upstream section of said gas distributing plate.
    Type: Grant
    Filed: March 28, 2003
    Date of Patent: February 22, 2005
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Satoru Ohtani, Shinji Abe, Hiroto Nishida