Interpolymer Of An Ester Derived From Ethylenically Unsaturated Alcohol, E.g., Interpolymer Of Vinyl Acetate, Etc. Patents (Class 526/330)
  • Patent number: 6117934
    Abstract: The invention is a surfactant composition comprising about 20 weight % to about 76 weight % of a fatty alcohol ethoxylate having a degree of ethoxylation of at least 14, about 4 weight % to about 40 weight % alkylpolyglycoside, and about 20 weight % to about 60 weight % water, wherein said composition is a liquid at room temperature, free of gel or solid phase, lattices containing said surfactant composition and a process for making said lattices.
    Type: Grant
    Filed: January 20, 1998
    Date of Patent: September 12, 2000
    Assignee: Henkel Corporation
    Inventors: Rudolph Klima, Wallace H. Pippin, Marcie Natale, Thomas Hopkins, Ching Feng, Dieter Feustel
  • Patent number: 6075107
    Abstract: The use of copolymers ofA) 60-99 mol % of N-vinylpyrrolidone, andB) 1-40 mol % of a monomer selected from the group ofb1) C.sub.8 -C.sub.30 -alkyl esters of monoethylenically unsaturated C.sub.3 -C.sub.8 -carboxylic acids,b2) N-alkyl- or N,N-dialkyl-substituted amides of acrylic acid or of methacrylic acid with C.sub.8 -C.sub.18 -alkyl radicals, orb3) vinyl esters of aliphatic C.sub.8 -C.sub.30 -carboxylic acids, or mixtures of these monomers,as surface-active substances in preparations of water-insoluble substances.
    Type: Grant
    Filed: May 7, 1998
    Date of Patent: June 13, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Stephan Kothrade, Helmut Meffert, Gunther Berndl, Axel Sanner, Stefan Stein, Volker Schehlmann, Folker Ruchatz
  • Patent number: 6048955
    Abstract: The present invention relates to a modacrylic copolymer composition comprising acrylonitrile, vinylidene chloride, vinyl acetate, and at least one ionic comonomer. In one embodiment, the modacrylic copolymer composition comprises from about 45 to about 60% acrylonitrile, from about 35 to about 50% vinylidene chloride, from about 0.5 to about 5% vinyl acetate, and up to about 2% of a salt of p-sulfophenyl methallyl ether by weight of the total composition. The copolymer composition of the present invention provides acceptable color while having acceptable flame resistance.
    Type: Grant
    Filed: February 2, 1999
    Date of Patent: April 11, 2000
    Assignee: Solutia Inc.
    Inventor: Bruce E. Wade
  • Patent number: 6048953
    Abstract: A curable liquid resin composition containing 100 parts by weight of the following (meth)acrylic liquid resin (A) and 1 to 1,000 parts by weight of a (meth)acrylic monomer (B) having an unsaturated double bond in its molecule and having a number average molecular weight of 1,000 or less, the (meth)acrylic liquid resin (A) being a liquid resin which is obtained by polymerizing monomers containing an alkyl (meth)acrylate monomer (a-1-1) of the formula (1),CH.sub.2 C(R.sup.1)COO--R.sup.2 (1)wherein R.sup.1 is a hydrogen atom or CH.sub.3 and R.sup.2 is an alkyl group,and/or an alkylene glycol (meth)acrylate monomer (a-1-2) of the formula (2) ,CH.sub.2 .dbd.C(R.sup.1)COO(C.sub.n H.sub.2n O).sub.m R.sup.3(2)wherein R.sup.1 is a hydrogen atom or CH.sub.3, R.sup.
    Type: Grant
    Filed: February 3, 1998
    Date of Patent: April 11, 2000
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Miki Kawashima, Kunio Horiuchi, Hiroaki Tanaka
  • Patent number: 6008262
    Abstract: The present invention relates to a foamable composition comprising a low viscosity thermoplastic composition comprising at least one ethylene/.alpha.-olefin. The foamable composition may comprise a single ethylene/.alpha.-olefin or a blend of such. Optionally, the foamable composition may further comprise at least one diluent including waxes, plasticizers such as oil, tackifying resin, and mixtures thereof. The present invention also relates to a method of foaming such compositions and articles constructed therefrom. More specifically, the present invention relates to foamable thermoplastic compositions having particular utility as cabinet sealant and as foam layers in disposable articles such as disposable diapers, incontinent devices, medical devices such as bandages and dressings, as well as a variety of other uses.
    Type: Grant
    Filed: September 16, 1997
    Date of Patent: December 28, 1999
    Assignee: H.B. Fuller Licensing & Financing, Inc.
    Inventors: Kevin W. McKay, Eugene R. Simmons, Donald P. Woodbridge
  • Patent number: 5994485
    Abstract: A vinyl chloride/vinyl acetate copolymer characterized in that it has a peak at a signal position of from 6.0 to 8.0 ppm in the .sup.1 H-NMR measurement.
    Type: Grant
    Filed: May 20, 1998
    Date of Patent: November 30, 1999
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Hirohisa Otake, Yukihisa Hoshino
  • Patent number: 5907011
    Abstract: Heterogeneous, solvent- and plasticizer-free polyvinyl ester dispersions which are stabilized by protective colloids and which have a minimum filming temperature of below 10.degree. C. are disclosed. These dispersions are made of a mixture of(a) a homopolymer or copolymer A having a glass transition temperature of above 20.degree. C., whereby homopolymer or copolymer A includes(i) from 85 to 100% by weight of at least one vinyl ester of carboxylic acids having 1 to 18 carbon atoms;(ii) from 0 to 5% by weight of at least one .alpha., .beta.-unsaturated carboxylic acid;(iii) from 0 to 5% by weight of at least one mono-olefinically unsaturated compound (a3) having at least one amino or amido group, and(iv) from 0 to 5% by weight of at least one polyethylenically unsaturated monomer, and(b) a copolymer B having a glass transition temperature of below 20.degree. C.
    Type: Grant
    Filed: March 31, 1997
    Date of Patent: May 25, 1999
    Assignee: Clariant GmbH
    Inventors: Martin Jakob, Detlev Seip, Volker Matz, Stefan Hess
  • Patent number: 5883169
    Abstract: Disclosed is a lens wafer suitable for use in preparing a laminated lens which wafer has a coating on at least one surface thereof in the form of a peelable protective film.
    Type: Grant
    Filed: April 17, 1996
    Date of Patent: March 16, 1999
    Assignee: Sola International Holdings Ltd.
    Inventors: David P. Spector, A. N. Sunder Ram
  • Patent number: 5866655
    Abstract: A vinyl alcohol polymer with a side chain being a hydroxyalkyl group having 2 to 20 carbon atoms is disclosed. Conventional water-soluble vinyl alcohol polymers gives, where they have a high interfacial activity, an aqueous solution with much-foaming and hence a problem when used for commercial purposes. On the other hand, the vinyl alcohol polymer of the present invention gives, where it is water-soluble, an aqueous solution with less-foaming in spite of its high interfacial activity, and hence an excellent industrial applicability. The vinyl alcohol polymer of the present invention is useful as thermoplastic resin and dispersion stabilizer. In addition, the vinyl alcohol polymer of the present invention is usable for various purposes, e.g.
    Type: Grant
    Filed: May 28, 1997
    Date of Patent: February 2, 1999
    Assignee: Kuraray Co., Ltd.
    Inventors: Naoki Fujiwara, Takeshi Kusudou, Takaharu Kawahara, Toshiaki Sato
  • Patent number: 5859160
    Abstract: A free radical curable composition that includes a free radical curable and a vinyl aromatic compound that is chemically different than the free radical curable component, wherein the vinyl aromatic compound is present in an amount sufficient to decelerate the cure rate of the free radical composition without adversely effecting completion of cure and the properties of the curable composition after it has cured. The composition is particularly useful as a two part adhesive that includes a free radical catalyst system and a diene elastomer.
    Type: Grant
    Filed: January 9, 1997
    Date of Patent: January 12, 1999
    Assignee: Lord Corporation
    Inventors: Robin F. Righettini, Kirk J. Abbey
  • Patent number: 5849840
    Abstract: A dispersing stabilizer including (A) a polyvinyl alcohol resin containing oxyalkylene groups and having a surface tension of 35 to 55 dyne/cm at 20.degree. C. as a 1% by weight aqueous solution, or said resin and (B) a water-soluble polymer or a polyvinyl alcohol resin having a low degree of hydrolysis and a low degree of polymerization. When using the dispersing stabilizer of the present invention, both of a porosity and a bulk density of a polyvinyl resin particle can be improved at the same time, and, in addition, a distribution of particle size and a uniformity of porosity can be further improved.
    Type: Grant
    Filed: April 23, 1997
    Date of Patent: December 15, 1998
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Motokazu Maruhashi, Kizo Ohnishi
  • Patent number: 5830439
    Abstract: An improved hydrocarbon tolerant, aerosol hair spray resin composition includes a fixative polymer which is a tetrapolymer consisting essentially of (1) vinyl acetate, (2) vinyl neodecanoate or vinyl neononanoate, (3) monoisobutyl maleate and (4) N-t-butyl acrylamide, N-t-octyl acrylamide, or isobornyl (meth)acrylate, in a molar ratio from 10:10:15:1 to 26:1:15:1, preferably in a molar ratio of 12.5:7.5:15:1, exhibits advantageous small spray particle size, short tack and drying times, and hydrolytic stability, which are the desired performance characteristics on hair.
    Type: Grant
    Filed: May 16, 1997
    Date of Patent: November 3, 1998
    Assignee: ISP Investments Inc.
    Inventors: Jui-Chang Chuang, Edward Walls, Jr.
  • Patent number: 5817727
    Abstract: The present invention pertains to a film for detecting chemical substances comprising a homopolymer or a copolymer having recurring units represented by the following formula (I): ##STR1## wherein X is --H, --F, --Cl, --Br, --CH.sub.3, --CF.sub.3, --CN or --CH.sub.2 CH.sub.3 ; and R.sup.1 is --R.sup.2 or --Z--R.sup.2 ;wherein Z is --O--, --S--, --NH--, --NR.sup.2' --, --(C.dbd.Y)--, --(C.dbd.Y)--Y--, --Y--(C.dbd.Y)--, --(SO.sub.2)--, --Y'--(SO.sub.2)--, --(SO.sub.2)--Y'--, --Y'--(SO.sub.2)--Y'--, --NH--(C.dbd.O)--, --(C.dbd.O)--NH--, --(C.dbd.O)--NR.sup.2' --, --Y'--(C.dbd.Y)--Y'-- or --O--(C.dbd.O)--(CH.sub.2).sub.n --(C.dbd.O)--O--;wherein Y is independently O or S, and Y' is independently O or NH, and n is an integer of 0 to 20;and wherein R.sup.2 and R.sup.2' represent independently a hydrogen atom, a linear alkyl group, a branched alkyl group, a cycloalkyl group, an unsaturated hydrocarbon group, an aryl group, a saturated or unsaturated hetero ring or derivatives thereof, provided that R.sup.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: October 6, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Werner Prass, Thomas Stehlin, Yuan Liu, Shizuo Ogura, Tetsu Yamamoto, Akihiko Tokida, Kenji Motosugi
  • Patent number: 5789510
    Abstract: Terpolymers obtained by copolymerization of ethylene, a vinyl ester of at least one aliphatic monocarboxylic acid of 2 to 20 carbon atoms in the molecule and bicyclo?2.2.1!hept-2-ene (also referred to as norbornene) or its derivatives, a process for their preparation and their use as additives for mineral oils and mineral oil distillates.
    Type: Grant
    Filed: May 19, 1997
    Date of Patent: August 4, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Matthias Krull, Werner Reimann
  • Patent number: 5753753
    Abstract: This invention relates to an improved process for producing a vinyl alcohol containing polymer having a narrow particle size without substantial reactor fouling. The process for producing the vinyl alcohol containing polymer involves hydrolyzing a vinyl ester containing polymer, e.g., a polymer containing polymerized vinyl alkanoate units in the presence of an alcoholic medium and a hydrolysis catalyst in the presence of an alcoholic medium having finely divided, inert material such as an alkali metal carbonate dispersed therein. The finely divided inert material acts as nucleating sites for the polyvinyl alcohol as it precipitates from the solution during hydrolysis.
    Type: Grant
    Filed: February 19, 1997
    Date of Patent: May 19, 1998
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Kien Van Phung, Dennis Sagl
  • Patent number: 5747578
    Abstract: A copolymer in dispersion or redispersible powder form which is stabilized by a protective colloid and has a glass transition temperature of -40.degree. to 10.degree. C. and an ethylene content of at least 30% by weight, based on the total amount of monomers, with a heterogeneous build-up of the copolymer particles, including a first polymer phase, which includes vinyl acetate and >40% by weight of ethylene, based on the total amount of monomers in this phase, and a last copolymer phase, which includes vinyl acetate and 5 to 40% by weight of ethylene, based on the total amount of monomers in this phase, is suitable, for example, as a binder in building materials.
    Type: Grant
    Filed: July 30, 1996
    Date of Patent: May 5, 1998
    Assignee: Clariant GmbH
    Inventors: Ludwig Schmitz, Stefan Hess, Bettina Gerharz
  • Patent number: 5728788
    Abstract: The present invention provides a process of producing a vinyl acetate polymer by homopolymerization of a vinyl acetate monomer or copolymerization of a vinyl acetate monomer and another copolymerizable comonomer, wherein a polymerization initiator is an organic peroxide having a half life at 60.degree. C. of 10 to 110 minutes, and a polymerization liquid contains at least one carboxylic acid or its salt, said carboxylic acid being selected from the group consisting of a hydroxycarboxylic acid and a polycarboxylic acid.
    Type: Grant
    Filed: March 11, 1997
    Date of Patent: March 17, 1998
    Assignee: Kuraray Co., Ltd.
    Inventors: Hiroshi Takachi, Kazuyori Yoshimi
  • Patent number: 5719246
    Abstract: According to the present invention, there is provided an acrylic copolymer having a number average molecular weight of 1000-500,000, which comprises 1-90 % by weight of a structural unit represented by the following general formula ##STR1## (wherein R represents a hydrogen atom or a methyl group) and 99-10 % by weight of a structural unit-derived from an ethylenic unsaturated monomer, an acrylic copolymer composition and a paint containing the same.The coat obtained by applying the acrylic copolymer has excellent abrasion resistance, chemical resistance, flexibility, strength and the like.
    Type: Grant
    Filed: December 20, 1996
    Date of Patent: February 17, 1998
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Yasuyuki Taniguchi, Yuji Soejima
  • Patent number: 5686545
    Abstract: A liquid resin having a number average molecular weight of 10,000 to 200,000 and a viscosity, measured at 50.degree. C., of 500 to 30,000 cps, obtained by the copolymerization of a composition containing(a) 35 to 98% by weight of a monomer of the formula,CH.sub.2 =C(R.sup.1)COOR.sup.2wherein R.sup.1 is hydrogen or methyl and R.sup.2 is a hydrocarbon group having 4 to 22 carbon atoms,(b) 2 to 40% by weight of a polymerizable unsaturated carboxylic acid, and(c) 0 to 60% by weight of other polymerizable vinyl monomer.
    Type: Grant
    Filed: August 5, 1996
    Date of Patent: November 11, 1997
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Miki Kawashima, Kunio Horiuchi
  • Patent number: 5684108
    Abstract: An ethylene-based copolymer which is suitable as a flow improver for mineral oil middle distillates and is composed ofa) from 50 to 94% by weight of ethylene;b) from 3 to 30% by weight of one or more vinyl esters of C.sub.2 -C.sub.6 -monocarboxylic acids;c) from 3 to 20% by weight of one or more aminoalkyl acrylates of the formula I ##STR1## which R.sup.1 is hydrogen or methyl, R.sup.2 and R.sup.3 are identical or different and are each hydrogen or C.sub.1 -C.sub.6 -alkyl and A.sup.1 is straight-chain or branched C.sub.2 -C.sub.10 -alkylene; andd) from 0 to 10% by weight of one or more monomers which are copolymerizable with the monomers a) to c), wherein copolymers containing vinyl acetate as monomer b) and having a number average molecular weight of from 5,000 to 50,000 are excluded from the scope of the copolymer.
    Type: Grant
    Filed: April 2, 1996
    Date of Patent: November 4, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans-Joachim Muller, Bernd Wenderoth, Albin Berger, Dieter Littmann, Roger Klimesch, Knut Oppenlander, Bernd Lothar Marczinke, Thomas Ruhl, Marc Heider
  • Patent number: 5665844
    Abstract: The present invention pertains to a film for detecting chemical substances comprising a homopolymer or a copolymer having recurring units represented by the following formula (I): ##STR1## wherein X is --H, --F, --Cl, --Br, --CH.sub.3, --CF.sub.3, --CN or --CH.sub.2 CH.sub.3 ; and R.sup.1 is --R.sup.2 or --Z--R.sup.2 ;wherein Z is --O--, --S--, --NH--, --NR.sup.2' --, --(C.dbd.Y)--, --(C.dbd.Y)--Y--, --Y--(C.dbd.Y)--, --(SO.sub.2)--, --Y'--(SO.sub.2)--, --(SO.sub.2)--Y'--, --Y'--(SO.sub.2)--Y'--, --NH--(C.dbd.O)--, --(C.dbd.O)--NH--, --(C.dbd.O)--NR.sup.2' --, --Y'--(C.dbd.Y)--Y'-- or --O--(C.dbd.O)--(CH.sub.2).sub.n --(C.dbd.O)--O--;wherein Y is independently O or S, and Y' is independently O or NH, and n is an integer of 0 to 20;and wherein R.sup.2 and R.sup.2' represent independently a hydrogen atom, a linear alkyl group, a branched alkyl group, a cycloalkyl group, an unsaturated hydrocarbon group, an aryl group, a saturated or unsaturated hetero ring or derivatives thereof, provided that R.sup.
    Type: Grant
    Filed: November 15, 1993
    Date of Patent: September 9, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Werner Prass, Thomas Stehlin, Yuan Liu, Shizuo Ogura, Tetsu Yamamoto, Akihiko Tokida, Kenji Motosugi
  • Patent number: 5665840
    Abstract: The present invention describes a water-soluble crosslinkable prepolymer that comprises, in the copolymer chain, units derived from the following monomeric structural units: a vinyl lactam (a), vinyl alcohol (b), optionally a lower alkanecarboxylic acid vinyl ester (c), a vinylic crosslinking agent (d) and optionally a vinylic photoinitiator (e); a process for the preparation of the novel prepolymers; crosslinked water-insoluble polymeric networks therefrom; hydrogels and moulded articles made from the crosslinked water-insoluble polymeric networks, especially contact lenses; and a process for the manufacture of hydrogels and finished contact lenses using the mentioned crosslinkable water-soluble prepolymers.
    Type: Grant
    Filed: November 3, 1995
    Date of Patent: September 9, 1997
    Assignee: Novartis Corporation
    Inventors: Thomas Pohlmann, Achim Muller, Bernhard Seiferling
  • Patent number: 5605995
    Abstract: Hydroxy-functional allyl terpolymers are disclosed. The terpolymers comprise recurring units of an allyl ester, an allylic alcohols or propoxylated allylic alcohol, and a vinyl monomer. The high hydroxyl group content and favorable solubility characteristics make the terpolymers easy to formulate into many polymer products, including polyurethanes, polyesters, melamines, alkyds, uralkyds, and other thermoset polymers.
    Type: Grant
    Filed: March 18, 1996
    Date of Patent: February 25, 1997
    Assignee: Arco Chemical Technology, L.P.
    Inventor: Shao-Hua Guo
  • Patent number: 5599890
    Abstract: A polymeric binder for ceramic materials is provided. The polymeric binder has a temperature range for pyrolysis which is broader than that for polymeric binders conventionally used in ceramic materials. The broader pyrolysis range provides for gradual removal of the binder when a ceramic part containing the binder is heated. Gradual removal of the binder minimizes the formation of voids and cracking in the ceramic part. Voids or cracking can lead to defects in the part, and destruction of the part may occur during removal if a polymeric binder used in the part is rapidly decomposed into gases. Therefore the polymeric binder of the present invention provides for ceramic parts with fewer defects and less chance of destruction than occurs with polymeric binders conventionally used in ceramic parts.
    Type: Grant
    Filed: March 21, 1994
    Date of Patent: February 4, 1997
    Assignee: Rohm and Haas Company
    Inventor: Xun Tang
  • Patent number: 5578689
    Abstract: Vinyl polymers, e.g., the homo- and copolyvinyl chlorides, are prepared in one or more stages, to a degree of conversion of at least 50%, by suspended emulsion polymerizing at least one vinyl monomer, e.g., vinyl chloride, said at least one monomer having dispersed therein finely divided droplets of an aqueous solution of at least one component of a polymerization initiating system, and wherein the amount of water in said aqueous solution constitutes at least 19%, and preferably at least 20% by weight of the at least one monomer.
    Type: Grant
    Filed: February 22, 1994
    Date of Patent: November 26, 1996
    Assignee: Atochem
    Inventors: Pierre Nogues, Francois Erard
  • Patent number: 5576405
    Abstract: A liquid resin having a number average molecular weight of 10,000 to 200,000 and a viscosity, measured at 50.degree. C., of 500 to 30,000 cps, obtained by the copolymerization of a composition containing(a) 35 to 98% by weight of a monomer of the formula,CH.sub.2 .dbd.C(R.sup.1)COOR.sup.2wherein R.sup.1 is a hydrogen or methyl and R.sup.2 is a hydrocarbon group having 4 to 22 carbon atoms,(b) 2 to 40% by weight of a polymerizable unsaturated carboxylic acid, and(c) 0 to 60% by weight of other polymerizable vinyl monomer.
    Type: Grant
    Filed: June 8, 1994
    Date of Patent: November 19, 1996
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Miki Kawashima, Kunio Horiuchi
  • Patent number: 5574120
    Abstract: The preparation of terpolymers by free radical polymerization of an unsaturated dicarboxylic acid with an unsaturated monocarxylic acid and a further saturated monomer which contains no free carboxyl groups, in an aqueous medium, is carried out, according to the invention, in the presence of surfactant compounds.
    Type: Grant
    Filed: November 6, 1995
    Date of Patent: November 12, 1996
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Klaus Heidel, Wulf Ruback, Frank Krause
  • Patent number: 5565537
    Abstract: This invention provides a maleimide-based copolymer in which, because its molecular weight-retention ratio at high temperature is high, deterioration of physical properties by heating is little. Also, this invention provides a process wherein a maleimide-based copolymer is arranged so as not to heat more than necessity and thereby a maleimide-based copolymer containing only a small amount of residual volatile components is efficiently obtained without deterioration of physical properties. The maleimide-based copolymer is such as having a glass transition temperature of 170.degree. C. or higher, a weight-average molecular weight of 100,000 to 500,000, and a molecular weight-retention ratio of 90% or more when heated at 280.degree. C. for 10 minutes.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: October 15, 1996
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Kimio Uda, Fumioki Shimoyama, Kazumi Fujioka
  • Patent number: 5548039
    Abstract: A polymer scale deposition preventive agent for use in polymerization of a monomer having an ethylenically unsaturated double bond, comprising an alkaline solution containing a condensation product of (A) an anthraquinone compound having at least two amino groups and (B) at least one compound selected from the group consisting of benzoquinone compounds and naphthoquinone compounds. When the monomer is polymerized in a polymerization vessel having a coating formed by applying the aforementioned preventive agent to inner wall surfaces followed by drying, polymer scale can be effectively prevented from being deposited not only on the areas located in the liquid-phase region but also on the areas around the interface between the gas and liquid phases in the polymerization vessel. When an obtained polymer is formed into a sheet or the like, it is possible to obtain a formed product having few fish eyes and low initial coloration.
    Type: Grant
    Filed: December 27, 1994
    Date of Patent: August 20, 1996
    Assignee: Shin-Etsu Chemical Co., Ltd
    Inventors: Toshihide Shimizu, Mikio Watanabe
  • Patent number: 5543483
    Abstract: Hydroxy-functional allyl terpolymers are disclosed. The terpolymers comprise recurring units of an allyl ester, an allylic alcohols or propoxylated allylic alcohol, and a vinyl monomer. The high hydroxyl group content and favorable solubility characteristics make the terpolymers easy to formulate into many polymer products, including polyurethanes, polyesters, melamines, alkyds, uralkyds, and other thermoset polymers.
    Type: Grant
    Filed: May 15, 1995
    Date of Patent: August 6, 1996
    Assignee: ARCO Chemical Technology, L.P.
    Inventor: Shao-Hua Guo
  • Patent number: 5540987
    Abstract: The free formaldehyde content of the emulsion polymer, the amount of emitted formaldehyde and, even more particularly, of the finished nonwoven or textile may be substantially reduced by the use of a particular initiator system comprising a hydrophobic hydroperoxide and ascorbic acid. Moreover, this reduction in formaldehyde levels is accompanied by an unexpected improvement in the tensile properties of the emulsion binders.
    Type: Grant
    Filed: September 28, 1994
    Date of Patent: July 30, 1996
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Paul R. Mudge, James L. Walker, Ronald Pangrazi
  • Patent number: 5532329
    Abstract: Copolymers which are self-curable with atmospheric humidity and are based on acrylic, methacrylic and/or vinyl esters which have been prepared using silicon-containing regulators, and mixtures of such polymers with crosslinkers, are suitable as adhesive, sealing and coating compositions which are self-curable with atmospheric humidity.
    Type: Grant
    Filed: December 28, 1994
    Date of Patent: July 2, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Ulrich Filges, Oral Aydin, Gerhard Auchter, Juergen Barwich, Hermann Anders, Werner Langer, Klaus Vorspohl
  • Patent number: 5519103
    Abstract: Allyl ester copolymers with allylic alcohols and propoxylated allylic alcohols are disclosed. The high primary hydroxyl group content and favorable solubility characteristics make the allyl ester copolymers easy to formulate into many polymer products, including polyurethanes, polyesters, melamines, alkyds, uralkyds, and crosslinked polymeric resins.
    Type: Grant
    Filed: April 28, 1995
    Date of Patent: May 21, 1996
    Assignee: Arco Chemical Company
    Inventor: Shao-Hua Guo
  • Patent number: 5502136
    Abstract: A process is described for making substantially homogeneous copolymers comprising 50-90% of vinyl pyrrolidone (VP) and 10-50% of vinyl acetate (VA), by weight, which form clear aqueous solutions.
    Type: Grant
    Filed: December 28, 1994
    Date of Patent: March 26, 1996
    Assignee: ISP Investments Inc.
    Inventors: Yuanzhen Zhong, Philip F. Wolf, Yakir Reuven
  • Patent number: 5480954
    Abstract: Allyl ester copolymers with allylic alcohols and propoxylated allylic alcohols are disclosed. The high hydroxyl group content and favorable solubility characteristics make the allyl ester copolymers easy to formulate into many polymer products, including polyurethanes, polyesters, melamines, alkyds, uralkyds, and other thermoset polymers.
    Type: Grant
    Filed: September 21, 1994
    Date of Patent: January 2, 1996
    Assignee: ARCO Chemical Technology, L.P.
    Inventor: Shao-Hua Guo
  • Patent number: 5476912
    Abstract: An adhesive which exhibits excellent adhesiveness and is capable of firmly adhering an acrylic resin and a silicone rubber together at a temperature of as low as about 20.degree. to 30.degree. C. requiring a time of as short as several minutes. The adhesive is obtained by dissolving in a solvent a novel silicone-modified acrylic copolymer having a polyorganosiloxane with an SiH reaction point on the side chain.
    Type: Grant
    Filed: June 30, 1994
    Date of Patent: December 19, 1995
    Assignee: Tokuyama Corporation
    Inventors: Yasuhiro Hosoi, Osamu Iwamoto, Masataka Himeno
  • Patent number: 5447727
    Abstract: The subject invention provides a surface-crosslinked water-absorbent polymer having improved properties. The subject invention further pertains to a process for preparing such a polymer. Through the use of a preferred primary crosslinking agent coupled with surface crosslinking, desirable absorptive properties are achieved. Suitable primary crosslinking agents include methylenebisacrylamide, bis(acrylamido)acetic acid and its salts, allyl acrylate, allyl methacrylate and esters or amides having both a vinyl and an allyl functionality.
    Type: Grant
    Filed: October 14, 1992
    Date of Patent: September 5, 1995
    Assignee: The Dow Chemical Company
    Inventor: Andrew T. Graham
  • Patent number: 5403905
    Abstract: Process for producing polyvinyl ester having a high degree of polymerization and an intrinsic viscosity of from 15 dl g.sup.-1 to 3.2 dl g.sup.-1, and a polyvinyl ester obtained thereby. The process comprises subjecting a vinyl ester monomer to emulsion polymerization using nonionic emulsifiers nonionic-anionic emulsifiers, or anionic emulsifiers and a redox initiator at a temperature of -60.degree. to 15.degree. C.
    Type: Grant
    Filed: February 3, 1994
    Date of Patent: April 4, 1995
    Assignee: Kuraray Company, Ltd.
    Inventors: Toshiaki Sato, Ken Yuki, Junnosuke Yamauchi, Takuji Okaya
  • Patent number: 5395905
    Abstract: The present invention provides water-soluble poylmers containing, as polymerized units: (a) from about 3 to about 95 percent by weight of one or more cyclohexene anhydrides or the alkali metal or ammonium salts thereof. The present further provides aqueous polymerization processes for making the polymers. The water-soluble polymers are useful as water-treatment additives for boiler waters and cooling towers and as detergent additives acting as builders, anti-filming agents, dispersants, sequestering agents and encrustation inhibitors.
    Type: Grant
    Filed: January 12, 1993
    Date of Patent: March 7, 1995
    Assignee: Rohm and Haas Company
    Inventors: Marianne P. Creamer, Thomas F. McCallum, III, Graham Swift, Barry Weinstein
  • Patent number: 5395904
    Abstract: A process for making homogeneous copolymers of vinylpyrrolidone (VP) and vinyl acetate (VA) which form clear aqueous solutions and have high cloud points. The process involves precharging VP and VA monomers in a predetermined ratio, and then feeding VP and VA at a predetermined rate, the ratio of the components in the initial charge and the feeding rates for the monomer being selected in accordance with the reactivity rates of the monomers towards copolymerization as opposed to homopolymerization.
    Type: Grant
    Filed: December 7, 1993
    Date of Patent: March 7, 1995
    Assignee: ISP Investments Inc.
    Inventors: Yuanzhen Zhong, Hemant Parikh, Terry E. Smith
  • Patent number: 5387634
    Abstract: Opaque tinted acrylic glass produced with organic pigments or with organic dyes, which in addition to the colorant, also contains an acid in the polymer matrix, exhibits improved resistance to weathering.
    Type: Grant
    Filed: January 15, 1993
    Date of Patent: February 7, 1995
    Assignee: Roehm GmbH Chemische Fabrik
    Inventors: Hans Lichtenstein, Silvia Ebert, Manfred Krieg
  • Patent number: 5384381
    Abstract: Graft copolymers having improved phase binding between the graft base and the grafted-on polymer, are prepared from:a) a grafted-on polymer phase containing one or more monomers from the group consisting of (meth)acrylates of alcohols having 1 to 10 carbon atoms, vinyl esters of saturated aliphatic carboxylic acids having 2 to 10 carbon atoms, olefins, vinyl halides, styrene and styrene derivatives, andb) a peroxy group-containing copolymer phase containing from 0.01 to 20% by weight of an olefinically unsaturated peroxy compound of the general formula I or II ##STR1## where R.sup.1 is a chemical bond or a linear or branched alkyl chain having 1 to 10 carbon atoms or a cycloalkyl group having 3 to 10 carbon atoms, R.sup.2 and R.sup.3 are an alkyl group having 1 to 4 carbon atoms, R.sup.4 is an alkyl group or an alkyl-substituted phenyl group having 3 to 12 carbon atoms, and R.sup.5 is a cycloalkyl group having 3 to 12 carbon atoms, and from 80 to 99.
    Type: Grant
    Filed: November 15, 1993
    Date of Patent: January 24, 1995
    Assignee: Wacker Chemie GmbH
    Inventors: Klaus Kohlhammer, Hermann Petersen, Walter Dobler
  • Patent number: 5371159
    Abstract: An improved solution polymerization process is provided wherein vinyl monomers are polymerized in the presence of at least one reactive modifier which is a substituted alpha-olefin that incorporates at least three ether groups, is hydrophilic, and has a molecular weight of at least about 200. The modified vinyl polymers so produced are characterized by various improved physical properties including, in particular, electrical characteristics such as antistatic capacity.
    Type: Grant
    Filed: February 2, 1993
    Date of Patent: December 6, 1994
    Assignee: Asahi Denka Kogyo K.K.
    Inventors: Masahide Tsuzuki, Kaoru Komiya
  • Patent number: 5367015
    Abstract: Preparation of soluble polyvinyl acetals having a low degree of crosslinking, which show improved melt viscosity characteristics, by acetalization of soluble polyvinyl alcohols having a low degree of crosslinking, which have been obtained by hydrolysis or alcoholysis of soluble copolymers having a low degree of crosslinking of vinyl esters and monomers having multiple ethylenic unsaturations, for example, glyoxal bisacrylamide. As against comparable non-crosslinked, soluble polyvinyl acetals, polyvinyl acetals having a low degree of crosslinking according to the present invention show increased intrinsic viscosities and surprisingly exhibit advantageous properties in thermoplastic forming, in particular when extruded in a plastified form. The polyvinyl acetals having a low degree of crosslinking furthermore have improved mechanical properties in comparison with non-crosslinked polyvinyl acetals and, in the form of plastified films, are particularly advantageously employed in the production of composite glass.
    Type: Grant
    Filed: October 2, 1992
    Date of Patent: November 22, 1994
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Matthias Gutweiler, Matthias Kroggel
  • Patent number: 5346974
    Abstract: This invention provides polyether polycarboxylate compositions selected from the group consisting of polyether polycarboxylates which may be prepared by oxidizing copolymers of furan and maleic anhydride, and other polyether polycarboxylate compositions prepared by oxidizing novel, intermediate polymers of furan, maleic anhydride, and at least one copolymerizable comonomer, selected from the group consisting of furan, alkenyl alkyl ethers, alkyl acrylates, alkenyl carboxyalkyl ethers, vinyl esters of carboxylic acids, unsaturated carboxylic acids, unsaturated dicarboxylic acids and their anhydrides and esters, and olefins. This invention also provides novel, unoxidized terpolymer intermediates comprising furan, maleic anhydride, and at least one copolymerizable comonomer, other than furan and maleic anhydride, selected from the above group, as well as a process for oxidizing these polymers and the furan and maleic anhydride copolymers.
    Type: Grant
    Filed: September 17, 1992
    Date of Patent: September 13, 1994
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Carmine P. Iovine, Rama S. Chandran, John C. Leighton
  • Patent number: 5319041
    Abstract: This invention relates to an improved process for producing a clear solution of vinylpyrrolidone (VP) and vinyl acetate (VA) monomers which comprises, in an anhydrous system,(a) reacting a C.sub.2 to C.sub.3 alcoholic solution containing said VA monomer and between about 60 and about 80 wt. % portion of total VP monomer in the presence of between about 0.05 and about 0.3 wt. % of a free radical initiator selected from the group consisting of tertamylperoxy pivalate and 2,2-azobis(2-methylbutyronitrile) or a mixture thereof for a period of from about 5 to about 10 hours, at a temperature between about 60.degree. and about 110.degree. C.;(b) gradually adding the remaining VP monomer in C.sub.2 to C.sub.3 alcohol solution at reaction temperature after the addition of the VA monomer is complete;(c) raising the temperature of the resulting reaction mixture to between about 110.degree. and about 150.degree. C.;(d) continuing the polymerization reaction at said higher temperature in the presence of from about 0.
    Type: Grant
    Filed: March 26, 1993
    Date of Patent: June 7, 1994
    Assignee: ISP Investments Inc.
    Inventors: Yuanzhen Zhong, Hemant Parikh, Paul D. Taylor, Terry E. Smith
  • Patent number: 5310841
    Abstract: A liquid composition, polymerizable by free-radical polymerization to yield organic glasses which are endowed with characteristics of low water absorption and high thermal stability, is constituted by the product of transesterification of diallyl-carbonate with a cycloaliphatic diol or a mixture of cycloaliphatic diols, from among said diols 1,4-cyclohexane-di-methanol and 3(4),8(9)-bis-(hydroxymethyl)tricyclo[5.2.1.0.sup.2.6 ]decane being preferred.
    Type: Grant
    Filed: September 26, 1990
    Date of Patent: May 10, 1994
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Fiorenzo Renzi, Franco Rivetti, Ugo Romano
  • Patent number: 5298327
    Abstract: A plastic light conduit of cross-linked polymer material having good light transmitting characteristics, without voids or noticeable bubbles, is disclosed. Also disclosed is a method of manufacture and an apparatus, involving progressive heating of reactive monomer mixture in a tube which is submerged in a progressive reactor utilizing cold oil to maintain a cold, non-reacting zone, and hot water to create a hot zone that causes reaction, while simultaneously carrying away the excess exothermic heat of reaction.
    Type: Grant
    Filed: January 23, 1989
    Date of Patent: March 29, 1994
    Assignee: Lumenyte International Corporation
    Inventors: Jamshid Zarian, John A. Robbins
  • Patent number: 5298577
    Abstract: A solution polymerisation process carried out continuously in a cascade produces high molecular weight gel-free ethylene terpolymers having on the one hand high resistance to fuels, oils and organic solvents and on the other hand high flexibility even at low temperatures when narrow ranges are adhered to in respect of solvent content, pressure, temperature control and degree of conversion.
    Type: Grant
    Filed: December 12, 1989
    Date of Patent: March 29, 1994
    Assignee: Bayer AG
    Inventors: Wolfgang Baade, Werner Obrecht, Christian Ohm, Rudolf Casper, Kurt P. Neurer, Gerd Sylvester
  • Patent number: 5294693
    Abstract: A copolymer comprised of at least one monomer having ethylenic unsaturation and a carboxylic acid group, optionally at least one monomer having ethylenic unsaturation and not having a carboxylic acid group, at least one oxyalkylated monomer having ethylenic unsaturation and terminated by a fatty hydrophobic chain having at least 26 C atoms, and optionally at least one monomer having at least two sites of ethylenic unsaturation. The copolymer is employed as a modifier of rheological properties, stabilizing agent, and/or an antisedimentation or suspension agent for coarse mineral or organic materials, in applications such as drilling muds, textile printing pies, cosmetics, detergents, plant protection, and paints and coatings.
    Type: Grant
    Filed: June 29, 1993
    Date of Patent: March 15, 1994
    Assignee: Coatex S.A.
    Inventors: Jean-Bernard Egraz, Henri Grondin, Jean-Marc Suau