Interpolymer Of An Ester Derived From Ethylenically Unsaturated Alcohol, E.g., Interpolymer Of Vinyl Acetate, Etc. Patents (Class 526/330)
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Patent number: 6117934Abstract: The invention is a surfactant composition comprising about 20 weight % to about 76 weight % of a fatty alcohol ethoxylate having a degree of ethoxylation of at least 14, about 4 weight % to about 40 weight % alkylpolyglycoside, and about 20 weight % to about 60 weight % water, wherein said composition is a liquid at room temperature, free of gel or solid phase, lattices containing said surfactant composition and a process for making said lattices.Type: GrantFiled: January 20, 1998Date of Patent: September 12, 2000Assignee: Henkel CorporationInventors: Rudolph Klima, Wallace H. Pippin, Marcie Natale, Thomas Hopkins, Ching Feng, Dieter Feustel
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Patent number: 6075107Abstract: The use of copolymers ofA) 60-99 mol % of N-vinylpyrrolidone, andB) 1-40 mol % of a monomer selected from the group ofb1) C.sub.8 -C.sub.30 -alkyl esters of monoethylenically unsaturated C.sub.3 -C.sub.8 -carboxylic acids,b2) N-alkyl- or N,N-dialkyl-substituted amides of acrylic acid or of methacrylic acid with C.sub.8 -C.sub.18 -alkyl radicals, orb3) vinyl esters of aliphatic C.sub.8 -C.sub.30 -carboxylic acids, or mixtures of these monomers,as surface-active substances in preparations of water-insoluble substances.Type: GrantFiled: May 7, 1998Date of Patent: June 13, 2000Assignee: BASF AktiengesellschaftInventors: Stephan Kothrade, Helmut Meffert, Gunther Berndl, Axel Sanner, Stefan Stein, Volker Schehlmann, Folker Ruchatz
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Patent number: 6048955Abstract: The present invention relates to a modacrylic copolymer composition comprising acrylonitrile, vinylidene chloride, vinyl acetate, and at least one ionic comonomer. In one embodiment, the modacrylic copolymer composition comprises from about 45 to about 60% acrylonitrile, from about 35 to about 50% vinylidene chloride, from about 0.5 to about 5% vinyl acetate, and up to about 2% of a salt of p-sulfophenyl methallyl ether by weight of the total composition. The copolymer composition of the present invention provides acceptable color while having acceptable flame resistance.Type: GrantFiled: February 2, 1999Date of Patent: April 11, 2000Assignee: Solutia Inc.Inventor: Bruce E. Wade
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Patent number: 6048953Abstract: A curable liquid resin composition containing 100 parts by weight of the following (meth)acrylic liquid resin (A) and 1 to 1,000 parts by weight of a (meth)acrylic monomer (B) having an unsaturated double bond in its molecule and having a number average molecular weight of 1,000 or less, the (meth)acrylic liquid resin (A) being a liquid resin which is obtained by polymerizing monomers containing an alkyl (meth)acrylate monomer (a-1-1) of the formula (1),CH.sub.2 C(R.sup.1)COO--R.sup.2 (1)wherein R.sup.1 is a hydrogen atom or CH.sub.3 and R.sup.2 is an alkyl group,and/or an alkylene glycol (meth)acrylate monomer (a-1-2) of the formula (2) ,CH.sub.2 .dbd.C(R.sup.1)COO(C.sub.n H.sub.2n O).sub.m R.sup.3(2)wherein R.sup.1 is a hydrogen atom or CH.sub.3, R.sup.Type: GrantFiled: February 3, 1998Date of Patent: April 11, 2000Assignee: Toyo Ink Manufacturing Co., Ltd.Inventors: Miki Kawashima, Kunio Horiuchi, Hiroaki Tanaka
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Patent number: 6008262Abstract: The present invention relates to a foamable composition comprising a low viscosity thermoplastic composition comprising at least one ethylene/.alpha.-olefin. The foamable composition may comprise a single ethylene/.alpha.-olefin or a blend of such. Optionally, the foamable composition may further comprise at least one diluent including waxes, plasticizers such as oil, tackifying resin, and mixtures thereof. The present invention also relates to a method of foaming such compositions and articles constructed therefrom. More specifically, the present invention relates to foamable thermoplastic compositions having particular utility as cabinet sealant and as foam layers in disposable articles such as disposable diapers, incontinent devices, medical devices such as bandages and dressings, as well as a variety of other uses.Type: GrantFiled: September 16, 1997Date of Patent: December 28, 1999Assignee: H.B. Fuller Licensing & Financing, Inc.Inventors: Kevin W. McKay, Eugene R. Simmons, Donald P. Woodbridge
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Patent number: 5994485Abstract: A vinyl chloride/vinyl acetate copolymer characterized in that it has a peak at a signal position of from 6.0 to 8.0 ppm in the .sup.1 H-NMR measurement.Type: GrantFiled: May 20, 1998Date of Patent: November 30, 1999Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Hirohisa Otake, Yukihisa Hoshino
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Patent number: 5907011Abstract: Heterogeneous, solvent- and plasticizer-free polyvinyl ester dispersions which are stabilized by protective colloids and which have a minimum filming temperature of below 10.degree. C. are disclosed. These dispersions are made of a mixture of(a) a homopolymer or copolymer A having a glass transition temperature of above 20.degree. C., whereby homopolymer or copolymer A includes(i) from 85 to 100% by weight of at least one vinyl ester of carboxylic acids having 1 to 18 carbon atoms;(ii) from 0 to 5% by weight of at least one .alpha., .beta.-unsaturated carboxylic acid;(iii) from 0 to 5% by weight of at least one mono-olefinically unsaturated compound (a3) having at least one amino or amido group, and(iv) from 0 to 5% by weight of at least one polyethylenically unsaturated monomer, and(b) a copolymer B having a glass transition temperature of below 20.degree. C.Type: GrantFiled: March 31, 1997Date of Patent: May 25, 1999Assignee: Clariant GmbHInventors: Martin Jakob, Detlev Seip, Volker Matz, Stefan Hess
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Patent number: 5883169Abstract: Disclosed is a lens wafer suitable for use in preparing a laminated lens which wafer has a coating on at least one surface thereof in the form of a peelable protective film.Type: GrantFiled: April 17, 1996Date of Patent: March 16, 1999Assignee: Sola International Holdings Ltd.Inventors: David P. Spector, A. N. Sunder Ram
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Patent number: 5866655Abstract: A vinyl alcohol polymer with a side chain being a hydroxyalkyl group having 2 to 20 carbon atoms is disclosed. Conventional water-soluble vinyl alcohol polymers gives, where they have a high interfacial activity, an aqueous solution with much-foaming and hence a problem when used for commercial purposes. On the other hand, the vinyl alcohol polymer of the present invention gives, where it is water-soluble, an aqueous solution with less-foaming in spite of its high interfacial activity, and hence an excellent industrial applicability. The vinyl alcohol polymer of the present invention is useful as thermoplastic resin and dispersion stabilizer. In addition, the vinyl alcohol polymer of the present invention is usable for various purposes, e.g.Type: GrantFiled: May 28, 1997Date of Patent: February 2, 1999Assignee: Kuraray Co., Ltd.Inventors: Naoki Fujiwara, Takeshi Kusudou, Takaharu Kawahara, Toshiaki Sato
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Patent number: 5859160Abstract: A free radical curable composition that includes a free radical curable and a vinyl aromatic compound that is chemically different than the free radical curable component, wherein the vinyl aromatic compound is present in an amount sufficient to decelerate the cure rate of the free radical composition without adversely effecting completion of cure and the properties of the curable composition after it has cured. The composition is particularly useful as a two part adhesive that includes a free radical catalyst system and a diene elastomer.Type: GrantFiled: January 9, 1997Date of Patent: January 12, 1999Assignee: Lord CorporationInventors: Robin F. Righettini, Kirk J. Abbey
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Patent number: 5849840Abstract: A dispersing stabilizer including (A) a polyvinyl alcohol resin containing oxyalkylene groups and having a surface tension of 35 to 55 dyne/cm at 20.degree. C. as a 1% by weight aqueous solution, or said resin and (B) a water-soluble polymer or a polyvinyl alcohol resin having a low degree of hydrolysis and a low degree of polymerization. When using the dispersing stabilizer of the present invention, both of a porosity and a bulk density of a polyvinyl resin particle can be improved at the same time, and, in addition, a distribution of particle size and a uniformity of porosity can be further improved.Type: GrantFiled: April 23, 1997Date of Patent: December 15, 1998Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki KaishaInventors: Motokazu Maruhashi, Kizo Ohnishi
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Patent number: 5830439Abstract: An improved hydrocarbon tolerant, aerosol hair spray resin composition includes a fixative polymer which is a tetrapolymer consisting essentially of (1) vinyl acetate, (2) vinyl neodecanoate or vinyl neononanoate, (3) monoisobutyl maleate and (4) N-t-butyl acrylamide, N-t-octyl acrylamide, or isobornyl (meth)acrylate, in a molar ratio from 10:10:15:1 to 26:1:15:1, preferably in a molar ratio of 12.5:7.5:15:1, exhibits advantageous small spray particle size, short tack and drying times, and hydrolytic stability, which are the desired performance characteristics on hair.Type: GrantFiled: May 16, 1997Date of Patent: November 3, 1998Assignee: ISP Investments Inc.Inventors: Jui-Chang Chuang, Edward Walls, Jr.
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Patent number: 5817727Abstract: The present invention pertains to a film for detecting chemical substances comprising a homopolymer or a copolymer having recurring units represented by the following formula (I): ##STR1## wherein X is --H, --F, --Cl, --Br, --CH.sub.3, --CF.sub.3, --CN or --CH.sub.2 CH.sub.3 ; and R.sup.1 is --R.sup.2 or --Z--R.sup.2 ;wherein Z is --O--, --S--, --NH--, --NR.sup.2' --, --(C.dbd.Y)--, --(C.dbd.Y)--Y--, --Y--(C.dbd.Y)--, --(SO.sub.2)--, --Y'--(SO.sub.2)--, --(SO.sub.2)--Y'--, --Y'--(SO.sub.2)--Y'--, --NH--(C.dbd.O)--, --(C.dbd.O)--NH--, --(C.dbd.O)--NR.sup.2' --, --Y'--(C.dbd.Y)--Y'-- or --O--(C.dbd.O)--(CH.sub.2).sub.n --(C.dbd.O)--O--;wherein Y is independently O or S, and Y' is independently O or NH, and n is an integer of 0 to 20;and wherein R.sup.2 and R.sup.2' represent independently a hydrogen atom, a linear alkyl group, a branched alkyl group, a cycloalkyl group, an unsaturated hydrocarbon group, an aryl group, a saturated or unsaturated hetero ring or derivatives thereof, provided that R.sup.Type: GrantFiled: June 7, 1995Date of Patent: October 6, 1998Assignee: Hoechst AktiengesellschaftInventors: Werner Prass, Thomas Stehlin, Yuan Liu, Shizuo Ogura, Tetsu Yamamoto, Akihiko Tokida, Kenji Motosugi
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Patent number: 5789510Abstract: Terpolymers obtained by copolymerization of ethylene, a vinyl ester of at least one aliphatic monocarboxylic acid of 2 to 20 carbon atoms in the molecule and bicyclo?2.2.1!hept-2-ene (also referred to as norbornene) or its derivatives, a process for their preparation and their use as additives for mineral oils and mineral oil distillates.Type: GrantFiled: May 19, 1997Date of Patent: August 4, 1998Assignee: Hoechst AktiengesellschaftInventors: Matthias Krull, Werner Reimann
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Patent number: 5753753Abstract: This invention relates to an improved process for producing a vinyl alcohol containing polymer having a narrow particle size without substantial reactor fouling. The process for producing the vinyl alcohol containing polymer involves hydrolyzing a vinyl ester containing polymer, e.g., a polymer containing polymerized vinyl alkanoate units in the presence of an alcoholic medium and a hydrolysis catalyst in the presence of an alcoholic medium having finely divided, inert material such as an alkali metal carbonate dispersed therein. The finely divided inert material acts as nucleating sites for the polyvinyl alcohol as it precipitates from the solution during hydrolysis.Type: GrantFiled: February 19, 1997Date of Patent: May 19, 1998Assignee: Air Products and Chemicals, Inc.Inventors: Kien Van Phung, Dennis Sagl
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Patent number: 5747578Abstract: A copolymer in dispersion or redispersible powder form which is stabilized by a protective colloid and has a glass transition temperature of -40.degree. to 10.degree. C. and an ethylene content of at least 30% by weight, based on the total amount of monomers, with a heterogeneous build-up of the copolymer particles, including a first polymer phase, which includes vinyl acetate and >40% by weight of ethylene, based on the total amount of monomers in this phase, and a last copolymer phase, which includes vinyl acetate and 5 to 40% by weight of ethylene, based on the total amount of monomers in this phase, is suitable, for example, as a binder in building materials.Type: GrantFiled: July 30, 1996Date of Patent: May 5, 1998Assignee: Clariant GmbHInventors: Ludwig Schmitz, Stefan Hess, Bettina Gerharz
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Patent number: 5728788Abstract: The present invention provides a process of producing a vinyl acetate polymer by homopolymerization of a vinyl acetate monomer or copolymerization of a vinyl acetate monomer and another copolymerizable comonomer, wherein a polymerization initiator is an organic peroxide having a half life at 60.degree. C. of 10 to 110 minutes, and a polymerization liquid contains at least one carboxylic acid or its salt, said carboxylic acid being selected from the group consisting of a hydroxycarboxylic acid and a polycarboxylic acid.Type: GrantFiled: March 11, 1997Date of Patent: March 17, 1998Assignee: Kuraray Co., Ltd.Inventors: Hiroshi Takachi, Kazuyori Yoshimi
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Patent number: 5719246Abstract: According to the present invention, there is provided an acrylic copolymer having a number average molecular weight of 1000-500,000, which comprises 1-90 % by weight of a structural unit represented by the following general formula ##STR1## (wherein R represents a hydrogen atom or a methyl group) and 99-10 % by weight of a structural unit-derived from an ethylenic unsaturated monomer, an acrylic copolymer composition and a paint containing the same.The coat obtained by applying the acrylic copolymer has excellent abrasion resistance, chemical resistance, flexibility, strength and the like.Type: GrantFiled: December 20, 1996Date of Patent: February 17, 1998Assignee: Mitsubishi Chemical CorporationInventors: Yasuyuki Taniguchi, Yuji Soejima
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Patent number: 5686545Abstract: A liquid resin having a number average molecular weight of 10,000 to 200,000 and a viscosity, measured at 50.degree. C., of 500 to 30,000 cps, obtained by the copolymerization of a composition containing(a) 35 to 98% by weight of a monomer of the formula,CH.sub.2 =C(R.sup.1)COOR.sup.2wherein R.sup.1 is hydrogen or methyl and R.sup.2 is a hydrocarbon group having 4 to 22 carbon atoms,(b) 2 to 40% by weight of a polymerizable unsaturated carboxylic acid, and(c) 0 to 60% by weight of other polymerizable vinyl monomer.Type: GrantFiled: August 5, 1996Date of Patent: November 11, 1997Assignee: Toyo Ink Manufacturing Co., Ltd.Inventors: Miki Kawashima, Kunio Horiuchi
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Patent number: 5684108Abstract: An ethylene-based copolymer which is suitable as a flow improver for mineral oil middle distillates and is composed ofa) from 50 to 94% by weight of ethylene;b) from 3 to 30% by weight of one or more vinyl esters of C.sub.2 -C.sub.6 -monocarboxylic acids;c) from 3 to 20% by weight of one or more aminoalkyl acrylates of the formula I ##STR1## which R.sup.1 is hydrogen or methyl, R.sup.2 and R.sup.3 are identical or different and are each hydrogen or C.sub.1 -C.sub.6 -alkyl and A.sup.1 is straight-chain or branched C.sub.2 -C.sub.10 -alkylene; andd) from 0 to 10% by weight of one or more monomers which are copolymerizable with the monomers a) to c), wherein copolymers containing vinyl acetate as monomer b) and having a number average molecular weight of from 5,000 to 50,000 are excluded from the scope of the copolymer.Type: GrantFiled: April 2, 1996Date of Patent: November 4, 1997Assignee: BASF AktiengesellschaftInventors: Hans-Joachim Muller, Bernd Wenderoth, Albin Berger, Dieter Littmann, Roger Klimesch, Knut Oppenlander, Bernd Lothar Marczinke, Thomas Ruhl, Marc Heider
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Patent number: 5665844Abstract: The present invention pertains to a film for detecting chemical substances comprising a homopolymer or a copolymer having recurring units represented by the following formula (I): ##STR1## wherein X is --H, --F, --Cl, --Br, --CH.sub.3, --CF.sub.3, --CN or --CH.sub.2 CH.sub.3 ; and R.sup.1 is --R.sup.2 or --Z--R.sup.2 ;wherein Z is --O--, --S--, --NH--, --NR.sup.2' --, --(C.dbd.Y)--, --(C.dbd.Y)--Y--, --Y--(C.dbd.Y)--, --(SO.sub.2)--, --Y'--(SO.sub.2)--, --(SO.sub.2)--Y'--, --Y'--(SO.sub.2)--Y'--, --NH--(C.dbd.O)--, --(C.dbd.O)--NH--, --(C.dbd.O)--NR.sup.2' --, --Y'--(C.dbd.Y)--Y'-- or --O--(C.dbd.O)--(CH.sub.2).sub.n --(C.dbd.O)--O--;wherein Y is independently O or S, and Y' is independently O or NH, and n is an integer of 0 to 20;and wherein R.sup.2 and R.sup.2' represent independently a hydrogen atom, a linear alkyl group, a branched alkyl group, a cycloalkyl group, an unsaturated hydrocarbon group, an aryl group, a saturated or unsaturated hetero ring or derivatives thereof, provided that R.sup.Type: GrantFiled: November 15, 1993Date of Patent: September 9, 1997Assignee: Hoechst AktiengesellschaftInventors: Werner Prass, Thomas Stehlin, Yuan Liu, Shizuo Ogura, Tetsu Yamamoto, Akihiko Tokida, Kenji Motosugi
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Patent number: 5665840Abstract: The present invention describes a water-soluble crosslinkable prepolymer that comprises, in the copolymer chain, units derived from the following monomeric structural units: a vinyl lactam (a), vinyl alcohol (b), optionally a lower alkanecarboxylic acid vinyl ester (c), a vinylic crosslinking agent (d) and optionally a vinylic photoinitiator (e); a process for the preparation of the novel prepolymers; crosslinked water-insoluble polymeric networks therefrom; hydrogels and moulded articles made from the crosslinked water-insoluble polymeric networks, especially contact lenses; and a process for the manufacture of hydrogels and finished contact lenses using the mentioned crosslinkable water-soluble prepolymers.Type: GrantFiled: November 3, 1995Date of Patent: September 9, 1997Assignee: Novartis CorporationInventors: Thomas Pohlmann, Achim Muller, Bernhard Seiferling
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Patent number: 5605995Abstract: Hydroxy-functional allyl terpolymers are disclosed. The terpolymers comprise recurring units of an allyl ester, an allylic alcohols or propoxylated allylic alcohol, and a vinyl monomer. The high hydroxyl group content and favorable solubility characteristics make the terpolymers easy to formulate into many polymer products, including polyurethanes, polyesters, melamines, alkyds, uralkyds, and other thermoset polymers.Type: GrantFiled: March 18, 1996Date of Patent: February 25, 1997Assignee: Arco Chemical Technology, L.P.Inventor: Shao-Hua Guo
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Patent number: 5599890Abstract: A polymeric binder for ceramic materials is provided. The polymeric binder has a temperature range for pyrolysis which is broader than that for polymeric binders conventionally used in ceramic materials. The broader pyrolysis range provides for gradual removal of the binder when a ceramic part containing the binder is heated. Gradual removal of the binder minimizes the formation of voids and cracking in the ceramic part. Voids or cracking can lead to defects in the part, and destruction of the part may occur during removal if a polymeric binder used in the part is rapidly decomposed into gases. Therefore the polymeric binder of the present invention provides for ceramic parts with fewer defects and less chance of destruction than occurs with polymeric binders conventionally used in ceramic parts.Type: GrantFiled: March 21, 1994Date of Patent: February 4, 1997Assignee: Rohm and Haas CompanyInventor: Xun Tang
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Patent number: 5578689Abstract: Vinyl polymers, e.g., the homo- and copolyvinyl chlorides, are prepared in one or more stages, to a degree of conversion of at least 50%, by suspended emulsion polymerizing at least one vinyl monomer, e.g., vinyl chloride, said at least one monomer having dispersed therein finely divided droplets of an aqueous solution of at least one component of a polymerization initiating system, and wherein the amount of water in said aqueous solution constitutes at least 19%, and preferably at least 20% by weight of the at least one monomer.Type: GrantFiled: February 22, 1994Date of Patent: November 26, 1996Assignee: AtochemInventors: Pierre Nogues, Francois Erard
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Patent number: 5576405Abstract: A liquid resin having a number average molecular weight of 10,000 to 200,000 and a viscosity, measured at 50.degree. C., of 500 to 30,000 cps, obtained by the copolymerization of a composition containing(a) 35 to 98% by weight of a monomer of the formula,CH.sub.2 .dbd.C(R.sup.1)COOR.sup.2wherein R.sup.1 is a hydrogen or methyl and R.sup.2 is a hydrocarbon group having 4 to 22 carbon atoms,(b) 2 to 40% by weight of a polymerizable unsaturated carboxylic acid, and(c) 0 to 60% by weight of other polymerizable vinyl monomer.Type: GrantFiled: June 8, 1994Date of Patent: November 19, 1996Assignee: Toyo Ink Manufacturing Co., Ltd.Inventors: Miki Kawashima, Kunio Horiuchi
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Patent number: 5574120Abstract: The preparation of terpolymers by free radical polymerization of an unsaturated dicarboxylic acid with an unsaturated monocarxylic acid and a further saturated monomer which contains no free carboxyl groups, in an aqueous medium, is carried out, according to the invention, in the presence of surfactant compounds.Type: GrantFiled: November 6, 1995Date of Patent: November 12, 1996Assignee: Chemische Fabrik Stockhausen GmbHInventors: Klaus Heidel, Wulf Ruback, Frank Krause
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Patent number: 5565537Abstract: This invention provides a maleimide-based copolymer in which, because its molecular weight-retention ratio at high temperature is high, deterioration of physical properties by heating is little. Also, this invention provides a process wherein a maleimide-based copolymer is arranged so as not to heat more than necessity and thereby a maleimide-based copolymer containing only a small amount of residual volatile components is efficiently obtained without deterioration of physical properties. The maleimide-based copolymer is such as having a glass transition temperature of 170.degree. C. or higher, a weight-average molecular weight of 100,000 to 500,000, and a molecular weight-retention ratio of 90% or more when heated at 280.degree. C. for 10 minutes.Type: GrantFiled: June 6, 1995Date of Patent: October 15, 1996Assignee: Nippon Shokubai Co., Ltd.Inventors: Kimio Uda, Fumioki Shimoyama, Kazumi Fujioka
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Patent number: 5548039Abstract: A polymer scale deposition preventive agent for use in polymerization of a monomer having an ethylenically unsaturated double bond, comprising an alkaline solution containing a condensation product of (A) an anthraquinone compound having at least two amino groups and (B) at least one compound selected from the group consisting of benzoquinone compounds and naphthoquinone compounds. When the monomer is polymerized in a polymerization vessel having a coating formed by applying the aforementioned preventive agent to inner wall surfaces followed by drying, polymer scale can be effectively prevented from being deposited not only on the areas located in the liquid-phase region but also on the areas around the interface between the gas and liquid phases in the polymerization vessel. When an obtained polymer is formed into a sheet or the like, it is possible to obtain a formed product having few fish eyes and low initial coloration.Type: GrantFiled: December 27, 1994Date of Patent: August 20, 1996Assignee: Shin-Etsu Chemical Co., LtdInventors: Toshihide Shimizu, Mikio Watanabe
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Patent number: 5543483Abstract: Hydroxy-functional allyl terpolymers are disclosed. The terpolymers comprise recurring units of an allyl ester, an allylic alcohols or propoxylated allylic alcohol, and a vinyl monomer. The high hydroxyl group content and favorable solubility characteristics make the terpolymers easy to formulate into many polymer products, including polyurethanes, polyesters, melamines, alkyds, uralkyds, and other thermoset polymers.Type: GrantFiled: May 15, 1995Date of Patent: August 6, 1996Assignee: ARCO Chemical Technology, L.P.Inventor: Shao-Hua Guo
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Patent number: 5540987Abstract: The free formaldehyde content of the emulsion polymer, the amount of emitted formaldehyde and, even more particularly, of the finished nonwoven or textile may be substantially reduced by the use of a particular initiator system comprising a hydrophobic hydroperoxide and ascorbic acid. Moreover, this reduction in formaldehyde levels is accompanied by an unexpected improvement in the tensile properties of the emulsion binders.Type: GrantFiled: September 28, 1994Date of Patent: July 30, 1996Assignee: National Starch and Chemical Investment Holding CorporationInventors: Paul R. Mudge, James L. Walker, Ronald Pangrazi
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Patent number: 5532329Abstract: Copolymers which are self-curable with atmospheric humidity and are based on acrylic, methacrylic and/or vinyl esters which have been prepared using silicon-containing regulators, and mixtures of such polymers with crosslinkers, are suitable as adhesive, sealing and coating compositions which are self-curable with atmospheric humidity.Type: GrantFiled: December 28, 1994Date of Patent: July 2, 1996Assignee: BASF AktiengesellschaftInventors: Ulrich Filges, Oral Aydin, Gerhard Auchter, Juergen Barwich, Hermann Anders, Werner Langer, Klaus Vorspohl
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Patent number: 5519103Abstract: Allyl ester copolymers with allylic alcohols and propoxylated allylic alcohols are disclosed. The high primary hydroxyl group content and favorable solubility characteristics make the allyl ester copolymers easy to formulate into many polymer products, including polyurethanes, polyesters, melamines, alkyds, uralkyds, and crosslinked polymeric resins.Type: GrantFiled: April 28, 1995Date of Patent: May 21, 1996Assignee: Arco Chemical CompanyInventor: Shao-Hua Guo
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Patent number: 5502136Abstract: A process is described for making substantially homogeneous copolymers comprising 50-90% of vinyl pyrrolidone (VP) and 10-50% of vinyl acetate (VA), by weight, which form clear aqueous solutions.Type: GrantFiled: December 28, 1994Date of Patent: March 26, 1996Assignee: ISP Investments Inc.Inventors: Yuanzhen Zhong, Philip F. Wolf, Yakir Reuven
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Patent number: 5480954Abstract: Allyl ester copolymers with allylic alcohols and propoxylated allylic alcohols are disclosed. The high hydroxyl group content and favorable solubility characteristics make the allyl ester copolymers easy to formulate into many polymer products, including polyurethanes, polyesters, melamines, alkyds, uralkyds, and other thermoset polymers.Type: GrantFiled: September 21, 1994Date of Patent: January 2, 1996Assignee: ARCO Chemical Technology, L.P.Inventor: Shao-Hua Guo
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Patent number: 5476912Abstract: An adhesive which exhibits excellent adhesiveness and is capable of firmly adhering an acrylic resin and a silicone rubber together at a temperature of as low as about 20.degree. to 30.degree. C. requiring a time of as short as several minutes. The adhesive is obtained by dissolving in a solvent a novel silicone-modified acrylic copolymer having a polyorganosiloxane with an SiH reaction point on the side chain.Type: GrantFiled: June 30, 1994Date of Patent: December 19, 1995Assignee: Tokuyama CorporationInventors: Yasuhiro Hosoi, Osamu Iwamoto, Masataka Himeno
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Patent number: 5447727Abstract: The subject invention provides a surface-crosslinked water-absorbent polymer having improved properties. The subject invention further pertains to a process for preparing such a polymer. Through the use of a preferred primary crosslinking agent coupled with surface crosslinking, desirable absorptive properties are achieved. Suitable primary crosslinking agents include methylenebisacrylamide, bis(acrylamido)acetic acid and its salts, allyl acrylate, allyl methacrylate and esters or amides having both a vinyl and an allyl functionality.Type: GrantFiled: October 14, 1992Date of Patent: September 5, 1995Assignee: The Dow Chemical CompanyInventor: Andrew T. Graham
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Patent number: 5403905Abstract: Process for producing polyvinyl ester having a high degree of polymerization and an intrinsic viscosity of from 15 dl g.sup.-1 to 3.2 dl g.sup.-1, and a polyvinyl ester obtained thereby. The process comprises subjecting a vinyl ester monomer to emulsion polymerization using nonionic emulsifiers nonionic-anionic emulsifiers, or anionic emulsifiers and a redox initiator at a temperature of -60.degree. to 15.degree. C.Type: GrantFiled: February 3, 1994Date of Patent: April 4, 1995Assignee: Kuraray Company, Ltd.Inventors: Toshiaki Sato, Ken Yuki, Junnosuke Yamauchi, Takuji Okaya
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Patent number: 5395905Abstract: The present invention provides water-soluble poylmers containing, as polymerized units: (a) from about 3 to about 95 percent by weight of one or more cyclohexene anhydrides or the alkali metal or ammonium salts thereof. The present further provides aqueous polymerization processes for making the polymers. The water-soluble polymers are useful as water-treatment additives for boiler waters and cooling towers and as detergent additives acting as builders, anti-filming agents, dispersants, sequestering agents and encrustation inhibitors.Type: GrantFiled: January 12, 1993Date of Patent: March 7, 1995Assignee: Rohm and Haas CompanyInventors: Marianne P. Creamer, Thomas F. McCallum, III, Graham Swift, Barry Weinstein
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Patent number: 5395904Abstract: A process for making homogeneous copolymers of vinylpyrrolidone (VP) and vinyl acetate (VA) which form clear aqueous solutions and have high cloud points. The process involves precharging VP and VA monomers in a predetermined ratio, and then feeding VP and VA at a predetermined rate, the ratio of the components in the initial charge and the feeding rates for the monomer being selected in accordance with the reactivity rates of the monomers towards copolymerization as opposed to homopolymerization.Type: GrantFiled: December 7, 1993Date of Patent: March 7, 1995Assignee: ISP Investments Inc.Inventors: Yuanzhen Zhong, Hemant Parikh, Terry E. Smith
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Patent number: 5387634Abstract: Opaque tinted acrylic glass produced with organic pigments or with organic dyes, which in addition to the colorant, also contains an acid in the polymer matrix, exhibits improved resistance to weathering.Type: GrantFiled: January 15, 1993Date of Patent: February 7, 1995Assignee: Roehm GmbH Chemische FabrikInventors: Hans Lichtenstein, Silvia Ebert, Manfred Krieg
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Patent number: 5384381Abstract: Graft copolymers having improved phase binding between the graft base and the grafted-on polymer, are prepared from:a) a grafted-on polymer phase containing one or more monomers from the group consisting of (meth)acrylates of alcohols having 1 to 10 carbon atoms, vinyl esters of saturated aliphatic carboxylic acids having 2 to 10 carbon atoms, olefins, vinyl halides, styrene and styrene derivatives, andb) a peroxy group-containing copolymer phase containing from 0.01 to 20% by weight of an olefinically unsaturated peroxy compound of the general formula I or II ##STR1## where R.sup.1 is a chemical bond or a linear or branched alkyl chain having 1 to 10 carbon atoms or a cycloalkyl group having 3 to 10 carbon atoms, R.sup.2 and R.sup.3 are an alkyl group having 1 to 4 carbon atoms, R.sup.4 is an alkyl group or an alkyl-substituted phenyl group having 3 to 12 carbon atoms, and R.sup.5 is a cycloalkyl group having 3 to 12 carbon atoms, and from 80 to 99.Type: GrantFiled: November 15, 1993Date of Patent: January 24, 1995Assignee: Wacker Chemie GmbHInventors: Klaus Kohlhammer, Hermann Petersen, Walter Dobler
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Patent number: 5371159Abstract: An improved solution polymerization process is provided wherein vinyl monomers are polymerized in the presence of at least one reactive modifier which is a substituted alpha-olefin that incorporates at least three ether groups, is hydrophilic, and has a molecular weight of at least about 200. The modified vinyl polymers so produced are characterized by various improved physical properties including, in particular, electrical characteristics such as antistatic capacity.Type: GrantFiled: February 2, 1993Date of Patent: December 6, 1994Assignee: Asahi Denka Kogyo K.K.Inventors: Masahide Tsuzuki, Kaoru Komiya
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Patent number: 5367015Abstract: Preparation of soluble polyvinyl acetals having a low degree of crosslinking, which show improved melt viscosity characteristics, by acetalization of soluble polyvinyl alcohols having a low degree of crosslinking, which have been obtained by hydrolysis or alcoholysis of soluble copolymers having a low degree of crosslinking of vinyl esters and monomers having multiple ethylenic unsaturations, for example, glyoxal bisacrylamide. As against comparable non-crosslinked, soluble polyvinyl acetals, polyvinyl acetals having a low degree of crosslinking according to the present invention show increased intrinsic viscosities and surprisingly exhibit advantageous properties in thermoplastic forming, in particular when extruded in a plastified form. The polyvinyl acetals having a low degree of crosslinking furthermore have improved mechanical properties in comparison with non-crosslinked polyvinyl acetals and, in the form of plastified films, are particularly advantageously employed in the production of composite glass.Type: GrantFiled: October 2, 1992Date of Patent: November 22, 1994Assignee: Hoechst AktiengesellschaftInventors: Matthias Gutweiler, Matthias Kroggel
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Patent number: 5346974Abstract: This invention provides polyether polycarboxylate compositions selected from the group consisting of polyether polycarboxylates which may be prepared by oxidizing copolymers of furan and maleic anhydride, and other polyether polycarboxylate compositions prepared by oxidizing novel, intermediate polymers of furan, maleic anhydride, and at least one copolymerizable comonomer, selected from the group consisting of furan, alkenyl alkyl ethers, alkyl acrylates, alkenyl carboxyalkyl ethers, vinyl esters of carboxylic acids, unsaturated carboxylic acids, unsaturated dicarboxylic acids and their anhydrides and esters, and olefins. This invention also provides novel, unoxidized terpolymer intermediates comprising furan, maleic anhydride, and at least one copolymerizable comonomer, other than furan and maleic anhydride, selected from the above group, as well as a process for oxidizing these polymers and the furan and maleic anhydride copolymers.Type: GrantFiled: September 17, 1992Date of Patent: September 13, 1994Assignee: National Starch and Chemical Investment Holding CorporationInventors: Carmine P. Iovine, Rama S. Chandran, John C. Leighton
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Patent number: 5319041Abstract: This invention relates to an improved process for producing a clear solution of vinylpyrrolidone (VP) and vinyl acetate (VA) monomers which comprises, in an anhydrous system,(a) reacting a C.sub.2 to C.sub.3 alcoholic solution containing said VA monomer and between about 60 and about 80 wt. % portion of total VP monomer in the presence of between about 0.05 and about 0.3 wt. % of a free radical initiator selected from the group consisting of tertamylperoxy pivalate and 2,2-azobis(2-methylbutyronitrile) or a mixture thereof for a period of from about 5 to about 10 hours, at a temperature between about 60.degree. and about 110.degree. C.;(b) gradually adding the remaining VP monomer in C.sub.2 to C.sub.3 alcohol solution at reaction temperature after the addition of the VA monomer is complete;(c) raising the temperature of the resulting reaction mixture to between about 110.degree. and about 150.degree. C.;(d) continuing the polymerization reaction at said higher temperature in the presence of from about 0.Type: GrantFiled: March 26, 1993Date of Patent: June 7, 1994Assignee: ISP Investments Inc.Inventors: Yuanzhen Zhong, Hemant Parikh, Paul D. Taylor, Terry E. Smith
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Patent number: 5310841Abstract: A liquid composition, polymerizable by free-radical polymerization to yield organic glasses which are endowed with characteristics of low water absorption and high thermal stability, is constituted by the product of transesterification of diallyl-carbonate with a cycloaliphatic diol or a mixture of cycloaliphatic diols, from among said diols 1,4-cyclohexane-di-methanol and 3(4),8(9)-bis-(hydroxymethyl)tricyclo[5.2.1.0.sup.2.6 ]decane being preferred.Type: GrantFiled: September 26, 1990Date of Patent: May 10, 1994Assignee: Enichem Synthesis S.p.A.Inventors: Fiorenzo Renzi, Franco Rivetti, Ugo Romano
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Patent number: 5298327Abstract: A plastic light conduit of cross-linked polymer material having good light transmitting characteristics, without voids or noticeable bubbles, is disclosed. Also disclosed is a method of manufacture and an apparatus, involving progressive heating of reactive monomer mixture in a tube which is submerged in a progressive reactor utilizing cold oil to maintain a cold, non-reacting zone, and hot water to create a hot zone that causes reaction, while simultaneously carrying away the excess exothermic heat of reaction.Type: GrantFiled: January 23, 1989Date of Patent: March 29, 1994Assignee: Lumenyte International CorporationInventors: Jamshid Zarian, John A. Robbins
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Patent number: 5298577Abstract: A solution polymerisation process carried out continuously in a cascade produces high molecular weight gel-free ethylene terpolymers having on the one hand high resistance to fuels, oils and organic solvents and on the other hand high flexibility even at low temperatures when narrow ranges are adhered to in respect of solvent content, pressure, temperature control and degree of conversion.Type: GrantFiled: December 12, 1989Date of Patent: March 29, 1994Assignee: Bayer AGInventors: Wolfgang Baade, Werner Obrecht, Christian Ohm, Rudolf Casper, Kurt P. Neurer, Gerd Sylvester
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Patent number: 5294693Abstract: A copolymer comprised of at least one monomer having ethylenic unsaturation and a carboxylic acid group, optionally at least one monomer having ethylenic unsaturation and not having a carboxylic acid group, at least one oxyalkylated monomer having ethylenic unsaturation and terminated by a fatty hydrophobic chain having at least 26 C atoms, and optionally at least one monomer having at least two sites of ethylenic unsaturation. The copolymer is employed as a modifier of rheological properties, stabilizing agent, and/or an antisedimentation or suspension agent for coarse mineral or organic materials, in applications such as drilling muds, textile printing pies, cosmetics, detergents, plant protection, and paints and coatings.Type: GrantFiled: June 29, 1993Date of Patent: March 15, 1994Assignee: Coatex S.A.Inventors: Jean-Bernard Egraz, Henri Grondin, Jean-Marc Suau