Abstract: Ethylene-based polymers are characterized by a density from 0.92 to 0.955 g/cm3, a HLMI of less than 35 g/10 min, and a ratio of a number of short chain branches (SCBs) per 1000 total carbon atoms at Mz to a number of SCBs per 1000 total carbon atoms at Mn in a range from 11.5 to 22. These polymers can have a higher molecular weight (HMW) component and a lower molecular weight (LMW) component, in which a ratio of a number of SCBs per 1000 total carbon atoms at Mn of the HMW component to a number of SCBs per 1000 total carbon atoms at Mn of the LMW component is in a range from 10.5 to 22. These ethylene polymers can be produced using a dual catalyst system containing an unbridged metallocene compound with an indenyl group having at least one halogen-substituted hydrocarbyl substituent with at least two halogen atoms, and a single atom bridged metallocene compound with a fluorenyl group and a cyclopentadienyl group.

Abstract: Described herein are caps or closures made from a resin composition having at least one polyethylene having a density of at least 0.940 g/cm3 when measured following the ISO 1183-2 method at 23° C.; erucamide; and at least 700 ppm based on the total weight of the resin composition of at least one ultraviolet absorber selected from the hydroxyphenylbenzotriazole class. A process for the production of such caps or closures is also described herein.

Abstract: In some embodiments, ethylene-propylene random copolymers as viscosity modifiers were synthesized with pyridyldiamido catalyst systems and a chain transfer agent. In some embodiments, the present disclosure provides for ethylene-propylene random copolymers having an ethylene content between about 45 wt % and about 55 wt %. In some embodiments, the ethylene-propylene random copolymer is used as a viscosity modifier in a lubricating composition and a fuel composition.

Abstract: Embodiments of methods for producing a trimodal polymer in a solution polymerization process comprise three solution polymerization reactors organized in parallel or in series.

Abstract: Supported chromium catalysts containing a solid oxide and 0.1 to 15 wt. % chromium, in which the solid oxide or the supported chromium catalyst has a particle size span from 0.5 to 1.4, less than 3 wt. % has a particle size greater than 100 ?m, and less than 10 wt. % has a particle size less than 10 ?m, can be contacted with an olefin monomer in a loop slurry reactor to produce an olefin polymer. Representative ethylene-based polymers produced using the chromium catalysts have a HLMI of 4 to 70 g/10 min, a density from 0.93 to 0.96 g/cm3, from 150 to 680 ppm solid oxide (such as silica), from 1.5 to 6.8 ppm chromium, and a film gel count of less than 15 catalyst particle gels per ft2 of 25 micron thick film and/or a gel count of less than or equal to 50 catalyst particles of greater than 100 ?m per five grams of the ethylene polymer.

Abstract: The present invention relates to a process for supply of a polymerization catalyst component to a polymerization reactor which comprises: a. Providing a first stream comprising the catalyst component in a first line, which first line is connected to and downstream of a pump outlet or of a flow control valve, b. Providing a diluent stream in a second line, c. Contacting the first stream and the diluent stream to form a mixed stream and passing the mixed stream to a polymerization reactor, characterised in that the mixing of the first stream and the diluent stream takes place by providing the first stream from the first line and the diluent stream from the second line separately to a mixing chamber which has an enlarged cross-section compared to the first and second lines.

Abstract: A stirring device of a plug-flow fermentation device includes a shaft rotatable about an axis of rotation which defines an axial direction. The stirring device further includes a boundary stirring element that defines the axial extent of a stirring volume covered by the stirring device. A nearest neighbor of the boundary stirring element in the axial direction has an axial maximum width which is smaller than an axial maximum width of the boundary stirring element and which is larger than an axial maximum width of a next-nearest neighbor of the boundary stirring element.

Abstract: In some embodiments, ethylene-propylene branched copolymers are synthesized with pyridyldiamido catalysts and a chain transfer agent, and their performance as viscosity modifiers in oil are detailed. In some embodiments, the present disclosure provides for ethylene-propylene branched copolymers having a shear thinning onset of less than about 0.01 rad/s and an HTHS value of less than about 3.3. In some embodiments, the ethylene-propylene branched copolymer is used as a viscosity modifier in a lubricating composition and a fuel composition.

Abstract: The present invention relates to an olefinic monomer recovery device capable of suppressing fouling and pressure drop in the recovery device in a process of separating and recovering unreacted monomers after production of a polyolefin resin. The olefinic monomer recovery device is used for separating and recovering unreacted olefinic monomers after production of a polyolefin resin, the apparatus comprising a vertical-type heat exchange unit, and a knock-out drum unit.

Abstract: A method broadening a molecular weight distribution and/or broadening a chemical composition distribution of the polyolefin product can include: polymerizing a feedstock in the presence of a metallocene catalyst in a loop reactor to produce a polyolefin product, the feedstock comprising two or more monomers; and adjusting a polymerization parameter selected from the group consisting of decreasing a recycle ratio, increasing a polymer concentration, increasing a LRSU number, and any combination thereof.

Abstract: The present disclosure relates to a catalyst composition for the oligomerization of ethylene comprising a zirconium-containing catalyst and an organoaluminum-containing co-catalyst. The disclosure also relates to a process for oligomerization of ethylene in the presence of the catalyst composition according to the disclosure. The disclosed process results in C4-C20 linear alpha olefins having improved linearity.

Abstract: A method may include polymerizing ethylene in a tubular reactor, where the polymerization is substantially free of a chain transfer agent. A method may include polymerizing ethylene in a tubular reactor, the ethylene having a specific delivery pressure and the polymerization having one or more specific peak temperatures. The molecular weight of the resulting polyethylene may be controlled by the selection of the delivery pressure and the one or more peak temperatures.

Abstract: This disclosure relates to systems and processes for cooling polymer product mixtures manufactured at high pressure. The processes of the invention involve cooling and then subsequently reducing the pressure of the product mixture from the reactor. In the systems of the invention, a product cooler is located downstream of the high pressure reactor and upstream of a high pressure let down valve.

Abstract: Methods of manufacturing highly crosslinked polymer particulate. The methods include positioning a granular polymeric material within a crosslinking apparatus and crosslinking the granular polymeric material with the crosslinking apparatus to form a highly crosslinked polymeric material. The methods also include forming a plurality of crosslinked polymer granules from the highly crosslinked polymeric material.

Abstract: Processes and systems for preparing copolymers of ethylene and a polar comonomer include contacting an initial feed comprising ethylene and a polar comonomer with a first polymerization initiator in a continuous stirred tank reactor to form a first polymer, which may then be contacted with second polymerization initiator in a plug flow reactor to form a second polymer. The process yields a second polymer having a lower melt flow index (and higher molecular weight) with high polar comonomer content. The polar comonomer may be, for example, vinyl acetate to prepare a poly(ethylene-vinyl acetate) copolymer having a vinyl acetate content of up to about 33% while maintaining the melt flow rate less than about 10 g/10 minutes without the use of fillers.

Abstract: A process and system for pre-polymerizing propylene are disclosed. A first catalyst suspension is formed by mixing catalyst particles with a hydrocarbon that is a saturated hydrocarbon or propylene. Various other catalyst components are added to the first catalyst suspension, and the first catalyst suspension is then pre-polymerized under pre-polymerization conditions to form a pre-polymerized catalyst suspension that is introduced to a polymerization reactor or a storage tank. The saturated hydrocarbon can be propane, mixed butanes, or mixture thereof.

Abstract: The present invention provides a method for manufacturing a polymer by a flow-type reaction. The method includes introducing a liquid A of an anionic polymerizable monomer, a liquid B of an anionic polymerization initiator, and a polymerization terminator into different flow paths, allowing the liquids to flow in the flow paths, allowing the liquid A and the liquid B to join together, subjecting the monomer to anionic polymerization while the liquids having joined together are flowing to downstream in a reaction flow path, and allowing a solution, which is obtained by the polymerization reaction and flows in the reaction flow path, and the polymerization terminator to join together so as to terminate the polymerization reaction and to obtain a polymer having a number-average molecular weight of 5,000 to 200,000. A static mixer is disposed in the reaction flow path, and a polymer having a number-average molecular weight equal to or greater than 2,000 is introduced into an inlet port of the mixer.

Abstract: The present invention relates to an injection-molded article, comprising at least one metallocene-catalyzed polyethylene resin comprising at least two metallocene-catalyzed polyethylene fractions A and B, wherein the at least one metallocene-catalyzed polyethylene resin comprises: at least 40% to at most 50% by weight of polyethylene fraction A based on the total weight of the at least one metallocene-catalyzed polyethylene resin, wherein fraction A has a melt index MI2 of at least 100.0 g/10 min as determined according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg; and wherein the at least one metallocene-catalyzed polyethylene resin has a density of at least 0.940 g/cm3 to at most 0.950 g/cm3 as measured on pellets according to ISO 1183 at 23° C.; a melt index MI2 of at least 1.4 g/10 min to at most 2.5 g/10 min as measured on pellets according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg.

Abstract: Disclosed are a method and system for propylene polymerization utilizing a loop slurry reactor. The method can include polymerizing propylene in a loop slurry reactor under bulk polymerization conditions to produce polypropylene. The propylene polymerization system can include i) a loop slurry reactor and a heat exchange system that is configured to cool the legs of the loop slurry reactor and/or ii) an inlet manifold that is configured to connect flashline heaters to a separator.

Abstract: An ethylene-(meth)acrylic acid copolymer has a polydispersity index (PDI) in a range from 3.5 to 8.0, and has a melt flow index (MFI) measured at 190° C. and 2.16 kg in a range from 350 g/10 min to 1800 g/10 min A water-dispersive composition includes the ethylene (meth)acrylic acid copolymer, a neutralizing agent and an aqueous medium.

Abstract: A process for the preparation of ethylene homopolymers or copolymers in a facility having a high-pressure tubular reactor and a preheater, wherein a reaction fluid introduced into the reactor at a reactor inlet is heated in the preheater and the average velocity of the reaction fluid in the preheater is lower than the average velocity of the reaction fluid in the tubular reactor and the ratio of the average velocity in the tubular reactor to the average velocity of the reaction fluid in the preheater is in the range from 1.5 to 5.

Abstract: Processes and apparatus for preparing bimodal polymers are provided. In some embodiments, processes include introducing a monomer, a first diluent, a catalyst, hydrogen, at a first hydrogen concentration, and optional comonomer, to a first loop reactor to produce, under polymerization conditions, a first slurry of polymer solids. Processes may also include continuously discharging the first slurry of polymer solids from the loop reactor as a first polymerization effluent to a first flash tank; separating the first polymerization effluent in the first flash tank to provide a first concentrated polymer slurry with significantly lower hydrogen concentration; and transferring the first concentrated polymer slurry from the flash tank to a re-slurry mixer. Processes may further include introducing a re-slurry mixer diluent to the first concentrated polymer slurry to form a second concentrated polymer slurry in the re-slurry mixer that can be pumped to a second slurry loop reactor.

Abstract: A system and method including providing a feed having alkyl-bridged multi-aromatic compounds to a tubular reactor, heating the tubular reactor, and cleaving an alkyl bridge of the alkyl-bridged multi-aromatic compounds.

Abstract: A process for the polymerization of olefins in gas phase carried out in a reactor having two interconnected polymerization zones, a first zone (riser) and a second zone (downcomer), wherein growing polymer particles: a) flow through the riser under fast fluidization conditions established by feeding a mixture of gas and liquid; b) leave the riser and enter the downcomer, through which the growing polymer particles flow downward in a densified form; and c) leave the downcomer and are reintroduced into the riser, thereby establishing a circulation of polymer between the riser and the downcomer; the reactor is operated at a temperature between 0° C. and 5° C. above the dew point of the riser gas at the operating pressure, and in the riser, besides the growing polymer particles and gas flow, an amount of liquid is present.

Abstract: A high pressure polymerization, as described herein, to form an ethylene-based polymer, comprising the following steps: polymerizing a reaction mixture comprising ethylene, using a reactor system comprising at least three ethylene-based feed streams and a reactor configuration that comprises at least four reaction zones, and at least one of the following a) through c), is met: (a) up to 100 wt % of the ethylene stream to the first zone comes from a high pressure recycle, and/or up to 100 wt % of the last ethylene stream to a zone comes from the output from a Primary compressor system; and/or (b) up to 100 wt % of the ethylene stream to first zone comes from the output from a Primary compressor system, and/or up to 100 wt % of the last ethylene stream to a zone comes from a high pressure recycle; and/or (c) the ethylene stream to the first zone, and/or the last ethylene stream to a zone, each comprises a controlled composition; and wherein each ethylene stream to a zone receives an output from two or more cyli

Abstract: A process to form an ethylene-based polymer in a reactor system, said process comprising at least the following steps: a) injecting a first initiator mixture into the tubular reactor at location L along the reactor, b) injecting a compressed make-up CTA system at the location L1, at a distance (L?L1) from 145*Dprehehater to 1000*Dpreheater, upstream from L, and wherein Dpreheater=the inner diameter of the pre-heater in meter (m); and wherein L1 is located in the preheater, and c) optionally, injecting one or more additional compressed make-up CTA system(s) into the preheater, at one or more location: LiLi+1, Ln (2?i and 2?n), upstream from L1, and each location is, independently, at a distance from 145*Dprehehater to 1000*Dpreheater, and wherein n equals the total number of injection locations of the make-up CTA system(s) injected into the preheater, upstream from L1, and wherein (L?L1) is less than each (L?Li), (L?Li+1), (L?Ln); and d) polymerizing a reaction mixture comprising at least ethylene, the first i

Abstract: A process for preparing an ethylene polymer including the step of homopolymerizing ethylene or copolymerizing ethylene with one or more comonomers in a gas-phase polymerization reactor including a riser unit wherein growing polymer particles flow upwards under fluidization, fast fluidization or transport conditions and a downcomer wherein growing polymer particles flow downward in a densified form, wherein the hold-up of polymer particles in the downcomer is from 55 wt. % to 80 wt. % of the total hold-up of polymer particles in the gas-phase polymerization reactor.

Abstract: Disclosed herein are ethylene homopolymers generally characterized by a density of less than 0.94 g/cm3 and an inverse short chain branch distribution. These homopolymers can be further characterized by a ratio of Mw/Mn from 2 to 100, a number of short chain branches from 2 to 20 short chain branches per 1000 total carbon atoms, and wherein at least 50% of the short chain branches are methyl branches.

Abstract: A polyethylene composition comprising a base resin is disclosed herein. The base resin includes an ethylene homo- or copolymer fraction (A1), and an ethylene homo- or copolymer fraction (A2). Fraction (A1) has a lower weight average molecular weight than fraction (A2). The base resin has a melt flow rate MFR21 of equal to or less than 8.0 g/10 min and a density of 930 to 950 kg/m3. The polyethylene composition has a melt flow rate MFR5 of 0.01 to 0.3 g/10 min, a flow rate ratio FRR21/5 of equal to or more than 20 and a ratio of the weight average molecular weight and the number average molecular weight (Mw/Mn) of equal to or less than 30. Also the polyethylene composition has a tensile modulus of less than 1000 MPa. Also a process for the production of a polyethylene composition comprising polyethylene base resin is disclosed herein.

Abstract: The present disclosure relates to a process for preparing polymers using a plug flow reactor. The process includes providing an aqueous monomer solution comprising amide monomers; evaporating the aqueous monomer solution to form a concentrated monomer solution; and polymerizing the concentrated monomer solution in a plug flow reactor comprising a shell side and a tube side to form a first process fluid comprising polymers. The concentrated monomer solution flows on the shell side from the inlet to the outlet.

Abstract: A process for selectively producing 1-butene comprises combining at least one antifouling agent and at least one aluminum alkyl compound to form an antifouling feed stream, wherein bringing the antifouling agent into contact with the aluminum alkyl compound forms at least one antifouling agent co-catalyst in a first step. The antifouling agent co-catalyst may comprise a structure comprising a central aluminum molecule bound to an R1 group, an R2 group, and an R3 group. The process further comprises feeding the antifouling feed stream, a catalyst comprising at least one titanate compound, and ethylene into a reactor dimerize ethylene in a second step. The catalyst is fed as a stream separated from the antifouling feed stream. The feeds may be varied in real-time to adjust a ratio of the formed antifouling agent co-catalyst and residual aluminum alkyl compound or antifouling agent in the antifouling feed stream.

Abstract: The present invention relates to the use of a polyethylene material in liquid containers that are sterilisable at a temperature of ?100° C. during a period of >15 minutes, wherein the polyethylene material has a density >928 kg/m3 as determined according to ISO 1183-1, method A, and a melt mass flow rate of ?0.50 and 51.00 g/10 min as determined according to ISO 1133-1 at a temperature of 190° C. and a load of 2.16 kg; wherein the polyethylene material produced in a high-pressure free-radical polymerisation process at a pressure of ?1600 bar.

Abstract: Described is a polyethylene composition comprising at least one polyethylene having a crystallinity of less than 60, or 55, or 50% and within a range from 0.2 wt % to 15 wt % of cyclic-olefin copolymer and within a range from 0.2 wt % to 15 wt % of hydrocarbon resin, by weight of the polyethylene composition. The polyethylene compositions can be formed into useful articles such as films and injection molded and thermoformed articles.

Abstract: A process to form an ethylene-based polymer comprising polymerizing a mixture comprising ethylene, in the presence of a free-radical initiator, and in a tubular reactor system comprising at least two ethylene-based feed streams, and a reactor configuration that comprises at least three reaction zones; and the inlet pressure of the first zone is <3200 Bar; and the ethylene conversion >28%, and an m value from 20 mole % to 70 mole %, where m=mol % of ethylene-based feed stream to the first zone, based on total moles of ethylene-based feed streams fed to the reactor configuration; and the ratio (Q) of a “MWDB of a broad polymer polymerized, to a “MWDN of a narrow polymer polymerized, is as follows: {(T)*(?2.3×log(m)+7)}?Q?{(T)*(?13.0×log(m)+29.8)}; at the same melt index; and “T” is the “chain transfer activity ratio” as described herein.

Abstract: A polyolefinic fiber made from or containing from 2 wt % to 20 wt % relative to the total weight of the fiber of a polyolefin composition made from or containing: A) 5-35% by weight of a propylene homopolymer or a propylene ethylene copolymer; B) 20-50% by weight of a copolymer of ethylene and a C3-C8 alpha-olefin containing from 0.1% to 20% by weight of alpha-olefin units and containing 25% by weight or less of a fraction soluble in xylene at 25° C.; and C) 30-60% by weight of a copolymer of ethylene and propylene containing from 25% to 75% by weight of ethylene units and containing from 40% to 95% by weight of a fraction soluble in xylene at 25° C.; the amounts of (A), (B) and (C) being referred to the total weight of (A)+(B)+(C), the sum of the amount of (A)+(B)+(C) being 100.

Abstract: A process to form an ethylene-based polymer comprises polymerizing a reaction mixture comprising ethylene, at least one symmetrical polyene and at least one chain transfer agent system comprising at least one chain transfer agent (CTA) in the presence of at least one free-radical initiator and in a reactor configuration comprising at least two reaction zones, reaction zone 1 and reaction zone i (i?2), wherein reaction zone i is downstream from reaction zone 1. The ratio of “the activity of the CTA system of the feed to the first reaction zone” to the “activity of the CTA system of the cumulative feed to the reaction zone i,” (Z1/Zi), is less than or equal to (0.8?0.2*log(Cs)), wherein Cs is from 0.0001 to 10.

Abstract: The present invention provides a hydrogen generating apparatus and a hydrogen generating method, wherein the hydrogen generating apparatus generates hydrogen by dehydrating formic acid, and comprises: a reactor for containing water and a heterogeneous catalyst; a formic acid feeder for feeding formic acid into the reactor; and a moisture remover for removing moisture generated from the reactor.

Abstract: A process is provided to form an ethylene-based polymer, in the presence of at least one free-radical, said process comprises at least the following: polymerizing a mixture comprising ethylene, in a reactor configuration comprising at least three reaction zones, and comprising two ethylene feed streams, and wherein the ratio (RLCBf40%), in percent, of the “LCB content of the first 40 wt % of the total polymer formed” to “the total LCB content in the final polymer” is ?22.5%; and wherein the amount of ethylene, and optionally one or more comonomers, and optionally one or more CTAs, fed to the first reaction zone, is from 40 mole % to 80 mole %, based on the total moles of ethylene, and optionally one or more comonomers, and optionally one or more CTAs, fed to the polymerization.

Abstract: A method for olefin oligomerization comprising i) injecting an olefin monomer and a solvent into a continuous stirred tank reactor; ii) injecting an oligomerization catalyst system comprising a ligand compound, a transition metal compound, and a co-catalyst into the continuous stirred tank reactor; and iii) performing a multimerization reaction of the olefin monomer, wherein a ratio of the flowing rates of the olefin monomer and the solvent is from 1:1 to 2:1.

Abstract: A method of reactive extrusion copolymerization of vinyl monomer consisting of (1) feeding vinyl monomer or at least one vinyl monomer together with an initiator into the first screw of twin-screw extruder, and modified resin into the subsequent screw section; (2) feeding the above monomer into the screw segment after auto-acceleration zone and feeding the initiator corresponding to the temperature of barrel and micro/nano inorganic modified fillers after the half-life period of the initiator; (3) feeding the antioxidant and anti-UV agent at the end of the polymerization, and then removing unpolymerized monomer and by-products by devolatilization of screw segment; (4) obtaining vinyl copolymer resin with a anticipated molecular weight of 5×102 to 6×105 from the reactive extrusion polymerization by controlling the temperature of different screw segments.

Abstract: A process comprising reacting, in a reactor having a fixed bed containing a solid catalyst which contains a zeolite, hydrogen sulfide and an oxirane in the presence of the solid catalyst to yield a reaction product with contains a mercapto-alcohol. A reactor system includes the reactor, an oxirane feed stream, a hydrogen sulfide feed stream, a fixed bed containing the solid catalyst placed inside the reactor, and an effluent stream containing the reaction product. The hydrogen sulfide and the oxirane are present in a mole ratio in a range of about 5:1 to 50:1.

Abstract: The disclosure provides a multilayer blown film for stretch hood made from or containing a layer made from or containing a first polyolefin composition made from or containing from 20 wt % to 80 wt %, based upon the total weight of the first polyolefin composition, of Component A) and from 20 wt % to 80 wt %, based upon the total weight of the first polyolefin composition, of Component B); wherein Component A) is an ethylene copolymer and Component B) is a polyolefin composition made from or containing: (i) 5-35% by weight, based upon the total weight of Component B, of a propylene homopolymer or a propylene ethylene copolymer (ii) 20-50% by weight, based upon the total weight of Component B, of a copolymer of ethylene and a C3-C8 alpha-olefin; and (iii) 30-60% by weight, based upon the total weight of Component B, of a copolymer of ethylene and propylene.

Abstract: Methods of making polyisobutylene and catalyst systems are described. Polyisobutylene compositions and catalyst system compositions are also described. In some embodiments, a method of making a catalyst system includes: providing a support material; calcining the support material; and forming a catalyst system by adding to the support material (a) a mixture comprising BF3, (b) a mixture comprising BF3 and a complexing agent, or (c) both. In some embodiments, a method of making a polymer composition includes providing a catalyst system comprising: (a) a support material selected from the group consisting of Al2O3, ZrO2, TiO2, SnO2, CeO2, SiO2, SiO2/Al2O3, and combinations thereof; and (b) BF3; providing a feedstock comprising isobutylene; forming a reaction mixture comprising the feedstock and the catalyst system; contacting the isobutylene with the catalyst system; and obtaining a polymer composition.

Abstract: Catalyst systems and methods for making and using the same are disclosed. In an example, a method of synthesizing a monocyclopentadienyl compound is provided. The method includes melting a dicyclopentadienyl compound including the following structure: As used herein, M is hafnium or zirconium. Each R is independently an H, a hydrocarbyl group, a substituted hydrocarbyl group, a heteroatom group. Each X is a leaving group selected from a halogen or a heteroatom group.

Abstract: The present invention relates to a process for preparing a polyethylene product having a multimodal molecular weight distribution, said process comprising the steps of: (a) feeding ethylene monomer, a diluent, at least one metallocene catalyst, optionally hydrogen, and optionally one or more olefin co-monomers into a first slurry loop reactor; and polymerizing the ethylene monomer, and the optionally one or more olefin co-monomers, in the presence of said at least one metallocene catalyst, and optionally hydrogen, in said first slurry loop reactor thereby producing a first polyethylene fraction; (b) feeding the first polyethylene fraction to a second slurry loop reactor serially connected to the first slurry loop reactor, and in the second slurry loop reactor polymerizing ethylene, and optionally one or more olefin co-monomers, in the presence of the first polyethylene fraction, and optionally hydrogen, thereby producing a second polyethylene fraction; and (c) feeding the second polyethylene fraction to a gas

Abstract: A process to form an ethylene-based polymer, said process comprising at least the following: polymerizing a mixture comprising ethylene, in the presence of at least one free-radical initiator, and in a reactor configuration comprising at least three reaction zones and at least two ethylene feed streams; and wherein the inlet pressure of the first reaction zone is less than, or equal to, 3200 Bar; and wherein the amount of ethylene, and optionally one or more comonomers, and optionally one or more CTAs, fed to the first reaction zone is from 40 mole % to 80 mole %, based on the total moles of ethylene, and optionally one or more comonomers, and optionally one or more CTAs, fed to the polymerization; and wherein the average polymerization temperature of the first 40 wt % polymer formed (APT40 wt %) (based on the total amount of polymer formed) is less than, or equal to, 200° C.

Abstract: A process to form an ethylene-based polymer, in the presence of at least one free-radical, said process comprises at least the following: polymerizing a mixture comprising ethylene in a reactor configuration comprising at least four reaction zones, and comprising at least three ethylene feed streams; and wherein the ratio of (RLCBf40%), in percent, of the LCB content of the “first 40 wt % of the total polymer formed” to the “total LCB content in the final polymer” is ?29%; and wherein the amount of ethylene, and optionally one or more comonomers, and optionally one or more CTAs, fed to the first reaction zone, is from 20 mole % to 70 mole %, based on the total moles of ethylene, and optionally one or more comonomers, and optionally one or more CTAs, fed to the polymerization.

Abstract: Novel polyethylene copolymers having a relatively high comonomer partitioning tendency are disclosed as are methods for their preparation. The comonomer partitioning tendency is the tendency for a copolymer to have comonomer in the higher molecular weight chains. Novel metrics for describing the comonomer partitioning tendency are also disclosed.

Abstract: Disclosed herein is a process for producing polymers of an N-vinyl carboxamide, including the steps of flowing a reaction mixture containing an aqueous liquid containing at least one polymerization initiator, N-vinyl carboxamide monomer or a monomer mixture containing N-vinyl carboxamide into a reactor system, and polymerizing the monomer or monomer mixture to produce the polymer of a N-vinyl carboxamide. The polymers resulting therefrom may be hydrolyzed to provide polymers containing vinyl amine units. Also disclosed herein is an apparatus suitable for producing the polymers.

Abstract: A propylene-based polymer resin is characterized by a low volatile emission signature. For example, the propylene-based polymer resin may have a volatile organic compound content no greater than 125 ppm, a semi-volatile organic compound content no greater than 500 ppm, and a C36 oligomeric content no greater than 250 ppm.