Abstract: A process for the polymerization of vinyl halides and/or vinylidene halides which comprising contacting the vinyl halide and/or vinylidene halide in gaseous form with a catalyst composition comprising(a) at least one compound of a transition metal of Groups IVA to VIA of the Periodic Table of the Elements, as hereinbefore defined, and(b) at least one compound having the structure ##STR1## WHERE M is aluminum or zinc, n and m each is an integer not greater than one less than the valency of M, at least one of the groups R is a hydrocarbon group, R.sup.1 is hydrogen or a hydrocarbon group, and X is hydrogen or a monovalent organic group.
Type:
Grant
Filed:
July 18, 1974
Date of Patent:
December 12, 1978
Assignee:
Imperial Chemical Industries Limited
Inventors:
Philip D. Roberts, Geoffrey L. P. Randall, David G. Simon, Jeffrey Booth
Abstract: Polymerization of a mono-.alpha.-olefine monomer is effected by contacting the gaseous monomer with a solid phase comprising polymer and catalyst at a pressure and temperature which are such that the temperature is in the range from tp + 0.1.degree. C up to tp + 5.0.degree. C, where tp is the temperature at which the monomer condenses at a pressure which is equal to the monomer partial pressure within the polymerization vessel.
Abstract: Articles such as containers made of a highly crystalline olefin polymer having improved transparency and impact strength are obtained by biaxially extending an extruded tubular body of said polymer at an orientation temperature below the melting point thereof to attain an extension magnification ratio of at least 1.5 for each of the longitudinal and lateral directions. The polymer is a statistical random copolymer of propylene and from 1.5% to 5.0%, and preferably from 3.0% to 5.0%, by weight ethylene having a melt index of 0.6 - 3.0 g/10 min. Optionally, from 0.03 to 0.20 part by weight of p-tert. butyl benzoic acid, benzoic acid or sodium benzoate are added to 100 parts by weight of said copolymer.
Abstract: The polymerization of olefins to form polymers having a molecular weight greater than 50,000 wherein the polymerization is carried out in the presence of a catalyst component formed of a compound of a transition metal of the sub-groups IVa, Va and VIa, and a co-catalyst component of at least one organo-metallic compound of a metal from groups II and III of the periodic table, in which the co-catalyst is in the form of a liquid which is separately introduced into the reaction vessel on a carrier formed of an inert porous powder which is impregnated with the co-catalyst.
Abstract: A fluid bed reactor system and process employing a silyl chromate catalyst therein wherein the reactor system comprises a vertical reactor having a fluidizing medium permeable distribution plate towards the base thereof, a fluidizing medium supply line to supply fluidizing medium to the base of the reactor, a catalyst injection means to supply particulate catalyst to the side of the reactor, a polymer product recovery means to recover polymer product from the reactor and beneath the distribution plate, a fluidizing medium recycle line to recycle the fluidizing medium from and to the reactor, and a heat exchanger in the recycle line to remove heat of reaction from the recycled fluidizing medium.