Abstract: The present technology relates to a latex composition for dip molding comprising a carboxylic acid-modified nitrile-based copolymer latex satisfying General Formulas 1 and 2, wherein the carboxylic acid-modified nitrile-based copolymer includes a conjugated diene-based monomer-derived unit, an ethylenic unsaturated nitrile-based monomer-derived unit, and an ethylenic unsaturated acid monomer-derived unit, and a molded article.

Abstract: A method for producing polymer particles includes a preparation step for preparing a first oily liquid containing an oily olefin monomer, a radical polymerization initiator, and an iodine molecule; a synthesis step for obtaining a second oily liquid containing at least an iodine compound produced by a reaction between a radical generated by cleavage of the radical polymerization initiator and the iodine molecule in the first oily liquid; a suspension step for obtaining an oil droplet of the second oily liquid by suspending the second oily liquid in an aqueous solution containing an oxidizing agent, an acid, and a dispersant; and a polymerization step for polymerizing the oily olefin monomer in the oil droplet.

Abstract: A procedure for improved temperature control in controlled radical polymerization processes is disclosed. The procedure is directed at controlling the concentration of the persistent radical in ATRP and NMP polymerizations procedures and the concentration of radicals in a RAFT polymerization process by feeding a reducing agent or radical precursor continuously or intermittently to the reaction medium through one of more ports.

Abstract: Process for the preparation of polybutadiene effected by the polymerization of butadiene in an aliphatic and/or cyclo-aliphatic solvent in the presence of a catalytic system prepared in situ which comprises: (i) a carboxylate of neodymium soluble in the process solvent containing a variable quantity of water, the H2O/Nd molar ratio ranging from 0.001/1 to 0.50/1; (ii) an alkyl compound of aluminum; (iii) an alkyl compound of aluminum in which at least one bond of Al consists of an Al—Cl bond; The total Al/Nd molar ratio ranging from 4/1 to 12/1, and the Cl/Nd molar ratio ranging from 2/1 to 6/1.

Abstract: A process for producing an olefin-based polymer in a polymerization reactor including a fluidized bed, a disengaging section and a neck connecting the bed and disengaging section, at least one monomer, in the gas phase, in the presence of at least one catalyst containing at least two transition metals, one of the at least two transition metals being Ti, at least one cocatalyst, a composition having at least one compound selected from formula (I), and/or at least one compound selected from formula (II): (R1CO2)2AlOH (I), (R2)xN(R3OH)y (II); wherein R1 is a hydrocarbon radical containing from 13 to 25 carbons; R2 is a hydrocarbon radical containing from 14 to 26 carbons; R3 is a hydrocarbon radical containing from 1 to 4 carbons; and x+y=3, and x has a value of 1 or 2; and wherein the reactor is operated in a condensed mode and the average height of the fluidized bed is maintained above the neck of the polymerization reactor is provided. The reaction product of the process is also provided.

Abstract: A polymer composition comprising A) a first polymer comprising (a) hydrophobized nanoparticle; (b) C1 to C18, straight, branched, or cyclic alkyl(meth)acrylate; (c) N-methylol(meth)acrylamide or a monomer of formula (I) R—(OCH2CH2)a—O—C(O)—C(R1)?CH2??(I) ?wherein R is hydrogen, C1-C4 alkyl, or —C(O)—C(R1)?CH2, and R1 is H or —CH3; said first polymer in contact with B) a second polymer comprising (d) a fluorinated monomer of formula (II) Rf1-L-X—C(O)—C(R)?CH2??(II) ?wherein Rf1 is a monovalent, partially or fully fluorinated, linear or branched, alkyl radical having 2 to about 100 carbon atoms; optionally interrupted by 1 to about 50 oxygen atoms; wherein the ratio of carbon atoms to oxygen atoms is at least 2:1 and no oxygen atoms are bonded to each other; L is a bond or a linear or branched divalent linking group having 1 to about 20 carbon atoms, said linking group optionally interrupted by 1 to about 4 hetero-radicals selected from the group consisting of —O—, —NR6—, —S—, —SO—, —SO2—, and —N(R6)

Abstract: An aqueous polymerizable monomer composition including an ?,?-unsaturated carboxylic acid monomer and a polyvalent metal ion in an amount sufficient to neutralize 10 to 90% of a carboxyl group of the ?,?-unsaturated carboxylic acid monomer in the form of a solution or dispersion in water in an amount of 20 to 85% by weight based on the whole amount of the composition, a gas barrier film including an ionically crosslinked polycarboxylic acid polymer film formed by subjecting a coating film of the aqueous polymerizable monomer composition to a polymerization treatment and having an oxygen transmission rate of at most 50×10?4 cm3(STP)/(m2·s·MPa) as measured under conditions of a temperature of 30° C. and a high relative humidity of 80%, and a production process of the film.

Abstract: Of the many embodiments presented herein, one is a subterranean treatment fluid comprising: an aqueous fluid; and a water-soluble degradable synthetic vinyl polymer having a labile link in its backbone. Also provided in one instance is a water-soluble degradable synthetic vinyl polymer with labile group in its backbone made by a redox polymerization, the redox polymerization reaction comprising these reactants: a macroinitiator that comprises a labile link, an oxidizing metal ion, and a vinyl monomer.

Abstract: The present invention relates to conjugates of biologically active compounds, preferably therapeutically active compounds, with polymeric moieties having low polydispersity, as well as controlled polymerisation processes for producing the conjugates. An initiation for a controlled radical polymerisation process comprises a biologically active, usually therapeutically active, moiety and the monomer includes zwitterionic monomer for instance 2-methacryloyloxyethyl -2?-trimethylammonium ethyl phosphate inner salt. The process allows close control of the molecular weight and polydispersity of the polymeric moiety and the possibility of optimizing the delivery characteristics of the active agent.

Abstract: Process for preparing an aqueous polymer dispersion by polymerizing at least one ethylenically unsaturated monomer B in an aqueous medium in the presence of polymer particles A and at least one dispersant.

Abstract: Method of preparing olefin polymers, which comprises the polymerization of at least one ?-olefin in the presence of a hybrid catalyst to produce a polymer comprising at least a higher molecular weight polymer component and a lower molecular weight polymer component in the presence of water in an amount of from 2 to 100 mol ppm and/or carbon dioxide in an amount of from 2 to 100 mol ppm, in each case based on the total reaction mixture, in order to alter the ratio of the higher molecular weight polymer component to the lower molecular weight polymer component. This enables the ratio of the higher molecular weight component to the lower molecular weight component to be controlled selectively.

Abstract: An aqueous polymer dispersion is prepared by reacting at least one olefin in the presence of at least one polymerization catalyst and one emulsifier in an aqueous medium by a process wherein the polymerization catalyst is prepared in an in situ reaction by reacting the ligand compound 2,6-dichloro-para-benzoquinone (Ia) and/or 2,3,6-trichloro-para-benzoquinone (Ib) with a phosphine compound or diphosphine compound and with a metal compound and the polymerization reaction is effected in an aqueous medium.

Abstract: The invention provides for a process to produce polymers utilizing a hydrofluorocarbon diluent.

Abstract: An object of the present invention is to provide a particle-shaped water absorbing agent having a remarkably improved surface color and excellent water-absorbing properties (better water absorption capacity, and lower water soluble content and residual monomer content) at the same time. In order to attain the object, a particle-shaped water absorbing agent according to the present invention is a particle-shaped water absorbing agent whose main component is a polyacrylic acid and/or a salt thereof, the particle-shaped water absorbing agent having a surface color of Hunter b value in a range of ?5 to 10, and having a cross-linking absorption property index (CPI) in a range of 1 to 100, the CPI defined by the following two equations: GEX=(GVs+17)/Ln (water soluble content)??Equation 1; CPI=(GEX/residual monomer content)×100??Equation 3 where GVs is gel volume in saline, Ln (water soluble content) is a logarithm natural of water soluble content.

Abstract: The present invention relates to the field of polymer chemistry and more particularly to multiblock copolymers and methods of preparing the same.

Abstract: An aqueous semi-batch polymerization process is disclosed for the manufacture of dipolymers of tetrafluoroethylene and 3,3,3-trifluoropropene that contain between 45 and 95 mole percent tetrafluoroethylene and between 5 and 55 mole percent 3,3,3-trifluoropropene.

Abstract: A novel semi-batch emulsion polymerization process for the production of fluoroelastomers is disclosed wherein a hydrocarbon anionic surfactant is employed as the dispersing agent. The surfactant has the formula R-L-M wherein R is an alkyl group having between 6 and 17 carbon atoms, L is selected from the group consisting of ArSO3?, SO3?, SO4?, PO3? and COO? and M is a univalent cation. Preferred surfactants are sulfonates of the formula CH3—(CH2)n—SO3M, CH3—(CH2)n—C6H4—SO3M, or CH3—(CH2)n—CH?CHCH2—SO3M, where n is an integer from 6 to 17, or mixtures thereof, and M is a cation having a valence of 1. Surfactant is not introduced to the reactor until shortly after the polymerization reaction has begun.

Abstract: The invention provides for polymerization processes to produce polymers utilizing boiling pool reactor systems and diluents including hydrofluorocarbons.

Abstract: Process for the emulsion polymerization of one or more olefins by preparing a catalyst by reacting a quinoid compound with a metal compound and a phosphine compound which is substituted by at least one polar radical; and subsequently (co)polymerizing said one or more olefins in water or in a solvent mixture which contains at least 50% by weight of water and at least one emulsifier.

Abstract: This present invention is directed towards the identification or design, preparation, and use of suitable transition metal complexes for use as catalysts. The transition metal complexes may comprise heterodonor ligands. The present invention is also directed toward a method of determining the suitability of a transition metal complex for use in a catalytic reaction, such as, but not limited to, atom transfer radical polymerization (“ATRP”), atom transfer radical addition (“ATRA”), atom transfer radical cyclization (“ATRC”), and other catalytic redox reactions. The method assists in the approximate determination of the fundamental properties of the transition metal complex in a reaction media, such as, but not limited to, solubility, redox potential, stability towards acidic, basic, or ionic species, conditional radically transferable atom phylicity, and propensity toward disproportionation and therefore, the suitability of the complex to be used as a catalyst in the reaction media.

Abstract: Chemical compositions are disclosed. One exemplary composition, among others, includes: a basic component, an acidic component, at least one acrylate component, oxidizing agent, reducing agent, and a binder. The binder includes a viscosity modifier and a surface tension modifier. The binder is capable of stimulating a reaction between the basic component and the acidic component. A portion of the binder is capable of undergoing a polymerization reaction between at least one acrylate component, the oxidizing agent, and the reducing agent. The polymerization reaction being initiated by the redox reaction between the oxidizing agent and the reducing agent.

Abstract: This invention provides a chemically coated surface for the electrophoretic separation application. The surface comprises of block copolymers prepared from addition monomers selected from a group consisting of acrylates and its derivatives, metharylates and its derivatives, styrene and its derivatives, acrylamide, methacrylamide, dimethacrylamide, N-monosubstituted acrylamide, N-monosubstituted methacrylamide, N,N-bissubstituted acrylamide, N,N-bissubstituted methacrylamide, vinyl acetate, vinyl pyrolidone, vinyl ether, acrylic acid and methacrylic acid. This invention also provides a chemical process for making the chemically coated surface for the electrophoretic separation application. The process comprises: (a) contacting the support surface with a coupling agent solution, then (b) contacting the support surface with a first living radical polymerizing solution, and optionally (c) contacting the support surface with a second living radical polymerizing solution.

Abstract: Polymers may be made from zwitterionic monomers having controlled architectures and molecular weights, using living polymerisations such as group or atom transfer radical polymerisation. For instance polymers may be formed by atom transfer radical polymerisation using a copper chloride catalyst, a ligand which is water soluble, and a water soluble tertiary alkyl halide initiator to form homopolymers having controlled polydispersities of less than 1.5 and block copolymers with other hydrophilic or hydrophobic monomers. One suitable zwitterionic monomer is 2-methacryloyloxy-2?-trimethylammoniumethyl phosphate inner salt. The block copolymers may spontaneously form micelles, believed to have zwitterionic, for instance phosphorylcholine, groups at the external surface, which may be useful as drug delivery systems with improved biocompatibility.

Abstract: This invention provides a chemically coated surface for the plastics surface such as contact lens. The chemical surface coating comprises of at least one addition polymer prepared from addition monomers selected from a group consisting of acrylates and its derivatives, metharylates and its derivatives, styrene and its derivatives, acrylamide, methacrylamide, dimethacrylamide, N-monosubstituted acrylamide, N-monosubstituted methacrylamide, N,N-bissubstituted acrylamide, N,N-bissubstituted methacrylamide, vinyl acetate, vinyl pyrolidone, vinyl ether, acrylic acid and methacrylic acid. This invention also provides a chemical process for making the chemically coated surface on the plastics surface. The process comprises: (a) contacting the plastics surface with a coupling agent solution, then (b) contacting the plastics surface with a first living radical polymerizing solution, and optionally (c) contacting the plastics surface with a second living radical polymerizing solution.

Abstract: The invention provides for a process to produce polymers utilizing a hydrofluorocarbon diluent.

Abstract: A process for preparing an aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer, containing structural units according to formula (I): in which R1 and R2 independently of one another represent hydrogen or a C1-5-alkyl group or together form an optionally substituted C1-5-alkylene residue, comprising the step of: preparing the polythiophene or thiophene copolymer with an initiator in a reaction medium in the presence of polyanions under oxidizing or reducing conditions under an inert atmosphere such that when said initiator is added less than 3 mg of oxygen per litre of the reaction medium is present in the reaction medium; an aqueous or non-aqueous solution or dispersion prepared therewith; the use of an aqueous or non-aqueous dispersion or solution comprising the aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer for coating an object; a printable paste containing the aqueous or non-aqueous solution or dispersion of a polythiophene o

Abstract: A method for making hydrophilic homopolymers and copolymers of poly 2-hydroxyethyl methacrylate. Also disclosed are coatings, films, hydrogels, cosmetic compositions, dermatological compositions, pressure sensitive adhesives containing the hydrophilic homopolymers or copolymers of poly 2-hydroxyethylmethacrylate. Further disclosed are methods of coating substrates with the hydrophilic homopolymers and copolymers of poly 2-hydroxyethyl methacrylate and hydrophilic pressure sensitive adhesives.

Abstract: In order to provide a novel Lewis acid catalyst, which shows high reaction activity in aqueous medium, is easily recovered, and is excellent in reusability, a Lewis acid group expressed by the general formula (I): MXn??(I) (wherein M represents a polyvalent element, X represents an anionic group, and n is an integer representing the valence of M) is linked and supported on a polymer membrane via an SO3 or SO4 group.

Abstract: The present invention relates to a process for the manufacture of a porous polymer; wherein a composition comprising a polymerizable component, a porogen having an inverse temperature dependent solubility and a solvent are polymerized at a temperature around the cloud point temperature of the composition. The porous polymers obtainable according to the process of the invention are useful, for example, as materials for the manufacture of biomedical devices and prostheses, including ophthalmic devices such as contact lenses or artificial corneas.

Abstract: The invention relates to a catalyst which contains a catalytically active quantity of at least one oxygen-containing molybdenum and/or wolfram compound on an oxidic support material and which has been calcinated at temperatures of 400 to 900° C. after the precursor compound of the catalytically active compounds have been applied to the support material or to a support material precursor. The transport pores for this catalyst each have a diameter of >25 nm and a volume of at least 50 mm3/g. The catalyst contains x ?mol (wolfram and/or molybdenum)/m2 molybdenum and/or wolfram, with 10.1<x<20.9 in relation to the finished catalyst, with the oxidic support material having a BET surface area of 135 to 220 m2/g. Catalysts of this type are characterized by an acidity of at least 70 ?mol/g at pKs<?3 in the dry state and are therfore very active. The invention also relates to a method for producing a catalyst of this type and to the preferred use thereof.

Abstract: The present invention relates to a process for preparing an elastomeric ethylene-hexafluoropropylene copolymer with excellent vulcanization properties, which comprises emulsion polymerizing ethylene, hexafluoropropylene and when in demand, a monomer copolymerizable therewith in a aqueous medium at a low temperature of ?20° C. to 40° C. using a radical polymerization initiator.

Abstract: Polymers may be made from zwitterionic monomers having controlled architectures and molecular weights, using living polymerisations such as group or atom transfer radical polymerisation. For instance polymers may be formed by atom transfer radical polymerisation using a copper chloride catalyst, a ligand which is water soluble, and a water soluble tertiary alkyl halide initiator to form homopolymers having controlled polydispersities of less than 1.5 and block copolymers with other hydrophilic or hydrophobic monomers. One suitable zwitterionic monomer is 2-methacryloyloxy-2?-trimethylammoniumethyl phosphate inner salt. The block copolymers may spontaneously form micelles, believed to have zwitterionic, for instance phosphorylcholine, groups at the external surface, which may be useful as drug delivery systems with improved biocompatibility.

Abstract: The present invention is directed to a polyethylene resin having a density of 940-970 kg/m3 and a long-term relaxation component index of 1.5-10. The polyethylene resin exhibits, among other properties, excellent extrudability and bubble stability during blow film extrusion, and well-balanced physical properties of a film; e.g., impact resistance, and in particular, low unevenness in thickness. The polyethylene resin can provide a blown film having few gels.

Abstract: An at least two-component mortar composition is described, which can be cured by thermal initiation and contains at least one polymerizable monomer and/or at least one curable resin, at least one polymerization initiator for the polymerizable monomer and/or the curable resin and optionally at least one filler, wherein, as polymerization initiator, at least one organically substituted ammonium salt is contained as constituent of a mortar component and at least one inorganic persulfate is contained as constituent of a further mortar component, and which, after the mortar components are mixed in situ, results in an organically substituted ammonium persulfate, the nature and amount of organically substituted ammonium salt and inorganic persulfate as well as of polymerizable monomer or curable resin being selected so that a mortar composition results, which can be polymerized by free radical polymerization due to the action of heat, as well as a method for fastening tie rods, reinforcing steel for concrete or the

Abstract: The use of concurrent reverse and normal initiation processes in an ATRP enables the use of highly active catalysts under “reverse ATRP” conditions and leads to the synthesis of well-defined polymers with low molecular weight distributions while employing much lower levels of the transition metal in the system. This dual activation/initiating system allows use of active catalysts that are added to the reaction in an oxidatively stable form. The benefits of this dual initiating system can be attained in bulk, solution and multi-phase ATRP processes, including emulsions, miniemulsions and polymerization from surfaces.

Abstract: This present invention is directed towards the identification or design, preparation, and use of suitable transition metal complexes for use as catalysts. The transition metal complexes may comprise heterodonor ligands. The present invention is also directed toward a method of determining the suitability of a transition metal complex for use in a catalytic reaction, such as, but not limited to, atom transfer radical polymerization (“ATRP”), atom transfer radical addition (“ATRA”), atom transfer radical cyclization (“ATRC”), and other catalytic redox reactions.

Abstract: Superabsorbent polymers having a slow rate of absorption, and a process for their preparation. The superabsorbent polymer has a slow rate of absorption, is crosslinked with a covalent crosslinking agent and the metal of a polyvalent metal coordination compound, has the metal of the coordination compound distributed essentially homogeneously throughout the polymer, and has an Absorption Rate Index of at least about 5 minutes.

Abstract: A controlled polymerization process is described in which the polymerization free radically (co)polymerizable ionic monomers is initiated in the presence of a system initially comprising a transition metal complex, and an initiator comprising a radically transferable azide group. The process may include an excess of one or more uncomplexed ligand and at least a portion of the nonionic monomers may be polar monomers. The ionic monomer may be anionic or cationic.

Abstract: The present invention relates to a process for hydrogenating ethylenically unsaturated double bonds in polymers P by reacting an aqueous dispersion of at least one polymer P with hydrogen in the presence of at least one hydrogenation catalyst comprising at least one transition metal selected from rhodium and/or ruthenium and at least one nonionic phosphorus compound capable of forming a coordinative compound with the transition metal, which comprises incorporating the hydrogenation catalyst into the aqueous dispersion of the polymer P without adding a solvent. The present invention also relates to the aqueous dispersions of the hydrogenated polymers P obtainable by this process and to coating compositions comprising such dispersions.

Abstract: A method for producing an ethylene-vinyl acetate copolymer aqueous emulsion is provided which uses a redox catalyst comprising a transition metal salt and an erysorbic acid and/or an ascorbic acid, as the reducing agent thereof, and 1.8 to 10 mol of hydrogen peroxide, as an oxidizing agent thereof, per one mol of the erysorbic acid and the ascorbic acid, and by this method, an ethylene-vinyl acetate copolymer aqueous emulsion which causes no generation of formalin and in which discoloration is suppressed can be obtained.

Abstract: A process of producing particles for diagnostic reagent, including a step of polymerizing a polymerizable monomer in the presence of a matrix particle having a magnetic substance layer containing at least one of Fe2O3 and Fe3O4 on the surface thereof and having a mean particle size of 0.4-200 &mgr;m to form a polymer layer on the magnetic substance layer.

Abstract: The present invention describes preparation of nanocomposite particles and structures by polymerizing monomers onto a functional inorganic colloid comprising a polymerization initiation site. The polymerization process is preferably a controlled/living polymerization process, including but not limited to, atom transfer radical polymerization and stable free radical polymerization. The nanocomposite particles can self-organize in solution, on surfaces or in films forming nanocomposite structures. Tethered AB block nanocomposite particles bring size control, solubility control and control over micro- and macro-functionality to the particles. The process may be catalyzed by a transition metal complex which participates in a reversible redox cycle with at least one of the group and a compound having a radically transferable atom or group, to form a nanocomposite particle with a tethered polymer chain. The process may be continued to form tethered copolymer chain.

Abstract: Superabsorbent polymers having a slow rate of absorption, and a process for their preparation. The superabsorbent polymer has a slow rate of absorption, is crosslinked with a covalent crosslinking agent and the metal of a polyvalent metal coordination compound, has the metal of the coordination compound distributed essentially homogeneously throughout the polymer, and has an Absorption Rate Index of at least about 5 minutes. Prepare water-swellable, water-insoluble polymer particles having a slow rate of water absorption by polymerizing a monomer in the presence of a covalent crosslinking agent and a polyvalent metal coordination compound under conditions such that there is formed a polymer having reversible cationic crosslinks and such that the metal is distributed essentially homogeneously throughout the polymer particles.

Abstract: The present invention is directed to processes of polymerizing olefin monomers and copolymerizing olefin monomer(s) with functionalized alpha-olefin monomers in the presence of certain late transition metal pyrrolaldimine chelates, especially bidenate or in the presence of a combination of a transition metal in its zero valence and a pyrrolaldimine represented by the formula: wherein each R1, R2, R3, R4, R5, R6, M and L are defined in the specification herein below.

Abstract: Process that is capable of synthesizing a metal-containing resin having a good antifouling property in a short period of time without having such problems associated with the synthesis as gelation. The process for producing a metal-containing resin by conducting a copolymerization reaction of a monomer mixture (A) comprising 1 to 50% by weight of a carboxyl group-containing polymerizable unsaturated monomer (a) and 50 to 99% by weight of other polymerizable unsaturated monomer (b) in an organic solvent in the presence of water and an oxide or hydroxide of a metal having a valency of at least 2, wherein the amount of water is 1 to 30 parts by weight based on 100 parts by weight of the monomer mixture (A), and the formation of a metal carboxylate bond occurs together with the copolymerization of the monomer mixture (A); and an antifouling coating composition containing, as an active constituent, a metal-containing resin obtained by the production process.

Abstract: Ruthenium and osmium carbene compounds that are stable in the presence of a variety of functional groups and can be used to catalyze olefin metathesis reactions on unstrained cyclic and acyclic olefins are disclosed. Also disclosed are methods of making the carbene compounds. The carbene compounds are of the formula where M is Os or Ru; R1 is hydrogen; R is selected from the group consisting of hydrogen, substituted or unsubstituted alkyl, and substituted or unsubstituted aryl; X and X1 are independently selected from any anionic ligand; and L and L1 are independently selected from any neutral electron donor. The ruthenium and osmium carbene compounds of the present invention may be synthesized using diazo compounds, by neutral electron donor ligand exchange, by cross metathesis, using acetylene, using cumulated olefins, and in a one-pot method using diazo compounds and neutral electron donors.

Abstract: Polymers based on monomers having a C—C double bond and/or C—C triple bond are prepared by polymerization of these monomers in the presence of a catalyst system comprising as active constituents a transition metal compound of an early transition metal and, if desired, a cation-forming compound B) and, if desired, further components C), wherein the polymerization mixture contains at least 30% by weight of water.

Abstract: Superabsorbent polymers having a slow rate of absorption, and a process for their preparation. The superabsorbent polymer has a slow rate of absorption, is crosslinked with a covalent crosslinking agent and the metal of a polyvalent metal coordination compound, has the metal of the coordination compound distributed essentially homogeneously throughout the polymer, and has an Absorption Rate Index of at least about 5 minutes. Prepare water-swellable, water-insoluble polymer particles having a slow rate of water absorption by polymerizing a monomer in the presence of a covalent crosslinking agent and a polyvalent metal coordination compound under conditions such that there is formed a polymer having reversible cationic crosslinks and such that the metal is distributed essentially homogeneously throughout the polymer particles.

Abstract: The present invention describes preparation of nanocomposite particles and structures by polymerizing monomers onto a functional inorganic colloid comprising a polymerization initiation site. The polymerization process is preferably a controlled/living polymerization process, including but not limited to, atom transfer radical polymerization and stable free radical polymerization. The nanocomposite particles can self-organize in solution, on surfaces or in films forming nanocomposite structures. Tethered AB block nanocomposite particles bring size control, solubility control and control over micro- and macro-functionality to the particles. The process may be catalyzed by a transition metal complex which participates in a reversible redox cycle with at least one of the group and a compound having a radically transferable atom or group, to form a nanocomposite particle with a tethered polymer chain. The process may be continued to form tethered copolymer chain.

Abstract: An olefin polymer of an alkenyl hydrocarbon having 5 or more carbon atoms, wherein said olefin polymer is an amorphous polymer having a Mn of 300,000 and a Mw/Mn of 2.40 or less, and substantially not having a melting point, and a process for producing said olefin polymer which comprises polymerizing an alkenyl hydrocarbon having 5 or more carbon atoms with an olefin polymerization catalyst obtained by contacting: a specific transition metal compound(A), an organoaluminumoxy compound (B) soluble in an aromatic solvent and water (C).