Interpolymer From At Least Three Ethylenically Unsaturated Monoolefinic Hydrocarbon Monomers Patents (Class 526/916)
  • Patent number: 11505719
    Abstract: Described herein is an adhesive composition including a copolymer. The adhesive composition has a viscosity of from about 2,000 mPa·s to about 11,500 mPa·s at 150° C. The adhesive composition has a Storage Modulus at 37° C. of from about 3 MPa to 9.5 MPa. The adhesive composition has a Yield Stress at 37° C. of from about 0.8 MPa to about 1.45 MPa.
    Type: Grant
    Filed: April 18, 2019
    Date of Patent: November 22, 2022
    Assignee: The Procter & Gamble Company
    Inventors: Robert Haines Turner, Torsten Lindner, Matthias Morand, Benjamin John Kutay, Holger Beruda, Ekaterina Ponomarenko, William L. Bunnelle, Jon Fagerness, Nick Fowler, Bill Turner, Andres Sustic, Enrico Buenacosa, Steve Oetting, Steve McHaney, J. J. DeCair
  • Patent number: 10982028
    Abstract: The present invention relates to nucleated propylene-ethylene-butylene-terpolymers comprising propylene, butylene, and ethylene, having improved stiffness, better impact behaviour and improved optical properties such as low haze, and low amounts of soluble or extractable fractions.
    Type: Grant
    Filed: June 12, 2017
    Date of Patent: April 20, 2021
    Assignee: BOREALIS AG
    Inventors: Jingbo Wang, Markus Gahleitner, Elisabeth Potter
  • Patent number: 8617717
    Abstract: A film structure having a base layer comprising a film-forming thermoplastic polymer; and a heat-seal layer having a seal-initiation temperature less than or about 130° C. and comprising from about 50 to about 98 wt % of a first polymer component and about 2 to about 50 wt % of a second polymer component. The first polymer component comprising propylene-derived units and, optionally, up to about 20 wt % of comonomer units derived from a C2 and/or C4-C20 ?-olefin, and having a heat of fusion greater than 75 J/g and a melting point greater than or equal to 105° C. The second polymer component comprising at least 75 wt % propylene-derived units, and having a melting point less than 105° C. and a heat of fusion less than 75 J/g.
    Type: Grant
    Filed: October 26, 2006
    Date of Patent: December 31, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Michael Glenn Williams, Hans Joachim Pip
  • Patent number: 8039555
    Abstract: The invention provides a thermoplastic resin composition including a thermoplastic resin component (I) in an amount of 100 parts by mass, and a filler (II) in an amount of 1 to 900 parts by mass, wherein the thermoplastic resin component (I) contains a block copolymer (A) in an amount of 5 to 90 mass %, the block copolymer (A) being at least one species selected from among a block copolymer and a hydrogenated product thereof, the block copolymer having a polymer block (a1) formed mainly of an aromatic vinyl compound unit(s), and a polymer block (a2) formed mainly of a conjugated diene unit(s); a polyolefin resin (B) in an amount of 5 to 90 mass %; and a block copolymer (C) in an amount of 5 to 90 mass %, the block copolymer (C) having a polymer block formed from a repeating unit having a polar group.
    Type: Grant
    Filed: April 4, 2007
    Date of Patent: October 18, 2011
    Assignee: Kuraray Co., Ltd.
    Inventors: Hiromitsu Sasaki, Kenji Shachi, Daisuke Konishi
  • Patent number: 8008417
    Abstract: Disclosed herein is a polymer composition, its manufacture and use, said composition may comprise greater than about 90 mole % propylene monomer, and having a unique combination of properties, including one or more of the following: a heat of fusion of more than about 108 J/g, a melting point of 165° C. or higher, a Melt Flow Rate so low that it is essentially not measurable and a molecular weight of greater than about 1.5×106. Further disclosed herein are blends or mixtures of the present novel polymer composition and products, such as, for example, microporous film structures and the like comprising same.
    Type: Grant
    Filed: December 8, 2010
    Date of Patent: August 30, 2011
    Assignee: Toray Tonen Specialty Separator Godo Kaisha
    Inventors: Patrick Brant, Jeffrey L. Brinen, Zerong Lin, Koichi Kono, Kohtaro Kimishima, Hiroyuki Ozaki
  • Patent number: 7872086
    Abstract: Disclosed herein is a polymer composition, its manufacture and use, said composition may comprise greater than about 90 mole % propylene monomer, and having a unique combination of properties, including one or more of the following: a heat of fusion of more than about 108 J/g, a melting point of 165° C. or higher, a Melt Flow Rate so low that it is essentially not measurable and a molecular weight of greater than about 1.5×106. Further disclosed herein are blends or mixtures of the present novel polymer composition and products, such as, for example, microporous film structures and the like comprising same.
    Type: Grant
    Filed: January 17, 2008
    Date of Patent: January 18, 2011
    Assignee: Tonen Chemical Corporation
    Inventors: Patrick Brant, Jeffrey L. Brinen, Zerong Lin, Koichi Kono, Kohtaro Kimishima, Hiroyuki Ozaki
  • Patent number: 7507781
    Abstract: A papermaking method and a composition which utilize, as a drainage aid, a water-soluble anionic copolymer prepared via a water-in-oil polymerization technique that, absent a cross-linking agent, is characterized by a Huggins' constant (k?) determined in 0.01M NaCl greater than 0.75 and a storage modulus (G?) for a 1.5 wt. % actives polymer solution at 4.6 Hz greater than 175 Pa.
    Type: Grant
    Filed: July 23, 2007
    Date of Patent: March 24, 2009
    Assignee: Hercules Incorporated
    Inventors: Brian Walchuk, Fushan Zhang, John C. Harrington, William Sean Carey, Richard Lee Brady
  • Patent number: 7396874
    Abstract: A papermaking method and a composition which utilize, as a drainage aid, a water-soluble cationic or amphoteric copolymer prepared via a water-in-oil polymerization technique that, absent a cross-linking agent, is characterized by a Huggins' constant (k?) determined in 0.01M NaCl greater than 0.3 and a storage modulus (G?) at 6.3 Hz greater than 50 Pa.
    Type: Grant
    Filed: December 4, 2003
    Date of Patent: July 8, 2008
    Assignee: Hercules Incorporated
    Inventors: Martha Hollomon, Brian L. Walchuk, Frank J. Sutman
  • Patent number: 7396886
    Abstract: A process for making high specific viscosity copolymers of maleic anhydride and an alkyl vinyl either having as specific viscosity of at least 7, preferably 10-50, are made by copolymerizing maleic anhydride and an alkly vinyl ether monomers in the presence of added acetylene.
    Type: Grant
    Filed: June 21, 2005
    Date of Patent: July 8, 2008
    Assignee: ISP Investments Inc.
    Inventors: Yoon Tae Kwak, Paul D. Taylor, William J. Swatos
  • Patent number: 7306700
    Abstract: The present invention relates to a process for the production of paper from a suspension containing cellulosic fibres, and optional fillers, comprising adding to the suspension drainage and retention aids comprising a cationic organic polymer and anionic microparticulate material, forming and dewatering the suspension on a wire, wherein the cationic organic polymer has a non-aromatic hydrophobic group. The invention further relates to a cationic vinyl addition polymer comprising in polymerized form at least one non-cationic monomer having a non-aromatic hydrophobic group and at least one cationic monomer.
    Type: Grant
    Filed: April 26, 1999
    Date of Patent: December 11, 2007
    Assignee: Akzo Nobel NV
    Inventors: Hans Hällström, Rein Sikkar, Oliver Struck
  • Patent number: 7250448
    Abstract: A papermaking method and a composition which utilize, as a drainage aid, a water-soluble anionic copolymer prepared via a water-in-oil polymerization technique that, absent a cross-linking agent, is characterized by a Huggins' constant (k?) determined in 0.01M NaCl greater than 0.75 and a storage modulus (G?) for a 1.5 wt. % actives polymer solution at 4.6 Hz greater than 175 Pa.
    Type: Grant
    Filed: December 6, 2002
    Date of Patent: July 31, 2007
    Assignee: Hercules Incorporated
    Inventors: Brian Walchuk, Fushan Zhang, John C. Harrington, William Sean Carey, Richard Lee Brady
  • Patent number: 6914112
    Abstract: An ethylene-based copolymer is useful as a modifier for resins, e.g., polypropylene, and can be used in an ethylene/?-olefin copolymer composition containing the same ethylene-based copolymer. The inventive copolymer is characterize by: (a-1) having temperature (Tm) at the maximum peak in the endothermic curve, measured by a differential scanning calorimeter (DSC), of 40 to 90° C., (a-2) containing the component soluble in decane at normal temperature at 1 to 70% b weight, and (a-3) containing the component soluble in decane at normal temperature which comprises (i) a recurring unit derived from ethylene and (ii) a recurring unit derived from an ?-olefin of 4 or more carbon atoms, and in which a content of (i) the recurring unit derived from ethylene is 50 to 75% by mole.
    Type: Grant
    Filed: May 15, 2001
    Date of Patent: July 5, 2005
    Assignee: Mitsui Chemical, Inc.
    Inventors: Ryoji Mori, Kouichi Kizu, Keiji Okada, Kazuyuki Takimoto
  • Patent number: 6881801
    Abstract: In a method of adding catalysts for the polymerization of C2-C20-olefins, the catalyst is firstly introduced into a container A and the cocatalysts used are subsequently mixed with an inert solvent in a container B, and the contents of the container B are introduced into the container A and mixed with the catalyst there and the mixture is introduced from there into the actual polymerization reactor.
    Type: Grant
    Filed: February 28, 2002
    Date of Patent: April 19, 2005
    Assignee: Basell Polyolefine GmbH
    Inventors: Volker Dolle, Eduardo Enrique Chicote
  • Patent number: 6762266
    Abstract: The present invention provides a phase retarder made of a copolymer prepared by polymerizing one non-cyclic olefin monomer (A) selected from ethylene and &agr;-olefin compound having 3 to 20 carbon atoms, one cyclic olefin monomer (B) selected from cyclic olefin compound such as norbornene, and one cyclic vinyl monomer (C) selected from vinyl compound having a cyclic unit made of an aromatic hydrocarbon or an alicyclic hydrocarbon such as styrene or vinylcyclohexane; wherein (1) an amount of the aromatic vinyl monomer is from about 1 to about 20 mol % and a total amount of the non-cyclic olefin monomer (A) and the cyclic olefin monomer (B) is from about 80 to about 99 mol % in case the component (C) is the aromatic vinyl monomer, or (2) an amount of the alicyclic vinyl monomer is from about 80 to about 99 mol % and a total amount of the non-cyclic olefin monomer and the cyclic olefin monomer is from about 1 to about 20 mol % in case the component (C) is the alicyclic vinyl monomer.
    Type: Grant
    Filed: April 17, 2002
    Date of Patent: July 13, 2004
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Keiichi Minakuchi, Koji Higashi, Nobuo Oi
  • Patent number: 6716931
    Abstract: There is provided vulcanized solid rubber, which comprises a vulcanized product of an oil-extended copolymer comprising: (i) 100 parts by weight of an ethylene-&agr;-olefin-non-conjugated diene copolymer satisfying the following requirements (1) to (4), and (ii) 10 to 90 parts by weight of an extender oil: (1) a weight ratio of an ethylene unit to an &agr;-olefin unit in the ethylene-&agr;-olefin-non-conjugated diene copolymer is from 73/27 to 40/60, (2) an iodine value of the ethylene-&agr;-olefin-non-conjugated diene copolymer is from 20 to 36, (3) Mooney viscosity (ML1+4 (121° C.)) measured according to JIS-K-6300 of a blend containing 100 parts by weight of the ethylene-&agr;-olefin-non-conjugated diene copolymer and 20 parts by weight of an extender oil is from 100 to 180, and (4) a ratio of weight average molecular chain length/number average molecular chain length measured by gel permeation chromatography of the ethylene-&agr;-olefin-non-conjugated diene copolymer is from 3 to 5.
    Type: Grant
    Filed: April 2, 2002
    Date of Patent: April 6, 2004
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Junichi Koshiba, Sadayuki Nakano
  • Patent number: 6680361
    Abstract: Shear-thinning ethylene/&agr;-olefin and ethylene/&agr;-olefin/diene monomer interpolymers that do not include a traditional branch-inducing monomer such as norbornadiene are prepared at an elevated temperature in an atmosphere that has little or no hydrogen using a constrained geometry complex catalyst and an activating cocatalyst.
    Type: Grant
    Filed: May 2, 2001
    Date of Patent: January 20, 2004
    Assignee: DuPont Dow Elastomers LLC
    Inventors: Larry Duane Cady, Morgan Mark Hughes, Michael Kenneth Laughner, Larry Alan Meiske, Deepak Rasiklal Parikh
  • Patent number: 6627714
    Abstract: An olefinic copolymer having a cyclic structure is prepared by copolymerizing a) ethylene (M1) and b) dicyclopentadiene or tricyclopentadiene (M2), and, optionally c) a cyclic olefin (M3), in the presence of a catalyst which contains a metallocene compound (A) having formula [1]: H2C(R′mCp)(R″nCp)MX2[1], wherein M is zirconium or hafnium, Cp has a cyclopentadienyl skeleton, each of R′ and R″ is a hydrocarbon group having 1 to 10 carbon atoms, each of two X's which may be the same or different from each other, is a halogen, a hydrogen, a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group, an alkylamino group, an alkoxy group, an aryloxy group of the formula —O—Ar—Yp, a thioalkyl group, or a thioaryl group of the formula —S—Ar—Yp; wherein Ar is an aromatic ring, Y is a halogen, a hydrogen, a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group, an alkoxy group, an alkylamino
    Type: Grant
    Filed: November 5, 2001
    Date of Patent: September 30, 2003
    Assignee: Maruzen Petrochemical Co., Ltd.
    Inventors: Shigeharu Yamamoto, Sakae Kamiyama, Toshifumi Takemori, Yoji Suzuki, Kazuhiko Mizuno, Yoko Furuyama, Hiroshi Yamazaki
  • Patent number: 6620895
    Abstract: Polyethylenes made from ethylene and a series of &agr;-olefins using a catalyst that copolymerizes ethylene and &agr;-olefins usually have excellent melt processing characteristics, especially in uses where high zero shear viscosity and low high shear viscosity are desirable. These polyethylenes are preferably made by forming the &agr;-olefins in situ from ethylene during the polymerization process. The polyethylenes are especially useful in blow molding, extrusion or extruded blown film processes.
    Type: Grant
    Filed: September 28, 2000
    Date of Patent: September 16, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Patricia Metzger Cotts, William Howard Tuminello, Lin Wang, Joel David Citron
  • Patent number: 6596832
    Abstract: A drag-reducing polymer capable of dissolving even in cold fluids is described, along with a method for manufacturing said drag-reducing polymer. The drag-reducing polymer has at least one alpha-olefin monomer with between a four and nine carbon chain length and a co-monomer and has less than 25% monomers (molar content) with carbon chain lengths of 12 or longer. A drag-reducing polymer suspension is also described.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: July 22, 2003
    Assignee: ConocoPhillips Company
    Inventors: Ray L. Johnston, Stuart N. Milligan
  • Patent number: 6552149
    Abstract: A process for producing terpolymers of propylene, comprising a) feeding into a slurry reactor a reaction mixture containing 50-85 w-% of propylene, 1-10 w-% of ethylene, 15-40 w-% of another C4-C8 alpha-olefin, a catalyst system maintaining olefin polymerization at said temperature conditions, and optionally hydrogen, b) polymerizing said reaction mixture at a temperature of lower than 70° C. a sufficient time to obtain a propylene terpolymer amounting to 50-99 w-% of the end product, c) transferring said reaction mixture into a gas phase reactor operating at a pressure of higher than 5 bars, preferably higher than 10 bars, optionally adding 0-30 w-% of ethylene, 0-10 w-% of another C4-C8 alpha-olefin, 0-40 w-% of propylene and optionally hydrogen, and d) continuing polymerization in said gas phase reactor for obtaining a propylene terpolymer amounting to 1-50 wt-% of the end product. The terpolymer has a melting temperature a less than 135° C., preferably less than 132° C.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: April 22, 2003
    Assignee: Borealis Technology Oy
    Inventors: Kauno Alastalo, Bo Malm, Päivi Pitkänen, Mika Meller, Anne Britt Bjåland, Nina Ackermans, Kshama Motha
  • Publication number: 20020165330
    Abstract: This invention relates to a polyolefin copolymer composition produced with a catalyst having a metallocene complex in a single reactor in a process for the polymerization of an &agr;olefin monomer with one or more olefin comonomers, and a molecular weight maximum which occurs in that 50 percent by weight of the composition which has the highest weight percent comonomer content. Preferably, the composition has a comonomer partitioning factor C pf which is equal to or greater than 1.10 or molecular weight partitioning factor M pf which is equal to or greater than 1.15. Preferred composition also have at least 0.01 long chain branches per 1000 carbon atoms along the polymer backbone. These compositions with reverse molecular engineering have superior properties and are easily processable due to the simultaneous presence of the association of high molecular weight with high comonomer content and of long chain branching.
    Type: Application
    Filed: November 6, 1998
    Publication date: November 7, 2002
    Inventors: LARRY D. CADY, CHRISTOPHER J. FRYE, PHILIP HOWARD, TERESA P. KARJALA, PETER J. MADDOX, IAN M. MUNRO, DEEPAK R. PARIKH, S. ROY PARTINGTON, KEVIN P. PEIL, LEE SPENCER, WILLIAM R. VAN VOLKENBURGH, PETER S. WILLIAMS, DAVID R. WILSON, J. MARK WINTER
  • Patent number: 6465584
    Abstract: The invention relates to an elastomeric copolymer derived from components comprising a) ethylene, b) an &agr;-olefin, c) a non-conjugated polyene (C) having one C═C bond that is copolymerizable using a Ziegler-Natta catalyst, and d) optionally a non-conjugated polyene (D) which in the molecule contains two or more C═C bonds that are copolymerizable using a Ziegler-Natta catalyst. The copolymer is characterized by, inter alia, a specific branching coefficient BC. The invention also relates to a process for the preparation of such copolymers.
    Type: Grant
    Filed: December 27, 1999
    Date of Patent: October 15, 2002
    Assignee: DSM N.V.
    Inventors: Georges G. Evens, Emanuel M. J. Pijpers, Andreas A. Oosterlaken, Jacob Renkema, Henri J. H. Beelen
  • Patent number: 6462161
    Abstract: The invention relates to a polyolefin copolymer composition produced with a catalyst having a metallocene, complex in a single reactor for the polymer of an &agr;-olefin monomer with one or more olefin comonomers, and a molecule weight maximum which occurs in that 50 percent by weight of the composition which has the highest weight percent comonomer content. Preferably, the composition has a comonomer partitioning fact Cpf which is equal to or greater than 1.10 or molecule weight partitioning fact Mpf which is equal to or greater than 1.15. Preferred composition also have at least 0.01 long chain branches per 1000 carbon atoms along the polymer backbone. These compositions with reverse molecular engineering have. superior properties and are easily processable due to the simultaneous presence of the association of high molecular weight with high comonomer content and of long chain branching.
    Type: Grant
    Filed: November 6, 1998
    Date of Patent: October 8, 2002
    Assignee: BP Chemicals Limited
    Inventors: Larry D. Cady, Christopher J. Frye, Philip Howard, Teresa P. Karjala, Peter J. Maddox, Ian M. Munro, Deepak R. Parikh, S. Roy Partington, Kevin P. Peil, Lee Spencer, William R. Van Volkenburgh, Peter S. Williams, David R. Wilson, J. Mark Winter
  • Patent number: 6451946
    Abstract: A copolymer of (a)ethylene and/or an &agr;-olefin, (b) a cyclic olefin and (c) an alkenyl aromatic hydrocarbon, having acyclic olefin content of 0.01 to 66 mol % and a styrene content of 3 to 99 mol %, wherein the styrene content is more than a half of the cyclic olefin content, a process for producing the copolymer with a specific catalyst and a molded article made from the copolymer. The copolymer and molded article thereof are transparent, and excellent in flexibility and heat resistance.
    Type: Grant
    Filed: December 9, 1999
    Date of Patent: September 17, 2002
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Nobuo Oi, Yasuro Suzuki, Tatsuya Miyatake
  • Patent number: 6420506
    Abstract: An &agr;-olefin-alkenyl aromatic hydrocarbon-diene copolymer, a process for producing the copolymer, which comprises copolymerizing an &agr;-olefin, a mono-alkenyl aromatic hydrocarbon and a diene in the presence of a specific catalyst, and a molded article comprising the copolymer.
    Type: Grant
    Filed: March 2, 2000
    Date of Patent: July 16, 2002
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Nobuo Oi, Yuki Iseki, Yasuro Suzuki
  • Patent number: 6417300
    Abstract: Disclosed are terpolymers and processes of terpolymerization, wherein the terpolymer comprises units derived from ethylene, 1-pentene and another alpha-olefin containing at least six carbon atoms.
    Type: Grant
    Filed: May 12, 1999
    Date of Patent: July 9, 2002
    Assignee: Sasol Technology Proprietary Limited
    Inventors: Dawid Johannes Joubert, Ignatius Hendrik Potgieter, Ioan Tincul
  • Patent number: 6388051
    Abstract: A process for selecting and extruding a copolymer having improved extrusion processability comprising (a) selecting one or more copolymers of ethylene and one or more alpha-olefins having 3 to 12 carbon atoms, each of said copolymers having essentially no long chain branching and having (1) a melt index selected from the range of about 0.1 to about 20 grams per 10 minutes, and (2) a melt flow ratio having at least about a value determined by the following formula: 2.7183 to the power of {(1.477 minus [0.279 times the natural logarithm of the selected melt index]) divided by 0.29} and (b) extruding said copolymer around an electrical conductor.
    Type: Grant
    Filed: December 20, 2000
    Date of Patent: May 14, 2002
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Jinder Jow, Alfred Mendelsohn
  • Patent number: 6365682
    Abstract: A process for producing terpolymers of propylene, comprising a) feeding into a slurry reactor a reaction mixture containing 50-85 w-% of propylene, 1-10 w-% of ethylene, 15-40 w-% of another C4-C8 alpha-olefin, a catalyst system maintaining olefin polymerization at said temperature conditions, and optionally hydrogen, b) polymerizing said reaction mixture at a temperature of lower than 70° C. a sufficient time to obtain a propylene terpolymer amounting to 50-99 w-% of the end product, c) transferring said reaction mixture into a gas phase reactor operating at a pressure of higher than 5 bars, preferably higher than 10 bars, optionally adding 0-30 w-% of ethylene, 0-10 w-% of another C4-C8 alpha-olefin, 0-40 w-% of propylene and optionally hydrogen, and d) continuing polymerization in said gas phase reactor for obtaining a propylene terpolymer amounting to 1-50 wt-% of the end product. The terpolymer has a melting temperature a less than 135° C., preferably less than 132° C.
    Type: Grant
    Filed: February 22, 2000
    Date of Patent: April 2, 2002
    Assignee: Borealis Technology Oy
    Inventors: Kauno Alastalo, Bo Malm, Päivi Pitkänen, Mika Meller, Anne Britt Bjåland, Nina Ackermans, Kshama Motha
  • Patent number: 6316560
    Abstract: The invention relates to a method for producing a cycloolefin copolymer by polymerization of 0.1-99.0 wt %, with respect to the total amount of monomers, of at least one polycyclic, 0-99.9 wt. %, with respect to the total amount of monomers, of at least one moncyclic olefin, and 0.1-99.9 wt. %, with respect to the total amount of monomers, of at least one acyclic 1-olefin, in the presence of a catalyst system consisting of at least one cocatalyst and at least one metallocene.
    Type: Grant
    Filed: July 29, 1999
    Date of Patent: November 13, 2001
    Assignee: Ticona GmbH
    Inventors: Alexandra Jacobs, Gerhard Fink, Dieter Ruchatz
  • Patent number: 6300447
    Abstract: An ethylene-&agr;-olefin-nonconjugated polyene random copolymer obtained by polymerizing the following components (a), (b) and (c) in the presence of a catalyst comprising a transition metal complex having at least one cyclopentadienyl skeleton and satisfying the conditions (1), (2), (3) and (4): (a) ethylene, (b) &agr;-olefin having 3 to 20 carbon atoms, and (c) one or more nonconjugated polyene at least containing a nonconjugated polyene in which at least one or more hydrogen atoms are respectively bound to all of carbon atoms having a double bond; (1) the molar ratio of a unit derived from ethylene to a unit derived from &agr;-olefin in the copolymer is 95/5 to 20/80, (2) the iodine value is 0 to 50 (g/100 g polymer), (3) the intrinsic viscosity [&eegr;] measured in xylene at 70° C. is 0.5 to 10 dl/g, and (4) the Q value (weight average molecular weight/number average molecular weight) measured by gel permeation chromatography (GPC) is 3.0 or more.
    Type: Grant
    Filed: May 20, 1999
    Date of Patent: October 9, 2001
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hirofumi Johoji, Toshiyuki Kuwabara, Atsuko Ogawa
  • Patent number: 6288193
    Abstract: An ethylene-based polymer comprising ethylene and at least one addition polymerizable monomer containing a vinyl compound (A) described below, wherein the ethylene-based polymer has a melting temperature (Tm) of 119 ° C. or lower and, the melt index MI (g/10 minutes) of the ethylene-based polymer and the molar content “m” (mole %) of the vinyl compound (A) satisfy the following formula (1): Vinyl compound (A): a vinyl compound represented by the structural formula CH2═CH—R containing a saturated hydrocarbon group R wherein the substituent R has a steric parameter Es of not less than −2.77 and not more than −1.64 and the substituent R has a steric parameter B1 of not less than 1.53 and not more than 2.90: 0.01≧MI≦18+m1.
    Type: Grant
    Filed: October 25, 1999
    Date of Patent: September 11, 2001
    Assignee: Sumitomo Chemical Co., Ltd.
    Inventors: Yuki Iseki, Yasuro Suzuki
  • Patent number: 6281316
    Abstract: A polymer of the invention comprising the comonomers ethylene, one or more alpha-olefins having 3 to 20 carbon atoms, and one or more cyclic dienes having up to 30 carbon atoms, said polymer having a density of at least 0.890 gram per cubic centimeter; long chain branching; a plurality of double bonds; an Mw/Mn ratio ratio (PDI) of at least 2.5; a flow activation energy of greater than about 6.5 kcal/mol; and a Relaxation Spectrum Index (RSI), PDI, and Melt Index (MI), such that RSI·MIa>2.7 and RSI·MIa·PDIb is in the range of about 0.8 to about 60, when a and b are about 0.6 and minus 1.2, respectively.
    Type: Grant
    Filed: March 22, 1999
    Date of Patent: August 28, 2001
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Scott Hanley Wasserman, James LaMonte Adams, Tong Chen, George Norris Foster, Laurence Herbert Gross, Day-Chyuan Lee, Walter Thomas Reichle, Robert Harold Vogel
  • Patent number: 6262215
    Abstract: Elastomeric ethylene/propylene or ethylene/propylene/polyene copolymers containing small amounts of one or more &agr;-olefins are prepared by a slurry process wherein the polymerization reaction is carried out in a mixture of liquid propylene and alpha-olefin.
    Type: Grant
    Filed: February 7, 2000
    Date of Patent: July 17, 2001
    Assignee: Montell Technology Company bv
    Inventors: Maurizio Galimberti, Enrico Albizzati
  • Patent number: 6255425
    Abstract: A syndiotactic polypropylene copolymer is disclosed which comprises 70 to 99.9 mole % of propylene and 0.1 to 30 mole % of an olefin other than propylene; in the 13C-NMR spectrum of the syndiotactic polypropylene copolymer, a ratio of the intensity of a peak at about 20.2 ppm to the sum of the intensities of the total peaks attributable to methyl groups in propylene units at about 19-22 ppm being 0.3 or more. Also disclosed are extrusion-molded high-transparency articles, especially films and sheets and blown films, obtained by the extrusion of a polypropylene substantially having a syndiotactic structure.
    Type: Grant
    Filed: January 18, 1994
    Date of Patent: July 3, 2001
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Tadashi Asanuma, Tetsunosuke Shiomura, Nobutaka Uchikawa, Tateyo Sasaki, Osamu Uchida, Tutomu Iwatani, Shigeru Kimura, Takeo Inoue
  • Patent number: 6221984
    Abstract: Random copolymers of propylene with ethylene and at least one C4-C10-alk-1-ene, having a melting point, determined by the DSC method, of less than or equal to 135° C., are obtainable by polymerization of propylene, ethylene and at least one C4-C10-alk-1-ene in the absence of a liquid reaction medium from the gas phase at from 50 to 100° C. and a pressure of from 15 to 40 bar in the presence of a Ziegler-Natta catalyst system comprising a) a titanium-containing solid component comprising at least one halogen-containing magnesium compound, an electron donor and an inorganic oxide as support, b) an aluminum compound and c) a further electron donor compound, wherein the ratio of the partial pressures of propylene and ethylene is set to from 20:1 to 100:1 and the ratio of the partial pressures of the C4-C10-alk-1-ene(s) and ethylene is set to from 2.5:1 to 20:1. A process for preparing such random copolymers is also provided, and they can be used in films, fibers or moldings.
    Type: Grant
    Filed: May 21, 1998
    Date of Patent: April 24, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Meinolf Kersting, Werner Schöne, Franz Langhauser
  • Patent number: 6218488
    Abstract: The invention is a polymerization process for ethylene copolymers having a density less than 0.915 comprising contacting ethylene, one or more &agr;-olefin monomer, and optionally one or more diene monomer, with a catalyst composition comprising the reaction product of at least one organometallic Group 4 metallocene compound derived from a bridged, fused-ring ligand containing biscyclopentadienyl hafnocene, said bridge being a substituted or unsubstituted carbon or silicon atom connecting the biscyclopentadienyl ligands, and a salt of a Group 13 element anionic complex having halogenated aromatic ligands in an essentially tetrahedral structure wherein the aromatic groups are polycyclic fused or pendant aromatic rings. The process is particularly suitable for the preparation of high comonomer content and high molecular weight ethylene-&agr;-olefin plastomers and ethylene-propylene or ethylene-propylene-diene monomer elastomers.
    Type: Grant
    Filed: March 4, 1999
    Date of Patent: April 17, 2001
    Assignee: Exxon Mobil Chemical Patents Inc.
    Inventors: Rinaldo S. Schiffino, Donna J. Crowther, Bernard J. Folie, John F. Walzer, Jr.
  • Patent number: 6207779
    Abstract: The present invention provides a ring-opened polymer, which is prepared by reacting at least one pericyclic olefin elected from those represented by formulae (I) and (II) through ring-opening metathesis polymerization wherein A and B may be the same or different and are independently selected from the group consisting of halogen, hydrogen, C3-20 cyclic or pericyclic alkyl, C1-20 linear and branched alkyl, C6-20 aryl, C7-20 arylalkyl, C7-20 alkylaryl, silyl, alkylsilyl, germyl, alkylgermyl, alkoxycarbonyl, acyl, and a heterocylic group; or, A and B are linked together to form a C3-20 saturated or unsaturated cyclic hydrocarbon group or a substituted or unsubstituted heterocyclic group; C is selected from the group consisting of oxygen, sulfur,  —CH2—, and —SiH2—, wherein each R1 is independently selected from C1-20 alkyl and phenyl; each R is independently selected from hydrogen, halogen, and C1-20 alkyl; and each n is an integer from 1 to 6
    Type: Grant
    Filed: December 17, 1998
    Date of Patent: March 27, 2001
    Assignees: Industrial Technology Research Institute, Everlight Chemical Industrial Corporation
    Inventors: Sheng-Yueh Chang, Bang-Chein Ho, Jian-Hong Chen, Tai-Sheng Yeh, Jui-Fa Chang
  • Patent number: 6207773
    Abstract: A metallocene complex in which the cyclopentadienyl group is substituted with an alkanediyl silyl group. The yield of the metallocene complex is high, and it can be used as the catalyst for preparing high molecular weight olefin polymers.
    Type: Grant
    Filed: July 28, 1999
    Date of Patent: March 27, 2001
    Assignees: Industrial Technology Research Institute, Taiwan Synthetic Rubber Corporation, Chinese Petroleum Corporation
    Inventors: Ching Ting, Jing-Cherng Tsai, Yi-Chun Chen, Sung-Song Hua, Tsai-Tien Su, Yu-Shan Chao
  • Patent number: 6194526
    Abstract: A process to produce a polymer is provided. The process comprises polymerizing monomers wherein the monomers comprise ethylene, 1-butene, and 1-hexene. The total amount of 1-butene and 1-hexene in the polymer is less than 10 mole percent of the polymer, and the mole ratio of 1-butene to 1-hexene is in a range of 4:1 to 9:1. The polymerizing is conducted in a loop reactor under slurry polymerization conditions with a diluent that comprises isobutane, where the isobutane is a majority of the diluent by weight. A catalyst that comprises titanium, magnesium, and halide and a cocatalyst that comprises organoaluminum are utilized. The polymerizing is conducted at a temperature from 73° C. to 85° C. The polymer produced has a heterogeneity index (Mw/Mn) from about 3 to about 7, a density from about 0.915 to about 0.925 grams per cubic centimeter, a melt index from about 0.25 to about 3.5 grams per ten minutes, and a shear ratio from about 24 to about 30.
    Type: Grant
    Filed: July 7, 1998
    Date of Patent: February 27, 2001
    Assignee: Phillips Petroleum Company
    Inventors: Elizabeth A. Benham, Rhutesh K. Shah, Ashish M. Sukhadia, Joel L. Martin, Max P. McDaniel
  • Patent number: 6191246
    Abstract: The invention provides a polymer which is a polymerization product obtained by polymerizing at least ethylene, 1-pentene and 1-hexene; and a process for producing a polymer by reacting at least ethylene, 1-pentene and 1-hexene in a reaction zone at a pressure between atmospheric and 60 kg/cm3 and at a temperature between 30° C. and 120° C., in the presence of a catalyst system. The invention also provides a polymer composition which comprises a terpolymer of ethylene, 1-pentene and 1-hexene, a phenolic stabilizer component, a metal salt of a higher aliphatic acid, and, optionally, at least one organic phosphite stabilizer.
    Type: Grant
    Filed: January 12, 1998
    Date of Patent: February 20, 2001
    Assignee: Sasol Technology (Proprietary) Limited
    Inventors: Dawid Johannes Joubert, Ignatius Hendrik Potgieter, Ioan Tincul, Peter Loggenberg
  • Patent number: 6180738
    Abstract: There is provided a polymerization, especially a gas phase polymerization, of a sticky polymer in the presence of a catalyst under polymerization conditions using carbon black as an inert particulate material, the improvement comprises conducting said polymerization in the presence of a carbon black having a sugar-containing or sugar-derived binder, which carbon black is prepared by heating the carbon black to a temperature of at least about 280° C. for a time sufficient to decompose said sugar-containing or sugar-derived binder prior to polymerization.
    Type: Grant
    Filed: June 29, 1999
    Date of Patent: January 30, 2001
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Weidong Wang, Kevin Joseph Cann
  • Patent number: 6180554
    Abstract: The present invention relates to a catalyst system comprising: a) an organoaluminum compound, b) a metal compound selected from subgroups IV to VI of the periodic system, c) a reactivator in a molar ratio of 0.5 to 100 relative to compound b), wherein said reactivator comprises a characterized in that a mono- or dihalocarboxylic acid alkyl ester of the following formula: wherein X is a C1-6 alkyl or C1-6 alkoxy group, Y is Cl, Br or H, Z is Cl or Br and R is a C1-6 alkyl group.
    Type: Grant
    Filed: June 22, 1999
    Date of Patent: January 30, 2001
    Assignee: Bayer Aktiengesellschaft
    Inventors: Martin Hoch, Johannes-Rudolf Jansen, Thomas Essert, Andreas Sattler, J{umlaut over (u)}rgen Schneider
  • Patent number: 6084047
    Abstract: The present invention is an elastomeric polyolefin terpolymer comprising about 5 to 25 weight percent ethylene units, from greater than about 5 to about 40 weight percent hexene units, and about 35 to less than about 90 weight percent propylene units, wherein the total weight percent of monomer units equals 100 percent. The high molecular weight terpolymer is amorphous, is elastomeric, has a melt flow rate of about 0.01 to 500 grams per 10 minutes and has a tensile set of about 65 to 120 percent, according to ASTM D-412.
    Type: Grant
    Filed: November 6, 1997
    Date of Patent: July 4, 2000
    Assignee: Eastman Chemical Company
    Inventors: Robert Emmett Holliday, Richard Kingsley Stuart, Jr.
  • Patent number: 6060164
    Abstract: Primary polymer particles having a size at least 90% below 10 .mu.m and which contain water soluble and water insoluble polymer are made by reverse phase polymerisation of a water soluble ethylenically unsaturated monomer or monomer blend with cross linking agent, and the emulsion is then spray dried to form spray dried granules which disintegrate upon addition to water, thereby forming an aqueous composition of the insoluble particles having activity similar to the starting emulsion. This aqueous composition of insoluble particles is particularly useful for flocculation, for instance flocculation of sewage sludge followed by centrifugation or belt pressing, or for viscosification.
    Type: Grant
    Filed: May 29, 1997
    Date of Patent: May 9, 2000
    Assignee: Ciba Specialty Chemicals Water Treatments Limited
    Inventors: Michael Green, Malcolm Hawe, John Rodney Field
  • Patent number: 6046287
    Abstract: Elastomeric ethylene/propylene or ethylene/propylene/-polyene copolymers containing small amounts of one or more .alpha.-olefins are prepared by a slurry process wherein the polymerization reaction is carried out in a mixture of liquid propylene and alpha-olefin. Problems due to fouling phenomena in the reactor are avoided.
    Type: Grant
    Filed: April 3, 1997
    Date of Patent: April 4, 2000
    Assignee: Montell Technology Company bv
    Inventors: Maurizio Galimberti, Enrico Albizzati
  • Patent number: 5866665
    Abstract: Substantially random ethylene copolymers containing at least 3.0 mole percent of geminally disubstituted olefin monomers are described. The geminally disubstituted olefin monomers can be represented by the generic formula R.sub.1 =R.sub.2 (R.sub.3)(R.sub.4), where R.sub.1 is CH.sub.2, R.sub.2 is C, and R.sub.3 and R.sub.4 are, independently, essentially linear hydrocarbyl groups having from 1 to 30 carbon atoms, or more, and containing one carbon atom bound directly to R.sub.2. The copolymers can be prepared by coordination polymerization by means of contacting at least one geminally disubstituted olefin monomer and ethylene, optionally with one or more other coordination polymerizable monomers, with a catalyst system comprising a monocyclopentadienyl, heteroatom-containing Group 4 transition metal catalyst component.
    Type: Grant
    Filed: October 28, 1997
    Date of Patent: February 2, 1999
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Timothy Daniel Shaffer, Jo Ann Marie Canich, Kevin Richard Squire
  • Patent number: 5807946
    Abstract: Motor vehicle brake parts based on an ethylene, alpha-olefin, vinyl norbornene elastomeric polymer are manufactured with more efficiency due to brake part compounds having lower viscosity, faster and fuller cures than ethylene, alpha-olefins, diene monomer compounds, where the diene monomer is other than vinyl norbornene. Additionally, the brake parts based on the ethylene, alpha-olefin, vinyl norbornene elastomeric polymer have improved resistance to elevated temperature properties, and good heat aging characteristics, compared to for instance ethylene, alpha-olefin, non-conjugated diene elastomers (where the diene is other than vinyl norbornene) or styrene butadiene rubbers.
    Type: Grant
    Filed: June 14, 1995
    Date of Patent: September 15, 1998
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Eric Paul Jourdain, Periagaram S. Ravishankar
  • Patent number: 5780567
    Abstract: Syndiotactic terpolymers of styrene comprising repetitive units deriving from:a) 99.5-60% in moles of styrene; andb) 0.5-40% in moles of vinyltoluene having a weight average molecular weight of more than 20,000 and a stereoregularity of the syndiotactic type of more than 90%.
    Type: Grant
    Filed: May 17, 1996
    Date of Patent: July 14, 1998
    Assignee: Enichem S.p.A.
    Inventors: Riccardo Po, Nicoletta Cardi
  • Patent number: 5763556
    Abstract: Substantially random ethylene copolymers containing at least 3.0 mole percent of geminally disubstituted olefin monomers are described. The geminally disubstituted olefin monomers can be represented by the generic formula R.sub.1 =R.sub.2 (R.sub.3)(R.sub.4), where R.sub.1 is CH.sub.2, R.sub.2 is C, and R.sub.3 and R.sub.4 are, independently, essentially linear hydrocarbyl groups having from 1 to 30 carbon atoms, or more, and containing one carbon atom bound directly to R.sub.2. The copolymers can be prepared by coordination polymerization by means of contacting at least one geminally disubstituted olefin monomer and ethylene, optionally with one or more other coordination polymerizable monomers, with a catalyst system comprising a monocyclopentadienyl, heteroatom-containing Group 4 transition metal catalyst component.
    Type: Grant
    Filed: May 21, 1996
    Date of Patent: June 9, 1998
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Timothy Daniel Shaffer, Jo Ann Marie Canich, Kevin Richard Squire
  • Patent number: 5698650
    Abstract: Motor vehicle brake parts and power transmission belt based on an ethylene, alpha-olefin, vinyl norbornene elastomeric polymer are manufactured with more efficiency due to brake part compounds having lower viscosity, faster and fuller cures than ethylene, alpha-olefins, diene monomer compounds, where the diene monomer is other than vinyl norbornene. Additionally, the brake parts and the power transmission belt based on the ethylene, alpha-olefin, vinyl norbornene elastomeric polymer have improved resistance to elevated temperature properties, and good heat aging characteristics, compared to for instance ethylene, alpha-olefin, non-conjugated diene elastomers (where the diene is other than vinyl norbornene) polychloroprene, or styrene butadiene rubbers.
    Type: Grant
    Filed: September 20, 1996
    Date of Patent: December 16, 1997
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Eric Paul Jourdain, Periagaram Srinivasan Ravishankar