Ethylenic Monomers Containing At Least One Salt Group Patents (Class 526/923)
  • Patent number: 11945977
    Abstract: A hot melt adhesive comprises at least one polymer selected from the group consisting of polystyrene, polybutene, polyisobutene, linear low density polyethylene, polypropylene random copolymer, polypropylene, olefin block copolymer, polyolefins, styrene block copolymers, and ethyl vinyl acetate polymers; a tackifying resin; and at least one precisely end-capped polystyrene (PECPS). The use of the styrene-based oligomers and polymers with the precisely controlled end-groups in hot melt adhesive formulations to improve compatibility with polymers and block copolymers frequently used in such adhesives.
    Type: Grant
    Filed: February 20, 2018
    Date of Patent: April 2, 2024
    Assignee: Bostik, Inc.
    Inventors: Steven D. Gray, Darius K. Deak, Brian R. Minix, Edward P. Tomlinson
  • Patent number: 8883946
    Abstract: Here is provided a charge control resin which is prompt in charge rising up, excellent in electrostatic charging propensity and easy in manufacturing. This charge control resin contains a polymer as an active ingredient having a constituent unit represented by following Formula (1) in the Formula (1), R1 is independent of one another, and is a hydrogen atom, a hydroxyl group, a halogen atom, a carboxy-containing group, a straight-chained or branched alkyl group having 1-18 carbon atoms, or a straight-chained or branched alkoxy group having 1-18 carbon atoms; R2 is a hydrogen atom, a hydroxyl group, a halogen atom, a carboxy-containing group, a straight-chained or branched alkyl group having 1-18 carbon atoms, or a straight-chained or branched alkoxy group having 1-18 carbon atoms; g is a number of 1-3; h is a number of 1-3; and M is a hydrogen atom, an alkali metal, a straight-chained or branched alkyl group having 1-18 carbon atoms, an ammonium radical or a mixture of any of these.
    Type: Grant
    Filed: May 17, 2012
    Date of Patent: November 11, 2014
    Assignee: Orient Chemical Industries Co., Ltd.
    Inventors: Masashi Yasumatsu, Kaori Inoue, Satoko Ozaki
  • Patent number: 8653215
    Abstract: A process for producing water-absorbing polymer particles by polymerizing an aqueous monomer solution in a kneader having at least two shafts in axially parallel rotation, wherein the reaction mixture is transported in axial direction and the region at the start of the kneader is trace-heated.
    Type: Grant
    Filed: May 23, 2012
    Date of Patent: February 18, 2014
    Assignee: BASF SE
    Inventors: Matthias Weismantel, Ulrich Riegel, Markus Braun, Martin Wendker, Thomas Gieger
  • Patent number: 8592541
    Abstract: Gypsum wallboard can be made lighter and less dense, without sacrificing strength, by adding to the gypsum slurry used in making the board a styrene butadiene polymer latex substantially stable against divalent ions in which the styrene butadiene polymer includes at least 0.25 wt. % of an ionic monomer.
    Type: Grant
    Filed: February 1, 2011
    Date of Patent: November 26, 2013
    Assignee: OMNOVA Solutions Inc.
    Inventor: Ira John Westerman
  • Patent number: 8592539
    Abstract: Methods of forming a cobaltocenium-containing polymer are provided through polymerizing a plurality of cobaltocenium-containing monomers via controlled radical polymerization or controlled ring-opening polymerization. Each cobaltocenium-containing monomer comprises a cobaltocenium moiety covalently connected to a polymerizable group. Cobaltocenium-containing monomers are also provided that include a cobaltocenium moiety covalently connected to a polymerizable group. Cobaltocenium-containing polymers are also generally provided, such as the polymers formed according to any of the methods or from any of the monomers discussed herein. Methods are also generally provided for exchanging an anion associated with a cobaltocenium side group of a cobaltocenium-containing polymer with a new anion.
    Type: Grant
    Filed: August 15, 2011
    Date of Patent: November 26, 2013
    Assignee: University of South Carolina
    Inventors: Chuanbing Tang, Lixia Ren
  • Patent number: 8541528
    Abstract: A process for producing water-absorbing polymer particles, wherein an aqueous polymer gel is dried in a forced-air belt drier on a circulating conveyor belt and the surface of the conveyor belt has a multitude of elevations or depressions which are suitable for restricting the mobility of the aqueous polymer gel in transverse direction.
    Type: Grant
    Filed: February 22, 2011
    Date of Patent: September 24, 2013
    Assignee: BASF SE
    Inventors: Rüdiger Funk, Thomas Pfeiffer, Matthias Weismantel, Stefan Blei, Wilfried Heide, Volker Braig, Thomas Gieger, Andreas Brockmeyer
  • Patent number: 8461278
    Abstract: A process for producing water-absorbing polymer particles, wherein heated water-absorbing polymer particles are remoisturized and cooled in a high-speed mixer.
    Type: Grant
    Filed: March 24, 2011
    Date of Patent: June 11, 2013
    Assignee: BASF SE
    Inventors: Rüdiger Funk, Thomas Pfeiffer
  • Patent number: 7879965
    Abstract: A polymer latex suitable for use in gypsum wallboard or other applications. The polymer latex is a styrene butadiene latex that is substantially stable against divalent ions. The polymer latex includes styrene, butadiene, and an ionic monomer comprised of a 2-acrylamido-2-methyl propanesulfonic acid salt. The polymer latex may also include hydrophilic adjunct comonomers. The latex includes at least 0.25 wt. % of the ionic monomer.
    Type: Grant
    Filed: April 4, 2008
    Date of Patent: February 1, 2011
    Assignee: OMNOVA Solutions Inc.
    Inventor: Ira John Westerman
  • Patent number: 7683150
    Abstract: A water-absorbing resin has a polymer molecular chain in which 50 mol % or more of repeating units in the chain are carboxy group-containing units, wherein the carboxy group neutralization ratio in the central part of the resin is 60 mol % or more and the carboxy group neutralization ratio on the external surface of the resin is 50 mol % or less. A method for producing the water-absorbing resin comprises polymerizing a monomer solution to form a polymer, drying the resulting polymer, and heat-treating the dried polymer, wherein the monomer solution contains a mixture comprising an alkali metal salt of an unsaturated carboxylic acid and an ammonium salt thereof, the percentage of the ammonium salt being more than 50 mol % of the mixture, and further contains a condensation crosslinking agent.
    Type: Grant
    Filed: July 27, 2006
    Date of Patent: March 23, 2010
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Naonori Higashimoto, Tsutomu Nakagawa
  • Patent number: 7348382
    Abstract: A recording liquid capable of giving a printed matter which is high in printing density, is suppressed in blur, has high printing quality, and has good fastness of a recorded matter including light fastness, water fastness and the like and having a low viscosity, good discharge properties and excellent storage stability. The invention is concerned with a polyvinyl alcohol based block copolymer represented by the following general formula (1), a pigment dispersion aqueous liquid containing this polyvinyl alcohol based block copolymer and a pigment in an aqueous medium, and a recording liquid containing this pigment dispersion aqueous liquid. wherein A, B, X1, X2, X3, X4, m1, and m2 have the same meanings as defined in the specification.
    Type: Grant
    Filed: October 3, 2005
    Date of Patent: March 25, 2008
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Nobuhiko Ueno, Takahiro Saitou, Masanobu Yokoyama, Hideko Akai, Hideaki Tanaka
  • Patent number: 7339016
    Abstract: Disclosed is a method for preparing a water-absorbent polymer composite comprising the steps of contacting a droplet containing a solvent and said polymerizable monomer before polymerization and/or under polymerization with first fibers fed through a first supply port of said reactor in a gas phase, proceeding with polymerization of said polymerizable monomer, contacting the resultant droplet containing said solvent, the polymerizable monomer under polymerization and said first fibers with second fibers fed through a second supply port of said reactor in a gas phase, and proceeding with further polymerization of said polymerizable monomer to form said water-absorbent polymer composite.
    Type: Grant
    Filed: October 21, 2005
    Date of Patent: March 4, 2008
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Shunichi Himori, Kiichi Itoh, Yoshiaki Mori, Yasunari Sugyo, Taisuke Ishii
  • Patent number: 7306700
    Abstract: The present invention relates to a process for the production of paper from a suspension containing cellulosic fibres, and optional fillers, comprising adding to the suspension drainage and retention aids comprising a cationic organic polymer and anionic microparticulate material, forming and dewatering the suspension on a wire, wherein the cationic organic polymer has a non-aromatic hydrophobic group. The invention further relates to a cationic vinyl addition polymer comprising in polymerized form at least one non-cationic monomer having a non-aromatic hydrophobic group and at least one cationic monomer.
    Type: Grant
    Filed: April 26, 1999
    Date of Patent: December 11, 2007
    Assignee: Akzo Nobel NV
    Inventors: Hans Hällström, Rein Sikkar, Oliver Struck
  • Patent number: 7208555
    Abstract: The present invention provides a polyvinylidene fluoride copolymer capable of forming a uniform film, a solution of the copolymer and a thin film comprising the polyvinylidene fluoride copolymer. The polyvinylidene fluoride copolymer of the present invention is characterized in that the ratio of the scattered-light intensity (I) for a 15% solution of the polyvinylidene fluoride copolymer in dimethylformamide solvent to the scattered-light intensity (I0) for dimethylformamide, (I/I0), is 10 or lower. The polyvinylidene fluoride copolymer solution comprises the polyvinylidene fluoride copolymer and an organic solvent capable of dissolving the copolymer.
    Type: Grant
    Filed: September 17, 2003
    Date of Patent: April 24, 2007
    Assignee: Kureha Chemical Industry Company, Limited
    Inventors: Masahito Tada, Takumi Katsurao, Tsukasa Ikeda, Kazuyuki Suzuki
  • Patent number: 6488764
    Abstract: A cement composition comprising a polymeric latex prepared by aqueous emulsion polymerization of a monomeric mixture comprising styrene and butadiene in the presence of a seed polymer prepared by aqueous emulsion polymerization of styrene and a salt of 2-acrylamido-2-methylpropanesulfonic acid.
    Type: Grant
    Filed: September 11, 2001
    Date of Patent: December 3, 2002
    Assignee: OMNOVA Solutions Inc.
    Inventor: Ira John Westerman
  • Publication number: 20020103291
    Abstract: A polymeric latex prepared by aqueous emulsion polymerization of a monomeric mixture comprising styrene and butadiene in the presence of a seed polymer prepared by aqueous emulsion polymerization of styrene and a salt of 2-acrylamido-2-methylpropanesulfonic acid.
    Type: Application
    Filed: September 11, 2001
    Publication date: August 1, 2002
    Inventor: Ira John Westerman
  • Patent number: 6407162
    Abstract: Disclosed is an improved method of making polymers. The method utilizes at least one ethylenically unsaturated monomer and at least one polymerizable surface active agent. The polymerizable surface active agent is capable of co-polymerization with traditional monomers and/or polymerization with itself (i.e. homopolymerization) and is preferably substantially completely consumed during the course of the polymerization. Polymers produced by the method of the present invention are well suited for use in coatings, adhesives, sealants, elastomers and the like, as they form stable films, possess excellent adhesion properties and have improved hydrolytic stability characteristics. The present invention also encompasses homopolymeric surface active agents and their use in polymerization reactions.
    Type: Grant
    Filed: March 9, 2000
    Date of Patent: June 18, 2002
    Assignee: Stepan Company
    Inventors: Alfred K. Schultz, Adnan Siddiqui
  • Publication number: 20020049280
    Abstract: A polymeric latex prepared by aqueous emulsion polymerization of a monomeric mixture comprising styrene and butadiene in the presence of a seed polymer prepared by aqueous emulsion polymerization of styrene and a salt of 2-acrylamido-2-methylpropanesulfonic acid.
    Type: Application
    Filed: October 2, 2001
    Publication date: April 25, 2002
    Inventor: Ira John Westerman
  • Patent number: 6297337
    Abstract: Improved crosslinked ionic polymers or salts thereof having a soluble polymer fraction of less than about 15 wt %, and methods for making the same. The polymers are useful as bioadhesives, thickeners, emulsifiers, suspending aids, and pharmaceutical controlled release excipients.
    Type: Grant
    Filed: May 19, 1999
    Date of Patent: October 2, 2001
    Assignee: PMD Holdings Corp.
    Inventors: Nancy S. Marchant, Simon Hsaio-Pao Yu, Zahid Amjad
  • Patent number: 6184287
    Abstract: A polymeric latex prepared by aqueous emulsion polymerization of a monomeric mixture comprising styrene and butadiene in the presence of a seed polymer prepared by aqueous emulsion polymerization of styrene and a salt of 2-acrylamido-2-methylpropanesulfonic acid.
    Type: Grant
    Filed: January 26, 1999
    Date of Patent: February 6, 2001
    Assignee: Omnova Solutions Inc.
    Inventor: Ira John Westerman
  • Patent number: 6153288
    Abstract: Coatable ink-receptive compositions and coated substrates are provided. The compositions contain a pigment dispersed in a binder composed of an ethylene vinyl acetate emulsion polymer and at least one water soluble, cationic polymer, such as polydiallyldimethylammonium chloride and copolymers of a quaternary amino acrylate or methacrylate and a hydroxy-lower alkyl acrylate or methacrylate. Papers, films, labels and similar products, coated with an ink-receptive composition, are also provided.
    Type: Grant
    Filed: July 24, 1997
    Date of Patent: November 28, 2000
    Assignee: Avery Dennison Corporation
    Inventors: Frank Yen-Jer Shih, Kenneth S. C. Lin
  • Patent number: 5997952
    Abstract: A method of preparing a fast-setting coating material on a substrate which comprises contacting a stable aqueous dispersion of a polymer that contains strong cationic groups and weak acid groups onto a substrate that is basic or treated to be basic.
    Type: Grant
    Filed: May 23, 1997
    Date of Patent: December 7, 1999
    Assignee: The Dow Chemical Company
    Inventors: John K. Harris, Donald L. Schmidt, Gene D. Rose
  • Patent number: 5621055
    Abstract: A process for producing polymer particles with an irregular shape by polymerizing a water-soluble polymerizable monomer in a system comprising a hydrophobic organic solvent inert to the polymerization and an aqueous solution of the water-soluble polymerizable monomer, characterized in that the system further contains an anionic surfactant.
    Type: Grant
    Filed: September 19, 1995
    Date of Patent: April 15, 1997
    Assignee: Kao Corporation
    Inventors: Seiichi Miyanaga, Yoshimitsu Ina, Takahide Minami, Takayuki Amiya
  • Patent number: 5401809
    Abstract: Polymer ammonium borates having a molecular weight from about 5000 to about 500,000 and obtained by homopolymerization of monomers, such as, for example, diallyldialkylammonium chloride, and by copolymerization of mixtures of two monomers, such as, for example, diallyldimethylammonium chloride and diallylmethyloctylammonium chloride, having molar monomer ratios of about 0.5:0.5 to about 0.95:0.05 in the copolymer, followed, if desired, by anion exchange, and mixtures of these compounds. Polymer ammonium borates according to the invention are suitable as colorless charge-control agents in toners and developers for electrophotographic recording processes and as charge-improving agents in powders and coatings for surface coating.
    Type: Grant
    Filed: December 3, 1993
    Date of Patent: March 28, 1995
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Jorg Gitzel, Detlef Wehle, Hans-Tobias Macholdt
  • Patent number: 5189111
    Abstract: Water-dilutable side-chain-containing vinylic copolymers comprising groups (.gamma.) of the formula--X--Alk--Y-- (I),whereinAlk signifies alkylene with 2-6 carbon atoms or hydroxysubstituted alkylene with 3-6 carbon atoms or alkylene with 4-6 carbon atoms, interrupted by --O--,X signifies a basic amino group or an ammonium group andY signifies a basic --NH-group or an acid adduct thereof,one of X and Y being further bound to an optionally substituted aliphatic or heteroaromatic hydrocarbon radical and the other to hydrogen or an optionally substituted aliphatic hydrocarbon radical, as a constituent of a least some of the side-chains and at least one mole % of the comonomer units constituting the copolymer bearing such (.gamma.)-containing side-chains - which are obtainable by copolymerization of corresponding comonomers or by amino-alkylation of corresponding starting polymers - are particularly suitable as precipitating and/or flocculating agents, e.g.
    Type: Grant
    Filed: January 4, 1989
    Date of Patent: February 23, 1993
    Assignee: Sandoz Ltd.
    Inventor: Bernard Danner
  • Patent number: 4996274
    Abstract: Polymer and process of polymerizing a monomer charge containing at least 85% of an olefinically unsaturated carboxyl monomer of 3 to 5 carbon atoms at up to 15% of a copolymerizable comonomer, in the presence of a mixed reaction medium containing an organic solvent and a hydrocarbon solvent in respective weight ratio of 95/5 to 1/99, said organic solvent is selected from ketones, esters, ethers, and alcohols having solubility parameter in the range of 8 to 15 and said hydrocarbon solvent is selected from aliphatic and cyclic aliphatic alkanes containing 4 to 12 carbon atoms and non-benzene aromatics of 7 to 9 carbon atoms. Said organic solvent and said hydrocarbon solvent are preferably liquid at room temperature. Viscosity of the 0.2% by weight polymer is in excess of 15,000 cps, preferably in excess of 20,000 cps, and its clarity is at least 80%, preferably 85% transmittance. Viscosity of 1% mucilages containing 1% sodium chloride salt is greater than 5,000 cps, preferably greater than 8,000 cps.
    Type: Grant
    Filed: February 19, 1988
    Date of Patent: February 26, 1991
    Assignee: The B. F. Goodrich Company
    Inventor: Chin C. Hsu
  • Patent number: 4707297
    Abstract: An aqueous guidepath coating composition includes a fluorescent dye, and an acrylic ionomer, and is particularly useful in positional control of and positional detection by stimulated emission-guided Automated Guidance Vehicles (AGV). This coating, used to mark the actual position of the guidance track to be followed by the AGV, affords unexpected improvements over previous guidepath compositions in removal and reapplication characteristics, in post-application durability and in substrate aesthetics.
    Type: Grant
    Filed: April 29, 1986
    Date of Patent: November 17, 1987
    Assignee: Bell & Howell Company
    Inventors: Richard Paske, Jr., Michael Pallmer, William L. King, Jr.
  • Patent number: 4696981
    Abstract: Homopolyamino acids and copolyamino acids are prepared by polycondensation of one kind or a mixture of two or more kinds of monoammonium, diammonium, monoamide, diamide or monoamideammonium salts of malic acid and/or maleic acid and/or fumaric acid, one kind or two or more kinds of amino acid being added to said raw materials, respectively, with application of microwaves, the resulting polyamino acids (imide type) being converted to peptide type, homopolyamino acids and copolyamino acids, respectively upon partial hydrolysis. The operation involved in the reaction is simple and the method permits the use of low cost reaction materials. As a result, imide type and also peptide type, homopolyamino and copolyamino acids are produced with uniform quality at a high rate of yield within an extremely short period of time. Accordingly, the method is incomparably superior to those which have been announced in the past.
    Type: Grant
    Filed: March 13, 1986
    Date of Patent: September 29, 1987
    Assignee: Diamond Shamrock Chemicals Company
    Inventors: Kaoru Harada, Akira Shimoyama, Hiroji Mizumoto
  • Patent number: 4438245
    Abstract: A composition for use in light-sensitive elements which comprises a functional group containing polymer having aromatic sulfonic acid ester or amido groups and sensitizer and a process for preparing the functional polymer and light-sensitive element employing the functional polymer.
    Type: Grant
    Filed: October 16, 1973
    Date of Patent: March 20, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Masato Satomura
  • Patent number: 4415717
    Abstract: A new composition of matter is revealed which comprises a copolymer of a surface active quaternary ammonium monomer salt and from 50 wt % to 97 wt % of acrylamide. The new copolymers can have molecular weights substantially greater than 10,000 and still remain water soluble and surface active.
    Type: Grant
    Filed: November 4, 1982
    Date of Patent: November 15, 1983
    Assignee: Texaco Inc.
    Inventor: Edward C. Y. Nieh
  • Patent number: 4396752
    Abstract: Strong cationic polyelectrolytes in powder form based on acrylamide and quaternized or salified dimethylaminoethyl acrylate; and the use thereof for flocculation of solid material suspensions and coalescence of emulsions.Such polyelectrolytes contain in molar proportions more than 50% of cationic units uniformly distributed along the copolymer chains. They are used for flocculating colloidal suspensions and/or coalescing emulsions, especially, in sewage water purification installations.
    Type: Grant
    Filed: December 5, 1980
    Date of Patent: August 2, 1983
    Assignee: Societe Francaise Hoechst
    Inventors: Jean Cabestany, Claude Trouve, Dominique Depernet
  • Patent number: 4343730
    Abstract: Water-in-oil emulsions of homopolymers and copolymers of acrylamido alkylene quaternary ammonium salts and their use as sewage treatment acids, demulsifying agents, water clarification aids, etc.
    Type: Grant
    Filed: March 9, 1981
    Date of Patent: August 10, 1982
    Assignee: Petrolite Corporation
    Inventors: Harold L. Becker, Rudolf S. Buriks
  • Patent number: 4319013
    Abstract: Cationic polyelectrolytes in water-soluble powder form, applicable to the flocculation of municipal sludge comprise copolymers of acrylamide and of quaternized or salified dimethylamino-ethyl acrylate, containing in molar proportions 10 to 50% of cationic units distributed regularly along the copolymer chains. They have an intrinsic viscosity higher than 6 and a measured cationicity higher than 90% of the theoretical cationicity.
    Type: Grant
    Filed: May 12, 1978
    Date of Patent: March 9, 1982
    Assignee: Societe Francaise Hoechst
    Inventors: Jean Cabestany, Claude Trouve, Dominique Depernet
  • Patent number: 4267103
    Abstract: Carboxyl or carboxyl salt containing polymers are prepared by polymerizing carboxyl containing monomers wherein greater than one percent of the carboxyl groups are neutralized with an alkali, ammonia or an amine, optionally copolymerized with other vinylidene monomers containing at least one terminal CH.sub.2 .dbd.CH< group dissolved in a solvent for the monomers which is a non-solvent for the polymer with a free radical catalyst, so that the resulting polymer is obtained suspended as a fine, readily recoverable substantially non-swollen fine powder. The solvents used are moderately to strongly hydrogen bonded and have solubility parameters of from about 8 to 15.
    Type: Grant
    Filed: December 7, 1978
    Date of Patent: May 12, 1981
    Assignee: The B. F. Goodrich Company
    Inventor: Louis Cohen
  • Patent number: 4266044
    Abstract: Mordanting agents for anionic organic compounds are described which comprise recurring units of the formula: ##STR1## wherein R.sub.1 is hydrogen or methyl; A is methylene or methylene substituted by C.sub.1 -C.sub.5 alkyl;n is 0 or 1;R.sub.2 is alkyl, andX is an acid radical.They are particularly suitable for hindering diffusion of dyes in hydrophilic colloid media e.g. hydrophilic colloid layers of a photographic silver halide element, for hindering diffusion of color couplers in such layers e.g. layers of a radiographic silver halide color element and for the formation of color images by the relief imbibition process.
    Type: Grant
    Filed: December 11, 1978
    Date of Patent: May 5, 1981
    Assignee: AGFA-GEVAERT N.V.
    Inventors: Daniel M. Timmerman, Walter F. De Winter, Albert E. Van Hoof
  • Patent number: 4237253
    Abstract: Copolymers having the formula ##STR1## where B represents Na, K, NH.sub.4, ##STR2## or 2-amino-2-methylpropanol-1, R.sub.1 and R.sub.2 represent hydrogen or -(X) OH; X represents an alkylene having 1-3 carbon atoms or alkylene substituted by at least one hydroxy methyl, M represents at least one unsaturated monomer selected from acrylamides or methacrylamides substituted on the nitrogen by alkyl, the acrylates or methacrylates of monoalkyl ether of ethylene glycol or of polyethylene glycol, and N-vinylpyrrolidone, x is 22-64 mole percent, y is 13-71 mole percent, z is 6-23 mole percent, v is 0-22 mole percent and x+y+z+v is equal to 100 mole percent, can be produced by copolymerizing N,N-dimethylamino-2 ethyl methacrylate, methyl methacrylate, methacrylic acid and optionally at least one other monomer corresponding to M.
    Type: Grant
    Filed: April 18, 1978
    Date of Patent: December 2, 1980
    Assignee: L'Oreal
    Inventors: Bernard Jacquet, Claude Mahieu, Christos Papantoniou
  • Patent number: 4230839
    Abstract: This invention relates to adducts of salts of polymerizable tertiary amines with acrylic compounds illustrated by acrylamide and acrylonitrile; to polymers and copolymers containing said adducts and to processes for preparing them. This invention also relates to the use of said polymers and copolymers, particularly in the clarification of turbid waters by flocculation or flotation of oil and/or suspended solids. In the preferred embodiment, the quaternary adduct monomer is: ##STR1## where X is an anion, preferably halide such as chloride or carboxylate such as acetate; and polymers and copolymers containing units thereof.
    Type: Grant
    Filed: October 27, 1978
    Date of Patent: October 28, 1980
    Assignee: Petrolite Corporation
    Inventors: Rudolf S. Buriks, Allen R. Fauke, David W. Griffiths
  • Patent number: 4230810
    Abstract: A method of preparing a resin by free radical emulsion polymerizing a monomer mixture comprised of (A) a water soluble bifunctional monomer, (B) a hard segment hydrophobic enhancing monomer, (C) optionally, a soft segment hydrophobic enhancing monomer, and (D) a hydrophilic enhancing organic acid. The particular advantage in the invention is the utilization of the water soluble bifunctional monomer which has the purpose of essentially eliminating the necessity of additional emulsifying agents. The resin prepared thereby is designed to be suitable for a water reducible composition.
    Type: Grant
    Filed: May 7, 1979
    Date of Patent: October 28, 1980
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Richard R. Lattime
  • Patent number: 4225689
    Abstract: Disclosed herein are monomeric compounds having the formula (I): ##STR1## wherein: R, R.sup.1, R.sup.2 and R.sup.3 are independently hydrogen or alkyl having from 1 to 4 carbon atoms;R.sup.4 is arylene having 6 to 18 carbon atoms;m is an integer from 1 to 4; andn is an integer from 0 to 4.These monomers can be homopolymerized or copolymerized with one or more other polymerizable monomers, and can particularly be copolymerized with those monomers having substituents which are susceptible to attack or degradation by a base. The resulting crosslinkable polymers are useful in relief image materials, such as photoresists and lithographic plates.
    Type: Grant
    Filed: July 26, 1978
    Date of Patent: September 30, 1980
    Assignee: Eastman Kodak Company
    Inventor: John C. Wilson
  • Patent number: 4224150
    Abstract: This invention relates to adducts of salts of polymerizable tertiary amines with acrylic compounds illustrated by acrylamide and acrylonitrile; to polymers and copolymers containing said adducts and to processes for preparing them. This invention also relates to the use of said polymers and copolymers, particularly in the clarification of turbid waters by flocculation or flotation of oil and/or suspended solids. In the preferred embodiment, the quaternary adduct monomer is: ##STR1## where X is an anion, preferably halide such as chloride or carboxylate such as acetate; and polymers and copolymers containing units thereof.
    Type: Grant
    Filed: October 27, 1978
    Date of Patent: September 23, 1980
    Assignee: Petrolite Corporation
    Inventors: Rudolf S. Buriks, Allen R. Fauke, David W. Griffiths
  • Patent number: 4218554
    Abstract: A novel hydrogel soft contact lens and a process for preparation thereof is disclosed which employs quaternary ammonium salts as a co-monomer which provide control over the percent of hydration with as high as 85% hydration obtainable in the resulting lens.
    Type: Grant
    Filed: October 11, 1978
    Date of Patent: August 19, 1980
    Inventor: William M. Foley, Jr.
  • Patent number: 4212782
    Abstract: Disclosed are solid, readily water-soluble addition polymers of acid addition salts of methacrylic acid and a 2-mono(lower)alkylaminoethyl methacrylate, whose lower alkyl group has up to 6 carbons and is straight or branched chain or cyclic. These polymers are insoluble in pentane, hexane and butane below their boiling points, and their aqueous solutions show amphoteric activity. These polymers result from polymerizing the starting monomeric acid addition salt of methacrylic acid and a 2-mono(lower)alkylaminoethyl methacrylate in the ratio of from about one mol to about 1.5 mols of one of them per mol of the other. Also disclosed is the method of producing these addition polymers by heating the starting acid addition salt under pressure in a low boiling aliphatic solvent at a temperature above its boiling point, from which after lowering the temperature the resulting addition polymer readily is separated as a light weight finely divided product.
    Type: Grant
    Filed: May 8, 1978
    Date of Patent: July 15, 1980
    Assignee: Normac, Inc.
    Inventor: Max Klein
  • Patent number: 4206051
    Abstract: A process for demineralizing an aqueous saline solution containing a deoxygenating agent by treating it with a thermally regenerable ion-exchange resin comprising a resinous material derived from a substituted diallylamine.
    Type: Grant
    Filed: December 18, 1978
    Date of Patent: June 3, 1980
    Assignees: ICI Australia Limited, Commonwealth Scientific and Industrial Research Organization
    Inventors: Brian A. Bolto, Kurt H. Eppinger, Mervyn B. Jackson
  • Patent number: 4198497
    Abstract: N-substituted acrylamidines having the general formula: ##STR1## in which R.sub.1 is an isopropyl group, R.sub.2 and R.sub.3 each is hydrogen, ethyl, propyl, butyl, pentyl, octyl, or octadecyl. The acrylamidine is copolymerized with at least one ester of acrylic and/or methacrylic acid esters, and the copolymer has use as an oil additive and for the manufacture of molded articles, paints and adhesives.
    Type: Grant
    Filed: September 9, 1977
    Date of Patent: April 15, 1980
    Assignee: Compagnie Francaise de Raffinage
    Inventors: Yannick Jolivet, Christian Lachevre
  • Patent number: 4179549
    Abstract: This invention relates to adducts of salts of polymerizable tertiary amines with acrylic compounds illustrated by acrylamide and acrylonitrile; to polymers and copolymers containing said adducts and to processes for preparing them. This invention also relates to the use of said polymers and copolymers, particularly in the clarification of turbid waters by flocculation or flotation of oil and/or suspended solids. In the preferred embodiment, the quaternary adduct monomer is: ##STR1## where X is an anion, preferably halide such as chloride or carboxylate such as acetate; and polymers and copolymers containing units thereof.
    Type: Grant
    Filed: November 14, 1974
    Date of Patent: December 18, 1979
    Assignee: Petrolite Corporation
    Inventors: Rudolf S. Buriks, Allen R. Fauke, David W. Griffiths
  • Patent number: 4178221
    Abstract: Water-soluble acrylic polymers are prepared by a sequential photopolymerization process. A monomer solution is deposited on a support which is subsequently irradiated to effect polymerization. Photopolymerization promoters are incorporated in the monomer solution to facilitate polymerization.
    Type: Grant
    Filed: April 11, 1977
    Date of Patent: December 11, 1979
    Assignee: Rhone-Poulenc Industries
    Inventors: Jean Boutin, Jean Neel
  • Patent number: 4171418
    Abstract: Novel water-soluble acrylamide copolymers contain 40 to 70 percent by weight acrylamide units, at least 30 percent of hydrophobic vinyl units and at least 10 percent of vinyl units having ionic properties. In aqueous solution these copolymers have the properties of cationic or amphoteric surface active agents.
    Type: Grant
    Filed: November 22, 1977
    Date of Patent: October 16, 1979
    Assignee: American Cyanamid Company
    Inventors: Girish C. Barua, Daniel E. Nagy
  • Patent number: 4170672
    Abstract: A process is disclosed for coating paper with a novel water-soluble thermosetting resin, which has the property of providing paper with a nearly constant wet and dry strength over a wide pH range; the resin can be mixed, if desired, with other water-soluble polymers such as starch, its derivatives, cellulose derivatives, polyvinylalcohol and polyacrylamide, and various pigments such as clay, calcium carbonate and titanium dioxide.
    Type: Grant
    Filed: August 9, 1978
    Date of Patent: October 9, 1979
    Assignee: The Japan Carlit Co., Ltd.
    Inventors: Koichi Moriya, Iwao Honda
  • Patent number: 4167464
    Abstract: Highly water absorbent films and fibers are prepared by photopolymerizing an alkaline metal salt of acrylic acid, at least one alkyl acrylate or methacrylate wherein the alkyl group contains 10 to 30 carbon atoms, at least one alkyl acrylate or methacrylate wherein the alkyl group contains 1 to 4 carbon atoms and a photoinitiator. The resulting interpolymers are particularly useful in the preparation of highly absorbent personal hygiene and care products.
    Type: Grant
    Filed: October 16, 1978
    Date of Patent: September 11, 1979
    Assignee: The B. F. Goodrich Company
    Inventor: Paul J. George
  • Patent number: RE30259
    Abstract: Disclosed is a novel water-soluble thermosetting resin which has the property of providing paper with a nearly constant wet and dry strength over a wide pH range according to methods of wet-end additions or surface applications.
    Type: Grant
    Filed: February 23, 1979
    Date of Patent: April 22, 1980
    Assignee: The Japan Carlit Co., Ltd.
    Inventors: Koichi Moriya, Iwao Honda
  • Patent number: RE43168
    Abstract: A polymeric latex prepared by aqueous emulsion polymerization of a monomeric mixture comprising styrene and butadiene in the presence of a seed polymer prepared by aqueous emulsion polymerization of styrene and a salt of 2-acrylamido-2-methylpropanesulfonic acid.
    Type: Grant
    Filed: December 13, 2004
    Date of Patent: February 7, 2012
    Assignee: OMNOVA Solutions Inc.
    Inventor: Ira John Westerman