Optical Clarity Patents (Class 526/937)
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Patent number: 8927650Abstract: There are provided a radical polymerizable composition having a low viscosity suitable for coating and a cured product and a plastic lens each obtained by curing the composition, the cured product having a high refractive index, good adhesiveness to a plastic film substrate, and good adhesiveness kept even under high-temperature and high-humidity conditions. The radical polymerizable composition includes phenylbenzyl (meth)acrylate (A), an epoxy (meth)acrylate (X) having an aromatic ring in its molecular structure, and a radical polymerization initiator (Y) as essential components.Type: GrantFiled: December 30, 2013Date of Patent: January 6, 2015Assignee: DIC CorporationInventors: Nobuo Kobayashi, Akihiro Kondo, Atsuhisa Miyawaki, Naoya Ikushima, Kazuaki Hatsusaka
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Patent number: 8344083Abstract: The present invention relates to a transparent resin composition which comprises (a) a (meth)acrylate based unit comprising one or more (meth)acrylate based derivatives; (b) an aromatic based unit having a chain having the hydroxy group containing portion and an aromatic moiety and (c) a styrene-based unit comprising one or more styrene-based derivatives, and an optical film that is formed by using the same.Type: GrantFiled: May 4, 2009Date of Patent: January 1, 2013Assignee: LG Chem, Ltd.Inventors: Jun-Geun Um, Min-Hee Lee, Nam-Jeong Lee, Jong-Hun Lee, Dong-Ryul Kim, Sae-Han Cho
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Patent number: 7985356Abstract: A non-linear optical device comprising a polymer configured to be photorefractive upon irradiation by a green laser. The polymer comprises a repeating unit including a moiety selected from the group consisting of the structures (M-1), (M-2) and (M-3), as defined herein.Type: GrantFiled: July 23, 2007Date of Patent: July 26, 2011Assignee: Nitto Denko CorporationInventors: Michiharu Yamamoto, Peng Wang
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Patent number: 7842740Abstract: Provided are an optical resin and an optical member using the same, both orientation birefringence and photoelasticity birefringence of the optical material being deadened and generally eliminated. The optical material consists of a composite constituent system of three or more constituents including a copolymerization system of monomer-element number not smaller than two, combination and constituent ratio of the composite constituent system being set so that both orientation birefringence and photoelasticity birefringence of the optical material are deadened at the same time and 5.0×10?5 or less is given under a condition that principal chains of the copolymerization system have degree of orientation equal to 0.03, and further a photoelasticity constant not greater than 1.0×10?12 (Pa?1) is obtained. The composite constituent system may contain an additive containing a low molecular weight compound which has an anisotropic polarizability and can be orientated in a polymer.Type: GrantFiled: April 18, 2006Date of Patent: November 30, 2010Inventor: Yasuhiro Koike
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Patent number: 7736548Abstract: A non-linear optical device comprising a polymer configured to provide a grating holding ratio of 20% or higher after about four minutes, wherein the polymer comprises a first repeating unit comprising a first moiety having formula (M-1) and a second repeating unit comprising a second moiety having formula (M-2), as defined herein.Type: GrantFiled: July 23, 2007Date of Patent: June 15, 2010Assignee: Nitto Denko CorporationInventors: Michiharu Yamamoto, Peng Wang
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Patent number: 6914113Abstract: A method of modifying a polyethylene material is accomplished by providing a polyethylene resin. The initial rheological breadth of the polyethylene resin is determined. The resin is then modified to adjust the rheological breadth of the polyethylene from the initial rheological breadth to a different rheological breadth that corresponds to a desired resin property, such as haze. A method for predicting clarity and rheological breadth properties is also provided, which utilizes a template of measured properties for polyethylene resins.Type: GrantFiled: July 25, 2002Date of Patent: July 5, 2005Assignee: Fina Technology, Inc.Inventors: Michael McLeod, Gerhard Guenther, Nguong van Nguyen
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Patent number: 6794474Abstract: The invention is a composition comprising: 40 to 95 parts by weight of one or several monomers (I) of formula (a) wherein: R1 and R2 represent H or CH; A represents a divalent radical of formula (b) or (c) wherein m1 and m2 represent each an integer ranging between 2 and 6; and 5 to 50 parts by weight of a monomer (II) comprising at least a urethane unit and at least two (meth)acrylate functions. The invention is useful for making optical and ophthalmic articles.Type: GrantFiled: December 8, 2003Date of Patent: September 21, 2004Assignee: Essilor International Compagnie Generale d'OptiqueInventors: Gilles Richard, Odile Primel, Leanirith Yean
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Patent number: 6355307Abstract: Clear lacquer coating media suitable for multi-layer coatings, containing self-crosslinking or externally crosslinkable binder vehicles, organic solvents, and in the case of externally-crosslinkable binder vehicles containing one or more crosslinking agents which are different from aldehyde condensation resins, and optionally also containing one or more reactive thinners and customary additives for clear lacquers, with an additional content of A) 0.1 to 3% by weight one or more urea compounds, and B) 0.05 to 10% by weight one or more substances which supply formaldehyde, with respect in each case to the resin solids content which is formed by the binder vehicles, reactive thinners and crosslinking agents.Type: GrantFiled: March 16, 2000Date of Patent: March 12, 2002Assignee: Dupont Performance Coatings GmbH & Co.Inventors: Stephan Brenke, Karl-Friedrich Dössel, Friedrich Herrmann, Heinz-Walter Reifferscheidt
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Patent number: 5326843Abstract: An emulsion polymerization process for making a low molecular weight alkali-soluble copolymer of a water insoluble monoethylenically unsaturated aromatic monomer and methacrylic acid, includes heating an aqueous reaction mixture, said reaction mixture having a pH of less than or equal to about 4.5 and including from about 25 parts by weight to about 75 parts by weight of the water insoluble monoethylenically unsaturated aromatic monomer; from about 25 parts by weight to about 75 parts by weight methacrylic acid; a polymerization initiator; a reducing agent; a catalyst effective for promoting decomposition of the polymerization initiator in the presence of the reducing agent; and an amount of a chain transfer agent effective to limit copolymer weight average molecular weight to a range of about 2,000 to about 40,000; to a temperature greater than or equal to about 75.degree. C.; and maintaining the reaction mixture at a temperature greater than or equal to about 75.degree. C.Type: GrantFiled: October 4, 1993Date of Patent: July 5, 1994Assignee: Rohm and Haas CompanyInventors: Dennis P. Lorah, Thomas G. Madle
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Patent number: 5198305Abstract: A novel optical element substrate which comprises a random copolymer comprising, in specific weight proportions, a methyl methacrylate unit, an aromatic vinyl compound unit, an unsaturated aliphatic acid unit and a hexagonal acid anhydride unit of the formula ##STR1## The substrate has excellent heat resistance, thermal stability, transparency, resistance to scratching and metal layer corrosion preventive properties and exhibits advantageously low double refraction and warpage. The novel substrate can be advantageously employed as a substrate for an optical element such as an optical disc, e.g. a digital audio disc, a video disc and a disc capable of being directly read after recording, a mirror, a lens and the like.Type: GrantFiled: December 23, 1991Date of Patent: March 30, 1993Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Akihiro Wada, Rin-ichi Kakuta
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Patent number: 5081315Abstract: Compounds of the formula ##STR1## in which A represents the radicals ##STR2## in which R.sup.1 and R.sup.2 are different from one another and denote hydrogen, --NO.sub.2 or --NH.sub.2, R.sup.3 is hydrogen or halogen, X represents --NO.sub.2 or --NH.sub.2, with the proviso that R.sup.1 is hydrogen, if R.sup.2 is --NO.sub.2 or --NH.sub.2 and R.sup.2 is hydrogen, if R.sup.1 is --NO.sub.2 or --NH.sub.2.The compounds are prepared from 4,4'-bis[2-(4-hydroxyphenyl)hexafluoroisopropyl]diphenyl ether by nitration or reaction with nitrobenzenes followed by reduction of the nitro groups. They are used for the preparation of high-temperature-resistant polycondensates.Type: GrantFiled: August 20, 1990Date of Patent: January 14, 1992Assignee: Hoechst AktiengesellschaftInventors: Jurgen Lau, Gunter Siegemund
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Patent number: 5026805Abstract: Optical materials having well balanced properties such as high heat resistance, low hygroscopicity and low double refractivity. The optical materials are derived from a low hygroscopic, random copolymer comprising units of methacrylic acid and ester derivatives, and units of a six-membered ring acid anhydride.Type: GrantFiled: December 1, 1989Date of Patent: June 25, 1991Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Kazuhiro Hosoya, Ikuji Ohtani, Kimio Imaizumi
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Patent number: 4978790Abstract: Compounds of the formula ##STR1## in which A represents the radicals ##STR2## in which R.sup.1 and R.sup.2 are different from one another and denote hydrogen, --NO.sub.2 or --NH.sub.2, R.sup.3 is hydrogen or halogen, X represents --NO.sub.2 or --NH.sub.2, with the proviso that R.sup.1 is hydrogen, if R.sup.2 is --NO.sub.2 or --NH.sub.2 and R.sup.2 is hydrogen, if R.sup.1 is --NO.sub.2 or --NH.sub.2.The compounds are prepared from 4,4'-bis[2-(4-hydroxyphenyl)hexafluoroisopropyl]diphenyl ether by nitration or reaction with nitrobenzenes followed by reduction of the nitro groups. They are used for the preparation of high-temperature-resistant polycondensates.Type: GrantFiled: November 23, 1988Date of Patent: December 18, 1990Assignee: Hoechst AktiengesellschaftInventors: Jurgen Lau, Gunter Siegemund
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Patent number: 4939190Abstract: An aqueous emulsion-type pressure sensitive adhesive characterized in that the aqueous emulsion is prepared by(i) a first step of emulsion polymerizing an ethylenically unsaturated monomer composed essentially of at least one type of styrene, alpha-methylstyrene, acrylonitrile, methyl methacrylate and vinyltoluene in the presence of an emulsion composed of at least one tackifier resin selected from a rosin ester, a petroleum resin and a terpene resin to form an aqueous emulsion containing particles of a two-layered structure having a core layer of the tackifier resin and a layer of a polymer (polymer A.sub.Type: GrantFiled: May 24, 1988Date of Patent: July 3, 1990Assignee: Dainippon Ink And Chemicals, Inc.Inventors: Reizaburo Tomioka, Yasuhiro Shigematsu
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Patent number: 4725397Abstract: This invention provides novel thermosetting preform having superior transparency which is composed of the resin produced by partially polymerizing the mixture of (A) 4 to 30 wt % of at least one vinyl monomer containing carboxyl group, (B) 4 to 96 wt % of at least one vinyl monomer containing glycidyl group, and (C) up to 92 wt % of at least one copolymerizable monomer, said preform being characterized in that the amount of unreacted monomer remaining therein is less than 20 wt % and the glass transition temperature range is 120.degree. C. or lower. This invention also provides a method of production of a highly transparent molded article with high productivity which is superior in heat resistance and in chemical resistance by heating and molding said preform.Type: GrantFiled: November 25, 1985Date of Patent: February 16, 1988Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Jun Nakauchi, Shunsuke Minami
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Patent number: 4628071Abstract: An emulsion polymer of a water insoluble vinylic monomer and an acrylic monomer is formed by precharging a portion of the acrylic monomer and thereafter adding a comonomer charge corresponding to the final desired composition of the vinylic monomer and acrylic monomer at an addition rate generally corresponding to the steady state monomers concentration. A high non-volatiles content is maintained to inhibit the acrylic monomer from partitioning into the aqueous phase.Type: GrantFiled: August 16, 1985Date of Patent: December 9, 1986Assignee: S. C. Johnson & Son, Inc.Inventor: Lee W. Morgan