With Ethylenically Unsaturated Reactant Patents (Class 527/603)
  • Patent number: 11591488
    Abstract: A rosin-modified phenol resin (A) is a reaction product of a rosin (b), a phenol (c), a formaldehyde (d) and a polyol (e), wherein the rosin (b) contains 0.1 to 3.5% by mass of a monoterpene (a1) and a sesquiterpene (a2) relative to the total weight of the rosin, and Mw/Mn which is the ratio of the weight average molecular weight (Mw) and the number average molecular weight (Mn) is 10 to 60.
    Type: Grant
    Filed: May 18, 2021
    Date of Patent: February 28, 2023
    Assignees: TOYO INK SC HOLDINGS CO., LTD., TOYO INK CO., LTD.
    Inventor: Kazuya Okamoto
  • Patent number: 7910635
    Abstract: The specification describes a process for making gelled ink resins which exhibit improved properties such as lower viscosity under low shear and less viscosity decrease with increasing shear. In a preferred embodiment, a rosin-based or hydrocarbon-based resin is mixed with an organic solvent and reacted with a polyamine reactant, such as melamine-formaldehyde resin or hexamethylene diamine, under conditions sufficient to produce a substantially covalently cross-link gelled resin. The resulting gelled resin resists viscosity breakdown under high shear conditions and may be used directly for making ink compositions, obviating the need for further gelation and avoiding the use of conventional organo-metallic gelling agents.
    Type: Grant
    Filed: October 14, 2006
    Date of Patent: March 22, 2011
    Assignee: Lubrizol Advanced Materials, Inc.
    Inventors: John H. Larsen, Joshua M. Rosenheck, Robert E. Quinn
  • Patent number: 7910680
    Abstract: The present invention relates to new (meth)acrylate compositions, their preparation and their use in ultraviolet light curable applications such as coatings, inks and adhesives.
    Type: Grant
    Filed: April 25, 2007
    Date of Patent: March 22, 2011
    Assignee: Dow Global Technologies LLC
    Inventors: Jerry E. White, Jim D. Earls, Peter S. Martin, Mike B. McIntosh, Richard M. Wehmeyer
  • Patent number: 6593460
    Abstract: The invention relates to biologically degradable lignin graft polymers comprised of lignin and ethylenically unsaturated monomers which are formed by an enzymatically catalyzed polymerization method in the presence of organic peroxides. The polymerizates are suited, for example, for utilization as absorbers for water and aqueous liquids, as coagulants and thickeners, as water softeners and as dispersing agents.
    Type: Grant
    Filed: October 12, 2000
    Date of Patent: July 15, 2003
    Assignee: Stockhausen GmbH & Co KG
    Inventors: Aloys Hüttermann, Carsten Mai
  • Patent number: 6153693
    Abstract: This invention relates to novel rosin-based resins and the process for preparing them. In particular, the invention relates to elastomeric-modified pigment binder compositions which exhibit properties that make them useful in formulating vehicles for lithographic printing inks and other coating applications.
    Type: Grant
    Filed: February 11, 1999
    Date of Patent: November 28, 2000
    Assignee: Westvaco Corporation
    Inventors: Michael D. Matzinger, G. Frederick Hutter
  • Patent number: 5100989
    Abstract: The invention relates to surface-active compounds of the general formula (I) ##STR1## in which Ar is an aromatic system which is optionally substituted by C.sub.1 -C.sub.18 -alkyl, C.sub.1 -C.sub.18 -alkoxy, C.sub.2 -C.sub.5 -alkanoyl, C.sub.6 -C.sub.10 -aryl, (C.sub.6 -C.sub.10 -aryl)-C.sub.1 -C.sub.4 -alkyl, A has the formula --(X--O).sub.n --Y, wherein n denotes 1 to 50, X denotes ethylene or methylethylene and all or some of Y denote an acyl radical of a non-modified or modified natural resin acid and the other radicals Y denote radicals from the group comprising hydrogen, acyl radicals of saturated C.sub.1-24 -carboxylic acids, unsaturated C.sub.3-24 -carboxylic acids, C.sub.2-24 -hydroxy-fatty acids or C.sub.8-18 -alkyl-, -alkenyl- and -alkylidene-succinic acids, maleic acid, fumaric acid, sulfosuccinic acid, sulfuric acid, benzodicarboxylic acids and C.sub.1-16 -n-alkanedicarboxylic acids, W is a group --CHR-- or --CHR--N(R*)--T--N(R*)--CHR--, wherein R*is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.2 -C.
    Type: Grant
    Filed: September 1, 1988
    Date of Patent: March 31, 1992
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Heinz Uhrig, Erich Ackermann, Reinhold Deubel
  • Patent number: 5021538
    Abstract: Improved polyol esters of phenol-rosin condensates and polyimide/polyamide derivatives thereof and their method of manufacture are disclosed as well as their applications as varnishes for lithographic inks and in pigment dispersion (flushing). Advantages of ink varnishes comprising these derivatives include higher water yields, increased gloss, transparency, and color strength, as well as reduced bronzing in both pigment concentrates and finished lithographic inks.
    Type: Grant
    Filed: December 1, 1989
    Date of Patent: June 4, 1991
    Assignee: Westvaco Corporation
    Inventor: Everett Crews
  • Patent number: 4985474
    Abstract: A resin composition hardenable by irradiation of a high energy ray is disclosed, which includes:(a) a resin selected from the group consisting of rosins and modified rosins and having an acid value of at least 150 and a Gardner color scale of not greater than 15;(b) a compound of the general formula (I):Y--CO--O--A--O).sub. m CO--CR.dbd.CH.sub.2 (I)wherein Y represents ##STR1## A represents an alkylene having 1-4 carbon atoms, R represents hydrogen or methyl and m is an integer of 1-4;(c) a hydroxyl group-containing compound having only one acrylic or methacrylic group and at least one hydroxyl group; and(d) a polyol compound having at least two hydroxyl groups. The resin composition is useful for plugging through-holes of a metal plated board in manufacturing printed wiring boards.
    Type: Grant
    Filed: November 13, 1989
    Date of Patent: January 15, 1991
    Assignee: Somar Corporation
    Inventors: Osamu Ogitani, Ryuichi Fujii
  • Patent number: 4971881
    Abstract: A toner composition for use in electrophotography comprises a rosin modified styrene-acrylic binder resin which has been prepared by steam stripping a mixture solution polymerized styrene acrylic copolymer resin, rosin and a suitable solvent such a toluene or xylene followed by cooling and grinding to form styrene acrylic/rosin binder resin. This binder resin is then formulated with conventional coloring pigments, charge controlling dyes and carriers such as iron powder or glass beads to provide dry toner compositions of high positive charge. An important feature of the present invention is that the styrene acrylic/rosin binder resin will have an inherent positive charge of at least 2.0. This inherent positive charge is in contrast to typical prior art toner binders which are inherently negatively charged.
    Type: Grant
    Filed: January 5, 1989
    Date of Patent: November 20, 1990
    Assignee: Monsanto Company
    Inventors: Gary Deets, Richard M. Zielinski
  • Patent number: 4880906
    Abstract: A finishing agent for finishing fibers or fiber products is disclosed. The agent is a mixture of the following components:(a) 34 to 99% by weight of a polymer of the general formula ##STR1## in which R.sup.1 is a z-hybric aliphatic alcohol, z=2 to 9, m=20 to 75, n=0 to 10, p=0 to 3,(b) 0 to 55% by weight of a copolymer, obtained by copolymerization of(b.sub.1) one mole of a macromonomer of the general formula ##STR2## in which q=5 to 75, r=0 to 10, s=0 to 3, with (b.sub.2) 2 to 12 moles of a vinyl ester of the general formula CH.sub.2 .dbd.CHOCOR.sup.2, in which R.sup.2 is an alkyl group with 1 to 4 carbon atoms,(b.sub.3) 1 to 6 moles of N-vinylpyrrolidone,(b.sub.4) 0 to 6 moles of an acrylate or methacrylate ester of the general formula CH.sub.3 .dbd.CR.sup.3 --COOR.sup.4, in which R.sup.3 .dbd.H or CH.sub.3, R.sup.4 is an alkyl group with 1 to 4 carbon atoms, the quotient of the average molecular weight of the monomer (b.sub.1) and the number of moles of the monomers (b.sub.2), (b.sub.3) and (b.sub.
    Type: Grant
    Filed: July 15, 1988
    Date of Patent: November 14, 1989
    Assignee: Th. Goldschmidt AG
    Inventors: Eberhard Esselborn, Jurgen Fock
  • Patent number: 4391640
    Abstract: A process for producing an animal or vegetable oil-modified and rosin-modified phenolic resin for printing inks, which comprises:[I] reacting (a) a resol-type phenol/formaldehyde initial condensation product, (b) an animal or vegetable oil having an iodine value of 100 to 210 or containing a hydroxyl group, (c) a rosin and (d) an alchohol, and if required, (e) an acid or (f) a hydrocarbon resin; or[II] reacting the condensation product (a) and the animal or vegetable oil (b) with a rosin ester obtained by the reaction of the rosin (c) and the alcohol (d) and if required, the acid (e) or the hydrocarbon resin (f) in advance.
    Type: Grant
    Filed: June 3, 1981
    Date of Patent: July 5, 1983
    Assignee: Dainippon Ink & Chemicals, Inc.
    Inventors: Noboru Okoshi, Kin-ichi Kudo, Shoichi Shimoyama
  • Patent number: 4359552
    Abstract: Hot melt adhesive compositions are provided which contain (a) about 10-30 weight % of an alkenyl succinic anhydride, (b) about 20-60 weight % of an ethylene copolymer, and (c) about 10-40 weight % of a tackifying resin which is an aliphatic hydrocarbon resin.
    Type: Grant
    Filed: August 10, 1981
    Date of Patent: November 16, 1982
    Assignee: Gulf Oil Corporation
    Inventors: Vikramkumar Acharya, Pallavoor R. Lakshmanan