Abstract: A compound having the formula ##STR1## This compound is useful in enhancing the flame retardancy of polyesters.

Abstract: Aralkylene phenol resins, curable to thermoset polymers are made by reacting an aralkylene ester of formula R'(CH.sub.2 OYR,).sub.a, where R' is aromatic, Y is carbonyl or sulphonyl and R' is alkyl or aryl, a is 2 or 3 with a molar excess of a phenol or mixture thereof with a non-phenolic aromatic compound.

Abstract: A flame-retardant phenolic resin which comprises the product obtained on(a) reacting at least one halogenated compound represented by the general formula (I) ##STR1## wherein A is --CH.dbd.CH.sub.2 or --O--CH.sub.2 --CH.dbd.CH.sub.2, X is a chlorine atom or a bromine atom, and n is an integer of 1, 2 or 3, with at least one phenol in the presence of an acidic catalyst; and(b) reacting the resulting reaction product with at least one phosphoric acid ester compound containing a phenolic OH group represented by the general formula (II), (III) or (IV). ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents an unsubstituted or substituted hydrocarbyl group, where R.sub.1 and R.sub.2 may be the same or different, and n is 1, 2 or 3, and at least one aldehyde or a precursor thereof in the presence of an acidic or alkali catalyst; and a process for producing the flame-retardant phenolic resin.

Abstract: The present invention relates to a flame retardant polyester having a phosphorus atom content of 500-50,000 ppm, which polyester contains a flame-retarding amount of a phosphorus containing compound represented by the following general formula: ##STR1## wherein each of R.sup.1 is a hydrogen atom or hydrocarbon group having 1-10 carbon atoms which may contain a hydroxyl group, and both R.sup.1 's may together form a dehydrated ring when both of R.sup.1 's represent hydrogen atoms, each of R.sup.2 and R.sup.3 is a member selected from the group consisting of halogen atoms and hydrocarbon groups having 1-10 carbon atoms, and each of n2 and n3 is an integer of 0-4. Polyesters containing the claimed phosphorus containing compounds are characterized by exhibiting excellent flame retardancy and at the same time, the physical properties of the polyesters are not impaired by incorporation of the phosphorus compound therein.

Abstract: Phosphorus- and bromine-containing polymers having the formula ##STR1## WHEREIN R.sub.1 is an alkylene group having 2-3 carbon atoms; ##STR2## WHEREIN M IS AN INTEGER OF 1-4 AND B is an alkylene or alkylidene group having 1-6 carbon atoms or sulfone group; Z is --R.sub.2 or --OR.sub.2, provided that R.sub.2 is an alkyl or aryl group; Y is sulfur or oxygen; l is 0 or 1; p and q are integers of at least 1 and a sum of p and q is an integer of not more than 4; and n is an integer of 3-40 are colorless and have an excellent thermal property. The polymers are excellent as a flame retardant for inflammable organic high polymers, and flame resistant compositions having excellent washing resistance, light resistance and whiteness can be obtained by compounding the phosphorus- and bromine-containing polymer with the inflammable organic high polymer.

Abstract: Phosphorus containing linear, branched and/or crosslinked block polymers of polyphenylene oxides are described which comprise di- and/or tri-functional phosphoryl radicals coupled with mono- and/or polyphenoxy radicals, said polyphenoxy radicals being derived from (a) polyphenylene oxides having an average hydroxyl group per molecule value greater than zero including 1.0 or less, or (b) polyphenylene oxide-quinone coupled polymers having an average hydroxyl group per molecule value greater than zero including 2.0 or less, and mixtures thereof. The resulting polyphenylene oxides can be used to prepare flame-retardant polyphenylene oxide articles of manufacture.

Abstract: A process of forming phosphorus containing linear, branched and/or cross-linked polymers of polyphenylene oxides is described which comprises contacting phosphoryl halides with (a) polyphenylene oxides having an average hydroxyl group per molecule value greter than zero including 1.0 or less, or (b) quinone-coupled polyphenylene oxides having an average hydroxyl group per molecule value greater than zero including 2.0 or less, including mixtures of (a) and (b).

Abstract: The present invention relates to a phosphorus-containing compound of the formula ##STR1## wherein each of R.sup.1 is a hydrogen atom or hydrocarbon group having 1-10 carbon atoms which may contain a hydroxyl group, and both R.sup.1 's may together form a dehydrated ring when both of R.sup.1 's represent hydrogen atoms, each of R.sup.2 and R.sup.3 is a member selected from the group consisting of halogen atoms and hydrocarbon groups having 1-10 carbon atoms, and each of n2 and n3 is an integer of 0-4. These compounds are especially useful for incorporation into polymers, such as polyesters, as flame-retardants. Further, such phosphorus-containing compound imparts excellent flame-retardant properties to such polyesters, while at the same time does not deleteriously affect the physical properties of the polyester.

Abstract: An aromatic copolyester composition comprising (A) an aromatic copolyester derived from terephthalic acid, isophthalic acid and a bisphenol and (B) a phosphorus-containing compound represented by the general formula (II) ##STR1## wherein n is 0 or an integer of 1 to 3, and R is an alkyl group containing 1 to 18 carbon atoms, in which one or more of the hydrogen atoms of the alkyl group may be replaced by a halogen atom or a hydrocarbon group.Molded products obtained from the aromatic copolyester composition have markedly reduced coloration and reduced occurrence of water crazing.

Abstract: This invention relates to polyphosphazenes which have an at least partially regulated structure corresponding to the formula:--N.sub.3 P.sub.3 (Cl).sub.5 (OR.sup.1)--.sub.n (I)where n is greater than 2, and where R.sup.1 is phenyl or substituted phenyl. This invention further relates to copolymers, derived from the above polymers (I), which correspond to the formula:--N.sub.3 P.sub.3 (OR.sup.1)(OR.sup.2).sub.5 --.sub.n (II)where R.sup.1 is phenyl or substituted phenyl and where R.sup.2 is different than R.sup.1 and is an alkyl or substituted alkyl radical or a phenyl or substituted phenyl radical.These polymers are prepared by polymerizing cyclic triphosphazenes of the formula: ##STR1## to form the polymers (I) which, in turn, are reacted to replace the chlorine with organic radicals to form polymers (II).The polymers (II) can be formed by chemical blowing agents to form fire retardant articles. These polymers have fire retardant properties and evolve little or no smoke when exposed to an open flame.

Abstract: A fireproof linear aromatic polyester having a high stability to ultraviolet rays and heat contains a unit of the formula: ##STR1## WHEREIN R.sub.1 and R.sub.2 are each a straight or branched alkylene group having 1 to 5 carbon atoms and n.sub.1 and n.sub.2 are each an integer of from 1 to 4. The addition of an organic pentavalent phosphorus compound may improve the fireproof properties of products prepared from said polyesters.