Abstract: Aromatic polyethers are made by boiling an organic sulphoxide or sulphone solvent containing i) an equimolar mixture of a bisphenol and an aromatic dihalo compound or ii) a halophenol, in which dihalo compound or halophenol the halogen atoms are activated by ortho or para --SO.sub.2 -- or --CO-- groups, and an alkali metal carbonate with removal of the water produced by the reaction by distillation in the absence of an azeotrope forming solvent.
Abstract: Aromatic polyetherketones and polyether sulphones are prepared from a hydrated alkali metal bisphenate by heating a substantially equimolar mixture of the bisphenate and an activated aromatic dihalide in the presence of an aromatic sulphone to distil off the water, preferably at atmospheric pressure, and then heating at temperatures in the range 250.degree. to 400.degree. C. to effect polymerization.