Material Contains A Phosphorus Or Sulfur Atom Patents (Class 528/242)
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Patent number: 10494472Abstract: Crosslinked polydithiocarbamates based on 1,3,5-triazinane cores linked to pyrrole-dithiocarbamates via alkyl chains. A process for preparing these crosslinked polydithiocarbamates via a Mannich-type polycondensation of diaminoalkane, paraformaldehyde and a pyrrole compound, which is followed by additional modification of the pyrrole moiety to a pyrrole-dithiocarbamate. A method for removing heavy metals, such as Cd(II) from an aqueous solution or an industrial wastewater sample with these crosslinked polydithiocarbamates is also described.Type: GrantFiled: December 28, 2017Date of Patent: December 3, 2019Assignee: King Fahd University of Petroleum and MineralsInventors: Othman Charles Sadeq Al Hamouz, Mohammed Estatie, Tawfik Abdo Saleh Awadh
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Patent number: 8697772Abstract: Certain novel polymerizable phosphoric acid derivatives (hereinafter referred to as monomers) comprising a polyalicyclic structure element, mixtures comprising one or a plurality of these compounds and corresponding curable blends and products as well as their respective use as a dental material or for the preparation of a dental material are described. The compounds are eminently suitable as bonding agents, in particular in dental adhesive materials. A process for preparing these compounds or mixtures and a method for preparing a product, preferably a product suitable for dentistry, are also described.Type: GrantFiled: November 8, 2011Date of Patent: April 15, 2014Assignee: VOCO GmbHInventors: Tobias Blömker, Manfred Stepputtis, Manfred Thomas Plaumann
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Patent number: 8586289Abstract: The aromatic hydrocarbon resin can be used as a coating material and a resist resin for a semiconductor, and has a high carbon concentration and a low oxygen concentration. A composition for forming an underlayer film for lithography that has excellent etching resistance as an underlayer film for a multilayer resist process, an underlayer film formed with the same, and a pattern forming method using the same are disclosed. An aromatic hydrocarbon is reacted with an aromatic aldehyde in the presence of an acidic catalyst, thereby providing an aromatic hydrocarbon resin that has a high carbon concentration of from 90 to 99.9% by mass and a low oxygen concentration of from 0 to 5% by mass. A composition for forming an underlayer film for lithography contains the resin and an organic solvent, an underlayer film is formed with the same, and a pattern forming method uses the same.Type: GrantFiled: September 14, 2010Date of Patent: November 19, 2013Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Ryuji Ideno, Seiji Kita, Masashi Ogiwara, Gou Higashihara
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Patent number: 8481671Abstract: The present invention relates to a process for the preparation of oxymethylene polymers as well as oxymethylene polymers obtainable therefrom. The process includes polymerization of a monomer, which forms —CH2—O— units in the presence of an acetal of formaldehyde or a polyhydric alcohol and an initiator for cationic polymerization. The initiator may be a heteropoly acid or an acid salt thereof which is dissolved in an alkyl ester of a polybasic carboxylic acid.Type: GrantFiled: May 26, 2010Date of Patent: July 9, 2013Assignee: Ticona GmbHInventors: Michael Haubs, Michael Hoffmockel, Jurgen Lingnau, Robert M. Gronner, Lowell Larson
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Publication number: 20130102716Abstract: The present invention relates to new condensation resins of urea, formaldehyde, and CH-acidic aldehydes, to methods for preparing them, and to their use.Type: ApplicationFiled: August 17, 2012Publication date: April 25, 2013Applicant: BASF SEInventors: Gabor Börzsönyi, Günter Scherr, Klaus Menzel, Stefan Meuer
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Patent number: 8367795Abstract: The invention relates to chemical industry, in particular to a substance with antiseptic properties and to a method for obtaining and use thereof. The inventive substance can be used as a filtering material or an additive for the mixture of filtering materials, or as a component of filtering composites used for disinfection and purification of liquids, preferably drinking water, or gases. The inventive antiseptic material consists of a solid non-water soluble cross-linked polymer material, which comprises chlorine atoms reversibly bound with nitrogen atoms and is characterized by the following general formula: M(F)1.0-5.5(Ph)0.6-1.0Cl-4.2, where M is melamine, F—bridge and terminal groups—formaldehyde derivatives, Ph—phosphorus with oxidation level +5, Cl—chlorine atoms bound with nitrogen atoms, wherein the above-mentioned material is cross-linked by binding phosphorus-containing ions with melamine links of polymer chains.Type: GrantFiled: September 3, 2008Date of Patent: February 5, 2013Assignee: OOO AquaphorInventor: Oleg Vladimirovich Dubov
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Publication number: 20120268840Abstract: Disclosed is a carbon nano-tube dispersant comprising a highly branched polymer having a repeating unit represented by, for example, formula (12) or (13), wherein the highly branched polymer is produced by the polycondensation of a triarylamine compound and an aldehyde compound and/or a ketone compound in the presence of an acid catalyst. The carbon nano-tube dispersant enables the dispersion of CNTs in a medium such as an organic solvent until the CNTs are so decomposed as to have an individual size. (In the formula, Z1 and Z2 independently represent a hydrogen atom, a phenyl group, a thienyl group, or the like.Type: ApplicationFiled: November 25, 2010Publication date: October 25, 2012Applicant: Nissan Chemical Industries, Ltd.Inventors: Masahiro Hida, Daigo Saito, Tatsuya Hatanaka
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Publication number: 20120171611Abstract: The aromatic hydrocarbon resin can be used as a coating material and a resist resin for a semiconductor, and has a high carbon concentration and a low oxygen concentration. A composition for forming an underlayer film for lithography that has excellent etching resistance as an underlayer film for a multilayer resist process, an underlayer film formed with the same, and a pattern forming method using the same are disclosed. An aromatic hydrocarbon is reacted with an aromatic aldehyde in the presence of an acidic catalyst, thereby providing an aromatic hydrocarbon resin that has a high carbon concentration of from 90 to 99.9% by mass and a low oxygen concentration of from 0 to 5% by mass. A composition for forming an underlayer film for lithography contains the resin and an organic solvent, an underlayer film is formed with the same, and a pattern forming method uses the same.Type: ApplicationFiled: March 24, 2011Publication date: July 5, 2012Inventors: Ryuji Ideno, Seiji Kita, Masashi Ogiwara, Gou Higashihara
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Publication number: 20100324255Abstract: The present invention provides a polyfunctional dimethylnaphthalene formaldehyde resin which is polyfunctional, rich in reactivity and useful as a variety of raw materials to be modified, specifically a dimethylnaphthalene formaldehyde resin obtained by allowing (1) one kind or two or more kinds of a dimethylnaphthalene having one methyl group on each of two benzene rings in a naphthalene ring thereof and selected from the group consisting of 1,5-dimethylnaphthalene, 1,6-dimethylnaphthalene, 2,6-dimethylnaphthalene, 1,7-dimethylnaphthalene, 1,8-dimethylnaphthalene and 2,7-dimethylnaphthalene; and (2) formaldehyde to react with each other in the presence of water and an acid catalyst, the polyfunctional dimethylnaphthalene formaldehyde resin having a mean value of the number of hydrogen atoms substituted by the reaction among the six hydrogen atoms directly bonded on the naphthalene ring in the dimethylnaphthalene of from 1.8 to 3.5.Type: ApplicationFiled: November 11, 2008Publication date: December 23, 2010Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Seiji Kita, Masashi Ogiwara
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Patent number: 7718760Abstract: The present invention provides a ?-conjugated polymer containing a repeating unit expressed by the following General Formula (I): where, in the General Formula (I), Y and Ar represent one of a substituted or unsubstituted aromatic hydrocarbon and a substituted or unsubstituted divalent group of aromatic heterocyclic ring, Y1 represents one of a substituted or unsubstituted unsaturated aliphatic hydrocarbon, a substituted or unsubstituted aromatic hydrocarbon and a substituted or unsubstituted divalent group of aromatic heterocyclic ring and R represents one of a hydrogen atom, a substituted or unsubstituted alkyl group and a substituted or unsubstituted aromatic hydrocarbon group.Type: GrantFiled: March 10, 2006Date of Patent: May 18, 2010Assignee: Ricoh Company, Ltd.Inventors: Masaomi Sasaki, Toshiya Sagisaka, Masafumi Torii, Takashi Okada, Shinichi Kawamura
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Patent number: 7645822Abstract: Process for preparation of polyoxymethylenes via polymerization of the monomers a) in the presence of cationic initiators b) and also, if appropriate, in the presence of regulators c), followed by deactivation and discharge from the reactor, which comprises using, as deactivator (d) at least one basic compound having at least 2 amino functions of different reactivity in one molecule.Type: GrantFiled: November 5, 2005Date of Patent: January 12, 2010Assignee: BASF SEInventors: Jens Assmann, Knut Zollner
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Publication number: 20090275724Abstract: Process for preparing polyoxymethylenes by polymerization of the monomers a) in the presence of cationically active initiators b) and, if appropriate in the presence of regulators c) and subsequent deactivation d) and discharge from the reactor, wherein at least one ionic liquid is used as initiator b).Type: ApplicationFiled: September 7, 2007Publication date: November 5, 2009Applicant: BASF SE Patents ,Trademarks and LicensesInventors: Karthikeyan Sharavanan, Kathrin Wissel
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Patent number: 7262237Abstract: Curable urea formaldehyde binder compositions are provided which are useful in coated abrasive and wood engineering applications, in a time released fashion. The time released curable binder compositions include a urea formaldehyde resin and an aryl phosphite in varying concentrations. The curable binder compositions of the present invention provide desirable working times and faster curing times tinder ambient or near ambient conditions.Type: GrantFiled: June 24, 2004Date of Patent: August 28, 2007Assignee: Hexion Specialty Chemicals, Inc.Inventor: Jimmy Pingao Chen
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Patent number: 7169191Abstract: A novel synthetic aluminium tanning agent as an alternative for chromium based tanning salts without using formaldehyde was prepared by using aromatic polymeric matrix and aluminium (III) salts as raw materials with suitable masking agents. The preparation of the syntan consists of sulphonation of aromatic molecule, which is incorporated with a polymeric network along with ligands specially designed for the complexation of aluminium (III) salts. The complex can be used as a self-tanning agent in leather industry with fairly good filling behavior. The tanned leathers exhibit shrinkage temperature about 85° C. Due to the higher precipitation point of the product, it can be used for tanning directly after deliming thus eliminating the pickling process. This product, unlike the conventional phenol based products, does not undergo photo-oxidation thereby preventing the discoloration of the tanned leathers.Type: GrantFiled: March 20, 2003Date of Patent: January 30, 2007Assignee: Council of Scientific and Industrial ResearchInventors: Mookandi Kanthimathi, Palanisamy Thanikaivelan, Jonnalagadda Raghava Rao, Balachandran Unni Nair, Thirumalachari Ramasami
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Patent number: 7071290Abstract: The invention relates to polymers and oligomers, methods of their synthesis, and electronic devices comprising them.Type: GrantFiled: April 28, 2005Date of Patent: July 4, 2006Assignee: The Ohio State UniversityInventors: Arthur J. Epstein, Daike Wang
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Patent number: 7049389Abstract: This invention relates to a process for preparing high-purity aromatic oligomers by effectively separating an organic layer containing aromatic oligomers or the reaction products of a polycyclic aromatic compound with formaldehyde from an aqueous layer containing an acid catalyst in a simplified manner, hitherto regarded difficult to accomplish, and obtaining high-purity aromatic oligomers from the organic layer containing a reduced amount of impurities. In separating the aqueous layer containing the acid catalyst and the organic layer containing the oligomers from the reaction mixture formed by the condensation of a polycyclic aromatic compound and formaldehyde, the emulsion phase is broken by adding a nonionic or cationic surfactant in an effective amount and an alkali in an amount sufficient to neutralize 1–70% of the acid in the acid catalyst, the organic and aqueous layers are separated and the aromatic oligomers are recovered from the organic layer.Type: GrantFiled: December 26, 2002Date of Patent: May 23, 2006Assignee: Nippon Steel Chemical Co., Ltd.Inventors: Toshihide Senzaki, Takahiro Imamura, Kazuyoshi Horibe, Tomoaki Yoshida, Atsuhiko Katayama, Yasuo Wada, Katsuhide Noguchi
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Patent number: 7022805Abstract: The present invention relates to a process for the preparation of acetal polymers, in particular of polyoxymethylene (POM) by cationic polymerization where organophosphonic and/or organophosphinic acids and/or their derivatives and/or their precursors are used as the initiator.Type: GrantFiled: September 10, 2004Date of Patent: April 4, 2006Assignee: Ticona GmbHInventors: Michael Haubs, Stanislaw Penczek
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Patent number: 6906166Abstract: The invention relates to polymers and oligomers, methods of their synthesis, and electronic devices comprising them.Type: GrantFiled: May 18, 2004Date of Patent: June 14, 2005Assignee: The Ohio State UniversityInventors: Arthur J. Epstein, Daike Wang
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Patent number: 6794480Abstract: A monomer containing an electron-withdrawing group and an electron-donative group which can be easily controlled in the upper limit of the amount of a sulfonic acid, which impairs the mechanical properties of a copolymer, and can provide a sulfonated polymer that forms a proton-conductive membrane having a high proton conductivity over a wide temperature range, an excellent mechanical strength and an excellent proton conductivity and showing inhibited swelling in hot water and an aqueous solution of methanol, and a copolymer obtained from the monomer. A monomer containing an electron-withdrawing group and an electron-donative group represented by the following general formula (1): wherein Y represents a iodine atom, chlorine atom or bromine atom; X represents an electron-withdrawing group; B represents an electron-donative group; and Z represents an aryl group having a specific structure or a monovalent condensed ring hydrocarbon group such as naphthyl group.Type: GrantFiled: March 26, 2002Date of Patent: September 21, 2004Assignee: JSR CorporationInventors: Kohei Goto, Masayuki Takahashi, Yoshitaka Yamakawa, Makoto Higami
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Patent number: 6777532Abstract: The invention relates to polymers and oligomers, methods of their synthesis, and electronic devices comprising them.Type: GrantFiled: February 28, 2002Date of Patent: August 17, 2004Assignee: The Ohio State UniversityInventors: Arthur J. Epstein, Daike Wang
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Publication number: 20040019176Abstract: There are provided a curable fluorine-containing polymer which can realize a high hardness by photo-curing while maintaining a low refractive index, an antireflection film possessing improved scratch resistance and abrasion resistance while maintaining a reflection reducing effect, and an antireflection-treated article provided with such an antireflection film.Type: ApplicationFiled: February 26, 2003Publication date: January 29, 2004Inventors: Takayuki Araki, Mihoko Ohashi, Yoshito Tanaka, Tetsuo Shimizu
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Patent number: 6620903Abstract: This invention relates to fluoropolymer fibers and films which can be modified by cationic agents, such as cationic dyes. The fiber or film comprises a blend of a first and a second copolymer, or it comprises a terpolymer, the blend or terpolymer having (1) an acid or ionic functionality provided by a pendant group represented by the formula —(O—CF2CFR)aO—CF2CFR′SO3−Z+, wherein R and R′ are independently selected from F, Cl or a perfluorinated alkyl group having 1 to 10 carbon atoms, a=0, 1 or 2, and Z+ is H+, an alkali metal cation, or a cation derived from a compound selected from the group consisting of a cationic dye, a cationic whitener, a cationic flame retardant, a cationic antistatic agent, and mixtures thereof, and (2) a larger amount of a fluoroalkylvinylether, a fluoroalkene, or ethylene functionality. Such fibers and films are useful in various consumer goods where the product is desirably colored, whitened, antistatic, or flame retardant.Type: GrantFiled: December 3, 2002Date of Patent: September 16, 2003Assignee: E. I. du Pont de Nemours and CompanyInventor: Uy William Cheng
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Patent number: 6605685Abstract: An improved resin for use in making honeycomb sandwich panels. The improvement involves modifying a phenolic resin so that the amount of smoke and heat generated during combustion is reduced. The reduction in smoke and heat generation is achieved by reducing the amount of phenol used to form the phenolic resin. The phenol is replaced by low-smoke producing sulfone compounds such as 4,4′-bisphenol-S, 3,3′-bisphenol-S, biphenol and bisphenol ethers which reduce the number of smoke producing methylene or methylene ether linkages present in the cured phenolic resin. The low-smoke producing resin may be used as a dip resin for coating the honeycomb or as the matrix resin for the core and face sheets of the sandwich panel.Type: GrantFiled: August 14, 2001Date of Patent: August 12, 2003Assignee: Hexcel CorporationInventor: Yen-Seine Wang
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Patent number: 6590067Abstract: A method for lateral chain modification of aryl main chain polymers with aromatic ketones or aldehydes containing tertiary basic N-groups is described. The modification can be accomplished via addition of an aromatic carboxylic acid or an acid derivative containing a tertiary amine moiety to a metallized polymer. The tertiary amines on the modified polymer can be converted to quaternary amines with halogen alkanes. Modification of the aryl main chain polymers with aromatic groups containing sulphonic acid radicals is also described. The polymers formed can be crosslinked and prepared for use in a wide variety of membrane technologies including ion exchange, dialysis, reverse osmosis, nanofiltration.Type: GrantFiled: February 12, 2001Date of Patent: July 8, 2003Assignee: Universitaet StuttgartInventors: Jochen Kerres, Andreas Ullrich, Thomas Haring
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Publication number: 20030040598Abstract: An improved resin for use in making honeycomb sandwich panels. The improvement involves modifying a phenolic resin so that the amount of smoke and heat generated during combustion is reduced. The reduction in smoke and heat generation is achieved by reducing the amount of phenol used to form the phenolic resin. The phenol is replaced by low-smoke producing sulfone compounds such as 4,4′-bisphenol-S, 3,3′-bisphenol-S, biphenol and bisphenol ethers which reduce the number of smoke producing methylene or methylene ether linkages present in the cured phenolic resin. The low-smoke producing resin may be used as a dip resin for coating the honeycomb or as the matrix resin for the core and face sheets of the sandwich panel.Type: ApplicationFiled: August 14, 2001Publication date: February 27, 2003Inventor: Yen-Seine Wang
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Patent number: 6433128Abstract: A process for producing an oxymethylene copolymer by polymerizing trioxan and 1,3-dioxolan in the presence of a cationically active catalyst, wherein (1) 1,3-dioxolan is used in an amount of 0.01 to 2.9 mol % based on trioxan; and (2) the cationically active catalyst is used in an amount of 1×10−7 to 1.2×10−4 mol based on 1 mol of trioxan. The process of the present invention makes it possible to obtain at a high yield an oxymethylene copolymer which has almost as high mechanical strength and stiffness as an oxymethylene homopolymer while retaining the tenacity and heat stability of an oxymethylene copolymer.Type: GrantFiled: May 16, 2001Date of Patent: August 13, 2002Assignee: Mitsubishi Gas Chemical Co, Inc.Inventors: Takahiro Nakamura, Akira Okamura, Masanori Furukawa, Isamu Masumoto, Kaneo Yoshioka, Kazumasa Maji
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Publication number: 20020045729Abstract: A method for lateral chain modification of aryl main chain polymers with aromatic ketones or aldehydes containing tertiary basic N-groups is described. The modification can be accomplished via addition of an aromatic carboxylic acid or an acid derivative containing a tertiary amine moiety to a metallized polymer. The tertiary amines on the modified polymer can be converted to quaternary amines with halogen alkanes. Modification of the aryl main chain polymers with aromatic groups containing sulphonic acid radicals is also described. The polymers formed can be crosslinked and prepared for use in a wide variety of membrane technologies including ion exchange, dialysis, reverse osmosis, nanofiltration.Type: ApplicationFiled: February 12, 2001Publication date: April 18, 2002Inventors: Jochen Kerres, Andreas Ullrich, Thomas Haering
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Patent number: 6342271Abstract: The invention relates to a resin composition based on a urea-modified phenol-formaldehyde resole which has a formaldehyde/phenol molar ratio of 2 to 5, exhibiting a free formaldehyde content lower than or equal to 3 percent (by weight relative to the total weight of the composition), a free phenol content lower than or equal to 0.5 percent and a dilutability measured at 20° C., of at least 1000 percent and to a process for the preparation of this composition. This composition is characterized in that it contains an overcondensed resole obtained by the condensation of phenol, of formaldehyde, and optionally of urea in basic medium, until the product has a water dilutability at pH 9 that is lower than or equal to 2000 percent, or the product of neutralization of such as resole. The modification of an overcondensed phenolic resole by neutralization with boric acid according to the invention permits the dilutability of the resole to be increased.Type: GrantFiled: April 27, 2000Date of Patent: January 29, 2002Assignee: Isover Saint-GobainInventors: Bernard Lericque, Serge Tetart, Claire Labbe, Philippe Espiard
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Patent number: 6335304Abstract: A metal (M) alkyl acid phosphate catalyst for the reaction of an epoxy compound with a carboxyl compound to provide a coating formulation that is stable at room temperature; that is humidity resistant, and non-yellowing, wherein the alkyl acid phosphate has the formula: (RO)n—(P═O)—(OH)m and wherein: a. each R is selected from the group consisting of: i) a C1 to C18 alkly, cycloalkyl, or aryl; ii) a linear or branched C6 to C18 alkyl substituted with —(O—CH2—CH2—)o or —(O—CH—CH3—CH2—)p, wherein o or p is from 1 to 20; iii) a &bgr;-hydroxyethyl compound, R′—X—CH2—CH—OH—CH2—, wherein R′ is a C6 to C18 alkyl or cycloalkyl or aryl, X is either —CH2—, —O— or —COO—; b. n+m=3 and n is between 2 to 1; and c. M is Zn or Sn (II) in a mole equivalent of 0.7 to 1.5 moles per mole of alkyl acid phosphate.Type: GrantFiled: November 9, 1999Date of Patent: January 1, 2002Assignee: KIng Industries, INCInventors: Zhiqiang Alex He, Werner J. Blank, Marie Emmanuelle Picci
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Patent number: 6316591Abstract: Ordered poly(arylene-vinylene)terpolymers, process for their preparation and their use as electroluminescence materials Poly(arylene-vinylene) terpolymers comprising repeating units of the formula (I), where the symbols have the following meanings: Ar1, Ar2, Ar3 are identical or different and are monocyclic or polycyclic, substituted or unsubstituted aryl or heteroaryl groups which may be linked via one or more bridges or be fused, R1, R2, R3, R4, R5, R6, R7, R8 are identical or different and are each H or a hydrocarbon radical having from 1 to 22 carbon atoms which may be substituted, preferably by F, and may also contain heteroatoms, preferably O, are suitable as electroluminescence materials.Type: GrantFiled: August 13, 1999Date of Patent: November 13, 2001Assignee: Aventis Research & Technologies GmbH & Co. KGInventors: Willi Kreuder, Hans-Heinrich Hörhold, Henning Rost, Annett Hartmann
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Patent number: 6265528Abstract: A particularly useful process which includes the steps of providing a feedstream comprising a soluble condensation promoting component capable of activating a heterogeneous acidic catalyst and a source of formaldehyde formed by conversion of dimethyl ether in the presence of a catalyst comprising silver as an essential catalyst component; and heating the feedstream with the heterogeneous acidic catalyst in a catalytic distillation column to convert methanol and formaldehyde present to methylal and higher polyoxymethylene dimethyl ethers and to separate the methylal from the higher polyoxymethylene dimethyl ethers is disclosed. Advantageously, methylal and higher polyoxymethylene dimethyl ethers are formed and separated in a catalytic distillation column.Type: GrantFiled: November 12, 1998Date of Patent: July 24, 2001Assignee: BP Corporation North America Inc.Inventors: Gary P. Hagen, Michael J. Spangler
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Patent number: 6174986Abstract: A process for polymerizing a vinyl chloride monomer wherein the vinyl chloride monomer is subjected to homopolymerization or (co)polymerization with a monomer copolymerizable with the vinyl chloride monomer in an aqueous solvent, comprising applying in advance a coating liquid containing a cocondensation product obtained by reacting either a phenothiazine derivative and an aldehyde or a phenothiazine derivative, a naphthol derivative and an aldehyde to give an initial condensation product and then reacting the initial product with a polyphenol, to an inner wall of a polymerization tank and parts of an apparatus in contact with the monomers during the polymerization process. The process makes it possible to apply the cocondensation product as an aqueous solution to, e.g., an inner wall of a polymerization tank; to quite effectively prevent polymer adhesion in, e.g.Type: GrantFiled: December 18, 1997Date of Patent: January 16, 2001Assignee: Mitsui Chemicals, Inc.Inventors: Ichisaburo Nakamura, Akihiko Takahashi, Masaaki Ozawa
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Patent number: 5994455Abstract: A process for the preparation of polyoxymethylene copolymers, wherein 1,3,5-trioxane is polymerized with generally known comonomers in the presence of a strong protonic acid initiator and in the presence of a formaldehyde dialkyl acetal, and wherein the initiator is dissolved in the formaldehyde dialkyl acetal before admixing to the trioxane and the comonomers.Type: GrantFiled: September 8, 1998Date of Patent: November 30, 1999Assignee: Ticonna GmbHInventors: Karl-Friedrich Muck, Horst Roschert, Robert M. Gronner, Satyajit Verma, Michael G. Yearwood
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Patent number: 5962623Abstract: A continuous process for the preparation of polyacetal copolymers from 1,3,5-trioxane and the comonomers known for this purpose using strong protic acids as an initiator, in which the initiator is added in an amount of 0.01 to 0.6 ppm, based on the total amount of monomers, in finely divided form to the monomer mixture, after the polymerization step the crude polymer is transferred from the polymerization reactor to a mixing unit without further intermediate steps, excess monomer is removed from the crude polymer in the mixing unit or between polymerization reactor and mixing unit by applying reduced pressure and, if desired, generally customary stabilizers, assistants, fillers, reinforcing materials and/or colorants are incorporated into the polymer in the mixing unit.Type: GrantFiled: September 8, 1998Date of Patent: October 5, 1999Assignee: Ticona GmbHInventors: Peter Eckardt, Michael Hoffmockel, Karl-Friedrich Muck, Gerhard Reuschel, Satyajit Verma, Michael G. Yearwood
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Patent number: 5929195Abstract: A branched or crosslinked polyacetal resin is excellent in blow moldability, has impact resistances such as plane impact resistance, and the smoothness of the inner surfaces of moldings produced therefrom, and is suitable for molding, particularly blow molding. It can be produced by the bulk polymerization of (A) trioxane with (B) a cyclic ether and/or cyclic formal and (C) a polyfunctional glycidyl ether compound in the presence of (D) a cationic polymerization catalyst, a mixture prepared by mixing the cyclic ether and/or cyclic formal (B) with the polyfunctional glycidyl ether compound (C) and the cationic polymerization catalyst (D) is added to trioxane (A) to conduct the polymerization.Type: GrantFiled: July 14, 1998Date of Patent: July 27, 1999Assignee: Polyplastics Co., Ltd.Inventors: Kuniaki Kawaguchi, Kaoru Yamamoto, Hajime Serizawa
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Patent number: 5866670Abstract: A process for producing a polyacetal copolymer, which is extremely heat-stable and is extremely reduced in the quantity of unstable terminals even in a high polymerization yield in which trioxane as the principal monomer, comprises copolymerization of trioxane as the principal monomer with a cyclic ether or cyclic formal having at least one carbon-to-carbon bond as the comonomer by using a specific heteropoly-acid or acid salt thereof as a polymerization catalyst until the content of the remaining monomers is lowered to at most 10% by weight based on all the monomers fed, adding 0.01 to 10% by weight, based on the resulting crude polymer, of a solution containing a catalyst deactivator, or contacting a basic gas as the deactivator to deactivate the catalyst, and subjecting the crude polymer as such to heat melting treatment without washing thereof.Type: GrantFiled: August 15, 1996Date of Patent: February 2, 1999Assignee: Polyplastics Co., Ltd.Inventors: Akira Nakai, Kaoru Yamamoto, Eiji Masuda, Hiroyuki Kanai
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Patent number: 5728798Abstract: In preparing a polyacetal copolymer through copolymerization of trioxane as the principal monomer with a cyclic ether or cyclic formal having at least one carbon-carbon bond as the comonomer, 0.05 to 100 ppm (on the weight basis), based on the total amount of the monomers, of a heteropoly-acid or an acidic salt thereof is used as a polymerization catalyst, and a liquid mixture preliminarily prepared by mixing at least part or the whole of the comonomer with the polymerization catalyst is added to trioxane to effect copolymerization. According to such the process, the polymerization yield and the degree of polymerization (molecular weight) are enhanced, and a polyacetal copolymer having an improved stability can be obtained.Type: GrantFiled: March 7, 1997Date of Patent: March 17, 1998Assignee: Polyplastics Co., Ltd.Inventors: Akira Nakai, Kaoru Yamamoto
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Patent number: 5691426Abstract: A resin composition useful as a binder is provided comprising a mixture of a formaldehyde-based resin with a resin substitute comprising the reaction product of an amine derivative chosen from melamine, glycolurile or their mixtures with 1 to 2 moles of a C.sub.1 to C.sub.8 dialkoxyethanal, the reaction product is mixed, preferably reacted, with a polyol.Type: GrantFiled: February 28, 1997Date of Patent: November 25, 1997Assignee: Sequa Chemicals, Inc.Inventor: William Floyd
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Patent number: 5688897Abstract: The present invention provides a method for producing an oxymethylene copolymer, which comprises:copolymerizing trioxane and a cyclic ether and/or a cyclic formal in the presence of at least one selected from the group consisting of boron trifluoride, boron trifluoride hydrate, and a coordination compound of an organic compound having an oxygen or a sulphur atom with boron trifluoride,volatilizing the residual polymerization catalyst to decrease its amount, by heating the obtained oxymethylene copolymer in an atmosphere of inert gas at or below its melting point, and/or reducing the pressure, without conducting any operation of deactivating the residual polymerization catalyst before volatilizing the residual polymerization catalyst, andstabilizing terminal moities of the oxymethylene copolymer after deactivating residual catalyst or stabilizing terminal moieties of the oxymethylene copolymer directly.Type: GrantFiled: July 10, 1996Date of Patent: November 18, 1997Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Noritaka Tanimura, Yukio Tanigawa, Sumio Komatsu
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Patent number: 5608030Abstract: Process for continuous preparation of homo- and copolyoxymethylenes with stable end groups in a homogeneous phase, in which in a tubular reactor with static mixing elements cyclic formaldehyde oligomers are polymerized in the presence of protonic acids as initiators in amounts of 0.005 to 500 ppm in a polymerization zone, in which the residence time of the reaction components in this zone is 0.1 to 10 min and in which the initiator is deactivated immediately after polymerization, there being a fluid transition between the polymerization and deactivator zones which is determined solely by the addition of deactivator, and in which, besides deactivation, stabilization of the chain ends is carried out in the presence of residual monomers, with the volatile constituents being removed from the reaction mixture in a subsequent vent unit. Stabilization is carried out in the presence of alkaline substances, either at temperatures of 150.degree. C. to 250.degree. C.Type: GrantFiled: August 15, 1994Date of Patent: March 4, 1997Assignee: Hoechst AktiengesellschaftInventors: Michael Hoffmockel, Karl-Friedrich M uck, Helmut Schlaf, Karlheinz Burg
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Patent number: 5608027Abstract: A composition comprising a phosphorus containing acid and an ester of a phosphorus containing acid useful for imparting improved physical and chemical properties to polymers containing polyesters, copolyester carbonates, polycarbonates, and mixtures thereof, a method of treating said polymers with said composition, and articles of manufacture comprising said polymers and said composition.Type: GrantFiled: November 22, 1995Date of Patent: March 4, 1997Assignee: General Electric CompanyInventors: Richard Crosby, James L. DeRudder, Larry I. Flowers, Ye-Gang Lin, Roy R. Odle
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Patent number: 5587449Abstract: In the process for the preparation, with simultaneous end group stabilization, of polyacetal copolymers in a homogeneous phase and working up thereof, cyclic formaldehyde oligomers are copolymerized with cyclic acetals in the presence of an initiator in a polymerization reactor and immediately thereafter the initiator is deactivated by addition of basic substances, the unstable chain ends being degraded down to 0.01% to 1% in the presence of residual monomer, the product losing the majority of the residual monomer at the reactor outlet by letting down into a pelletizing device and the residual monomer which remains and the impurities dissolved in the product being removed by extraction with solvents and the product being pelletized, after drying and stabilization.Type: GrantFiled: August 31, 1995Date of Patent: December 24, 1996Assignee: Hoechst AktiengesellschaftInventors: Dietrich Fleischer, Michael Hoffmockel, Karl-Friedrich Muck, Gunter Sextro
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Patent number: 5500477Abstract: A moulding composition based on linear polyoxymethylene copolymers and customary additives with a melt index MFI (2,16 kg, 190.degree. C.) of .ltoreq.0,8, preferably .ltoreq.0,5 and especially .ltoreq.0,2 g/10 min has an extraordinary high toughness, which eliminates an addition of elastomer modifiers. In its preparation Lewis acids or protonic acids are used as initiators.Type: GrantFiled: April 26, 1995Date of Patent: March 19, 1996Assignee: Hoechst AktiengesellschaftInventors: Gerhard Reuschel, Dietrich Fleischer, Kaoru Yamamoto, Shuichi Chino
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Patent number: 5380789Abstract: A catalyst selected from a perfluorosulfonic acid and an anhydride thereof enables a non-conjugated drying oil to react with a phenol to form a phenol-added vegetable oil without causing hydrolysis of the non-conjugated drying oil. The phenol-added vegetable oil is allowed to react with an aldehyde to form a vegetable oil-modified phenolic resin. A laminate produced by impregnating paper with the vegetable oil-modified phenolic resin and laminating and molding the impregnated paper is excellent in low temperature punching quality and electrical properties and is free from low molecular weight components oozing out the surface of the laminate.Type: GrantFiled: August 10, 1993Date of Patent: January 10, 1995Assignee: Hitachi Chemical Company, Ltd.Inventors: Ken Nanaumi, Takeshi Horiuchi, Masahiro Nomoto, Mitsuhiro Inoue
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Patent number: 5374697Abstract: Sulfonium compounds of formula 1 or 2 ##STR1## wherein R is a mononuclear cycloalkyl radical containing 3 to 8 ring carbon atoms or a mononuclear cycloalkyl radical which contains 3 to 8 ring carbon atoms and to which at least one further ring containing carbon atoms is fused,X is a non-nucleophilic anion, andZ is a single bond, an oxygen or sulfur atom, a group of formula >S.sup..sym. --R X.sup..crclbar., wherein R and X are as defined above, or is >C.dbd.O or a methylene bridge,which sulfonium compounds are either unsubstituted or carry one or more than substituent selected from the group consisting of halogen, nitro, C.sub.1 -C.sub.8 alkyl, phenyl, hydroxyl, C.sub.1 -C.sub.8 alkoxy, phenoxy, benzyloxy, alkoxycarbonyl containing 1 to 4 carbon atoms in the alkoxy moiety or acyl of 1 to 12 carbon atoms.Type: GrantFiled: July 14, 1993Date of Patent: December 20, 1994Assignee: Ciba-Geigy CorporationInventor: Beat Muller
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Patent number: 5362842Abstract: A urea-formaldehyde resin useful as a binder for making a variety of products, and of a method for making the resin. The resin is prepared by reacting formaldehyde, urea, triethanolamine, and optionally ammonia in a two-step process, first under alkaline conditions and then under acidic conditions. The urea-formaldehyde resin thus produced has good resistance to hydrolysis, cures quickly without smoking, and is characterized by low formaldehyde release.Type: GrantFiled: September 10, 1993Date of Patent: November 8, 1994Assignee: Georgia Pacific Resins, Inc.Inventors: Larry R. Graves, Jay V. Mueller
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Patent number: 5288840Abstract: A polyoxymethylene copolymer excellent in stability and mechanical properties which is comprised of oxymethylene units and oxyalkylene units and has a molecular weight of 10,000 to 200,000. The proportion of oxyalkylene units to oxymethylene units is 0.07 to 0.5% by mole and the ratio of the absorbance of terminal formate groups to that of methylene groups determined by infrared spectrophotometry is not more than 0.025. A process for producing the copolymer is also disclosed.Type: GrantFiled: June 2, 1992Date of Patent: February 22, 1994Assignee: Asahi Kasei Kabushiki KaishaInventors: Hirohisa Morishita, Kazuhiko Matsuzaki
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Patent number: 5260415Abstract: This invention relates to a process for the crosslinking of polymers containing diaryl ketone groups consisting of heating the polymer with an alcohol and/or alkoxide, and optionally exposing the polymer to a strong mineral acid. The crosslinked polymers have enhanced chemical resistance.Type: GrantFiled: March 12, 1992Date of Patent: November 9, 1993Assignee: E. I. Du Pont de Nemours and CompanyInventor: Israel A. David
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Patent number: 5223323Abstract: The present invention relates to a process for coating finish foils and endless edges, wherein an acid-curing aqueous coating composition, on the basis of aminoplast resin/compound containing hydroxyl groups/self-crosslinking acrylate dispersion, is applied and baked in. The coating composition used contains 5 to 20% by weight of one or more fillers of a mean particle size from 0.015 to 10 .mu.m, a maximum particle size of .ltoreq.40 .mu.m and a density of .ltoreq.2.9 g/cm.sup.3.The invention also relates to the coating compositions positions used in the process and to finish foils and endless edges produced by the process, which especially have the advantage of an extremely low formaldehyde emission, particularly as a composite with a low-formaldehyde chipboard.Type: GrantFiled: September 30, 1991Date of Patent: June 29, 1993Assignee: BASF CorporationInventors: Karl-Heinz Dickerhof, Joachim Roll, Wilhelm Moss, Thomas Schwalm
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Patent number: RE39182Abstract: A process for the preparation of polyoxymethylene copolymers, wherein 1,3,5-trioxane is polymerized with generally known comonomers in the presence of a strong protonic acid initiator and in the presence of a formaldehyde dialkyl acetal, and wherein the initiator is dissolved in the formaldehyde dialkyl acetal before admixing to the trioxane and the comonomers.Type: GrantFiled: November 30, 2001Date of Patent: July 11, 2006Assignee: Ticona GmbHInventors: Karl-Friedrich Mück, Horst Röschert, Robert M. Gronner, Satyajit Verma, Michael G. Yearwood