Sulfur-containing Polyhydroxy Compound Or Salt Of A Sulfur-containing Polyhydroxy Compound Patents (Class 528/294)
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Patent number: 10208155Abstract: The invention relates to a compound prepared by (i) reacting (a) at least one compound selected from diisocyanate, polyisocyanate, or mixture thereof; (b) at least one isocyanate-reactive compound selected from a fluorinated alcohol; a cyclic or acyclic sugar alcohol which is substituted with at least one —R1, —C(O)R1, —(CH2CH2O)n(CH(CH3)CH2O)mR2, —(CH2CH2O)n(CH(CH3)CH2O)mC(O)R1, or mixtures thereof; or mixtures of a fluorinated alcohol and a substituted cyclic or acyclic sugar alcohol; and (c) at least one isocyanate-reactive ethylenically unsaturated compound; wherein each n is independently 0 to 20; each m is independently 0 to 20; m+n is greater than 0; each R1 is independently a linear or branched alkyl group having 5 to 29 carbons optionally comprising at least 1 unsaturated bond; each R2 is independently —H, or a linear or branched alkyl group having 6 to 30 carbons optionally comprising at least 1 unsaturated bond, or mixtures thereof; and (ii) reacting the reaction product of step (i) with a bisulfatType: GrantFiled: September 24, 2015Date of Patent: February 19, 2019Assignee: THE CHEMOURS COMPANY FC, LLCInventors: John Christopher Sworen, Gerald Oronde Brown, Tatsiana Haidzinskaya
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Patent number: 9934809Abstract: The magnetic recording medium composition contains ferromagnetic powder, binder, and a crosslinkable component selected from the group consisting of a component capable of forming a crosslinking structure by a radical reaction, a component capable of forming a crosslinking structure by an ionic reaction, and a component capable of forming a crosslinking structure by a pericyclic reaction, wherein the crosslinkable component contains at least polyester, and the polyester has a weight average molecular weight ranging from 1,000 to 20,000, as well as contains, per molecule, one or more acidic groups, and one or more reactive groups selected from the group consisting of a radical reactive group, an ionic reactive group, and a pericyclic reactive group.Type: GrantFiled: March 24, 2016Date of Patent: April 3, 2018Assignee: FUJIFILM CorporationInventors: Toshihide Aoshima, Reiko Inushima, Mika Imamura, Tatsuo Mikami
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Publication number: 20150133579Abstract: Methods for making biomaterials for use as a tissue sealant, kits containing precursors for forming the biomaterials, and the resulting biomaterials are described herein. The biomaterials are formed from a composition comprising at least a first and a second precursor molecule, wherein: i) the first precursor molecule is a poly(ethylene glycol) based polymer having x nucleophilic groups selected from the group consisting of thiol or amino groups, wherein x is greater than or equal to 2 ii) the second precursor molecule is of the general formula: A-[(C3H6O)n—(C2H4O)m—B]i wherein m and n are integers from 1 to 200 i is greater than 2 A is a branch point B is a conjugated unsaturated group The precursors are selected based on the desired properties of the biomaterial. Optionally, the biomaterials contain additives, such as thixotropic agents, radiopaque agents, or bioactive agents.Type: ApplicationFiled: January 16, 2015Publication date: May 14, 2015Inventors: Annemie Rehor, Simona Cerritelli
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Publication number: 20140357789Abstract: A sulfopolyester includes the reaction product of a diacid and a diol wherein the diacid includes at least 30 mole percent of one difunctional sulfomonomer containing at least one sulfonate group bonded to an aromatic ring wherein the functional groups are carboxyl or esters thereof and a diacid moiety which is not a sulfonated aromatic moiety. The sulfopolyester composition of the present invention has a charge density of greater than 1.0 meq/g polymer solids. Another aspect of the invention is a coating composition containing from 1 to 50 weight percent of the sulfopolyester.Type: ApplicationFiled: May 29, 2013Publication date: December 4, 2014Applicant: Eastman Chemical CompanyInventors: Scott Ellery George, Joshua Seth Cannon, Suzanne Winegar Dobbs, James Allen McCaulley
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Patent number: 8865313Abstract: The present invention relates generally to the field of organic chemistry and particularly to the optical retardation films for liquid crystal displays. The present invention provides an optical film comprising a substrate having front and rear surfaces, and at least one solid retardation layer on the front surface of the substrate.Type: GrantFiled: July 14, 2011Date of Patent: October 21, 2014Assignee: Crysoptix K.K.Inventor: Ellina Kharatiyan
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Publication number: 20140197359Abstract: An oxygen-scavenging composition includes a sulfide group-containing polyester and a catalyst. The sulfide group-containing polyester is obtained by subjecting a reaction composition to esterification and condensation reactions. The reaction composition includes an aromatic diacid component and a diol component including aliphatic diol and a diol compound represented by the following formula (I): HO—(X1—O)n—X3—S—X4—(O—X2)m—OH??(I) wherein X1 and X2 independently represent a C1-C6 alkylene group, X3 and X4 represent a C6-C10 arylene group, and m and n represent an integer ranging from 1 to 5. The catalyst is for inducing reaction between the sulfide group-containing polyester and oxygen.Type: ApplicationFiled: January 10, 2014Publication date: July 17, 2014Applicant: FAR EASTERN NEW CENTURY CORPORATIONInventors: Fa-Chen Chi, Yi-Hsuan Tang, Yu-Shiang Peng, Wen-Teng Chang
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Patent number: 8734952Abstract: The present invention relates generally to the field of organic chemistry and particularly to the optical retardation films for liquid crystal displays. The present invention provides an optical film comprising a substrate having front and rear surfaces, and at least one solid retardation layer on the front surface of the substrate.Type: GrantFiled: July 14, 2011Date of Patent: May 27, 2014Assignee: Crysoptix KKInventor: Ellina Kharatiyan
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Publication number: 20140039150Abstract: Disclosed are methods of fiber spinning and polymer fibers that utilize multifunctional thiol and enes compounds. Also, the subject matter disclosed herein relates to uses of polymer fibers and articles prepared from such fibers.Type: ApplicationFiled: April 6, 2012Publication date: February 6, 2014Applicant: BOARD OF REGENTS OF THE UNIVERSITY OF TEXAS SYSTEMInventors: Christopher Ellison, Kadhiravan Shanmuganathan
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Publication number: 20130232937Abstract: A spinnable, gel-free and thermally stable polyester composition includes at least one dicarboxylic acid or monoesters thereof or diesters thereof; at least one diol; at least one carboxylic acid anhydride; at least one sodium or lithium based aromatic co-monomer and at least one hydroxyl terminated polyester polyol. The polyester is produced by esterifying at least one dicarboxylic acid or monoesters thereof or diesters thereof and at least one diol along with at least one acid anhydride at a temperature in the range of 250° C. to 290° C. and pressure in the range of 0 kg/cm2g to 5 kg/cm2g; and polycondensing the esterified mixture along with at least one sodium or lithium based aromatic compound and at least one hydroxyl terminated polyether polyol at a temperature in the range of 250° C. to 290° C. and under vacuum of 0.1 torr to 10 torr.Type: ApplicationFiled: September 6, 2012Publication date: September 12, 2013Applicant: Reliance Industries LimitedInventors: Vikas Madhusudan Nadkarni, Santosh Raghavendra Huilgol, Shilpa Girish Nayak, Ashwin Kumar Jain, Makarand Renukadas Megde, Sanjay Kesarwani
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Patent number: 8378060Abstract: A composition of the formulae MZAORSnR1F1mOAZ1M1, wherein O and S have their normal meaning of oxygen and sulfur, n is at least 2 and not more than 8, F1 is of the formula —OAORSnR1—, m is at least 1, Z and Z1 are the same or different and are oxy or amino, M and M1 are the same or different and are hydrogen or an organic substituent, R and R1 are the same or different and are organic divalent radicals, each having from 2 to 20 carbon atoms, and A is the residue of a dicarboxylic acid of from 2 to 40 carbon atoms.Type: GrantFiled: March 22, 2012Date of Patent: February 19, 2013Assignee: POLYMERight, Inc.Inventors: Leonid Rappoport, Aleksander Yam, Alexander Vainer
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Patent number: 8279582Abstract: The present invention provides a conductive polymer suspension for providing a conductive polymer material having a high conductivity and a method for producing the same, and in particular, a solid electrolytic capacitor having a low ESR and a method for producing the same. The conductive polymer suspension can be is produced by: synthesizing a conductive polymer by chemical oxidative polymerization of a monomer giving the conductive polymer by using an oxidant in an aqueous solvent containing a dopant consisting of a low-molecular organic acid or a salt thereof, or a polyacid having a weight average molecular weight of less than 2,000 or a salt thereof.Type: GrantFiled: July 28, 2009Date of Patent: October 2, 2012Assignee: NEC Tokin CorporationInventors: Tomoki Nobuta, Ryuta Kobayakawa, Naoki Takahashi, Yasuhisa Sugawara, Satoshi Suzuki, Toshihiko Nishiyama
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Publication number: 20120177592Abstract: A method of developing degradable linear poly(ethylene glycol) PEG (DPEG) with multiple functioning capacities, which can be used as drug carriers for cancer cell delivery. A DPEG may be effective in targeting cancerous tumors through an enhanced permeation and retention effect (EPR). The DPEG will then degrade in the acidic extracellular fluid of solid tumors leading to fast cellular internalizations, finally degrading in the lysosome for efficient renal clearance. These may be used in conjunction with drugs and/or targeting groups. Furthermore, DPEGs are thermoresponsive, on an as needed basis, making them useful for in vivo application.Type: ApplicationFiled: May 30, 2008Publication date: July 12, 2012Applicant: UNIVERSITY OF WYOMINGInventors: Maciej Radosz, Youqing Shen
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Patent number: 8158726Abstract: The present invention provides poly(thioesters) and monomeric diesters, produced from di(hydroxyethyl)polysulfides and various mono- and di-basic carbonic acids or their anhydrides, and their derivatives. The new compounds combine properties of polyesters and polysulfides. The poly(thioesters) can be used as components in many compositions, including but not limited to adhesives, sealants, caulks, coatings, plastics, paints and elastomers. The monomeric diesters find use in compositions such as solvents and plasticizers.Type: GrantFiled: June 28, 2006Date of Patent: April 17, 2012Assignee: Polymeright, Inc.Inventors: Leonid Rappoport, Aleksander Yam, Alex Vainer
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Patent number: 8133592Abstract: A laminated adhesive thermoplastic resin film includes a laminated layer containing a polyester resin (A) and a polyester resin (B) different from each other in glass transition temperature and a melamine-based crosslinking agent (C) as components and having a surface energy of 48 to 55 mN/m, formed at least on one surface of the thermoplastic resin film, wherein the glass transition temperature of the polyester resin (A) is 110° C. or higher; the glass transition temperature of the polyester resin (B) is 60° C. to lower than 110° C.; and the amount of the melamine-based crosslinking agent (C) is 75 to 200 parts by weight per 100 parts by weight based on the weight of the polyester resin (A) and the polyester resin (B).Type: GrantFiled: February 14, 2008Date of Patent: March 13, 2012Assignee: Toray Industries, Inc.Inventors: Yasushi Takada, Mitsuhiro Horiuchi, Masato Yanagibashi
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Publication number: 20110269903Abstract: The present invention provides bis(hydroxyalkyl)mercaptosuccinates of the formula: and derivatives thereof, where X1, X2, Z1, Z2, Y1, Y2, Ra, Rb, R1, and R2 are those defined herein. The present invention also provides methods for producing and using the same.Type: ApplicationFiled: April 29, 2011Publication date: November 3, 2011Applicant: WYSIS TECHNOLOGY FOUNDATION, INC.Inventors: John P. Droske, Mark J. Juetten
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Patent number: 8026339Abstract: A polysulfone is provided with a nitrogen-containing functional group having an affinity to an acid, an electrolyte membrane using the polysulfone, and a fuel cell including the electrolyte membrane. In particular, the polysulfone includes a nitrogen-containing functional group that has an affinity to an acid, such as a phosphoric acid, thereby having an excellent acid retaining ability. In an electrolyte membrane including the polysulfone and an acid, the amount of the retained acid can be controlled. Therefore, the electrolyte membrane has a high ionic conductivity and a high mechanical strength. A polysulfone blend of polysulfone and a thermoplastic resin prevents the dissolution of polysulfone by phosphoric acid, so that an electrolyte membrane using the polysulfone blend has an improved durability. A cross-linked reaction product of polysulfone, a cross-linking agent and a polymerization product of polysulfone, a thermoplastic resin, and a cross-linking agent strongly resist a phosphoric acid.Type: GrantFiled: June 1, 2007Date of Patent: September 27, 2011Assignee: Samsung SDI Co., Ltd.Inventors: Chung-kun Cho, Myung-jin Lee, Myeong-soon Kang
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Publication number: 20110184130Abstract: A polyester production process employing an esterification system that utilizes a horizontally elongated esterification vessel as an esterification reactor and/or a vapor-liquid disengagement vessel.Type: ApplicationFiled: April 4, 2011Publication date: July 28, 2011Applicant: GRUPO PETROTEMEX, S.A. DE C.V.Inventor: Bruce Roger DeBruin
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Publication number: 20110152492Abstract: A composition comprising a reaction product of reactants comprising (a) a compound comprising (i) a polysulfide moiety and (ii) an oxygen atom in a ?-position to a sulfur link having the formula: where each R is independently selected from H or a C1 to C20 organyl group, R? is independently selected from a C1 to C20 organyl group, R?? is independently selected from H or a C1 to C20 organyl group, and x has an average of greater than 2, (b) a compound comprising a nucleophilic moiety; and (c) a compound comprising a moiety reactive to active hydrogen.Type: ApplicationFiled: June 25, 2010Publication date: June 23, 2011Applicant: POLYMERIGHT, INC.Inventors: Leonid RAPPOPORT, Alexander VAINER, Aleksander YAM
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Patent number: 7923526Abstract: A sulfopolyester comprising repeat residue units from the reaction product dimethyl-5-sodiosulfoisophthalate, isophthalic acid, 1,4-cyclohexanedimethanol and diethylene glycol, has at least one property selected from: a) an acidity of greater than 0.030 measured as milliequivalents H+/gram of sulfopolyester; b) a titanium concentration, measured as metal, of less than about 27 ppm, based on the amount of sulfopolyester; or c) an acidity of greater than 0.010 measured as milliequivalents H+/gram of sulfopolyester, a pH of less than 6.0 and a concentration of a base compound of less than 0.0335 moles/kg of sulfopolyester. A method for making the water-dispersible or water-dissipative sulfopolyester of the present invention is disclosed. Aqueous dispersion having from 0.001 to about 35 weight % of the sulfopolyester of the present invention is also disclosed. The sulfopolyester is useful in making hair spray formulations suitable for pump or aerosol spray applicators.Type: GrantFiled: July 29, 2005Date of Patent: April 12, 2011Assignee: Eastman Chemical CompanyInventors: Terry Ann Oldfield, Suzanne Winegar Dobbs, Scott Ellery George, Ricky Thompson, Edward Enns McEntire, George William Tindall
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Patent number: 7915374Abstract: Processes for producing polyethylene terephthalate copolyesters are disclosed, that include the steps of: esterifying a mixture of at least terephthalic acid, from 20 mole percent to 45 mole percent 1,4-cyclohexanedimethanol, and ethylene glycol, optionally in the presence of one or more alkaline earth metals or alkali metals, to form an oligomer; polycondensing the oligomer in the melt phase in the presence of aluminum and one or more alkaline earth metals or alkali metals, to obtain a copolyester having an intrinsic viscosity of at least 0.5 dL/g; and thereafter adding to the copolyester a phosphorus-containing compound.Type: GrantFiled: April 27, 2009Date of Patent: March 29, 2011Assignee: Eastman Chemical CompanyInventors: Jason Christopher Jenkins, Gary Wayne Connell, Howard Smith Carman, Jr., Douglas Weldon Carico, Jr., Jimmy Ray Trotter, Alan Wayne White, Mary Therese Jernigan, Rodney Scott Armentrout
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Publication number: 20100324605Abstract: High strength bioresorbable polymers suitable for orthopaedic applications comprising sulphonyl diphenol, hydroxybenzoic acid and dicarboxylic acid.Type: ApplicationFiled: March 23, 2007Publication date: December 23, 2010Applicant: SMITH & NEPHEW, PLCInventors: Anthony Dagger, De Oca Horacio Montes
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Patent number: 7834127Abstract: Disclosed are amorphous copolyesters having an inherent viscosity (IV) of about 0.5 to 1.1 dL/g measured at a temperature of 25° C. at 0.5 g/dL concentration in a solvent mixture of symmetric tetrachloroethane and phenol having a weight ratio of symmetric tetrachloroethane to phenol of 2:3 comprising (1) a diacid component comprising about 90 to 100 mole percent terephthalic acid residues and 0 to about 10 mole percent isophthalic acid residues; and (2) a diol component comprising about 10 to 70 mole percent 1,4-cyclohexanedimethanol residues and about 90 to 30 mole percent neopentyl glycol residues; wherein the amorphous copolyesters comprises 100 mole percent diacid component and 100 mole percent diol component. The amorphous copolyesters are useful in the manufacture or fabrication of medical devices which have improved resistance to degradation upon exposure to lipids, as a profile produced by profile extrusion and as an injection molded article.Type: GrantFiled: February 23, 2006Date of Patent: November 16, 2010Assignee: Eastman Chemical CompanyInventors: Sam Richard Turner, Jonathan Terrill Milburn, Robert William Seymour, Kab Sik Seo
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Patent number: 7700187Abstract: The invention relates to a biaxially oriented polyester film, preferably PET film, which has a hydrophilic coating on at least one surface. The coating composition used to form the hydrophilic coating includes water, a sulfopolyester, a surfactant, and optionally an adhesion-promoting polymer. The inventive films have a hydrophilic surface which inhibit condensation of water droplets on the films.Type: GrantFiled: October 10, 2006Date of Patent: April 20, 2010Assignee: Mitsubishi Polyester Film GmbHInventors: Matthias Konrad, Herbert Peiffer, Gottfried Hilkert
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Patent number: 7638590Abstract: The invention provides a novel polyester adapted for use in a charge control agent for a toner for an electrophotographic process, having a charge stability, a high charge amount, an improved dispersibility and a biodegradability, and a producing method and an application technology therefore.Type: GrantFiled: June 24, 2005Date of Patent: December 29, 2009Assignee: Canon Kabushiki KaishaInventors: Tatsuki Fukui, Tetsuya Yano, Chieko Mihara, Shinya Kozaki, Tsutomu Honma, Takashi Kenmoku, Ako Kusakari
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Patent number: 7521126Abstract: A readily-adhesive polyester film for optical applications that suppresses rainbow reflections under fluorescent lamps and has excellent adhesion to a hard coating layer and exhibits excellent adhesion at high temperatures and high humidities (resistance to humidity and heat) includes a biaxially-stretched polyester film and a coating layer that is stacked on at least one side of the polyester film and produced by applying to at least one side of the polyester film an aqueous coating liquid containing a resin composition including (A) an aqueous polyester resin and (B) at least one compound that is a water-soluble titanium chelate compound, a water-soluble titanium acylate compound, a water-soluble zirconium chelate compound or a water-soluble zirconium acylate compound as main components. The mixing ratio (A)/(B) is from 10/90 to 95/5 by weight. After that the coating is dried and then stretched in at least one direction.Type: GrantFiled: August 20, 2004Date of Patent: April 21, 2009Assignee: Toyo Boseki Kabushiki KaishaInventors: Hiroshi Taki, Chikao Morishige, Harunobu Kuroiwa
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Publication number: 20080167440Abstract: comonomers have been shown to improve flammability characteristics of polyesters and copolyesters. Incorporation of sulfonate containing monomers such as 5-sodiosulfoisophthalic acid significantly decreases the heat release capacity of copolyesters. These comonomers also increase the formation of char as measured by thermogravimetric analysis. The decrease in the heat release capacity and increase in char formation indicates that these compositions may have reduced flammability and thus are useful for producing products have reduced flammability. In particular, it has also been demonstrated that incorporation of as little as 0.1 mole % 5-sodiosulfoisophthalic acid to a polyester or copolyester significantly increases the char formation independent of composition.Type: ApplicationFiled: January 10, 2007Publication date: July 10, 2008Inventors: Deanna L. Pickel, Marc Alan Strand, Gether Irick, Douglas Stephens McWilliams, Michael Eugene Donelson
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Patent number: 7196157Abstract: Biodegradable aliphatic thermoplastic copolyesters of the saturated-unsaturated type, utilizable for the production of several types of articles such as films, sheets, nets, expanded molded products, and the like, and process for their production.Type: GrantFiled: October 21, 2004Date of Patent: March 27, 2007Assignee: Novamont S.p.A.Inventors: Catia Bastioli, Tiziana Milizia
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Patent number: 7189798Abstract: This invention relates to new cyclodextrin derivatives, processes for producing these cyclodextrin derivatives, and inclusion complexes comprised of the new cyclodextrin derivatives and guest molecules, as well as methods of making such materials and related materials and methods of using the same.Type: GrantFiled: June 24, 2003Date of Patent: March 13, 2007Assignee: Eastman Chemical CompanyInventors: Charles M. Buchanan, Steven N. Falling, Juanelle L. Lambert, Shannon E. Large, Jozsef Szejtli, Lajos Szente, Laszlo Jicsinszky
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Patent number: 7084213Abstract: A polymer composition comprising chains of at least one aromatic polymer or a mixture thereof together with at least one chain linking component wherein the at least one aromatic polymer comprises polymer chains of number average molecular weight (Mn) in a first range and characterised by a polymer flow temperature, and having at least one reactive end group, and wherein the at least one chain linking component comprises at least two linking sites, characterised in that a plurality of the polymer chain end groups are adapted to react with the linking sites at chain linking temperature in excess of the polymer flow temperature to form linked polymer chains of number average molecular weight (Mn) in a second range which is in excess of the first range, substantially thermoplastic in nature; process for the preparation thereof; prepreg, composite or shaped product obtained therewith and the use thereof.Type: GrantFiled: August 20, 2001Date of Patent: August 1, 2006Assignee: Cytec Technology Crop.Inventors: Patrick Terence McGrail, Jeffrey Thomas Carter
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Patent number: 6979719Abstract: The invention pertains to a coating composition comprising a compound comprising at least one bicyclo-orthoester group and at least one other functional group. The invention also comprises a process for curing the present coating composition. Further, a process for making a bicyclo-orthoester-functional compound from the corresponding oxetane compound is described.Type: GrantFiled: February 22, 2000Date of Patent: December 27, 2005Assignee: Akzo Nobel N.V.Inventors: Klaus Hobel, Huig Klinkenberg, Arie Noomen
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Patent number: 6872461Abstract: The invention relates to a co-extruded, biaxially oriented polyester films containing a flame-retardant agent which can be dissolved in the polyester. The film has a matt outer layer which contains a mixture and/or a blend of two components (I) and (II), whereby component (I) is a polyethylene terephthalate homopolymer, or a polyethylene terephthalate copolymer, or a mixture of polyethylene terephthalate homopolymers or copolymers and component (II) is a polymer containing at least one sulphonate group.Type: GrantFiled: January 10, 2001Date of Patent: March 29, 2005Assignee: Mitsubishi Polyester Film GmbHInventors: Ursula Murschall, Ulrich Kern, Guenther Crass, Gottfried Hilkert
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Patent number: 6872460Abstract: The invention relates to biaxially oriented, co-extruded polyester films. Said films comprise a base layer which consists of at least 70% by weight of a thermoplastic polyester, preferably polyethylene terephthalate (PET) with a diethylene glycol and/or polyethylene glycol content greater than 1.3% by weight and have at least one matt outer layer and optionally additional intermediate layers. The films also contain at least one UV-absorber, preferably hydroxy benzotriazoles and triazines. The films are characterized by high UV-stability, no embrittlement after exposure to temperature, a matt surface devoid of unwanted clouding and excellent thermoforming properties and are, together with the molded bodies produced therefrom, suitable for numerous interior and exterior applications.Type: GrantFiled: January 10, 2001Date of Patent: March 29, 2005Assignee: Mitsubishi Polyester Film GmbHInventors: Ursula Murschall, Ulrich Kern, Guenther Crass
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Patent number: 6869782Abstract: A polyhydroxyalkanoate that comprises a unit represented by the following chemical formula (1): wherein x is an integer of 1 to 8 being the same or different in the polyhydroxyalkanoate. The microbial production process is also disclosed.Type: GrantFiled: July 3, 2002Date of Patent: March 22, 2005Assignee: Canon Kabushiki KaishaInventors: Takashi Kenmoku, Etsuko Sugawa, Tetsuya Yano, Takeshi Imamura
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Patent number: 6828010Abstract: Provided is a laminated polyester film, in which a laminated layer comprising two types of polyester resins having different glass transition points from each other is formed on at least one side of a base polyester film wherein the two types of polyester resins are composed of a polyester resin (A) having a glass transition point of from 60° C. to 100° C., and a polyester resin (B) having a glass transition point of from 0° C. to 60° C. and the polyester resin (B) contains a specified component, and a dicarboxylic acid component having a sulfonic acid metal base is set as a specified ratio of the entire dicarboxylic acid components in the polyester resins (A) and (B), satisfies adhesiveness to various types of coating materials which has conventionally been incompatible and, further, satisfies anti-blocking properties, transparency, scratch resistance and the other properties.Type: GrantFiled: December 13, 2002Date of Patent: December 7, 2004Assignee: Toray Industries, Inc.Inventors: Yuri Kubota, Takashi Mimura, Yasushi Takada, Masato Yanagibashi
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Patent number: 6683132Abstract: Self-crosslinking aqueous coating compositions are disclosed comprising a water-dispersible alkyd having both sulfonate and acetoacetate functionality, a suitable bi- or poly-functional primary amine, and a monofunctional primary or cycloaliphatic secondary amine. The crosslinking of the composition includes oxidative curing via the fatty acid segments of the alkyd, and crosslinking via reaction between the acetoacetate groups of the alkyd and the primary amine groups of the polyfunctional amine. The aqueous alkyd systems disclosed do not require the presence of amines for the purpose of dispersing the alkyds, while exhibiting superior tack-free and through-dry times when used in coating compositions. Performance levels are achieved that heretofore had required increases in molecular weight and Tg, with a concomitant increase in VOC levels. Also disclosed are methods of making the inventive compositions.Type: GrantFiled: December 19, 2002Date of Patent: January 27, 2004Assignee: Eastman Chemical CompanyInventors: Martin Frederick Schick, Amy Lee Bolton, Thauming Kuo
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Silicone coated film with back side slip control coating and method of controlling slip of such film
Patent number: 6645615Abstract: The present invention relates to a self-supporting polymer film with a silicone-containing coating layer on the front surface that is capable of releasing free silicone oil and a slip control coating on the back surface, where the slip control coating has an exposed surface adapted to contact the free silicone oil. The slip control coating includes water soluble copolyester; and optionally includes a coupler, preferably a silane. A method for controlling the slip of silicone coated film by coating the back side of the film with this slip control coating is also disclosed.Type: GrantFiled: January 9, 2002Date of Patent: November 11, 2003Assignee: Mitsubishi Polyester Film, LLCInventors: John M. Heberger, Kenneth J. Muschelewicz -
Patent number: 6629833Abstract: A transparent conductive film (1) having a transparent plastic film (11) and a transparent conductive thin film (12) formed on at least one side thereof, characterized in that a resin layer (P) containing an ionic group in the range of 20 to 1000 eq/ton is provided between the transparent plastic film and the transparent conductive thin film and the ionic group containing resin has a cross-linked structure. The transparent conductive film has excellent adhesion to other conductive thin films and therefore exhibits excellent durability to input with a pen when used in touch panels.Type: GrantFiled: November 13, 2000Date of Patent: October 7, 2003Assignee: Toyo Boseki Kabushiki KaishaInventors: Toshiyuki Ohya, Tetsuo Shimomura, Yozo Yamada
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Patent number: 6627280Abstract: To provide a polyester hollow molded product which eliminates the possibility of contaminating its contents, retains excellent transparency after it is used repeatedly by recycling and can be re-used with a substantially unscratched surface. The polyester hollow molded product has a polyester coating layer on the exterior surface and the coating layer can be removed with hot water or alkaline aqueous solution.Type: GrantFiled: July 2, 2001Date of Patent: September 30, 2003Assignee: Teijin LimitedInventors: Minoru Suzuki, Hiroki Nagano
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Patent number: 6525165Abstract: An aromatic polyester film, which comprises an aromatic polyester comprising 2,6-naphthalenedicarboxylic acid as the main dicarboxylic acid component and 1,3-propanediol as the main diol component and having a density of at least 1.310 g/cm3. A laminated film comprising another polyester layer can be formed from this aromatic polyester film. An aromatic polyester containing a small amount of a sulfonic acid phosphonium salt used as one of the aromatic polyesters forming this laminated film is excellent in electrostatic casting properties and resistance to the contamination of an electrostatic wire, and an aromatic polyester containing an inorganic anti-fungus agent is used for antifungal application.Type: GrantFiled: January 3, 2001Date of Patent: February 25, 2003Assignee: Teijin LimitedInventors: Ryoji Tsukamoto, Takafumi Kudo, Masahiko Kosuge, Tomokatsu Ura, Hideshi Kurihara, Shinichi Kawai, Shinya Watanabe, Koji Furuya, Makoto Handa, Kenji Suzuki
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Patent number: 6468632Abstract: A method for coating the sawed edges of gypsum wallboard to prevent dusting of gypsum particles in clean rooms. The method includes applying a water-dispersible polymers to the sawed edges of gypsum wallboard. The polymer forms a water-insoluble salt through an ion exchange with the calcium found in gypsum wallboard. The result is a tough, tack free, fast-drying coating that substantially reduces the levels of airborne gypsum particles that come from the sawed edges of gypsum wallboards.Type: GrantFiled: December 6, 2000Date of Patent: October 22, 2002Assignee: National Gypsum Properties, LLCInventor: Daniel A. Winkowski
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Patent number: 6455142Abstract: The present invention provides a coated polymer film having an essentially streak-free coated surface that resists the formation of fog. The film includes a self-supporting polymer film layer, and an anti-fog coating on the film layer. The anti-fog coating, which can also be applied to alternate substrates, consisting essentially of a copolyester binder and an anionic surfactant, wherein the surfactant contains less than about 0.5 weight percent of a fluorosurfactant. A slip agent can also be included in the anti-fog coating.Type: GrantFiled: December 17, 1999Date of Patent: September 24, 2002Assignee: Mitsubishi Polyester Film, LLCInventors: John M. Heberger, Robin M. Donald, Jan C. Westermeier, F. Gene Funderburk, John G. Rollins
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Patent number: 6423774Abstract: The present invention is directed to an electrodepositable composition of a resinous phase dispersed in an aqueous medium. The resinous phase includes an ionic polyester polymer prepared from a) an aromatic and/or cycloaliphatic carboxylic acid compound having at least two aromatic and/or secondary aliphatic carboxyl groups, b) a branched aliphatic, cycloaliphatic or araliphatic compound containing at least two aliphatic hydroxyl groups, the aliphatic hydroxyl groups being either secondary or tertiary hydroxyl groups or primary hydroxyl groups attached to a carbon adjacent to a tertiary or quaternary carbon, c) a compound including an ionic salt group or a group which is converted to an ionic salt group, and d) optionally, at least one hydroxyl substituted carboxylic compound comprising at least one tertiary aliphatic carboxyl group and at least two aliphatic hydroxyl groups.Type: GrantFiled: March 21, 2000Date of Patent: July 23, 2002Assignee: PPG Industries Ohio, Inc.Inventors: Steven R. Zawacky, Raphael O. Kollah, Craig A. Wilson, Gregory J. McCollum, Robin M. Peffer, Geoffrey R. Webster, Jr., Venkatachalam Eswarakrishnan, Linda K. Anderson
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Patent number: 6380349Abstract: The present invention relates to golf equipment, such as golf shoes, golf clubs, golf gloves, or portions thereof, formed from compositions comprising a sulfonated, carboxylated, or phosphonated acid moieties, or a mixture thereof. The preferred ionomer composition comprises sulfonated thermoplastic elastomers, sulfonated thermoplastic polymers, sulfonated thermoset polymers, and mixtures thereof. The compositions include a blend of about 1 weight % to about 99 weight % of at least one sulfonated, carboxylated, or phosphonated ionomer and about 99 weight % to about 1 weight % of at least co-component polymer. The co-component polymer may be a conventional ionomer, a thermoplastic, a thermoplastic elastomer, a thermoset polymer, or mixtures thereof.Type: GrantFiled: December 13, 1999Date of Patent: April 30, 2002Assignee: Acushnet CompanyInventor: Murali Rajagopalan
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Publication number: 20010051706Abstract: This invention relates to water-dispersible sulfopolyesters comprising residues of (i) terephthalic acid; (ii) an amount sufficient to provide water-dispersibility to the sulfopolyester of at least one difunctional sulfomonomer containing at least one sulfonate group bonded to an aromatic ring; (iii) less than 5 mole % of at least one dicarboxylic acid that is not terephthalic acid or a sulfomonomer; (iv) 25 to 90 mole % of at least one polyethylene glycol having the structure:Type: ApplicationFiled: December 3, 1999Publication date: December 13, 2001Inventors: SCOTT E. GEORGE, BERNARD J. MENTRO, MICHAEL J. ABROSINI
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Patent number: 6287656Abstract: Amorphous copolyesters containing residues derived from 2,2′-[2,2-](sulfonylbis(4,1-phenyleneoxy))bis(ethanol). They exhibit enhanced heat distortion temperatures and glass transition temperatures without a significant increase in viscosity at low shear rates. The amorphous copolyesters also have improved resistance to attack by lipid solutions and are readily molded and extruded to form medial devices such as connectors, tubes, etc. which are useful for transport of lipids and other medical solutions.Type: GrantFiled: December 1, 2000Date of Patent: September 11, 2001Assignee: Eastman Chemical CorporationInventors: S. Richard Turner, Gary W. Connell, Bobby J. Sublett
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Patent number: 6183848Abstract: An amorphous copolyester having a maximum melt viscosity at 1 radian/second and at about 260 to about 290° C. of about 12000 poise, a glass transition temperature ranging from about 88° C. to about 120° C., and an inherent viscosity of at least about 0.6 dl/g. The amorphous copolyesters comprise the reaction product of a diol component and a dicarboxylic acid component. The diol component comprises residues of from about 5.0 to about 50 mole % of 2,2′-(sulfonylbis (4,1-phenyleneoxy))-bis(ethanol) which has the following chemical formula: and from about 50 to about 95 mole % of a mixture of at least two diols selected from the group consisting of ethylene glycol, neopentyl glycol, 1,3-propanediol, 1,4-butanediol, 1,4-cyclohexanedimethanol, and mixture thereof. The dicarboxylic acid component comprises residues of terephthalic acid, isophthalic acid, 1,4-cyclohexandedicarboxylic acid, 2,6-naphthalene dicarboxylic acid and mixtures thereof.Type: GrantFiled: April 28, 2000Date of Patent: February 6, 2001Assignee: Eastman Chemical CompanyInventors: S. Richard Turner, Bobby J. Sublett, Gary W. Connell
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Patent number: 6171685Abstract: Provided are water-dispersible sulfopolyester compositions having relatively large proportions of pigments and/or fillers. Such compositions are useful as packaging materials and are substantially non-blocking when processed using packaging rolls and are comprised of at least one sulfopolyester as described herein, about 10 to about 75 weight percent of a pigment and/or filler, and a wax.Type: GrantFiled: November 26, 1999Date of Patent: January 9, 2001Assignee: Eastman Chemical CompanyInventors: Scott Ellery George, Richard Anthony Miller, Jimmy Ray Trotter, Jayne Webb Lettich, Sammy Ray Repass
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Patent number: 6165701Abstract: A base film for photographic films formed from a copolyester comprising 97 to 100 mol % of 2,6-naphthalenedicarboxylic acid and 0 to 3 mol % of a dicarboxylic acid other than 2,6-naphthalenedicarboxylic acid and (i) 87 to 99.8 mol % of ethylene glycol, 0.2 to 10 mol % of bis[4-(.omega.-hydroxyalkoxy)phenyl]sulfone and 0 to 3 mol % of a glycol other than ethylene glycol and bis[4-(.omega.-hydroxyalkoxy)phenyl]sulfone or (ii) 97 to 100 mol % of ethylene glycol, 0 to 3 mol % of a diol other than ethylene glycol and 1 to 7 mol % of an oxycarboxylic acid. This base film has an endothermic peak having a peak top temperature, measured by a differential scanning calorimeter, of 120 to 160.degree. C. and showing an endothermic energy of 0.3 mJ/mg or more.Type: GrantFiled: November 14, 1997Date of Patent: December 26, 2000Assignee: Teijin LimitedInventors: Mitsuru Teramoto, Manabu Kimura, Shinya Watanabe, Koji Furuya, Kenji Suzuki
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Patent number: 6120889Abstract: The invention relates to an amorphous copolyester having a maximum melt viscosity at 1 radian/second and at about 260 to about 290.degree. C. of about 12000 poise, a glass transition temperature ranging from about 88.degree. C. to about 120.degree. C., and an inherent viscosity of at least about 0.6 dl/g. The amorphous copolyesters comprise the reaction product of a diol component and a dicarboxylic acid component. The diol component comprises residues of from about 5.0 to about 50 mole % of 2,2'-(sulfonylbis(4,1 -phenyleneoxy))-bis(ethanol) which has the following chemical formula: ##STR1## and from about 50 to about 95 mole % of a mixture of at least two diols selected from the group consisting of ethylene glycol, neopentyl glycol, 1,3-propanediol, 1,4-butanediol, 1,4-cyclohexanedimethanol, and mixture thereof. The dicarboxylic acid component comprises residues of terephthalic acid, isophthalic acid, 1,4-cyclohexandedicarboxylic acid, 2,6-naphthalene dicarboxylic acid and mixtures thereof.Type: GrantFiled: June 3, 1999Date of Patent: September 19, 2000Assignee: Eastman Chemical CompanyInventors: S. Richard Turner, Bobby J. Sublett
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Patent number: 6117532Abstract: An oriented polyester film coated on at least one surface with a coating that improves its adhesion to gelatin is disclosed. The dry coating contains one or more sulfopolyesters; one or more tetrablock copolymer resins; and one or more non-volatile polyamines. Other ingredients, such as particulate materials and surfactants, may be present in the coating. The coating is preferably applied at the interdraw stage.Type: GrantFiled: October 30, 1997Date of Patent: September 12, 2000Assignee: E. I. du Pont de Nemours and CompanyInventors: Junaid Ahmed Siddiqui, Cornell Chappell, Jr