Sulfur-containing Aryl Compound Patents (Class 528/295)
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Patent number: 9523007Abstract: A polymer composition comprising 1 to 99 wt % of a copolymer (A) and 99 to 1 wt % of a copolymer (B); the polymer composition used as a light emitting material of a light emitting device having high performances; Copolymers (A) and (B) being copolymers showing fluorescence in the solid state and having a polystyrene-reduced number average molecular weight of 103 to 108, and containing a repeating unit (a) and a repeating unit (b); Copolymer (A) has a relation of 100>XaA>5, where XaA (%) is a percentage of the mol number of repeating unit (a) based on the sum of the mol numbers of repeating units (a), and Copolymer (B) satisfies a relation of XaB?XaA?5, where XaB (%) is a percentage of the mol number of repeating unit (a) based on the sum of the mol numbers of repeating units (a) and (b).Type: GrantFiled: July 3, 2014Date of Patent: December 20, 2016Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Katsumi Agata, Takeshi Yamada
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Patent number: 9169334Abstract: This invention relates to a reaction product obtained by ring-opening metathesis polymerization of norbornene ketones functionalized with the residual portion of a vinyl terminated macromonomer.Type: GrantFiled: January 14, 2014Date of Patent: October 27, 2015Assignee: ExxonMobil Chemical Patents Inc.Inventors: Ian C. Stewart, David T. Harris
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Patent number: 9018336Abstract: A polymer of sulfonated poly(arylene ether)s (PAEs) and a manufacturing method thereof are provided. A main structure of the PAEs has a first side formed by multi-phenyl glycol monomer and a second side formed by multi-phenyl dihalo monomer with an electron-withdrawing group. The glycol monomer and the dihalo monomer are reacted with each other by a nucleophilic displacement reaction, so as to form the main structure of the PAEs. A film made of the PAEs has a better size stability under a high water uptake.Type: GrantFiled: January 26, 2014Date of Patent: April 28, 2015Assignee: National Sun Yat-sen UniversityInventors: Wen-yao Huang, Chun-Che Lee, Hsu-feng Lee, Steven Holdcroft
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Patent number: 8987407Abstract: A fuel cell catalyst layer having sulfonated poly(arylene ether)s and a manufacturing method therefor are provided. The manufacturing method includes steps of: providing at least one type of sulfonated poly(arylene ether)s; mixing the sulfonated poly(arylene ether)s with a catalyst composition to prepare a catalyst slurry; and coating the catalyst slurry to form a film which is dried to be an electrode catalyst layer, in which the weight ratio of the sulfonated poly(arylene ether)s is 5-50 wt %. The sulfonated poly(arylene ether)s in the electrode catalyst layer can provide good thermal stability, glass transition temperature, chemical resistance, mechanical properties, water impermeability, low proton transmission loss, and a relatively simple process to shorten the manufacturing time and lower the cost thereof.Type: GrantFiled: January 23, 2014Date of Patent: March 24, 2015Assignee: National Sun Yat-sen UniversityInventors: Wen-yao Huang, Chun-Che Lee, Hsu-feng Lee, Steven Holdcroft
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Patent number: 8945711Abstract: It is an object of the present invention to provide a water-based composite resin composition which has an excellent long-term storage stability and which enables formation of a coating film having an excellent water resistance and solvent resistance. The present invention relates to a water-based composite resin composition and a coating agent; the water-based composite resin composition containing composite resin particles (A) and an aqueous medium (B), the composite resin particles (A) containing polyester resin (a1) particles having a sulfonate group and an epoxy resin (a2) of which some or all parts are encapsulated in the polyester resin (a1) particles, wherein a mass ratio [(a1)/(a2)] of the polyester resin (a1) to the epoxy resin (a2) in the composite resin particles (A) is in the range of 95/5 to 30/70.Type: GrantFiled: March 9, 2012Date of Patent: February 3, 2015Assignee: DIC CorporationInventors: Tomokazu Higeshiro, Mitsuru Kitada
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Patent number: 8916674Abstract: A method for preparing series of terpolymer of poly (diphenyl ether sulfone) and poly (diphenyl ether diphenyl sulfone) comprises: adding high temperature organic solvent, stirring and heating; sequentially adding 4,4?-dihydroxydiphenyl, 4,4?-dichlorodiphenyl sulfone and 4,4?-Bis(4-chlorophenyl)sulfonyl-1,1?-biphenyl; after all the monomers are completely dissolved, heating to 100° C. and adding alkali metal carbonate salt-forming agent which is 5-10 mol % more than the amount of 4,4?-dihydroxydiphenyl added, and subsequently adding xylene; continuously heating and salt-forming reaction begins in the system, and controlling the temperature at 190˜210° C.; then heating to 230˜236° C., and maintaining for 3-4 hours to obtain polymer viscous liquid; and refining the polymer viscous liquid to obtain a terpolymer containing different structural units in the molecular chain, wherein the Tg of the terpolymer can be regulated by changing the ratio of the two dichloro-containing monomers.Type: GrantFiled: December 10, 2010Date of Patent: December 23, 2014Assignee: Kingfa Sci & Tech Co., Ltd.Inventors: Zhongwen Wu, Rongtang Ma, Xiangbin Zeng
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Publication number: 20140356787Abstract: A resist composition comprising a compound (m0) (wherein Rb1 represents an electron withdrawing group; Rb2 and Rb3 each independently represents an aryl group, an alkyl group or an alkenyl group, provided that Rb2 and Rb3 may be mutually bonded to form a ring with the sulfur atom; and X0? represents a monovalent counteranion).Type: ApplicationFiled: May 30, 2014Publication date: December 4, 2014Applicant: Tokyo Ohka Kogyo Co., Ltd.Inventors: Yoshitaka Komuro, Takaaki Kaiho, Toshiaki Hato, Akiya Kawaue, Junichi Tsuchiya, Yoshiyuki Utsumi
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Patent number: 8865313Abstract: The present invention relates generally to the field of organic chemistry and particularly to the optical retardation films for liquid crystal displays. The present invention provides an optical film comprising a substrate having front and rear surfaces, and at least one solid retardation layer on the front surface of the substrate.Type: GrantFiled: July 14, 2011Date of Patent: October 21, 2014Assignee: Crysoptix K.K.Inventor: Ellina Kharatiyan
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Publication number: 20140227516Abstract: A carbon fiber sizing agent imparts good bonding performance to carbon fiber, is used to reinforce a thermoplastic matrix resin, and provides a carbon fiber strand applied with the sizing agent and a fiber-reinforced composite reinforced with the carbon fiber strand. The sizing agent for carbon fiber is used to reinforce thermoplastic matrix resin. The sizing agent essentially contains a polymer component having a glass transition temperature of at least 20 deg.C. and exhibits no endothermic peaks indicating an endothermic heat of fusion due to crystalline melting of at least 3 J/g in a determination with a DSC. The weight ratio of the polymer component is 10 to 100 wt % of the nonvolatile components of the sizing agent. The polymer component is at least one component selected from the group consisting of an aromatic polyester resin, aromatic polyester-polyurethane resin and amine-modified aromatic epoxy resin.Type: ApplicationFiled: October 15, 2012Publication date: August 14, 2014Inventors: Yoshio Hashimoto, Yusuke Shimizu, Mikio Nakagawa
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Patent number: 8734952Abstract: The present invention relates generally to the field of organic chemistry and particularly to the optical retardation films for liquid crystal displays. The present invention provides an optical film comprising a substrate having front and rear surfaces, and at least one solid retardation layer on the front surface of the substrate.Type: GrantFiled: July 14, 2011Date of Patent: May 27, 2014Assignee: Crysoptix KKInventor: Ellina Kharatiyan
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Patent number: 8710176Abstract: A method of producing a sulfonated polyarylether block copolymer is provided. The method includes producing a sulfonated polyarylether block copolymer containing a hydrophobic segment having a structural unit represented by formula (5) and a hydrophilic segment having a structural unit having a sulfonic acid groups or derivative thereof incorporated into a structure represented by formula (6). A hydrophilic segment prepolymer having a sulfonic acid group in a potassium salt form and a hydrophobic segment prepolymer are block copolymerized. A proton conductor that includes the sulfonated polyarylether block copolymer is also provided.Type: GrantFiled: March 2, 2012Date of Patent: April 29, 2014Assignee: Ube Industries, Ltd.Inventors: Tetsuji Hirano, Nobuharu Hisano, Tatsuya Arai, Masayuki Kinouchi
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Publication number: 20140058059Abstract: A polyester has excellent thermostability with only a small reduction in intrinsic viscosity during melt molding. The polyester is obtained from a dicarboxylic acid, and/or an ester-forming derivative thereof, and a diol which contains 15 to 500 ppm of a 1,2-propanediol-derived component.Type: ApplicationFiled: August 24, 2012Publication date: February 27, 2014Inventors: Takuro Okubo, Youichiro Tanaka, Kunihiro Morimoto
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Publication number: 20140031511Abstract: A continuous polymerization process where one or more stirred vessels (intermittent reactor vessels) are employed in oligomer transfer line for mixing additives. An additive is added in the stirred vessel either as a solution or as slurry. The additive may or may not be reactive with the other monomer of the polyester molecule. The additive reacts with the monomer and incorporates in the polymer backbone in one of the embodiment. One or more further additives are mixed with the pre-reactor monomer mix and are charged in the first reactor or charged through the stirred vessel in the form of single slurry or solution or multiple slurries or solutions. Any further vessels employed provide higher residence time proportionate to output and use of such vessels in reactor system is independent of the any further additives.Type: ApplicationFiled: January 23, 2013Publication date: January 30, 2014Inventors: Uday Shankar AGARWAL, Ved Prakash MISHRA, Krishna Srinivas RAO, S. VENKATACHALAM, Rajiv DIXIT, Ashwin Kumar JAIN, Anil Krishna KELKAR
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Publication number: 20140018496Abstract: A sulfopolyester containing residues of 2,2,4,4-tetralkylcyclobutane-1,3-diol such as 2,2,4,4-tetramethylcyclobutane-1,3-diol is highly dispersible in water. This allows one to reduce the content of sulfonate groups or reduce the amount of ethylene glycol or other hydrophilic glycols to retain good water resistance in cured coatings. The sulfopolyester may also be a reaction product of a 2,2,4,4-tetralkylcyclobutane-1,3-diol along with 1,4-cyclohexanedimethanol, neopentyl glycol, or a mixture thereof with an acid component. Coating compositions may also contain these sulfopolyesters along with water and a polymer resin.Type: ApplicationFiled: September 13, 2013Publication date: January 16, 2014Applicant: EASTMAN CHEMICAL COMPANYInventors: Thauming Kuo, Phillip Bryan Hall
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Patent number: 8609783Abstract: The present invention relates to a blend of sulfo-modified copolyester wherein the diacid is aromatic or cyclic and polyglycolic acid. The blend of sulfo-modified copolyester and polyglycolic acid can be used to prepare containers with good transparency and high gas barrier properties. The preferred sulfo-modified copolyester composition comprises terephthalic acid, isophthalic acid and 5-sulfoisophthalic acid. A method of preparing a blend of sulfo-modified copolyester and polyglycolic acid is disclosed, as well as master batch processes. The present invention also relates to a method of making a container wherein the sulfo-modified copolyester is blended with the polyglycolic acid at an injection molding machine used to make preforms, which are then blown into bottles.Type: GrantFiled: October 6, 2006Date of Patent: December 17, 2013Assignee: Invista North America S.A.R.L.Inventor: Mehta Sanjay
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Publication number: 20130323505Abstract: A fiber made of a polyester copolymer (B), wherein the polyester copolymer (B) comprises a dicarboxylic acid component and a glycol component, and the dicarboxylic acid component comprises 75 mol % or more of a terephthalic acid component, 1.0 mol % to 3.5 mol % of component (a) derived from a compound represented by formula (I), 2.0 mol % to 10.0 mol % of a cyclohexane dicarboxylic acid component (b), and 2.0 mol % to 8.0 mol % of an aliphatic dicarboxylic acid component (c). This can afford a polyester fiber that exhibits deep color property to cation dyes and disperse dyes under a normal pressure environment and is superior in color fastness to washing and color fastness to light and can secure good spinnability.Type: ApplicationFiled: February 17, 2012Publication date: December 5, 2013Applicant: KURARAY CO., LTD.Inventors: Hitoshi Nakatsuka, Kazuhiko Tanaka, Kazuhide Oka, Daisuke Ohga, Shinya Kawakado
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Patent number: 8580872Abstract: A sulfopolyester containing residues of 2,2,4,4-tetralkylcyclobutane-1,3-diol such as 2,2,4,4-tetramethylcyclobutane-1,3-diol is highly dispersible in water. This allows one to reduce the content of sulfonate groups or reduce the amount of ethylene glycol or other hydrophilic glycols to retain good water resistance in cured coatings. The sulfopolyester may also be a reaction product of a 2,2,4,4-tetralkylcyclobutane-1,3-diol along with 1,4-cyclohexanedimethanol, neopentyl glycol, or a mixture thereof with an acid component. Coating compositions may also contain these sulfopolyesters along with water and a polymer resin.Type: GrantFiled: July 21, 2011Date of Patent: November 12, 2013Assignee: Eastman Chemical CompanyInventors: Thauming Kuo, Phillip Bryan Hall
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Patent number: 8519081Abstract: Polysulfone based polymer comprising a repeat unit represented by the following Chemical Formula 1 is provided: wherein, X, M1, M2, a, b, c, d, e, f, R1, R2, R3, R4 and n are as defined in the detailed description.Type: GrantFiled: April 9, 2010Date of Patent: August 27, 2013Assignees: Hyundai Motor Company, Dongjin Semichem Co., Ltd.Inventors: Ju Ho Lee, Dong II Kim, Jang-Bae Son, Hyung-Su Park, Inchul Hwang, Ki Yun Cho
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Patent number: 8512519Abstract: Sulfopolyester thermoplastic resins provide advantages in papermaking processes and in paper products including paperboard. Improvements in wet strength and dry strength of paper products are achieved by addition of sulfopolyester thermoplastic resins and cationic strength additives during the paper making process. The use of sulfopolyester thermoplastic resins in paper products also significantly enhances the repulpability of the paper.Type: GrantFiled: April 22, 2010Date of Patent: August 20, 2013Assignee: Eastman Chemical CompanyInventors: Rakesh Kumar Gupta, Daniel William Klosiewicz, Melvin Glenn Mitchell, Marvin Lynn Mitchell
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Patent number: 8487070Abstract: A sulfonated poly(arylene ether) copolymer that has a crosslinking structure in a chain of a polymer, a sulfonated poly(arylene ether) copolymer that has a crosslinking structure in and at an end of a chain of a polymer, and a polymer electrolyte film that is formed by using them are disclosed. According to the polycondensation reaction of the sulfonated dihydroxy monomer (HO—SAr1-OH), the none sulfonated dihydroxy monomer (HO—Ar—OH), the crosslinkable dihalide monomer (X—CM-X) and the none sulfonated dihalide monomer (X—Ar—X), the poly(arylene ether) copolymer in which the sulfonic acid is included is synthesized. The formed poly(arylene ether) copolymer has the crosslinkable structure in the chain of the polymer. In addition, by carrying out the polycondensation reaction in respects to the crosslinkable monohydroxy monomer or the crosslinkable monohalide monomer, the crosslinking can be formed at the end of the polymer.Type: GrantFiled: October 6, 2008Date of Patent: July 16, 2013Assignee: Gwangju Institute of Science and TechnologyInventors: Jae-Suk Lee, Myung-Hwan Jeong, Kwan-Soo Lee, Eun-Seon Park, Young-Mu Joe
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Patent number: 8420767Abstract: Disclosed herein is a polyarylene-based polymer, a preparation method for the same, and a polymer electrolyte membrane for fuel cell using the polymer. The polyarylene-based polymer, which is designed to have long side chains of a hydrophilic moiety and dense sulfonic acid groups, may improve the formation of ion channels when fabricating a polymer membrane and also ensures good chemical stability of the hydrophilic moiety and good dimensional stability against water. Further, the preparation method of the present invention simplifies production of the polymer, and polymer electrolyte membranes using the polymer exhibits improved properties as a polymer electrolyte membrane for a fuel cell, such as high proton conductivity, even under an atmosphere of low water uptake, and good dimensional stability against a long-term exposure to water.Type: GrantFiled: December 9, 2011Date of Patent: April 16, 2013Assignee: Hyundai Motor CompanyInventors: Inchul Hwang, Nak Hyun Kwon, Young Taek Kim, Dong Il Kim, Ju Ho Lee, Jang-Bae Son
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Publication number: 20130023604Abstract: A sulfopolyester containing residues of 2,2,4,4-tetralkylcyclobutane-1,3-diol such as 2,2,4,4-tetramethylcyclobutane-1,3-diol is highly water dispersible in water. This allows one to reduce the content of sulfonate groups or reduce the amount of ethylene glycol or other hydrophilic glycols to retain good water resistance in cured coatings.Type: ApplicationFiled: July 21, 2011Publication date: January 24, 2013Applicant: EASTMAN CHEMICAL COMPANYInventors: Thauming Kuo, Phillip Bryan Hall
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Patent number: 8349905Abstract: Disclosed herein is a proton-conducting polymer and uses thereof and, more particularly, a hydrocarbon-based proton-conducting polymer derived from a monomer having a multi-naphthyl group and comprising a plurality of acid groups on the side chain of the repeating unit, an electrolyte membrane comprising the polymer, a membrane-electrode assembly comprising the electrolyte membrane, and a fuel cell comprising the membrane-electrode assembly.Type: GrantFiled: December 9, 2011Date of Patent: January 8, 2013Assignee: Hyundai Motor CompanyInventors: Inchul Hwang, Nak Hyun Kwon, Young Taek Kim, Dong Il Kim, Ju Ho Lee, Jang-Bae Son
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Patent number: 8344091Abstract: A polymer represented by the following Formula 1, and a membrane-electrode assembly and a fuel cell system including the polymer: In the above Formula 1, definitions of the substituents are the same as in described in the detailed description.Type: GrantFiled: May 8, 2009Date of Patent: January 1, 2013Assignee: Samsung SDI Co. Ltd.Inventors: Sung-Guk An, Sung-Yong Cho, Sang-Il Han, Kie Hyun Nam
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Patent number: 8334358Abstract: The present invention relates to a sulfonated poly(arylene ether) copolymer, a manufacturing method thereof and a polymer electrolyte membrane for fuel cell using the same.Type: GrantFiled: October 29, 2010Date of Patent: December 18, 2012Assignee: Hyundai Motor CompanyInventors: Inchul Hwang, Ki Yun Cho, Dong Il Kim, Ju Ho Lee
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Publication number: 20120309665Abstract: The invention relates to polyesters, obtainable by means of polymerisation of the components including (a) one or more sulfo group-free aromatic dicarboxylic acids and/or salts thereof and/or anhydrides thereof and/or esters thereof, b) optionally one or more sulfo group-containing dicarboxylic acids, salts thereof and/or anhydrides thereof and/or esters thereof, c) 1,2-propylene glycol, d) ethylene glycol, e) one or more compounds of the formula (1) R1O(CHR2CHR3O)nH (1), where R1 is a linear or branched, saturated or unsaturated alkyl group having from 1 to 22 C atoms, R2 and R3, independently of one another, are hydrogen or an alkyl group having from 1 to 4 carbon atoms, and N is an integer of from 1 to 50, f) optionally one or more compounds of the formula (2) H—(OCH2CH2)m—SO3X (2), in which m is an integer from 1 to 10 and X is hydrogen or an alkali metal ion, and g); optionally one or more cross-linking polyfunctional compounds, provided that at least one of the components b) or f) is present, and providType: ApplicationFiled: November 24, 2010Publication date: December 6, 2012Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Roman Morschhaeuser, Barbara Duecker, Hans Juergen Scholz
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Patent number: 8324338Abstract: An oligomer removing agent for polyester-based fiber materials comprises a polyester copolymer which is obtained by polycondensation of a dibasic acid component containing 15-65 mol % of a sulfonate group-containing dibasic acid and a dihydric alcohol component containing polyethylene glycol with a molecular weight of 900-3500, and which has a 200° C. melt viscosity of 5000-23,000 mPa·s and has 10-40 mass % polyoxyethylene chains in the molecule. The oligomer removing agent is able to overcome the problems caused by deposition of polyester oligomers, when added to the dyeing bath in a dyeing step for polyester fiber materials or for fiber materials that are composites thereof with other fiber materials.Type: GrantFiled: January 21, 2011Date of Patent: December 4, 2012Assignee: Nicca Chemical Co., Ltd.Inventors: Masaaki Hosoda, Masatoshi Hayashi
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Patent number: 8288500Abstract: The present invention relates to a sulfonated poly(arylene ether) copolymer, a manufacturing method thereof and a polymer electrolyte membrane for fuel cell using the same.Type: GrantFiled: November 2, 2010Date of Patent: October 16, 2012Assignee: Hyundai Motor CompanyInventors: Ju Ho Lee, Dong Ii Kim, Nak Hyun Kwon, Inchul Hwang
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Patent number: 8222367Abstract: A proton conducting hydrocarbon-based polymer has acid groups on side chains attached to the main chain, where the acid groups are between 7 and 12 atoms away from the main chain. Another polymer includes a semi-fluorinated aromatic hydrocarbon main chain and side chains that include at least one —CF2— group and an acid group. Another polymer includes an aromatic hydrocarbon main chain and side chains that include at least one —CH2-CF2— group and an acid group. Another aromatic polymer includes acid groups attached to both the main chain and the side chains where less than about 65 weight percent of the acid groups are attached to the side chains. Another aromatic polymer includes side chains attached to the main chain that include at least one aryl ring, and acid groups attached to both the main chain and to the aryl groups. Another polymer includes an aliphatic hydrocarbon main chain, side chains that include at least one deactivating aryl ring, and acid groups attached to the deactivating aryl rings.Type: GrantFiled: September 29, 2006Date of Patent: July 17, 2012Assignee: Battelle Memorial InstituteInventors: Ramanathan S. Lalgudi, Bhima R. Vijayendran, Jeffrey Cafmeyer, Jay R. Sayre
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Patent number: 8163385Abstract: Disclosed are multicomponent fibers derived from a blend of a sulfopolyester with a water non-dispersible polymer wherein the as-spun denier is less than about 6 and wherein the water dispersible sulfopolyester exhibits a melt viscosity of less than 12,000 poise measured at 240° C. at a strain rate of 1 rad/sec, and wherein the sulfopolyester comprising less than about 25 mole % of residues of at least one sulfomonomer, based on the total moles of diacid or diol residues. The multicomponent fiber is capable of being drawn at a relatively high fiber speed, particularly at least about 2000 m/min, and may be used to produce microdenier fibers. Fibrous articles may be produced from the multicomponent fibers and microdenier fibers. Also disclosed is a process for multicomponent fibers, nonwoven fabrics, and microdenier webs.Type: GrantFiled: December 22, 2010Date of Patent: April 24, 2012Assignee: Eastman Chemical CompanyInventors: Rakesh Kumar Gupta, Scott Ellery George, Daniel William Klosiewicz, Kab Sik Seo, Coralie McKenna Fleenor, Allen Lynn Crain
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Patent number: 8163864Abstract: The invention relates to the field of polymer chemistry and relates to sulfonated polyarylene compounds such as can be used for example in ion exchange membranes in fuel cells, as well as a method for the production thereof and the use thereof. The object of the present invention is to disclose hydrolytically and thermally resistant sulfonated polyarylene compounds with a defined degree and position of sulfonation, from which membrane materials with an improved resistance to hydrolysis can be produced. The object is attained through sulfonated polyarylene compounds according to at least one of the general formulas (I)-(IV).Type: GrantFiled: July 13, 2007Date of Patent: April 24, 2012Assignee: Leibniz-Institut fuer Polymerforschung Dresden E.V.Inventors: Dieter Lehmann, Jochen Meier-Haack, Claus Vogel, Wladimir Butwilowski
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Publication number: 20120094050Abstract: The invention relates to active oxygen-scavenger based polymer resin composition for oxygen barrier, a process for preparing such composition and articles such as bottles or other format of packaging. These compositions have an ability to consume an amount of oxygen and thereby deplete the level of the same from the immediate atmosphere surrounding the packaged content and at ambient temperatures.Type: ApplicationFiled: November 4, 2011Publication date: April 19, 2012Applicant: RELIANCE INDUSTRIES LIMITEDInventors: Uday Shankar Agarwal, B. V. Venkatakrishnan, Rajesh Jalan, Thaliyil Veedu Sreekumar, Srinivasacharya Ramacharya Ayodhya, Ashwin Kumar Jain, Shrivamurthy Padadayya Jadimath
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Patent number: 8133592Abstract: A laminated adhesive thermoplastic resin film includes a laminated layer containing a polyester resin (A) and a polyester resin (B) different from each other in glass transition temperature and a melamine-based crosslinking agent (C) as components and having a surface energy of 48 to 55 mN/m, formed at least on one surface of the thermoplastic resin film, wherein the glass transition temperature of the polyester resin (A) is 110° C. or higher; the glass transition temperature of the polyester resin (B) is 60° C. to lower than 110° C.; and the amount of the melamine-based crosslinking agent (C) is 75 to 200 parts by weight per 100 parts by weight based on the weight of the polyester resin (A) and the polyester resin (B).Type: GrantFiled: February 14, 2008Date of Patent: March 13, 2012Assignee: Toray Industries, Inc.Inventors: Yasushi Takada, Mitsuhiro Horiuchi, Masato Yanagibashi
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Patent number: 8084568Abstract: The present invention relates to a poly(arylene ether) copolymer having an ion exchange group, particularly a positive ion exchange group, a method for manufacturing the same, and use thereof. In the poly(arylene ether) copolymer having the ion exchange group according to the present invention, physical characteristics, ion exchanging ability, metal ion adsorption ability and a processability are excellent, and thus the copolymer can be molded in various shapes and can be extensively applied to various fields such as recovering of organic metal, air purification, catalysts, water treatment, medical fields and separating of proteins.Type: GrantFiled: December 6, 2010Date of Patent: December 27, 2011Assignee: Hyundai Motor CompanyInventors: Inchul Hwang, Nak Hyun Kwon, Young Taek Kim, Dong Il Kim, Ju Ho Lee
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Publication number: 20110229674Abstract: The polymerization processes described herein provide methods for controlling the dehydration of glycols such that dimers are formed as glycol ethers and incorporated into aliphatic-aromatic copolyetheresters during polycondensation. Control over this phenomenon provides unique polymer compositions with a range of thermo-mechanical properties, crystallinity, bio-content and biodegradability.Type: ApplicationFiled: December 14, 2009Publication date: September 22, 2011Applicant: E.I. DuPont De Nemours and CompanyInventor: Mark F. Teasley
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Patent number: 8012571Abstract: The present invention relates to multilayer optical films and birefringent copolyester films. The birefringent copolyester optical layer or birefringent copolyester film comprises a major amount of naphthalate units, ethylene units, and a minor amount of branched or cyclic C4 to C10 alkyl units. Also described are certain copolyester polymeric materials further comprising subunits of a phthalate ionomer such as dimethyl sulfosodium isophthtalate ionomer.Type: GrantFiled: May 2, 2008Date of Patent: September 6, 2011Assignee: 3M Innovative Properties CompanyInventors: Yufeng Liu, David T. Yust, Stephen A. Johnson, Kristopher J. Derks
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Publication number: 20110206883Abstract: The polymerization processes described herein provide methods for dehydrating diols such that dimers of the diols are formed and incorporated into polyesters during polycondensation. Control over this phenomenon provides unique polymer compositions with a range of thermo-mechanical properties, crystallinity, bio-content and biodegradability. Generation of a wide range of properties allows development of polymers that can be used for a wide range of applications.Type: ApplicationFiled: December 14, 2009Publication date: August 25, 2011Applicant: E.I. DUPONT DE NEMOURS AND COMPANYInventors: Noel M. Hasty, Edward J. Stancik
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Patent number: 7947800Abstract: A sulfonated poly(aryl ether) (SPAE) having a poly(aryl ether) (PAE) main chain and a sulfonated phenyl group pendent from the main chain are useful in proton exchange membranes (PEMs), particularly for fuel cells. The pendent phenyl group can provide an easily sulfonable site that may be sulfonated under mild conditions, providing the ability to precisely control the sulfonic acid content of the SPAE.Type: GrantFiled: July 13, 2007Date of Patent: May 24, 2011Assignee: National Research Council of CanadaInventors: Baijun Liu, Michael D. Guiver, Gilles P. Robertson
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Publication number: 20110097530Abstract: Non-sulfonated aliphatic-aromatic polyester compositions having improved thermal properties and biodegradability, and articles such as films, coatings and laminates, produced from the non-sulfonated aliphatic-aromatic polyester compositions, are provided.Type: ApplicationFiled: January 6, 2011Publication date: April 28, 2011Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventors: Rameshchandra M. Gohil, Noel M. Hasty, Richard Allen Hayes, Joseph V. Kurian, Yuanfeng Liang, Edward J. Stancik, Marko Strukelj, Susan Yen-Tee Tseng
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Patent number: 7923526Abstract: A sulfopolyester comprising repeat residue units from the reaction product dimethyl-5-sodiosulfoisophthalate, isophthalic acid, 1,4-cyclohexanedimethanol and diethylene glycol, has at least one property selected from: a) an acidity of greater than 0.030 measured as milliequivalents H+/gram of sulfopolyester; b) a titanium concentration, measured as metal, of less than about 27 ppm, based on the amount of sulfopolyester; or c) an acidity of greater than 0.010 measured as milliequivalents H+/gram of sulfopolyester, a pH of less than 6.0 and a concentration of a base compound of less than 0.0335 moles/kg of sulfopolyester. A method for making the water-dispersible or water-dissipative sulfopolyester of the present invention is disclosed. Aqueous dispersion having from 0.001 to about 35 weight % of the sulfopolyester of the present invention is also disclosed. The sulfopolyester is useful in making hair spray formulations suitable for pump or aerosol spray applicators.Type: GrantFiled: July 29, 2005Date of Patent: April 12, 2011Assignee: Eastman Chemical CompanyInventors: Terry Ann Oldfield, Suzanne Winegar Dobbs, Scott Ellery George, Ricky Thompson, Edward Enns McEntire, George William Tindall
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Patent number: 7834127Abstract: Disclosed are amorphous copolyesters having an inherent viscosity (IV) of about 0.5 to 1.1 dL/g measured at a temperature of 25° C. at 0.5 g/dL concentration in a solvent mixture of symmetric tetrachloroethane and phenol having a weight ratio of symmetric tetrachloroethane to phenol of 2:3 comprising (1) a diacid component comprising about 90 to 100 mole percent terephthalic acid residues and 0 to about 10 mole percent isophthalic acid residues; and (2) a diol component comprising about 10 to 70 mole percent 1,4-cyclohexanedimethanol residues and about 90 to 30 mole percent neopentyl glycol residues; wherein the amorphous copolyesters comprises 100 mole percent diacid component and 100 mole percent diol component. The amorphous copolyesters are useful in the manufacture or fabrication of medical devices which have improved resistance to degradation upon exposure to lipids, as a profile produced by profile extrusion and as an injection molded article.Type: GrantFiled: February 23, 2006Date of Patent: November 16, 2010Assignee: Eastman Chemical CompanyInventors: Sam Richard Turner, Jonathan Terrill Milburn, Robert William Seymour, Kab Sik Seo
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Publication number: 20100212804Abstract: A process for the production of a polymeric film comprising a copolyester having an acid component and a diol component, said acid component comprising a dicarboxylic acid and a sulfomonomer containing a sulfonate group attached to the aromatic nucleus of an aromatic dicarboxylic acid, said process comprising the steps of: (i) melt-extruding a layer of said copolyester; (ii) stretching the extrudate in at least one direction; (iii) heat-setting the film by raising the temperature of the stretched film to a temperature T1 in a first heating zone such that (TM?T1 is in the range of from 5 to 30° C., and then raising the temperature of the film to a temperature T2 in a second heating zone such that (TM?T2 is in the range of from 0 to 10° C.Type: ApplicationFiled: February 23, 2010Publication date: August 26, 2010Applicant: DuPont Teijin Films U.S. Limited PartnershipInventors: William Alasdair MacDonald, Pierre Georges Osborne Moussalli, Kenneth Evans, Jullian Peter Attard, David Boyce, Christopher Charles Naylor, Brian John Farmer, David Edward Robins
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Patent number: 7709594Abstract: A polyester composition produced without using an antimony compound as a polycondensation catalyst and including (I) composition containing, on a weight basis, 30 ppm or less of antimony, 0.5 to 50 ppm of titanium, and 0.1 to 100 ppm of phosphorus, in which the number density of titanium-containing particles, the equivalent circular diameter of which is 1?m or more, is less than 100/0.02 mg; and (II) a composition containing, on a weight basis, antimony, titanium and phosphorous as defined above, in which organic polymer particles are contained in amount of 0.1 to 5 wt%, the organic polymer particles having an average particle diameter determined by dynamic light scattering of 0.05 to 3?m and containing 0.01% or less of coarse particles relative to the total number of the particles, the coarse particles having a diameter at least twice the average particle diameter.Type: GrantFiled: October 3, 2003Date of Patent: May 4, 2010Assignee: TORAY Industries, Inc.Inventors: Jun Sakamoto, Masatoshi Aoyama, Yoshihiro Honma, Hitoshi Yoshimura, Yuzo Shimizu
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Patent number: 7700187Abstract: The invention relates to a biaxially oriented polyester film, preferably PET film, which has a hydrophilic coating on at least one surface. The coating composition used to form the hydrophilic coating includes water, a sulfopolyester, a surfactant, and optionally an adhesion-promoting polymer. The inventive films have a hydrophilic surface which inhibit condensation of water droplets on the films.Type: GrantFiled: October 10, 2006Date of Patent: April 20, 2010Assignee: Mitsubishi Polyester Film GmbHInventors: Matthias Konrad, Herbert Peiffer, Gottfried Hilkert
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Publication number: 20100022741Abstract: A copolymer of formula 1 in which M1 is a unit obtainable from ring opening metathesis polymerisation (ROMP); R is an alkyl, ether, ester or aryl unit; M2 and M3 are independently selected from units obtainable by reversible addition fragmentation chain transfer polymerization (RAFT); X is a terminal unit selected from the group consisting of dithioester, trithiocarbonate, xanthate; and m is an integer from 2 to 1 million, n is an integer from 2 to 500,000 and k is an integer from 2 to 500,000.Type: ApplicationFiled: November 2, 2007Publication date: January 28, 2010Inventors: Chong Cheng, Ezat Khoshdel, Karen Lynn Wooley
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Patent number: 7638590Abstract: The invention provides a novel polyester adapted for use in a charge control agent for a toner for an electrophotographic process, having a charge stability, a high charge amount, an improved dispersibility and a biodegradability, and a producing method and an application technology therefore.Type: GrantFiled: June 24, 2005Date of Patent: December 29, 2009Assignee: Canon Kabushiki KaishaInventors: Tatsuki Fukui, Tetsuya Yano, Chieko Mihara, Shinya Kozaki, Tsutomu Honma, Takashi Kenmoku, Ako Kusakari
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Patent number: 7635745Abstract: Processes for the recovery of a sulfopolyester polymer from an aqueous dispersion and a sulfopolyester concentrate are provided. Particularly, a sulfopolyester concentrate, from which the sulfopolyester may be recovered and reused, are formed by processes such as evaporation and/or nanofiltration. Final recovery of the sulfopolyester may be achieved by further evaporation of water and/or salt precipitation. In addition, the recovered sulfopolyester and articles manufactured from the recovered sulfopolyester are also provided.Type: GrantFiled: January 31, 2006Date of Patent: December 22, 2009Assignee: Eastman Chemical CompanyInventors: Rakesh Kumar Gupta, Allen Lynn Crain, Daniel William Klosiewicz, Scott Ellery George, Kab Sik Seo
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Patent number: 7625994Abstract: A sulfonated aliphatic-aromatic copolyetherester that comprises the polymerization product of 80.0 to 20.0 mole percent of an aromatic dicarboxylic acid or an ester thereof based on the total moles of dicarboxylic acid or ester thereof, 20.0 to 80.0 mole percent of an aliphatic dicarboxylic acid or an ester thereof based on the total moles of dicarboxylic acid or ester thereof, 0.1 to 10.0 mole percent of a sulfonate component, 99.9 to 91.0 mole percent of a first glycol selected from the group consisting of ethylene glycol, 1,3-propanediol and 1,4-butanediol based on the total moles of glycol, 0.1 to 4.0 mole percent of a poly(alkylene ether) glycol based on the total moles of glycol, 0 to 5.0 mole percent of an other glycol based on the total moles of glycol, and 0 to 5.0 mole percent of a polyfunctional branching agent.Type: GrantFiled: July 30, 2002Date of Patent: December 1, 2009Assignee: E.I. du Pont de Nemours and CompanyInventor: Richard Allen Hayes
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Publication number: 20090163402Abstract: A polyester textile softening agent comprising the reaction product of from about 1 to about 99 mole %, based on the total mole % of hydroxyl equivalents, of at least one glycol having a number average molecular weight of less than about 300 grams/mole; a difunctional sulfomonomer containing at least one metal sulfonate group bonded to an aromatic ring wherein the functional groups are ester, carboxyl, or hydroxyl in an amount to provide water dispersibility to the polyester; from about 1 to about 99 mole % a diacid other than a sulfomonomer; and from about 99 to about 1 mole % of a second glycol having a number average molecular weight greater than about 300 grams/mole. An aqueous dispersion comprising the textile softening agent and amount of water sufficient to disperse the textile softening agent is also disclosed.Type: ApplicationFiled: December 19, 2007Publication date: June 25, 2009Applicant: EASTMAN CHEMICAL COMPANYInventor: Scott Ellery George
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Publication number: 20090131628Abstract: A normal-pressure cation-dyeable polyester is provided which contains an isophthalic acid component having a metal sulfonate group in a predetermined proportion based on the total of acid components present in the polyester, and contains a polyalkylene glycol having an average molecular weight of 150 to 600 in a predetermined proportion based on the polyester, wherein the proportion of diethylene glycol based on the total of glycol components and a terminal carboxyl group concentration are each set within a predetermined range. The polyester is stable in quality and excellent in dark- and pale-color light fastness when used for textile products.Type: ApplicationFiled: March 2, 2006Publication date: May 21, 2009Applicant: KB SEIREN, LTD.Inventor: Keita Katsuma