Polycarboxylic Acid Reactant Which Is A Dimer Or Trimer Of An Ethylenically Unsaturated Aliphatic Monocarboxylic Acid Having At Least Ten Carbon Atoms; Or Adduct Of Said Unsaturated Monocarboxylic Acid With An Alpha, Beta Ethylenically Unsaturated Carboxylic Acid Or Derivative Patents (Class 528/295.3)
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Patent number: 9139729Abstract: It is provided that a resin composition for sealing electrical electronic components which is not susceptible to gelation even when stagnant under high temperature conditions, and which are excellent in initial bond strength to an aluminum material, and which exhibits superior durability under a cooling and heating cycle load and the like. It is also provided that a sealed electrical electronic component with the resin composition for sealing electrical electronic components. A resin composition for sealing electrical electronic components, containing a crystalline polyester-based elastomer (A), a phenol-modified xylene resin (B1) and/or a phenol resin (B2), and a polyolefin resin (C), and having a melt viscosity of 5 dPa·s or more and 3000 dPa·s or less when dried to a water content of 0.1% or less, heated to 220° C., subjected to a pressure of 1 MPa, and extruded through a die with a hole diameter of 1.0 mm and a thickness of 10 mm.Type: GrantFiled: February 21, 2012Date of Patent: September 22, 2015Assignee: TOYOBO CO., LTD.Inventors: Daiki Funaoka, Kenji Shiga
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Patent number: 8999503Abstract: A thermally removable pressure-sensitive adhesive sheet includes a substrate and a pressure-sensitive adhesive layer that is provided on at least one side of the substrate and made from a polyester-based pressure-sensitive adhesive composition containing a polyester including at least a lactic acid unit, a dibasic acid unit, and a glycol unit, a foaming agent, and a crosslinking agent. The dibasic acid unit includes a dimer acid, the polyester has a weight average molecular weight of 20,000 to 200,000 and a glass transition temperature of ?70 to ?20° C. as measured using a differential scanning calorimeter at a temperature rise rate of 20° C./minute, and the polyester has a hydroxyl value of 1 to 60 mgKOH/g.Type: GrantFiled: October 20, 2010Date of Patent: April 7, 2015Assignee: Nitto Denko CorporationInventors: Hitoshi Takahira, Satomi Yoshie
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Use, as a shock absorber, of a material formed from branched molecules containing associative groups
Patent number: 8975363Abstract: A shock absorber is prepared from a material formed from branched molecules comprising associative groups. The branched molecules each contains at least bifunctional fragments and at least trifunctional fragments joined together by ester or thioester bridges alone or in combination with amide or urea bridges.Type: GrantFiled: March 29, 2010Date of Patent: March 10, 2015Assignee: Arkema FranceInventors: Manuel Hidalgo, Nicolas Dufaure, Jean-Luc Couturier, Bruno Hemelryck -
Publication number: 20150050493Abstract: Provided are: a polyester-based pressure-sensitive adhesive composition which can be produced even from plant-derived raw materials with no need of using a costly silicone-based pressure-sensitive adhesive or the like and which is usable for producing a pressure-sensitive adhesive sheet excellent in wettability to an adherend, light peelability (removability), anti-staining property (little adhesive residues), and workability, and to provide a pressure-sensitive adhesive sheet using the composition. A polyester-based pressure-sensitive adhesive composition comprising a polyester obtained by condensation polymerization of at least a carboxylic acid component and a diol component, and a crosslinking agent, wherein the carboxylic acid component contains a dicarboxylic acid having a side chain in an amount of 50 to 90% by weight and a tricarboxylic acid having a side chain in an amount of 10 to 50% by weight, and wherein the polyester has a weight average molecular weight of 5000 to 150000.Type: ApplicationFiled: March 7, 2013Publication date: February 19, 2015Applicant: NITTO DENKO CORPORATIONInventors: Satomi Yoshie, Shigeki Ishiguro, Hiroki Senda
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Publication number: 20150031848Abstract: The present invention relates to a polyester polyol, suitable for use in the manufacture of a polyurethane, suitable for use in the manufacture of a polyurethane, the polyester polyol having an ABA-structure, in which A represents a lactide-oligomer and in which B represents an initiator. The initiator includes a reaction product having long chain dicarboxylic acid components having 18 or more carbon atoms. The invention also relates to a method for the manufacture of the polyester polyol. The invention further pertains to polyurethanes including the before-mentioned polyester polyol as well as the use of these polyurethanes as an elastomer having a high toughness. The toughness is believed to originate from the combination of the hydrophobic character of the initiator and the hydrophilic character of the lactide parts in the polyol structure. The strength of the invented polylactide-polyurethane elastomers can be further improved by incorporating a carbodiimide in the elastomer material.Type: ApplicationFiled: April 15, 2013Publication date: January 29, 2015Inventors: Wilhelmus Jacobus Adrianus Honcoop, Chris François Hubert Schaekens, Jurgen Cornelis Henricus Maas, Mauraline Alison Maxine Gumbs
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Patent number: 8932790Abstract: The toner includes a pigment; and a block copolymer having a polyester block A including a residual group of a hydroxycarboxylic acid, and a polyester block B including an anionic group. When cross-section of the block copolymer is observed by a tapping mode atomic force microscope to obtain a phase image of the cross-section, the polyester block B, which has relatively large phase delay, is dispersed as domains having an average size of from 20 nm to 100 nm in a domain of the polyester block A, which has relatively small phase delay. The block copolymer has a first glass transition temperature of from ?20° C. to 20° C., and a second glass transition temperature of from 35° C. to 65° C. when the first and second glass transition temperatures are determined from a thermogram obtained by subjecting the block copolymer to differential scanning calorimetry (DSC) at a temperature rising speed of 5° C./min.Type: GrantFiled: December 17, 2012Date of Patent: January 13, 2015Assignee: Ricoh Company, Ltd.Inventors: Yoshitaka Yamauchi, Masahide Yamada, Yoshihiro Moriya, Taichi Nemoto, Yukiko Nakajima, Keiji Makabe, Daiki Yamashita, Suzuka Amemori, Akiyoshi Sabu
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Publication number: 20140349109Abstract: A method for making a pressure sensitive adhesive comprising: (a) reacting (i) at least one dibasic acid or anhydride thereof with (ii) at least one epoxide having at least two epoxy groups, one diol or polyol, or one diamine at a stoichiometric molar excess of reactive carboxylic acid groups relative reactive epoxy groups, hydroxyl groups or amine groups to produce a thermoplastic prepolymer or oligomer capped with a carboxylic acid group at both prepolymer or oligomer chain ends, or a thermoplastic branched prepolymer or oligomer with at least two of the prepolymer or oligomer branches and chain ends capped with a carboxylic acid group; and (b) curing the resulting carboxylic acid-capped prepolymer or oligomer with at least one polyfunctional epoxy to produce a pressure sensitive adhesive, wherein the polyfunctional epoxy is not an epoxidized vegetable oil.Type: ApplicationFiled: December 5, 2012Publication date: November 27, 2014Applicants: State UniversityInventors: Kaichang Li, Anlong Li
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Patent number: 8889255Abstract: A radiation-cure removable type pressure-sensitive adhesive sheet includes: a pressure-sensitive adhesive layer made from a polyester-based pressure-sensitive adhesive composition containing a polyester including at least a lactic acid unit, a dibasic acid unit, and a glycol unit, a radiation-cure resin, a radiation reaction initiator, and a crosslinking agent. The dibasic acid unit includes a dimer acid, the polyester has a glass transition temperature of ?70 to ?20° C., a weight average molecular weight of 20,000 to 200,000, and a hydroxyl value of 1 to 60 mgKOH/g, the composition contains 30 to 70 parts by weight of the radiation-cure resin based on 100 parts by weight of the polyester and contains 3 to 10% by weight of the radiation reaction initiator based on the amount of the radiation-cure resin.Type: GrantFiled: October 20, 2010Date of Patent: November 18, 2014Assignee: Nitto Denko CorporationInventors: Hitoshi Takahira, Satomi Yoshie
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Publication number: 20130344764Abstract: A method for forming a biodegradable aliphatic polyester suitable for use in fibers is provided. In one embodiment, for example, an aliphatic polyester is melt blended with an alcohol to initiate an alcoholysis reaction that results in a polyester having one or more hydroxyalkyl or alkyl terminal groups. By selectively controlling the alcoholysis conditions (e.g., alcohol and polymer concentrations, catalysts, temperature, etc.), a modified aliphatic polyester may be achieved that has a molecular weight lower than the starting aliphatic polyester. Such lower molecular weight polymers also have the combination of a higher melt flow index and lower apparent viscosity, which is useful in a wide variety of fiber forming applications, such as in the meltblowing of nonwoven webs.Type: ApplicationFiled: August 28, 2013Publication date: December 26, 2013Applicant: Kimberly-Clark Worldwide, Inc.Inventors: Aimin He, James H. Wang
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Patent number: 8524036Abstract: The present invention relates to cost-effective and environmentally friendly polyester surfactants for use in flotation deinking. The improved ink collection of the present invention can result in deinked pulp of high quality and/or yields that has excellent brightness and effective residual ink concentration values.Type: GrantFiled: October 22, 2012Date of Patent: September 3, 2013Assignee: Kemira Chemicals, Inc.Inventors: Terrence Cotter, Scott Rosencrance, Robert Wilson
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Patent number: 8420745Abstract: A thermally curable solder resist composition for a flexible printed circuit board is provided. The solder resist composition includes (a) 50-100 parts by weight of an epoxy resin, wherein the epoxy resin includes at least an aliphatic polyester modified epoxy resin having formula (I) or (II), in which, each of R1 and R2, independently, is a C6-38 saturated or an unsaturated carbon chain, R3 is ether, phenyl, a C6-38 heterocyclic or C6-38 saturated carbon chain, n is an integer of 1-10 and the aliphatic polyester modified epoxy resin had a molecular weight of 1000-5000; (b) 1-10 parts by weight of a curing agent; and (c) 1-10 parts by weight of a catalyst.Type: GrantFiled: August 24, 2011Date of Patent: April 16, 2013Assignee: Industrial Technology Research InstituteInventors: Jhy-Long Jeng, Jeng-Yu Tsai, Shur-Fen Liu, Jinn-Shing King
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Patent number: 8389662Abstract: Disclosed herein is a polycarbonate polymer comprising: an isosorbide unit, a polysiloxane unit, and an aliphatic unit different from the isosorbide unit, wherein the isosorbide unit, polysiloxane unit, and aliphatic unit are each carbonate, or a combination of carbonate and ester units, the aliphatic unit different from the isosorbide unit is derived from an aliphatic oligomer having a molecular weight of 900 to 4000, and the calculated bio-content is greater than or equal to 40 weight percent, based on the total weight of the polycarbonate polymer.Type: GrantFiled: September 29, 2010Date of Patent: March 5, 2013Assignee: SABIC Innovative Plastics IP B.V.Inventors: Hans de Brouwer, Robert Dirk van de Grampel, Jan Henk Kamps, Jan-Pleun Lens, Hendrik Theodurus van de Grampel
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Patent number: 8377457Abstract: The present invention is directed to a series of polymeric glyceryl esters that have two different molecular weight ester chains, one solid and one liquid, which when combined into a single molecule make a polymer that is solid, and crosslinked by dimer acid. These products have very unique skin feel and water proofing properties. These materials find applications as additives to formulations in personal care products where there is a desire to have a structured film (provided by the solid fatty group) and flow properties, (provided by the liquid fatty group). These compounds by virtue of their unique structure provide outstanding skin feel.Type: GrantFiled: February 22, 2010Date of Patent: February 19, 2013Assignee: SurfaTech CorporationInventors: Kevin A. O'Lenick, Andrew J. O'Lenick, Anthony J. O'Lenick, Jr.
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Publication number: 20130037229Abstract: The present invention relates to cost-effective and environmentally friendly polyester surfactants for use in flotation deinking The improved ink collection of the present invention can result in deinked pulp of high quality and/or yields that has excellent brightness and effective residual ink concentration values.Type: ApplicationFiled: October 22, 2012Publication date: February 14, 2013Applicant: Kemira Chemicals, Inc.Inventor: Kemira Chemicals, Inc.
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Patent number: 8317973Abstract: The present invention relates to cost-effective and environmentally friendly polyester surfactants containing a condensation esterification product of a polyhydric alcohol, a multimeric acid, and at least one polyalkylene glycol for use in flotation deinking under traditional alkaline, reduced alkali, and true neutral deinking conditions. The polyester deinking surfactants of the present invention will effectively exhibit greater selectivity than traditional flotation deinking surfactants. In particular, the polyester deinking surfactants can give better foam control, improved yield, and no loss in ERIC reduction.Type: GrantFiled: November 11, 2009Date of Patent: November 27, 2012Assignee: Kemira Chemical, Inc.Inventors: Terrence Cotter, Scott W. Rosencrance, Robert Wilson
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Patent number: 8192727Abstract: The present invention is directed to a series of sorbitol esters that have two different molecular weight ester chains, one solid and one liquid, which when combined into a single molecule make a polymer that is solid, but has very unique flow properties. These materials find applications as additives to formulations in personal care products where there is a desire to have a structured film (provided by the solid fatty group) and flow properties, (provided by the liquid fatty group). These compounds by virtue of their unique structure provide outstanding skin feel.Type: GrantFiled: December 16, 2009Date of Patent: June 5, 2012Assignee: Surpa Tech CorporationInventors: Kevin A. O'Lenick, Andrew J. O'Lenick, Anthony J. O'Lenick, Jr.
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Patent number: 8163843Abstract: A description is given of the preparation of high molecular mass, crystalline copolyesters with high solubility in non-halogenated and non-aromatic solvents, and of their use in adhesives.Type: GrantFiled: January 8, 2008Date of Patent: April 24, 2012Assignee: Evonik Degussa GmbHInventors: Gabriele Brenner, Rene Koschabek, Georg Becker
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Patent number: 8143368Abstract: Hydrolytically degradable polymers in the form of biodegradable disposable medical devices for use in medicine and laboratories such as syringes, test tubes, catheters, tubing, trays, medical fabrics, and gloves are described. The devices are formed in whole or in part of a hydrolytically degradable polymer. In the preferred embodiment, the devices or structural components thereof degrade in a period of weeks to months, preferably within a year and more preferably within six months of exposure to aqueous solutions. Conventional hydrolytically degradable polymers may be utilized or these may be modified to increase mechanical or processing characteristics, for example, using a polyfunctional branching agent and/or a chain extending agent. In one embodiment, the hydrolytically degradable polymer is a member of a new class of polyesters comprising an aliphatic dicarboxylic acid, an aliphatic diol and optionally, one or more bifunctional fatty acids such as ricinoleic acid and/or castor oil.Type: GrantFiled: December 22, 2005Date of Patent: March 27, 2012Assignee: Massachusetts Institute of TechnologyInventors: Abraham J. Domb, Robert S. Langer
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Patent number: 8110650Abstract: Methods of making unsaturated polyester compositions are provided and include reacting: (i) plant and animal oil triglycerides, an alkyl ester of a saturated or unsaturated fatty acid or mixtures thereof; (ii) a difunctional, or polyfunctional glycol or mixtures thereof; (iii) a difunctional or polyfunctional acid, their anhydrides or alkyl esters and mixtures thereof; (iv) a strained cycloolefin; (v) a component(s) that function as a compound capable of initiating polymerization at high temperature and which is stable at room temperature; and (vi) low profile additives, fillers and reinforcements.Type: GrantFiled: July 19, 2011Date of Patent: February 7, 2012Assignee: Reichold, Inc.Inventors: Hildeberto Nava, Lianzhou Chen
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Patent number: 8106148Abstract: A series of resins were synthesized using a range of bio-based materials to control the molecular architecture, and therefore the properties, of the inventive resins. The utility of these resins was demonstrated in the formulation of powder coatings, such as ?-hydroxy amide crosslinked and hybrid types. Generally, the bio-based resins flowed out on heating faster than conventional petrochemically-based resins, allowing the use of lower temperatures in the curing oven than is typically possible and a more active catalyst system, especially in the carboxylic acid-epoxy crosslinked hybrid coatings formulations.Type: GrantFiled: March 20, 2006Date of Patent: January 31, 2012Assignee: Battelle Memorial InstituteInventors: Bhima R. Vijayendran, Jerry L. King, II, Katherine P. Mitchell, Michael C. Clingerman, Jeffrey T. Cafmeyer
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Patent number: 7985826Abstract: Unsaturated polyester compositions are disclosed that are obtainable by reacting: (i) plant and animal oil triglycerides, an alkyl ester of a saturated or unsaturated fatty acid or mixtures thereof; (ii) a difunctional, or polyfunctional glycol or mixtures thereof; (iii) a difunctional or polyfunctional acid, their anhydrides or alkyl esters and mixtures thereof; (iv) a strained cycloolefin; (v) a component(s) that function as a compound capable of initiating polymerization at high temperature and which is stable at room temperature; and (vi) low profile additives, fillers, and reinforcements. Also disclosed are methods for the preparation of the polyesters and the use of the polyesters in closed and open mold compositions such as sheet molding compound (SMC), bulk molding compounding (BMC), resin transfer molding (RTM), pultrusion, infusion, filament winding, and spray up.Type: GrantFiled: December 22, 2006Date of Patent: July 26, 2011Assignee: Reichhold, Inc.Inventors: Hildeberto Nava, Lianzhou Chen
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Patent number: 7897699Abstract: This invention relates to processes for the production of purified, partially esterified polyol fatty acid polyesters and the compositions derived from those processes. The purified, partially esterified polyol fatty acid polyesters of the present invention are particularly well suited for use in a variety of food, beverage, pharmaceutical, and cosmetic applications and comprise less than about 5% polyol; less than about 5 ppm of residual solvent; less than about 700 ppm of lower alky esters; less than about 5% of a soap and free fatty acid mixture; less than about 3% of ash; and have an acid value of less than about 6.Type: GrantFiled: September 7, 2004Date of Patent: March 1, 2011Assignee: The Procter & Gamble CompanyInventors: Jared John Schaefer, James Earl Trout
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Patent number: 7795371Abstract: A grind resin, a pigment dispersion, and a coating composition are provided. The grind resin comprises a reaction product of a dibasic acid, optionally a polybasic acid, a diol, optionally a polyol, and a fatty compound. The fatty compound has a fatty chain and two reactive groups reactive with at least one of the dibasic acid and the diol provided that ?5% of all acid groups are provided by the polybasic acid and <20% of all hydroxyl groups are provided by the polyol. The reaction product is substantially free from branching comprising the reaction product of acid groups or hydroxyl groups and the dibasic acid, polybasic acid, diol, polyol, or fatty compound. The pigment dispersion comprises a pigment and the grind resin. The coating composition comprises a vehicle resin, the pigment, the grind resin, and a cross-linking agent reactive with the vehicle resin and/or the grind resin.Type: GrantFiled: September 11, 2007Date of Patent: September 14, 2010Assignee: PPG Industries Ohio, Inc.Inventors: David E. Lindow, Mark P. Slawikowski
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Patent number: 7723459Abstract: The present invention is directed to a class of polyesters that are lightly crosslinked polyesters made by reacting polysorbate units (linked by the reaction of their hydroxyl groups) to the carboxyl group of dimer acid. As will become clear, lightly crosslinked as used herein relates to reactions in which there is an excess of hydroxyl groups on a molar basis to carboxylic groups on the dimer acid. The polymers and a contribute softness, lubricity and antistatic properties when applied to hair, skin, textile fiber and paper.Type: GrantFiled: October 31, 2007Date of Patent: May 25, 2010Assignee: Zenetech LLCInventors: Carter LaVay, Anthony J. O'Lenick, Jr.
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Patent number: 7638116Abstract: The present invention relates to a series of novel polyesters that are prepared by crosslinking polyglycerol and dimer acid. The nature of the water loving polyglycerol group as well as the fact that a C-36 fatty diacid is used in preparation of the products results in unique products.Type: GrantFiled: October 29, 2007Date of Patent: December 29, 2009Assignee: Zenitech LLCInventors: Carter LaVay, Anthony J. O'Lenick, Jr.
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Patent number: 7601793Abstract: A polyurethane composition containing (A) a urethane compound obtained by reacting 100 parts by weight of a polyol with a polyisocyanate such that the NCO/OH equivalent weight ratio is greater than 0.5 but smaller than 15, and (B) a compound selected from a linear olefin compound having at least 6 carbon atoms, an oligomer of a linear olefin compound having at least 6 carbon atoms or an epoxy compound of an oligomer of a linear olefin compound having at least 6 carbon atoms, wherein the content of said compound (B) per 100 parts by weight of said polyol is greater than 5 parts by weight but smaller than 400 parts by weight. This composition is a composition with no suspicions that it contains an endocrine-disrupting chemical.Type: GrantFiled: February 9, 2005Date of Patent: October 13, 2009Assignee: Idemitsu Kosan Co., Ltd.Inventors: Shintaro Suzuki, Yuichi Fukunaga, Haruhito Sato
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Publication number: 20090105377Abstract: A series of resins were synthesized using a range of bio-based materials to control the molecular architecture, and therefore the properties, of the inventive resins. The utility of these resins was demonstrated in the formulation of powder coatings, such as ?-hydroxy amide crosslinked and hybrid types. Generally, the bio-based resins flowed out on heating faster than conventional petrochemically-based resins, allowing the use of lower temperatures in the curing oven than is typically possible and a more active catalyst system, especially in the carboxylic acid-epoxy crosslinked hybrid coatings formulations.Type: ApplicationFiled: March 20, 2006Publication date: April 23, 2009Inventors: Bhima R. Vijayendran, Jerry L King, II, Katherine P. Mitchell, Michael C. Clingerman, Jeffrey T. Cafmeyer
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Patent number: 7452927Abstract: Sulfonated aliphatic-aromatic polyester compositions having improved thermal properties, and articles such as films, coatings and laminates, produced from the sulfonated aliphatic-aromatic polyester compositions, are provided. Some of the films are biocompostable. Films made from the sulfonated aliphatic-aromatic copolyesters can be used to make shaped articles, such as sheets, thermoformed containers, and coatings for, for example, films and other substrates. The sulfonated aliphatic-aromatic copolyesters are produced from a mixture of aromatic dicarboxylic acids, aliphatic dicarboxylic acids, certain glycols, and components containing alkali metal or alkaline earth metal sulfonate groups, such as a metal 5-sulfoisophthalic acid derivative.Type: GrantFiled: January 30, 2004Date of Patent: November 18, 2008Assignee: E. I. du Pont de Nemours and CompanyInventor: Richard Allen Hayes
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Patent number: 7192538Abstract: An antistatic composition containing various types of polymers such as a polyamide, an aliphatic polyester, an elastomer thereof and a polyurethane elastomer, and a metal salt in specific amounts, and preferably, an antistatic composition in which an additive component such as an organic compound which has an —{O(AO)n}— group (A represents an alkylene group having 2 to 4 carbon atoms, and n represents an integer of 1 to 7) and all molecular chain terminals of which are CH3 and/or CH2 groups is compounded as needed.Type: GrantFiled: March 1, 2001Date of Patent: March 20, 2007Assignees: Sanko Chemical Industry Co., Ltd., Riken Technos CorporationInventors: Noriaki Fujihana, Yoshiharu Tatsukami, Masaki Enomoto, Ikuo Ohkoshi
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Patent number: 7169860Abstract: Biodegradable block copolyesters obtained from crystalline blocks and amorphous blocks, wherein the repeating units of both blocks are of the dicarboxylic acid/diol type. Said copolyesters are characterized by a melting temperature equal to or less than 15% lower than the starting crystalline polymer temperature, and by increased tenacity that makes them particularly useful in the production of different types of objects.Type: GrantFiled: October 19, 2004Date of Patent: January 30, 2007Assignee: Novamont S.p.A.Inventors: Catia Bastioli, Giandomencio Cella, Tiziana Milizia
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Patent number: 7052764Abstract: A shaped article comprising poly[(trimethylene-co-dianhydrosugar ester) dicarboxylate] or poly(trimethylene-co-dianhydro-dicarboxylate having improved stability in the form of less change of Tg and reduced shrinkage upon storage at elevated temperature is disclosed.Type: GrantFiled: June 10, 2003Date of Patent: May 30, 2006Assignee: E. I. du Pont de Nemours and CompanyInventors: Jing-Chung Chang, Joseph V. Kurian
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Patent number: 7014574Abstract: Golf balls comprising thermoplastic, thermoset, castable, or millable elastomer compositions are presently disclosed. These elastomer compositions comprise reaction products of polyisocyanates and telechelic polymers having isocyanate-reactive end-groups such as hydroxyl groups and/or amine groups. These elastomer compositions can be used in any one or more portions of the golf balls, such as inner center, core, inner core layer, intermediate core layer, outer core layer, intermediate layer, cover, inner cover layer, intermediate cover layer, and/or outer cover layer.Type: GrantFiled: February 23, 2005Date of Patent: March 21, 2006Assignee: Acushnet CompanyInventors: Shenshen Wu, Shawn Ricci
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Patent number: 7005474Abstract: The invention discloses an acrylic acid-modified epoxy polyester resin and the preparation process thereof. The resin comprises 100 pbw of a copolymer (A) formed from an unsaturated fatty acid-modified polyester and a bisphenol A type epoxy resin, and 20-40 pbw of poly(meth)acrylic acid (ester) (B). The preparation process comprises the following steps: (1) alcoholyzing a drying oil with a polyol; (2) adding successively, to the product from step (1), a dibasic anhydride, a fatty acid containing a conjugated double bond and an epoxy resin, and esterifying to obtain an epoxy polyester; and (3) copolymerizing the epoxy polyester from step (2) and an acrylic monomer. This invention also provides a water-based emulsion containing said resin, and a water-based paint exhibiting excellent antirust property and having low production cost.Type: GrantFiled: March 11, 2002Date of Patent: February 28, 2006Assignee: Marine Research Institute of Chemical IndustryInventors: Fuchang Liu, Wenlin Liu, Peimin Hou, Yuanhao Xu
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Patent number: 6972123Abstract: The present invention deals with the certain castor polyesters that give high gloss when applied to the skin. Said ester are the reaction of the hydroxyl group of castor oil with less than one equivalent of a fatty acid then in a subsequently step the remainder of an equivalent of a diacid, in this case dimer acid.Type: GrantFiled: September 24, 2002Date of Patent: December 6, 2005Assignee: Zenitech LLCInventor: Anthony J. O'Lenick, Jr.
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Patent number: 6903157Abstract: A thickened aqueous coating composition (preferably paints and the like or adhesives) containing a film-forming polymeric binder which produces dried coatings having less sensitivity to water by using a thickener which is autoxidisable. Preferred autoxidisable moieties are provided by derivatives of long chain fatty acids of the type used in alkyd paints and association is the preferred thickener mechanism. The moieties may form part of a compound which can take part in a copolymerisation to form a polymeric backbone for the thickener and if the compound is not very soluble in water, the copolymerisation mixture is subjected to intensive agitation to form droplets of less than 500 nm which compensates for the lack of solubility. The thickener may serve as its own binder if sufficient amounts are used.Type: GrantFiled: July 19, 2001Date of Patent: June 7, 2005Assignee: Imperial Chemical Industries PLcInventors: Manish Sarkar, Stephane Patrick Belmudes
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Patent number: 6800275Abstract: The present invention is directed to a series of polyester compounds made from the reaction of (a) a difunctional hydroxy compound, specifically polyoxyalkylene glycols, (b) a difunctional carboxylic acid, specifically dimer acid and hydrogenated dimer acid, and (c) a capping carboxylic acid, which only contains one acid group. These compounds are very well suited to the preparation of products for the personal care market.Type: GrantFiled: March 11, 2003Date of Patent: October 5, 2004Assignee: Zenitech LLCInventor: Anthony J. O'Lenick, Jr.
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Patent number: 6737481Abstract: A polymer comprising poly(alkylene-co-dianhydrosugar ester) dicarboxylate and its preparation by reacting an alkylene diol, terephthalic acid, and a moiety of formula 1 X-Ia-(A-I)n-Ab-X Formula 1 wherein: A is the ester residue from an anhydrosugar alcohol or dianhydrosugar alcohol, I is the ester residue from a diacid or its dialkyl esters, X is H when linked to an A residue, OH when linked to an I residue derived from a dibasic acid, and OR when linked to an I residue derived from a dialkyl ester of the dibasic acid, R is a C1-C4 straight or branched chain alkyl group, a and b are independently 0 or 1, and n is 1 to 10 is disclosed.Type: GrantFiled: June 10, 2003Date of Patent: May 18, 2004Assignee: E. I. du Pont de Nemours and CompanyInventors: Joseph V. Kurian, Yuanfeng Liang
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Patent number: 6670429Abstract: A block copolyester comprises a hard segment and a soft segment, wherein the melting point of the copolyester is greater than or equal to 200° C., and the glass transition temperature of the copolyester is less than or equal to −40° C. The hard segment is preferably polyethylene terephthalate, polybutylene terephthalate, or polyethylene naphthalate. The soft segment is preferably formed from at least one dimer fatty acid and/or dimer fatty diol and/or equivalent thereof. The copolyester is especially suitable for use in automotive parts, particularly where thermal stability is required.Type: GrantFiled: December 31, 2002Date of Patent: December 30, 2003Assignee: Imperial Chemical Industries PLCInventors: Eric Appelman, Jeffrey Thomas Carter
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Patent number: 6670441Abstract: The present invention deals with the certain castor polyesters which give high gloss when applied to the skin. The ester are the reaction of the hydroxyl group of castor oil a fatty acid and a dimer acid.Type: GrantFiled: December 7, 2001Date of Patent: December 30, 2003Assignee: Zenitech LLCInventors: Anthony J. O'Lenick, Jr., Carter LaVay
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Patent number: 6485819Abstract: A copolyester of the reaction product of: (a) one or more aromatic dicarboxylic acids or an ester thereof; (b) one or more aliphatic dicarboxylic acids or an ester thereof; and (c) isosorbide. The polyesters are useful to form articles of increased biodegradability.Type: GrantFiled: December 19, 2000Date of Patent: November 26, 2002Assignee: E. I. du Pont de Nemours and CompanyInventor: Richard Allen Hayes
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Patent number: 6465063Abstract: Heat-shrinkable polyester films, each having a heat shrinkability of 40% or higher in the main shrinkage direction of the film after treatment in hot water at 80° C. for 10 seconds, the change of heat shrinkability in the main shrinkage direction of the film after treatment in hot water at 55-75° C. for 10 seconds before and after the film is left under an atmosphere at 40° C. for 160 hours being 15% or lower, exhibit beautiful shrinkage finish in appearance involving only rare occurrence of shrinkage spots, wrinkles, strains, folding and other defects during shrinkage in the step of shrinking with hot air, and in particular, exhibit a quite small lowering in shrinkage finish after a lapse of time for storage and have low spontaneous shrinkability; therefore, these films are suitably used for applications such as labels and cap seals.Type: GrantFiled: October 2, 2001Date of Patent: October 15, 2002Assignee: Toyo Boseki Kabushiki KaishaInventors: Satoshi Hayakawa, Maki Sato, Shoichi Gyobu, Norimi Tabota, Katsuya Ito
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Patent number: 6464828Abstract: Polyester water-based defoamers are prepared by reaction of a dimer fatty acid, a fatty acid and two different polyalkylene polyols, e.g. polypropylene glycol and polyethylene glycol. The resulting polyesters are readily dispersible in water to form a water-based macroemulsion in the absence of any oil or short chain alcohols. The macroemulsion is an effective defoamer in ground-wood and thermomechanical pulping operations.Type: GrantFiled: March 1, 2000Date of Patent: October 15, 2002Assignee: Callaway Chemical Corp.Inventor: Robert Furman
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Publication number: 20020115817Abstract: A copolyester of the reaction product of: (a) one or more aromatic dicarboxylic acids or an ester thereof, (b) one or more aliphatic dicarboxylic acids or an ester thereof, and (c) isosorbide. The polyesters are useful to form articles of increased biodegradability.Type: ApplicationFiled: December 19, 2000Publication date: August 22, 2002Inventor: Richard A. Hayes
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Patent number: 6368710Abstract: A sulfonated copolyester of the reaction product of: (a) one or more aromatic dicarboxylic acids or an ester thereof; (b) one or more aliphatic dicarboxylic acids or an ester thereof; (c) one or more sulfonated compound; and (d) isosorbide. The polyesters are useful to form articles of increased biodegradability.Type: GrantFiled: December 19, 2000Date of Patent: April 9, 2002Assignee: E. I. du Pont de Nemours and CompanyInventor: Richard Allen Hayes
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Patent number: 6346597Abstract: A process for preparing a polyester carbonate is provided. The process comprises the steps of: (I) reacting a diacid with a carbonic acid diester and a catalyst in the presence of a polycarbonate oligomer via melt condensation polymerization to form a pre-polymer; and (II) reacting the pre-polymer via solid state polymerization to form a polyester carbonate.Type: GrantFiled: December 27, 1999Date of Patent: February 12, 2002Assignee: General Electric CompanyInventors: Timothy Edward Banach, Gregory Ronald Gillette
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Patent number: 6342281Abstract: Heat-shrinkable polyester films suitable for label use, wherein the value of tan &dgr; for dynamic viscoelasticity in a main shrinkage direction of the film is 0.15 or higher at 65° C. and takes a maximum of 0.40 or higher at a temperature of 65° C. to 100° C. both inclusive, and the heat shrinkability in the main shrinkage direction of the film after treatment in hot water at 80° C. for 10 seconds is 30% or higher, have excellent shrinkage characteristics over a wide range of temperature extending from low temperatures to high temperatures, particularly in the low temperature range, which may cause only rare occurrence of shrinkage spots, wrinkles, strains, longitudinal sinking, and other defects during heat shrinkage, and which may further have excellent break resistance.Type: GrantFiled: January 26, 2001Date of Patent: January 29, 2002Assignee: Toyo Boseki Kabushiki KaishaInventors: Satoshi Hayakawa, Hideto Ohashi, Norimi Tabota, Maki Sato, Chikao Morishige
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Publication number: 20010014729Abstract: Heat-shrinkable polyester films suitable for label use, wherein the value of tan &dgr; for dynamic viscoelasticity in a main shrinkage direction of the film is 0.15 or higher at 65° C. and takes a maximum of 0.40 or higher at a temperature of 65° C. to 100° C. both inclusive, and the heat shrinkability in the main shrinkage direction of the film after treatment in hot water at 80° C. for 10 seconds is 30% or higher, have excellent shrinkage characteristics over a wide range of temperature extending from low temperatures to high temperatures, particularly in the low temperature range, which may cause only rare occurrence of shrinkage spots, wrinkles, strains, longitudinal sinking, and other defects during heat shrinkage, and which may further have excellent break resistance.Type: ApplicationFiled: January 26, 2001Publication date: August 16, 2001Inventors: Satoshi Hayakawa, Hideto Ohashi, Norimi Tabota, Maki Sato, Chikao Morishige
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Patent number: 6258897Abstract: Low molar mass polyester polyols having a weight-average molar mass M, of not more than 2000 g/mol, with hydroxyl numbers of from 80 to 300 mg/g and acid numbers of from 5 to 35 mg/g, comprising the stated mole fractions (in %=mol/100 mol) of structural units derived from: a) from 1 to 45% of aliphatic polycyclic polyhydroxy compounds having at least two hydroxyl groups per molecule, b) from 5 to 50% of branched aliphatic acyclic dihydroxy compounds, c) from 30 to 50% of aliphatic cyclic polycarboxylic acids, d) from 0 to 30% of aliphatic acyclic or monocyclic polyhydroxy compounds having three or more hydroxyl groups per molecule, and e) from 0 to 10% of polyfunctional compounds selected from aliphatic linear and monocyclic dihydroxy compounds, aliphatic linear and branched dicarboxylic acids, aromatic dicarboxylic acids and polycaboxylic acids having three or more carboxyl groups per molecule, and also f) from 0 to 10% of monofunctional units selected from monocarboxylic acids and monoalcohols,Type: GrantFiled: May 31, 2000Date of Patent: July 10, 2001Assignee: Vianova Resins AGInventors: Ulrich Epple, Ulrike Kuttler, Claudia Pietsch
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Patent number: 6248844Abstract: A polyester is provided which facilitates the separation of blood into light and heavy phases via centrifugation in a blood collection vessel. The polyester is useful as a component of a partitioning composition formulated to have appropriate specific gravity to be positioned intermediate the light and heavy blood phases during centrifugation. The polyester composition can be prepared with relative ease compared to prior art polyesters useful in blood partitioning compositions. The polyesters of this invention comprise a dicarboxylic acid member, a polymeric fatty acid, a diol member and a moiety having at least one polymerizable carbon—carbon double bond and at least one functional group capable of reacting with the ends of the polyester chain. The polyesters have a lower viscosity when synthesized and are later cured to increase their viscosity to the desired level.Type: GrantFiled: June 4, 1999Date of Patent: June 19, 2001Assignee: Henkel CorporationInventors: Jeffrey A. Gates, Michael S. Sharp
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Patent number: 6239189Abstract: A radiation-polymerizable composition contains at least one radiation curable acrylate resin oligomer prepared by reacting an alkoxylated polyol with a first acid component which includes an ethylenically unsaturated carboxylic acid; and a rheology modifier prepared by reacting a diepoxide with a second acid component which includes an ethylenically unsaturated carboxylic acid or reactive derivative thereof in the presence of a polyamide based on a polymerized fatty acid. The ethylenically unsaturated carboxylic acids of the first and second acid components are preferably acrylic acid or methacrylic acids. The diepoxide is preferably a diglycidyl ether such as bisphenol A. Colorants such as pigments or dyes optionally may be incorporated into the composition to form a printing ink which is curable by ultraviolet (UV) or electron beam radiation.Type: GrantFiled: March 27, 1998Date of Patent: May 29, 2001Assignee: Henkel CorporationInventors: Ramesh Narayan, Miguel Dones, Theresa Miller