Reactant Which Is A Fatty Acid Glycerol Ester, A Fatty Acid Or Salt Derived From A Naturally Occurring Glyceride, Tall Oil, Or A Fatty Acid Derived From Tall Oil Patents (Class 528/295.5)
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Patent number: 12077692Abstract: 1) An HMPSA composition comprising: from 20% to 50% by weight of a composition of styrene block copolymers; from 35% to 65% by weight of one or more tackifying resins; and from 7% to 25% by weight of a plasticizer consisting of a composition comprising a stand oil of a vegetable oil. 2) A multilayer system comprising: an adhesive layer (A) consisting of said HMPSA composition; a printable support layer (B) adjacent to the adhesive layer (A); and a nonstick protective layer (C), adjacent to the adhesive layer (A). 3) The use of said multilayer system for the manufacture of self-adhesive articles.Type: GrantFiled: February 13, 2020Date of Patent: September 3, 2024Assignee: BOSTIK SAInventors: Christophe Robert, Amandine Rafaitin, Lahoucine Idttalbe
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Patent number: 11891481Abstract: Compositions and methods related to the synthesis and application of poly(aryl ether)s are generally described.Type: GrantFiled: June 24, 2021Date of Patent: February 6, 2024Assignee: Massachusetts Institute of TechnologyInventors: Timothy Manning Swager, Zachary Smith, Francesco Maria Benedetti, Sheng Guo
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Patent number: 9695105Abstract: The invention relates to a process to prepare complex oligomeric structures obtained from vegetable oils. The process allows to use a mixture of triglycerides containing dicarboxylic acids produced by the oxidative cleavage of vegetable oils as a starting material, these oils being subjected to a step of heating (condensation) followed by a step of esterification with alcohols at temperatures up to 250° C.Type: GrantFiled: March 10, 2015Date of Patent: July 4, 2017Assignee: NOVAMONT S.P.A.Inventors: Catia Bastioli, Luigi Capuzzi, Francesca Digioia
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Patent number: 9475956Abstract: The present invention discloses powder coating compositions and to components and ingredients for incorporation therein, suitable for low temperature curing schedule and with excellent resistance to outside aging. The powder coating composition can be cured at a temperature from 140° C. to lead to a coating with excellent flow and high gloss. In one aspect of the invention, a composition having a polyester resin comprises 0.1 to 60 weight percent of mono or poly-functional satured or unsatured fatty acids of mixtures of them, 30 to 60 weight percent of an aromatic diacid or cycloalkyl diacids or anhydride 20 to 30 weight percent of aliphatic diol, 0 to 6 weight percent of aliphatic triol, 0 to 10 weight percent of isosorbide and isomers or cycloalkyl diol, 0 to 10 weight percent of C3-C12 aliphatic diacid, and with total weight percent of the monomers equal to 100.Type: GrantFiled: August 14, 2013Date of Patent: October 25, 2016Assignee: SYNTHOMER USA LLCInventors: Damiano Beccaria, Imir Bejko, Andrea Capra, Irene Panero, Alessandro Munari
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Patent number: 9296895Abstract: Disclosed herein are self-healing materials, which are smart materials that are capable of repairing themselves without any external intervention when they are damaged. The self-healing materials may be microencapsulated, for example in a one-capsule system or a two-capsule system, and damage to a matrix containing the microcapsules may rupture the microcapsules and cause the healing materials to be released into the site of damage, where it may polymerize and restore the functional capabilities of the matrix. The self-healing materials may be based on unsaturated multi-functional resins capable of oxygen-initiated cross-linking, and may include alkyd resins, such as alkyd resins that include one or more telechelic end groups.Type: GrantFiled: June 12, 2014Date of Patent: March 29, 2016Assignee: Autonomic Materials, Inc.Inventor: Gerald O. Wilson
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Patent number: 9290698Abstract: The invention provides for new flame retardant non-furan dicarboxylic acid (FDCA) based polyols; oligomers and polymers made from these new polyols with flame retardation properties; and methods of using them as a part or all of the flame retardation composition/material, such as foams and binders.Type: GrantFiled: July 15, 2011Date of Patent: March 22, 2016Assignee: Battelle Memorial InstituteInventors: Herman P. Benecke, Daniel B. Garbark
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Patent number: 9212124Abstract: Mixture of triglycerides obtained from vegetable oils comprising one or more of the following oligomeric structures: R4—[O—C(O)—R1—C(O)—O—CH2—CH(OR2)—CH2]n—O—R3 wherein R1 is selected from C2-C22 alkylenes, R2 is selected from one or more of the following groups consisting of C6-C24 dicarboxylic acid residues and C6-C24 monocarboxylic acid residues, R3 is selected from one or more of the following groups consisting of H, C6-C24 dicarboxylic acid residues and C6-C24 monocarboxylic acid residues, R4 is an alkyl group, n is an integer greater than or equal to 2, said C6-C24 dicarboxylic acid residues of R2 and R3 being esterified with monoalcohols and said mixture of triglycerides having a Numerical Average Molecular Weight (Mn) of between 800 and 10.000 Da.Type: GrantFiled: December 20, 2011Date of Patent: December 15, 2015Assignee: Novamont S.p.A.Inventors: Catia Bastioli, Luigi Capuzzi, Paolo Magistrali, Sebastia Gesti' Garcia
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Patent number: 9068091Abstract: Disclosed is a copolyester which is the reaction product of a mixture having from between 30 and 50 mol % of a first monomer being an isohexide; between 40 and 60 mol % of a second monomer being an aromatic dicarboxylic acid or a cycloaliphatic dicarboxylic acid; and between 1 and 20 mol % of a third monomer being an aliphatic diol, the copolyester having an acid number of between 10 and 50. Also disclosed is a process for preparing such copolyesters, a latex composition containing such a copolyester, a method for preparing such a latex composition and the use of a particular latex as an (ink-jet) ink.Type: GrantFiled: September 9, 2013Date of Patent: June 30, 2015Assignee: OCE TECHNOLOGIES B.V.Inventors: Ronald Hofstra, Roy W. N. Evers
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Publication number: 20150140196Abstract: A crystallization accelerator includes a polymer compound that includes, as constituent components, a C18-28 hydroxy saturated fatty acid, which respectively has a hydroxyl group and a carboxyl group at both terminals and may have one carbonyl group in the chain thereof, a glycerin and optionally a fatty acid. The polymer compound is obtained by polymerizing the constituent components to a molecular weight of 3,000 to 100,000.Type: ApplicationFiled: November 17, 2014Publication date: May 21, 2015Inventors: Tadayoshi SADAKANE, Yusuke HARA, Takashi YAMAGUCHI
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Publication number: 20150099830Abstract: Pressure sensitive adhesives produced from naturally occurring fats and oils are described. Also described are methods of producing the pressure sensitive adhesives. Generally, one or more naturally occurring fats or oils are epoxidized, and then reacted with certain alcohols or amines to thereby obtain the noted pressure sensitive adhesives.Type: ApplicationFiled: December 12, 2014Publication date: April 9, 2015Inventors: Carol A. KOCH, Charles R. WILLIAMS, Prakash MALLYA
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Publication number: 20150031828Abstract: The object of a present invention is an alkyd resin as well as the method for preparing such a resin, said alkyd resin comprising: a preferably biosourced, polyacid component or its preferably biosourced acid anhydride; a first polyol component, preferably biosourced, having at least two hydroxyl groups; a second biosourced polyol component having at least one 1,4:3,6-dianhydrohexitol unit; and a component based on biosourced oil or its corresponding biosourced fatty acid.Type: ApplicationFiled: February 1, 2013Publication date: January 29, 2015Inventors: Joël Roussel, Clothilde Buffe, Laura Crowther-Alwyn, Arnaud Verraes
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Patent number: 8895689Abstract: An alkyd resin formed by reacting waste cooking oil, one or more aromatic polycarboxylic acids, aliphatic polycarboxylic acids, or esterified polymerization products, and one or more polyols.Type: GrantFiled: July 17, 2008Date of Patent: November 25, 2014Assignee: Valspar Sourcing, Inc.Inventors: Thomas John Melnyk, Gregory B. Hayes
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Publication number: 20140221561Abstract: An alkyd surfactant which is effective in emulsifying alkyd resins is formed by copolymerization of at least one monomer having a hydrophilic group, at least one ethylenically unsaturated fatty acid or ester, and optionally, at least one polyol, and has a low degree of branching. Stable alkyd emulsions are formed by emulsification of alkyd resins with the alkyd surfactant. Since the alkyd surfactant has ethylenically unsaturated hydrophobe groups which can react with the alkyd resin during curing, the alkyd surfactant is not subject to migration, blooming or leaching from cured coatings.Type: ApplicationFiled: January 29, 2014Publication date: August 7, 2014Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Gary E. Spilman, Timothy J. Young, Robert W. Sandoval, Rebecca S. Ortiz, Martin C. Beebe, III, Ahmad Madkour
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Patent number: 8758644Abstract: An oxygen-scavenging component and methods for producing the oxygen-scavenging component are provided. The oxygen-scavenging component, which in preferred embodiments is suitable for use in packaging articles, includes an oxygen-scavenging group preferably having at least one double bond. The oxygen-scavenging component may be combined with a polymer and/or an oxidation catalyst to form an oxygen-scavenging composition.Type: GrantFiled: April 7, 2008Date of Patent: June 24, 2014Assignee: Valspar Sourcing, Inc.Inventors: Paul Share, Jeffrey Niederst, Richard H. Evans, Grant Schutte
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Patent number: 8716515Abstract: The present invention relates to a process for the preparation of polyether ester polyols starting from fatty acid esters and starter compounds having Zerewitinoff-active hydrogen atoms, and to their use in the production of solid or foamed polyurethane materials.Type: GrantFiled: October 15, 2009Date of Patent: May 6, 2014Assignee: Bayer MaterialScience AGInventors: Klaus Lorenz, Reinhard Albers, Frank Otto
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Patent number: 8691907Abstract: A water-borne stain blocking primer comprises a) from about 10 to about 30 wt % of a water-dispersible, hydrophobic alkyd resin having an acid number of less, than 40 KOH/g, b) from about 5 to about 30 wt % of a pigment, the pigment having an average aspect ratio of at least 3:3:1; c) from about 0.05 to about 3 wt % of a tannin chelation agent; d) from about 0 to about 20 wt % of a water-dispersible, hydrophobic free-radically polymerized copolymer; e) a hydrophobically modified associative rheology modifier in an amount effective to provide a water-borne primer having an ICI viscosity of from about 0.5 to about 3.0 poise; and a KU viscosity range of from about 80 to about 120 Krebs units; and f) water. The water-borne primer has a VOC content of less than 5%. Methods of preparing and using such water-borne stain blocking primers also are described.Type: GrantFiled: November 22, 2011Date of Patent: April 8, 2014Assignee: Valspar Sourcing, Inc.Inventors: Matthew S. Gebhard, Cynthia Baricos
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Publication number: 20140065428Abstract: Disclosed is a polymer which is prepared by reacting (a) dimer fatty acids with (b) at least one polyether of general structural formula (I) where R is a C3 to C6 alkylene radical and n is selected accordingly such that said polyether has a number-average molecular weight of 450 to 2200 g/mol, components (a) and (b) are used in a molar ratio of 0.7/2.3 to 1.3/1.7, and the resulting polymer has a number-average molecular weight of 1500 to 5000 g/mol and an acid number <10 mg KOH/g. Also disclosed is a pigmented aqueous basecoat material which comprises this polymer, and the use of said polymer in pigmented aqueous basecoat materials. It further relates to a method for producing multicoat paint systems, and also to the multicoat paint systems producible by means of said method. Moreover, the present invention relates to the refinish of defect areas on multicoat paint systems.Type: ApplicationFiled: August 28, 2013Publication date: March 6, 2014Inventors: Peter Hoffmann, Bernhard Steinmetz, Jorn Lavalaye, Hardy Reuter
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Patent number: 8552081Abstract: The present invention is a high modulus bio-based polymer plastic composition or mixture and methods of preparing the same. The composition is formed from the reaction of a bio-based epoxidized triglyceride oil, an energy activated catalyst and a bio-based non-aromatic cross-linking compound to form a structural polymer plastic. The bio-based epoxidized triglyceride oil is selected from a bio-based epoxidized triglyceride or a bio-based acrylated epoxidized triglyceride. The non-aromatic cross-linking compound is selected from itaconic acid or itaconic anhydride, and the energy activated catalyst is activated by UV radiation or heat.Type: GrantFiled: June 4, 2008Date of Patent: October 8, 2013Assignee: South Dakota School of Mines and TechnologyInventors: David A. Boyles, Mohammad S. Al-Omar
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Patent number: 8524036Abstract: The present invention relates to cost-effective and environmentally friendly polyester surfactants for use in flotation deinking. The improved ink collection of the present invention can result in deinked pulp of high quality and/or yields that has excellent brightness and effective residual ink concentration values.Type: GrantFiled: October 22, 2012Date of Patent: September 3, 2013Assignee: Kemira Chemicals, Inc.Inventors: Terrence Cotter, Scott Rosencrance, Robert Wilson
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Publication number: 20130197152Abstract: The invention relates to a polyester resin which is based on at least one fatty acid, with a zero oil length (0%) or an oil length of between 0 and 35%, with a weight ratio of oxidizable fatty acids (monoacids), relative to the overall fatty acids, of 0 or greater than 0 and ranging up to 1, and which is based on an acid component comprising, in addition to said fatty acid, from 30% to 85% by weight, relative to the total weight of said resin, of rosin and/or of derivatives thereof bearing at least one carboxylic acid function. The resin of the invention is used as binder in coatings and in particular in water-based coatings such as paints, varnishes and surface coatings, in the form of an aqueous dispersion of resin, with particular performance in terms of aqueous dispersibility, development of hardness over time in the absence of siccativating agent during drying, and of resistance to yellowing and to water.Type: ApplicationFiled: September 23, 2011Publication date: August 1, 2013Applicant: Arkema FranceInventors: Grégoire Herve, Patricia Beurdeley, Michael Kurczak
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Publication number: 20130017333Abstract: The invention relates to a polyester AB comprising moieties derived from di- or polyfunctional organic acid compounds A and moieties derived from di- or polyfunctional organic hydroxy compounds B, wherein the compounds A comprise “hard” acid compounds A1 having two or more acid groups per molecule, and soft acid compounds A2, and the compounds B comprise “hard” hydroxyfunctional compounds B1 having two or more hydroxyl groups per molecule, and soft hydroxyfunctional compounds B2, and coating compositions prepared from these with crosslinkers selected from the group consisting of isocyanates, capped isocyanates, aminoplast crosslinkers, and phenoplast crosslinkers, as well as their application in coating of metal substrates.Type: ApplicationFiled: November 22, 2010Publication date: January 17, 2013Applicant: Cytec Austria GmbHInventors: Roland Feola, Johann Gmoser, Oliver Etz
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Patent number: 8317973Abstract: The present invention relates to cost-effective and environmentally friendly polyester surfactants containing a condensation esterification product of a polyhydric alcohol, a multimeric acid, and at least one polyalkylene glycol for use in flotation deinking under traditional alkaline, reduced alkali, and true neutral deinking conditions. The polyester deinking surfactants of the present invention will effectively exhibit greater selectivity than traditional flotation deinking surfactants. In particular, the polyester deinking surfactants can give better foam control, improved yield, and no loss in ERIC reduction.Type: GrantFiled: November 11, 2009Date of Patent: November 27, 2012Assignee: Kemira Chemical, Inc.Inventors: Terrence Cotter, Scott W. Rosencrance, Robert Wilson
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Publication number: 20120059087Abstract: Pressure sensitive adhesives produced from naturally occurring fats and oils are described. Also described are methods of producing the pressure sensitive adhesives. Generally, one or more naturally occurring fats or oils are epoxidized, and then reacted with certain alcohols or amines to thereby obtain the noted pressure sensitive adhesives.Type: ApplicationFiled: August 16, 2011Publication date: March 8, 2012Inventors: Carol A. Koch, Prakash Mallya, Charles R. Williams
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Patent number: 8110650Abstract: Methods of making unsaturated polyester compositions are provided and include reacting: (i) plant and animal oil triglycerides, an alkyl ester of a saturated or unsaturated fatty acid or mixtures thereof; (ii) a difunctional, or polyfunctional glycol or mixtures thereof; (iii) a difunctional or polyfunctional acid, their anhydrides or alkyl esters and mixtures thereof; (iv) a strained cycloolefin; (v) a component(s) that function as a compound capable of initiating polymerization at high temperature and which is stable at room temperature; and (vi) low profile additives, fillers and reinforcements.Type: GrantFiled: July 19, 2011Date of Patent: February 7, 2012Assignee: Reichold, Inc.Inventors: Hildeberto Nava, Lianzhou Chen
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Patent number: 8106148Abstract: A series of resins were synthesized using a range of bio-based materials to control the molecular architecture, and therefore the properties, of the inventive resins. The utility of these resins was demonstrated in the formulation of powder coatings, such as ?-hydroxy amide crosslinked and hybrid types. Generally, the bio-based resins flowed out on heating faster than conventional petrochemically-based resins, allowing the use of lower temperatures in the curing oven than is typically possible and a more active catalyst system, especially in the carboxylic acid-epoxy crosslinked hybrid coatings formulations.Type: GrantFiled: March 20, 2006Date of Patent: January 31, 2012Assignee: Battelle Memorial InstituteInventors: Bhima R. Vijayendran, Jerry L. King, II, Katherine P. Mitchell, Michael C. Clingerman, Jeffrey T. Cafmeyer
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Patent number: 8097564Abstract: Oligoesters including residues of alk(en)yl succinic anhydrides and polyols having at least 3 OH groups, optionally further esterified with fatty acid residues are surfactants which can be used for emulsifiers or similar uses. The surfactants are usually made from C8 to C30 alk(en)yl succinic anhydride and polyols having at least 4 hydroxyl groups and are particularly of the formula (I): R1—[OR2O(O)C.C(HR3).(HR4)C.C(O)]m—R5 (I), where R1, R2, R3, R4, R5, R6, R7 and m have defined meanings. The surfactants are useful as emulsifiers, particularly oil in water emulsifiers.Type: GrantFiled: November 14, 2007Date of Patent: January 17, 2012Assignee: Croda International PLCInventors: Hanamanthsa Shankarsa Bevinakatti, Alan Geoffrey Waite
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Publication number: 20110319504Abstract: The invention relates to a method for processing mixtures of carboxylic acids obtained as hydrolysis products of suberin and cutin, particularly suberin and cutin isolated from birch bark, to give mono-, oligo- and polyesters, or corresponding ester-ethers, as well as the use of the products thus obtained as lubricants, fuel components, plasticizers, surface active agents, environmentally friendly agents for modifying wood, binders in coatings, adhesives, printing inks and composites, further in various cosmetic applications.Type: ApplicationFiled: September 8, 2011Publication date: December 29, 2011Applicant: VALTION TEKNILLINEN TUTKIMUSKESKUSInventors: Salme KOSKIMIES, Janne Hulkko, Pauliina Pitkänen, Nina Heiskanen, Jari Yli-Kauhaluoma, Kristiina Wähälä
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Patent number: 8039654Abstract: Disclosed is an esterification reaction product which is capable of gelling both an oil agent and a cyclic silicone or a volatile dimethylpolysiloxane, or both an oil agent and a nonvolatile dimethylpolysiloxane. Also disclosed are a gelling agent contacting the esterification reaction product, and a cosmetic preparation containing the esterification reaction product or the gelling product and having an excellent feeling of use. Specifically, the cosmetic preparation contains, as a gelling agent, an esterification reaction product which is obtained by esterifying a component A that is a polyhydric alcohol or a condensate thereof, a component B that is a saturated dibasic acid having 10-28 carbon atoms, a component C that is a linear saturated fatty acid having 16-28 carbon atoms, and a component D that is a branched saturated fatty acid having 8-28 carbon atoms at a blending ratio (component A:component B) of 1.0 mole:0.10-0.20 mole.Type: GrantFiled: July 20, 2007Date of Patent: October 18, 2011Assignee: The Nisshin Oillio Group, Ltd.Inventor: Haruki Mori
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Patent number: 8030364Abstract: The present invention relates to a preparing method of polyols, polyurethane and polyurethane foams using the same. Polyester, polyamide and polyurethane are depolymerized with the polymeric fatty acid mono(polyhydroxyl alcohol)ide composition and additionally reacted with the polybasic acid, polyol and amine to prepare acid value of 05-˜1 mgKOH/g, hydroxyl value of 10˜500 mgKOH/g, and amine value of 1˜50 mgKOH/g in polyol. This is to transform the double bond of the unsaturated fatty acid from the component of the oils and fats into a conjugated double bond to induce the Diels-Alder reaction, and with the improvement of the reactivity to form a stable combination in the chemical structure to prevent the separate leaching appearance of fat and fatty oil from the final product. In particular, by recycling waste edible oil and waste synthetic resin that can be employed as industrially useful material, the invention provides environment advantages.Type: GrantFiled: October 10, 2005Date of Patent: October 4, 2011Inventors: Do Gyun Kim, Hyosung Kim
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Publication number: 20110207859Abstract: This invention relates to aliphatic-aromatic copolyesters that can exhibit improved tear strength and improved rate of biodegradation. Particularly to an aliphatic-aromatic copolyester having a dicarboxylic acid component and a glycol component. The invention also relates to articles and blends using the copolyesters.Type: ApplicationFiled: December 14, 2009Publication date: August 25, 2011Applicant: E.I.DU PONT DE NEMOURS AND COMPANYInventors: Noel M. Hasty, Mark F. Teasley, Edward J. Stancik
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Patent number: 7985826Abstract: Unsaturated polyester compositions are disclosed that are obtainable by reacting: (i) plant and animal oil triglycerides, an alkyl ester of a saturated or unsaturated fatty acid or mixtures thereof; (ii) a difunctional, or polyfunctional glycol or mixtures thereof; (iii) a difunctional or polyfunctional acid, their anhydrides or alkyl esters and mixtures thereof; (iv) a strained cycloolefin; (v) a component(s) that function as a compound capable of initiating polymerization at high temperature and which is stable at room temperature; and (vi) low profile additives, fillers, and reinforcements. Also disclosed are methods for the preparation of the polyesters and the use of the polyesters in closed and open mold compositions such as sheet molding compound (SMC), bulk molding compounding (BMC), resin transfer molding (RTM), pultrusion, infusion, filament winding, and spray up.Type: GrantFiled: December 22, 2006Date of Patent: July 26, 2011Assignee: Reichhold, Inc.Inventors: Hildeberto Nava, Lianzhou Chen
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Publication number: 20110135924Abstract: The present invention provides a polyester, a polyester composition and a pressure-sensitive adhesive composition capable of obtaining a pressure-sensitive adhesive which is global-environmentally friendly and is excellent in pressure-sensitive adhesion properties, using a plant-derived raw material; and a pressure-sensitive adhesive layer and a pressure-sensitive adhesive sheet which can be obtained by using the same. A polyester of the present invention is a polyester comprising at least a lactic acid unit, a dibasic acid unit and a glycol unit, wherein the dibasic acid unit contains dimer acid, and the polyester has a glass transition temperature as measured at a temperature rising rate of 20° C./minute using a differential scanning calorimeter, of ?70 to ?20° C., a weight average molecular weight of 20,000 to 300,000 and a hydroxyl value of 1 to 100 mgKOH/g.Type: ApplicationFiled: August 5, 2009Publication date: June 9, 2011Applicants: NITTO DENKO CORPORATION, TOYO BOSEKI KABUSHIKI KAISHAInventors: Hitoshi Takahira, Satomi Yoshie, Tadashi Nakajima, Daiki Funaoka, Katsuya Shimeno
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Patent number: 7915374Abstract: Processes for producing polyethylene terephthalate copolyesters are disclosed, that include the steps of: esterifying a mixture of at least terephthalic acid, from 20 mole percent to 45 mole percent 1,4-cyclohexanedimethanol, and ethylene glycol, optionally in the presence of one or more alkaline earth metals or alkali metals, to form an oligomer; polycondensing the oligomer in the melt phase in the presence of aluminum and one or more alkaline earth metals or alkali metals, to obtain a copolyester having an intrinsic viscosity of at least 0.5 dL/g; and thereafter adding to the copolyester a phosphorus-containing compound.Type: GrantFiled: April 27, 2009Date of Patent: March 29, 2011Assignee: Eastman Chemical CompanyInventors: Jason Christopher Jenkins, Gary Wayne Connell, Howard Smith Carman, Jr., Douglas Weldon Carico, Jr., Jimmy Ray Trotter, Alan Wayne White, Mary Therese Jernigan, Rodney Scott Armentrout
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Publication number: 20100331191Abstract: Oligoesters including residues of alk(en)yl succinic anhydrides and polyols having at least 3 OH groups, optionally further esterified with fatty acid residues are surfactants which can be used for emulsifiers or similar uses. The surfactants are usually made from C8 to C30 alk(en)yl succinic anhydride and polyols having at least 4 hydroxyl groups and are particularly of the formula (I): R1—[OR2O(O)C.C(HR3).(HR4)C.C(O)]m—R5 (I), where R1, R2, R3, R4, R5, R6, R7 and m have defined meanings. The surfactants are useful as emulsifiers, particuarly oil in water emulsifiers.Type: ApplicationFiled: November 14, 2007Publication date: December 30, 2010Applicant: Croda International PLCInventors: Hanamanthsa Shankarsa Bevinakatti, Alan Geoffrey Waite
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Publication number: 20100261806Abstract: A method for forming a pressure sensitive adhesive including providing a substance that is an epoxidized triglyceride or an epoxidized fatty ester, and polymerizing the substance. A pressure sensitive adhesive can be formed by copolymerizing at least two substances that can be an epoxidized triglyceride, epoxidized fatty ester, or (meth)acrylic copolymer. In yet another method, the at least two substances can be an acrylated epoxidized triglyceride, acrylic copolymer, fatty acid based monomer produced by the reaction of an acid group of a fatty acid and an epoxy group of glycidylmethacrylate, or (meth)acrylic monomer.Type: ApplicationFiled: May 20, 2008Publication date: October 14, 2010Inventor: Carol A. Koch
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Patent number: 7795371Abstract: A grind resin, a pigment dispersion, and a coating composition are provided. The grind resin comprises a reaction product of a dibasic acid, optionally a polybasic acid, a diol, optionally a polyol, and a fatty compound. The fatty compound has a fatty chain and two reactive groups reactive with at least one of the dibasic acid and the diol provided that ?5% of all acid groups are provided by the polybasic acid and <20% of all hydroxyl groups are provided by the polyol. The reaction product is substantially free from branching comprising the reaction product of acid groups or hydroxyl groups and the dibasic acid, polybasic acid, diol, polyol, or fatty compound. The pigment dispersion comprises a pigment and the grind resin. The coating composition comprises a vehicle resin, the pigment, the grind resin, and a cross-linking agent reactive with the vehicle resin and/or the grind resin.Type: GrantFiled: September 11, 2007Date of Patent: September 14, 2010Assignee: PPG Industries Ohio, Inc.Inventors: David E. Lindow, Mark P. Slawikowski
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Publication number: 20100183534Abstract: Polyester oil structurants are obtainable by the reaction of a C4 to C10 Q dicarboxylic acid, a polyol and a C16 to C30, particularly a C20 to C24, monocarboxylic fatty acid. The structurants can be used to provide structure, particularly thickening and/or gelling, in oils of a wide range of polarity. Thickened oils can find application in a range of personal care and other applications.Type: ApplicationFiled: December 21, 2006Publication date: July 22, 2010Inventors: Hanamanthsa Shankarsa Bevinakatti, Alan Geoffrey Waite, Thomas Phillip Wells
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Publication number: 20100105861Abstract: A method for producing a pearly luster composition containing pearly luster particles (A) containing a fatty acid glycol ester (a1) and a fatty acid glycol ester (a2) having a melting point higher than the melting point of the fatty acid glycol ester (a1), and a surfactant (B), wherein the method includes the steps of (i) solubilizing the fatty acid glycol ester (a2) in the presence of the surfactant (B); (ii) mixing the solubilized solution obtained in the step (i) with a molten fatty acid glycol ester (a1), to emulsify the mixture; and (iii) cooling the emulsified mixture obtained in the step (ii), to precipitate the pearly luster particles (A); a pearly luster composition obtained by the method; and a shampoo containing the pearly luster composition. The pearly luster composition obtained by the present invention is suitably used for shampoos, conditioners, body shampoos, liquid detergents, and the like.Type: ApplicationFiled: April 7, 2008Publication date: April 29, 2010Inventors: Shingo Hosoya, Koji Mine, Takeshi Nakai
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Patent number: 7687066Abstract: A self emulsification type oily liquid cosmetic composition includes 8 to 30% by mass of the following component A and 50 to 92% by mass of the following component B. Component A: a polyglycerin fatty acid ester having a hydroxyl value of 450 to 700, and a branched fatty acid residue having 16 to 18 carbon atoms and/or a linear unsaturated fatty acid residue having 16 to 18 carbon atoms accounting for 50 to 100% by mass of total constituent fatty acid residues, and in a polyglycerin constituting the polyglycerin fatty acid ester, a total content of a polyglycerin cyclic compound of a dimer and a trimer is from 0 to 3% based on the entire polyglycerin, a total content of a polyglycerin of a undecamer or a higher multimer is from 10 to 30% based on the entire polyglycerin, and each content of a polyglycerin of a tetramer to a decamer is from 4 to 20% based on the entire polyglycerin. Component B: an oily component.Type: GrantFiled: May 7, 2004Date of Patent: March 30, 2010Assignee: The Nisshin OilliO Group, Ltd.Inventors: Jin Fujino, Keiichi Oyama, Kazuhito Uchida
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Publication number: 20100041821Abstract: An alkyd resin comprising A) a polyol-polyacid alkyd; and B) a composition comprising a highly esterified polyol polyester, wherein the polyester comprises a polyol residue and a plurality of fatty acids esters, and wherein from about 5% to about 80% of the fatty acid esters contains exactly one pair of conjugated double bonds.Type: ApplicationFiled: August 7, 2009Publication date: February 18, 2010Inventors: Delano R. Eslinger, Dennis A. Ryer, Neal Rogers, Roger S. Berger, Deborah J. Back
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Publication number: 20100016543Abstract: A description is given of the preparation of high molecular mass, crystalline copolyesters with high solubility in non-halogenated and non-aromatic solvents, and of their use in adhesives.Type: ApplicationFiled: January 8, 2008Publication date: January 21, 2010Applicant: EVONIK DEGUSSA gmbHInventors: Gabriele Brenner, Rene Koschabek, Georg Becker
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Publication number: 20090324519Abstract: Disclosed is an esterification reaction product which is capable of gelling both an oil agent and a cyclic silicone or a volatile dimethylpolysiloxane, or both an oil agent and a nonvolatile dimethylpolysiloxane. Also disclosed are a gelling agent contacting the esterification reaction product, and a cosmetic preparation containing the esterification reaction product or the gelling product and having an excellent feeling of use. Specifically, the cosmetic preparation contains, as a gelling agent, an esterification reaction product which is obtained by esterifying a component A that is a polyhydric alcohol or a condensate thereof, a component B that is a saturated dibasic acid having 10-28 carbon atoms, a component C that is a linear saturated fatty acid having 16-28 carbon atoms, and a component D that is a branched saturated fatty acid having 8-28 carbon atoms at a blending ratio (component A: component B) of 1.0 mole:0.10-0.20 mole.Type: ApplicationFiled: July 20, 2007Publication date: December 31, 2009Inventor: Haruki Mori
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Patent number: 7638116Abstract: The present invention relates to a series of novel polyesters that are prepared by crosslinking polyglycerol and dimer acid. The nature of the water loving polyglycerol group as well as the fact that a C-36 fatty diacid is used in preparation of the products results in unique products.Type: GrantFiled: October 29, 2007Date of Patent: December 29, 2009Assignee: Zenitech LLCInventors: Carter LaVay, Anthony J. O'Lenick, Jr.
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Patent number: 7560526Abstract: Methods and compositions for forming polyurethane foam. A method for manufacturing an aromatic polyester polyol comprises heating a glycol, a dicarboxylic acid or ester, functionality enhancing agent, and a natural oil to about 480° F. to form a reaction product, allowing the reaction product to cool to about 140° F., and adding additional glycol to form an aromatic polyester polyol composition, wherein the total glycol comprises less than about 36 weight percent of the polyol composition. An aromatic polyester polyol composition comprises a glycol, a dicarboxylic acid or ester, functionality enhancing agent, and a natural oil, wherein the total glycol comprises less than about 36 weight percent of the aromatic polyester polyol composition.Type: GrantFiled: March 20, 2007Date of Patent: July 14, 2009Assignee: Oxid, L.P.Inventor: David J. Shieh
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Patent number: 7544763Abstract: The present invention relates to a manufacturing process for producing a polyol from a fatty acid ester in-situ. The process does not use any added organic or inorganic acid catalyst. The polyol produced by the process is essentially free of any cation or anion. The fatty acid ester oil epoxidation and hydroxylation reactions can occur progressively in the same reactor for essentially a one-pot reaction. The polyol produced by the process is essentially free of any cation or anion. The polyol can be used to produce polyurethanes having improved properties.Type: GrantFiled: November 7, 2006Date of Patent: June 9, 2009Assignee: Arkema Inc.Inventor: Mohammad Kazemizadeh
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Publication number: 20090069498Abstract: A grind resin, a pigment dispersion, and a coating composition are provided. The grind resin comprises a reaction product of a dibasic acid, optionally a polybasic acid, a diol, optionally a polyol, and a fatty compound. The fatty compound has a fatty chain and two reactive groups reactive with at least one of the dibasic acid and the diol provided that ?5% of all acid groups are provided by the polybasic acid and <20% of all hydroxyl groups are provided by the polyol. The reaction product is substantially free from branching comprising the reaction product of acid groups or hydroxyl groups and the dibasic acid, polybasic acid, diol, polyol, or fatty compound. The pigment dispersion comprises a pigment and the grind resin. The coating composition comprises a vehicle resin, the pigment, the grind resin, and a cross-linking agent reactive with the vehicle resin and/or the grind resin.Type: ApplicationFiled: September 11, 2007Publication date: March 12, 2009Inventors: DAVID E. LINDOW, MARK P. SLAWIKOWSKI
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Publication number: 20090068416Abstract: A process is provided for coating a surface of a substrate using a coating precursor comprising a reactive mixture which is reacted to form a coating as a product of ester condensation. The reactive mixture includes a monomer mixture comprising at least one polyhydric alcohol and a reactant selected from the group consisting of at least one organic polyacid; at least one organic anhydride; and combinations thereof. Alternatively, the reactive mixture comprises a prepolymer formed from the monomer mixture; a combination of the prepolymer and the monomer mixture; or a combination of the prepolymer and reactants such as polyhydric alcohol, organic polyacid, organic anhydride, and combinations thereof.Type: ApplicationFiled: December 20, 2007Publication date: March 12, 2009Inventors: Isao Noda, William Maxwell Allen, JR., Michael Matthew Satkowski
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Publication number: 20080227925Abstract: The present invention relates to a composition which includes macrocyclic ethylene isophthalate dimer. More specifically, the composition can be: i) A composition comprising polyhydric alcohol, multi-functional carboxylic acid and macrocyclic ethylene isophthalate dimer; ii) A multi-arm polyester resin having a polymer containing: a central unit of a multi-functional molecule of either a multi-functional carboxylic acid or a multi-functional polyhydric alcohol, but not both, and arms derived from macrocyclic ethylene isophthalate dimer. iii) An unsaturated polyester comprising a macrocyclic ethylene isophthalate dimer and one or more polyhydric alcohols, and optionally, one or more aliphatic and/or aromatic acids to form a melt of polymer; then condensing the polymer and one or more ethylenically unsaturated dicarboxylic acids.Type: ApplicationFiled: March 14, 2007Publication date: September 18, 2008Inventor: Wayne R. Pretzer
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Publication number: 20080220267Abstract: A glyceride compound comprising a first aliphatic group and a first substituent group bonded to said first aliphatic group. The first substituent group has the formula —O(CH2CH2O)nP where n is 1 to 14 and P is a polymerisable group. An aqueous emulsion of the glyceride can be used in an emulsion polymerisation reaction to yield a polymer resin, which can then be mixed with a suitable base material, such as wood strands, to produce a composite material, such as Oriented Strand Board.Type: ApplicationFiled: July 20, 2006Publication date: September 11, 2008Applicants: KEELE UNIVERSITY, ADVANCE ENTERPRISES LTDInventors: James Alan Stephen Howell, Con Robert McElroy, Robert Heathcote, Derek Peter Taylor
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Publication number: 20080160202Abstract: A multi-coat system for staining a substrate which system comprises: (a) a first coat comprising a non-aqueous pretreatment composition; and (b) a second coat comprising an aqueous stain composition; wherein the non-aqueous pretreatment composition comprises a carbohydrate-based alkyd having pendent fatty acid residues.Type: ApplicationFiled: December 21, 2007Publication date: July 3, 2008Applicant: THE SHERWIN-WILLIAMS COMPANYInventors: James M. Reuter, Richard F. Tomko, Edward W. Gierlach, Paul Masters