Reactant Contains Three Or More Carboxylic Acid Groups Or Is Derivative Thereof Patents (Class 528/296)
  • Patent number: 11427676
    Abstract: An aliphatic polyester is provided. The aliphatic polyester comprises: a first structural unit represented by wherein R1 is absent or a C1 to C40 aliphatic hydrocarbyl; a second structural unit represented by wherein R2 is a C1 to C10 aliphatic hydrocarbyl; and a third structural unit derived from a first cross-linking agent, wherein the first cross-linking agent has three reactive functional groups, wherein at least one reactive functional group is a secondary or tertiary hydroxyl, with the proviso that the first cross-linking agent is not malic acid.
    Type: Grant
    Filed: March 23, 2020
    Date of Patent: August 30, 2022
    Assignee: CHANG CHUN PLASTICS CO., LTD.
    Inventors: Ching-Jui Huang, Ping-Chieh Wang
  • Patent number: 10865273
    Abstract: A thermoplastic elastomer contains (a) hard segments of a polyester and (b) soft segments containing repeating units derived from an aliphatic carbonate, wherein the thermoplastic elastomer exhibits a melt flow index (MFI) measured at 230° C. under a load of 10 kg (MFI 230° C./10 kg) according to ISO1133 (2011) of at most 40 g/10 min. The thermoplastic elastomer is produced by subjecting a precursor of the thermoplastic elastomer to solid state post reaction processing at a temperature between 140 and 170° C. until the thermoplastic elastomer has the required MFI of at most 40 g/10 min measured at 230° C. under a load of 10 kg (MFI 230° C./10 kg) according to ISO1133 (2011).
    Type: Grant
    Filed: June 26, 2017
    Date of Patent: December 15, 2020
    Assignee: DSM IP ASSETS B.V.
    Inventors: Ellen Van Hemelrijck, Wilhelmus Petrus Johannes Appel
  • Patent number: 10723877
    Abstract: A lens containing a polycarbonate composition is disclosed. The polycarbonate composition includes a copolycarbonate having bisphenol A carbonate units and second carbonate units of the formula and 2 to 40 ppm of an organosulfonic stabilizer of the formula wherein the second carbonate units are present in an amount of 20 to 49 mol %, preferably 30 to 40 mol % based on the sum of the moles of the copolycarbonate and the bisphenol A homopolycarbonate. The polycarbonate composition has: a Vicat B120 of 160° C. or higher measured according to ISO 306; and a yellowness index of less than 12, measured according to ASTM D1925.
    Type: Grant
    Filed: May 27, 2017
    Date of Patent: July 28, 2020
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Mark Adrianus Johannes Van Der Mee, Nathalie Gonzalez Vidal, Fabrizio Micciche, Roland Sebastian Assink, Kazuhiko Mitsui, Johannes De Brouwer, Shahram Shafaei, Henrikus Petrus Cornelis Van Heerbeek, Tamara Marijke Eggenhuisen, Robert Dirk Van De Grampel
  • Patent number: 10394146
    Abstract: A binder resin for toner of the present invention comprising: a polyester resin (A) which contains a constitutional unit derived from isosorbide and has a softening temperature of higher than 120° C.; and a polyester resin (B) different from the polyester resin (A), wherein the binder resin for toner has a pulverizability index of 25 or more.
    Type: Grant
    Filed: June 1, 2016
    Date of Patent: August 27, 2019
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Tadahiro Ozawa, Yoko Tamura, Kanako Funabashi
  • Patent number: 10047194
    Abstract: A biodegradable polyester is consisting of a poly(terephthalate-di-(?-caprolactone) segment, a poly(terephthalate-butylene-terephthalate) segment, a poly(terephthalate-butylene-?-caprolactone) segment, a poly(?-caprolactone-butylene-?-caprolactone) segment, and a poly(tri(?-caprolactone) segment. The above five segments are obtained by polycondensation reaction of terephthalic acid, 1,4-butanediol and ?-caprolactone under the presence of a catalyst, with a polycondensation temperature of 255° C. to 270° C. and a polycondensation time of 2 hours to 4 hours. Furthermore, based on 1 mole of terephthalic acid, a molar ratio of 1,4-butanediol to terephthalic acid is in the range of 1.1 to 1.4, and a molar ratio of ?-caprolactone to terephthalic acid is in the range of 0.5 to 1.6. The biodegradable polyester can have a melting point (Tm) of 90° C. to 170° C.
    Type: Grant
    Filed: June 4, 2013
    Date of Patent: August 14, 2018
    Assignees: Tatung Company, TATUNG UNIVERSITY
    Inventors: C. Will Chen, Ching-Huang Wang, Ping-Hsun Tsai
  • Patent number: 9518143
    Abstract: A “no-bake” process allows the forming of larger metal castings, by providing longer work times, in the range of about 45 to about 60 minutes. This is achieved using a liquid curing catalyst that is a pyridine, substituted at the second or third position with a moiety having a molecular weight in the range of about 30 to about 100 mwu. Examples of the liquid curing catalyst include 2-ethanolpyridine, 3-chloropyridine and 2-methoxypyridine. When combined with a two-part polyurethane binder precursor and a foundry aggregate, the liquid curing catalyst provides not only the longer work time, but also a strip time that is less than about 167% of the work time, as measured from the point of activating the polyurethane precursors by mixing them in the presence of the curing catalyst.
    Type: Grant
    Filed: June 7, 2013
    Date of Patent: December 13, 2016
    Assignee: ASK Chemicals, L.P.
    Inventors: Michael R. Nocera, Gregory P. Sturtz, Jörg Kroker
  • Patent number: 9518345
    Abstract: In a process for producing a spinnable silica sol material, a viscosity value VS is stipulated which the spinnable silica sol material should have after ripening. A viscosity value VR corresponding to VS which the silica sol material has before ripening is ascertained. An aqueous acid solution and a hydrolysable silicon compound are combined. The combined mixture is evaporated to give a single-phase solution while measuring the viscosity of the mixture and the evaporation process is terminated upon reaching the viscosity value VR. The single-phase solution thus obtained is then ripened to give a silica sol material with the viscosity value VS. The process exhibits reduced waste and more exact reproducibility of the spinning sol properties during the synthesis and an increased space-time yield in the production of biologically degradable and/or resorbable fibers and nonwoven fabrics.
    Type: Grant
    Filed: July 17, 2012
    Date of Patent: December 13, 2016
    Assignee: JIANGSU SYNECOUN MEDICAL TECHNOLOGY CO., LTD
    Inventors: Ekkehard Barth, Bastian Mahr
  • Patent number: 9416224
    Abstract: A continuous preparation method of a biodegradable aliphatic/aromatic polyester copolymer includes: performing a first esterification reaction of an aliphatic dihydroxy compound with an aliphatic dicarboxylic acid at a temperature of 185° C. or less; continuously performing a second esterification reaction of a reaction product from the first esterification reaction; continuously performing a first polycondensation reaction of a reaction product from the second esterification reaction to obtain a prepolymer; continuously performing a second polycondensation reaction of the prepolymer to obtain a second polycondensation reaction product having an intrinsic viscosity from about 0.9 dl/g to about 1.
    Type: Grant
    Filed: July 18, 2013
    Date of Patent: August 16, 2016
    Assignees: LOTTE FINE CHEMICAL CO., LTD., S-ENPOL CO., LTD.
    Inventors: Gyung Don Kang, Ki Chull Yun, Sang Yob Kim, Kil Seuk Byun, Jung Ryum, Boo Seong Kim, Sei Hoon Kim, Sung Bae Park
  • Patent number: 9403938
    Abstract: A continuous preparation method of a biodegradable aliphatic/aromatic polyester copolymer includes: performing a first esterification reaction of an aliphatic dihydroxy compound with an aliphatic dicarboxylic acid at a temperature of 185° C.
    Type: Grant
    Filed: July 18, 2013
    Date of Patent: August 2, 2016
    Assignees: LOTTE FINE CHEMICAL CO., LTD., S-ENPOL CO., LTD.
    Inventors: Gyung Don Kang, Ki Chull Yun, Sang Yob Kim, Kil Seuk Byun, Jung Ryum, Boo Seong Kim, Sei Hoon Kim, Sung Bae Park
  • Patent number: 8969507
    Abstract: A method of producing an aliphatic polyester resin by continuously esterifying and melt polycondensing an aliphatic dicarboxylic acid and an aliphatic diol; and at least one aliphatic hydroxycarboxylic acid; and at least one of an aliphatic unsaturated dicarboxylic acid and cis- and trans-isomers of aliphatic unsaturated tricarboxylic acids, wherein the total amount of the at least one aliphatic hydroxycarboxylic acid and the at least one of aliphatic unsaturated dicarboxylic acid and cis- and trans-isomers of aliphatic unsaturated tricarboxylic acids is from 0.0010 to 0.50 mol % of the total amount of the aliphatic polyester resin; and the total amount of the at least one aliphatic hydroxycarboxylic acid is from 1.0 to 7.0 in terms of a molar ratio to the total amount of the at least one of aliphatic unsaturated dicarboxylic acid and cis- and trans-isomers of aliphatic unsaturated tricarboxylic acids.
    Type: Grant
    Filed: September 14, 2012
    Date of Patent: March 3, 2015
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Toyomasa Hoshino, Shinichiro Matsuzono, Hiroyuki Kaneko, Toshiyuki Hamano, Takayuki Aoshima, Tadashi Ueda
  • Publication number: 20150038668
    Abstract: Branched polyesters obtained by polycondensation of citric acid with at least one poly-alcohol having at least two hydroxyl groups and, if desired, further polycarboxylic acid components, the molar ratio of citric acid to polyalcohol being 2.4:1 to 1:3.
    Type: Application
    Filed: September 29, 2014
    Publication date: February 5, 2015
    Inventors: Dejan Djuric, Monika Haberecht, Karl Kolter, Bernd Bruchmann
  • Patent number: 8946377
    Abstract: The present invention relates to a process for preparing high-functionality polyetherols by reacting at least one trifunctional or higher-functionality alcohol and if appropriate further di- and/or monofunctional alcohols and/or modifying reagents, with the aid of acidic catalysts, where the trifunctional or higher-functionality alcohol is not glycerol. The present invention further relates to high-functionality polyetherols obtainable by such a process and to the use of these high-functionality polyetherols as adhesion promoters, thixotropic agents, rheology modifiers of polymers, phase transfer reagents, micro- or nanocontainers for biologically active compounds, for example for active medical ingredients, biocides, herbicides or fungicides, as pigment dispersants, an additive in printing inks or as structural units for preparing polyaddition or polycondensation polymers or for treatment of seed.
    Type: Grant
    Filed: February 12, 2009
    Date of Patent: February 3, 2015
    Assignee: BASF SE
    Inventors: Rolf Muelhaupt, Anne Fiedler, Fabian Schueler, Bernd Bruchmann, Markus Schuette, Daniel Schoenfelder
  • Patent number: 8907130
    Abstract: The invention relates to novel ?-hydroxyalkylamides, to a method for their production and to the use thereof.
    Type: Grant
    Filed: March 10, 2011
    Date of Patent: December 9, 2014
    Assignee: Evonik Degussa GmbH
    Inventors: Werner Grenda, Emmanouil Spyrou, Thomas Weihrauch, Christoph Lammers, Holger Loesch, Klaus Behrendt
  • Publication number: 20140349109
    Abstract: A method for making a pressure sensitive adhesive comprising: (a) reacting (i) at least one dibasic acid or anhydride thereof with (ii) at least one epoxide having at least two epoxy groups, one diol or polyol, or one diamine at a stoichiometric molar excess of reactive carboxylic acid groups relative reactive epoxy groups, hydroxyl groups or amine groups to produce a thermoplastic prepolymer or oligomer capped with a carboxylic acid group at both prepolymer or oligomer chain ends, or a thermoplastic branched prepolymer or oligomer with at least two of the prepolymer or oligomer branches and chain ends capped with a carboxylic acid group; and (b) curing the resulting carboxylic acid-capped prepolymer or oligomer with at least one polyfunctional epoxy to produce a pressure sensitive adhesive, wherein the polyfunctional epoxy is not an epoxidized vegetable oil.
    Type: Application
    Filed: December 5, 2012
    Publication date: November 27, 2014
    Applicants: State University
    Inventors: Kaichang Li, Anlong Li
  • Publication number: 20140350211
    Abstract: The present invention relates to a process for producing high-molecular-weight copolyesters with use of a kneader.
    Type: Application
    Filed: December 10, 2012
    Publication date: November 27, 2014
    Applicant: Evonik Industries AG
    Inventors: Andre Hennig, Thomas Schmied, Juergen Luh, Thorsten Brand, Guenter Schmitt, Michael Korell
  • Publication number: 20140295349
    Abstract: The present invention relates to novel antireflective coating compositions and their use in image processing. The compositions self-segregate to form hydrophobic surfaces of the novel antireflective coating compositions, the composition being situated between a reflective substrate and a photoresist coating. Such compositions are particularly useful in the fabrication of semiconductor devices by photolithographic techniques. The present invention also related to self-segregating polymers useful in image processing and processes of their use.
    Type: Application
    Filed: March 28, 2013
    Publication date: October 2, 2014
    Applicant: AZ ELECTRONIC MATERIALS (LUXEMBOURG) S.A.R.L.
    Inventors: Huirong YAO, JoonYeon CHO, Zachary BOGUSZ, Salem K. MULLEN, Guanyang LIN, Mark O. NEISSER
  • Patent number: 8846786
    Abstract: The invention relates to a radiation curable aqueously dispersed polyester resin composition containing an emulsifier D and the reaction product AC of a hydroxy functional polyester resin A and an olefinically unsaturated compound C which can be radically polymerized and which is attached to the polyester resin backbone by an ester linkage or a urethane linkage. The invention also relates to a process for its preparation and to a method of use thereof.
    Type: Grant
    Filed: October 9, 2009
    Date of Patent: September 30, 2014
    Assignee: Allnex Belgium S.A.
    Inventors: Luc De Waele, Stephan Peeters, Thierry Randoux, Edmund Urbano
  • Publication number: 20140288215
    Abstract: The present invention relates to an aliphatic-aromatic copolyester resin composition with excellent hydrolysis resistance, wherein an unsaturated compound or an anhydride thereof is introduced into a molecular structure, and specifically, the aliphatic-aromatic copolyester resin composition can be manufactured into all molded products by extrusion, injection and the like, by solving problems with respect to physical properties, processability, reaction rates and water solubility of conventional biological resins.
    Type: Application
    Filed: November 28, 2011
    Publication date: September 25, 2014
    Applicant: Gio-Soltech Co., Ltd.
    Inventors: Ki Cheol Kim, Jung Hyun Choi
  • Patent number: 8835087
    Abstract: A polyester for a toner obtained by polycondensing an aliphatic hydroxycarboxylic acid compound having a total number of hydroxy group or groups and carboxyl group or groups of 4 or more; an alcohol component containing an aliphatic diol having a hydroxyl group bound to a secondary carbon atom in an amount of 50% by mol or more; and a carboxylic acid component, provided that the aliphatic hydroxycarboxylic compound is not included, wherein the aliphatic hydroxycarboxylic acid compound and the aliphatic diol having a hydroxyl group bound to a secondary carbon atom are in a molar ratio, i.e. the aliphatic hydroxycarboxylic acid compound/the aliphatic diol having a hydroxyl group bound to a secondary carbon atom, of from 0.05 to 0.8; a resin binder for a toner, containing the polyester; and a toner for electrophotography, containing the resin binder.
    Type: Grant
    Filed: September 30, 2010
    Date of Patent: September 16, 2014
    Assignee: Kao Corporation
    Inventors: Norihiro Fukuri, Takashi Kubo, Katsutoshi Aoki, Yasunori Inagaki
  • Publication number: 20140197349
    Abstract: Disclosed are formaldehyde-free, thermally-curable, alkaline, aqueous binder compositions, curable to formaldehyde-free, water-insoluble thermoset polyester resins, and uses thereof as binders for non-woven fibers and fiber material.
    Type: Application
    Filed: March 18, 2014
    Publication date: July 17, 2014
    Applicant: Knauf Insulation GmbH
    Inventor: Clarence H. HELBING
  • Patent number: 8772437
    Abstract: Disclosed herein is a biodegradable nitric oxide-generating polymer comprising a nitric oxide-releasing N2O231 (NONOate) functional group. The polymer can be applied to various medical devices for the treatment of various diseases such as thrombosis and restenosis.
    Type: Grant
    Filed: October 24, 2013
    Date of Patent: July 8, 2014
    Assignee: Northwestern University
    Inventors: Guillermo Ameer, Melina Kibbe, Haichao Zhao
  • Patent number: 8754173
    Abstract: The present invention relates to a process for the continuous production of polymer mixtures comprising: a) from 10 to 80% by weight of a biodegradable polyester (Q) composed of aliphatic or aliphatic and aromatic dicarboxylic acids and of aliphatic dihydroxy compounds, and b) from 20 to 90% by weight of one or more polymers (T) selected from the group consisting of: polylactic acid, polycaprolactone, polypropylene carbonate, polyglycolide, aliphatic polyester, cellulose acetate, and polyhydroxyalkanoate, where i) a mixture composed of the aliphatic dihydroxy compounds, of the aliphatic and aromatic dicarboxylic acids and, if appropriate, of further comonomers (component C) is mixed, without addition of any catalyst, to give a paste or, as an alternative, the liquid esters of the dicarboxylic acids are fed into the system, as also are the dihydroxy compound and, if appropriate, further comonomers, without addition of any catalyst, and in a first stage this mixture, together with the entire amount or with a
    Type: Grant
    Filed: October 12, 2010
    Date of Patent: June 17, 2014
    Assignee: BASF SE
    Inventors: Robert Loos, Uwe Witt, Motonori Yamamoto, Günther Mair, Andreas Garbe
  • Publication number: 20140142207
    Abstract: Compositions and/or structures of degradable shape memory polymers (SMPs) ranging in form from neat/unfoamed to ultra low density materials of down to 0.005 g/cc density. These materials show controllable degradation rate, actuation temperature and breadth of transitions along with high modulus and excellent shape memory behavior. A method of making extremely low density foams (up to 0.005 g/cc) via use of combined chemical and physical blowing agents, where the physical blowing agents may be a single compound or mixtures of two or more compounds, and other related methods, including of using multiple co-blowing agents of successively higher boiling points in order to achieve a large range of densities for a fixed net chemical composition. Methods of optimization of the physical properties of the foams such as porosity, cell size and distribution, cell openness etc. of these materials, to further expand their uses and improve their performance.
    Type: Application
    Filed: March 12, 2013
    Publication date: May 22, 2014
    Inventors: Lawrence Livermore National Security, LLC, The Texas A&M University System
  • Patent number: 8722754
    Abstract: This invention provides an economical process for extruding a PLA resin into a low density foam with a high closed cell content. Excellent quality, low density foam is produced easily and reproducibly. The PLA resin in the foam has a weight average molecular weight of at least 500,000 and an intrinsic viscosity of at least 1.4 deciliters/gram.
    Type: Grant
    Filed: April 24, 2009
    Date of Patent: May 13, 2014
    Assignee: NatureWorks LLC
    Inventors: James Nangeroni, Jed Richard Randall
  • Patent number: 8712655
    Abstract: A control system is provided for shifting an automatic transmission of a motor vehicle, which includes, but is not limited to a speed controller, and an electronic control device. Through the electronic control device the parameters vehicle speed, position of the speed controller and acceleration of the speed controller can be captured. Through the electronic control device and through comparison of the captured values of the parameters with predetermined reference values a shifting time is determined for shifting the automatic transmission.
    Type: Grant
    Filed: September 21, 2012
    Date of Patent: April 29, 2014
    Assignee: GM Global Technology Operations LLC
    Inventors: Martin Gentile, Gernot Becker
  • Patent number: 8691934
    Abstract: Disclosed are formaldehyde-free, thermally-curable, alkaline, aqueous binder compositions, curable to formaldehyde-free, water-insoluble thermoset polyester resins, and uses thereof as binders for non-woven fibers and fiber materials.
    Type: Grant
    Filed: November 5, 2010
    Date of Patent: April 8, 2014
    Assignee: Knauf Insulation GmbH
    Inventors: Mary Hession, James Helbing
  • Publication number: 20140066587
    Abstract: The present invention is directed to a novel biocompatible polymer that may be used in tissue engineering. More specifically, the specification describes methods and compositions for making and using citric acid copolymers.
    Type: Application
    Filed: August 20, 2013
    Publication date: March 6, 2014
    Applicant: NORTHWESTERN UNIVERSITY
    Inventors: Guillermo Ameer, Jian Yang, Ryan Hoshi
  • Publication number: 20140051824
    Abstract: An environmentally friendly, pre-reacted product of a polyol and monomeric or polymeric polycarboxylic acid or polyglycerol is provided. The pre-reacted product may include glycerol and esters of citric acid such a monoglyceryl citrate, diglyceryl citrate, and triglyceryl citrate as well as other citric acid-based esters. The pre-reacted product, when used in a binder, helps to speed the crosslinking reaction, induces faster water evaporation, decreases the viscosity of the binder, helps to reduce the amount of water needed for application of the binder, and decreases tackiness. The pre-reacted product may be used, for example, in the formation of insulation materials and non-woven chopped strand mats.
    Type: Application
    Filed: April 4, 2012
    Publication date: February 20, 2014
    Applicant: CARGILL, INCORPORATED
    Inventors: Kevin R. Anderson, Larry T. Banner, Shannon N. Shriver, Shuang Zhou
  • Publication number: 20140050692
    Abstract: The invention provides polymers and methods for the treatment of pain and inflammation.
    Type: Application
    Filed: August 19, 2013
    Publication date: February 20, 2014
    Applicant: Rutgers, The State University of New Jersey
    Inventors: Kathryn E. Uhrich, Roselin Rosario-Melendez
  • Publication number: 20140027669
    Abstract: The present invention relates to the use of branched polyesters obtainable by polycondensation of citric acid with at least one polyalcohol, and optionally with polycarboxylic acid component as additive in washing compositions, cleaners, detergents or a formulation for water treatment and to mixtures comprising such branched polyesters. The invention further relates to the use of hydrophobically modified branched polyesters, and to the method for cleaning, washing or water treatment using such branched polyesters.
    Type: Application
    Filed: July 25, 2013
    Publication date: January 30, 2014
    Applicant: BASF SE
    Inventors: Jürgen Detering, Monika Haberecht, Anna Müller-Cristadoro, Heike Weber
  • Patent number: 8614280
    Abstract: A process for the continuous production of a biodegradable polyester, where a mixture of aliphatic dihydroxy compounds, aliphatic and aromatic dicarboxylic acids or their liquid esters, and, optionally, further comonomers is mixed, without addition of a catalyst, to give a paste, and i) this mixture with at least a portion of the catalyst, is continuously esterified or, transesterified; ii) the transesterification or, esterification product obtained in i) is continuously precondensed with any remaining amount of catalyst to an intrinsic viscosity of from 20 to 70 cm3/g; iii) the product obtainable from ii) is continuously polycondensed to an intrinsic viscosity of from 60 to 170 cm3/g, and iv) the product obtainable from iii) is reacted continuously with a chain extender in a polyaddition reaction to an intrinsic viscosity of from 150 to 320 cm3/g. The invention further relates to biodegradable polyesters obtained by this process.
    Type: Grant
    Filed: April 7, 2009
    Date of Patent: December 24, 2013
    Assignee: BASF SE
    Inventors: Uwe Witt, Motonori Yamamoto
  • Patent number: 8603631
    Abstract: Disclosed are formaldehyde-free, thermally-curable, alkaline, aqueous binder compositions. The disclosed binder compositions may be cured to substantially water-insoluble thermoset polyester resins, including formaldehyde-free, substantially water-insoluble thermoset polyester resins. Uses of the disclosed binder compositions as binders for non-woven fibers and fiber materials are also disclosed.
    Type: Grant
    Filed: October 11, 2005
    Date of Patent: December 10, 2013
    Assignee: Knauf Insulation GmbH
    Inventors: Mary Hession, James Helbing
  • Patent number: 8580912
    Abstract: Disclosed herein is a biodegradable nitric oxide-generating polymer comprising a nitric oxide-releasing N2O2? (NONOate) functional group. The polymer can be applied to various medical devices for the treatment of various diseases such as thrombosis and restenosis.
    Type: Grant
    Filed: September 21, 2009
    Date of Patent: November 12, 2013
    Assignee: Northwestern University
    Inventors: Guillermo Ameer, Melina Kibbe, Haichao Zhao
  • Publication number: 20130274433
    Abstract: There is provided an epoxy resin composition having low viscosity and a high cationic curing property. An epoxy compound of Formula (1): (in Formula (1), A is an (n4)-valent C4-20 linear hydrocarbon group optionally containing an epoxy group, an (n4)-valent C4-20 cyclic hydrocarbon group optionally containing an epoxy group, or an (n4)-valent group of a combination of the linear hydrocarbon group and the cyclic hydrocarbon group; R1 and R2 are each independently a hydrogen atom or a C1-10 alkyl group; n1 is an integer of 2 to 6; n2 is an integer of 2; n3 is an integer of 1; and n4 is an integer of 3 to 8). For example, A is an (n4)-valent organic group formed by removing (n4) hydrogen atoms from butane, pentane, or hexane, or an (n4)-valent organic group formed by removing (n4) hydrogen atoms from cyclobutane, cyclopentane, cyclohexane, epoxycyclohexane, alkyl-substituted epoxycyclohexane, bicycloheptene, or bicyclooctene.
    Type: Application
    Filed: November 14, 2011
    Publication date: October 17, 2013
    Applicant: NISSAN CHEMICAL INDUSTRIES, LTD.
    Inventors: Yuki Endo, Toshiaki Takeyama, Sayoko Yanagisawa
  • Patent number: 8557945
    Abstract: The present invention relates to a kind of biodegradable polyester and its preparation method, which belongs to the field of biodegradable co-polyester product technology. The number-average molecular weight of the biodegradable polyester material under this invention is 6000-135000 g/mol, the molecular weight distribution is 1.2-6.5, and the range of crystallization temperature is 15° C.-105° C., which could overcome the disadvantages of existing technical products and can be processed into membrane materials, sheet materials and foam materials. During processing, the picking property will be dramatically changed with the appearance quality improved; after heat resistance is improved, this new type of polyester material could also be applied to the processing course with long cycles, for example, the injection processing course, and the biodegradable aliphatic/aromatic polyester materials provided by this invention has excellent mechanical properties.
    Type: Grant
    Filed: May 15, 2009
    Date of Patent: October 15, 2013
    Assignees: Kingfa Science & Technology Co., Ltd, Shanghai Kingfa Science & Technology Co., Ltd
    Inventors: Yibin Xu, Renxu Yuan, Tongmin Cai, Jian Jiao, Shiyong Xia, Zhimin Yuan
  • Publication number: 20130253165
    Abstract: A process of producing a polyester composition includes carrying out an esterification reaction of a dicarboxylic acid component with a diol component, and then carrying out a polycondensation reaction, wherein the diol component is added twice or more during a time from completion of the esterification reaction until beginning the polycondensation reaction, and alkali metal phosphate is added with an amount of COOH terminal groups of an esterification reactant being not more than 150 eq/ton.
    Type: Application
    Filed: July 29, 2011
    Publication date: September 26, 2013
    Applicant: TORAY INDUSTRIES, INC.
    Inventors: Mayumi Matsumoto, Hiroji Kojima, Jun Sakamoto
  • Patent number: 8530611
    Abstract: In one aspect, the present invention describes biodegradable photoluminescent polymer (BPLP) compositions. In some embodiments, an aliphatic biodegradable photoluminescent polymer (BPLP) composition comprises a degradable oligomer, wherein the oligomer is synthesized from a diol, an amino acid, and a biocompatible multifunctional carboxylic acid comprising a hydroxyl group. The amino acid is linked as a side group to the degradable oligomer backbone, and fluorescence emanates from a 6-membered ring formed by a carboxylic acid group of the amino acid, an alpha carbon of the amino acid, an amide linkage formed by an amino group of the amino acid, and a central carbon of the multifunctional carboxylic acid via an esterification reaction of the carboxylic acid group of the amino acid and the hydroxyl group of the multifunctional carboxylic acid.
    Type: Grant
    Filed: June 18, 2009
    Date of Patent: September 10, 2013
    Assignee: Board of Regents, The University of Texas System
    Inventors: Jian Yang, Santosh Gautam
  • Patent number: 8524837
    Abstract: The invention relates to heat-curing powder-lacquer compositions exhibiting a matte surface after curing of the coating, as well as to a simple method for production of the same.
    Type: Grant
    Filed: March 10, 2011
    Date of Patent: September 3, 2013
    Assignee: Evonik Degussa GmbH
    Inventors: Werner Grenda, Emmanouil Spyrou, Thomas Weihrauch, Christoph Lammers, Holger Loesch, Klaus Behrendt
  • Publication number: 20130171555
    Abstract: A resin binder for use in a toner, containing an amorphous polyester having a furan ring; and a toner for electrophotography, containing the resin binder. The resin binder for use in a toner of the present invention is suitably used in a toner usable in development of latent images formed in electrophotography, an electrostatic recording method, an electrostatic printing method, or the like.
    Type: Application
    Filed: October 26, 2011
    Publication date: July 4, 2013
    Applicant: KAO CORPORATION
    Inventors: Takashi Kubo, Osamu Yamashita, Norihiro Hirai
  • Publication number: 20130149643
    Abstract: The present disclosure describes a polyester that contains plural pendant adjacent carboxylic acid or acid salt side groups for use in making a toner for use in imaging devices.
    Type: Application
    Filed: December 12, 2011
    Publication date: June 13, 2013
    Inventors: Karen A. Moffat, Dragan Nikolic, Valerie M. Farrugia, Jordan Wosnick, Andriy Kovalenko, Alexander Kobryn, Sergey Gusarov
  • Patent number: 8445627
    Abstract: The invention provides new aliphatic diester-di-acid-containing PEA polymer compositions with significant improvement in hydrolytic degradation rates as compared to aliphatic di-acid-containing PEA polymers. The di-acids used in the invention PEA compositions include non-toxic fatty aliphatic homologs. These molecules inherently contain two-ester groups, which easily can be cleaved by biotic (enzymatic) and abiotic hydrolysis. Additional di-acid-type compounds useful for active polycondensation are ?,?-alkylene dicarboxylates composed of short aliphatic non toxic diols and di-acids. In addition, the invention PEA polymer compositions optionally can include a second monomer, such as a C-protected L-lysine-based monomer, to introduce additional chain flexibility into the polymer. The invention PEA polymer compositions are useful for delivery of bioactive agents when administered internally.
    Type: Grant
    Filed: March 22, 2007
    Date of Patent: May 21, 2013
    Assignee: Medivas, LLC
    Inventors: Ramaz Katsarava, Natia Mazanashvili, Zaza D. Gomurashvili, Turner Daniel Jenkins, Nino Mchedlishvili
  • Publication number: 20120322155
    Abstract: The present invention is directed to a novel biocompatible polymer that may be used in tissue engineering. More specifically, the specification describes methods and compositions for making and using a citric acid copolymers.
    Type: Application
    Filed: August 28, 2012
    Publication date: December 20, 2012
    Applicant: NORTHWESTERN UNIVERSITY
    Inventors: Guillermo Ameer, Jian Yang, Antonio Roy Webb
  • Patent number: 8318893
    Abstract: An aliphatic polyester resin having excellent moldability and its production method are provided. When the amount of specific structural units contained in an aliphatic polyester resin is adjusted to an optimum amount, an aliphatic polyester resin having sufficient melt tension at the time of molding and excellent moldability than in the past and its production method is provided.
    Type: Grant
    Filed: December 10, 2008
    Date of Patent: November 27, 2012
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Toyomasa Hoshino, Shinichiro Matsuzono, Hiroyuki Kaneko, Toshiyuki Hamano, Takayuki Aoshima, Tadashi Ueda
  • Patent number: 8313881
    Abstract: A toner for an electrophotographic image forming process or an electrostatic printing process, and a polyester resin for the toner are disclosed. The polyester resin comprises: acid components including 70 to 96 mol % of aromatic dibasic acid component, 3 to 20 mol % of cycloaliphatic dibasic acid component, and 1 to 10 mol % of trivalent or higher acid component; alcohol components including 10 to 50 mol % of cycloaliphatic diol component, 2 to 20 mol % of trihydric or higher alcohol component, and 30 to 88 mol % of aliphatic diol component; and a heat stabilizer.
    Type: Grant
    Filed: July 10, 2008
    Date of Patent: November 20, 2012
    Assignee: SK Chemicals Co., Ltd.
    Inventors: Young-Man Yoo, Jae-Kyoung Roh, Kye-Yune Lee, Tae-Woong Lee
  • Patent number: 8309229
    Abstract: The invention discloses specific polyester resins which are obtained by the technique of reacting polyesterpolyol oligomer of specific monomeric composition further with polyvalent carboxylic acid (anhydride) and the like; thermosetting water-borne coating compositions using the polyester resins, and coating film-forming methods using the thermosetting water-borne coating compositions.
    Type: Grant
    Filed: June 9, 2005
    Date of Patent: November 13, 2012
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Shuichi Nakahara, Hiromi Harakawa
  • Patent number: 8309217
    Abstract: Disclosed is an easy adhesion film which attains sufficient adhesiveness in various processings without using any crosslinking agent such as a melamine resin to possibly pollute the environment and has a primer layer excellent in high-temperature hot water resistance. In the easy adhesion film, a coating film including a polyester resin and a crosslinking agent component in a content of 0.1% by mass or less, inclusive of 0% by mass, is formed on at least one side of a substrate film. The sum of the acid number and the hydroxyl number of the polyester resin is 50 to 200 mg KOH/g, wherein the acid number is 20 to 60 mg KOH/g and the hydroxyl number is 30 to 150 mg KOH/g. The amount of the oligomers contained in the polyester is 2.0% by mass or less. The thickness of the coating film is 0.001 to 0.5 ?m.
    Type: Grant
    Filed: February 12, 2008
    Date of Patent: November 13, 2012
    Assignee: Unitika Ltd.
    Inventors: Takayoshi Okuzu, Hideki Kuwata
  • Publication number: 20120264047
    Abstract: A polyester resin toner-forming composition containing a biopolyol is described. The biopolyol can enhance branching, crosslinking or both.
    Type: Application
    Filed: April 15, 2011
    Publication date: October 18, 2012
    Applicant: XEROX CORPORATION
    Inventors: Valerie M. Farrugia, Biritawit Asfaw
  • Patent number: 8287991
    Abstract: Disclosed are laminated articles comprising a first polymer layer and a second polymer layer having an inclusion embedded between the layers, wherein at least one layer comprises a branching agent to improve dimensional stability during the lamination process. Disclosed are laminated articles comprising a first polymer layer and a second polymer layer having an inclusion embedded between the layers, wherein at least one layer comprises a copolyester comprising a branching agent to improve dimensional stability during the lamination process. Also disclosed are methods of laminating a first layer and a second layer with an inclusion between the layers to form a laminated article with an embedded inclusion, wherein at least one layer comprises a copolyester comprising a branching agent.
    Type: Grant
    Filed: July 13, 2007
    Date of Patent: October 16, 2012
    Assignee: Eastman Chemical Company
    Inventors: Michael Eugene Donelson, Ryan Thomas Neill, James Collins Maine, Bryan Steven Bishop, Robert Erik Young
  • Publication number: 20120252968
    Abstract: Copoly(imide oxetane) materials are disclosed that can exhibit a low surface energy while possessing the mechanical, thermal, chemical and optical properties associated with polyimides. The copoly(imide oxetane)s are prepared using a minor amount of fluorinated oxetane-derived oligomer with sufficient fluorine-containing segments of the copoly(imide oxetane)s that migrate to the exterior surface of the polymeric material to yield low surface energies. Thus the coatings and articles of manufacture made with the copoly(imide oxetane)s of this invention are characterized as having an anisotropic fluorine composition. The low surface energies can be achieved with very low content of fluorinated oxetane-derived oligomer. The copolymers of this invention can enhance the viability of polyimides for many applications and may be acceptable where homopolyimide materials have been unacceptable.
    Type: Application
    Filed: November 1, 2011
    Publication date: October 4, 2012
    Applicant: U.S.A. as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Christopher J. Wohl, John W. Connell, Emilie J. Siochi, Joseph G. Smith
  • Patent number: 8257543
    Abstract: The invention relates to a process for the production of a layered composite structure comprising (1) a semi-permeable membrane made of a polymer composition comprising a polyetherester elastomer and (2) at least one web layer bonded to the membrane, wherein the process comprises a step wherein a melt layer of the polymer composition is applied onto the at least one web layer, and wherein the polyetherester elastomer comprises polyether soft segments formed from poly(alkylene-ether)glycols comprising alkylene-ether segments formed from ethylene oxide and polyester hard segments consisting of ester units derivable from short chain diols and dicarboxylic acid consisting of 98-65 mole % terephthalic acid (TPA), 2-35 mole % isophthalic acid (IPA) and optionally 0-20 mole % other dicarboxylic acids, wherein the mole % is relative to the total molar amount of dicarboxylic acid.
    Type: Grant
    Filed: May 30, 2006
    Date of Patent: September 4, 2012
    Assignee: DSM IP Assets B.V.
    Inventors: Hermanus P. Snuverink Ook Lansink, Hendricus F. Aussems, Paul W. J. Heuvel Van Den, Angelika Schmidt