Halogen-containing Reactant Other Than Solely As Halogen Atom Bonded To A Carbonyl Group Patents (Class 528/299)
  • Patent number: 4367315
    Abstract: An improved fire retardant polyester polymer system and composition comprising an interpolymer of a reaction product of hexachlorocyclopentadiene, a polyhydric alcohol, a carboxylic acid containing aliphatic carbon-to-carbon unsaturation, a styrene-type monomer, maleic acid or anhydride and a copolymerizable brominated neopentylacrylate comonomer.
    Type: Grant
    Filed: January 29, 1981
    Date of Patent: January 4, 1983
    Assignee: Occidental Chemical Corporation
    Inventors: Paul Zwaenepoel, Guido Strzelbicki, Daniel J. Scharf, George M. Wagner
  • Patent number: 4363907
    Abstract: Cohalogenation of unsaturated polyesters containing pendant unsaturation and a dicyclopentadienyl ester of an .alpha.,.beta.-unsaturated carboxylic acid is carried out at room temperature or lower to simultaneously and selectively halogenate the non .alpha.,.beta.-unsaturation. These materials have utility in plastics, such as fire-retardant castings.
    Type: Grant
    Filed: July 14, 1981
    Date of Patent: December 14, 1982
    Assignee: The Dow Chemical Company
    Inventors: Robert E. Hefner, Jr., Hans R. Friedli, Mark J. Hazelrigg, Jr.
  • Patent number: 4360647
    Abstract: Unsaturated polyesters modified with a norbornene functional compound, such as dicyclopentadiene, and containing a phosphonate group cure into fire retardant plastics.
    Type: Grant
    Filed: July 14, 1981
    Date of Patent: November 23, 1982
    Assignee: The Dow Chemical Company
    Inventor: Robert E. Hefner, Jr.
  • Patent number: 4354019
    Abstract: An oxidated silicon compound will react with a substituted organic compound in the presence of an alkali compound to produce organic alkali metal silicate products which may be used as molding powders, as adhesives, as coating agents and be reacted with polyisocyanates to produce insulating foams.
    Type: Grant
    Filed: December 10, 1981
    Date of Patent: October 12, 1982
    Inventor: David H. Blount
  • Patent number: 4346235
    Abstract: A novel fluorine-containing compound of the formulaR.sub.1 --A--R.sub.2whereinA is ##STR1## R.sub.1 and R.sub.2 are each hydrogen or R.sub.3 OOC--CH.sub.2).sub.n, while R.sub.1 and R.sub.2 may not be hydrogen at the same time; X is hydrogen or halogen; R.sub.3 is hydrogen or a lower alkyl group; m is an integer of 1 to 5; and n is an integer of 4 to 11, and a process for preparing the same.
    Type: Grant
    Filed: June 10, 1980
    Date of Patent: August 24, 1982
    Assignees: Okamura Oil Mill Limited, Daikin Kogyo Co., Ltd.
    Inventors: Noboru Sonoda, Shinji Murai, Kazuhisa Takii
  • Patent number: 4309497
    Abstract: In an electrically activatable recording element, such as one comprising an electrically conductive support having thereon, in sequence: (a) a polymeric electrically active conductive (EAC) layer, (b) an electrically activatable recording layer comprising (A) a dye-forming coupler, and (B) an oxidation-reduction combination comprising (i) an organic silver salt oxidizing agent, such as a silver salt of a 1,2,4-mercaptotriazole derivative, with (ii) a reducing agent which, in its oxidized form, forms a dye with the dye-forming coupler, (c) a photoconductive layer separated from (b) by an air gap of up to 20 microns, and (d) an electrically conductive layer; improvements are provided by means of a polymeric EAC layer (a) comprising a halogen containing polyester, such as poly(2,2'-oxydiethylene:2,2'-dimethyl 1,3-propylene 50:50-2,5-dibromoterephthalate) and poly(ethylene:2,2-dimethyl-1,3-propylene 50:50-2,5-dibromoterephthalate).
    Type: Grant
    Filed: June 13, 1980
    Date of Patent: January 5, 1982
    Assignee: Eastman Kodak Company
    Inventors: Mark Lelental, Mohammad A. Sandhu
  • Patent number: 4299950
    Abstract: A novel unsaturated polyester resin composition comprising an unsaturated alkyd and a crosslinkable vinyl monomer, said unsaturated alkyd being a modified unsaturated alkyd obtained by reacting a polybasic acid with a polyhydric alcohol in the presence of a cyclopentadiene-type oil having a viscosity at 25.degree. C. of 50 to 50,000.
    Type: Grant
    Filed: July 22, 1980
    Date of Patent: November 10, 1981
    Assignee: Nippon Zeon Co. Ltd.
    Inventors: Riso Iwata, Atsuo Ishikawa, Hisataka Komai
  • Patent number: 4292898
    Abstract: A filament wound railroad car including an elongated, load bearing body having walls formed of a specified fiber reinforced plastic resin composite of glass reinforcing filaments and a structural organopolymeric resin having particular characteristics.
    Type: Grant
    Filed: January 18, 1980
    Date of Patent: October 6, 1981
    Assignees: Cargill, Incorporated, Structural Composite Industries, Inc.
    Inventors: Robert Gordon, Harry A. King, James V. Springrose, Robert W. Cuddihy
  • Patent number: 4283512
    Abstract: A copolymer having peroxy bonds in the molecule thereof which is obtained by copolymerizing an diacyl type polymeric peroxide having ester bonds therein with one or more monomers having double bonds therein, may have a broad range of average molecular weight and a lot of peroxy bonds therein, and it may be used as an useful polymerization initiator in producing a block copolymer.
    Type: Grant
    Filed: November 27, 1979
    Date of Patent: August 11, 1981
    Assignee: Nippon Oil and Fats Co., Ltd.
    Inventors: Masaru Matsushima, Takeshi Komai, Masaharu Nakayama
  • Patent number: 4264745
    Abstract: A polyol is produced as the reaction product of dibromonepentyl glycol and tetrabromophthalic anhydride with defined alkyoxides. This polyol can be used to produce a insulating foam having flame retardant properties.
    Type: Grant
    Filed: September 14, 1979
    Date of Patent: April 28, 1981
    Assignee: Owens-Corning Fiberglas Corporation
    Inventor: Millard E. Foucht
  • Patent number: 4254243
    Abstract: The invention relates to copolyesters of ethylene terephthalate-tetrachlorobenzenedimethylene terephthalate. They can be random or block copolyester. The products have high second order transition temperatures and can be formed into products that can be sterilized.
    Type: Grant
    Filed: February 22, 1979
    Date of Patent: March 3, 1981
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Max H. Keck
  • Patent number: 4250300
    Abstract: A fluorine-containing polyester which comprises essentially as the constituting units (a) a group of the formula: ##STR1## wherein Rf is a perfluoroalkyl group having 8 to 21 carbon atoms and n is an integer of 0 or 1 and (b) a group of the formula: ##STR2## wherein R is one of the groups represented by the formulas: ##STR3## wherein R.sub.1 to R.sub.6 is each a hydrogen atom or a lower alkyl group, R.sub.1 and R.sub.3 being optionally combined together at the terminal carbon atoms to form a cyclic ring, X is a halogen atom or a lower alkyl group and m is an integer of 0 to 4, and is useful as a water and oil-repelling agent or a non-sticking agent.
    Type: Grant
    Filed: March 12, 1979
    Date of Patent: February 10, 1981
    Assignee: Daikin Kogyo Co., Ltd.
    Inventors: Takeo Saegusa, Akira Yamada, Masaaki Iwase, Akitoshi Iwatani
  • Patent number: 4248995
    Abstract: A process is disclosed for the production of alkylaromatic copolyesters, characterized in that there are reacted, successively, at a temperature below 250.degree. C., a diester of a dihydroxyaromatic compound and an aliphatid diacid of the general formula HOOC(CH.sub.2).sub.n COOH, in which 3.ltoreq.n.ltoreq.10, with a molar ratio of the diester to the diacid of between 1.5 and 4, until the degree of completion of the reaction is greater than or equal to 85%, and them, at a temperature above 250.degree. C., an aromatic and/or cycloaliphatic dicarboxylic acid, and in that the product obtained is subjected to a polycondensation reaction under reduced pressure for a duration which is less than or equal to 1 hour 30 minutes. This process makes it possible to produce copolyesters which may be readily converted in the molten state to threads, films and molded articles.
    Type: Grant
    Filed: September 25, 1979
    Date of Patent: February 3, 1981
    Assignee: Rhone-Poulenc Industries
    Inventor: Bernard Fayolle
  • Patent number: 4238602
    Abstract: A fluorinated polyether is synthesized by (1) reacting perfluoroglutaryl chloride and 1,5-hexafluoropentane diol to provide a fluorinated polyester and (2) converting ester groups of the polyester to ether groups by SF.sub.4 reduction. The product obtained is a thermally stable polyether which is particularly useful in providing an elastomeric material for aircraft fuel tank sealants, tire valves, O-rings, hose, gaskets, and the like.
    Type: Grant
    Filed: April 26, 1979
    Date of Patent: December 9, 1980
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventor: Warren R. Griffin
  • Patent number: 4219625
    Abstract: As an additive imparting oil and water repellency, durable against laundering and abrasion, to PET fibers: a partially or fully acylated polyol, especially pentaerythritol, glycerol, hydroquinone or ethylene glycol, acylated with a phthalic or terephthalic monoester having a perfluorinated alkyl or alkoxyalkyl C.sub.2 to C.sub.20 radical, especially C.sub.5 to C.sub.10 n-alkyl or (CF.sub.2).sub.n OR.sub.f where R.sub.f is C.sub.1 to C.sub.6 perfluoroalkyl, especially perfluoroisopropyl and (CF.sub.2).sub.n is a straight chain C.sub.2 to C.sub.10 diradical.
    Type: Grant
    Filed: December 16, 1977
    Date of Patent: August 26, 1980
    Assignee: Allied Chemical Corporation
    Inventors: Frank Mares, Bryce C. Oxenrider, Cyril Woolf
  • Patent number: 4217440
    Abstract: A method for preparing branched polyesters in melt or solid phase comprises reacting together diols, diacids and polyfunctional modifiers having at least three functional radicals to form a condensation polymer. This condensation polymer is polycondensed to form a polyester by linear extension and branching while correlating catalyst activity, reaction temperature and pressure to restrain the extent of reaction for linear extension to within about 0.1 percent of the extent of reaction for branching.
    Type: Grant
    Filed: August 20, 1979
    Date of Patent: August 12, 1980
    Assignee: Eastman Kodak Company
    Inventor: Kenneth T. Barkey
  • Patent number: 4206025
    Abstract: Radio-hardenable acrylic polyesters of the general formula:[A][B--C--D.sub.m ].sub.2 (I)wherein A is the radical of a linear polyester of the general formula:--O--[R.sub.1 --R.sub.2 ].sub.x R.sub.1 --O-- (II)wherein R.sub.1 is a radical derived from at least one dihydroxylated compound, R.sub.2 a radical derived from at least one dicarboxylic acid and x an integer from 1 to 20; wherein B has the same meaning as R.sub.2, C is a radical derived from at least one aliphatic polyhydroxylated compound, D a radical derived from acrylic acid and m is an integer from 2 to 7.Manufacture of said polyesters and use as binders in radio-hardenable compositions.
    Type: Grant
    Filed: September 5, 1978
    Date of Patent: June 3, 1980
    Assignee: U C B, Societe Anonyme
    Inventors: August Vrancken, Paul Dufour
  • Patent number: 4184035
    Abstract: Disclosed is a process for neutralizing an inorganic acid in the presence of a halogenated aliphatic polybasic acid or anhydride. The neutralization is carried out by adding to said acid or anhydride a primary or secondary amine containing at least two active hydrogen atoms per molecule as determined by the Zerewittenoff Method, and neutralizing the inorganic acid in the presence of the polybasic acid or anhydride. In one embodiment, the halogenated aliphatic or alicyclic polybasic acid or anhydride is present in a mixture wth a halogenated aromatic polybasic acid or anhydride and with a polyol and the neutralization is carried out before substantial polymerization occurs between the acids and polyol.
    Type: Grant
    Filed: September 9, 1974
    Date of Patent: January 15, 1980
    Assignee: Velsicol Chemical Corporation
    Inventor: Otto K. Goins
  • Patent number: 4182842
    Abstract: Disclosed are poly(ester-amides) prepared from an aromatic dicarboxylic acid, ethylene glycol and a p-acylaminobenzoic acid.
    Type: Grant
    Filed: November 3, 1978
    Date of Patent: January 8, 1980
    Assignee: Eastman Kodak Company
    Inventors: Winston J. Jackson, Herbert F. Kuhfuss
  • Patent number: 4180652
    Abstract: A novel polyester type powder coating composition which includes a specific self-hardening polyester of air-hardening type comprising as main ester-constituting monomer units, (1) at least one polycarboxylic acid component containing at least 10 mole %, based on the polycarboxylic acid component, of at least one aromatic polycarboxylic acid component (A) and (2) at least one polyhydric alcohol component, having in its main chain at least one terminal blocked with a monofunctional unsaturated alicyclic compound component (B) and having a softening point of 30.degree. to 150.degree. C. This composition is excellent in storage stability and adaptability to either thin coating or thick coating, and when it is applied onto an article to be coated and baked at a temperature of 170.degree. to 230.degree. C. for 5 to 30 minutes, a coating excellent in appearance, mechanical strength, gloss and reflection sharpness can be formed advantageously without generating undesired gases at the baking.
    Type: Grant
    Filed: February 16, 1978
    Date of Patent: December 25, 1979
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Sumitaka Nogami, Yoshio Matsumoto, Keiichi Waki, Tooru Okada
  • Patent number: 4175072
    Abstract: Light-colored unsaturated polyester resins containing at least 2% by weight bromine can be prepared by using at least a portion of the glycol ingredient dibromo neopentyl glycol and by using from 5 to 85 mol percent of tetrahydrophthalic acid or anhydride or endomethylene tetrahydrophthalic acid or anhydride.
    Type: Grant
    Filed: May 24, 1978
    Date of Patent: November 20, 1979
    Assignee: Freeman Chemical Corporation
    Inventors: Alan J. Parr, Bryan O. Brown
  • Patent number: 4153779
    Abstract: Disclosed is a liquid crystal copolyester having unobviously high mechanical properties. The copolyester is prepared from an aromatic dicarboxylic acid, a substituted phenylhydroquinone and optionally other hydroquinones.
    Type: Grant
    Filed: June 26, 1978
    Date of Patent: May 8, 1979
    Assignee: Eastman Kodak Company
    Inventors: Winston J. Jackson, Jr., Gary G. Gebeau, Herbert F. Kuhfuss
  • Patent number: 4134881
    Abstract: Polyester polymers consisting essentially of ester condensation products of specific proportions of propylene glycol, adipic and fumaric acids, isophthalic acid and halogenated phthalic anhydride, and cured resins containing such polymers. The polymers are particularly useful in high performance matrices for fiber composites requiring properties including a combination of high heat deflection temperature and high tensile elongation.
    Type: Grant
    Filed: August 5, 1977
    Date of Patent: January 16, 1979
    Assignee: Cargill, Incorporated
    Inventors: Robert W. Cuddihy, Daniel S. Knoebel
  • Patent number: 4134934
    Abstract: An improvement in an unsaturated polyesters having recurring units of the formula ##STR1## wherein A is the residue of an alcoholic moiety and B is the residue of an acid moiety, which improvement resides in the fact that some of the A residues are chloroxylylene containing residues having the formula ##STR2##
    Type: Grant
    Filed: January 9, 1978
    Date of Patent: January 16, 1979
    Assignee: Dynamit Nobel Aktiengesellschaft
    Inventors: Georg Blumenfeld, Norbert Vollkommer
  • Patent number: 4130579
    Abstract: Aromatic-aliphatic dinitriles of the formula ##STR1## in which Ar is an arylene or substituted arylene are useful in the preparation of the corresponding amines which are intermediates for the preparation of thermally stable, rigid, polyamides.
    Type: Grant
    Filed: June 8, 1977
    Date of Patent: December 19, 1978
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: August H. Frazer, John F. Harris, Jr., Elmore L. Martin
  • Patent number: 4113703
    Abstract: An improvement in an unsaturated polyesters having recurring units of the formula ##STR1## wherein A is the residue of an alcoholic moiety and B is the residue of an acid moiety, which improvement resides in the fact that some of the A residues are chloroxylylene containing residues having the formula ##STR2##
    Type: Grant
    Filed: December 12, 1975
    Date of Patent: September 12, 1978
    Assignee: Dynamit Nobel Aktiengesellschaft
    Inventors: Georg Blumenfeld, Norbert Vollkommer
  • Patent number: 4101528
    Abstract: A flame-retardant filament-forming copolymer of at least 75 mol % of ethylene-2,6-naphthalene dicarboxylate units and at least 3 mol % up to 25 mol % of randomly copolymerized esters units having bromine or chlorine chemically united with either the diacid residue or both the diacid residue and the diol residue of said ester units. In addition, fibers of the above flame-retardant copolyester resin and flame-retardant cellulosic fibers are blended together to provide flame-retardant yarns and fabrics of excellent physical properties.
    Type: Grant
    Filed: June 16, 1977
    Date of Patent: July 18, 1978
    Assignee: Avtex Fibers Inc.
    Inventor: William N. Knopka