Halogen-containing Reactant Other Than Solely As Halogen Atom Bonded To A Carbonyl Group Patents (Class 528/299)
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Patent number: 4367315Abstract: An improved fire retardant polyester polymer system and composition comprising an interpolymer of a reaction product of hexachlorocyclopentadiene, a polyhydric alcohol, a carboxylic acid containing aliphatic carbon-to-carbon unsaturation, a styrene-type monomer, maleic acid or anhydride and a copolymerizable brominated neopentylacrylate comonomer.Type: GrantFiled: January 29, 1981Date of Patent: January 4, 1983Assignee: Occidental Chemical CorporationInventors: Paul Zwaenepoel, Guido Strzelbicki, Daniel J. Scharf, George M. Wagner
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Patent number: 4363907Abstract: Cohalogenation of unsaturated polyesters containing pendant unsaturation and a dicyclopentadienyl ester of an .alpha.,.beta.-unsaturated carboxylic acid is carried out at room temperature or lower to simultaneously and selectively halogenate the non .alpha.,.beta.-unsaturation. These materials have utility in plastics, such as fire-retardant castings.Type: GrantFiled: July 14, 1981Date of Patent: December 14, 1982Assignee: The Dow Chemical CompanyInventors: Robert E. Hefner, Jr., Hans R. Friedli, Mark J. Hazelrigg, Jr.
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Patent number: 4360647Abstract: Unsaturated polyesters modified with a norbornene functional compound, such as dicyclopentadiene, and containing a phosphonate group cure into fire retardant plastics.Type: GrantFiled: July 14, 1981Date of Patent: November 23, 1982Assignee: The Dow Chemical CompanyInventor: Robert E. Hefner, Jr.
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Patent number: 4354019Abstract: An oxidated silicon compound will react with a substituted organic compound in the presence of an alkali compound to produce organic alkali metal silicate products which may be used as molding powders, as adhesives, as coating agents and be reacted with polyisocyanates to produce insulating foams.Type: GrantFiled: December 10, 1981Date of Patent: October 12, 1982Inventor: David H. Blount
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Patent number: 4346235Abstract: A novel fluorine-containing compound of the formulaR.sub.1 --A--R.sub.2whereinA is ##STR1## R.sub.1 and R.sub.2 are each hydrogen or R.sub.3 OOC--CH.sub.2).sub.n, while R.sub.1 and R.sub.2 may not be hydrogen at the same time; X is hydrogen or halogen; R.sub.3 is hydrogen or a lower alkyl group; m is an integer of 1 to 5; and n is an integer of 4 to 11, and a process for preparing the same.Type: GrantFiled: June 10, 1980Date of Patent: August 24, 1982Assignees: Okamura Oil Mill Limited, Daikin Kogyo Co., Ltd.Inventors: Noboru Sonoda, Shinji Murai, Kazuhisa Takii
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Patent number: 4309497Abstract: In an electrically activatable recording element, such as one comprising an electrically conductive support having thereon, in sequence: (a) a polymeric electrically active conductive (EAC) layer, (b) an electrically activatable recording layer comprising (A) a dye-forming coupler, and (B) an oxidation-reduction combination comprising (i) an organic silver salt oxidizing agent, such as a silver salt of a 1,2,4-mercaptotriazole derivative, with (ii) a reducing agent which, in its oxidized form, forms a dye with the dye-forming coupler, (c) a photoconductive layer separated from (b) by an air gap of up to 20 microns, and (d) an electrically conductive layer; improvements are provided by means of a polymeric EAC layer (a) comprising a halogen containing polyester, such as poly(2,2'-oxydiethylene:2,2'-dimethyl 1,3-propylene 50:50-2,5-dibromoterephthalate) and poly(ethylene:2,2-dimethyl-1,3-propylene 50:50-2,5-dibromoterephthalate).Type: GrantFiled: June 13, 1980Date of Patent: January 5, 1982Assignee: Eastman Kodak CompanyInventors: Mark Lelental, Mohammad A. Sandhu
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Patent number: 4299950Abstract: A novel unsaturated polyester resin composition comprising an unsaturated alkyd and a crosslinkable vinyl monomer, said unsaturated alkyd being a modified unsaturated alkyd obtained by reacting a polybasic acid with a polyhydric alcohol in the presence of a cyclopentadiene-type oil having a viscosity at 25.degree. C. of 50 to 50,000.Type: GrantFiled: July 22, 1980Date of Patent: November 10, 1981Assignee: Nippon Zeon Co. Ltd.Inventors: Riso Iwata, Atsuo Ishikawa, Hisataka Komai
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Patent number: 4292898Abstract: A filament wound railroad car including an elongated, load bearing body having walls formed of a specified fiber reinforced plastic resin composite of glass reinforcing filaments and a structural organopolymeric resin having particular characteristics.Type: GrantFiled: January 18, 1980Date of Patent: October 6, 1981Assignees: Cargill, Incorporated, Structural Composite Industries, Inc.Inventors: Robert Gordon, Harry A. King, James V. Springrose, Robert W. Cuddihy
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Patent number: 4283512Abstract: A copolymer having peroxy bonds in the molecule thereof which is obtained by copolymerizing an diacyl type polymeric peroxide having ester bonds therein with one or more monomers having double bonds therein, may have a broad range of average molecular weight and a lot of peroxy bonds therein, and it may be used as an useful polymerization initiator in producing a block copolymer.Type: GrantFiled: November 27, 1979Date of Patent: August 11, 1981Assignee: Nippon Oil and Fats Co., Ltd.Inventors: Masaru Matsushima, Takeshi Komai, Masaharu Nakayama
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Patent number: 4264745Abstract: A polyol is produced as the reaction product of dibromonepentyl glycol and tetrabromophthalic anhydride with defined alkyoxides. This polyol can be used to produce a insulating foam having flame retardant properties.Type: GrantFiled: September 14, 1979Date of Patent: April 28, 1981Assignee: Owens-Corning Fiberglas CorporationInventor: Millard E. Foucht
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Patent number: 4254243Abstract: The invention relates to copolyesters of ethylene terephthalate-tetrachlorobenzenedimethylene terephthalate. They can be random or block copolyester. The products have high second order transition temperatures and can be formed into products that can be sterilized.Type: GrantFiled: February 22, 1979Date of Patent: March 3, 1981Assignee: The Goodyear Tire & Rubber CompanyInventor: Max H. Keck
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Patent number: 4250300Abstract: A fluorine-containing polyester which comprises essentially as the constituting units (a) a group of the formula: ##STR1## wherein Rf is a perfluoroalkyl group having 8 to 21 carbon atoms and n is an integer of 0 or 1 and (b) a group of the formula: ##STR2## wherein R is one of the groups represented by the formulas: ##STR3## wherein R.sub.1 to R.sub.6 is each a hydrogen atom or a lower alkyl group, R.sub.1 and R.sub.3 being optionally combined together at the terminal carbon atoms to form a cyclic ring, X is a halogen atom or a lower alkyl group and m is an integer of 0 to 4, and is useful as a water and oil-repelling agent or a non-sticking agent.Type: GrantFiled: March 12, 1979Date of Patent: February 10, 1981Assignee: Daikin Kogyo Co., Ltd.Inventors: Takeo Saegusa, Akira Yamada, Masaaki Iwase, Akitoshi Iwatani
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Patent number: 4248995Abstract: A process is disclosed for the production of alkylaromatic copolyesters, characterized in that there are reacted, successively, at a temperature below 250.degree. C., a diester of a dihydroxyaromatic compound and an aliphatid diacid of the general formula HOOC(CH.sub.2).sub.n COOH, in which 3.ltoreq.n.ltoreq.10, with a molar ratio of the diester to the diacid of between 1.5 and 4, until the degree of completion of the reaction is greater than or equal to 85%, and them, at a temperature above 250.degree. C., an aromatic and/or cycloaliphatic dicarboxylic acid, and in that the product obtained is subjected to a polycondensation reaction under reduced pressure for a duration which is less than or equal to 1 hour 30 minutes. This process makes it possible to produce copolyesters which may be readily converted in the molten state to threads, films and molded articles.Type: GrantFiled: September 25, 1979Date of Patent: February 3, 1981Assignee: Rhone-Poulenc IndustriesInventor: Bernard Fayolle
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Patent number: 4238602Abstract: A fluorinated polyether is synthesized by (1) reacting perfluoroglutaryl chloride and 1,5-hexafluoropentane diol to provide a fluorinated polyester and (2) converting ester groups of the polyester to ether groups by SF.sub.4 reduction. The product obtained is a thermally stable polyether which is particularly useful in providing an elastomeric material for aircraft fuel tank sealants, tire valves, O-rings, hose, gaskets, and the like.Type: GrantFiled: April 26, 1979Date of Patent: December 9, 1980Assignee: The United States of America as represented by the Secretary of the Air ForceInventor: Warren R. Griffin
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Patent number: 4219625Abstract: As an additive imparting oil and water repellency, durable against laundering and abrasion, to PET fibers: a partially or fully acylated polyol, especially pentaerythritol, glycerol, hydroquinone or ethylene glycol, acylated with a phthalic or terephthalic monoester having a perfluorinated alkyl or alkoxyalkyl C.sub.2 to C.sub.20 radical, especially C.sub.5 to C.sub.10 n-alkyl or (CF.sub.2).sub.n OR.sub.f where R.sub.f is C.sub.1 to C.sub.6 perfluoroalkyl, especially perfluoroisopropyl and (CF.sub.2).sub.n is a straight chain C.sub.2 to C.sub.10 diradical.Type: GrantFiled: December 16, 1977Date of Patent: August 26, 1980Assignee: Allied Chemical CorporationInventors: Frank Mares, Bryce C. Oxenrider, Cyril Woolf
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Patent number: 4217440Abstract: A method for preparing branched polyesters in melt or solid phase comprises reacting together diols, diacids and polyfunctional modifiers having at least three functional radicals to form a condensation polymer. This condensation polymer is polycondensed to form a polyester by linear extension and branching while correlating catalyst activity, reaction temperature and pressure to restrain the extent of reaction for linear extension to within about 0.1 percent of the extent of reaction for branching.Type: GrantFiled: August 20, 1979Date of Patent: August 12, 1980Assignee: Eastman Kodak CompanyInventor: Kenneth T. Barkey
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Patent number: 4206025Abstract: Radio-hardenable acrylic polyesters of the general formula:[A][B--C--D.sub.m ].sub.2 (I)wherein A is the radical of a linear polyester of the general formula:--O--[R.sub.1 --R.sub.2 ].sub.x R.sub.1 --O-- (II)wherein R.sub.1 is a radical derived from at least one dihydroxylated compound, R.sub.2 a radical derived from at least one dicarboxylic acid and x an integer from 1 to 20; wherein B has the same meaning as R.sub.2, C is a radical derived from at least one aliphatic polyhydroxylated compound, D a radical derived from acrylic acid and m is an integer from 2 to 7.Manufacture of said polyesters and use as binders in radio-hardenable compositions.Type: GrantFiled: September 5, 1978Date of Patent: June 3, 1980Assignee: U C B, Societe AnonymeInventors: August Vrancken, Paul Dufour
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Patent number: 4184035Abstract: Disclosed is a process for neutralizing an inorganic acid in the presence of a halogenated aliphatic polybasic acid or anhydride. The neutralization is carried out by adding to said acid or anhydride a primary or secondary amine containing at least two active hydrogen atoms per molecule as determined by the Zerewittenoff Method, and neutralizing the inorganic acid in the presence of the polybasic acid or anhydride. In one embodiment, the halogenated aliphatic or alicyclic polybasic acid or anhydride is present in a mixture wth a halogenated aromatic polybasic acid or anhydride and with a polyol and the neutralization is carried out before substantial polymerization occurs between the acids and polyol.Type: GrantFiled: September 9, 1974Date of Patent: January 15, 1980Assignee: Velsicol Chemical CorporationInventor: Otto K. Goins
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Patent number: 4182842Abstract: Disclosed are poly(ester-amides) prepared from an aromatic dicarboxylic acid, ethylene glycol and a p-acylaminobenzoic acid.Type: GrantFiled: November 3, 1978Date of Patent: January 8, 1980Assignee: Eastman Kodak CompanyInventors: Winston J. Jackson, Herbert F. Kuhfuss
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Patent number: 4180652Abstract: A novel polyester type powder coating composition which includes a specific self-hardening polyester of air-hardening type comprising as main ester-constituting monomer units, (1) at least one polycarboxylic acid component containing at least 10 mole %, based on the polycarboxylic acid component, of at least one aromatic polycarboxylic acid component (A) and (2) at least one polyhydric alcohol component, having in its main chain at least one terminal blocked with a monofunctional unsaturated alicyclic compound component (B) and having a softening point of 30.degree. to 150.degree. C. This composition is excellent in storage stability and adaptability to either thin coating or thick coating, and when it is applied onto an article to be coated and baked at a temperature of 170.degree. to 230.degree. C. for 5 to 30 minutes, a coating excellent in appearance, mechanical strength, gloss and reflection sharpness can be formed advantageously without generating undesired gases at the baking.Type: GrantFiled: February 16, 1978Date of Patent: December 25, 1979Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Sumitaka Nogami, Yoshio Matsumoto, Keiichi Waki, Tooru Okada
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Patent number: 4175072Abstract: Light-colored unsaturated polyester resins containing at least 2% by weight bromine can be prepared by using at least a portion of the glycol ingredient dibromo neopentyl glycol and by using from 5 to 85 mol percent of tetrahydrophthalic acid or anhydride or endomethylene tetrahydrophthalic acid or anhydride.Type: GrantFiled: May 24, 1978Date of Patent: November 20, 1979Assignee: Freeman Chemical CorporationInventors: Alan J. Parr, Bryan O. Brown
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Patent number: 4153779Abstract: Disclosed is a liquid crystal copolyester having unobviously high mechanical properties. The copolyester is prepared from an aromatic dicarboxylic acid, a substituted phenylhydroquinone and optionally other hydroquinones.Type: GrantFiled: June 26, 1978Date of Patent: May 8, 1979Assignee: Eastman Kodak CompanyInventors: Winston J. Jackson, Jr., Gary G. Gebeau, Herbert F. Kuhfuss
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Patent number: 4134881Abstract: Polyester polymers consisting essentially of ester condensation products of specific proportions of propylene glycol, adipic and fumaric acids, isophthalic acid and halogenated phthalic anhydride, and cured resins containing such polymers. The polymers are particularly useful in high performance matrices for fiber composites requiring properties including a combination of high heat deflection temperature and high tensile elongation.Type: GrantFiled: August 5, 1977Date of Patent: January 16, 1979Assignee: Cargill, IncorporatedInventors: Robert W. Cuddihy, Daniel S. Knoebel
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Patent number: 4134934Abstract: An improvement in an unsaturated polyesters having recurring units of the formula ##STR1## wherein A is the residue of an alcoholic moiety and B is the residue of an acid moiety, which improvement resides in the fact that some of the A residues are chloroxylylene containing residues having the formula ##STR2##Type: GrantFiled: January 9, 1978Date of Patent: January 16, 1979Assignee: Dynamit Nobel AktiengesellschaftInventors: Georg Blumenfeld, Norbert Vollkommer
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Patent number: 4130579Abstract: Aromatic-aliphatic dinitriles of the formula ##STR1## in which Ar is an arylene or substituted arylene are useful in the preparation of the corresponding amines which are intermediates for the preparation of thermally stable, rigid, polyamides.Type: GrantFiled: June 8, 1977Date of Patent: December 19, 1978Assignee: E. I. Du Pont de Nemours and CompanyInventors: August H. Frazer, John F. Harris, Jr., Elmore L. Martin
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Patent number: 4113703Abstract: An improvement in an unsaturated polyesters having recurring units of the formula ##STR1## wherein A is the residue of an alcoholic moiety and B is the residue of an acid moiety, which improvement resides in the fact that some of the A residues are chloroxylylene containing residues having the formula ##STR2##Type: GrantFiled: December 12, 1975Date of Patent: September 12, 1978Assignee: Dynamit Nobel AktiengesellschaftInventors: Georg Blumenfeld, Norbert Vollkommer
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Patent number: 4101528Abstract: A flame-retardant filament-forming copolymer of at least 75 mol % of ethylene-2,6-naphthalene dicarboxylate units and at least 3 mol % up to 25 mol % of randomly copolymerized esters units having bromine or chlorine chemically united with either the diacid residue or both the diacid residue and the diol residue of said ester units. In addition, fibers of the above flame-retardant copolyester resin and flame-retardant cellulosic fibers are blended together to provide flame-retardant yarns and fabrics of excellent physical properties.Type: GrantFiled: June 16, 1977Date of Patent: July 18, 1978Assignee: Avtex Fibers Inc.Inventor: William N. Knopka