Two Or More Carboxylic Acid Or Derivatives Or Mixtures Thereof Patents (Class 528/302)
  • Patent number: 8409677
    Abstract: Disclosed is a composition comprising an aliphatic-aromatic copolyester consisting essentially of a dicarboxylic acid component that includes a terephthalic acid component and a linear aliphatic dicarboxylic acid component, a glycol component consisting essentially of a linear aliphatic glycol component and 0 to 4 mole percent based on 100 mole percent total glycol component of a dialkylene glycol component and at least one additional component; starch; water; and polyol plasticizer. Also described are shaped articles such as films which exhibit greater than expected tear strength and methods for preparing the films.
    Type: Grant
    Filed: January 11, 2011
    Date of Patent: April 2, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventors: Barry Alan Morris, Edward J Stancik, Mark F Teasley
  • Publication number: 20130078431
    Abstract: The present invention relates to: a composition for label base containing a polyester resin having a repeating unit formed by condensation of an aliphatic dicarboxylic acid and an aliphatic diol; a method for producing a label base containing developing the composition for label base to form a solid image having a label shape, transferring the solid image onto a pressure-sensitive adhesive layer side of a release paper, and fixing the transferred solid image on the pressure-sensitive adhesive layer by heat and pressure application into a film shape; and a label containing the label base and a label image provided thereon obtained by transferring a toner image to the label base and fixing the transferred toner image to the label base by heat and pressure application
    Type: Application
    Filed: September 12, 2012
    Publication date: March 28, 2013
    Applicants: CASIO COMPUTER CO., LTD., CASIO ELECTRONICS MANUFACTURING CO., LTD.
    Inventors: Tomohumi SANO, Toshiaki KANAMURA
  • Publication number: 20130071588
    Abstract: This invention relates to an aliphatic-aromatic copolyester characterised in that it has appreciable workability properties even when mixed with other polymers, appreciable toughness and high values for ultimate tensile strength and elastic modulus. This invention also relates to mixtures of the said copolyester with other polymers.
    Type: Application
    Filed: May 24, 2011
    Publication date: March 21, 2013
    Applicant: NOVAMONT S.p.A.
    Inventors: Catia Bastioli, Giampietro Borsotti, Luigi Capuzzi, Tiziana Milizia, Roberto Vallero
  • Publication number: 20130059957
    Abstract: One aspect of the invention is polyester compositions containing: (I) at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) 70 to 100 mole % of terephthalic acid residues; (ii) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and (iii) 0 to 10 mole % of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) a glycol component comprising: (i) 1 to 99 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and (ii) 1 to 99 mole % of cyclohexanedimethanol residues; and (II) at least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the glycol component is 100 mole %.
    Type: Application
    Filed: August 28, 2012
    Publication date: March 7, 2013
    Applicant: Eastman Chemical Company
    Inventors: Ted Calvin Germroth, Gary Wayne Connell, Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, Benjamin Fredrick Barton, Damon Bryan Shackelford
  • Patent number: 8389117
    Abstract: Disclosed are hot-melt adhesives prepared from polyesters containing 1,4-cyclohexane-dicarboxylic acid as a diacid component and a diol component containing at least two diols chosen from 1,4-cyclohexanedimethanol, triethylene glycol, and diethylene glycol. These adhesives set up rapidly within a well-defined temperature window. The hot-melt adhesives can be used in a variety of applications, but are especially suited as seaming adhesives for roll-applied labels. These adhesives have melting temperatures and crystallization properties that allow their application at temperatures cool enough to prevent curling and premature shrinkage of the shrink label during seaming, and yet produce strong label seams that can withstand the elevated temperatures of a shrink tunnel without sacrificing line speed. Also disclosed are labeled containers and a process for applying a roll-on, shrink label to a container using the hot-melt adhesives of the invention.
    Type: Grant
    Filed: October 12, 2009
    Date of Patent: March 5, 2013
    Assignee: Eastman Chemical Company
    Inventors: Marcus David Shelby, Scott Ellery George, Gary Robert Robe, Freddie Wayne Williams, Michael Eugene Donelson, Joshua Seth Cannon, Emmett Patrick O'Brien, Jeremy Richard Lizotte, Anthony Joseph Pasquale
  • Patent number: 8372325
    Abstract: Endolumenal prostheses that readily and extensively convert from a delivery configuration to a deployed configuration are disclosed. Endolumenal prostheses may be fabricated from one or more shape memory polymers, a high modulus elastomer, a polymer that is both elastomeric and exhibits shape memory behavior, a hydrogel, or some combination thereof. Polymers used to fabricate the prostheses are selectively synthesized to exhibit desired characteristics such as crystallinity, strain fixity rate, strain recovery rate, elasticity, tensile strength, mechanical strength, cross-linking density, extent physical cross-linking, extent of covalent cross-linking, extent of interpenetrating networks, rate of erosion, heat of fusion, crystallization temperature, and acidity during erosion. The endolumenal prostheses convert to the deployed configuration following delivery to a treatment site, upon exposure to an initiator either present within the body naturally or introduced into the body.
    Type: Grant
    Filed: April 22, 2008
    Date of Patent: February 12, 2013
    Assignee: SyneCor LLC
    Inventors: Michael S. Williams, Robert S. Langer, Yadong Wang
  • Publication number: 20130022906
    Abstract: A polyester resin for a toner including: a repeating unit derived from a dicarboxylic acid component; and a repeating unit derived from a diol component represented by Formula 1: wherein each of R1 and R2 independently represents a hydrogen atom or a methyl group, each of L1, L2 and L3 independently represents a divalent linking group selected from the group consisting of carbonyl groups, ester groups, ether groups, sulfonyl groups, substituted or unsubstituted chained alkylene groups, substituted or unsubstituted cyclic alkylene groups, substituted or unsubstituted arylene groups, and combinations thereof, L1 and L2 or L1 and L3 optionally forms a ring, and each of A1 and A2 independently represents a rosin ester group, wherein the solubility parameter (SP) value is from 9.1 to 9.7.
    Type: Application
    Filed: September 25, 2012
    Publication date: January 24, 2013
    Applicant: FUJI XEROX CO., LTD.
    Inventor: FUJI XEROX CO., LTD.
  • Publication number: 20130018130
    Abstract: Biodegradable compositions containing an aliphatic-aromatic copolyester derived from aromatic polyesters. Methods of making the compositions and articles made from the compositions.
    Type: Application
    Filed: July 15, 2011
    Publication date: January 17, 2013
    Applicant: SABIC INNOVATIVE PLASTICS IP B.V.
    Inventors: Husnu Alp ALIDEDEOGLU, Ganesh KANNAN
  • Publication number: 20130017333
    Abstract: The invention relates to a polyester AB comprising moieties derived from di- or polyfunctional organic acid compounds A and moieties derived from di- or polyfunctional organic hydroxy compounds B, wherein the compounds A comprise “hard” acid compounds A1 having two or more acid groups per molecule, and soft acid compounds A2, and the compounds B comprise “hard” hydroxyfunctional compounds B1 having two or more hydroxyl groups per molecule, and soft hydroxyfunctional compounds B2, and coating compositions prepared from these with crosslinkers selected from the group consisting of isocyanates, capped isocyanates, aminoplast crosslinkers, and phenoplast crosslinkers, as well as their application in coating of metal substrates.
    Type: Application
    Filed: November 22, 2010
    Publication date: January 17, 2013
    Applicant: Cytec Austria GmbH
    Inventors: Roland Feola, Johann Gmoser, Oliver Etz
  • Patent number: 8354491
    Abstract: Described are container(s) comprising polyesters comprising (a) a dicarboxylic acid component comprising terephthalic acid residues; optionally, aromatic dicarboxylic acid or aliphatic dicarboxylic acid residues; and (b) a glycol component comprising 15 to 50 mole % 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and 50 to 85 mole % 1,4-cyclohexanedimethanol residues; wherein the total mole % of said dicarboxylic acid component is 100 mole %, and the total mole % of said glycol component is 100 mole %; wherein the inherent viscosity of the polyester is from 0.50 to 0.75 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C.; wherein said polyester has a notched Izod impact strength of at least 7.5 ft-lb/inch at 23° C. according to ASTM D256 with a 10-mil notch in a 1/8-inch thick bar; and wherein the melt viscosity of said polyester is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C.
    Type: Grant
    Filed: January 28, 2011
    Date of Patent: January 15, 2013
    Assignee: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, David Scott Porter, Gary Wayne Connell, Michael James Keegan
  • Publication number: 20130011631
    Abstract: A laminate film including at least one bio-based polyester layer. The polyester layer has a radiocarbon (14C) content of at least 21.5 pMC. The laminate film may further have additional layers such as a second bio-based polyester resin-containing layer of at least about 21.5 pMC radiocarbon content, a metal layer, or combinations thereof.
    Type: Application
    Filed: July 8, 2011
    Publication date: January 10, 2013
    Applicant: TORAY PLASTICS (AMERICA), INC.
    Inventors: Stefanos L. SAKELLARIDES, Keunsuk P. CHANG
  • Patent number: 8344093
    Abstract: An object of the present invention is to provide a method for efficient continuous production of aliphatic polyester having good quality. The invention relates to a continuous production method of aliphatic polyester, wherein the polyester is obtained through a preparation step of slurry containing aliphatic dicarboxylic acid and aliphatic diol, an esterification reaction step and a polycondensation reaction step, wherein temperature range of the slurry during the preparation step thereof is from the coagulation point of the aliphatic diol to 80° C., and moisture content in the slurry is from 0.01 to 10% by weight.
    Type: Grant
    Filed: March 23, 2009
    Date of Patent: January 1, 2013
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Shinichiro Matsuzono, Toshiyuki Hamano, Hiromichi Matsui
  • Patent number: 8324316
    Abstract: Disclosed are unsaturated polyester resins comprising residues of 1,2-propanediol, 2,2,4,4-tetramethyl-1,3-cyclobutanediol, an aliphatic, cycloaliphatic, or aromatic diacid, and 2-butenedioic acid. Also disclosed are curable compositions containing admixtures of the unsaturated polyesters and aromatic vinyl compounds copolymerizable with the unsaturated polyesters, and coatings and casted and molded articles obtained from the curable compositions. The curable compositions are useful for coatings and casted and molded articles that have at least one surface that is persistently exposed to organic or aqueous liquids.
    Type: Grant
    Filed: February 6, 2009
    Date of Patent: December 4, 2012
    Assignee: Eastman Chemical Company
    Inventors: Jeffery Earl Powell, Angela Hartley Honeycutt
  • Patent number: 8318893
    Abstract: An aliphatic polyester resin having excellent moldability and its production method are provided. When the amount of specific structural units contained in an aliphatic polyester resin is adjusted to an optimum amount, an aliphatic polyester resin having sufficient melt tension at the time of molding and excellent moldability than in the past and its production method is provided.
    Type: Grant
    Filed: December 10, 2008
    Date of Patent: November 27, 2012
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Toyomasa Hoshino, Shinichiro Matsuzono, Hiroyuki Kaneko, Toshiyuki Hamano, Takayuki Aoshima, Tadashi Ueda
  • Patent number: 8309217
    Abstract: Disclosed is an easy adhesion film which attains sufficient adhesiveness in various processings without using any crosslinking agent such as a melamine resin to possibly pollute the environment and has a primer layer excellent in high-temperature hot water resistance. In the easy adhesion film, a coating film including a polyester resin and a crosslinking agent component in a content of 0.1% by mass or less, inclusive of 0% by mass, is formed on at least one side of a substrate film. The sum of the acid number and the hydroxyl number of the polyester resin is 50 to 200 mg KOH/g, wherein the acid number is 20 to 60 mg KOH/g and the hydroxyl number is 30 to 150 mg KOH/g. The amount of the oligomers contained in the polyester is 2.0% by mass or less. The thickness of the coating film is 0.001 to 0.5 ?m.
    Type: Grant
    Filed: February 12, 2008
    Date of Patent: November 13, 2012
    Assignee: Unitika Ltd.
    Inventors: Takayoshi Okuzu, Hideki Kuwata
  • Patent number: 8309229
    Abstract: The invention discloses specific polyester resins which are obtained by the technique of reacting polyesterpolyol oligomer of specific monomeric composition further with polyvalent carboxylic acid (anhydride) and the like; thermosetting water-borne coating compositions using the polyester resins, and coating film-forming methods using the thermosetting water-borne coating compositions.
    Type: Grant
    Filed: June 9, 2005
    Date of Patent: November 13, 2012
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Shuichi Nakahara, Hiromi Harakawa
  • Patent number: 8304490
    Abstract: It is an object of the present invention to provide polylactic acid containing a stereocomplex crystal and having excellent moldability, a high molecular weight, high crystallinity and a high melting point and a process for manufacturing the same. It is another object of the present invention to provide a composition comprising the polylactic acid and a molded product of the polylactic acid. The present invention is characterized from polylactic acid having a weight average molecular weight of 80,000 to 500,000 and a melting peak at 195° C. or higher which accounts for 80% or more of the total of melting peaks in the temperature elevation step when measured by a differential scanning calorimeter (DSC) and a process for manufacturing the same.
    Type: Grant
    Filed: July 20, 2005
    Date of Patent: November 6, 2012
    Assignees: Teijin Limited, Musashino Chemical Laboratory, Ltd, Mutual Corporation
    Inventors: Yoshiharu Kimura, Zhen Tang, Kazuki Fukushima, Kiyotsuna Toyohara, Ryuji Nonokawa, Yasuhito Maeda, Masayuki Takada, Yuka Komazawa, Tsuyoshi Aoki
  • Patent number: 8299204
    Abstract: Described as one aspect of the invention are polyester compositions containing: (I) at least one polyester which comprises: (a) dicarboxylic acid component comprising: (i) 70 to 100 mole % of terephthalic acid residues; (ii) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 20 carbons atoms; and (iii) 0 to 10 mole % of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) a glycol component comprising: (i) 1 to 99 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and (ii) 1 to 99 mole % of cyclohexanedimethanol residues; and (II) at least one thermal stabilizer chosen from at least one alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the glycol component is 100 mole %.
    Type: Grant
    Filed: October 27, 2006
    Date of Patent: October 30, 2012
    Assignee: Eastman Chemical Company
    Inventors: Ted Calvin Germroth, Gary Wayne Connell, Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephen McWilliams, Benjamin Fredrick Barton, Damon Bryan Shackelford
  • Publication number: 20120260436
    Abstract: Disclosed is a fiber made of a polyester resin, wherein the polyester resin is a copolymer including a dicarboxylic acid component and a glycol component; of the dicarboxylic acid component, 80 mol % or more is accounted for by a terephthalic acid component, 4.0 to 12.0 mol % is accounted for by a cyclohexane dicarboxylic acid component, and 2.0 to 8.0 mol % is accounted for by an adipic acid component; and the glycol component contains an ethylene glycol component as a main component thereof. A polyester fiber is thereby provided which can be dyed with excellent deep color property and fastness property in dyeing under a normal pressure environment and which can offer stable quality and processing performance also by a direct spinning stretching method or other general melt-spinning methods.
    Type: Application
    Filed: December 3, 2010
    Publication date: October 18, 2012
    Applicant: KURARAY CO., LTD.
    Inventors: Kazuhide Oka, Hiroyuki Nakada, Masao Kawamoto, Kazuhiko Tanaka
  • Patent number: 8287970
    Abstract: The invention is generally directed to baby bottles and other articles produced by blow molding from polymeric materials having glass transition temperatures ranging from 100° C. to 130° C., as well as to processes for producing them. These articles can be exposed to boiling water and can be produced by using a suitable combination of a stretch ratio of less than 3 and a preform temperature at least 20° C. greater than the glass transition temperature (Tg) of the polymeric material.
    Type: Grant
    Filed: November 20, 2008
    Date of Patent: October 16, 2012
    Assignee: Eastman Chemical Company
    Inventors: Thomas Joseph Pecorini, Spencer Allen Gilliam, Alan Keith Phillips
  • Patent number: 8287991
    Abstract: Disclosed are laminated articles comprising a first polymer layer and a second polymer layer having an inclusion embedded between the layers, wherein at least one layer comprises a branching agent to improve dimensional stability during the lamination process. Disclosed are laminated articles comprising a first polymer layer and a second polymer layer having an inclusion embedded between the layers, wherein at least one layer comprises a copolyester comprising a branching agent to improve dimensional stability during the lamination process. Also disclosed are methods of laminating a first layer and a second layer with an inclusion between the layers to form a laminated article with an embedded inclusion, wherein at least one layer comprises a copolyester comprising a branching agent.
    Type: Grant
    Filed: July 13, 2007
    Date of Patent: October 16, 2012
    Assignee: Eastman Chemical Company
    Inventors: Michael Eugene Donelson, Ryan Thomas Neill, James Collins Maine, Bryan Steven Bishop, Robert Erik Young
  • Publication number: 20120231283
    Abstract: The invention relates to a carboxylic acid functional branched polyester for thermosetting powder coating composition, wherein said polyester is prepared from at least the following monomers: a difunctional aromatic acid, the difunctional aromatic acid being a combination of terephthalic acid (TPA), isophthalic acid (IPA), an at least trifunctional monomer and a difunctional alcohol, the difunctional alcohol being a combination of at least ethylene glycol (EG) and/or diethylene glycol (DEG) and neopentyl glycol (NPG), the molar ratio of TPA to IPA in the carboxylic acid functional branched polyester is at most 12.4, and the functionality of the carboxylic acid functional branched polyester is from 2.15 to 4.0, and the carboxylic acid functional branched polyester has an acid value of from 14 to 80 mg KOH/g resin, and the carboxylic acid functional branched polyester has a glass transition temperature of at least 40C.
    Type: Application
    Filed: April 28, 2010
    Publication date: September 13, 2012
    Inventors: Paulus Franciscus Anna Buijsen, Juul Cuijpers, Marcellinus Hermanus Johannes Schutte, Johannes Albertus Hettinga
  • Patent number: 8263731
    Abstract: The present invention relates to multilayer optical films and birefringent copolyester films. The birefringent copolyester optical layer or birefringent copolyester film comprises a major amount of naphthalate units, ethylene units, and a minor amount of branched or cyclic C4 to C10 alkyl units. Also described are certain copolyester polymeric materials further comprising subunits of a phthalate ionomer such as dimethyl sulfosodium isophthalate ionomer.
    Type: Grant
    Filed: July 14, 2011
    Date of Patent: September 11, 2012
    Assignee: 3M Innovative Properties Company
    Inventors: Yufeng R. Liu, David T. Yust, Stephen A. Johnson, Kristopher J. Derks
  • Publication number: 20120220676
    Abstract: The present invention relates to polyesters that can be prepared from renewable resources and/or recycled materials, to their use and their production process. In particular there are provided hydroxyl-functional or carboxyl-functional polyesters comprising moieties of (e) terephthalic acid and/or isophthalic acid, (f) ethylene glycol, (g) a dianhydrohexitol, and of (h) one or more linear chain dicarboxylic acids; wherein the polyester has a number average molecular weight, as measured by gel permeation chromatography, of from 400 to 15000 daltons, more preferably from 550 to 15000 daltons. Polyesters of the invention can basically be prepared from recycled polyethylene terephthalate and from renewable polyacids and/or polyols. The present invention further provides a process to produce such polyesters via glycolysis of a polyethylene terepthalate and/or a polyethylene isophthalate with a dianhydrohexitol.
    Type: Application
    Filed: November 12, 2010
    Publication date: August 30, 2012
    Inventor: Luc Moens
  • Publication number: 20120220680
    Abstract: The present invention relates to biodegradable aliphatic-aromatic polyesters obtained from aliphatic dicarboxylic acids, polyfunctional aromatic acids and diols, wherein the polyfunctional aromatic acids are constituted by mixtures of acids of renewable and synthetic origin.
    Type: Application
    Filed: November 5, 2010
    Publication date: August 30, 2012
    Applicant: Novamont S.P.A.
    Inventors: Catia Bastioli, Giampietro Borsotti, Luigi Capuzzi, Gian Tomaso Masala, Tiziana Milizia, Roberto Vallero
  • Publication number: 20120184708
    Abstract: A polyester for a toner obtained by polycondensing an aliphatic hydroxycarboxylic acid compound having a total number of hydroxy group or groups and carboxyl group or groups of 4 or more; an alcohol component containing an aliphatic diol having a hydroxyl group bound to a secondary carbon atom in an amount of 50% by mol or more; and a carboxylic acid component, provided that the aliphatic hydroxycarboxylic compound is not included, wherein the aliphatic hydroxycarboxylic acid compound and the aliphatic diol having a hydroxyl group bound to a secondary carbon atom are in a molar ratio, i.e. the aliphatic hydroxycarboxylic acid compound/the aliphatic diol having a hydroxyl group bound to a secondary carbon atom, of from 0.05 to 0.8; a resin binder for a toner, containing the polyester; and a toner for electrophotography, containing the resin binder.
    Type: Application
    Filed: September 30, 2010
    Publication date: July 19, 2012
    Applicant: Kao Corporation
    Inventors: Norihiro Fukuri, Takashi Kubo, Katsutoshi Aoki, Yasunori Inagaki
  • Publication number: 20120172520
    Abstract: Disclosed are polyester resins and solvent borne thermosetting coating compositions that include these resins in combination with at least one crosslinker. The polyester resins contain 2,2,4,4-tetramethyl-1,3-cyclobutanediol and exhibit a combination of good solubility in organic solvents and high hardness with good flexibility in a coating composition.
    Type: Application
    Filed: March 13, 2012
    Publication date: July 5, 2012
    Applicant: Eastman Chemical Company
    Inventors: Stacey James Marsh, Angela Hartley Honeycutt
  • Patent number: 8211827
    Abstract: The present invention relates to a dye receptor layer composition for thermal transfer image-receiving sheets which includes (a) a resin dispersion containing a polyester-containing resin, (b) a glycol ether having a boiling point of from 160° C. to 280° C. and a vapor pressure at 20° C. of from 20 to 1,000 Pa and (c) an oxazoline group-containing compound, and is excellent in film-forming property; and a thermal transfer image-receiving sheet obtained from the composition which can be dried at a low temperature for a short period of time, exhibits a low heat fusibility, is excellent in releasability, printing sensitivity and imaging performance, and can produce images with a high density.
    Type: Grant
    Filed: November 20, 2008
    Date of Patent: July 3, 2012
    Assignee: KAO Corporation
    Inventors: Nobumichi Kamiyoshi, Takashi Mukai, Shinichi Sata
  • Patent number: 8207289
    Abstract: Polyester compositions, especially polyethylene terephthalate homopolymer and copolymers, are disclosed containing titanium catalysts and catalyst deactivator added late in the manufacturing processing having reduced acetaldehyde generation rates. The polyester compositions are low in free acetaldehyde, making them suitable for fabrication into beverage containers for relatively tasteless beverages such as bottle water. Furthermore, the polyesters are polymerized to a high inherent viscosity in reduced processing time, without the necessity of further polymerization in the solid state, and in the absence of acetaldehyde scavengers leading to polyester polymers having reduced color.
    Type: Grant
    Filed: May 23, 2007
    Date of Patent: June 26, 2012
    Assignee: Grupo Petrotemex, S.A. de C.V.
    Inventor: Mary Therese Jernigan
  • Patent number: 8202921
    Abstract: The invention provides aqueous resin emulsion containing a resin obtained by reaction of a composition containing at least: at least one polyhydric alcohol having at least two hydroxyl groups, at least one polyetherpolyol having a molecular weight of 400 to 8000 g/mol, at least one monobasic carboxylic acid, and at least one polybasic carboxylic acid having at least two carboxyl groups or its anhydride, to form a resin and the resin emulsion is modified by providing basic groups. The invention further relates to a process for preparing a resin, to a resin as obtained by the process and to a coating film obtained from the resin emulsion.
    Type: Grant
    Filed: April 25, 2006
    Date of Patent: June 19, 2012
    Assignee: Ashland—Sudchemie-Kernfest GmbH
    Inventors: Peter Kuhlmann, Reinhard Winter, Kurt Holzhäuser
  • Patent number: 8193299
    Abstract: Biodegradable aliphatic/aromatic copolyester comprising: A) an acid component comprising repeating units of: 1) 53 to 54 mol % of an aromatic carboxylic acid; 2) 47 to 36 mol % of an aliphatic acid at least 50% of which is azelaic acid; B) a diol component selected from the group consisting of C3, C4 and C6 diols; said AAPE being disintegrated according to the Standard ISO 20200 in 90 days.
    Type: Grant
    Filed: March 17, 2006
    Date of Patent: June 5, 2012
    Assignee: Novamont S.p.A.
    Inventors: Catia Bastioli, Tiziana Milizia, Giovanni Floridi, Andrea Scaffidi Lallaro, Giandomenico Cella, Maurizio Tosin
  • Patent number: 8193301
    Abstract: Biodegradable aliphatic/aromatic copolyester comprising: A) an acid component comprising repeating units of: 1) 49 to 63 mol % of an aromatic carboxylic acid; 2) 51 to 37 mol % of an aliphatic carboxylic acid, at least 50% of which is brassylic acid; B) a diol component; said copolyester being disintegrated according to the Standard ISO 20200 in 90 days.
    Type: Grant
    Filed: March 17, 2006
    Date of Patent: June 5, 2012
    Assignee: Novamont S.p.A.
    Inventors: Catia Bastioli, Tiziana Milizia, Giovanni Floridi, Andrea Scaffidi Lallaro, Giandomenico Cella, Maurizio Tosin
  • Patent number: 8193300
    Abstract: Biodegradable aliphatic/aromatic copolyester comprising 49 to 66 mol % of an aromatic polyfunctional acid; 51 to 34 mol % of an aliphatic acid, at least 70% of which is sebacic acid; and butandiol; and blends containing such copolyester.
    Type: Grant
    Filed: March 17, 2006
    Date of Patent: June 5, 2012
    Assignee: Novamont S.p.A.
    Inventors: Catia Bastioli, Tiziana Milizia, Giovanni Floridi, Andrea Scaffidi Lallaro, Giandomenico Cella, Maurizio Tosin
  • Patent number: 8193302
    Abstract: Described as one aspect of the invention are polyester compositions containing: (I) at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) 70 to 100 mole % of terephthalic acid residues; (ii) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and (iii) 0 to 10 mole % of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) a glycol component comprising: (i) 1 to 99 mole % of 2,2,4,4-tetramethyl-1,3 -cyclobutanediol residues; and (ii) 1 to 99 mole % of cyclohexanedimethanol residues; and (II) at least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the glycol component is 100 mole %.
    Type: Grant
    Filed: October 27, 2006
    Date of Patent: June 5, 2012
    Assignee: Eastman Chemical Company
    Inventors: Ted Calvin Germroth, Gary Wayne Connell, Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, Benjamin Fredrick Barton, Damon Bryan Shackelford
  • Patent number: 8193298
    Abstract: Biodegradable aliphatic/aromatic copolyester comprising 50 to 60 mol % of an aromatic dicarboxylic acid and 40 to 50 mol % of an aliphatic acid, at least 90% of which is a long-chain dicarboxylic acid (LCDA) of natural origin selected from azelaic acid, sebacic acid, brassylic acid or mixtures thereof; and a diol component.
    Type: Grant
    Filed: March 17, 2006
    Date of Patent: June 5, 2012
    Assignee: Novamont S.p.A.
    Inventors: Catia Bastioli, Tiziana Milizia, Giovanni Floridi, Andrea Scaffidi Lallaro, Giandomenico Cella, Maurizio Tosin
  • Publication number: 20120108784
    Abstract: A nongelling and noncrosslinked, highly branched or hyperbranched polyester, obtained by reacting at least one selected from the group consisting of a monocarboxylic acid, a dicarboxylic acid, a tricarboxylic acid, a polycarboxylic acid, and a derivative thereof with at least one selected from the group consisting of a monoalcohol, a diol, a triol, a tetraol, and a polyol, wherein an average functionality of the carboxyl groups (f.A) and the hydroxyl groups (f.B) in a notionally hydrolyzed polyester satisfies a relation: f.A+f.B>4, a mole fraction of the carboxyl groups (x.A) in the notionally hydrolyzed polyester satisfies a relation: f.A/[(f.A*f.B)+f.A]?x?(f.A*f.B)/[(f.A*f.B)+f.B], and a degree of conversion (U) of the deficit functionality satisfies a relation: U.min?U?U.max.
    Type: Application
    Filed: January 6, 2012
    Publication date: May 3, 2012
    Applicant: BASF SE
    Inventors: Joachim Clauss, Marta Martin-Portugues, Harald Schäfer, Daniel Schönfelder, Bernd Bruchmann
  • Patent number: 8168721
    Abstract: Disclosed are solvent borne thermosetting coating compositions that contain a curable polyester resin blended with an acrylic copolymer, a crosslinker, and a solvent. The polyester resin contains 2,2,4,4-tetramethyl-1,3-cyclobutanediol and exhibits good dry time, compatibility with acrylic resins, sag resistance and hardness development in a coating composition. The coating compositions can be used to prepare clear coat or pigmented coatings for automotive OEM, auto refinish, and other applications.
    Type: Grant
    Filed: February 6, 2009
    Date of Patent: May 1, 2012
    Assignee: Eastman Chemical Company
    Inventors: Stacey James Marsh, Angela Hartley Honeycutt, Deepanjan Bhattacharya
  • Patent number: 8168302
    Abstract: A multilayered polymer film includes a first set of optical layers and a second set of optical layers. The first set of optical layers is made from a polyester which is often birefringent. The polyesters of the first set of optical layers typically have a composition in which 70-100 mol % of the carboxylate subunits are first carboxylate subunits and 0-30 mol % are comonomer carboxylate subunits and 70 to 100 mol % of the glycol subunits are first glycol subunits and 0 to 30 mol % of the glycol subunits are comonomer glycol subunits, where at least 0.5 mol % of the combined carboxylate and glycol subunits are comonomer carboxylate or comonomer glycol subunits. The multilayered polymer film may be used to form, for example, a reflective polarizer or a mirror.
    Type: Grant
    Filed: November 10, 2008
    Date of Patent: May 1, 2012
    Assignee: 3M Innovative Properties Company
    Inventors: Timothy J. Hebrink, William W. Merrill, Carl A. Stover
  • Patent number: 8163843
    Abstract: A description is given of the preparation of high molecular mass, crystalline copolyesters with high solubility in non-halogenated and non-aromatic solvents, and of their use in adhesives.
    Type: Grant
    Filed: January 8, 2008
    Date of Patent: April 24, 2012
    Assignee: Evonik Degussa GmbH
    Inventors: Gabriele Brenner, Rene Koschabek, Georg Becker
  • Patent number: 8163850
    Abstract: Disclosed are polyester resins and solvent borne thermosetting coating compositions that include these resins in combination with at least one crosslinker. The polyester resins contain 2,2,4,4-tetramethyl-1,3-cyclobutanediol and exhibit a combination of good solubility in organic solvents and high hardness with good flexibility in a coating composition.
    Type: Grant
    Filed: February 6, 2009
    Date of Patent: April 24, 2012
    Assignee: Eastman Chemical Company
    Inventors: Stacey James Marsh, Angela Hartley Honeycutt
  • Publication number: 20120082785
    Abstract: A back sheet for a solar cell, consisting of a polyester comprising at least one repeating unit of trimethylene naphthalate and trimethylene terephthalate in an amount of 85% by weight or more, has improved hydrolysis-resistance and is useful in the field requiring weatherability.
    Type: Application
    Filed: June 9, 2010
    Publication date: April 5, 2012
    Applicant: SKC CO., LTD.
    Inventors: Nam Ill Kim, Soo Hee Kim, Sung Jun Yoon
  • Patent number: 8143368
    Abstract: Hydrolytically degradable polymers in the form of biodegradable disposable medical devices for use in medicine and laboratories such as syringes, test tubes, catheters, tubing, trays, medical fabrics, and gloves are described. The devices are formed in whole or in part of a hydrolytically degradable polymer. In the preferred embodiment, the devices or structural components thereof degrade in a period of weeks to months, preferably within a year and more preferably within six months of exposure to aqueous solutions. Conventional hydrolytically degradable polymers may be utilized or these may be modified to increase mechanical or processing characteristics, for example, using a polyfunctional branching agent and/or a chain extending agent. In one embodiment, the hydrolytically degradable polymer is a member of a new class of polyesters comprising an aliphatic dicarboxylic acid, an aliphatic diol and optionally, one or more bifunctional fatty acids such as ricinoleic acid and/or castor oil.
    Type: Grant
    Filed: December 22, 2005
    Date of Patent: March 27, 2012
    Assignee: Massachusetts Institute of Technology
    Inventors: Abraham J. Domb, Robert S. Langer
  • Publication number: 20120065357
    Abstract: A resin for use in toner including a polyhydroxycarboxylic acid skeleton in an amount of 50 to 80% by mass. The resin is soluble in organic solvents and has a glass transition temperature of 60° C. or more.
    Type: Application
    Filed: August 10, 2011
    Publication date: March 15, 2012
    Inventors: Yoshitaka YAMAUCHI, Taichi Nemoto, Daisuke Asahina, Susumu Chiba, Chiaki Tanaka
  • Publication number: 20120064252
    Abstract: Disclosed are ester compositions, solvents, cleaning formulations, curing agents, reactive diluent solvents, controlled acid function release agents, polyol monomers, drilling mud and methods of making and using the same. Disclosed compositions include: a) about 10 to 60 weight percent methyl hydroxycaproate; b) about 20 to 80 weight percent dimethyl adipate; c) about 1 to 15 wt % of dimethyl glutarate; d) about 0.1 to 5 wt % of dimethyl succinate; e) about 0.1 to 7 wt % of at least one cyclohexanediol; and f) less than about 20 wt % oligomeric esters.
    Type: Application
    Filed: December 11, 2009
    Publication date: March 15, 2012
    Applicant: Invista North America S.A.R.L.
    Inventor: Richard P. Beatty
  • Patent number: 8133967
    Abstract: Described are restaurant smallware, comprising polyester based composition, comprising dicarboxylic acid component as terephthalic acid residues and optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues and glycol component, comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and cyclohexanedimethanol residues. The polyester composition has the inherent viscosity from 0.55 to 0.0.68 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C., glass transition temperature Tg of 110° C. to 160° C., notched Izod impact strength of at least 7.5 ft-lb/inch at 23° C. according to ASTM D256 with a 10-mil notch in a ?-inch thick bar, melt viscosity is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C. and does not contain polycarbonate.
    Type: Grant
    Filed: October 7, 2010
    Date of Patent: March 13, 2012
    Assignee: Eastman Chemical Company
    Inventors: Thomas Joseph Pecorini, Douglas Stephens McWilliams, Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
  • Patent number: 8119762
    Abstract: Described are film or sheet, comprising polyester based composition, comprising dicarboxylic acid component as terephthalic acid residues and optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues and glycol component, comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and cyclohexanedimethanol residues. The polyester composition has the inherent viscosity from 0.55 to 0.68 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C., glass transition temperature Tg of 110° C. to 160° C., notched Izod impact strength of at least 7.5 ft-lb/inch at 23° C. according to ASTM D256 with a 10-mil notch in a ?-inch thick bar, melt viscosity is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C. and does not contain polycarbonate.
    Type: Grant
    Filed: November 10, 2010
    Date of Patent: February 21, 2012
    Assignee: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
  • Patent number: 8119761
    Abstract: Described are polyester compositions comprising at least one polyester which comprises terephthalic acid residues in the amount from 80 to 100 mole %, 2,2,4,4-tetramethyl-1,3- cyclobutanediol in the preferable amount from 30 to 40 mole % and 1,4-cyclohexanedimethanol in the preferable amount from 60 to 70 mole % , wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mote %; and the inherent viscosity of polyester is from 0.55 to 0.68 dL/g as determined in 60/40 (wt/wt) phenol/tetrachtoroethane at a concentration of 0.5 g/100 ml at 25° C., polyester has a Tg from 110 to 160° C. and polyester composition comprises no polycarbonate. The polyesters may be manufactured into articles such as fibers, films, bottles or sheets.
    Type: Grant
    Filed: March 28, 2006
    Date of Patent: February 21, 2012
    Assignee: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
  • Patent number: 8110282
    Abstract: An object of the present invention is to provide a film having a high brightness and a natural metal-effect, and also having excellent formability, causing no delamination and maintaining the metal-effect after forming. Another object is to provide a molded body having less environmental burden, excellent in recycling efficiency and giving no electromagnetic interference. A laminated film including a structure where each 30 layers or more of a layer composed of a resin A (A layer) and a layer composed of a resin B (B layer) are alternately laminated, wherein a relative reflectance in a wavelength range of 400 nm to 1000 nm is 30% or more, tensile stresses at 100% elongation in a longitudinal direction and a width direction of the film are 3 MPa or more and 90 MPa or less in a tensile test at 150° C., and the number of layers with a layer-pair thickness of 10 nm or more and less than 220 nm is more than the number of layers with a layer-pair thickness of 220 nm or more and 320 nm or less.
    Type: Grant
    Filed: August 10, 2006
    Date of Patent: February 7, 2012
    Assignee: Toray Industries, Inc.
    Inventors: Syunichi Osada, Wataru Gouda
  • Patent number: 8110609
    Abstract: The invention relates to a composition comprising a modified, random copolyetherester containing a modified, random polytrimethylene terephthalate copolymer block that is derived from a polyethylene terephthalate component selected from the group consisting of polyethylene terephthalate and polyethylene terephthalate copolymers and combinations thereof; and contains at least one residue derived from the polyethylene terephthalate component; and a polyalkylene oxide copolymer block that contains polyalkylene oxide and at least one residue derived from the polyethylene terephthalate component.
    Type: Grant
    Filed: August 9, 2010
    Date of Patent: February 7, 2012
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Michael Determan, Ganesh Kannan, Kenneth Frederick Miller, Dhaval Shah
  • Patent number: 8106148
    Abstract: A series of resins were synthesized using a range of bio-based materials to control the molecular architecture, and therefore the properties, of the inventive resins. The utility of these resins was demonstrated in the formulation of powder coatings, such as ?-hydroxy amide crosslinked and hybrid types. Generally, the bio-based resins flowed out on heating faster than conventional petrochemically-based resins, allowing the use of lower temperatures in the curing oven than is typically possible and a more active catalyst system, especially in the carboxylic acid-epoxy crosslinked hybrid coatings formulations.
    Type: Grant
    Filed: March 20, 2006
    Date of Patent: January 31, 2012
    Assignee: Battelle Memorial Institute
    Inventors: Bhima R. Vijayendran, Jerry L. King, II, Katherine P. Mitchell, Michael C. Clingerman, Jeffrey T. Cafmeyer