Material Is An Alcohol, Ether, Or Inorganic Alcoholate Patents (Class 528/317)
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Publication number: 20150108070Abstract: Disclosed herein is a method of preparing hyperbranched polyamidoamine particles, including: a) preparing a polyamidoamine precursor mixture from a multifunctional amine monomer and a multifunctional acrylamide monomer; and b) polymerizing the polyamidoamine precursor mixture into cross-linked hyperbranched polyamidoamine particles using reverse phase suspension polymerization. Also, hyperbranched polyamidoamine particles prepared by the method are provided, which can remove heavy metals in an aqueous solution without the need for an ultrafiltration apparatus.Type: ApplicationFiled: March 12, 2013Publication date: April 23, 2015Inventors: Sang Youl Kim, Young Sik Eom
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Patent number: 8962769Abstract: The present invention relates to novel polyimidothioethers-inorganic nanoparticle hybrid material, which exhibit good surface planarity, thermal dimensional stability, tunable refractive index, and high optical transparency upon forming into films. The present invention also relates to polyimidothioethers which is an intermediate for preparing the present hybrid material, and their preparation.Type: GrantFiled: June 27, 2012Date of Patent: February 24, 2015Assignee: National Taiwan UniversityInventors: Guey-Sheng Liou, Chia-Liang Tsai, Hung-Ju Yen, Wen-Chang Chen, Wen-Yen Chiu, Yang-Yen Yu
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Publication number: 20140011972Abstract: Provided herein are novel processes for synthesis of polymers and/or polymer composites.Type: ApplicationFiled: February 7, 2012Publication date: January 9, 2014Applicant: GRAPHEA, INC.Inventors: Christopher W. Bielawski, Daniel R. Dreyer
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Publication number: 20130190471Abstract: Provided are: an impact-resistant polyamide composition which exhibits improved toughness and improved impact strength and which can be easily polymerized in-situ in a molding stage; and a novel process for the production of the same. The novel process comprises initiating the anionic polymerization of ?-caprolactam in the presence of (A) an anionic polymerization catalyst, (B) an anionic polymerization activator, (C) 2.0 to 30% by weight (relative to the ?-caprolactam) of an N,N-disubstituted vinylbenzylamine, and (D) a radical polymerization initiator, and subjecting the resulting system to reaction under conditions comprising a reaction temperature of the reaction system of 120 to 180° C. and a reaction time of 10 seconds to 120 minutes. Since radical polymerization in the process is conducted without hindering the anionic polymerization, an alloyed polyamide composed of both polycaprolactam and poly (N,N-disubstituted vinylbenzylamine) can be obtained.Type: ApplicationFiled: June 23, 2011Publication date: July 25, 2013Applicant: NAGASE CHEMTEX CORPORATIONInventors: Tokizane Imanishi, Hirofumi Nishida
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Publication number: 20130012596Abstract: A process for preparing poly N-substituted beta-alanines with the steps of: combining in a Michael reaction approximately 1.0 to 1.2 moles of methyl acrylate with approximately one mole of one or more primary amines to produce an alkyl(beta-n-alkylaminopropionate); and heating the alkyl(beta-n-alkylaminopropionate) to a reaction temperature between approximately 100 and 200 degrees C. and simultaneously evacuating the alkyl(beta-n-alkylaminopropionate) to remove volatiles, thereby forming a poly N-substituted beta-alanine.Type: ApplicationFiled: January 11, 2012Publication date: January 10, 2013Inventor: Robert B. Login
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Patent number: 8241545Abstract: The present disclosure provides a method for preparing polylactic acid and its products using a twin-screw extruder, comprising the step of mixing carbon dioxide adducts of carbene and lactide, and obtaining polylactic acid and its products via reactive extrusion using a twin-screw extruder.Type: GrantFiled: February 24, 2011Date of Patent: August 14, 2012Assignee: Nanjing Universty of TechnologyInventors: Zhenjiang Li, Pingkai Ouyang, He Huang
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Publication number: 20110152493Abstract: This disclosure provides a method of making polylactic acid using carbon dioxide adducts of carbenes, wherein the adducts of carbenes have a structure represented by formula (I) as follows:Type: ApplicationFiled: February 24, 2011Publication date: June 23, 2011Inventors: Zhenjiang Li, Pingkai Ouyang, He Huang
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Patent number: 7932346Abstract: A novel process is used to prepare synthetic rubbers (B) which feature very narrow molecular weight distribution and a correspondingly low value for the polydispersity index. The preparation process encompasses the treatment of a synthetic rubber with ultrasound, where the resultant synthetic rubber (B) has a lower weight-average molecular weight (Mw) than the synthetic rubber (A) used. The resultant synthetic rubbers (B) have excellent suitability for processing via extruder processes or injection-molding processes.Type: GrantFiled: June 7, 2010Date of Patent: April 26, 2011Assignee: LANXESS Deutschland GmbHInventors: Lothar Reif, Stephen Pask
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Publication number: 20100104794Abstract: A thermosetting epoxy resin composition characterized by containing as a resin ingredient a product of pulverization of a solid matter obtained by reacting a triazine derivative/epoxy resin with an acid anhydride in such a proportion that the amount of the epoxy groups is 0.6-2.0 equivalents to the acid anhydride groups.Type: ApplicationFiled: July 28, 2006Publication date: April 29, 2010Applicant: Shin-Etsu Chemical Co., Ltd.Inventors: Takayuki Aoki, Toshio Shiobara
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Publication number: 20100029893Abstract: It relates to a highly heat resistant thermosetting polyimide resin composition that is cured at a temperature of 150° C. or less, and provides a cured product that generates a less amount of decomposed gas even under heating to 250° C., and has flexibility and adhesiveness. A two-component thermosetting polyimide resin composition containing a liquid A containing a polyimide (a) having a main chain constituted by a repeating unit having a polyoxyalkylenediamine structure with amino groups on both ends thereof, and a liquid B containing a bismaleimide compound, and a cured product of a thermosetting polyimide resin composition obtained by mixing these two liquids and curing the mixture under heating.Type: ApplicationFiled: October 3, 2007Publication date: February 4, 2010Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Masahito Ohkido, Wataru Ueno, Jitsuo Oishi, Shuta Kihara
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Publication number: 20090123753Abstract: A method for preparing nylon microspheres is provided, said method comprising steps (1), (2) and (3) or steps (1?), (2) and (3) as follows: (1) a radically polymerizable monomer is dispersed in a molten lactam monomer, and a free radical initiator is added, so that radical polymerization of the radically polymerizable monomer is carried out, to give a mixture of a free radical polymer and the lactam monomer; or (1?) a mixture of a free radical polymer and a molten lactam monomer is provided; and (2) an initiator and an activator, used for anionic ring-opening polymerization of the lactam monomer, are added to the mixture obtained in step (1) wherein the remaining radically polymerizable monomer and water are removed, or to the mixture obtained in step (1?), so that the anionic ring-opening polymerization of the lactam is carried out to give a polymer alloy of the free radical polymer/polyamide; and (3) the free radical polymer in the polymer alloy obtained in step (2) is removed by dissolution, giving nylon mType: ApplicationFiled: November 12, 2008Publication date: May 14, 2009Inventors: Aihua PEI, Tingxiu Xie, Guisheng Yang
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Patent number: 7465780Abstract: The present invention is related to a polyimide, which has high ionic conductivity and good structural stability, does not decompose even under low humidity, and is inexpensive, and a polymer electrolyte and a fuel cell using the same.Type: GrantFiled: February 8, 2005Date of Patent: December 16, 2008Assignee: Samsung SDI Co., Ltd.Inventors: Myung-sup Jung, Do-yun Kim, Min-ju Jeong
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Patent number: 6965001Abstract: According to the present invention, organic-inorganic hybrid polymer materials with compositional gradient, and processes for preparing the same are provided. In the organic-inorganic hybrid polymer materials with compositional gradient, formation of cracks, removal of surface, or deformation such as warp and distortion, under heat shock or upon aging, hardly occurs. The organic-inorganic hybrid polymer materials with compositional gradient are comprised of an organic polymer component and a metal oxide component which are covalently bonded each other, characterized in that concentration of the organic polymer component, or of the metal oxide component is increased or decreased in the direction of thickness of the material.Type: GrantFiled: December 14, 2001Date of Patent: November 15, 2005Assignees: Orient Chemical Industries, Ltd., Osaka Municipal GovernmentInventors: Motoomi Arakawa, Kazuaki Sukata, Yasuyuki Agari, Masayuki Shimada
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Patent number: 6548621Abstract: The invention provides a poly(imide-benzoxazole) (PIBO) copolymer prepared from a trimellitic anhydride halide monomer and a bis(o-diaminophenol) monomer. The PIBO copolymer is characterized by the following recurring unit: wherein X is —O—, —S—, —C(CF3)2—, —C(CH3)2—, —CO—, —CH2—, —SO2—, —SO—, or deleted; and n is an integer. The PIBO copolymers of this invention are particularly useful as dielectric layers in semiconductor devices because they possess hydroxyl groups which create better adhesion to semiconductor substrates.Type: GrantFiled: November 8, 2001Date of Patent: April 15, 2003Assignee: Industrial Technology Research InstituteInventors: Shih-Jung Tsai, Steve Lien-Chung Hsu, Yuan-Pin Huang
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Patent number: 6482917Abstract: A process for the preparation of pulverulent, cationic, crosslinked polymers based on monoethylenically unsaturated monomers containing a quaternized or quaternizable nitrogen atom comprises carrying out the polymerization in supercritical carbon dioxide as inert diluent with mixing at from 31° C. to 150° C. and above 73 bar.Type: GrantFiled: January 2, 2001Date of Patent: November 19, 2002Assignee: BASF AktiengesellschaftInventors: Volker Hildebrandt, Reinhold Dieing, Katrin Zeitz
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Patent number: 6384181Abstract: A method of producing a polyamide resin by reacting with at least one diamine compounds at least one linear polyester resin consisting of at least one dicarboxylic acid component and at least one diol component and having an intrinsic viscosity of not less than 0.2 dl/g, so that the at least one diol component of the linear polyester resin is substituted by the diamine compound, resulting in the polyamide resin as a reaction product, wherein the improvement comprises: at least one of a carboxylic acid-activator and an inorganic salt being present in a reaction system of the linear polyester resin and the diamine compound.Type: GrantFiled: June 28, 2000Date of Patent: May 7, 2002Assignee: M & S Research and Development Co., Ltd.Inventor: Seiko Nakano
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Patent number: 6211326Abstract: The invention relates to a process for preparing hydroxyl- and carboxyl-containing polyesterimide resins, comprising as monomeric components: (A) imide-forming compounds having at least two primary amino groups and/or at least two isocyanate groups or imide-forming compounds having at least one primary amino group and/or at least one isocyanate group and at least one further functional group selected from hydroxyl, carboxyl and/or carboxylic anhydride, (B) polycarboxylic acids and/or their anhydrides and/or their esters and (C) polyols, characterized in that (I) component (A) is reacted with part of component (B) to form a polyimide, (II) the polyimide obtained in accordance with stage (I) is reacted with component (C) to form a polyesterimide, and finally (III) the polyesterimide obtained in accordance with stage (II) is reacted with the remaining part of component (B) to form the Also embraced by the invention is the use of the polyesterimides prepared by the process according to the invention as biType: GrantFiled: July 13, 1999Date of Patent: April 3, 2001Assignee: Schenectady International, Inc.Inventors: Brian W. Glasper, Geoffrey C. Rix, Klaus-Wilhelm Lienert
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Patent number: 6107438Abstract: A method of producing a polyamide resin by reacting with at least one diamine compound, at least one linear polyester resin consisting of at least one dicarboxylic acid component and at least one diol component and having an intrinsic viscosity of not less than 0.2 dl/g, the at least one diamine compound being used in an amount of 0.5-1.5 mol per 1 mol of the at least one linear polyester resin as calculated in the repeating unit thereof, the linear polyester resin and the diamine compound being reacted in a reaction medium comprising at least one solvent selected from aprotic protophobic polar solvents, so that the at least one diol component of the linear polyester resin is substituted by the diamine compound, resulting in the polyamide resin as a reaction product.Type: GrantFiled: October 1, 1998Date of Patent: August 22, 2000Assignee: M & S Research and Development Co., Ltd.Inventor: Seiko Nakano
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Patent number: 6072023Abstract: Polyamides and process for their preparation comprising eitherA) epoxidizing an unsaturated or partially hydrogenated fatty acid glyceride;B) transesterifying the epoxidized glyceride with a C.sub.1-4 alkanol to obtain epoxidized fatty acid C.sub.1-4 alkyl esters;C) ring opening and dimerizing the epoxidized fatty acid C.sub.1-4 alkyl esters; andD) reacting the dimerized fatty acid C.sub.1-4 alkyl esters with a polyamine to obtain a polyamide; orA) transesterifying an unsaturated or partially hydrogenated glyceride with a C.sub.14 alkanol to obtain olefinically unsaturated fatty acid C.sub.1-4 alkyl esters;B) epoxidizing the unsaturated fatty acid C.sub.1-4 alkyl esters;C) ring opening and dimerizing the epoxidized fatty acid C.sub.1-4 alkyl esters; andD) reacting the dimerized fatty acid C.sub.1-4 alkyl esters with a polyamine to obtain a polyamide.Type: GrantFiled: July 21, 1998Date of Patent: June 6, 2000Assignee: Henkel CorporationInventors: Setsuo Sato, Ramiro Carielo Bueno, Wanderson Bueno De Almeida
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Patent number: 5998571Abstract: A method for manufacturing shaped parts by polymerization of lactams in a mold includes the steps of providing a melt consisting of at least one catalyst, at least one activator, and amino-terminated polyethers in a mold and providing as the catalyst a 17% by weight solution of sodium lactamate in an amount of 1.0 weight-% to 3.8 weight-%.Type: GrantFiled: July 27, 1998Date of Patent: December 7, 1999Assignee: G. Schwartz GmbH & Co. KGInventor: Bernd Nussdorfer
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Patent number: 5985969Abstract: Polyimide precursor solutions comprise an organic liquid and the reaction product of an aromatic dianhydride and an aromatic diaminobenzoxazole capped, on at least one terminal end, with a bifunctional chain extender. The bifunctional chain extender has one functional group reactive with the amine of the aromatic diaminobenzoxazole or the anhydride of the aromatic dianhydride and another functional group which does not form amic acid linkages, but which is capable of further reaction to increase the molecular weight of the polyimide precursor under conditions other than those used to react the aromatic diamine and aromatic dianhydride to form the polyimide precursor. These polyimide precursors can be converted into polyimidebenzoxazole polymers.Type: GrantFiled: February 23, 1998Date of Patent: November 16, 1999Assignee: The Dow Chemical CompanyInventors: William J. Harris, Wen-Fang Hwang
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Patent number: 5866673Abstract: The invention relates to polymerisable double-bond derived polyamides obtainable by reacting the polyamide in an aqueous solution with a compound which contains both a polymerisable double bond and an oxirane ring. These derived polyamides may be processed to provide graft polymers with improved properties.Type: GrantFiled: July 21, 1997Date of Patent: February 2, 1999Assignee: Merck Patent Gesellschaft mit Beschrankter HaftungInventors: Egbert Muller, Anja Seiler, Roland Gensert
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Patent number: 5837803Abstract: A method of producing a polyamide resin by reacting 1 mol of linear polyester resin (as calculated in repeating unit of the linear polyester resin) consisting of at least one dicarboxylic acid component and at least one diol component and having an intrinsic viscosity of not less than 0.2 dl/g with 0.5-1.5 mol of at least one diamine compound in a reaction medium comprising at least one solvent which is selected from the group consisting of hydrocarbons, halogenated hydrocarbons, ethers and acetals, so that the diol component of the linear polyester resin is substituted by the diamine compound to provide the polyamide resin as a reaction product.Type: GrantFiled: March 31, 1997Date of Patent: November 17, 1998Assignee: M & S Research and Development Co., Ltd.Inventor: Seiko Nakano
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Patent number: 5780579Abstract: The present invention relates to a method for the preparation of polyamino acids, with controlled molecular weights, by polymerization of N-carboxyanhydrides (NCAs) of at least one amino acid, using at least one initiator of the strong base type and in liquid medium, characterized in that it consists in including, in the liquid reaction medium, given amounts of water and/or of alcohol. Application: synthesis of polyamino acids with mechanical and rheological characteristics adapted to applications as biomaterials.Type: GrantFiled: March 28, 1996Date of Patent: July 14, 1998Assignee: Flamel Technologies (Societe Anonyme)Inventors: Gerard Soula, Jean-Michel Grosselin, Rafael Jorda, Catherine Castan
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Patent number: 5744125Abstract: Disclosed are cosmetic melanins of different colors produced by procedures involving oxidative polymerization of monomeric precursors of melanin and/or co-monomers that enhance substantivity or adherence of the melanins to the skin and hair. Also disclosed are methods for preparing cosmetic melanins and methods for using these compositions topically to produce a natural-appearing tan and to prevent damage to skin caused by UV exposure.Type: GrantFiled: February 23, 1995Date of Patent: April 28, 1998Assignee: Yale UniversityInventors: John M. Pawelek, James T. Platt
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Patent number: 5741585Abstract: Polyimide precursor solutions comprise an organic liquid and the reaction product of an aromatic dianhydride and an aromatic diaminobenzoxazole capped, on at least one terminal end, with a bifunctional chain extender. The bifunctional chain extender has one functional group reactive with the amine of the aromatic diaminobenzoxazole or the anhydride of the aromatic dianhydride and another functional group which does not form amic acid linkages, but which is capable of further reaction to increase the molecular weight of the polyimide precursor under conditions other than those used to react the aromatic diamine and aromatic dianhydride to form the polyimide precursor. These polyimide precursors can be converted into polyimidebenzoxazole polymers.Type: GrantFiled: April 24, 1995Date of Patent: April 21, 1998Assignee: The Dow Chemical CompanyInventors: William J. Harris, Wen-Fang Hwang
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Patent number: 5650482Abstract: An at least two-step process for the preparation of polyamide resins wherein, in the first step, polyvalent carboxylic acids, optionally together with monovalent carboxylic acids, are reacted with a stoichiometric deficiency of polyamines in the presence of an organic solvent which forms an azeotrope with water, water is distilled off, and the reaction is controlled by means of the amount of water formed by the condensation reaction and, optionally, by the imidazoline formation. After removal of the theoretical amount of water or a lesser amount, in a further step more amine is added to the reaction mixture in an amount sufficient to achieve a final amine number of 10 to 300 mgKOH/g, the reaction is continued, substantially all of the residual water is removed, and the residual solvent is completely or partially removed.Type: GrantFiled: September 27, 1995Date of Patent: July 22, 1997Assignee: Air Products and Chemicals, Inc.Inventor: William Rene Eduard Raymond
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Insoluble, only slightly swellable polymers containing amino groups, their preparation and their use
Patent number: 5599898Abstract: Abstract of the Disclosure: Insoluble, only slightly swellable polymers containing amino groups, which can be obtained from popcorn polymers containing units of the structure ##STR1## where R and R.sup.1 are H or C.sub.1 -C.sub.4 -alkyl, by eliminating the group R--CO-- from at least 2% of the incorporated units of the structure I, with the formation of units of the structure II ##STR2## a process for the preparation of the amino-containing popcorn polymers by polymerizing N-vinylcarboxamides and, if desired, other monoethylenically unsaturated monomers copolymerizable therewith with from 0.Type: GrantFiled: April 25, 1995Date of Patent: February 4, 1997Assignee: BASF AktiengesellschaftInventors: Heinrich Hartmann, Walter Denzinger, Michael Kroener, Claudia Nilz -
Patent number: 5463063Abstract: Cyclic imides are inhibitors of tumor necrosis factor .alpha. and can be used to combat cachexia, endotoxic shock, and retrovirus replication. A typical embodiment is 2-(2,6-dioxo-3-piperidinyl)-4-azaisoindoline-1,3-dione.Type: GrantFiled: October 20, 1993Date of Patent: October 31, 1995Assignee: Celgene CorporationInventor: George W. Muller
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Patent number: 5421982Abstract: An electrically conductive polymer gel is composed of a crosslinked polyacrylamide polymer including an electrolytic salt, water and a polyhydric alcohol uniformly dissolved therein, wherein the water and the polyhydric alcohol are major components of said polymer gel. The polyacrylamide series polymer in the gel has properties of being hydrophilic and being a nonelectrolyte. Therefore, a desirable connection between the gel and the electrode can be achieved with low impedance. Moreover, the polyhydric alcohol reduces the drying speed of the electrically conductive polymer gel, thereby preventing an increase in the impedance due to the dryout of the gel. Therefore, the electrically conductive polymer gel of the present invention permits an accurate measurement of an electrical phenomenon in an organism for long periods of time.Type: GrantFiled: September 13, 1993Date of Patent: June 6, 1995Assignee: Sekisui Kaseihin Kogyo Kabushiki KaishaInventors: Toshiki Ikeda, Yoshikazu Kobayashi, Shuichi Sasahara, Takashi Higashi
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Patent number: 5380817Abstract: A process is provided for preparing polysuccinimides by forming a polymerization mixture of poly(alkylene glycol), aspartic acid and, optionally, one or more other amino acids; heating the mixture to an elevated temperature; and maintaining the mixture at the elevated temperature to form polysuccinimides.Type: GrantFiled: July 10, 1992Date of Patent: January 10, 1995Assignee: Rohm and Haas CompanyInventors: Yi H. Paik, Ethan S. Simon, Graham Swift
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Patent number: 5338828Abstract: Novel cyclic imino ether compositions containing one or more mesogenic moieties, when polymerized, result in products having improved properties.Type: GrantFiled: September 10, 1993Date of Patent: August 16, 1994Assignee: The Dow Chemical CompanyInventors: Robert E. Hefner, Jr., Jimmy D. Earls
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Patent number: 5286840Abstract: A thermally stable polyimide which is blocked at the polymer terminal with a dicarboxylic acid anhydride represented by the formula (III): ##STR1## wherein Z is a divalent radical selected from the group consisting of a monoaromatic radical which is substantially unsubstituted or substituted with a radical having no reactivity with amine or dicarboxylic acid anhydride and has from 6 to 15 carbon atoms, a condensed polyaromatic radical or a noncondensed aromatic radical connected each other with a direct bond or a bridge member, and has a fundamental skeleton represented by recurring structural units of the formula (IV): ##STR2## and a process of preparing the polyimide.Type: GrantFiled: November 21, 1991Date of Patent: February 15, 1994Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Hideaki Oikawa, Nobuhito Koga, Akihiro Yamaguchi, Shoji Tamai
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Patent number: 5254668Abstract: Amidamines of the following formula are described: ##STR1## where R is independently hydrogen or lower alkyl of 1 to 4 carbon atoms;R' is an alkyl group if k is 1, or an alkylene group if k is greater than 1; where R' has 2 to 18 carbon atoms;R" is independently lower alkylene of 2 to 4 carbon atoms;R'" is independently straight or branched lower alkylene of 2 to 6 carbon atoms;x is independently 1 to 200;y is independently 1 to 300;z is independently 1 to 200;p is independently 2 to 11; andk is from 1 to 8; where the x and z groups may be distributed in blocks or randomly.These compositions are made by reacting a cyclic lactam with an etheramine. Incorporation of increasing quantities of the polyetherpolyamine did not decrease the crystalline melting point (T.sub.m) of the resulting copolymer. The polyamidopolyfunctional amines (poly(amide-ether-amide) triblock copolymers) have a relatively low modulus and retain higher use temperatures than current polyetheramide segment block copolymers.Type: GrantFiled: June 29, 1992Date of Patent: October 19, 1993Assignee: Texaco Chemical CompanyInventors: Richard J. G. Dominguez, Richard J. Clark, II, Richele T. Howelton, George P. Speranza
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Patent number: 5223335Abstract: A process for the production of a fiber-reinforced composite material, which comprises the steps of(1) preparing a polymeric composition containing a substantially linear aromatic oligomer having a terminal aliphatic hydroxyl group, bis(acylcaprolactam) and a catalyst which promotes a ring opening-addition reaction of a hydroxyl group and a caprolactam ring,(2) melting the polymeric composition and impregnating it into a fibrous reinforcing material to form a impregnated product, and(3) heating the impregnated product up to a temperature sufficient to open the caprolactam ring while inhibiting elimination of caprolactam thereby to form, as a matrix resin, a thermoplastic copolymer having an ester group and an amide group in its main chain;and a fiber-reinforced composition material produced by the above-mentioned process.Type: GrantFiled: March 13, 1992Date of Patent: June 29, 1993Assignee: Teijin LimitedInventors: Hiroo Inata, Shunichi Matsumura, Takashi Yoshitomi
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Patent number: 5136015Abstract: An addition type imide resin prepolymer is obtained by a reaction of unsaturated bisimide of 1.0 mol to diamine of 0.25 to 0.43 mol and an addition of polyamine having three or more benzene rings. The prepolymer is thereby made to contain substantially no unreacted diamine component which affects human body of operators, and to have remarkably excellent heat resistance and adhesive properties, while effective to restrain a production of any component of a molecular weight exceeding 15,000.Type: GrantFiled: April 10, 1990Date of Patent: August 4, 1992Assignee: Matsushita Electric Works, Ltd.Inventors: Tatsuo Yonemoto, Masahiro Matsumura, Yoshihisa Sugawa, Eiichiro Saito, Hiroshi Yamamoto, Keiko Kashihara
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Patent number: 5118874Abstract: Compounds of the formula ##STR1## in which, independently of one another, each R is OH or lower alkyl having 1-4 carbon atoms and each R' is hydrogen or lower alkyl having 1-4 carbon atoms, are prepared by the condensation of partially fluorinated aromatic hydrocarbons in the presence of hydrogen fluoride or by the reductive coupling of partially fluorinated aromatic compounds. The compounds are used as a starting material for the preparation of partially fluorinated polycondensates.Type: GrantFiled: June 20, 1991Date of Patent: June 2, 1992Assignee: Hoechst AktiengesellschaftInventors: Wolfgang Appel, Gunter Siegemund
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Patent number: 5104968Abstract: Polyimide precursor compositions incorporating at least one compound of fula (1), at least one compound of formula (2), at least one compound of formula (3) and at least one compound of formula (4) ##STR1## in which one of the groups R.sup.3 and R.sup.4 represents a hydrogen atom and the other, in the same way as the groups R.sup.1 and R.sup.2, which can be the same or different, in each case represent a hydrocarbon group having 1 to 16 carbon atoms, m is a number between 5 and 20, n is an integer between 1 and 5 and R.sup.5 represents a hydrogen atom, a halogen atom, a hydrocarbon group with 1 to 16 carbon atoms, or a group of formula R.sup.6 --O-- in which R.sup.6 represents a hydrocarbon group having 1 to 16 carbon atoms. The preferred composition contains 30 to 70% by weight of dry matter of compounds of formulas (1), (2) and (3), in which the groups R.sup.1, R.sup.2 and one of the groups R.sup.3 and R.sup.4 is a methyl or ethyl group and the compound of formula (4) is benzyl alcohol.Type: GrantFiled: August 8, 1990Date of Patent: April 14, 1992Assignee: Centre d'Etude des Materiaux Organiques pour Technologies AvanceesInventors: Serge Gonzalez, Paul Mariaggi, Guy Rabilloud, Bernard Sillion
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Patent number: 5102972Abstract: A class of di-ortho-substituted bismaleimides undergo uncatalyzed Michael addition with polyhydric phenols to afford chain-extended bismaleimides having a significantly wider processing window than the non-extended parent. The fully cured resins show improved fracture toughness, generally have comparable or superior dielectric constant and dielectric loss, and show no degradation in other properties such as resistance to moisture, to methylene chloride, and coefficient of thermal expansion.Type: GrantFiled: July 25, 1990Date of Patent: April 7, 1992Assignee: Allied-Signal Inc.Inventors: Raymond J. Swedo, Joseph J. Zupancic
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Patent number: 5068311Abstract: The invention relates to high molecular weight thermoplastically deformable branched aliphatic polyamides prepared by polycondensation of lactams and/or polyamide-forming diamine/dicarboxylic acid reaction mixtures and/or amino acids in the presence of small amounts of specific diamino-alcohols and approximately equivalent amounts of polycarboxylic acids (preferably dicarboxylic acids), and to a process for their preparation, which is distinguished by considerably shortened polycondensation times, without crosslinked products being formed. If appropriate, the process additionally utilizes a solid phase after-condensation, in which rapid further condensation to products which are indeed branched but are soluble in m-cresol and have an increased melt viscosity takes place.Type: GrantFiled: June 15, 1990Date of Patent: November 26, 1991Assignee: Bayer AktiengesellschaftInventors: Klaus Horn, Hans-Detlef Heinz, Peter-Rolf Muller, Ralf Dujardin
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Patent number: 4987214Abstract: Imide prepolymer compositions containing an unsaturated component (A) and diamine component (B) at the (A)/(B) molar ratio of 0.9-1.5 and 0.01-5.0% by weight, based on the sum of said components (A) and (B), of at least one radical polymerization inhibitors, and preferably further 0.01-5.0% by weight, based on the sum of said components (A) and (B), of at least one compound selected from the group of carboxylic acid and carboxylic acid anhydride.The imide prepolymer compositions of the present invention which contain the above-defined components in specific proportions are tough and excellent in adhesive strength to glass cloths and metals and in heat resistance.Type: GrantFiled: March 20, 1990Date of Patent: January 22, 1991Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Kojiro Kan, Toru Tomoshige, Hideya Aoki
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Patent number: 4983717Abstract: A membrane filter material formed from a solvent resistant bismaleimide polymer which is formed by polymerizing a bismaleimide compound with a perhydrodiaza-type heterocyclic compound and has a main structural skeleton represented by the following formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represents a lower carbon chain which is linear or contains a methyl group or ethyl group on the side chain, R.sub.5 represents a divalent group containing an aromatic ring, Y is >R< or >N--R--N< in which R is a lower carbon chain, and m is 0 or 1.This bismaleimide polymer can be a membrane filter material having an excellent organic solvent resistance. When this polymer is formed into a hollow fiber or plain film, a high separating and filtering capacity and an excellent organic resistance can be attained.Type: GrantFiled: August 22, 1989Date of Patent: January 8, 1991Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Kazuyuki Yamasaki, Kimio Yamamoto, Masanobu Watanabe, Kojiro Kan, Yoshio Nakayama
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Patent number: 4970289Abstract: There is provided the process for producing an imide-based prepolymer having high solvent solubility by reacting an unsaturated bisimide of formula (I): ##STR1## wherein D is a divalent group having a carbon-to-carbon double bond, and A is a divalent group having at least two carbon atoms, with a diamine in the presence of a radical scavenger.Type: GrantFiled: May 8, 1989Date of Patent: November 13, 1990Assignee: Mitsui Petrochemical Industries, Ltd.Inventor: Kojiro Kan
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Patent number: 4880898Abstract: Water-soluble polycondensates of dialkanolamides, fatty acid diethylaminopolyglycolates and fatty acid diethyl ammonium alkyl polyglycolates, which are first reacted with maleic anhydride in a molar ratio of 1:0.5 to 1:2, followed by reaction of substantially all the olefinic double bonds in the .alpha.-position to carboxyl groups with sulfites, are excellent plasticizers for hydraulic compositions.Type: GrantFiled: December 20, 1988Date of Patent: November 14, 1989Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Bernd Wahle, Hermann Anzinger, Horst Ziche, Erhard Schinski
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Patent number: 4749760Abstract: This invention relates to a curable resin composition comprising (a) a component selected from the group consisting of a dicyanate-terminated aromatic polysulfone oligomer, a dicyanate-terminated aromatic polyketone oligomer and mixtures thereof, (b) a cyanate ester component selected from the group consisting of polyfunctional aromatic cyanate ester monomers having at least two cyanate groups bonded to their aromatic ring, prepolymers of the cyanate esters and prepolymers of the cyanate ester monomers and amines, and (c) a bismaleimide component selected from the group consisting of bismaleimides, bismaleimides prepolymers and prepolymers of the bismaleimides and amines.Type: GrantFiled: June 30, 1987Date of Patent: June 7, 1988Assignee: Shell Oil CompanyInventor: Pen-Chung Wang
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Patent number: 4719283Abstract: The invention relates to polyimides of the general formula ##STR1## wherein R.sub.1, R.sub.2 =H, C.sub.1-3 -alkyl, halogen,R.sub.3 =C.sub.2-12 -alkylene or ##STR2## m=0, 1, X=CH.sub.2, C(CH.sub.3).sub.2, CO, O, S, SO.sub.Type: GrantFiled: March 6, 1986Date of Patent: January 12, 1988Assignee: Huels AktiengesellschaftInventor: Martin Bartmann
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Patent number: 4717763Abstract: Homogeneous, flexible block copolyetheramides having a melting/softening point of at least 170.degree. C., a glass transition temperature, measured at ZHE, of at most -5.degree. C.Type: GrantFiled: December 11, 1985Date of Patent: January 5, 1988Assignee: Rhone-Poulenc Specialites ChimiquesInventors: Jean Coquard, Jean Goletto
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Patent number: 4695354Abstract: In a medium for electrophoresis suitably employable for determination of base sequence of DNA, RNA, their fragments, and their derivatives, which comprises an aqueous polyacrylamide gel formed by crosslinking polymerization of an acrylamide compound and a crosslinking agent in the presence of water and at least one compound having a carbamoyl group, the improvement wherein glycerol is contained in the medium in a small amount ranging from 0.1 to 1.0 wt/v %.Type: GrantFiled: September 17, 1986Date of Patent: September 22, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Mitsuru Sugihara, Naohiko Sugimoto
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Patent number: 4644051Abstract: The invention concerns a simple process for preparing an ester acyllactam and/or esteramide acyllactam by the catalytic condensation of imide and alcohol, characterized in that a polyol and an acyllactam compound are reacted in the liquid state in the presencce of a halide, carboxylate or acetylacetonate from beryllium, magnesium, calcium, strontium, barium, boron, aluminium, zinc or cadmium.The invention is important for the preparation of compounds which may be used in the preparation of nylon block copolymers, more in particular in RIM-nylon systems (Reaction Injection Moulding), since when the compounds obtained according to the present invention are used in a RIM system, a very fast lactam polymerization takes place, and it therefore also relates to the preparation of nylon block copolymers.Type: GrantFiled: December 26, 1984Date of Patent: February 17, 1987Assignee: Stamicarbon B.V.Inventor: Albert A. Van Geenen
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Patent number: 4600770Abstract: Methods of making water soluble polyimide resin compositions. A carboxy terminated bisimide is prepared by reacting a suitable aromatic dianhydride with a suitable oxoimine. The bisimide is then mixed with a sufficient quantity of a water soluble solvent to dissolve the bisimide. Water is added to make a solution of the desired viscosity. An aromatic diamine is added to this water solution. To the mixture is added a suitable quantity of a tertiary amine to stabilize the resin. The solution is coated onto a surface and dried to produce a smooth, flexible coating. The coating can then be heated to an appropriate temperature to produce a fully polymerized coating which is thermally stable and resistant to oils and solvents.Type: GrantFiled: January 23, 1985Date of Patent: July 15, 1986Inventors: John Gagliani, John V. Long