With Two Or More Reactants One Of Which Is A Carboxylic Acid Or Derivative And One Of Which Is An Organic Compound Containing At Least Two Amino Nitrogen Atoms Patents (Class 528/324)
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Patent number: 12153345Abstract: A photosensitive resin composition including an alkali-soluble resin, a photoacid generator, a first organic solvent, and a second organic solvent different from the first organic solvent, in which the alkali-soluble resin includes at least one selected from a polyamide resin, a polyimide resin, and precursors thereof, the second organic solvent includes a heterocyclic compound having a carbonyl group (provided that N-methyl-2-pyrrolidone is excluded), and the amount of the second organic solvent is 0.001% by mass or more and 4.0% by mass or less with respect to the entire photosensitive resin composition.Type: GrantFiled: February 8, 2022Date of Patent: November 26, 2024Assignee: SUMITOMO BAKELITE CO., LTD.Inventors: Makoto Horii, Sakiko Suzuki, Ryuji Hirosawa, Wataru Takada
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Patent number: 11964449Abstract: The present invention relates to a laminate comprising at least one first layer of at least one first metal and at least one further layer of a polyamide composition (PC). The present invention further relates to a process for producing the laminate according to the invention.Type: GrantFiled: March 12, 2018Date of Patent: April 23, 2024Assignee: BASF SEInventors: Philippe Desbois, Josef R. Wuensch
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Patent number: 11401416Abstract: A polyamide composition comprising a polyamide; a plurality of inorganic fibers; and a flame retardant system comprising a zinc phosphinate and a nitrogen-containing polyphosphate is provided. At thicknesses of from about 0.4 to about 3.2 millimeters, the composition exhibits a Glow Wire Ignition Temperature of about 775° C. or more as determined in accordance with IEC-60695-2-13:2010; a Glow Wire End Product Temperature (without flame) of about 750° C. or more as determined in accordance with IEC-60335-1:2010; a Glow Wire Flammability Index of about 850° C. or more as determined in accordance with IEC-60695-2-12:2010; a V0 rating as determined in accordance with UL94; and/or a comparative tracking index of about 550 volts or more as determined in accordance with IEC 60112:2003.Type: GrantFiled: October 17, 2018Date of Patent: August 2, 2022Assignee: Celanese Sales Germany GmbHInventors: Guglielmo Pasetti, Holger Brandt
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Patent number: 10767012Abstract: A functionalized polyamide is prepared by reacting a thio acid with an amide monomer or a mixture of a diamine and a dicarboxylic acid. In the reaction, the amide monomer is preferably a lactam compound, the thio acid has a formula of HOOC-A-SH wherein A represents an alkylene group containing from 1 to 10 carbon atoms, the diamine is an aliphatic diamine and the dicarboxylic acid is a aliphatic dicarboxylic acid. The functionalized polyamide can be vulcanized directly with rubber, which results in the use of less dip for adhering the tire cord to the rubber.Type: GrantFiled: April 10, 2018Date of Patent: September 8, 2020Assignee: Firestone Fibers & Textiles Company, LLCInventors: Laura S. Kocsis, William L. Hergenrother, Terrence E. Hogan, Kevin J. Bishop, Waruna C. B. Kiridena
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Patent number: 10703938Abstract: A novel hot-melt adhesive and a preparation method thereof are disclosed, and in particular a hot-melt adhesive for bonding aluminum, stainless steel or other metal materials and PVC plastics is disclosed. The specific nylon-type copolyamide is firstly prepared by designing specific raw materials and percentage thereof, and in combination with favorable bonding properties of the nylon-type copolyamide for metals and favorable bonding characteristics of the perchloroethylene resin for PVC, a double screw extruder is utilized to perform sufficient melt blending on the nylon-type copolyamide and the perchloroethylene resin under the synergistic actions of related aids, so that the obtained novel hot-melt adhesive has favorable bonding properties for both metals and PVC.Type: GrantFiled: December 16, 2016Date of Patent: July 7, 2020Assignees: KUNSHAN TIANYANG HOT MELT ADHESIVE CO., LTD, SHANGHAI TIANYANG HOT MELT ADHESIVE CO., LTD, EAST CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGYInventors: Zuoxiang Zeng, Xingquan Ma, Zhelong Li
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Patent number: 10507127Abstract: This invention relates to an expanded device and its uses in human medical care, which include, inter alia, appetite suppression in a subject in need thereof and kits comprising thereof.Type: GrantFiled: June 6, 2013Date of Patent: December 17, 2019Assignee: EPITOMEE MEDICAL LTD.Inventors: Nir Betser, Valery Artmanov, Ran Kapri
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Patent number: 10376461Abstract: Described herein is a polyether polyamide block copolymer as well compositions and products containing the polyether polyamide block copolymer. Methods of making and using the copolymer, the compositions, and products are also described herein.Type: GrantFiled: May 18, 2012Date of Patent: August 13, 2019Assignee: CRODA INTERNATIONAL PLCInventors: Geng Lin, Nancy W. Harman
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Patent number: 10017609Abstract: Polyamides based on dicarboxylic acids and on diamines are produced in a batch process by 1) feeding the entire amount of monomer composed of dicarboxylic acids, of diamines, and, if appropriate, of further polyamide-forming monomers, in the desired stoichiometry, in a closed stirred-tank reactor, 2) heating the monomer mixture in the stirred-tank reactor, with stirring, and with setting of a certain pressure, to a desired reaction temperature for the production of a prepolymer, 3) if appropriate, completely or partially depressurizing the reaction mixture from stage 2), 4) if appropriate, carrying out further thermal treatment of the reaction mixture from stage 2) or 3), and 5) reacting the reaction mixture from stage 2), 3), or 4) in the melt in a vented extruder for further increase of the molecular weight, with discharge of water vapor, and without use of additional polyamide-forming monomers or of polyamides.Type: GrantFiled: August 14, 2009Date of Patent: July 10, 2018Assignee: BASF SEInventors: Philippe Desbois, Faissal-Ali El-Toufaili, Michael Gall, Andreas Wollny
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Patent number: 9428612Abstract: The invention relates to a semi-crystalline semi-aromatic polyamide comprising A-A-B-B units derived from (a) dicarboxylic acids consisting of a mixture of aromatic dicarboxylic acid and aliphatic dicarboxylic acid and (b) diamines consisting of a mixture of long chain aliphatic diamine and short chain aliphatic diamine, wherein (a-i) the aromatic dicarboxylic acid consists for at least 80 mole % of terephthalic acid, and (a-ii) the aliphatic dicarboxylic acid constitutes at least 5 mole % of the dicarboxylic acids, (b-i) the short chain aliphatic diamine constitutes at least 10 mole % of the diamines, and (c) the aromatic dicarboxylic acid and the long chain aliphatic diamine constitute 60-90 mole % of the total molar amount of dicarboxylic acids and diamines.Type: GrantFiled: January 23, 2007Date of Patent: August 30, 2016Assignee: DSM IP ASSETS B.V.Inventors: Rudy Rulkens, Robert C. B. Crombach
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Patent number: 9376535Abstract: The invention relates to a high molecular weight branched polyamide polymer comprising (a) blocks predominantly consisting of AA-BB repeat units, (b) blocks predominantly consisting of AB repeat units, and (c) branching units. The invention also relates to a process for the preparation of the high molecular weight branched polyamide polymer, comprising (1) a melt-mixing step wherein an essentially linear polyamide prepolymer (X-1), predominantly consisting of AA-BB repeat units, an essentially linear polyamide (pre)polymer (X-2), predominantly consisting of AB repeat units, and a branching agent are provided to and mixed and heated in a melt mixing apparatus, thereby forming a mixed melt, and the mixed melt being cooled, thereby forming a solid mixture; and (2) a solid state post condensation step wherein the solid mixture is post-condensed at elevated temperature in the solid state, thereby forming a high molecular weight branched polyamide polymer.Type: GrantFiled: June 25, 2012Date of Patent: June 28, 2016Assignee: DSM IP ASSETS B.V.Inventors: Nileshkumar Prakash Kukalyekar, Zhujuan Wang, Rudy Rulkens, Godefridus Bernardus Wilhelmus Leonardus Ligthart
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Patent number: 9200124Abstract: The invention relates to a precursor article of a composite material comprising a polymer matrix and at least one reinforcing wire and/or fibers, said article comprising at least one reinforcing wire and/or fibers and at least one polymer matrix wire and/or fibers. The invention also relates to composite materials comprising a reinforcing material and a thermoplastic matrix and to the articles obtained using said materials.Type: GrantFiled: December 20, 2004Date of Patent: December 1, 2015Assignee: RHODIA OPERATIONSInventors: Franck Bouquerel, Frederic Philippon
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Patent number: 9012026Abstract: The invention relates to a copolyamide comprising at least two different units corresponding to the following general formulation: A/X.T A is chosen from a unit obtained from an amino acid, a unit obtained from a lactam and a unit corresponding to the formula (Ca diamine).(Cb diacid), with a representing the number of carbon atoms of the diamine and b representing the number of carbon atoms of the diacid, a and b each being between 4 and 36, advantageously between 9 and 18, X.Type: GrantFiled: April 1, 2014Date of Patent: April 21, 2015Assignee: Arkema FranceInventors: Thierry Briffaud, Philippe Blondel
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Patent number: 8971766Abstract: The present invention provides an electrophotographic member capable of more definitely suppressing occurrence of a C set image. The electrophotographic member has a surface layer including a modified polysiloxane having a structure represented by the following formula (1). In the formula (1), G represents a bivalent group having an ethylene oxide chain represented by (—O—C2H4—) and L represents polysiloxane having at least a SiO4/2(Q) unit or a SiO3/2(T) unit.Type: GrantFiled: June 4, 2013Date of Patent: March 3, 2015Assignee: Canon Kabushiki KaishaInventors: Tomohito Taniguchi, Hiroshi Mayuzumi, Yusuke Yagisawa
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Publication number: 20150054884Abstract: The invention relates to a latex ink composition, the latex ink composition comprising a water soluble resin. The invention further relates to a water soluble resin suitable for a latex ink composition, the water soluble resin comprising a backbone and a stabilizing group, wherein the stabilizing group is capable of forming hydrogen bonds. The invention further relates to the use of a water soluble resin in a latex ink composition.Type: ApplicationFiled: October 31, 2014Publication date: February 26, 2015Applicant: OCE-TECHNOLOGIES B.V.Inventors: Peter R. MARKIES, Jozef P. MOONEN, Frederik L. E. M. SUILEN, Ronald GROOTHUIJSE, Richard VAN HAMEREN, Peter O. COLIN, Mark A. M. LEENEN
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Patent number: 8907046Abstract: Copolymers containing at least one perfluoropolyether segment and multiple aminooxalylamino groups are described. Methods of making the copolymers are also described. The copolymers can be prepared by reacting an oxalylamino-containing compound and an amine compound having at least two primary amino groups, at least two secondary amino groups, or at least one primary amino group plus at least one secondary amino group.Type: GrantFiled: December 22, 2010Date of Patent: December 9, 2014Assignee: 3M Innovative Properties CompanyInventors: Suresh S. Iyer, Miguel A. Guerra, Richard G. Hansen, David S. Hays, Ramesh C. Kumar, George G. I. Moore, Yu Yang
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Patent number: 8889822Abstract: The invention relates to a process for producing a shaped article having excellent mechanical properties, said article comprising a block copolymer PAX.Y/PE comprising polyamide (PA) blocks alternating with polyether (PE) blocks, prepared from homopolyamide blocks PAX.Y by polycondenstation of linear aliphatic diamines where PAX.Y is selected from the group consisting of PA 10,12; PA 6,18; PA 10,14; and PA 12.12, reacted with polyether PE blocks in the presence of a catalyst to produce a block copolymer PAX.Y/PE, wherein said PE blocks are either PE diols, or PE blocks comprising NH2 ends. The articles formed are either a fabric, film, sheet, rod, pipe, injection-molded component, or a shoe sole; the copolymer PAX.Y/PE has an improved flexural modulus of at least 300 MPa greater than a copolymer polyamide 12/polytetrametylene with the same size of PA block and with the same size of PE block respectively.Type: GrantFiled: April 9, 2013Date of Patent: November 18, 2014Assignee: Arkema FranceInventor: Frederic Malet
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Patent number: 8883955Abstract: PROBLEM There is provided a method for producing polylactic acid, which is capable of obtaining polylactic acid at low cost, and having high molecular weight. SOLUTION A method for producing polylactic acid by polymerizing molten lactide using at least one reactor having plug flow characteristics with ?(?), calculated from the following FORMULA (1), of 0.3 or smaller: ?(?)=?0?(E(?)×ABS(1??))d???(1) in the Formula (1), E(?) is a residence time distribution function determined by impulse response by starch syrup having a viscosity of 3 Pa·s, and ? is ratio of elapsed time ? and mean residence time ?0.Type: GrantFiled: June 14, 2010Date of Patent: November 11, 2014Assignees: Toyo Engineering Corporation, Masashino Chemical Laboratory, LtdInventors: Kenichiro Matsuba, Tsuyoshi Aoki
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Patent number: 8877888Abstract: A polyamide modified by a multi-functional compound, and a method for producing said polyamide and compositions comprising same are described. A method for the production of a polyamide comprising linear macromolecular chains and star-shaped macromolecular chains is also described. A resulting polyamide having optimal mechanical and rheological properties in order to (i) improve mould filling speed and quality, and (ii) produce moldable compositions with high filler contents is also described.Type: GrantFiled: September 28, 2010Date of Patent: November 4, 2014Assignee: Rhodia OperationsInventors: Franco Speroni, Damien Zaher
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Publication number: 20140272371Abstract: A paper machine clothing (PMC) fabric includes a plurality of monofilament yarns, at least some of which have a composition which is a thermoplastic resin. The thermoplastic resin yarns have physical properties including a water absorption of less than approximately 6% and a loop tenacity of greater than approximately 8.0 grams/denier.Type: ApplicationFiled: March 15, 2013Publication date: September 18, 2014Applicant: VOITH PATENT GMBHInventors: Brian Good, Vikram Dhende, Yidan Zhu
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Patent number: 8822629Abstract: The present invention relates to a method of prepairing a heat-resistant polyamide by carrying out condensation polymerization with a monomer mixture including a diester compound and a diamine compound. The present invention provides an economical method of prepairing a heat-resistant polyamide in that a monomer, a raw material, is simply and chiefly prepared, and the polymerizing reaction time is short because it does not need solvent separately.Type: GrantFiled: April 10, 2009Date of Patent: September 2, 2014Assignee: SK Chemicals Co., Ltd.Inventors: Dong-June Hwang, Jae-Bong Lim, Seung-Do Leem, Tae-Young Kim, Sung-su Bae
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Patent number: 8809434Abstract: The invention concerns processes for forming a polymer comprising residues of terephthaloyl chloride, paraphenylene diamine, and a salt of formula I wherein A? is a halogen anion, HSO4?, OH?, NO3?, C2H3O2?, or H2PO4?; the process comprising the steps of: a) forming a mixture comprising salt of formula I and paraphenylene diamine in a solvent system comprising an organic solvent and an inorganic salt; and b) adding terephthaloyl chloride to the mixture and allowing the formation of the polymer.Type: GrantFiled: July 27, 2012Date of Patent: August 19, 2014Assignee: EI du Pont de Nemours and CompanyInventor: Kiu-Seung Lee
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Patent number: 8791226Abstract: The present invention generally relates to the large-scale (e.g., greater than 1 kg scale) preparation of low molecular weight polylysine or polyornithine in high yield by preparing a polylysine or polyornithine having a weight average molecular weight from about 12,500 Daltons to about 22,000 Daltons and hydrolyzing it to produce a polylysine or polyornithine having a weight average molecular weight from about 5,500 Daltons to about 12,000 Daltons.Type: GrantFiled: February 5, 2013Date of Patent: July 29, 2014Assignee: Sigma-Aldrich Co. LLCInventor: Ettigounder Ponnusamy
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Patent number: 8772438Abstract: A process for making a polyamide polymer, said process comprising heating, in one or more ionic liquid(s), one or more polyamide precursor(s) selected from: (i) one or more free dicarboxylic acid(s) or ester(s) thereof, with one or more diamine(s); or (ii) one or more salt(s) of a dicarboxylic acid with a diamine; or (iii) one or more lactam(s); or (iv) mixtures of any of the foregoing precursors (i) to (iii).Type: GrantFiled: June 30, 2010Date of Patent: July 8, 2014Assignee: Invista North America S.är.l.Inventors: Keith Whiston, Charles Richard Langrick, Kenneth Richard Seddon, Alberto V. Puga
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Patent number: 8772435Abstract: The present invention relates to dispersants for dispersing a particulate solid for millbases, paints and inks. The present invention provides a composition containing a particulate solid, a polar organic medium and a compound or salts thereof for formula T-(A)m(B)n—X—Z-Q(0-p) wherein T is hydrogen or a polymerization terminating group; A is the residue of a hydroxy carboxylic acid or lactone thereof; B is the residue of an amino carboxylic acid; X is a direct bond or a divalent group; Z is an acidic or basic group or a moiety which contains an acidic or basic group; Q is an optional residue of an oxide, urea or a dibasic acid or anhydride thereof; m and n are positive integers; and p represents the number of residual amino and/or imino groups in Z.Type: GrantFiled: April 7, 2006Date of Patent: July 8, 2014Assignee: Lubrizol Advanced Materials, Inc.Inventors: Neil L. Simpson, Dean Thetford
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Patent number: 8759475Abstract: Polyamides, e.g., polyhexamethylene adipamide, are continuously produced via the following stages: Stage 1: into and through a reactor, polycondensing a liquid stream which contain the polyamide monomer(s) at a pressure P1 greater than atmospheric pressure, the stream of material at the outlet of the reactor including a vapor phase which contains steam and a liquid phase which at least contains the product of polycondensation; Stage 2: feeding the outlet stream of material into a chamber, evacuating at least a portion of the vapor phase therefrom and recovering at least the liquid phase which at least contains the product of polycondensation, the pressure P2 in the chamber being regulated at a set value such that it is greater than atmospheric pressure and the residence time of said liquid phase in the chamber being less than 5 minutes; and Stage 3: pressure reducing at least the liquid phase which at least contains the stream of polycondensation product recovered during Stage 2.Type: GrantFiled: March 25, 2008Date of Patent: June 24, 2014Assignee: Rhodia OperationsInventors: Jean-Francois Thierry, Sébastien Lomel, Vincent Mollet, Matthieu Helft, Cédric Fillon
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Publication number: 20140171588Abstract: A composition for a flexible substrate includes a polymer and a solvent. The polymer is selected from the polyamic acid, polyimide, and a combination thereof, and is obtained by subjecting a mixture including a tetracarboxylic dianhydride component and a diamine component to a reaction. The tetracarboxylic dianhydride component includes a bicyclic alicyclic tetracarboxylic dianhydride compound and a fluorine-containing tetracarboxylic dianhydride compound. The bicyclic alicyclic tetracarboxylic dianhydride compound is in an amount ranging from 30 mole % to 70 mole % and the fluorine-containing tetracarboxylic dianhydride compound is in an amount ranging from 30 mole % to 70 mole % based on 100 mole % of the tetracarboxylic dianhydride component.Type: ApplicationFiled: December 6, 2013Publication date: June 19, 2014Applicant: CHI MEI CORPORATIONInventor: Yu-Hao Liang
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Patent number: 8748004Abstract: The invention relates to a copolyamide comprising at least two different units corresponding to the following general formulation: A/X.T A is chosen from a unit obtained from an amino acid, a unit obtained from a lactam and a unit corresponding to the formula (Ca diamine).(Cb diacid), with a representing the number of carbon atoms of the diamine and b representing the number of carbon atoms of the diacid, a and b each being between 4 and 36, advantageously between 9 and 18, X.Type: GrantFiled: August 6, 2009Date of Patent: June 10, 2014Assignee: Arkema FranceInventors: Thierry Briffaud, Philippe Blondel
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Patent number: 8741398Abstract: The present invention provides a liquid crystal panel and an alignment film thereof, and the alignment film is made of a modified polyimide which has conjugated double bond at side chain. Resistance value of the alignment film is less than the resistance value of a liquid crystal material of the liquid crystal panel by properties of the conjugated double bond that can reduce the resistance value of a prior art polyimide. In addition, improving the imidization ratio of a modified polyimide alignment film is important. The present invention is conducted the charged ion from liquid crystal layer to the alignment film by the conjugated double bond of the modified polyimide at the side chain to prevent the increase in the ion density of the liquid crystal in part of this area, and improve the problem of image sticking.Type: GrantFiled: October 21, 2011Date of Patent: June 3, 2014Assignee: Shenzhen China Star Optoelectronics Technology Co., Ltd.Inventors: Chung-Ching Hsieh, Cheng-ming He
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Patent number: 8722842Abstract: The present invention provides an optical film exhibiting wavelength dispersion such that a retardation value is smaller on the shorter wavelength side, and capable of being also formed comparatively thinly. The optical film of the present invention is an optical film including a polyimide-based polymer represented by the following general formula (I). In the formula (I), m is 40% by mol or more and 100% by mol or less. R1 and R2 each independently denote a substituent having a carbon-carbon double bond or a triple bond. A, A?, B, B?, E, G, and H each denote a substituent, and small letters corresponding to these alphabets denote substitution number thereof. X and Y each independently denote bond part such as a covalent bond. The substituents having a carbon-carbon double bond or a triple bond represented by R1 and R2 are a substituted or unsubstituted aryl group, a substituted or unsubstituted vinyl group, and a substituted or unsubstituted ethynyl group.Type: GrantFiled: April 3, 2008Date of Patent: May 13, 2014Assignee: Nitto Denko CorporationInventors: Toshiyuki Iida, Yutaka Ohmori, Miyuki Kurogi
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Patent number: 8697831Abstract: The invention is directed to a process for preparing polyamide polymers, particularly nylon 6, 6 and nylon 6, comprising fluoroether functionalized aromatic repeat units. In one embodiment, 1,6 diaminohexane, adipic acid, and fluoroether functionalized terephthallic or isophthallic acid or diester are reacted to form a polymer. The polymers so formed are useful for imparting soil resistance to polyamides, particularly in the form of films, molded parts, fibers, fabrics, and carpets.Type: GrantFiled: June 22, 2011Date of Patent: April 15, 2014Assignee: E I du Pont de Nemours and CompanyInventors: Neville Everton Drysdale, David Neil Marks, Fredrik Nederberg
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Patent number: 8680199Abstract: A polyamide modified by a compound including at least one hydroxyl group, as well as a method for preparing said polyamide and articles obtained from the modified polyamide are described. A polyamide composition including reinforcing fillers, and a modified polyamide obtained by polymerization from, in particular, a monofunctional hydroxyaromatic acid or amino acid compound in the presence of diacid, diamine and/or amino acid or lactam compounds are also described.Type: GrantFiled: September 25, 2009Date of Patent: March 25, 2014Assignee: Rhodia OperationsInventors: Franck Touraud, Stéphane Jeol
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Patent number: 8658724Abstract: What are described are a solution comprising a terpolymer formed from the monomers of components A, B and C, the total amount of which adds up to 100% by weight, a) 5 to 60% by weight of lactams as component A, b) 5 to 60% by weight of equimolar amounts of adipic acid and one or more aliphatic diamines as component B, c) 10 to 70% by weight of equimolar amounts of adipic acid and 4,4?-diaminodicyclohexylmethane (dicycan) as component C, in an aromatics-free solvent system comprising 50 to 100% by weight of C1-4-alkanol, 0 to 50% by weight of water and not more than 10% by weight of further aromatics-free solvents, where the total amount of the solvent system adds up to 100% by weight, and a terpolymer formed from the monomers of components A, B and C, the total amount of which adds up to 100% by weight, a) 15 to 40% by weight of lactams as component A, b) 20 to 45% by weight of equimolar amounts of adipic acid and one or more aliphatic diamines as component B, c) 25 to 60% by weight of equimolar amounts ofType: GrantFiled: June 15, 2010Date of Patent: February 25, 2014Assignee: BASF SEInventors: Christian Schmidt, Faissal-Ali El-Toufaili, Philippe Desbois, Raquel Fernandez Rodiles
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Patent number: 8603634Abstract: This invention relates to poly(ester amide)s (PEAs) comprising inactivated terminal amino and carboxyl groups, methods of synthesizing the inactivated PEAs and uses for them in the treatment of vascular diseases.Type: GrantFiled: March 23, 2009Date of Patent: December 10, 2013Assignee: Abbott Cardiovascular Systems Inc.Inventors: Jessica Renee DesNoyer, Stephen Dirk Pacetti, Vidya Nayak, Lothar Kleiner
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Publication number: 20130295309Abstract: A resin composition, preferably an adhesive composition, comprising a polyether polyamide elastomer capable of being strongly bended with a polyimide resin, preferably strongly bended through an easy process to form an interface between the polyimide resin and the composition, and a bonded composite having the resin composition and a polyimide resin which together form an interface to be bonded with each other. A resin composition for forming an interface together with a polyimide resin for bonding, wherein the resin composition comprises a polyether polyamide elastomer (component R) obtained by subjecting a specific aminocarboxylic acid compound A1 and/or lactam compound A2, polyether compound B, and dicarboxylic acid compound C to polymerization, wherein the content of the component R in the resin composition is 80 to 100% by weight.Type: ApplicationFiled: December 28, 2011Publication date: November 7, 2013Applicant: UBE INDUSTRIES, LTD.Inventors: Yuma Irisa, Shuichi Maeda
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Publication number: 20130261256Abstract: An object of the present invention is to provide a copolymer polyamide which has excellent strength, high-temperature strength, low water absorbance, low blocking properties, releasability and plasticizing time stability, and a copolymer polyamide composition which has excellent vibration fatigue characteristics, surface appearance and continuous productivity. A copolymer polyamide of the present invention is obtained by polymerizing (a) at least one alicyclic dicarboxylic acid, (b) one diamine having 8 or more carbon atoms, and (c) at least one copolymer component selected from the group consisting of the following (c-1) to (c-3): a (c-1) dicarboxylic acid other than the alicyclic dicarboxylic acid; a (c-2) diamine having fewer carbon atoms than the (b) diamine; and a (c-3) lactam and/or aminocarboxylic acid, and the copolymer polyamide satisfies specific conditions.Type: ApplicationFiled: January 6, 2012Publication date: October 3, 2013Applicant: ASAHI KASEI CHEMICALS CORPORATIONInventors: Shinji Ieda, Kazunori Terada, Yu Nitto
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Patent number: 8546517Abstract: The present invention generally relates to a poly(bisoxalamide) and a process for preparing and article comprising the poly(bisoxalamide).Type: GrantFiled: December 10, 2010Date of Patent: October 1, 2013Inventors: Rene Broos, Niels Jurrian Sijbrandi, Pieter Jelle Dijkstra, Jan Feijen
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Patent number: 8541539Abstract: A method for preparing a water-soluble polyamide, includes copolymerizing reactive monomers including caprolactam; ethylene glycol bis(2-aminoethyl)ether or ethylene glycol bis(3-aminopropyl)ether; and 5-sulfoisophthalic acid monosodium salt, wherein a molar ratio of caprolactam:ethylene glycol bis(2-aminoethyl)ether or ethylene glycol bis(3 -aminopropyl)ether:5-sulfoisophthalic acid monosodium salt is about 0:1:1 to about 5:1:1, advantageously about 1.85:1:1. Copolymerizing takes place at a copolymerization temperature of about 222-250° C. and a copolymerization pressure of about 3 Bar. The method further includes maintaining a temperature of about 222-250° C. for about 2-3 hours under normal pressure after the copolymerization step. The water-soluble polyamide has a solubility in water of about 10-70%.Type: GrantFiled: December 29, 2008Date of Patent: September 24, 2013Assignee: Taiwan Textile Research InstituteInventors: Yu-Chi Tseng, Chin-Wen Chen, S-P Rwei
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Publication number: 20130225786Abstract: The invention relates to a copolyamide comprising units resulting from the polycondensation reaction of the following precursors: terephthalic acid (a), an aliphatic diamine (b) comprising x carbon atoms, x being an integer between 6 and 22, and an aminocarboxylic acid and/or a lactam (c) comprising a main chain and at least one linear or branched alkyl branching, the total number of carbon atoms of the aminocarboxylic acid and/or of the lactam (c) being between 12 and 36. The invention also relates to the process for preparing said copolyamide and to a composition comprising such a copolyamide.Type: ApplicationFiled: September 2, 2011Publication date: August 29, 2013Applicants: INSTITUT NATIONAL DES SCIENCES APPLIQUEES DE LYON, ARKEMA FRANCEInventors: Thierry Briffaud, Quentin Pineau, Emilie Goncalves, Jerome Robert Dupuy, Alain Jean-Jacques Rousseau
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Patent number: 8507598Abstract: The invention relates to polyamide molding compounds with improved scratch resistance, which are constructed from (A1) 50 to 99.99 parts by weight of a copolyamide, (A2) 0 to 49.99 parts by weight of a transparent polyamide, (A3) 0 to 29.99 parts by weight of an aliphatic polyamide, (B) 0.01 to 5 parts by weight of at least one lubricant, and (C) 0 to 3 parts by weight of further additives, with the proviso that the sum of (A1) and (A2) and (A3) and (B) produces 100 parts by weight.Type: GrantFiled: December 19, 2008Date of Patent: August 13, 2013Assignee: EMS-Patent AGInventors: Friedrich Severin Bühler, Christian Rytka, Walter Alois Tobisch, Sepp Bass
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Publication number: 20120302723Abstract: A polyamide compound containing: from 25 to 50 mol % of a diamine unit, which contains an aromatic diamine unit represented by the following formula (I), in an amount of 50 mol % or more; from 25 to 50 mol % of a dicarboxylic acid unit, which contains a linear aliphatic dicarboxylic acid unit represented by the following formula (II-1) and/or an aromatic dicarboxylic acid unit represented by the following formula (II-2), in an amount in total of 50 mol % or more; and from 0.1 to 50 mol % of a constitutional unit represented by the following formula (III): wherein n represents an integer of from 2 to 18, Ar represents an arylene group, and R represents a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group.Type: ApplicationFiled: December 24, 2010Publication date: November 29, 2012Inventors: Takafumi Oda, Ryoji Otaki, Shota Arakawa, Tsuneaki Masuda, Hiroyuki Matsushita, Ryuji Hasemi
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Patent number: 8268955Abstract: Polyamide containing a compound which bears at least one hydroxy group and has chemical bonding by way of an amide group to the end of the polymer chain, process for preparing this polyamide, and also fibers, films, and moldings, comprising at least one such polyamide.Type: GrantFiled: October 28, 2003Date of Patent: September 18, 2012Assignee: BASF SEInventors: Helmut Winterling, Jürgen Demeter, Kurt Krempel
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Publication number: 20120165466Abstract: [Problem to be Solved] To provide a polyamide having a high melting point, which has excellent strength, toughness, and stability under heating. [Solution] This polyamide is obtained by polymerizing an (a) dicarboxylic acid comprising at least 50 mol % of an alicyclic dicarboxylic acid and a (b) diamine comprising at least 50 mol % of a diamine having a pentamethylenediamine skeleton, wherein the polyamide has a cyclic amino end amount of 30 to 60? equivalents/g.Type: ApplicationFiled: September 7, 2010Publication date: June 28, 2012Applicant: ASAHI KASEI CHEMICALS CORPORATIONInventors: Yu Nitto, Yasukazu Shikano, Shinji Ieda, Kazunori Terada, Masaaki Aramaki
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Publication number: 20120094102Abstract: The invention relates to an optically transparent polymer film or extrudate product made of a polymer composition comprising a semi-crystalline polyamide having a melting temperature of at least 270° C. or a blend of the semi-crystalline polyamide (A) and a second polymer (B), and optionally at least one additive, wherein the semi-crystalline polyamide (A) is present in an amount of more than 50 wt. %, relative to the total weight of the polymer composition, the polymer composition in the optically transparent polymer film or extrudate product has a melting temperature (Tm-C) in the range of 270-340 ° C., and wherein the film or a part of the extrudate product has a haze of less than 12% and a light transmittance, of at least 88% measured with the method according to ASTM D1003A.Type: ApplicationFiled: January 15, 2010Publication date: April 19, 2012Inventors: Alexander Antonius Maria Stroeks, Rudy Rulkens, Lee Sanghoon, Sidiki Tamim Peter
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Publication number: 20120095161Abstract: A molding compound, containing at least 30% by weight of a copolyamide, which is derived from the following monomers: a) 50 to 95 mole percent of the combination of a diamine, selected from the group consisting of 1,9-nonane diamine, 1,10-decane diamine, 1,11-undecane diamine and 1,12-dodecane diamine, and terephthalic acid, and b) 5 to 50 mole percent of the combination of a diamine, selected from the group consisting of 2,2,4-trimethylhexamethylene diamine, 2,4,4-trimethylhexamethylene diamine, and mixtures thereof, and terephthalic acid. The copolyamide is crystalline and has low water absorption.Type: ApplicationFiled: July 8, 2010Publication date: April 19, 2012Applicant: EVONIK DEGUSSA GmbHInventors: Andreas Pawlik, Martin Roos, Franz-Erich Baumann, Harald Haeger
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Publication number: 20120024577Abstract: The invention relates to a polymer film made of a polyamide composition comprising at least 80 weight percentage (wt. %) of a semi-crystalline semi-aromatic polyamide with a melting temperature (Tm) of at least 270° C., wherein the wt. % is relative to the total weight of the polymer composition, wherein the polymer film has an average coefficient of thermal expansion in plane in the temperature range of 20° C.-Tg, measured in plane with the method according to ASTM D969-08, of at most 40 ppm/K. The said film can be made from a polyamide moulding composition comprising said polyamide by film casting followed by axial stretching. The film has properties suitable for carrier films in flexible printed circuit boards.Type: ApplicationFiled: January 15, 2010Publication date: February 2, 2012Inventors: Alexander Antonius Marie Stroeks, Guido Richard Struijk
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Publication number: 20110288265Abstract: The invention relates to a plastic container or conduit for a cooling system, a heating system, an air intake system, an exhaust system, a pressure system or a fuel system, consisting of or comprising a part or a layer made of a thermoplastic polymer composition comprising a semi-crystalline semi-aromatic polyamide having a glass transition temperature (Tg) of at least 115° C.Type: ApplicationFiled: January 21, 2010Publication date: November 24, 2011Inventors: Eric W. Vegte Van Der, Johannes Hoekstra
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Patent number: 8044171Abstract: The invention relates to a polyamide molding material or copolyamide molding material and the use of such a polyamide molding material or copolyamide molding material for producing steam-sterilizable transparent moldings and extrudates. This polyamide molding material is characterized in that it comprises at least one copolyamide formed from 35-42 mol % of bis(4-amino-3-methylcyclohexyl)methane (MACM), 35-42 mol % of isophthalic acid (IPS) and 16-30 mol % of laurolactam (LC12). MACM may be replaced up to 50% by bis(4-aminocyclohexyl)-methane (PACM) and IPA up to 50% by terephthalic acid (TPA). The polyamide molding material may also be a blend of copolyamides or a blend of copolyamides with polyamide 12. The relative viscosity (RV) of the polyamide molding material or copolyamide molding material is in any case adjusted to a value which is greater than 1.45.Type: GrantFiled: January 31, 2006Date of Patent: October 25, 2011Assignee: EMS-Chemie AGInventors: Friedrich Severin Buhler, Ralf Hala
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Publication number: 20110171408Abstract: The present invention relates to a copolyamide comprising at least two units and corresponding to the following general formula: A/(diamine).(Cw diacid), in which: the diamine is a cycloaliphatic diamine, w represents the number of carbon atoms of the diacid, A is chosen from a unit obtained from an amino acid or from a lactam and a unit corresponding to the formula (Cx diamine).(Cy diacid), with x representing the number of carbon atoms of the diamine and y representing the number of carbon atoms of the diacid, and in which at least one of the monomers chosen from A and the Cw diacid is obtained, in all or part, from renewable starting materials according to Standard ASTM D6866. The invention also relates to a composition comprising this copolyamide and to the use of this copolyamide and of such a composition.Type: ApplicationFiled: June 22, 2009Publication date: July 14, 2011Applicant: Arkema FranceInventors: Benjamin Saillard, Philippe Blondel, Claire Michalowicz
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Publication number: 20110165359Abstract: The invention relates to a polyamide comprising at least two units having the following general formula: X.Y where: X is an alkylaromatic diamine and Y is an aliphatic carboxylic diacid selected from dodecanedioic (C12) acid, tetradecanedioic (C14) acid, hexadecanedioic (C16) acid, characterized in that the carboxylic diacid comprises organic carbon from a renewable source determined according to standard ASTM D6866 The invention also relates to a composition comprising this polyamide and the use of said polyamide and of such a composition.Type: ApplicationFiled: July 3, 2009Publication date: July 7, 2011Inventors: Guillaume Le, Julien Jouanneau, Benjamin Saillard
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Publication number: 20110146907Abstract: A binding fiber having, as at least one first thermoplastic component, a copolyamide which has a relative viscosity of at least 1.50 (measured at 0.5% in m-cresol at 25° C.), a MVR of maximum 20 cm3/10 min at 190° C. and 2.16 kg load, a hydrophobicity of less than 7.2, a melting temperature lower than 105° C. in the water saturated condition and a higher melting temperature in the dry condition. The binding fiber can, on the one hand, be activated with hot steam at approximately ambient pressure during the manufacture of flat materials containing natural fibers, such as paper, cardboard, wood fiber boards, or fiber mats. The finished flat material can, on the other hand, be subjected to higher temperatures, and the copolyamide develops good bonding with respect to the cellulose fibers normally used in the indicated flat materials.Type: ApplicationFiled: December 17, 2010Publication date: June 23, 2011Applicant: EMS-Patent AGInventors: Klaus Bender, Gunther Schäch, Eberhard Kinkelin