Polymerizing In The Presence Of A Specified Material Patents (Class 528/336)
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Patent number: 5824763Abstract: A process is disclosed for preparing a polyamide by polymerizing a diacid and a diamine, aminocarboxylic acid or lactam in the presence of excess of either acid or amine such that the ratio of acid to amine end groups or the ratio of amine end groups to acidend groups in the polymer is at least 2.0:1.0.Type: GrantFiled: August 21, 1996Date of Patent: October 20, 1998Assignee: E. I. du Pont de Nemours and CompanyInventor: Rolando Umali Pagilagan
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Patent number: 5821320Abstract: 18.4 grams of 4,4'-(hexafluoroisopropyridine)diphthalic acid dianhydride and 7.5 grams of 1,4-phenylenediamine dihydrochloride are mixed in a solvent consisting of 80 ml of N-methyl-2-pyrrolidone and 20 ml of dichlorobenzene and are heated at an argon atmosphere to raise its temperature from a room temperature to 170.degree. C. slowly and to be reacted for five hours while an azeotropic dihydration of water which is generated at 170.degree. C. is conducted. After the reaction is completed, a reaction product is precipitated in methanol, the precipitate is washed with methanol and dried at 80.degree. C. FIG. 1 shows the infrared spectra of the reaction product.Type: GrantFiled: May 15, 1997Date of Patent: October 13, 1998Assignee: Petroleum Energy CenterInventors: Masatoshi Maeda, Kenichi Ikeda
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Patent number: 5807972Abstract: The invention is directed to a hydrolytically polymerized polycaprolactam with new chain regulation, whereby the polymerization of caprolactam (I) is carried out with 0.1-0.7 weight percent of an aromatic dicarboxylic acid (II), 0.01-0.7 weight percent of an aliphatic or cycloaliphatic diamine (III) that carries a primary and a tertiary amino group, and/or 0.01-0.7 weight percent 4-amino-2,2,6,6-tetraalkyl piperidine (IV), whereby the quantities of constituents I through IV add up to 100 weight percent and the quantity of the constituents III and/or IV amounts to 0.01-0.7 weight percent.Type: GrantFiled: August 27, 1997Date of Patent: September 15, 1998Inventors: Hanns-Jorg Liedloff, Ernst Morf, Gerhard Schmidt
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Patent number: 5807968Abstract: A polyamide resin comprising the reaction product obtained by the reaction of an acid component comprised of a major concentration of a dimer acid and minor concentration of a monobasic acid and an amine component comprised of a major concentration of a short-chain alkylenediamine, a first minor concentration of a medium-chain alkylenediamine and second minor concentration of a polyoxyalkylene diamine having a molecular weight greater than about 500 is provided. The polyamide resin is used to form a blend of containing the polyamide in a major amount by weight and a first minor amount by weight of a polar wax and a second minor amount by weight of a polyolefin elastomer. The composition is used to reinforce a footwear upper, e.g. as a print on box toe material.Type: GrantFiled: April 4, 1996Date of Patent: September 15, 1998Assignee: Henkel CorporationInventors: Dwight D. Heinrich, Reimar Heucher, Sandra Drahos
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Patent number: 5807969Abstract: In a process for the preparation of poly-o-hydroxyamides and poly-o-mercaptoamides, a bis-o-aminophenol or a bis-o-aminothiophenol is reacted with a dicarboxylic acid derivative with the following structure:M--CO--R*--CO--Mwhere M stands for the residue of an (optionally substituted) 2-hydroxybenzoxazole, 2-hydroxybenzothiazole, or 1-hydroxybenzotriazole or of corresponding mercapto compounds and R* is the parent body of the dicarboxylic acid.Type: GrantFiled: August 28, 1996Date of Patent: September 15, 1998Assignee: Siemens AktiengesellschaftInventors: Recai Sezi, Hellmut Ahne, Eberhard Kuehn, Roland Gestigkeit
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Patent number: 5804682Abstract: A process is provided for preparing a dispersion of a polyamide in water, said process comprising:forming a solution of a polyamide having an acid value of greater than about 2 in an organic solvent to form a solution of said polyamide in said solvent, said polyamide and said solvent being at a temperature below the softening point of said polyamide during said dissolving, said solution further comprising a surfactant, wherein at least a portion of the acid value of said polyamide is neutralized,adding sufficient water to said solution with mixing to form an oil-in-water dispersion, the temperature of said solution and said water being below the softening point of said polyamide during said adding, andremoving at least a major amount of said organic solvent from said oil-in-water dispersion. The resulting dispersion is useful in preparing a coating of the polyamide, which coating is useful as an adhesive.Type: GrantFiled: October 25, 1996Date of Patent: September 8, 1998Assignee: Henkel CorporationInventors: Stephen A. Fischer, David I. Devore, Kartar S. Arora, Reimar Heucher, Michael S. Wiggins, Chase J. Boudreaux, Dwight D. Heinrich
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Patent number: 5801278Abstract: The invention provides a process for directly manufacturing a diamine/dicarboxylic acid salt with a low water content. The process includes reacting a diamine with a dicarboxylic acid to form a diamine/dicarboxylic acid salt. The reaction of the diamine and the dicarboxylic acid is carried out in the presence of about 0.5% to about 25% by weight water, based on the weight of the reaction mixture, while providing conditions in the reaction mixture such that the reaction mixture is in substantially solid particulate form.Type: GrantFiled: March 7, 1997Date of Patent: September 1, 1998Assignee: E. I. du Pont de Nemours and CompanhInventors: Ioannis V. Bletsos, Constantine D. Papaspyrides
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Patent number: 5798432Abstract: Liquid crystalline polymers that are made from 4-hydroxybenzoic acid, 2,6-naphthalenedicarboxylic acid, terephthalic acid, hydroquinone, and N-acetyl-4-aminophenol by heating the monomers in the presence of acetic anhydride are more easily synthesized in high molecular weight if isophthalic acid is also included as a monomer at a level of about 0.5 mole % to about 10 mole %.Type: GrantFiled: March 22, 1996Date of Patent: August 25, 1998Assignee: Hoechst Celanese Corp.Inventors: Cherylyn Lee, Vincent J. Provino, H. Clay Linstid, III
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Patent number: 5783654Abstract: In a process for the preparation of poly-o-hydroxyamides and poly-o-mercaptoamides, a bis-o-aminophenol or a bis-o-aminothiophenol is reacted with a dicarboxylic acid ester with the following structure:G--O--CO--R*--CO--O--G,where G is an (optionally substituted) succinimide or maleinimide group and R* is the parent body of the dicarboxylic acid.Type: GrantFiled: August 29, 1996Date of Patent: July 21, 1998Assignee: Siemens AktiengesellschaftInventors: Recai Sezi, Hellmut Ahne
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Patent number: 5770680Abstract: A process is provided for preparing a dispersion of a polyamide in water, said process comprising:dissolving a polyamide having an amine value of greater than about 2 in an organic solvent to form a solution of said polyamide in said solvent, said polyamide and said solvent being at a temperature below the softening point of, said polyamide during said dissolving, said solution further comprising a surfactant and an inorganic alkaline material,adding sufficient water containing an acid to said solution with mixing to form an oil-in-water dispersion, the temperature of said solution and said water being below the softening point of said polyamide during said adding, the amount of said acid being sufficient to neutralize a portion of said inorganic alkaline material, but insufficient to coagulate said polyamide from the resulting oil-in-water dispersion, andremoving at least a major amount of said organic solvent from said oil-in-water dispersion.Type: GrantFiled: October 25, 1996Date of Patent: June 23, 1998Inventors: Stephen A. Fischer, David I. Devore, Kartar S. Arora, Reimar Heucher
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Patent number: 5767228Abstract: The present invention relates to an aromatic polyamide pulp and its preparing process which has both excellent physical properties and high degree of polymerization wherein aromatic diamine is reacted with aromatic diacid chloride in amides and/or urea-based polymerization solvent containing inorganic salts and/or a little of Lewis acid compound. The present invention can easily provide the pulp of high polymerization degree and high orientation by stirrer in the continuous transferable polymerization-orientation-gelation apparatus within a short time without use of a tertiary amine affecting human body and without regard to isotropic or anisotropic, and continuous or uncontinuous ejection.Type: GrantFiled: October 4, 1996Date of Patent: June 16, 1998Assignee: Kolon Industries, Inc.Inventors: Jong Cheol Kim, Hyeong Rack Lee, Jae Hyun Lee, Seung Jo Lee, In Sik Han, Du Hyun Kim, Seock Chul Ryu, Won Jun Choe, Young Hwan Park
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Patent number: 5763561Abstract: Improved high temperature polyamides, and particularly partially aromatic polyamides, containing less than about 40 .mu.eq/g carboxylic acid endgroups, when stabilized with a copper-containing thermal stabilizer, the polyamides exhibit improved thermal oxidative stability.Type: GrantFiled: May 27, 1997Date of Patent: June 9, 1998Assignee: Amoco CorporationInventor: Robert G. Keske
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Patent number: 5760167Abstract: A copolyamide composition prepared from hexamethylene diamine and mixtures of adipic acid, terephthalic acid and isophthalic acid, has a melting point below 300.degree. C., a glass transition temperature between 100.degree. C. and 130.degree. C. and physical properties similar to nylon 66.Type: GrantFiled: November 15, 1995Date of Patent: June 2, 1998Assignee: Industrial Technology Research InstituteInventors: Wu-Bin Yuo, Chien-Shiun Liao, Wen-Jeng Lin, Li-Kuei Lin, Tien-San Lee, Szu-Yuan Chan
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Patent number: 5760164Abstract: A liquid system for executing the anionic lactam polymerization is proposed, which contains activators as well as catalysts and selectively additives and which is liquid at room temperature and remains stable when stored.Type: GrantFiled: January 21, 1997Date of Patent: June 2, 1998Assignee: Ems-Inventa AgInventors: Eduard Schmid, Roman Eder
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Patent number: 5750638Abstract: A method for producing poly-o-hydroxy amides by heating a dicarboxylic acid to a temperature .gtoreq.80.degree. C., together with a sulfonic acid chloride and a tertiary amine in a suitable solvent, to form a reaction mixture and reacting the mixture obtained with a bis-o-aminophenol solution at a temperature <80.degree. C.Type: GrantFiled: June 19, 1996Date of Patent: May 12, 1998Assignee: Siemens AktiengesesllschaftInventors: Recai Sezi, Hellmut Ahne, Roland Gestigkeit
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Patent number: 5739262Abstract: This invention relates to a novel ternary polyamide for the production of monofilaments, films and injection moulded articles.Type: GrantFiled: November 13, 1995Date of Patent: April 14, 1998Assignee: Bayer AGInventors: Heinrich Morhenn, Dieter Brokmeier, Werner Nielinger
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Patent number: 5726282Abstract: A class of rigid rod and latter polymers having light emitting capability is provided. Included in this class of polymers are those having novel repeating structural units. These rigid rod and ladder polymers are employed in light emitting diodes.Type: GrantFiled: June 19, 1996Date of Patent: March 10, 1998Assignee: Research Corporation Technologies, Inc.Inventors: Samson A. Jenekhe, John A. Osaheni
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Patent number: 5723562Abstract: Novel functionalized peroxides which may be used as crosslinking, grafting and curing agents, initiators for polymerization reactions and as monomers for condensation polymerizations to form peroxy-containing polymers, which in turn can be used to prepare block and graft copolymers, have the following Formula I: ##STR1## R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, X, Y.sup.1, Y.sup.2, Y.sup.3, Z.sup.1, Z.sup.2, x, y and z are as defined in the Summary of the Invention. The compounds of Formula I may be prepared by reacting hydroxy-containing tertiary hydroperoxides with diacid halides, phosgene, dichloroformates, diisocyanates, anhydrides and lactones to form the functionalized peroxides. These reaction products may be further reacted, if desired, with dialcohols, diamines, aminoalcohols, epoxides, epoxy alcohols, epoxy amines, diacid halides, dichloroformates and diisocyanates to form additional functionalized peroxides.Type: GrantFiled: December 5, 1996Date of Patent: March 3, 1998Assignee: Elf Atochem North America, Inc.Inventor: Daryl L. Stein
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Patent number: 5723568Abstract: A polyamide comprising a solution of (i) an aliphatic polyamide and/or an aliphatic aromatic poly amide dissolved in (ii) N-methyl-2-pyrrolidone and containing (iii) calcium chloride, the ratio between the polyamide (i) and the N-methyl-2-pyrrolidone (ii) in the solution composition being 3 to 25% by weight of the polyamide (i)to 97 to 75% by weight of the N-methyl-2-pyrrolidone, (ii) with the solution also containing calcium chloride (iii) in an amount of 5 to 60 parts by weight based on 100 parts by weight of the polyamide (i) which can be precipitated in a precipitant consisting essentially of water while stirring the precipitant to provide fibrids, which then can be mixed with fibers or natural pulp and formed into synthetic paper.Type: GrantFiled: December 29, 1995Date of Patent: March 3, 1998Assignee: Teijin LimitedInventors: Keizo Shimada, Jiro Sadanobu, Tsugusi Yosida, Yuzo Aito
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Patent number: 5714552Abstract: Disclosed is a two-step process for making an epichlorohydrin resin involving reacting the epichlorohydrin with a polyamine in a mixture first at a temperature of 25.degree.-40.degree. C. and then heating the mixture at 25.degree.-85.degree. C.Type: GrantFiled: March 24, 1994Date of Patent: February 3, 1998Assignee: Hercules IncorporatedInventor: Barton K. Bower
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Patent number: 5705603Abstract: The invention relates to reaction products of polyetheramines with polymers containing dicarboxylic anhydride groups, which contain 20-80, preferably 40-60, mol % of bivalent structural units A and/or C and, if required, B ##STR1## in which R.sup.1 and R.sup.2, independently of one another, are hydrogen or methyl,a and b are equal to zero or one and a+b is equal to one,Y is X or NRR.sup.3,X is --OH, --O--C.sub.1-30 -alkyl, NR.sup.3 R.sup.4 or --O.sup..crclbar. N.sup..sym. R.sup.3 R.sup.4,R.sup.3 and R.sup.4, independently of one another, are hydrogen, C.sub.6 -C.sub.40 -alkyl or R,R is ##STR2## with the proviso that at least 1 mol % of the anhydride groups bonded to the polymer have reacted with a polyetheramine,Z is C.sub.2 -C.sub.4 -alkyl,n is a number from 1 to 1000,R.sup.5 is hydrogen, C.sub.1 -C.sub.30 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl or C.sub.6 -C.sub.30 -aryl andR.sup.6 is hydrogen or C.sub.1 -C.sub.Type: GrantFiled: June 22, 1995Date of Patent: January 6, 1998Assignee: Hoechst AktiengesellschaftInventors: Matthias Krull, Michael Feustel, Erdmann Mielcke
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Patent number: 5698658Abstract: A linear polyamide having a weight average molecular weight above 200,000 is made by heating a lower molecular weight molten polyamide with thorough mixing at a temperature of about 265.degree.-300.degree. C. for at least 5 minutes while an inert gas is swept gently through the reactor, the increase of molecular weight of the polyamide being catalyzed by a particular phosphinic acid derivative.Type: GrantFiled: May 31, 1996Date of Patent: December 16, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventors: Ramdas Dujari, Daniel Gregory Tynan
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Patent number: 5688901Abstract: Partly aromatic semicrystalline thermoplastic polyamide molding compositions containA) from 40 to 100% by weight of a copolyamide composed ofa.sub.1) from 30 to 44 mol % of units which are derived from terephthalic acid,a.sub.2) from 6 to 20 mol % of units which are derived from isophthalic acid,a.sub.3) from 43 to 49.5 mol % of units which are derived from hexamethylenediamine anda.sub.4) from 0.5 to 7 mol % of units which are derived from aliphatic cyclic diamines of 6 to 30 carbon atoms,the molar percentages of components a.sub.1) to a.sub.4) together giving 100%, andB) from 0 to 50% by weight of a fibrous or particulate filler,C) from 0 to 30% by weight of an elastomeric polymer andD) from 0 to 30% by weight of conventional additives and processing assistants,the percentages by weight of components A) to D) together giving 100%.Type: GrantFiled: February 6, 1995Date of Patent: November 18, 1997Assignee: BASF AktiengesellschaftInventors: Herbert Fisch, Gunter Pipper, Klaus Muhlbach, Heiner Gorrissen
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Patent number: 5686556Abstract: Process for producing .alpha.-amino .omega.-ester monoamides such as H.sub.2 N--(CH.sub.2).sub.6 --NH--CO--(CH.sub.2).sub.4 --CO--OCH.sub.3 by reacting a diacid with a diamide at a diamine/diester molar ratio of 0.8 and 1.2 is provided. Additionally, a novel process for producing a polyamide by homopolymerization of an .alpha.-amino .omega.-ester monoamide is provided.Type: GrantFiled: September 14, 1995Date of Patent: November 11, 1997Assignee: Rhone-Poulenc ChimieInventors: Frederic Jouffret, Pierre-Jean Madec
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Patent number: 5674973Abstract: A process for the continuous production of polyamides from a mixture of at least one lactam and water and, if required, other monomer units and/or conventional additives and fillers under polyamide-forming conditions, where the mixture of the starting materials is heated in liquid phase in a first reaction zone until a conversion of at least 70% is reached, and undergoes adiabatic decompression and further polymerization in another reaction zone, wherein, in the first reaction zone, 0.5-7% by weight of water are employed, the temperature is increased to the range from 220.degree. to 310.degree. C., and polymerization is carried out until a conversion of at least 85% is reached and, in the second reaction zone, after the decompression further polymerization is carried out in the range from 215.degree. to 300.degree. C. without heat input.Type: GrantFiled: December 28, 1995Date of Patent: October 7, 1997Assignee: BASF AktiengesellschaftInventors: Gunter Pipper, Andreas Kleinke, Peter Hildenbrand
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Patent number: 5668248Abstract: A photosensitive resin composition comprising, as its main ingredient, a poly(amic acid) resin constituted of a diamino compound represented by formula: ##STR1## and optionally used other diamino compound and a tetracarboxylic acid dianhydride as its constituent monomers and/or a poly(amic acid) ester resin obtained by esterifying said poly(amic acid) resin and/or a polyimide resin obtained by a dehydrating or alcohol-eliminating ring-closure reaction of said poly(amic acid) resin or poly(amic acid) ester resin has an excellent developability and a high film strength and can form a relief patter of low thermal expansion.Type: GrantFiled: August 22, 1995Date of Patent: September 16, 1997Assignee: Hitachi Chemical Co., Ltd.Inventors: Hideo Hagiwara, Makoto Kaji, Hiroshi Nishizawa, Kenji Suzuki, Yasunori Kojima
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Patent number: 5668246Abstract: Disclosed is an improvement in a method of making a water-soluble epichlorohydrin resin involving reacting epichlorohydrin with a polyaminoamide. The improvement involves preparing the polyaminoamide in the presence of an acid catalyst (low temperature condensation) followed by reaction with epichlorohydrin.Type: GrantFiled: August 9, 1996Date of Patent: September 16, 1997Assignee: Hercules IncorporatedInventor: William W. Maslanka
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Patent number: 5665854Abstract: A low temperature process for polymerizing nylon monomers to freely flowing polymers is disclosed. The polymerization process is carried out at lower than conventional polymerization temperatures and produces a freely flowing polymer without thermal degradation.Type: GrantFiled: March 24, 1995Date of Patent: September 9, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventors: Leonard Edward Raymond Kosinski, Richard Robert Soelch
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Patent number: 5659009Abstract: In a process for producing filler-containing thermoplastic molding compositions by mixing fillers with thermoplastics in the melt,a) the fillers are mixed in a mixing apparatus in the melt with a low molecular weight thermoplastic having a melt viscosity of at most 30 Pas (measured at 20.degree. C. above the melting point of the thermoplastic compound and at a shear gradient of 1,000 s.sup.-1),b) the product thus obtained is removed from the mixing apparatus, cooled and comminuted, andc) the comminuted product is then subjected in the solid phase to a post-condensation.Type: GrantFiled: November 17, 1995Date of Patent: August 19, 1997Assignee: BASF AktiengesellschaftInventors: Gunter Pipper, Walter Goetz, Claus Cordes, Josef Georg Floss, Guenter Mattern, Peter Hildenbrand, James Hurley, Karl Schlichting, Graham Edmund McKee, Gerd Blinne
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Patent number: 5659007Abstract: A process for producing an aromatic polyamide film comprising forming a thin layer of an optically isotropic dope in which an aromatic polyamide is dissolved in a polar amide, immersing the thin layer dope in a polar solvent kept at a temperature not higher than -20.degree. C. to coagulate the dope to form a film and drying the film in the presence of an isocyanate compound. Said process can produce directly a transparent film from an aromatic polyamide dope without requiring the step of dissolving the aromatic polyamide in conc. sulfuric acid, does not require any acid resistant equipment and is inexpensive.Type: GrantFiled: July 26, 1995Date of Patent: August 19, 1997Assignee: Sumitomo Chemical Company, LimitedInventors: Kazunori Akiyoshi, Katsuhiko Iwasaki, Masahiro Niwano, Yoshitaka Ohbe
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Patent number: 5650482Abstract: An at least two-step process for the preparation of polyamide resins wherein, in the first step, polyvalent carboxylic acids, optionally together with monovalent carboxylic acids, are reacted with a stoichiometric deficiency of polyamines in the presence of an organic solvent which forms an azeotrope with water, water is distilled off, and the reaction is controlled by means of the amount of water formed by the condensation reaction and, optionally, by the imidazoline formation. After removal of the theoretical amount of water or a lesser amount, in a further step more amine is added to the reaction mixture in an amount sufficient to achieve a final amine number of 10 to 300 mgKOH/g, the reaction is continued, substantially all of the residual water is removed, and the residual solvent is completely or partially removed.Type: GrantFiled: September 27, 1995Date of Patent: July 22, 1997Assignee: Air Products and Chemicals, Inc.Inventor: William Rene Eduard Raymond
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Patent number: 5644021Abstract: Disclosed is an improvement in a method of making a water-soluble epichlorohydrin resin involving reacting epichlorohydrin with a polyaminoamide. The improvement involves preparing the polyaminoamide in the presence of an acid catalyst (low temperature condensation) followed by reaction with epichlorohydrin.Type: GrantFiled: June 7, 1995Date of Patent: July 1, 1997Assignee: Hercules IncorporatedInventor: William Ivalter Maslanka
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Patent number: 5627257Abstract: Process for synthesis of spinnable polyamide from .alpha., .omega.-alkyldinitriles and .alpha., .omega.-alkyldiamines and excess water, where a) the aqueous solution of the dinitrile is mixed with a catalytic amount of at least one oxygen-containing acid of phosphorus and/or a water-soluble salt of calcium, zinc, cadmium or manganese in the absence of the diamine, and the pH of this solution is adjusted to an initial value in the range of 2.0 to 4.0 before hydrolysis by adding a saturated aliphatic or aromatic dicarboxylic acid and the dinitrile is and the amide-containing precursors derived therefrom are hydrolyzed to dicarboxylic acid at an elevated temperature under autogenous pressure, whereby the hydrolysis is controlled by conductometric determination of the hydrolysate, and b) at least an equimolar amount of diamine is added to the solution from step a) and the mixture is subjected to polycondensation to form polyamide [nylon].Type: GrantFiled: February 12, 1996Date of Patent: May 6, 1997Assignee: Zimmer AktiengesellschaftInventor: Hartmut Liehr
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Patent number: 5612384Abstract: Disclosed are methods of producing super absorbing polymeric networks of polyaspartates from crosslinked polysuccinimide. In one preferred method aspect, polysuccinimide is first reacted with an organic crosslinking agent, preferably an organic base containing at least two primary amine groups to form crosslinked polysuccinimide. The crosslinked polysuccinimide is then hydrolyzed to a polymeric network of polyaspartate which demonstrates super absorbing capability in water and in saline solution. Alternative method aspects are disclosed in which super absorbing polymeric networks of polyaspartates are produced in a single reaction vessel by sequentially crosslinking polysuccinimide with organic crosslinking agent in an aqueous reaction mixture and then hydrolyzing the reaction product to produce a polymeric network of polyaspartate.Type: GrantFiled: September 13, 1994Date of Patent: March 18, 1997Assignee: Donlar CorporationInventors: Robert J. Ross, Kim C. Low, Larry P. Koskan, Alfred P. Wheeler
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Patent number: 5597888Abstract: The invention relates to a process for the production of high molecular weight polyamide 6 (polycaprolactam).Type: GrantFiled: June 9, 1995Date of Patent: January 28, 1997Assignee: Bayer AktiengesellschaftInventors: Werner Nielinger, Andreas Gittinger, Edgar Ostlinning, Karsten-Josef Idel, Helmut Schulte
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Patent number: 5585429Abstract: Polyphthalamide formulations containing from 0.1 to about 2 wt % alkali metal halide have a significantly reduced melt viscosity and both filled and untilled resin formulations containing the requisite amount of alkali metal halide are more readily processed by thermal means. When stabilized with a copper-containing stabilizer and, optionally, a polyolefin synergist the formulations exhibit substantially improved dry heat stability and are particularly useful in the production of thermally-stabilized melt spun polyphthalamide fiber for applications where extended exposure to elevated temperatures in air is contemplated.Type: GrantFiled: March 27, 1995Date of Patent: December 17, 1996Assignee: Amoco CorporationInventor: Mark G. Reichmann
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Patent number: 5582911Abstract: An aramid monofilament having high mechanical properties is provided. This monofilament has a slightly structured skin and resists fibrillation and abrasion. In addition, a process for the production of this monofilament is also provided. The process includes the following steps:(i) a solution of aromatic polyamide(s) is extruded as a liquid jet in a spinneret through a capillary; (ii) the jet is drawn from the capillary in a non-coagulating layer of fluid and (iii) the drawn liquid vein is introduced into a coagulating medium in order to form the monofilament, which is subsequently washed, dried and contacted with a solvent for said monofilament to produce the slightly structured skin. The aramid monofilament is characterized by the following relationships:1.7.ltoreq.Ti.ltoreq.260;40.ltoreq.D.ltoreq.480;T.gtoreq.180-D/3;Mi.gtoreq.1600;Ar>2.00; andEr>20-D/30.In the above relationship, Ti represents linear density in tex, D represents diameter in .mu.Type: GrantFiled: August 19, 1994Date of Patent: December 10, 1996Assignee: Michelin Recherche et. Technique, S.A.Inventors: Jean-Paul Meraldi, Joel Ribiere, Jean-Jacques Almon
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Patent number: 5574128Abstract: Polyetheresteramides, characterized in that they comprise both of the following repeating entities: ##STR1## in which X represents the residue of a polyamide-diacid oligomer with an Mn of between 300 and 8000, Y represents the residue of a polyetherdiol with an Mn of between 200 and 5000, and Z represents the residue of a polyetherdiamine with an Mn of between 200 and 5000, wherein the proportion by mass of the entities Z resulting from the condensation of the polyetherdiamine with respect to the total amount of the entities resulting from the polyetherdiol and polyetherdiamine, i.e. Z/(Z+Y), is between 1 and 50%. The polyetheresteramides according to the invention can be used as is and are suitable for the production of mouldings, extrudates, films, sheaths, or composite materials such as multi-layer film. They can also be mixed with other polymers and in particular with polyamides.Type: GrantFiled: August 10, 1994Date of Patent: November 12, 1996Assignee: Elf Atochem S.A.Inventors: Didier Judas, Jean-Marc Sage
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Patent number: 5554722Abstract: Aromatic polyamide compositions with improved electrostatic properties, formed structures produced therefrom, and use and production thereof.Described are compositions comprising an aromatic polyamide which is soluble in organic solvents and from 0.01 to 30% by weight, based on the weight of the composition, of an organic or organometallic charge control agent.The compositions can be used for producing formed structures, in particular fibers; these fibers are preferably used for producing webs which can be used for producing dust filters.Type: GrantFiled: August 15, 1994Date of Patent: September 10, 1996Assignee: Hoechst AGInventors: Dieter Eichenauer, Werner Groh, Hans-Tobias Macholdt, Jorg Dahringer, Holger Jung, Richard Neuert
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Patent number: 5550208Abstract: A process for preparing condensation polymers comprises forming a dispersion of a reaction mixture in a continuous vapor phase, maintaining the dispersion while passing it through a reaction zone, heating the dispersion in the reaction zone to polymerize reactants in the reaction mixture and form a polycondensate.Type: GrantFiled: February 10, 1995Date of Patent: August 27, 1996Assignee: Amoco CorporationInventors: Joel A. Richardson, Wassily Poppe, Benjamin A. Bolton, Edward E. Paschke
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Patent number: 5548031Abstract: A process for producing a copolymer having succinimide units represented by general formula (I) is provided which comprises reaction of a copolymer constituted of 40-60 mole % of maleic anhydride units, 60-40 mole % of olefin units, and 0-20 mole % of another copolymerizable monomer units with an amine to convert the maleic anhydride units to the succinimide units, wherein the succinimide units are formed by ring-closing imidation in a slurry state in a poor solvent: ##STR1## where R.sub.1 is a hydrogen atom, or an alkyl or cycloalkyl group of 1 to 6 carbons. The copolymer has low yellowness and high transparency.Type: GrantFiled: November 14, 1994Date of Patent: August 20, 1996Assignee: Tosoh CorporationInventor: Toru Doi
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Patent number: 5545833Abstract: A polymer including as integral parts of polymer chain, amide groups of the formula ##STR1## and phosphinic acid-salt groups of the formula ##STR2## wherein a and b are both greater than or equal to 2 and M is selected from the group of metal cations where n=1 or n=2.The polymer of the present invention is particularly useful in forming stain-resistant fibers for carpet pile.Type: GrantFiled: May 30, 1995Date of Patent: August 13, 1996Assignee: Monsanto CompanyInventor: John W. Stoddard
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Patent number: 5539079Abstract: Disclosed is a process for preparing nylon by adding an amidation catalyst concentrated in "masterbatches" to the process melt resulting in a product with increased molecular weight and viscosity.Type: GrantFiled: February 14, 1995Date of Patent: July 23, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventors: Gregory D. Cramer, Ramdas Dujari, Robert C. Wheland
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Patent number: 5534614Abstract: A polyamide precursor of a polybenzazole polymer is prepared by reacting an aromatic bis(alkenyl)ester with a ring forming, aromatic diamine. The precursor can be prepared in an organic solvent for the monomers to form a soluble polyamide precursor which can be subsequently cyclocondensed to form a PBX polymer. A polybenzoxazole precursor is prepared by the reaction of a bis(alkenyl)ester and a bis(ortho-hydroxyamine). A polybenzazole polymer is easily prepared by heating the polyamide, PBX precursor.Type: GrantFiled: March 28, 1994Date of Patent: July 9, 1996Assignee: The Dow Chemical CompanyInventors: James J. O'Briem, Edmund P. Woo
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Patent number: 5523383Abstract: A process for the preparation of a photocurable resin which comprises the steps of(I) (a) imidating 20 to 80 mole % of the acid arthydride groups present in an adduct prepared by the addition reaction of an .alpha.,.beta.-unsaturated dicarboxylic acid arthydride to a conjugated diene polymer or copolymer with a primary amine to produce water and an amide,(b) reacting the thus formed water as a by-product with at least a part of the remaining acid arthydride groups in said adduct to produce the succinic acid groups by opening the ring of said acid arthydride groups,(II) dehydrating the thus produced succinic acid groups by heating to cause ring closure again thereby forming acid anhydride groups and(III) reacting at least a part, preferably at least 50 mole %, of the acid anhydride rings present in the polymer with an .alpha.,.beta.-unsaturated monocarboxylic acid ester having an alcoholic hydroxyl group to conduct a half-esterification by opening the ring of said acid arthydride groups.Type: GrantFiled: May 11, 1994Date of Patent: June 4, 1996Assignee: Nippon Petrochemicals Co., Ltd.Inventors: Nobuo Ikeda, Teruhisa Kuroki, Tatsuo Yamaguchi, Hiroyoshi Oomiya
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Patent number: 5519109Abstract: Moisture-curing polyamides containing reactive alkoxysilane groups and a process for their preparation are provided. The reactive alkoxysilane groups contain organic groups which are not reactive during the production process, the intended application or the curing process. These moisture-curing polyamides have low melt viscosities and are useful as sealing compounds, hotmelt adhesives and encapsulating materials.Type: GrantFiled: January 17, 1995Date of Patent: May 21, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Hans-Georg Kinzelmann, Reimar Heucher, Juergen Wichelhaus
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Patent number: 5516882Abstract: A process for the preparation of a copolyamide involving copolymerization of (1) a carboxylic acid of terephthalic acid or a terephthalic acid/isophthalic acid mixture with (2) a mixture of hexamethylene diamine and 2-methyl pentamethylene diamine. The combined amount of isophthalic acid and 2-methyl pentamethylene diamine is controlled so that the resultant copolyamide exhibits few, if any, high melting fractions.Type: GrantFiled: September 6, 1994Date of Patent: May 14, 1996Assignee: E. I. du Pont de Nemours and CompanyInventor: Richard R. Soelch
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Patent number: 5506336Abstract: The present invention relates to an apparatus for processing materials, a process for mixing, finishing and de-volatizing polyamide to make 66 nylon and the 66 nylon made by this process. The apparatus comprises an agitator section having an outlet adjacent the bottom thereof; a transfer screw disposed adjacent the outlet of the agitator section; a spiral ribbon extending upwardly from the transfer screw; a ring disposed vertically above the spiral ribbon, at least one baffle disposed vertically above the spiral ribbon and connected to the ring and a wall-wiping spur connected to the ring. Preferably, the apparatus has two baffles--an upper one for pumping the material downwardly and a lower one for pumping the material upwardly. The diameter of each baffle is preferably about 80% of the diameter of the agitator section.Type: GrantFiled: November 30, 1994Date of Patent: April 9, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventor: John M. Iwasyk
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Patent number: 5504182Abstract: Thermoplastically processable aromatic polyether amideThermoplastically processable aromatic polyether amide of the formula (I) ##STR1## in which the symbols Ar, Ar', Ar.sub.1, Ar.sub.2, R, R', Y, x, y and z have the following meanings:Ar is a divalent, substituted or unsubstituted, aromatic or heteroaromatic radical or a group--Ar*--Q--Ar*--in whichQ is a bond or an --O--, --C(CH.sub.3).sub.2, --CO--, --S--, --SO-- or --SO.sub.2 -- bridge and Ar* is an aromatic radical. The carbonyl groups of the Ar radical are on non-adjacent ring carbon atoms.A is up to three different radicals.Ar' has the meaning given for Ar or is an Ar--Z--Ar group.In this case, Z is a --C(CH.sub.3).sub.2 -- or --O--Ar*--O--bridge.Y is a --C(CH.sub.3).sub.2 --, --SO.sub.2 --, --S-- or a --C(CF.sub.3).sub.2 --bridge and has up to two different meanings in the same polymer.Ar.sub.1 and Ar.sub.2 are identical or different from one another and are each a substituted or unsubstituted para- or meta-arylene radical.Type: GrantFiled: April 30, 1993Date of Patent: April 2, 1996Assignee: Hoechst AktiengesellschaftInventors: Harald Cherdron, Willi Kreuder, Arnold Schneller, Otto Herrmann-Schonherr
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Patent number: 5504184Abstract: Xanthene polyesters and polyamides are provided resulting from the reaction of alkylene, cycloaliphatic or aromatic diols or organo diamines with xanthene dicarboxylic esters or xanthene dicarboxylic acid halides. These amorphous, or crystalline film forming, high performance thermoplastics which are useful in automotive applications, and include copolymers and blends of such xanthene polymers.Type: GrantFiled: June 6, 1995Date of Patent: April 2, 1996Assignee: General Electric CompanyInventors: Andrew J. Caruso, Julia L. Lee