Polymerizing In The Presence Of A Specified Material Patents (Class 528/336)
  • Patent number: 5824763
    Abstract: A process is disclosed for preparing a polyamide by polymerizing a diacid and a diamine, aminocarboxylic acid or lactam in the presence of excess of either acid or amine such that the ratio of acid to amine end groups or the ratio of amine end groups to acidend groups in the polymer is at least 2.0:1.0.
    Type: Grant
    Filed: August 21, 1996
    Date of Patent: October 20, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Rolando Umali Pagilagan
  • Patent number: 5821320
    Abstract: 18.4 grams of 4,4'-(hexafluoroisopropyridine)diphthalic acid dianhydride and 7.5 grams of 1,4-phenylenediamine dihydrochloride are mixed in a solvent consisting of 80 ml of N-methyl-2-pyrrolidone and 20 ml of dichlorobenzene and are heated at an argon atmosphere to raise its temperature from a room temperature to 170.degree. C. slowly and to be reacted for five hours while an azeotropic dihydration of water which is generated at 170.degree. C. is conducted. After the reaction is completed, a reaction product is precipitated in methanol, the precipitate is washed with methanol and dried at 80.degree. C. FIG. 1 shows the infrared spectra of the reaction product.
    Type: Grant
    Filed: May 15, 1997
    Date of Patent: October 13, 1998
    Assignee: Petroleum Energy Center
    Inventors: Masatoshi Maeda, Kenichi Ikeda
  • Patent number: 5807972
    Abstract: The invention is directed to a hydrolytically polymerized polycaprolactam with new chain regulation, whereby the polymerization of caprolactam (I) is carried out with 0.1-0.7 weight percent of an aromatic dicarboxylic acid (II), 0.01-0.7 weight percent of an aliphatic or cycloaliphatic diamine (III) that carries a primary and a tertiary amino group, and/or 0.01-0.7 weight percent 4-amino-2,2,6,6-tetraalkyl piperidine (IV), whereby the quantities of constituents I through IV add up to 100 weight percent and the quantity of the constituents III and/or IV amounts to 0.01-0.7 weight percent.
    Type: Grant
    Filed: August 27, 1997
    Date of Patent: September 15, 1998
    Inventors: Hanns-Jorg Liedloff, Ernst Morf, Gerhard Schmidt
  • Patent number: 5807968
    Abstract: A polyamide resin comprising the reaction product obtained by the reaction of an acid component comprised of a major concentration of a dimer acid and minor concentration of a monobasic acid and an amine component comprised of a major concentration of a short-chain alkylenediamine, a first minor concentration of a medium-chain alkylenediamine and second minor concentration of a polyoxyalkylene diamine having a molecular weight greater than about 500 is provided. The polyamide resin is used to form a blend of containing the polyamide in a major amount by weight and a first minor amount by weight of a polar wax and a second minor amount by weight of a polyolefin elastomer. The composition is used to reinforce a footwear upper, e.g. as a print on box toe material.
    Type: Grant
    Filed: April 4, 1996
    Date of Patent: September 15, 1998
    Assignee: Henkel Corporation
    Inventors: Dwight D. Heinrich, Reimar Heucher, Sandra Drahos
  • Patent number: 5807969
    Abstract: In a process for the preparation of poly-o-hydroxyamides and poly-o-mercaptoamides, a bis-o-aminophenol or a bis-o-aminothiophenol is reacted with a dicarboxylic acid derivative with the following structure:M--CO--R*--CO--Mwhere M stands for the residue of an (optionally substituted) 2-hydroxybenzoxazole, 2-hydroxybenzothiazole, or 1-hydroxybenzotriazole or of corresponding mercapto compounds and R* is the parent body of the dicarboxylic acid.
    Type: Grant
    Filed: August 28, 1996
    Date of Patent: September 15, 1998
    Assignee: Siemens Aktiengesellschaft
    Inventors: Recai Sezi, Hellmut Ahne, Eberhard Kuehn, Roland Gestigkeit
  • Patent number: 5804682
    Abstract: A process is provided for preparing a dispersion of a polyamide in water, said process comprising:forming a solution of a polyamide having an acid value of greater than about 2 in an organic solvent to form a solution of said polyamide in said solvent, said polyamide and said solvent being at a temperature below the softening point of said polyamide during said dissolving, said solution further comprising a surfactant, wherein at least a portion of the acid value of said polyamide is neutralized,adding sufficient water to said solution with mixing to form an oil-in-water dispersion, the temperature of said solution and said water being below the softening point of said polyamide during said adding, andremoving at least a major amount of said organic solvent from said oil-in-water dispersion. The resulting dispersion is useful in preparing a coating of the polyamide, which coating is useful as an adhesive.
    Type: Grant
    Filed: October 25, 1996
    Date of Patent: September 8, 1998
    Assignee: Henkel Corporation
    Inventors: Stephen A. Fischer, David I. Devore, Kartar S. Arora, Reimar Heucher, Michael S. Wiggins, Chase J. Boudreaux, Dwight D. Heinrich
  • Patent number: 5801278
    Abstract: The invention provides a process for directly manufacturing a diamine/dicarboxylic acid salt with a low water content. The process includes reacting a diamine with a dicarboxylic acid to form a diamine/dicarboxylic acid salt. The reaction of the diamine and the dicarboxylic acid is carried out in the presence of about 0.5% to about 25% by weight water, based on the weight of the reaction mixture, while providing conditions in the reaction mixture such that the reaction mixture is in substantially solid particulate form.
    Type: Grant
    Filed: March 7, 1997
    Date of Patent: September 1, 1998
    Assignee: E. I. du Pont de Nemours and Companh
    Inventors: Ioannis V. Bletsos, Constantine D. Papaspyrides
  • Patent number: 5798432
    Abstract: Liquid crystalline polymers that are made from 4-hydroxybenzoic acid, 2,6-naphthalenedicarboxylic acid, terephthalic acid, hydroquinone, and N-acetyl-4-aminophenol by heating the monomers in the presence of acetic anhydride are more easily synthesized in high molecular weight if isophthalic acid is also included as a monomer at a level of about 0.5 mole % to about 10 mole %.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: August 25, 1998
    Assignee: Hoechst Celanese Corp.
    Inventors: Cherylyn Lee, Vincent J. Provino, H. Clay Linstid, III
  • Patent number: 5783654
    Abstract: In a process for the preparation of poly-o-hydroxyamides and poly-o-mercaptoamides, a bis-o-aminophenol or a bis-o-aminothiophenol is reacted with a dicarboxylic acid ester with the following structure:G--O--CO--R*--CO--O--G,where G is an (optionally substituted) succinimide or maleinimide group and R* is the parent body of the dicarboxylic acid.
    Type: Grant
    Filed: August 29, 1996
    Date of Patent: July 21, 1998
    Assignee: Siemens Aktiengesellschaft
    Inventors: Recai Sezi, Hellmut Ahne
  • Patent number: 5770680
    Abstract: A process is provided for preparing a dispersion of a polyamide in water, said process comprising:dissolving a polyamide having an amine value of greater than about 2 in an organic solvent to form a solution of said polyamide in said solvent, said polyamide and said solvent being at a temperature below the softening point of, said polyamide during said dissolving, said solution further comprising a surfactant and an inorganic alkaline material,adding sufficient water containing an acid to said solution with mixing to form an oil-in-water dispersion, the temperature of said solution and said water being below the softening point of said polyamide during said adding, the amount of said acid being sufficient to neutralize a portion of said inorganic alkaline material, but insufficient to coagulate said polyamide from the resulting oil-in-water dispersion, andremoving at least a major amount of said organic solvent from said oil-in-water dispersion.
    Type: Grant
    Filed: October 25, 1996
    Date of Patent: June 23, 1998
    Inventors: Stephen A. Fischer, David I. Devore, Kartar S. Arora, Reimar Heucher
  • Patent number: 5767228
    Abstract: The present invention relates to an aromatic polyamide pulp and its preparing process which has both excellent physical properties and high degree of polymerization wherein aromatic diamine is reacted with aromatic diacid chloride in amides and/or urea-based polymerization solvent containing inorganic salts and/or a little of Lewis acid compound. The present invention can easily provide the pulp of high polymerization degree and high orientation by stirrer in the continuous transferable polymerization-orientation-gelation apparatus within a short time without use of a tertiary amine affecting human body and without regard to isotropic or anisotropic, and continuous or uncontinuous ejection.
    Type: Grant
    Filed: October 4, 1996
    Date of Patent: June 16, 1998
    Assignee: Kolon Industries, Inc.
    Inventors: Jong Cheol Kim, Hyeong Rack Lee, Jae Hyun Lee, Seung Jo Lee, In Sik Han, Du Hyun Kim, Seock Chul Ryu, Won Jun Choe, Young Hwan Park
  • Patent number: 5763561
    Abstract: Improved high temperature polyamides, and particularly partially aromatic polyamides, containing less than about 40 .mu.eq/g carboxylic acid endgroups, when stabilized with a copper-containing thermal stabilizer, the polyamides exhibit improved thermal oxidative stability.
    Type: Grant
    Filed: May 27, 1997
    Date of Patent: June 9, 1998
    Assignee: Amoco Corporation
    Inventor: Robert G. Keske
  • Patent number: 5760167
    Abstract: A copolyamide composition prepared from hexamethylene diamine and mixtures of adipic acid, terephthalic acid and isophthalic acid, has a melting point below 300.degree. C., a glass transition temperature between 100.degree. C. and 130.degree. C. and physical properties similar to nylon 66.
    Type: Grant
    Filed: November 15, 1995
    Date of Patent: June 2, 1998
    Assignee: Industrial Technology Research Institute
    Inventors: Wu-Bin Yuo, Chien-Shiun Liao, Wen-Jeng Lin, Li-Kuei Lin, Tien-San Lee, Szu-Yuan Chan
  • Patent number: 5760164
    Abstract: A liquid system for executing the anionic lactam polymerization is proposed, which contains activators as well as catalysts and selectively additives and which is liquid at room temperature and remains stable when stored.
    Type: Grant
    Filed: January 21, 1997
    Date of Patent: June 2, 1998
    Assignee: Ems-Inventa Ag
    Inventors: Eduard Schmid, Roman Eder
  • Patent number: 5750638
    Abstract: A method for producing poly-o-hydroxy amides by heating a dicarboxylic acid to a temperature .gtoreq.80.degree. C., together with a sulfonic acid chloride and a tertiary amine in a suitable solvent, to form a reaction mixture and reacting the mixture obtained with a bis-o-aminophenol solution at a temperature <80.degree. C.
    Type: Grant
    Filed: June 19, 1996
    Date of Patent: May 12, 1998
    Assignee: Siemens Aktiengesesllschaft
    Inventors: Recai Sezi, Hellmut Ahne, Roland Gestigkeit
  • Patent number: 5739262
    Abstract: This invention relates to a novel ternary polyamide for the production of monofilaments, films and injection moulded articles.
    Type: Grant
    Filed: November 13, 1995
    Date of Patent: April 14, 1998
    Assignee: Bayer AG
    Inventors: Heinrich Morhenn, Dieter Brokmeier, Werner Nielinger
  • Patent number: 5726282
    Abstract: A class of rigid rod and latter polymers having light emitting capability is provided. Included in this class of polymers are those having novel repeating structural units. These rigid rod and ladder polymers are employed in light emitting diodes.
    Type: Grant
    Filed: June 19, 1996
    Date of Patent: March 10, 1998
    Assignee: Research Corporation Technologies, Inc.
    Inventors: Samson A. Jenekhe, John A. Osaheni
  • Patent number: 5723562
    Abstract: Novel functionalized peroxides which may be used as crosslinking, grafting and curing agents, initiators for polymerization reactions and as monomers for condensation polymerizations to form peroxy-containing polymers, which in turn can be used to prepare block and graft copolymers, have the following Formula I: ##STR1## R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, X, Y.sup.1, Y.sup.2, Y.sup.3, Z.sup.1, Z.sup.2, x, y and z are as defined in the Summary of the Invention. The compounds of Formula I may be prepared by reacting hydroxy-containing tertiary hydroperoxides with diacid halides, phosgene, dichloroformates, diisocyanates, anhydrides and lactones to form the functionalized peroxides. These reaction products may be further reacted, if desired, with dialcohols, diamines, aminoalcohols, epoxides, epoxy alcohols, epoxy amines, diacid halides, dichloroformates and diisocyanates to form additional functionalized peroxides.
    Type: Grant
    Filed: December 5, 1996
    Date of Patent: March 3, 1998
    Assignee: Elf Atochem North America, Inc.
    Inventor: Daryl L. Stein
  • Patent number: 5723568
    Abstract: A polyamide comprising a solution of (i) an aliphatic polyamide and/or an aliphatic aromatic poly amide dissolved in (ii) N-methyl-2-pyrrolidone and containing (iii) calcium chloride, the ratio between the polyamide (i) and the N-methyl-2-pyrrolidone (ii) in the solution composition being 3 to 25% by weight of the polyamide (i)to 97 to 75% by weight of the N-methyl-2-pyrrolidone, (ii) with the solution also containing calcium chloride (iii) in an amount of 5 to 60 parts by weight based on 100 parts by weight of the polyamide (i) which can be precipitated in a precipitant consisting essentially of water while stirring the precipitant to provide fibrids, which then can be mixed with fibers or natural pulp and formed into synthetic paper.
    Type: Grant
    Filed: December 29, 1995
    Date of Patent: March 3, 1998
    Assignee: Teijin Limited
    Inventors: Keizo Shimada, Jiro Sadanobu, Tsugusi Yosida, Yuzo Aito
  • Patent number: 5714552
    Abstract: Disclosed is a two-step process for making an epichlorohydrin resin involving reacting the epichlorohydrin with a polyamine in a mixture first at a temperature of 25.degree.-40.degree. C. and then heating the mixture at 25.degree.-85.degree. C.
    Type: Grant
    Filed: March 24, 1994
    Date of Patent: February 3, 1998
    Assignee: Hercules Incorporated
    Inventor: Barton K. Bower
  • Patent number: 5705603
    Abstract: The invention relates to reaction products of polyetheramines with polymers containing dicarboxylic anhydride groups, which contain 20-80, preferably 40-60, mol % of bivalent structural units A and/or C and, if required, B ##STR1## in which R.sup.1 and R.sup.2, independently of one another, are hydrogen or methyl,a and b are equal to zero or one and a+b is equal to one,Y is X or NRR.sup.3,X is --OH, --O--C.sub.1-30 -alkyl, NR.sup.3 R.sup.4 or --O.sup..crclbar. N.sup..sym. R.sup.3 R.sup.4,R.sup.3 and R.sup.4, independently of one another, are hydrogen, C.sub.6 -C.sub.40 -alkyl or R,R is ##STR2## with the proviso that at least 1 mol % of the anhydride groups bonded to the polymer have reacted with a polyetheramine,Z is C.sub.2 -C.sub.4 -alkyl,n is a number from 1 to 1000,R.sup.5 is hydrogen, C.sub.1 -C.sub.30 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl or C.sub.6 -C.sub.30 -aryl andR.sup.6 is hydrogen or C.sub.1 -C.sub.
    Type: Grant
    Filed: June 22, 1995
    Date of Patent: January 6, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Matthias Krull, Michael Feustel, Erdmann Mielcke
  • Patent number: 5698658
    Abstract: A linear polyamide having a weight average molecular weight above 200,000 is made by heating a lower molecular weight molten polyamide with thorough mixing at a temperature of about 265.degree.-300.degree. C. for at least 5 minutes while an inert gas is swept gently through the reactor, the increase of molecular weight of the polyamide being catalyzed by a particular phosphinic acid derivative.
    Type: Grant
    Filed: May 31, 1996
    Date of Patent: December 16, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Ramdas Dujari, Daniel Gregory Tynan
  • Patent number: 5688901
    Abstract: Partly aromatic semicrystalline thermoplastic polyamide molding compositions containA) from 40 to 100% by weight of a copolyamide composed ofa.sub.1) from 30 to 44 mol % of units which are derived from terephthalic acid,a.sub.2) from 6 to 20 mol % of units which are derived from isophthalic acid,a.sub.3) from 43 to 49.5 mol % of units which are derived from hexamethylenediamine anda.sub.4) from 0.5 to 7 mol % of units which are derived from aliphatic cyclic diamines of 6 to 30 carbon atoms,the molar percentages of components a.sub.1) to a.sub.4) together giving 100%, andB) from 0 to 50% by weight of a fibrous or particulate filler,C) from 0 to 30% by weight of an elastomeric polymer andD) from 0 to 30% by weight of conventional additives and processing assistants,the percentages by weight of components A) to D) together giving 100%.
    Type: Grant
    Filed: February 6, 1995
    Date of Patent: November 18, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Herbert Fisch, Gunter Pipper, Klaus Muhlbach, Heiner Gorrissen
  • Patent number: 5686556
    Abstract: Process for producing .alpha.-amino .omega.-ester monoamides such as H.sub.2 N--(CH.sub.2).sub.6 --NH--CO--(CH.sub.2).sub.4 --CO--OCH.sub.3 by reacting a diacid with a diamide at a diamine/diester molar ratio of 0.8 and 1.2 is provided. Additionally, a novel process for producing a polyamide by homopolymerization of an .alpha.-amino .omega.-ester monoamide is provided.
    Type: Grant
    Filed: September 14, 1995
    Date of Patent: November 11, 1997
    Assignee: Rhone-Poulenc Chimie
    Inventors: Frederic Jouffret, Pierre-Jean Madec
  • Patent number: 5674973
    Abstract: A process for the continuous production of polyamides from a mixture of at least one lactam and water and, if required, other monomer units and/or conventional additives and fillers under polyamide-forming conditions, where the mixture of the starting materials is heated in liquid phase in a first reaction zone until a conversion of at least 70% is reached, and undergoes adiabatic decompression and further polymerization in another reaction zone, wherein, in the first reaction zone, 0.5-7% by weight of water are employed, the temperature is increased to the range from 220.degree. to 310.degree. C., and polymerization is carried out until a conversion of at least 85% is reached and, in the second reaction zone, after the decompression further polymerization is carried out in the range from 215.degree. to 300.degree. C. without heat input.
    Type: Grant
    Filed: December 28, 1995
    Date of Patent: October 7, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Gunter Pipper, Andreas Kleinke, Peter Hildenbrand
  • Patent number: 5668248
    Abstract: A photosensitive resin composition comprising, as its main ingredient, a poly(amic acid) resin constituted of a diamino compound represented by formula: ##STR1## and optionally used other diamino compound and a tetracarboxylic acid dianhydride as its constituent monomers and/or a poly(amic acid) ester resin obtained by esterifying said poly(amic acid) resin and/or a polyimide resin obtained by a dehydrating or alcohol-eliminating ring-closure reaction of said poly(amic acid) resin or poly(amic acid) ester resin has an excellent developability and a high film strength and can form a relief patter of low thermal expansion.
    Type: Grant
    Filed: August 22, 1995
    Date of Patent: September 16, 1997
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Hideo Hagiwara, Makoto Kaji, Hiroshi Nishizawa, Kenji Suzuki, Yasunori Kojima
  • Patent number: 5668246
    Abstract: Disclosed is an improvement in a method of making a water-soluble epichlorohydrin resin involving reacting epichlorohydrin with a polyaminoamide. The improvement involves preparing the polyaminoamide in the presence of an acid catalyst (low temperature condensation) followed by reaction with epichlorohydrin.
    Type: Grant
    Filed: August 9, 1996
    Date of Patent: September 16, 1997
    Assignee: Hercules Incorporated
    Inventor: William W. Maslanka
  • Patent number: 5665854
    Abstract: A low temperature process for polymerizing nylon monomers to freely flowing polymers is disclosed. The polymerization process is carried out at lower than conventional polymerization temperatures and produces a freely flowing polymer without thermal degradation.
    Type: Grant
    Filed: March 24, 1995
    Date of Patent: September 9, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Leonard Edward Raymond Kosinski, Richard Robert Soelch
  • Patent number: 5659009
    Abstract: In a process for producing filler-containing thermoplastic molding compositions by mixing fillers with thermoplastics in the melt,a) the fillers are mixed in a mixing apparatus in the melt with a low molecular weight thermoplastic having a melt viscosity of at most 30 Pas (measured at 20.degree. C. above the melting point of the thermoplastic compound and at a shear gradient of 1,000 s.sup.-1),b) the product thus obtained is removed from the mixing apparatus, cooled and comminuted, andc) the comminuted product is then subjected in the solid phase to a post-condensation.
    Type: Grant
    Filed: November 17, 1995
    Date of Patent: August 19, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Gunter Pipper, Walter Goetz, Claus Cordes, Josef Georg Floss, Guenter Mattern, Peter Hildenbrand, James Hurley, Karl Schlichting, Graham Edmund McKee, Gerd Blinne
  • Patent number: 5659007
    Abstract: A process for producing an aromatic polyamide film comprising forming a thin layer of an optically isotropic dope in which an aromatic polyamide is dissolved in a polar amide, immersing the thin layer dope in a polar solvent kept at a temperature not higher than -20.degree. C. to coagulate the dope to form a film and drying the film in the presence of an isocyanate compound. Said process can produce directly a transparent film from an aromatic polyamide dope without requiring the step of dissolving the aromatic polyamide in conc. sulfuric acid, does not require any acid resistant equipment and is inexpensive.
    Type: Grant
    Filed: July 26, 1995
    Date of Patent: August 19, 1997
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kazunori Akiyoshi, Katsuhiko Iwasaki, Masahiro Niwano, Yoshitaka Ohbe
  • Patent number: 5650482
    Abstract: An at least two-step process for the preparation of polyamide resins wherein, in the first step, polyvalent carboxylic acids, optionally together with monovalent carboxylic acids, are reacted with a stoichiometric deficiency of polyamines in the presence of an organic solvent which forms an azeotrope with water, water is distilled off, and the reaction is controlled by means of the amount of water formed by the condensation reaction and, optionally, by the imidazoline formation. After removal of the theoretical amount of water or a lesser amount, in a further step more amine is added to the reaction mixture in an amount sufficient to achieve a final amine number of 10 to 300 mgKOH/g, the reaction is continued, substantially all of the residual water is removed, and the residual solvent is completely or partially removed.
    Type: Grant
    Filed: September 27, 1995
    Date of Patent: July 22, 1997
    Assignee: Air Products and Chemicals, Inc.
    Inventor: William Rene Eduard Raymond
  • Patent number: 5644021
    Abstract: Disclosed is an improvement in a method of making a water-soluble epichlorohydrin resin involving reacting epichlorohydrin with a polyaminoamide. The improvement involves preparing the polyaminoamide in the presence of an acid catalyst (low temperature condensation) followed by reaction with epichlorohydrin.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: July 1, 1997
    Assignee: Hercules Incorporated
    Inventor: William Ivalter Maslanka
  • Patent number: 5627257
    Abstract: Process for synthesis of spinnable polyamide from .alpha., .omega.-alkyldinitriles and .alpha., .omega.-alkyldiamines and excess water, where a) the aqueous solution of the dinitrile is mixed with a catalytic amount of at least one oxygen-containing acid of phosphorus and/or a water-soluble salt of calcium, zinc, cadmium or manganese in the absence of the diamine, and the pH of this solution is adjusted to an initial value in the range of 2.0 to 4.0 before hydrolysis by adding a saturated aliphatic or aromatic dicarboxylic acid and the dinitrile is and the amide-containing precursors derived therefrom are hydrolyzed to dicarboxylic acid at an elevated temperature under autogenous pressure, whereby the hydrolysis is controlled by conductometric determination of the hydrolysate, and b) at least an equimolar amount of diamine is added to the solution from step a) and the mixture is subjected to polycondensation to form polyamide [nylon].
    Type: Grant
    Filed: February 12, 1996
    Date of Patent: May 6, 1997
    Assignee: Zimmer Aktiengesellschaft
    Inventor: Hartmut Liehr
  • Patent number: 5612384
    Abstract: Disclosed are methods of producing super absorbing polymeric networks of polyaspartates from crosslinked polysuccinimide. In one preferred method aspect, polysuccinimide is first reacted with an organic crosslinking agent, preferably an organic base containing at least two primary amine groups to form crosslinked polysuccinimide. The crosslinked polysuccinimide is then hydrolyzed to a polymeric network of polyaspartate which demonstrates super absorbing capability in water and in saline solution. Alternative method aspects are disclosed in which super absorbing polymeric networks of polyaspartates are produced in a single reaction vessel by sequentially crosslinking polysuccinimide with organic crosslinking agent in an aqueous reaction mixture and then hydrolyzing the reaction product to produce a polymeric network of polyaspartate.
    Type: Grant
    Filed: September 13, 1994
    Date of Patent: March 18, 1997
    Assignee: Donlar Corporation
    Inventors: Robert J. Ross, Kim C. Low, Larry P. Koskan, Alfred P. Wheeler
  • Patent number: 5597888
    Abstract: The invention relates to a process for the production of high molecular weight polyamide 6 (polycaprolactam).
    Type: Grant
    Filed: June 9, 1995
    Date of Patent: January 28, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Werner Nielinger, Andreas Gittinger, Edgar Ostlinning, Karsten-Josef Idel, Helmut Schulte
  • Patent number: 5585429
    Abstract: Polyphthalamide formulations containing from 0.1 to about 2 wt % alkali metal halide have a significantly reduced melt viscosity and both filled and untilled resin formulations containing the requisite amount of alkali metal halide are more readily processed by thermal means. When stabilized with a copper-containing stabilizer and, optionally, a polyolefin synergist the formulations exhibit substantially improved dry heat stability and are particularly useful in the production of thermally-stabilized melt spun polyphthalamide fiber for applications where extended exposure to elevated temperatures in air is contemplated.
    Type: Grant
    Filed: March 27, 1995
    Date of Patent: December 17, 1996
    Assignee: Amoco Corporation
    Inventor: Mark G. Reichmann
  • Patent number: 5582911
    Abstract: An aramid monofilament having high mechanical properties is provided. This monofilament has a slightly structured skin and resists fibrillation and abrasion. In addition, a process for the production of this monofilament is also provided. The process includes the following steps:(i) a solution of aromatic polyamide(s) is extruded as a liquid jet in a spinneret through a capillary; (ii) the jet is drawn from the capillary in a non-coagulating layer of fluid and (iii) the drawn liquid vein is introduced into a coagulating medium in order to form the monofilament, which is subsequently washed, dried and contacted with a solvent for said monofilament to produce the slightly structured skin. The aramid monofilament is characterized by the following relationships:1.7.ltoreq.Ti.ltoreq.260;40.ltoreq.D.ltoreq.480;T.gtoreq.180-D/3;Mi.gtoreq.1600;Ar>2.00; andEr>20-D/30.In the above relationship, Ti represents linear density in tex, D represents diameter in .mu.
    Type: Grant
    Filed: August 19, 1994
    Date of Patent: December 10, 1996
    Assignee: Michelin Recherche et. Technique, S.A.
    Inventors: Jean-Paul Meraldi, Joel Ribiere, Jean-Jacques Almon
  • Patent number: 5574128
    Abstract: Polyetheresteramides, characterized in that they comprise both of the following repeating entities: ##STR1## in which X represents the residue of a polyamide-diacid oligomer with an Mn of between 300 and 8000, Y represents the residue of a polyetherdiol with an Mn of between 200 and 5000, and Z represents the residue of a polyetherdiamine with an Mn of between 200 and 5000, wherein the proportion by mass of the entities Z resulting from the condensation of the polyetherdiamine with respect to the total amount of the entities resulting from the polyetherdiol and polyetherdiamine, i.e. Z/(Z+Y), is between 1 and 50%. The polyetheresteramides according to the invention can be used as is and are suitable for the production of mouldings, extrudates, films, sheaths, or composite materials such as multi-layer film. They can also be mixed with other polymers and in particular with polyamides.
    Type: Grant
    Filed: August 10, 1994
    Date of Patent: November 12, 1996
    Assignee: Elf Atochem S.A.
    Inventors: Didier Judas, Jean-Marc Sage
  • Patent number: 5554722
    Abstract: Aromatic polyamide compositions with improved electrostatic properties, formed structures produced therefrom, and use and production thereof.Described are compositions comprising an aromatic polyamide which is soluble in organic solvents and from 0.01 to 30% by weight, based on the weight of the composition, of an organic or organometallic charge control agent.The compositions can be used for producing formed structures, in particular fibers; these fibers are preferably used for producing webs which can be used for producing dust filters.
    Type: Grant
    Filed: August 15, 1994
    Date of Patent: September 10, 1996
    Assignee: Hoechst AG
    Inventors: Dieter Eichenauer, Werner Groh, Hans-Tobias Macholdt, Jorg Dahringer, Holger Jung, Richard Neuert
  • Patent number: 5550208
    Abstract: A process for preparing condensation polymers comprises forming a dispersion of a reaction mixture in a continuous vapor phase, maintaining the dispersion while passing it through a reaction zone, heating the dispersion in the reaction zone to polymerize reactants in the reaction mixture and form a polycondensate.
    Type: Grant
    Filed: February 10, 1995
    Date of Patent: August 27, 1996
    Assignee: Amoco Corporation
    Inventors: Joel A. Richardson, Wassily Poppe, Benjamin A. Bolton, Edward E. Paschke
  • Patent number: 5548031
    Abstract: A process for producing a copolymer having succinimide units represented by general formula (I) is provided which comprises reaction of a copolymer constituted of 40-60 mole % of maleic anhydride units, 60-40 mole % of olefin units, and 0-20 mole % of another copolymerizable monomer units with an amine to convert the maleic anhydride units to the succinimide units, wherein the succinimide units are formed by ring-closing imidation in a slurry state in a poor solvent: ##STR1## where R.sub.1 is a hydrogen atom, or an alkyl or cycloalkyl group of 1 to 6 carbons. The copolymer has low yellowness and high transparency.
    Type: Grant
    Filed: November 14, 1994
    Date of Patent: August 20, 1996
    Assignee: Tosoh Corporation
    Inventor: Toru Doi
  • Patent number: 5545833
    Abstract: A polymer including as integral parts of polymer chain, amide groups of the formula ##STR1## and phosphinic acid-salt groups of the formula ##STR2## wherein a and b are both greater than or equal to 2 and M is selected from the group of metal cations where n=1 or n=2.The polymer of the present invention is particularly useful in forming stain-resistant fibers for carpet pile.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: August 13, 1996
    Assignee: Monsanto Company
    Inventor: John W. Stoddard
  • Patent number: 5539079
    Abstract: Disclosed is a process for preparing nylon by adding an amidation catalyst concentrated in "masterbatches" to the process melt resulting in a product with increased molecular weight and viscosity.
    Type: Grant
    Filed: February 14, 1995
    Date of Patent: July 23, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Gregory D. Cramer, Ramdas Dujari, Robert C. Wheland
  • Patent number: 5534614
    Abstract: A polyamide precursor of a polybenzazole polymer is prepared by reacting an aromatic bis(alkenyl)ester with a ring forming, aromatic diamine. The precursor can be prepared in an organic solvent for the monomers to form a soluble polyamide precursor which can be subsequently cyclocondensed to form a PBX polymer. A polybenzoxazole precursor is prepared by the reaction of a bis(alkenyl)ester and a bis(ortho-hydroxyamine). A polybenzazole polymer is easily prepared by heating the polyamide, PBX precursor.
    Type: Grant
    Filed: March 28, 1994
    Date of Patent: July 9, 1996
    Assignee: The Dow Chemical Company
    Inventors: James J. O'Briem, Edmund P. Woo
  • Patent number: 5523383
    Abstract: A process for the preparation of a photocurable resin which comprises the steps of(I) (a) imidating 20 to 80 mole % of the acid arthydride groups present in an adduct prepared by the addition reaction of an .alpha.,.beta.-unsaturated dicarboxylic acid arthydride to a conjugated diene polymer or copolymer with a primary amine to produce water and an amide,(b) reacting the thus formed water as a by-product with at least a part of the remaining acid arthydride groups in said adduct to produce the succinic acid groups by opening the ring of said acid arthydride groups,(II) dehydrating the thus produced succinic acid groups by heating to cause ring closure again thereby forming acid anhydride groups and(III) reacting at least a part, preferably at least 50 mole %, of the acid anhydride rings present in the polymer with an .alpha.,.beta.-unsaturated monocarboxylic acid ester having an alcoholic hydroxyl group to conduct a half-esterification by opening the ring of said acid arthydride groups.
    Type: Grant
    Filed: May 11, 1994
    Date of Patent: June 4, 1996
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Nobuo Ikeda, Teruhisa Kuroki, Tatsuo Yamaguchi, Hiroyoshi Oomiya
  • Patent number: 5519109
    Abstract: Moisture-curing polyamides containing reactive alkoxysilane groups and a process for their preparation are provided. The reactive alkoxysilane groups contain organic groups which are not reactive during the production process, the intended application or the curing process. These moisture-curing polyamides have low melt viscosities and are useful as sealing compounds, hotmelt adhesives and encapsulating materials.
    Type: Grant
    Filed: January 17, 1995
    Date of Patent: May 21, 1996
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Hans-Georg Kinzelmann, Reimar Heucher, Juergen Wichelhaus
  • Patent number: 5516882
    Abstract: A process for the preparation of a copolyamide involving copolymerization of (1) a carboxylic acid of terephthalic acid or a terephthalic acid/isophthalic acid mixture with (2) a mixture of hexamethylene diamine and 2-methyl pentamethylene diamine. The combined amount of isophthalic acid and 2-methyl pentamethylene diamine is controlled so that the resultant copolyamide exhibits few, if any, high melting fractions.
    Type: Grant
    Filed: September 6, 1994
    Date of Patent: May 14, 1996
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Richard R. Soelch
  • Patent number: 5506336
    Abstract: The present invention relates to an apparatus for processing materials, a process for mixing, finishing and de-volatizing polyamide to make 66 nylon and the 66 nylon made by this process. The apparatus comprises an agitator section having an outlet adjacent the bottom thereof; a transfer screw disposed adjacent the outlet of the agitator section; a spiral ribbon extending upwardly from the transfer screw; a ring disposed vertically above the spiral ribbon, at least one baffle disposed vertically above the spiral ribbon and connected to the ring and a wall-wiping spur connected to the ring. Preferably, the apparatus has two baffles--an upper one for pumping the material downwardly and a lower one for pumping the material upwardly. The diameter of each baffle is preferably about 80% of the diameter of the agitator section.
    Type: Grant
    Filed: November 30, 1994
    Date of Patent: April 9, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: John M. Iwasyk
  • Patent number: 5504182
    Abstract: Thermoplastically processable aromatic polyether amideThermoplastically processable aromatic polyether amide of the formula (I) ##STR1## in which the symbols Ar, Ar', Ar.sub.1, Ar.sub.2, R, R', Y, x, y and z have the following meanings:Ar is a divalent, substituted or unsubstituted, aromatic or heteroaromatic radical or a group--Ar*--Q--Ar*--in whichQ is a bond or an --O--, --C(CH.sub.3).sub.2, --CO--, --S--, --SO-- or --SO.sub.2 -- bridge and Ar* is an aromatic radical. The carbonyl groups of the Ar radical are on non-adjacent ring carbon atoms.A is up to three different radicals.Ar' has the meaning given for Ar or is an Ar--Z--Ar group.In this case, Z is a --C(CH.sub.3).sub.2 -- or --O--Ar*--O--bridge.Y is a --C(CH.sub.3).sub.2 --, --SO.sub.2 --, --S-- or a --C(CF.sub.3).sub.2 --bridge and has up to two different meanings in the same polymer.Ar.sub.1 and Ar.sub.2 are identical or different from one another and are each a substituted or unsubstituted para- or meta-arylene radical.
    Type: Grant
    Filed: April 30, 1993
    Date of Patent: April 2, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Harald Cherdron, Willi Kreuder, Arnold Schneller, Otto Herrmann-Schonherr
  • Patent number: 5504184
    Abstract: Xanthene polyesters and polyamides are provided resulting from the reaction of alkylene, cycloaliphatic or aromatic diols or organo diamines with xanthene dicarboxylic esters or xanthene dicarboxylic acid halides. These amorphous, or crystalline film forming, high performance thermoplastics which are useful in automotive applications, and include copolymers and blends of such xanthene polymers.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: April 2, 1996
    Assignee: General Electric Company
    Inventors: Andrew J. Caruso, Julia L. Lee