Polymerizing In The Presence Of A Specified Material Other Than A Reactant Patents (Class 528/368)
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Patent number: 9492789Abstract: A draw solute for forward osmosis may include a temperature-sensitive oligomer compound including a structural unit including a temperature-sensitive moiety. The temperature-sensitive oligomer compound may further include a hydrophilic functional group at the terminal end of the main chain.Type: GrantFiled: June 5, 2012Date of Patent: November 15, 2016Assignee: Samsung Electronics Co., Ltd.Inventors: Jae Eun Kim, Bo Kyung Jung, Sung Soo Han
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Patent number: 9074050Abstract: The present invention relates to a continuous process for the production of polymeric coupling products by using a reactor assembly which is equipped with two or more reaction cells. The educt fluid is pumped through the reaction cells and thoroughly mixed therein by means of agitators. Preferably the process according to the invention is used for the preparation of coupling products which show at least partially precipitation and/or gelation effects during the performance of the synthesis. The precipitation and/or gelation effects are associated with and increase of the viscosity of the reaction system under reaction conditions. The products which are obtained by the process according to the invention have increased molecular weight and low polydispersity over similar products which were obtained in batch experiments.Type: GrantFiled: May 29, 2012Date of Patent: July 7, 2015Assignee: BASF SEInventors: Matthias Kleiner, Martin Elbs, Marcel Kastler
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Publication number: 20140332730Abstract: The present invention relates to polymers (I), or (II), and their use as organic semiconductor in organic devices, especially in organic photovoltaics (solar cells) and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors, organic photovoltaics (solar cells) and photodiodes.Type: ApplicationFiled: December 3, 2012Publication date: November 13, 2014Applicant: BASF SEInventors: Pascal Hayoz, Patrice Bujard
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Patent number: 8778597Abstract: A curable composition that maintains good handleability in the liquid form and that can be photo- or heat-cured to form a cured product having physical properties including both high transparency and high flexural strength. A curable composition includes, an epoxy compound of (1): [where each of E1, E2, and E3 is independently an organic group of Formula (2) or Formula (3); and each of R1, R2, and R3 is independently an optionally branched alkylene group or oxyalkylene group: (where R4 is a hydrogen atom or a methyl group)]; and an acid generator.Type: GrantFiled: January 24, 2011Date of Patent: July 15, 2014Assignee: Nissan Chemical Industries, Ltd.Inventors: Toshiaki Takeyama, Yuki Endo, Takeo Moro, Kentaro Ohmori
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Publication number: 20140080994Abstract: The present invention relates to a continuous process for the production of polymeric coupling products by using a reactor assembly which is equipped with two or more reaction cells. The educt fluid is pumped through the reaction cells and thoroughly mixed therein by means of agitators. Preferably the process according to the invention is used for the preparation of coupling products which show at least partially precipitation and/or gelation effects during the performance of the synthesis. The precipitation and/or gelation effects are associated with and increase of the viscosity of the reaction system under reaction conditions. The products which are obtained by the process according to the invention have increased molecular weight and low polydispersity over similar products which were obtained in batch experiments.Type: ApplicationFiled: May 29, 2012Publication date: March 20, 2014Applicant: BASF SEInventors: Matthias Kleiner, Martin Elbs, Marcel Kastler
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Patent number: 8586063Abstract: Disclosed are compounds obtained by reacting (a) epoxides (I) which comprise at least two epoxide groups per molecule, with (b) compounds of the structure (II), having substituents as defined, and (c) optionally, alcohols (III) of the formula R4—OH, wherein R4 is C6-C22 alkyl, with the proviso that the molar ratio of the reactants (I):(II):(III) is in the range from 1:(1 to 3):(0.05 to 1.95). These compounds are useful as thickeners, and may be prepared as thickener concentrates.Type: GrantFiled: October 1, 2010Date of Patent: November 19, 2013Assignee: Cognis IP Management GmbHInventors: Cindy Münzenberg, Helena Wiethoff
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Patent number: 8362171Abstract: Norbornene monomers with epoxy groups and polymer materials thereof are disclosed. The Norbornene monomers with epoxy groups are prepared by Diels-Alder reaction. The Norbornene monomers with epoxy groups are highly active for ring-opening-metathesis polymerization (ROMP), and the molecular weight and PDI value of the obtained polymers are controllable.Type: GrantFiled: October 5, 2007Date of Patent: January 29, 2013Assignee: National Taiwan University of Science & TechnologyInventors: Der-Jang Liaw, Ching-Cheng Huang
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Publication number: 20120295199Abstract: A curable composition that maintains good handleability in the liquid form and that can be photo- or heat-cured to form a cured product having physical properties including both high transparency and high flexural strength. A curable composition includes, an epoxy compound of (1): [where each of E1, E2, and E3 is independently an organic group of Formula (2) or Formula (3); and each of R1, R2, and R3 is independently an optionally branched alkylene group or oxyalkylene group: (where R4 is a hydrogen atom or a methyl group)]; and an acid generator.Type: ApplicationFiled: January 24, 2011Publication date: November 22, 2012Applicant: NISSAN CHEMICAL INDUSTRIES, LTD.Inventors: Toshiaki Takeyama, Yuki Endo, Takeo Moro, Kentaro Ohmori
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Patent number: 8252864Abstract: An aqueous reaction product of a composition that may consist essentially of a source of an acid having a pKa in water of about 2 to about 8, a source of a base having a pKb in water of about 2 to about 6, and urea. A curable urea/formaldehyde resin composition may contain a curable urea/formaldehyde resin and the foregoing composition, and may be made by combining the resin with the composition. A reconstituted wood product may be made by combining particulate lignocellulosic material with the foregoing curable resin, and curing the resin. Optionally, a reconstituted wood panel may contain a particulate lignocellulosic material and a binder composition comprising the cured product of curable resin and the aforesaid aqueous reaction product. A concentrate for forming a polymerization enhancing composition is also disclosed.Type: GrantFiled: July 29, 2005Date of Patent: August 28, 2012Assignee: Momentive Specialty Chemicals Inc.Inventors: William K. Motter, David M. Harmon
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Patent number: 8247614Abstract: Fluorinated copolymers are prepared via copolycondensation polymerization in a process comprising reacting A) a telechelic fluoroazido compound of formula N3(Y)p—(CH2)n—R—(CH2)m—(Y)pN3, wherein Y is SO, SO2, C6H4, or CO, p=0 or 1, n and m are independently 1 to 4, and R is selected from the group consisting of i) a C3-C10 fluoroalkylene group, ii) a C3-C10 fluoroalkoxylene group, iii) a substituted aryl group, iv) an oligomer comprising copolymerized units of vinylidene fluoride and perfluoro(methyl vinyl ether), v) an oligomer comprising copolymerized units of vinylidene fluoride and hexafluoropropylene, vi) an oligomer comprising copolymerized units of tetrafluoroethylene and perfluoro(methyl vinyl ether), and vii) an oligomer comprising copolymerized units of tetrafluoroethylene and a hydrocarbon olefin with B) a telechelic diyne or dinitrile compound in the presence of copper halide catalyst.Type: GrantFiled: June 17, 2009Date of Patent: August 21, 2012Assignees: E I du Pont de Nemours and CompanyInventors: Ming-Hong Hung, Bruno Ameduri, Bernard Boutevin, Aurelien Soules
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Publication number: 20120148670Abstract: A polymer capsule manufactured by polymerizing a compound represented by Formula 1, or polymerizing the compound of Formula 1 and a compound of Formula 2, wherein a detailed structure of the compounds of Formulae 1 and 2 is presented in the detailed description.Type: ApplicationFiled: August 11, 2010Publication date: June 14, 2012Applicant: POSTECH ACADEMAY-INDUSTRY FOUNDATIONInventors: Ki moon Kim, Jiyeong Lee, Dongwoo Kim, Eunju Kim, Hyuntae Jung
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Publication number: 20120065361Abstract: The invention provides a production process of a poly(arylene sulfide), comprising a polymerization step of subjecting at least one sulfur source selected from the group consisting of alkali metal sulfides and alkali metal hydrosulfides and a dihalo-aromatic compound to a polymerization reaction in an organic amide solvent; a reaction step of adding a hydroxyl group-containing organic compound containing no bonded halogen atom in a proportion of 0.001 to 20 mol per 100 mol of the charged sulfur source into the polymerization reaction system containing the organic amide solvent and a formed polymer after the polymerization step to cause the formed polymer to react with the hydroxyl group-containing organic compound; and a collecting step of collecting a polymer from the polymerization reaction system after the reaction step, and the poly(arylene sulfide).Type: ApplicationFiled: May 11, 2010Publication date: March 15, 2012Applicant: KUREHA CORPORATIONInventors: Akihiro Konno, Hiroshi Sakabe, Ken-ichi Takaki
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Patent number: 8034873Abstract: In-situ plasticized thermoplastic polyurethane (TPU) compositions are made by a process which involves reacting a polyol, glycol chain extender and a polyisocyanate where the reaction is conducted in the presence of a plasticizer. The reactants together with the plasticizer are added to a reaction extruder and reacted to form the in-situ plasticized TPU.Type: GrantFiled: December 5, 2006Date of Patent: October 11, 2011Assignee: Lubrizol Advanced Materials, Inc.Inventor: Sridhar K. Siddhamalli
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Patent number: 7999060Abstract: A tailorable polyimide prepolymer blend comprising an end group component, a dianhydride component, and a diamine component. The dianhydride component includes at least 3,4,3?,4?-benzophenonetetracarboxylic dianhydride (BTDA), derivatives thereof, or combinations thereof, and 3,4,3?,4?-biphenyltetracarboxylic dianhydride (BPDA), derivatives thereof, or combinations thereof. The diamine component includes at least 1,3-phenylenediamine (mPDA), derivatives thereof, or combinations thereof; 1,4-phenylenediamine (pPDA), derivatives thereof, or combinations thereof; bis amino phenoxy benzene (APB), derivatives thereof, and combinations thereof; and optionally, 4,4?-(1,3-phenylene-bis(1-methylethylidene)bisaniline (Bis-M), derivatives thereof, and combinations thereof. A cured polyimide matrix has a glass transition temperature of at least about 450° F. (232° C.).Type: GrantFiled: October 30, 2007Date of Patent: August 16, 2011Assignee: General Electric CompanyInventors: Warren Ronk, Lisa Shafer
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Patent number: 7781521Abstract: This invention provides methods for producing furfural-urea resins and adhesives. The includes dissolving urea in hot water to produce a hot aqueous solution, mixing furfural with the aqueous solution, adding an acid catalyst such as maleic anhydride to the furfural containing aqueous solution upon which a resinification reaction begins immediately. The resinification reaction is quenched by cooling to a pre-selected temperature to produce a resin or adhesive.Type: GrantFiled: June 29, 2007Date of Patent: August 24, 2010Assignee: Infinity Wood Ltd.Inventors: Marc Henry Schneider, Jonathan Greer Phillips
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Patent number: 7750062Abstract: A method of producing a polymeric material including subjecting a starting material to conditions under which polymerisation occurs. The starting material includes a group of sub-formula (XIII) where R16 is selected from hydrogen, halo, nitro, hydrocarbyl, optionally substituted or interposed with functional groups, or R2 and R3 are independently selected from (CR6R7)n or a group CR8R9, CR6R7CR8R9 or CR8R9CR6R7 where n is 0, 1 or 2 and R6 and R7 are independently selected from hydrogen or alkyl, and either one of R8 or R9 is hydrogen and the other is an electron withdrawing group, or R8 or R9 together form an electron withdrawing group. R4 and R5 are independently selected from CH or CR1o where CR1o is an electron withdrawing group, X1 is a group CX2X3, Y1 is a group CY2Y3, and X2 X3, and, if present, Y2 and Y3, are each a C1 to C4 alkyl group.Type: GrantFiled: December 23, 2008Date of Patent: July 6, 2010Assignee: Novel Polymer Solutions LimitedInventors: James Rolfe, Warrick Allen
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Publication number: 20100168377Abstract: Catalytic processes have been developed for direct chemical conversion of amides to methyl ether polymers or methyl ether ladder polymers. Amides formed by reacting acetic acid with monoethanol amine (MEA) or acetic acid with butylamine were polymerized in the presence of transition metal catalysts in air to form linear polymers. Ethanol acetamide was catalytically converted to a linear polyether as characterized by FTIR spectra. The catalysts were based on molecular strings of mono-, di- or tri-valent transition metal compounds that opened the amide carbonyl double bond to produce linear polyethers. Laboratory results have demonstrated [cobalt(II)]2, [manganese(II)]2, cobalt(II)-manganese(II), [nickel(II)]2 and related families of catalysts to be effective for formation of methyl ether polymers by this process.Type: ApplicationFiled: December 29, 2008Publication date: July 1, 2010Applicant: Carter TechnologiesInventor: Melvin Keith Carter
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Patent number: 7732559Abstract: A method of preparing a halophthalic acid is disclosed which comprises the steps of contacting in a liquid phase reaction mixture at least one halogen-substituted ortho-xylene with oxygen and acetic acid at a temperature in a range between about 120° C. and about 220° C. in the presence of a catalyst system yielding a product mixture comprising less than 10 percent halogen-substituted ortho-xylene starting material, a halophthalic acid product, and less than about 10,000 ppm halobenzoic acid and less than about 1000 ppm halophthalide by-products based on a total amount of halophthalic acid present in the product mixture. In addition methods for the preparation of halophthalic anhydride, and recovery of high purity acetic acid from an aqueous acetic acid stream comprising HCl, which is generated during the preparation of the halophthalic acid are also disclosed.Type: GrantFiled: July 18, 2008Date of Patent: June 8, 2010Assignee: Sabic Innovative Plastics IP B.V.Inventors: Robert Edgar Colborn, David Bruce Hall, Peter Alois Koch, Bernd Volker Demuth, Thomas Wessel, Karl Ernst Mack, Prashant Anil Tatake, Uptal Mahendra Vakil, Shyamal Bhaskar Gondkar, John Edward Pace, Kwang Woong Won
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Patent number: 7728101Abstract: The invention relates to an overcoat lacquer containing a) at least one binding agent containing alkyd resins made from tris-(2-hydroxylethyl)-isocyanurate, 2,6-naphthaline dicarboxylic acid, drying fatty acids, and, optionally, other components known from alkyd resin chemistry, b) at least one solvent or at least one technical solvent or mixture thereof based on hydrocarbon and c) at least one siccative or at least one mixture of siccatives or several anti-skin agents.Type: GrantFiled: January 24, 2005Date of Patent: June 1, 2010Assignee: Altana Electrical Insulation GmbHInventors: Klaus-Wilhelm Lienert, Gerold Schmidt, Sascha Tödter-König
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Patent number: 7700709Abstract: A derivative of a cytidine metabolic antagonist which can exert a high therapeutic effect at a low dose. A polymeric derivative of a cytidine metabolic antagonist which comprises a polymeric compound having a polyethylene glycol moiety and a polymer moiety having a carboxyl group in a side chain and a cytidine metabolic antagonist, which has such a structure that the carboxyl group in the side chain of the polymeric compound and an amino group in the cytidine metabolic antagonist are bound together to form an amide bond.Type: GrantFiled: April 27, 2006Date of Patent: April 20, 2010Assignee: Nippon Kayaku Kabushiki KaishaInventors: Akira Masuda, Takeshi Onda, Hiroko Mashiba, Keiichirou Yamamoto, Kazutoshi Takashio
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Patent number: 7678880Abstract: A molecular-oriented polymer gel and its cast film obtained by self-assembly of a self-organizable amphiphilic compound and a monomer interacting with the amphiphilic compound, and then polymerizing the monomer, and their production methods.Type: GrantFiled: August 7, 2003Date of Patent: March 16, 2010Assignees: Honda Giken Kogyo Kabushiki KaishaInventors: Nobuo Kimizuka, Kazuhiro Kagawa, Takuya Nakashima
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Poly(carbonate-co-urea) copolymers and melt transesterification method of preparing these copolymers
Patent number: 7666977Abstract: Disclosed herein is a process to prepare a poly(carbonate-co-urea) copolymer comprising reacting in the melt: (a) a dihydroxy reaction component comprising a dihydroxy compound, (b) a diaryl carbonate reaction component comprising a diaryl carbonate, (c) a urea reaction component comprising a urea compound in the presence of (d) a transesterification catalyst during at least part of the reaction and removing a phenolic byproduct to produce a poly(carbonate-co-urea) copolymer, wherein the urea and dihydroxy compounds are reacted in a molar ratio: (total moles of urea compound)/((total moles of urea compound)+(total moles of dihydroxy compound)) of less than or equal to 0.5.Type: GrantFiled: May 3, 2007Date of Patent: February 23, 2010Assignee: SABIC Innovative Plastics IP B.V.Inventors: Jan Henk Kamps, Edward Kung, Jan-Pleun Lens -
Publication number: 20090005504Abstract: This invention provides methods for producing furfural-urea resins and adhesives. The includes dissolving urea in hot water to produce a hot aqueous solution, mixing furfural with the aqueous solution, adding an acid catalyst such as maleic anhydride to the furfural containing aqueous solution upon which a resinification reaction begins immediately. The resinification reaction is quenched by cooling to a pre-selected temperature to produce a resin or adhesive.Type: ApplicationFiled: June 29, 2007Publication date: January 1, 2009Inventors: Marc Henry Schneider, Jonathan Greer Phillips
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Publication number: 20080319097Abstract: The present invention relates to polymer resins, methods for their generation and uses thereof. In one aspect the present invention is directed to a resin obtainable by aminolysis of a precursor resin, wherein the precursor resin is obtainable by polymerisation of i) polydisperse di- or oligofunctional vinyl or cyclic ether compounds and ii) aminolytically sensitive, mono-functional vinyl or cyclic ether compounds.Type: ApplicationFiled: August 26, 2005Publication date: December 25, 2008Applicant: Versamatrix A/SInventors: Ib Johannsen, Patrik Gavelin
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Publication number: 20080299391Abstract: A composition includes a plurality of capsules, and a polymerizer in the capsules. The capsules have an average outer diameter less than 10 micrometers. The capsules can be made by sonicating an emulsion to form a microemulsion, where the emulsion includes water, a surfactant, a first polymerizer and a second polymerizer, and then polymerizing the first polymerizer. The capsules may be present in a composite material that includes a polymer matrix and an activator.Type: ApplicationFiled: May 31, 2007Publication date: December 4, 2008Inventors: Scott R. White, Nancy R. Sottos, Benjamin J. Blaiszik
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Publication number: 20080275211Abstract: A method of preparing a halophthalic acid is disclosed which comprises the steps of contacting in a liquid phase reaction mixture at least one halogen-substituted ortho-xylene with oxygen and acetic acid at a temperature in a range between about 120° C. and about 220° C. in the presence of a catalyst system yielding a product mixture comprising less than 10 percent halogen-substituted ortho-xylene starting material, a halophthalic acid product, and less than about 10,000 ppm halobenzoic acid and less than about 1000 ppm halophthalide by-products based on a total amount of halophthalic acid present in the product mixture. In addition methods for the preparation of halophthalic anhydride, and recovery of high purity acetic acid from an aqueous acetic acid stream comprising HCl, which is generated during the preparation of the halophthalic acid are also disclosed.Type: ApplicationFiled: July 18, 2008Publication date: November 6, 2008Inventors: Robert Edgar Colborn, David Bruce Hall, Peter Alois Koch, Bernd Volker Demuth, Thomas Wessel, Karl Ernst Mack, Prashant Anil Tatake, Utpal Mahendra Vakil, Shyamal Bhaskar Gondkar, John Edward Pace, Kwang Woong Won
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POLY(CARBONATE-CO-UREA) COPOLYMERS AND MELT TRANSESTERIFICATION METHOD OF PREPARING THESE COPOLYMERS
Publication number: 20080275209Abstract: Disclosed herein is a process to prepare a poly(carbonate-co-urea) copolymer comprising reacting in the melt: (a) a dihydroxy reaction component comprising a dihydroxy compound, (b) a diaryl carbonate reaction component comprising a diaryl carbonate, (c) a urea reaction component comprising a urea compound in the presence of (d) a transesterification catalyst during at least part of the reaction and removing a phenolic byproduct to produce a poly(carbonate-co-urea) copolymer, wherein the urea and dihydroxy compounds are reacted in a molar ratio: (total moles of urea compound)/((total moles of urea compound)+(total moles of dihydroxy compound)) of less than or equal to 0.5.Type: ApplicationFiled: May 3, 2007Publication date: November 6, 2008Applicant: GENERAL ELECTRIC COMPANYInventors: Jan Henk Kamps, Edward Kung, Jan-Pleun Lens -
Publication number: 20080114148Abstract: A manufacturing method for polyimide resin containing a norbornene group is disclosed. Take Nadic anhydride to react with diamine compound to form dinorbornene polyimide. Then the dinorbornene polyimide reacts with diisocyanate compounds to produce polyimide resin containing a norbornene group. The polyimide resin containing a norbornene group has good adhesion and electrical properties and is applied to glass fiber, copper foil, coating agents, molding materials and adhesives for generating printed circuit boards by hot pressing.Type: ApplicationFiled: November 13, 2006Publication date: May 15, 2008Inventor: Shen Jason Chou
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Patent number: 7348395Abstract: A cyanate ester system is disclosed. An aryl ether oligomer may be made from a dihydroxyaromatic compound and a dihaloaromatic compound in the presence of a base. The oligomer is then reacted with a cyanide compound in the presence of a base to form the cyanate ester shown below. The cyanate ester may then be cross-linked to a thermoset having triazine ring cross-links.Type: GrantFiled: June 22, 2006Date of Patent: March 25, 2008Assignee: The United States of America as represented by the Secretary of the NavyInventors: Teddy M Keller, Matthew Laskoski
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Patent number: 7342085Abstract: A cyanate ester system is disclosed. An aryl ether oligomer may be made from a dihydroxyaromatic compound and a dihaloaromatic compound in the presence of a base. The oligomer is then reacted with a cyanide compound in the presence of a base to form the cyanate ester shown below. The cyanate ester may then be cross-linked to a thermoset having triazine ring cross-links HO—Ar2O—Ar1—O—Ar2nOH.Type: GrantFiled: June 22, 2006Date of Patent: March 11, 2008Assignee: The United States of America as represented by the Secretary of the NavyInventors: Teddy M Keller, Matthew Laskoski
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Publication number: 20080045690Abstract: A description is given of azetidine derivatives and methods for producing them, and of their use as a latent curing component for resins having functional groups which are reactive toward amino groups. The particular advantages of the curing component proposed in accordance with the invention, such as effective producibility, high environmental friendliness, and excellent storage stability of the resin/curing agent mixtures, make these azetidine derivatives outstandingly suitable for one-component, moisture-hardening polymer compositions, which are of special interest in particular for the production of (floor) coatings, sealants, and adhesives.Type: ApplicationFiled: December 2, 2004Publication date: February 21, 2008Inventors: Stefan Ingrisch, Alois Maier, Thomas Pfeuffer, Norbert Steidl, Andrea Gantner, Herbert Winkelmann
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Publication number: 20070265424Abstract: A polyimide prepolymer blend including a first prepolymer component comprising a first polyimide oligomer having the formula E1-[R1]n-E1 and a second prepolymer component selected from M1, a second polyimide oligomer having the formula E2-[R2]n-E2, and combinations thereof; where R1 and R2 independently comprise: where n is from about 1 to about 5, V is a tetravalent substituted or unsubstituted aromatic monocyclic or polycyclic linking structure, R is a substituted or unsubstituted divalent organic radical. E1 and E2 independently comprise crosslinkable functional groups. M1 comprises a mixture of monomeric compounds including a diamine component, a dianhydride component, and an end group component. The prepolymer blend, prior to cure, provides at least one predetermined prepolymer blend property; and when cured under suitable cure conditions, the prepolymer blend provides a crosslinked polyimide matrix having at least one predetermined crosslinked matrix property.Type: ApplicationFiled: June 4, 2007Publication date: November 15, 2007Inventors: Stephen Mark Whiteker, Warren Rosal Ronk
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Patent number: 7279505Abstract: The present invention provides a radiation-curable prepolymer. The radiation-curable prepolymer of the invention is prepared by reacting an isocyanate-capped polyurethane with an ethylenically unsaturated amine or an ethylenically unsaturated monohydroxy compound or a mixture thereof, wherein the isocyanate-capped polyurethane is a copolymerization production of: (a) at least one polyalkylene glycol; (b) at least one branching agent having at least three hydroxy groups; and (c) at least one di- or polyisocyanate. The radiation-curable prepolymer of the invention can find use in economically producing contact lenses which have durable, highly elastic soft contact lenses with desired physical properties. In addition, the present invention provides method for making a radiation-curable prepolymer of the invention and for making a medical device, preferably an ophthalmic device, more preferably a contact lens.Type: GrantFiled: October 5, 2005Date of Patent: October 9, 2007Assignee: Novartis AGInventors: John Christopher Phelan, Michael Hugh Quinn, Joshua Andrew Wallach
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Patent number: 7087707Abstract: A cyanate ester system is disclosed. An aryl ether oligomer may be made from a dihydroxyaromatic compound and a dihaloaromatic compound in the presence of a base. The oligomer is then reacted with a cyanide compound in the presence of a base to form the cyanate ester shown below. The cyanate ester may then be cross-linked to a thermoset having triazine ring cross-links.Type: GrantFiled: April 14, 2004Date of Patent: August 8, 2006Assignee: The United States of America as represented by the Secretary of the NavyInventors: Teddy M. Keller, Matt Laskoski
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Patent number: 7057001Abstract: A process for the production of compounds which contain at least one urea group and at least one silyl group. The process involves reacting a compound containing at least one amino group and a carbamate compound. The compounds produced by this process are useful as surface coating compositions, foams and adhesives.Type: GrantFiled: October 24, 2001Date of Patent: June 6, 2006Assignee: Henkel Kommanditgesellschaft auf Aktien (Henkel KGAA)Inventors: Thomas Bachon, Wilfried Huebner, Hermann Kluth, Wolfgang Klauck, Johann Klein
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Patent number: 7026429Abstract: The present invention relates to new hydrophilic polyurethane prepolymers and to their aqueous polyurethane-polyurea (PU) dispersions.Type: GrantFiled: December 17, 2003Date of Patent: April 11, 2006Assignee: Bayer AktiengesellschaftInventors: Rolf Gertzmann, Christoph Gürtler, Thorsten Rische, Thomas Münzmay
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Patent number: 6995192Abstract: The present invention provides a radiation-curable prepolymer. The radiation-curable prepolymer of the invention is prepared by reacting an isocyanate-capped polyurethane with an ethylenically unsaturated amine or an ethylenically unsaturated monohydroxy compound or a mixture thereof, wherein the isocyanate-capped polyurethane is a copolymerization production of: (a) at least one polyalkylene glycol; (b) at least one branching agent having at least three hydroxy groups; and (c) at least one di- or polyisocyanate. The radiation-curable prepolymer of the invention can find use in economically producing contact lenses which have durable, highly elastic soft contact lenses with desired physical properties. In addition, the present invention provides method for making a radiation-curable prepolymer of the invention and for making a medical device, preferably an ophthalmic device, more preferably a contact lens.Type: GrantFiled: August 13, 2003Date of Patent: February 7, 2006Assignee: Novartis AGInventors: John Christopher Phelan, Michael Hugh Quinn, Joshua Andrew Wallach
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Patent number: 6750312Abstract: A method for preparing a solid support material for carrying out a chemical reaction, said method comprising the following steps: (i) reacting an amino functionalised solid material with a carboxylic acid having at least two similarly protected amino groups to form amide bonds between them, (ii) removing protecting groups in a single step, (iii) optionally repeating steps (i) and (ii) one or more times using the product of the preceding step as the amino functionalised solid material, and (iv) connecting a linkage agent to at least some of the free NH2 groups of the product. The method increases the loading capacity of the solid support material. It is particularly useful in connection with peptide synthesis.Type: GrantFiled: March 26, 2002Date of Patent: June 15, 2004Assignee: Avecia LimitedInventors: Craig Stephen Harris, Donald Alfred Wellings, Francis Joseph Montgomery, Richard John Brown
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Patent number: 6663966Abstract: Dendrimer additives incorporated in thermoplastic resins (such as polycarbonate resins) are effective to alter the surface characteristics of the thermoplastic resin. Such compositions can be injection molded to produce articles in which the dendrimer additive is concentrated at the surface of the article to alter the properties of the resin. By selection of the type of dendrimer additive, the resulting characteristics of the molded article may be controlled.Type: GrantFiled: July 15, 2002Date of Patent: December 16, 2003Assignee: General Electric CompanyInventor: Vijay R. Mhetar
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Patent number: 6660376Abstract: The present invention relates to a hot melt moisture cure adhesive composition well suited for bonding porous substrates such as fabric, methods of adhesively bonding substrates and corresponding articles. The adhesive composition exhibits a combination of flexibility, high green strength, low molten viscosity and high heat resistance. In view of these properties, the adhesive is particularly amendable to hot melt adhesive application techniques wherein small individual discrete deposits of adhesive are applied to a substrate. The adhesive composition prepolymer is preferably the reaction product of at least one polyol, at least one polyisocyanate and at least one high molecular weight thermoplastic polyurethane lacking hard segments.Type: GrantFiled: June 6, 2000Date of Patent: December 9, 2003Assignee: H. B. Fuller Licensing & Financing Inc.Inventors: John M. Zimmel, William L. Bunnelle, Brendon J. Kryzer
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Patent number: 6497959Abstract: Dendrimer additives incorporated in thermoplastic resins (such as polycarbonate resins) are effective to alter the surface characteristics of the thermoplastic resin. Such compositions can be injection molded to produce articles in which the dendrimer additive is concentrated at the surface of the article to alter the properties of the resin. By selection of the type of dendrimer additive, the resulting characteristics of the molded article may be controlled.Type: GrantFiled: March 30, 2000Date of Patent: December 24, 2002Assignee: General Electric CompanyInventor: Vijay R. Mhetar
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Patent number: 6127515Abstract: This invention is directed to a functionalized amino resin of formula ##STR1## wherein S is a solid support; R is H or alkyl; A is ##STR2## Y is OH or OCOR.sup.1 ; and R.sup.1 is aliphatic or aromatic which is useful for the solid phase synthesis of amides, peptides and hydroxamic acids.Type: GrantFiled: May 21, 1999Date of Patent: October 3, 2000Assignee: Aventis Pharmaceuticals Products Inc.Inventors: Franco Manfre, Benoit J. Vanasse, Richard F. Labaudiniere, George C. Morton
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Patent number: 6127514Abstract: The present invention relates to one-component, thermoset compositions containinga) compounds containing modified hydrazide groups and corresponding to formula I ##STR1## wherein p2 R represents the residue obtained by removing the isocyanate groups from a monomeric polyisocyanate, a polyisocyanate adduct or an NCO prepolymer,X represents OR' or NHR' andR' represents a group which is inert to isocyanate groups under the conditions used to form the compound of formula I andn has a value of 2 to 6,b) compounds containing two or more epoxy groups andc) a basic catalyst.The present invention also relates to coatings, adhesives and sealants prepared from these thermoset compositions.Type: GrantFiled: November 23, 1998Date of Patent: October 3, 2000Assignees: Bayer Corporation, Bayer AktiengesellschaftInventors: Douglas A. Wicks, Sze-Ming Lee, Eberhard Koenig, Carol L. Kinney, Karen M. Henderson
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Patent number: 6071568Abstract: The invention provides composite color-plus-clear coatings having improved appearance, especially with respect to wrinkling, and to methods and compositions for providing such coatings. The method of the invention utilizes a second coating composition comprising (A) a film forming component comprising (a) a first component comprising a compound having appended thereto at least one carbamate or urea functional group, or a group convertible to a carbamate or urea group, and (b) a second component comprising a compound reactive with said carbamate or urea groups on component (a), (B) a cyclic anhydride, and (C) a catalyst.Type: GrantFiled: May 1, 1998Date of Patent: June 6, 2000Assignee: BASF CorporationInventors: Herbert L. Harmon, Timothy P. Kandow, Gregory G. Menovcik
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Patent number: 6063898Abstract: The first aspect of the invention provides a novel compound containing a reactive functional group represented by formula (1)R.sup.2 --O--CO--NH--CH.dbd.CH--R.sup.1 (1)wherein R.sup.1 represents a hydrogen atom, an aromatic hydrocarbon group, or a saturated or unsaturated aliphatic hydrocarbon group, R.sup.2 represents a formula comprising alicyclic functionality.The second aspect provides an active energy ray-curable unsaturated resin composition prepared by mixing a reaction product of the above-mentioned compound (1) with an unsaturated resin containing an acid group and with a diluent. The composition can be cured by active energy rays, and it can be used as an alkali developable and active energy ray-curable type resist resin composition.Type: GrantFiled: August 13, 1998Date of Patent: May 16, 2000Assignee: Daicel Chemical Industries, Ltd.Inventors: Takeshi Endo, Hiroto Miyake
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Patent number: 6054528Abstract: The present invention relates to aqueous compositions containinga) bis(1,3,4-oxadiazolin-5-ones) corresponding to formula (I) ##STR1## wherein R represents a single bond or a divalent aliphatic, araliphatic or aromatic radical having 1 to 18 carbon atoms andb) organic polyamines or polyamine blends having an average of more than 2 NH-- and/or NH.sub.2 -- groups.The present invention also relates to coatings, adhesives or sealants prepared from these aqueous compositions, in particular automotive clear coats.Type: GrantFiled: July 17, 1998Date of Patent: April 25, 2000Assignee: Bayer AktiengesellschaftInventors: Josef Pedain, Klaus Konig, Peter Heitkamper, Manfred Schonfelder
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Patent number: 6045872Abstract: The curable coating composition of the invention comprises a film forming component (A) and a wrinkle reducing catalyst (B) comprising a compound of the formula:M.sub.y (L).sub.xwherein M is a metal having an empty or full d orbital and wherein the pk.sub.a of the aqua ion of M is less than or equal to 12; L is a ligand wherein the pk.sub.a of the parent acid is .gtoreq.-10 and is .ltoreq.4; and x is an integer which is a multiple of the charge of M, y is an interger which is a multiple of the charge of L, x and y selected so that ML is charge balanced. Film forming component (A) has first component (a) with a compound having appended thereto at least one carbamate or urea functional group, or a group convertible to a carbamate or urea group, and a second component (b) with a compound reactive with said carbamate or urea groups on component (a).Type: GrantFiled: May 1, 1998Date of Patent: April 4, 2000Assignee: BASF CorporationInventors: Herbert L. Harmon, Donald H. Campbell, Rodney L. Briggs
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Patent number: 6037444Abstract: A process for the preparation of a compound or polymer having at least one functional group selected from hydroxyl, thiol, amino and carboxylic acid groups is characterized in that a compound or polymer (A) containing a group of formula (I), ##STR1## where Q represents O or S and X represents --O--, --S--, --NH-- or a direct bond, the group being linked to the remainder of the compound or polymer through a carbon atom, is reacted with a compound (B) containing at least two functional groups selected from hydroxyl, thiol, amino and carboxylic acid groups, one of which functional groups (II) reacts with the group of formula (I) and one of which functional groups (III) is substantially unreactive with the group of formula (I) under the conditions of reaction, so that the compound (B) becomes bonded to (A) through the reaction of groups (I) and (II) forming a compound or polymer containing unreacted functional groups (III).Type: GrantFiled: June 18, 1998Date of Patent: March 14, 2000Assignee: Courtaulds Coatings (Holdings) LimitedInventors: Steven Paul Rannard, Nicola Jane Davis
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Patent number: 5898062Abstract: Poly (organophosphazene) polymers bearing various ratios of a carboxylic acid containing sidegroup and an alkylamino, alkoxy, or alkoxy ether sidegroup are disclosed. These water-soluble macromolecules are cross-linked and allowed to absorb water to form hydrogels. Because of their anionic character and high water content, the polymeric hydrogels are useful for a wide variety of biomedical applications including controlled drug delivery (e.g. pH sensitive drug delivery), biocompatible coatings, and pH sensitive membranes.Type: GrantFiled: April 10, 1997Date of Patent: April 27, 1999Assignee: The Penn State Research FoundationInventors: Harry R. Allcock, Archel M. A. Ambrosio
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Patent number: 5859175Abstract: Process for the preparation of polyether-amide solutions, steam-sterilizable dialysis membranes obtainable using the polyether-amide solutions, and a process for the production of these membranes.Polycondensation of one or more dicarboxylic acid derivatives of the formula I ##STR1## with one or more aromatic diamines of the formula II ##STR2## and, if appropriate, m-phenylenediamine, in aprotic polar solvents is known.As a result of passing ammonia, in an amount sufficient to neutralize the HCl formed, into the polymer solution obtained after the end of the polycondensation and filtering off the ammonium chloride formed, it is possible to prepare neutral, salt-free and particularly storage-stable polyether-amide solutions which can be further processed to membranes without isolation of the polymer. The resulting membranes are steam-sterilizable, chemically and thermally stable and show efficiency data in the region of that of good high-flux dialysis membranes.Type: GrantFiled: December 20, 1996Date of Patent: January 12, 1999Assignee: Hoechst AktiengesellschaftInventors: Karsten Blatter, Reinhard Wagener, Carl Martin Bell, Hermann Josef Gohl