Polymerizing In The Presence Of A Specified Material Other Than A Reactant Patents (Class 528/368)
  • Patent number: 9492789
    Abstract: A draw solute for forward osmosis may include a temperature-sensitive oligomer compound including a structural unit including a temperature-sensitive moiety. The temperature-sensitive oligomer compound may further include a hydrophilic functional group at the terminal end of the main chain.
    Type: Grant
    Filed: June 5, 2012
    Date of Patent: November 15, 2016
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Jae Eun Kim, Bo Kyung Jung, Sung Soo Han
  • Patent number: 9074050
    Abstract: The present invention relates to a continuous process for the production of polymeric coupling products by using a reactor assembly which is equipped with two or more reaction cells. The educt fluid is pumped through the reaction cells and thoroughly mixed therein by means of agitators. Preferably the process according to the invention is used for the preparation of coupling products which show at least partially precipitation and/or gelation effects during the performance of the synthesis. The precipitation and/or gelation effects are associated with and increase of the viscosity of the reaction system under reaction conditions. The products which are obtained by the process according to the invention have increased molecular weight and low polydispersity over similar products which were obtained in batch experiments.
    Type: Grant
    Filed: May 29, 2012
    Date of Patent: July 7, 2015
    Assignee: BASF SE
    Inventors: Matthias Kleiner, Martin Elbs, Marcel Kastler
  • Publication number: 20140332730
    Abstract: The present invention relates to polymers (I), or (II), and their use as organic semiconductor in organic devices, especially in organic photovoltaics (solar cells) and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors, organic photovoltaics (solar cells) and photodiodes.
    Type: Application
    Filed: December 3, 2012
    Publication date: November 13, 2014
    Applicant: BASF SE
    Inventors: Pascal Hayoz, Patrice Bujard
  • Patent number: 8778597
    Abstract: A curable composition that maintains good handleability in the liquid form and that can be photo- or heat-cured to form a cured product having physical properties including both high transparency and high flexural strength. A curable composition includes, an epoxy compound of (1): [where each of E1, E2, and E3 is independently an organic group of Formula (2) or Formula (3); and each of R1, R2, and R3 is independently an optionally branched alkylene group or oxyalkylene group: (where R4 is a hydrogen atom or a methyl group)]; and an acid generator.
    Type: Grant
    Filed: January 24, 2011
    Date of Patent: July 15, 2014
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Toshiaki Takeyama, Yuki Endo, Takeo Moro, Kentaro Ohmori
  • Publication number: 20140080994
    Abstract: The present invention relates to a continuous process for the production of polymeric coupling products by using a reactor assembly which is equipped with two or more reaction cells. The educt fluid is pumped through the reaction cells and thoroughly mixed therein by means of agitators. Preferably the process according to the invention is used for the preparation of coupling products which show at least partially precipitation and/or gelation effects during the performance of the synthesis. The precipitation and/or gelation effects are associated with and increase of the viscosity of the reaction system under reaction conditions. The products which are obtained by the process according to the invention have increased molecular weight and low polydispersity over similar products which were obtained in batch experiments.
    Type: Application
    Filed: May 29, 2012
    Publication date: March 20, 2014
    Applicant: BASF SE
    Inventors: Matthias Kleiner, Martin Elbs, Marcel Kastler
  • Patent number: 8586063
    Abstract: Disclosed are compounds obtained by reacting (a) epoxides (I) which comprise at least two epoxide groups per molecule, with (b) compounds of the structure (II), having substituents as defined, and (c) optionally, alcohols (III) of the formula R4—OH, wherein R4 is C6-C22 alkyl, with the proviso that the molar ratio of the reactants (I):(II):(III) is in the range from 1:(1 to 3):(0.05 to 1.95). These compounds are useful as thickeners, and may be prepared as thickener concentrates.
    Type: Grant
    Filed: October 1, 2010
    Date of Patent: November 19, 2013
    Assignee: Cognis IP Management GmbH
    Inventors: Cindy Münzenberg, Helena Wiethoff
  • Patent number: 8362171
    Abstract: Norbornene monomers with epoxy groups and polymer materials thereof are disclosed. The Norbornene monomers with epoxy groups are prepared by Diels-Alder reaction. The Norbornene monomers with epoxy groups are highly active for ring-opening-metathesis polymerization (ROMP), and the molecular weight and PDI value of the obtained polymers are controllable.
    Type: Grant
    Filed: October 5, 2007
    Date of Patent: January 29, 2013
    Assignee: National Taiwan University of Science & Technology
    Inventors: Der-Jang Liaw, Ching-Cheng Huang
  • Publication number: 20120295199
    Abstract: A curable composition that maintains good handleability in the liquid form and that can be photo- or heat-cured to form a cured product having physical properties including both high transparency and high flexural strength. A curable composition includes, an epoxy compound of (1): [where each of E1, E2, and E3 is independently an organic group of Formula (2) or Formula (3); and each of R1, R2, and R3 is independently an optionally branched alkylene group or oxyalkylene group: (where R4 is a hydrogen atom or a methyl group)]; and an acid generator.
    Type: Application
    Filed: January 24, 2011
    Publication date: November 22, 2012
    Applicant: NISSAN CHEMICAL INDUSTRIES, LTD.
    Inventors: Toshiaki Takeyama, Yuki Endo, Takeo Moro, Kentaro Ohmori
  • Patent number: 8252864
    Abstract: An aqueous reaction product of a composition that may consist essentially of a source of an acid having a pKa in water of about 2 to about 8, a source of a base having a pKb in water of about 2 to about 6, and urea. A curable urea/formaldehyde resin composition may contain a curable urea/formaldehyde resin and the foregoing composition, and may be made by combining the resin with the composition. A reconstituted wood product may be made by combining particulate lignocellulosic material with the foregoing curable resin, and curing the resin. Optionally, a reconstituted wood panel may contain a particulate lignocellulosic material and a binder composition comprising the cured product of curable resin and the aforesaid aqueous reaction product. A concentrate for forming a polymerization enhancing composition is also disclosed.
    Type: Grant
    Filed: July 29, 2005
    Date of Patent: August 28, 2012
    Assignee: Momentive Specialty Chemicals Inc.
    Inventors: William K. Motter, David M. Harmon
  • Patent number: 8247614
    Abstract: Fluorinated copolymers are prepared via copolycondensation polymerization in a process comprising reacting A) a telechelic fluoroazido compound of formula N3(Y)p—(CH2)n—R—(CH2)m—(Y)pN3, wherein Y is SO, SO2, C6H4, or CO, p=0 or 1, n and m are independently 1 to 4, and R is selected from the group consisting of i) a C3-C10 fluoroalkylene group, ii) a C3-C10 fluoroalkoxylene group, iii) a substituted aryl group, iv) an oligomer comprising copolymerized units of vinylidene fluoride and perfluoro(methyl vinyl ether), v) an oligomer comprising copolymerized units of vinylidene fluoride and hexafluoropropylene, vi) an oligomer comprising copolymerized units of tetrafluoroethylene and perfluoro(methyl vinyl ether), and vii) an oligomer comprising copolymerized units of tetrafluoroethylene and a hydrocarbon olefin with B) a telechelic diyne or dinitrile compound in the presence of copper halide catalyst.
    Type: Grant
    Filed: June 17, 2009
    Date of Patent: August 21, 2012
    Assignees: E I du Pont de Nemours and Company
    Inventors: Ming-Hong Hung, Bruno Ameduri, Bernard Boutevin, Aurelien Soules
  • Publication number: 20120148670
    Abstract: A polymer capsule manufactured by polymerizing a compound represented by Formula 1, or polymerizing the compound of Formula 1 and a compound of Formula 2, wherein a detailed structure of the compounds of Formulae 1 and 2 is presented in the detailed description.
    Type: Application
    Filed: August 11, 2010
    Publication date: June 14, 2012
    Applicant: POSTECH ACADEMAY-INDUSTRY FOUNDATION
    Inventors: Ki moon Kim, Jiyeong Lee, Dongwoo Kim, Eunju Kim, Hyuntae Jung
  • Publication number: 20120065361
    Abstract: The invention provides a production process of a poly(arylene sulfide), comprising a polymerization step of subjecting at least one sulfur source selected from the group consisting of alkali metal sulfides and alkali metal hydrosulfides and a dihalo-aromatic compound to a polymerization reaction in an organic amide solvent; a reaction step of adding a hydroxyl group-containing organic compound containing no bonded halogen atom in a proportion of 0.001 to 20 mol per 100 mol of the charged sulfur source into the polymerization reaction system containing the organic amide solvent and a formed polymer after the polymerization step to cause the formed polymer to react with the hydroxyl group-containing organic compound; and a collecting step of collecting a polymer from the polymerization reaction system after the reaction step, and the poly(arylene sulfide).
    Type: Application
    Filed: May 11, 2010
    Publication date: March 15, 2012
    Applicant: KUREHA CORPORATION
    Inventors: Akihiro Konno, Hiroshi Sakabe, Ken-ichi Takaki
  • Patent number: 8034873
    Abstract: In-situ plasticized thermoplastic polyurethane (TPU) compositions are made by a process which involves reacting a polyol, glycol chain extender and a polyisocyanate where the reaction is conducted in the presence of a plasticizer. The reactants together with the plasticizer are added to a reaction extruder and reacted to form the in-situ plasticized TPU.
    Type: Grant
    Filed: December 5, 2006
    Date of Patent: October 11, 2011
    Assignee: Lubrizol Advanced Materials, Inc.
    Inventor: Sridhar K. Siddhamalli
  • Patent number: 7999060
    Abstract: A tailorable polyimide prepolymer blend comprising an end group component, a dianhydride component, and a diamine component. The dianhydride component includes at least 3,4,3?,4?-benzophenonetetracarboxylic dianhydride (BTDA), derivatives thereof, or combinations thereof, and 3,4,3?,4?-biphenyltetracarboxylic dianhydride (BPDA), derivatives thereof, or combinations thereof. The diamine component includes at least 1,3-phenylenediamine (mPDA), derivatives thereof, or combinations thereof; 1,4-phenylenediamine (pPDA), derivatives thereof, or combinations thereof; bis amino phenoxy benzene (APB), derivatives thereof, and combinations thereof; and optionally, 4,4?-(1,3-phenylene-bis(1-methylethylidene)bisaniline (Bis-M), derivatives thereof, and combinations thereof. A cured polyimide matrix has a glass transition temperature of at least about 450° F. (232° C.).
    Type: Grant
    Filed: October 30, 2007
    Date of Patent: August 16, 2011
    Assignee: General Electric Company
    Inventors: Warren Ronk, Lisa Shafer
  • Patent number: 7781521
    Abstract: This invention provides methods for producing furfural-urea resins and adhesives. The includes dissolving urea in hot water to produce a hot aqueous solution, mixing furfural with the aqueous solution, adding an acid catalyst such as maleic anhydride to the furfural containing aqueous solution upon which a resinification reaction begins immediately. The resinification reaction is quenched by cooling to a pre-selected temperature to produce a resin or adhesive.
    Type: Grant
    Filed: June 29, 2007
    Date of Patent: August 24, 2010
    Assignee: Infinity Wood Ltd.
    Inventors: Marc Henry Schneider, Jonathan Greer Phillips
  • Patent number: 7750062
    Abstract: A method of producing a polymeric material including subjecting a starting material to conditions under which polymerisation occurs. The starting material includes a group of sub-formula (XIII) where R16 is selected from hydrogen, halo, nitro, hydrocarbyl, optionally substituted or interposed with functional groups, or R2 and R3 are independently selected from (CR6R7)n or a group CR8R9, CR6R7CR8R9 or CR8R9CR6R7 where n is 0, 1 or 2 and R6 and R7 are independently selected from hydrogen or alkyl, and either one of R8 or R9 is hydrogen and the other is an electron withdrawing group, or R8 or R9 together form an electron withdrawing group. R4 and R5 are independently selected from CH or CR1o where CR1o is an electron withdrawing group, X1 is a group CX2X3, Y1 is a group CY2Y3, and X2 X3, and, if present, Y2 and Y3, are each a C1 to C4 alkyl group.
    Type: Grant
    Filed: December 23, 2008
    Date of Patent: July 6, 2010
    Assignee: Novel Polymer Solutions Limited
    Inventors: James Rolfe, Warrick Allen
  • Publication number: 20100168377
    Abstract: Catalytic processes have been developed for direct chemical conversion of amides to methyl ether polymers or methyl ether ladder polymers. Amides formed by reacting acetic acid with monoethanol amine (MEA) or acetic acid with butylamine were polymerized in the presence of transition metal catalysts in air to form linear polymers. Ethanol acetamide was catalytically converted to a linear polyether as characterized by FTIR spectra. The catalysts were based on molecular strings of mono-, di- or tri-valent transition metal compounds that opened the amide carbonyl double bond to produce linear polyethers. Laboratory results have demonstrated [cobalt(II)]2, [manganese(II)]2, cobalt(II)-manganese(II), [nickel(II)]2 and related families of catalysts to be effective for formation of methyl ether polymers by this process.
    Type: Application
    Filed: December 29, 2008
    Publication date: July 1, 2010
    Applicant: Carter Technologies
    Inventor: Melvin Keith Carter
  • Patent number: 7732559
    Abstract: A method of preparing a halophthalic acid is disclosed which comprises the steps of contacting in a liquid phase reaction mixture at least one halogen-substituted ortho-xylene with oxygen and acetic acid at a temperature in a range between about 120° C. and about 220° C. in the presence of a catalyst system yielding a product mixture comprising less than 10 percent halogen-substituted ortho-xylene starting material, a halophthalic acid product, and less than about 10,000 ppm halobenzoic acid and less than about 1000 ppm halophthalide by-products based on a total amount of halophthalic acid present in the product mixture. In addition methods for the preparation of halophthalic anhydride, and recovery of high purity acetic acid from an aqueous acetic acid stream comprising HCl, which is generated during the preparation of the halophthalic acid are also disclosed.
    Type: Grant
    Filed: July 18, 2008
    Date of Patent: June 8, 2010
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Robert Edgar Colborn, David Bruce Hall, Peter Alois Koch, Bernd Volker Demuth, Thomas Wessel, Karl Ernst Mack, Prashant Anil Tatake, Uptal Mahendra Vakil, Shyamal Bhaskar Gondkar, John Edward Pace, Kwang Woong Won
  • Patent number: 7728101
    Abstract: The invention relates to an overcoat lacquer containing a) at least one binding agent containing alkyd resins made from tris-(2-hydroxylethyl)-isocyanurate, 2,6-naphthaline dicarboxylic acid, drying fatty acids, and, optionally, other components known from alkyd resin chemistry, b) at least one solvent or at least one technical solvent or mixture thereof based on hydrocarbon and c) at least one siccative or at least one mixture of siccatives or several anti-skin agents.
    Type: Grant
    Filed: January 24, 2005
    Date of Patent: June 1, 2010
    Assignee: Altana Electrical Insulation GmbH
    Inventors: Klaus-Wilhelm Lienert, Gerold Schmidt, Sascha Tödter-König
  • Patent number: 7700709
    Abstract: A derivative of a cytidine metabolic antagonist which can exert a high therapeutic effect at a low dose. A polymeric derivative of a cytidine metabolic antagonist which comprises a polymeric compound having a polyethylene glycol moiety and a polymer moiety having a carboxyl group in a side chain and a cytidine metabolic antagonist, which has such a structure that the carboxyl group in the side chain of the polymeric compound and an amino group in the cytidine metabolic antagonist are bound together to form an amide bond.
    Type: Grant
    Filed: April 27, 2006
    Date of Patent: April 20, 2010
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Akira Masuda, Takeshi Onda, Hiroko Mashiba, Keiichirou Yamamoto, Kazutoshi Takashio
  • Patent number: 7678880
    Abstract: A molecular-oriented polymer gel and its cast film obtained by self-assembly of a self-organizable amphiphilic compound and a monomer interacting with the amphiphilic compound, and then polymerizing the monomer, and their production methods.
    Type: Grant
    Filed: August 7, 2003
    Date of Patent: March 16, 2010
    Assignees: Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Nobuo Kimizuka, Kazuhiro Kagawa, Takuya Nakashima
  • Patent number: 7666977
    Abstract: Disclosed herein is a process to prepare a poly(carbonate-co-urea) copolymer comprising reacting in the melt: (a) a dihydroxy reaction component comprising a dihydroxy compound, (b) a diaryl carbonate reaction component comprising a diaryl carbonate, (c) a urea reaction component comprising a urea compound in the presence of (d) a transesterification catalyst during at least part of the reaction and removing a phenolic byproduct to produce a poly(carbonate-co-urea) copolymer, wherein the urea and dihydroxy compounds are reacted in a molar ratio: (total moles of urea compound)/((total moles of urea compound)+(total moles of dihydroxy compound)) of less than or equal to 0.5.
    Type: Grant
    Filed: May 3, 2007
    Date of Patent: February 23, 2010
    Assignee: SABIC Innovative Plastics IP B.V.
    Inventors: Jan Henk Kamps, Edward Kung, Jan-Pleun Lens
  • Publication number: 20090005504
    Abstract: This invention provides methods for producing furfural-urea resins and adhesives. The includes dissolving urea in hot water to produce a hot aqueous solution, mixing furfural with the aqueous solution, adding an acid catalyst such as maleic anhydride to the furfural containing aqueous solution upon which a resinification reaction begins immediately. The resinification reaction is quenched by cooling to a pre-selected temperature to produce a resin or adhesive.
    Type: Application
    Filed: June 29, 2007
    Publication date: January 1, 2009
    Inventors: Marc Henry Schneider, Jonathan Greer Phillips
  • Publication number: 20080319097
    Abstract: The present invention relates to polymer resins, methods for their generation and uses thereof. In one aspect the present invention is directed to a resin obtainable by aminolysis of a precursor resin, wherein the precursor resin is obtainable by polymerisation of i) polydisperse di- or oligofunctional vinyl or cyclic ether compounds and ii) aminolytically sensitive, mono-functional vinyl or cyclic ether compounds.
    Type: Application
    Filed: August 26, 2005
    Publication date: December 25, 2008
    Applicant: Versamatrix A/S
    Inventors: Ib Johannsen, Patrik Gavelin
  • Publication number: 20080299391
    Abstract: A composition includes a plurality of capsules, and a polymerizer in the capsules. The capsules have an average outer diameter less than 10 micrometers. The capsules can be made by sonicating an emulsion to form a microemulsion, where the emulsion includes water, a surfactant, a first polymerizer and a second polymerizer, and then polymerizing the first polymerizer. The capsules may be present in a composite material that includes a polymer matrix and an activator.
    Type: Application
    Filed: May 31, 2007
    Publication date: December 4, 2008
    Inventors: Scott R. White, Nancy R. Sottos, Benjamin J. Blaiszik
  • Publication number: 20080275211
    Abstract: A method of preparing a halophthalic acid is disclosed which comprises the steps of contacting in a liquid phase reaction mixture at least one halogen-substituted ortho-xylene with oxygen and acetic acid at a temperature in a range between about 120° C. and about 220° C. in the presence of a catalyst system yielding a product mixture comprising less than 10 percent halogen-substituted ortho-xylene starting material, a halophthalic acid product, and less than about 10,000 ppm halobenzoic acid and less than about 1000 ppm halophthalide by-products based on a total amount of halophthalic acid present in the product mixture. In addition methods for the preparation of halophthalic anhydride, and recovery of high purity acetic acid from an aqueous acetic acid stream comprising HCl, which is generated during the preparation of the halophthalic acid are also disclosed.
    Type: Application
    Filed: July 18, 2008
    Publication date: November 6, 2008
    Inventors: Robert Edgar Colborn, David Bruce Hall, Peter Alois Koch, Bernd Volker Demuth, Thomas Wessel, Karl Ernst Mack, Prashant Anil Tatake, Utpal Mahendra Vakil, Shyamal Bhaskar Gondkar, John Edward Pace, Kwang Woong Won
  • Publication number: 20080275209
    Abstract: Disclosed herein is a process to prepare a poly(carbonate-co-urea) copolymer comprising reacting in the melt: (a) a dihydroxy reaction component comprising a dihydroxy compound, (b) a diaryl carbonate reaction component comprising a diaryl carbonate, (c) a urea reaction component comprising a urea compound in the presence of (d) a transesterification catalyst during at least part of the reaction and removing a phenolic byproduct to produce a poly(carbonate-co-urea) copolymer, wherein the urea and dihydroxy compounds are reacted in a molar ratio: (total moles of urea compound)/((total moles of urea compound)+(total moles of dihydroxy compound)) of less than or equal to 0.5.
    Type: Application
    Filed: May 3, 2007
    Publication date: November 6, 2008
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Jan Henk Kamps, Edward Kung, Jan-Pleun Lens
  • Publication number: 20080114148
    Abstract: A manufacturing method for polyimide resin containing a norbornene group is disclosed. Take Nadic anhydride to react with diamine compound to form dinorbornene polyimide. Then the dinorbornene polyimide reacts with diisocyanate compounds to produce polyimide resin containing a norbornene group. The polyimide resin containing a norbornene group has good adhesion and electrical properties and is applied to glass fiber, copper foil, coating agents, molding materials and adhesives for generating printed circuit boards by hot pressing.
    Type: Application
    Filed: November 13, 2006
    Publication date: May 15, 2008
    Inventor: Shen Jason Chou
  • Patent number: 7348395
    Abstract: A cyanate ester system is disclosed. An aryl ether oligomer may be made from a dihydroxyaromatic compound and a dihaloaromatic compound in the presence of a base. The oligomer is then reacted with a cyanide compound in the presence of a base to form the cyanate ester shown below. The cyanate ester may then be cross-linked to a thermoset having triazine ring cross-links.
    Type: Grant
    Filed: June 22, 2006
    Date of Patent: March 25, 2008
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Teddy M Keller, Matthew Laskoski
  • Patent number: 7342085
    Abstract: A cyanate ester system is disclosed. An aryl ether oligomer may be made from a dihydroxyaromatic compound and a dihaloaromatic compound in the presence of a base. The oligomer is then reacted with a cyanide compound in the presence of a base to form the cyanate ester shown below. The cyanate ester may then be cross-linked to a thermoset having triazine ring cross-links HO—Ar2O—Ar1—O—Ar2nOH.
    Type: Grant
    Filed: June 22, 2006
    Date of Patent: March 11, 2008
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Teddy M Keller, Matthew Laskoski
  • Publication number: 20080045690
    Abstract: A description is given of azetidine derivatives and methods for producing them, and of their use as a latent curing component for resins having functional groups which are reactive toward amino groups. The particular advantages of the curing component proposed in accordance with the invention, such as effective producibility, high environmental friendliness, and excellent storage stability of the resin/curing agent mixtures, make these azetidine derivatives outstandingly suitable for one-component, moisture-hardening polymer compositions, which are of special interest in particular for the production of (floor) coatings, sealants, and adhesives.
    Type: Application
    Filed: December 2, 2004
    Publication date: February 21, 2008
    Inventors: Stefan Ingrisch, Alois Maier, Thomas Pfeuffer, Norbert Steidl, Andrea Gantner, Herbert Winkelmann
  • Publication number: 20070265424
    Abstract: A polyimide prepolymer blend including a first prepolymer component comprising a first polyimide oligomer having the formula E1-[R1]n-E1 and a second prepolymer component selected from M1, a second polyimide oligomer having the formula E2-[R2]n-E2, and combinations thereof; where R1 and R2 independently comprise: where n is from about 1 to about 5, V is a tetravalent substituted or unsubstituted aromatic monocyclic or polycyclic linking structure, R is a substituted or unsubstituted divalent organic radical. E1 and E2 independently comprise crosslinkable functional groups. M1 comprises a mixture of monomeric compounds including a diamine component, a dianhydride component, and an end group component. The prepolymer blend, prior to cure, provides at least one predetermined prepolymer blend property; and when cured under suitable cure conditions, the prepolymer blend provides a crosslinked polyimide matrix having at least one predetermined crosslinked matrix property.
    Type: Application
    Filed: June 4, 2007
    Publication date: November 15, 2007
    Inventors: Stephen Mark Whiteker, Warren Rosal Ronk
  • Patent number: 7279505
    Abstract: The present invention provides a radiation-curable prepolymer. The radiation-curable prepolymer of the invention is prepared by reacting an isocyanate-capped polyurethane with an ethylenically unsaturated amine or an ethylenically unsaturated monohydroxy compound or a mixture thereof, wherein the isocyanate-capped polyurethane is a copolymerization production of: (a) at least one polyalkylene glycol; (b) at least one branching agent having at least three hydroxy groups; and (c) at least one di- or polyisocyanate. The radiation-curable prepolymer of the invention can find use in economically producing contact lenses which have durable, highly elastic soft contact lenses with desired physical properties. In addition, the present invention provides method for making a radiation-curable prepolymer of the invention and for making a medical device, preferably an ophthalmic device, more preferably a contact lens.
    Type: Grant
    Filed: October 5, 2005
    Date of Patent: October 9, 2007
    Assignee: Novartis AG
    Inventors: John Christopher Phelan, Michael Hugh Quinn, Joshua Andrew Wallach
  • Patent number: 7087707
    Abstract: A cyanate ester system is disclosed. An aryl ether oligomer may be made from a dihydroxyaromatic compound and a dihaloaromatic compound in the presence of a base. The oligomer is then reacted with a cyanide compound in the presence of a base to form the cyanate ester shown below. The cyanate ester may then be cross-linked to a thermoset having triazine ring cross-links.
    Type: Grant
    Filed: April 14, 2004
    Date of Patent: August 8, 2006
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Teddy M. Keller, Matt Laskoski
  • Patent number: 7057001
    Abstract: A process for the production of compounds which contain at least one urea group and at least one silyl group. The process involves reacting a compound containing at least one amino group and a carbamate compound. The compounds produced by this process are useful as surface coating compositions, foams and adhesives.
    Type: Grant
    Filed: October 24, 2001
    Date of Patent: June 6, 2006
    Assignee: Henkel Kommanditgesellschaft auf Aktien (Henkel KGAA)
    Inventors: Thomas Bachon, Wilfried Huebner, Hermann Kluth, Wolfgang Klauck, Johann Klein
  • Patent number: 7026429
    Abstract: The present invention relates to new hydrophilic polyurethane prepolymers and to their aqueous polyurethane-polyurea (PU) dispersions.
    Type: Grant
    Filed: December 17, 2003
    Date of Patent: April 11, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Rolf Gertzmann, Christoph Gürtler, Thorsten Rische, Thomas Münzmay
  • Patent number: 6995192
    Abstract: The present invention provides a radiation-curable prepolymer. The radiation-curable prepolymer of the invention is prepared by reacting an isocyanate-capped polyurethane with an ethylenically unsaturated amine or an ethylenically unsaturated monohydroxy compound or a mixture thereof, wherein the isocyanate-capped polyurethane is a copolymerization production of: (a) at least one polyalkylene glycol; (b) at least one branching agent having at least three hydroxy groups; and (c) at least one di- or polyisocyanate. The radiation-curable prepolymer of the invention can find use in economically producing contact lenses which have durable, highly elastic soft contact lenses with desired physical properties. In addition, the present invention provides method for making a radiation-curable prepolymer of the invention and for making a medical device, preferably an ophthalmic device, more preferably a contact lens.
    Type: Grant
    Filed: August 13, 2003
    Date of Patent: February 7, 2006
    Assignee: Novartis AG
    Inventors: John Christopher Phelan, Michael Hugh Quinn, Joshua Andrew Wallach
  • Patent number: 6750312
    Abstract: A method for preparing a solid support material for carrying out a chemical reaction, said method comprising the following steps: (i) reacting an amino functionalised solid material with a carboxylic acid having at least two similarly protected amino groups to form amide bonds between them, (ii) removing protecting groups in a single step, (iii) optionally repeating steps (i) and (ii) one or more times using the product of the preceding step as the amino functionalised solid material, and (iv) connecting a linkage agent to at least some of the free NH2 groups of the product. The method increases the loading capacity of the solid support material. It is particularly useful in connection with peptide synthesis.
    Type: Grant
    Filed: March 26, 2002
    Date of Patent: June 15, 2004
    Assignee: Avecia Limited
    Inventors: Craig Stephen Harris, Donald Alfred Wellings, Francis Joseph Montgomery, Richard John Brown
  • Patent number: 6663966
    Abstract: Dendrimer additives incorporated in thermoplastic resins (such as polycarbonate resins) are effective to alter the surface characteristics of the thermoplastic resin. Such compositions can be injection molded to produce articles in which the dendrimer additive is concentrated at the surface of the article to alter the properties of the resin. By selection of the type of dendrimer additive, the resulting characteristics of the molded article may be controlled.
    Type: Grant
    Filed: July 15, 2002
    Date of Patent: December 16, 2003
    Assignee: General Electric Company
    Inventor: Vijay R. Mhetar
  • Patent number: 6660376
    Abstract: The present invention relates to a hot melt moisture cure adhesive composition well suited for bonding porous substrates such as fabric, methods of adhesively bonding substrates and corresponding articles. The adhesive composition exhibits a combination of flexibility, high green strength, low molten viscosity and high heat resistance. In view of these properties, the adhesive is particularly amendable to hot melt adhesive application techniques wherein small individual discrete deposits of adhesive are applied to a substrate. The adhesive composition prepolymer is preferably the reaction product of at least one polyol, at least one polyisocyanate and at least one high molecular weight thermoplastic polyurethane lacking hard segments.
    Type: Grant
    Filed: June 6, 2000
    Date of Patent: December 9, 2003
    Assignee: H. B. Fuller Licensing & Financing Inc.
    Inventors: John M. Zimmel, William L. Bunnelle, Brendon J. Kryzer
  • Patent number: 6497959
    Abstract: Dendrimer additives incorporated in thermoplastic resins (such as polycarbonate resins) are effective to alter the surface characteristics of the thermoplastic resin. Such compositions can be injection molded to produce articles in which the dendrimer additive is concentrated at the surface of the article to alter the properties of the resin. By selection of the type of dendrimer additive, the resulting characteristics of the molded article may be controlled.
    Type: Grant
    Filed: March 30, 2000
    Date of Patent: December 24, 2002
    Assignee: General Electric Company
    Inventor: Vijay R. Mhetar
  • Patent number: 6127515
    Abstract: This invention is directed to a functionalized amino resin of formula ##STR1## wherein S is a solid support; R is H or alkyl; A is ##STR2## Y is OH or OCOR.sup.1 ; and R.sup.1 is aliphatic or aromatic which is useful for the solid phase synthesis of amides, peptides and hydroxamic acids.
    Type: Grant
    Filed: May 21, 1999
    Date of Patent: October 3, 2000
    Assignee: Aventis Pharmaceuticals Products Inc.
    Inventors: Franco Manfre, Benoit J. Vanasse, Richard F. Labaudiniere, George C. Morton
  • Patent number: 6127514
    Abstract: The present invention relates to one-component, thermoset compositions containinga) compounds containing modified hydrazide groups and corresponding to formula I ##STR1## wherein p2 R represents the residue obtained by removing the isocyanate groups from a monomeric polyisocyanate, a polyisocyanate adduct or an NCO prepolymer,X represents OR' or NHR' andR' represents a group which is inert to isocyanate groups under the conditions used to form the compound of formula I andn has a value of 2 to 6,b) compounds containing two or more epoxy groups andc) a basic catalyst.The present invention also relates to coatings, adhesives and sealants prepared from these thermoset compositions.
    Type: Grant
    Filed: November 23, 1998
    Date of Patent: October 3, 2000
    Assignees: Bayer Corporation, Bayer Aktiengesellschaft
    Inventors: Douglas A. Wicks, Sze-Ming Lee, Eberhard Koenig, Carol L. Kinney, Karen M. Henderson
  • Patent number: 6071568
    Abstract: The invention provides composite color-plus-clear coatings having improved appearance, especially with respect to wrinkling, and to methods and compositions for providing such coatings. The method of the invention utilizes a second coating composition comprising (A) a film forming component comprising (a) a first component comprising a compound having appended thereto at least one carbamate or urea functional group, or a group convertible to a carbamate or urea group, and (b) a second component comprising a compound reactive with said carbamate or urea groups on component (a), (B) a cyclic anhydride, and (C) a catalyst.
    Type: Grant
    Filed: May 1, 1998
    Date of Patent: June 6, 2000
    Assignee: BASF Corporation
    Inventors: Herbert L. Harmon, Timothy P. Kandow, Gregory G. Menovcik
  • Patent number: 6063898
    Abstract: The first aspect of the invention provides a novel compound containing a reactive functional group represented by formula (1)R.sup.2 --O--CO--NH--CH.dbd.CH--R.sup.1 (1)wherein R.sup.1 represents a hydrogen atom, an aromatic hydrocarbon group, or a saturated or unsaturated aliphatic hydrocarbon group, R.sup.2 represents a formula comprising alicyclic functionality.The second aspect provides an active energy ray-curable unsaturated resin composition prepared by mixing a reaction product of the above-mentioned compound (1) with an unsaturated resin containing an acid group and with a diluent. The composition can be cured by active energy rays, and it can be used as an alkali developable and active energy ray-curable type resist resin composition.
    Type: Grant
    Filed: August 13, 1998
    Date of Patent: May 16, 2000
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Takeshi Endo, Hiroto Miyake
  • Patent number: 6054528
    Abstract: The present invention relates to aqueous compositions containinga) bis(1,3,4-oxadiazolin-5-ones) corresponding to formula (I) ##STR1## wherein R represents a single bond or a divalent aliphatic, araliphatic or aromatic radical having 1 to 18 carbon atoms andb) organic polyamines or polyamine blends having an average of more than 2 NH-- and/or NH.sub.2 -- groups.The present invention also relates to coatings, adhesives or sealants prepared from these aqueous compositions, in particular automotive clear coats.
    Type: Grant
    Filed: July 17, 1998
    Date of Patent: April 25, 2000
    Assignee: Bayer Aktiengesellschaft
    Inventors: Josef Pedain, Klaus Konig, Peter Heitkamper, Manfred Schonfelder
  • Patent number: 6045872
    Abstract: The curable coating composition of the invention comprises a film forming component (A) and a wrinkle reducing catalyst (B) comprising a compound of the formula:M.sub.y (L).sub.xwherein M is a metal having an empty or full d orbital and wherein the pk.sub.a of the aqua ion of M is less than or equal to 12; L is a ligand wherein the pk.sub.a of the parent acid is .gtoreq.-10 and is .ltoreq.4; and x is an integer which is a multiple of the charge of M, y is an interger which is a multiple of the charge of L, x and y selected so that ML is charge balanced. Film forming component (A) has first component (a) with a compound having appended thereto at least one carbamate or urea functional group, or a group convertible to a carbamate or urea group, and a second component (b) with a compound reactive with said carbamate or urea groups on component (a).
    Type: Grant
    Filed: May 1, 1998
    Date of Patent: April 4, 2000
    Assignee: BASF Corporation
    Inventors: Herbert L. Harmon, Donald H. Campbell, Rodney L. Briggs
  • Patent number: 6037444
    Abstract: A process for the preparation of a compound or polymer having at least one functional group selected from hydroxyl, thiol, amino and carboxylic acid groups is characterized in that a compound or polymer (A) containing a group of formula (I), ##STR1## where Q represents O or S and X represents --O--, --S--, --NH-- or a direct bond, the group being linked to the remainder of the compound or polymer through a carbon atom, is reacted with a compound (B) containing at least two functional groups selected from hydroxyl, thiol, amino and carboxylic acid groups, one of which functional groups (II) reacts with the group of formula (I) and one of which functional groups (III) is substantially unreactive with the group of formula (I) under the conditions of reaction, so that the compound (B) becomes bonded to (A) through the reaction of groups (I) and (II) forming a compound or polymer containing unreacted functional groups (III).
    Type: Grant
    Filed: June 18, 1998
    Date of Patent: March 14, 2000
    Assignee: Courtaulds Coatings (Holdings) Limited
    Inventors: Steven Paul Rannard, Nicola Jane Davis
  • Patent number: 5898062
    Abstract: Poly (organophosphazene) polymers bearing various ratios of a carboxylic acid containing sidegroup and an alkylamino, alkoxy, or alkoxy ether sidegroup are disclosed. These water-soluble macromolecules are cross-linked and allowed to absorb water to form hydrogels. Because of their anionic character and high water content, the polymeric hydrogels are useful for a wide variety of biomedical applications including controlled drug delivery (e.g. pH sensitive drug delivery), biocompatible coatings, and pH sensitive membranes.
    Type: Grant
    Filed: April 10, 1997
    Date of Patent: April 27, 1999
    Assignee: The Penn State Research Foundation
    Inventors: Harry R. Allcock, Archel M. A. Ambrosio
  • Patent number: 5859175
    Abstract: Process for the preparation of polyether-amide solutions, steam-sterilizable dialysis membranes obtainable using the polyether-amide solutions, and a process for the production of these membranes.Polycondensation of one or more dicarboxylic acid derivatives of the formula I ##STR1## with one or more aromatic diamines of the formula II ##STR2## and, if appropriate, m-phenylenediamine, in aprotic polar solvents is known.As a result of passing ammonia, in an amount sufficient to neutralize the HCl formed, into the polymer solution obtained after the end of the polycondensation and filtering off the ammonium chloride formed, it is possible to prepare neutral, salt-free and particularly storage-stable polyether-amide solutions which can be further processed to membranes without isolation of the polymer. The resulting membranes are steam-sterilizable, chemically and thermally stable and show efficiency data in the region of that of good high-flux dialysis membranes.
    Type: Grant
    Filed: December 20, 1996
    Date of Patent: January 12, 1999
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Karsten Blatter, Reinhard Wagener, Carl Martin Bell, Hermann Josef Gohl