At Least One Reactant Contains A Three-membered Heterocyclic Ring Having Two Carbon And One Oxygen Atoms, E.g., Oxirane, Etc. Patents (Class 528/393)
  • Publication number: 20090099301
    Abstract: The present invention relates to crosslinked polymeric nanospheres having a star-shaped structure of the core-branch type, in which the branches are of a hydrophilic nature and the core is of a polymeric, crosslinked, hydrophobic nature and forms the imprint of all or at least part of a target molecule and to a process for preparing them.
    Type: Application
    Filed: March 22, 2007
    Publication date: April 16, 2009
    Applicant: POLYINTELL
    Inventors: Kaynoush Naraghi, Sami Bayoudh, Michel Arotcarena
  • Publication number: 20090036614
    Abstract: Process for production of post-crosslinkable thermoplastic resins by bulk-polymerizing a polymerizable composition (A) comprising (I) a monomer fluid containing a cyclic olefin (?) having two or more metathetical ring-opening reaction sites in the molecule in an amount 10 wt % or above based on the total amount of the monomers or a monomer fluid containing a norbornene monomer and a crosslinking agent, (II) a metathetical polymerization catalyst, and (III) a chain transfer agent; thermoplastic resins obtained by this process. These thermoplastic resins are free from odor due to residual monomers and are excellent in storage stability. Process for producing crosslinked resins and composite materials which comprises laminating the thermoplastic resin to a substrate and then crosslinking the thermoplastic resin.
    Type: Application
    Filed: September 24, 2008
    Publication date: February 5, 2009
    Inventor: Tomoo SUGAWARA
  • Patent number: 7476716
    Abstract: The invention relates to a process for the production of post-crosslinkable thermoplastic resins by bulk-polymerizing a polymerizable composition (A) comprising (I) a monomer fluid containing a cyclic olefin (?) having two or more metathetical ring-opening reaction sites in the molecule in an amount 10 wt % or above based on the total amount of the monomers or a monomer fluid containing a norbornene monomer and a crosslinking agent, (II) a metathetical polymerization catalyst, and (III) a chain transfer agent; thermoplastic resins obtained by this process; and a process for producing crosslinked resins or crosslinked resin composite materials which comprises laminating such a thermoplastic resin with a substrate at need and then crosslinking the thermoplastic resin. According to the invention, thermoplastic resins which are free from odor due to residual monomers and excellent in storage stability can be efficiently obtained by a simple process of bulk-polymerizing the composition (A).
    Type: Grant
    Filed: June 26, 2003
    Date of Patent: January 13, 2009
    Assignee: Zeon Corporation
    Inventor: Tomoo Sugawara
  • Publication number: 20080221292
    Abstract: The invention provides a process for preparing vinyl chloride-vinyl acetate copolymers in the form of their solid resins by means of free-radically initiated suspension polymerization in aqueous medium of 70% to 90% by weight of vinyl chloride, 10% to 30% by weight of vinyl acetate and, if desired, further comonomers copolymerizable therewith, characterized in that 0.1% to 5% by weight of a vinyl acetate-vinyl chloride copolymer soluble in ethyl acetate is introduced as an initial charge, the amounts in % by weight being based in each case on the total weight of the comonomers.
    Type: Application
    Filed: August 9, 2006
    Publication date: September 11, 2008
    Applicant: WACKER POLYMER SYSTEMS GMBH & CO. KG
    Inventors: Stephan Kaiser, Claudia Strohmeier, Franz Zenk
  • Publication number: 20080188638
    Abstract: The present invention provides bifunctional polymers, methods of preparing the same, and intermediates thereto. These compounds are useful in a variety of applications including the PEGylation of biologically active molecules. The invention also provides methods of using said compounds and compositions thereof.
    Type: Application
    Filed: April 27, 2007
    Publication date: August 7, 2008
    Applicant: Intezyne Technologies
    Inventors: Kurt Breitenkamp, Kevin N. Sill, Habib Skaff
  • Publication number: 20080172937
    Abstract: The invention provides compounds having the general structure: wherein R and R? are independently selected from the group consisting of H, C1-24 alkyl, aryl, C1-24 alkylaryl, aryl(C1-24)alkyl, —C(?O)—R1 (esters), C(?O)—NHR1 (urethanes), or C(?O)—O—R1 (carbonates) wherein R1 is selected from the group consisting of C1-24 alkyl, aryl, C1-24 alkylaryl, C1-24 arylalkyl; A is an organic moiety derived from the group consisting of alkylene oxides having 4-12 carbon atoms and aryl epoxides having 8-12 carbon atoms; x=1-300; y=0-200; z=0-200; and with the proviso that R and R? can not be H or ether functionality at the same time. The compounds are useful for improving the water transport characteristics of hydrophobic surfaces.
    Type: Application
    Filed: January 23, 2008
    Publication date: July 24, 2008
    Inventors: Charles Francis Palmer, Calvin M. Wicker
  • Patent number: 7365147
    Abstract: In the technical field where a difunctional epoxy resin having increased molecular weight is used to impart flexibility or improving dielectric properties, the present invention has remarkably improved moisture resistance and water resistance when used to produce a cured epoxy resin article. The epoxy resin composition comprises a difunctional epoxy resin (A) having a structure wherein an aromatic hydrocarbon group (a1) having a bonding site in an aromatic nucleus and a hydrocarbon group (a2) having an ether bond or the other hydrocarbon group (a3) are bonded via an acetal bond (a4), and also has a structure wherein a glycidyloxy group is bonded to the aromatic hydrocarbon group (a1); and a curing agent (B) as essential component.
    Type: Grant
    Filed: June 19, 2006
    Date of Patent: April 29, 2008
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Ichiro Ogura, Nobuya Nakamura, Tomoyuki Imada
  • Publication number: 20080047648
    Abstract: The present invention provides a rubber composition for a sidewall or a rubber composition for a clinch apex capable of reducing rolling resistance and electric resistance and improving crack resistance, and a tire prepared by using the rubber compositions. The rubber composition for a sidewall and the rubber composition for a clinch apex of the present invention comprise 1.0 to 7.5 parts by weight of a compound having oxyethylene units based on 100 parts by weight of a diene rubber. The tire of the present invention is prepared by using the rubber compositions.
    Type: Application
    Filed: July 23, 2007
    Publication date: February 28, 2008
    Inventor: Yoichi Mizuno
  • Patent number: 7321008
    Abstract: Star polymers of soft segment forming monomers are useful in forming surgical devices. The star polymers can be endcapped with diketene acetals, mixed with a filler and/or cross-linked. The polymer compositions are useful, for example, as fiber coatings, surgical adhesives or bone putty, or tissue growth substrate.
    Type: Grant
    Filed: August 28, 2006
    Date of Patent: January 22, 2008
    Assignee: United States Surgical Corporation
    Inventors: Steven L. Bennett, Kevin Connolly, Elliott Gruskin, Ying Jiang
  • Patent number: 7291682
    Abstract: The present invention provides a method of forming comb or star copolymers. The comb or star copolymers are useful in surface modification of thermoplastic materials or as surfactants. The method is aimed at attaching a polymeric side chain differing in polarity and chemical structure from the backbone and forming a comb or star copolymer structure. In particular the process comprises polymerizing in a first step a polymer backbone from epoxy and nitroxylether group containing monomers and in a second step polymerizing under controlled radical conditions a comb or star structure onto this backbone.
    Type: Grant
    Filed: August 26, 2003
    Date of Patent: November 6, 2007
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Wiebke Wunderlich-Wippert, Rudolf Pfaendner, Francesco Fuso, Jochen Fink
  • Patent number: 7112650
    Abstract: A process for preparing thermoplastic poly(3-hydroxyalkanoates) with a molar mass greater than 6 000 g/mol and a melting point in the range from 70 to 170° C., by reacting an oxirane compound with carbon monoxide in the presence of a transition metal catalyst which has rhodium(0), nickel(0), iron(0), cobalt(0) or palladium(0) as central metal and has been chelated with neutral Lewis bases, and also in the presence of diisocyanates, ortho esters, acetals, anhydrides, P2O5, MgO, MgCl2, MgSO4, zeolites, or a mixture of these, at a pressure in the range from 1 to 250 bar and at from room temperature to 150° C.
    Type: Grant
    Filed: July 17, 2002
    Date of Patent: September 26, 2006
    Assignee: BASF Aktiengesellschaft
    Inventors: Michael Slany, Gerrit Luinstra, Xavier Sava
  • Patent number: 7087702
    Abstract: In the technical field where a difunctional epoxy resin having increased molecular weight is used to impart flexibility or improving dielectric properties, the present invention has remarkably improved moisture resistance and water resistance when used to produce a cured epoxy resin article. The epoxy resin composition comprises a difunctional epoxy resin (A) having a structure wherein an aromatic hydrocarbon group (a1) having a bonding site in an aromatic nucleus and a hydrocarbon group (a2) having an ether bond or the other hydrocarbon group (a3) are bonded via an acetal bond (a4), and also has a structure wherein a glycidyloxy group is bonded to the aromatic hydrocarbon group (a1); and a curing agent (B) as essential component.
    Type: Grant
    Filed: October 14, 2003
    Date of Patent: August 8, 2006
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Ichiro Ogura, Nobuya Nakamura, Tomoyuki Imada
  • Patent number: 7019107
    Abstract: The invention relates to a catalytical process for preparing poly(3-hydroxyalkanoates) by copolymerizing an oxirane compound with carbon monoxide in the presence of a) at least one single- or multicenter neutral transition metal complex (A) based on a metal of groups 5 to 11 of the Periodic Table of the Elements, in which the metal center(s) is/are present in the formal oxidation state 0, and/or b) at least one single- or multicenter anionic transition metal complex (B) based on a metal of groups 5 to 11 of the Periodic Table of the Elements, where multicenter transition metal complexes have metal centers which, without exception, are of the same transition metal, which comprises carrying out the copolymerization in the presence of at least one nucleophile other than hydroxy-substituted pyridine compounds.
    Type: Grant
    Filed: February 26, 2003
    Date of Patent: March 28, 2006
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerrit Luinstra, Markus Allmendinger, Bernhard Rieger
  • Patent number: 6974856
    Abstract: Disclosed are block copolymers represented by the following general formula (I) wherein AI represents a hydroxyl group or an organic residue derived from an anionic polymerization initiator, R represents a hydrogen atom or an acyl group, NP represents a residue derived from a nucleophilic reagent, m is an integer of 2 to 20,000, and n is an integer of 1 to 20,000.
    Type: Grant
    Filed: June 27, 2000
    Date of Patent: December 13, 2005
    Assignee: Nanocarrier Co., Ltd.
    Inventors: Kazunori Kataoka, Yukio Nagasaki, Yoshitsugu Akiyama
  • Patent number: 6933361
    Abstract: Thermally re-mendable cross-linked polymeric materials that can be repeatedly mended or repaired by simple thermal treatment. The polymeric materials are made by polymerizing furan monomers and maleimide monomers via the Diels-Alder (DA) reaction wherein the furan monomers have at least three furan moieties and the maleimide monomers have at least three maleimide moieties. The intermonomer linkages that form between the furan and maleimide monomers are thermally reversible and do not require the addition of catalysts, additional monomer or special surface treatments.
    Type: Grant
    Filed: July 12, 2002
    Date of Patent: August 23, 2005
    Assignee: The Regents of the University of California
    Inventors: Fred Wudl, Xiangxu Chen
  • Patent number: 6903174
    Abstract: The invention concerns a copolymer of ethylene oxide and at least one substituted oxirane carrying a cross-linkable function. The copolymer comprises ethylene oxide, —O—CH2—CHR— units in which R is a substituent containing a reactive function which is cross-linkable by free radical process, R may be different from one unit to the other, and possibly —O—CH2—CHR?— units in which R? is a substituent containing no reactive function which is cross-linkable by means of a free radical process, R? may be different from one unit to the other. It is characterized by an excellent polymolecularity index I=Mw/Mn and a statistical distribution of the different monomer units. The copolymer is prepared by an anionic copolymerization process. The copolymer is useful for preparing a solid electrolyte having good mechanical properties, a good cationic conductivity and a good chemical compatibility with the electrodes of a generator operating with alkali metals such as lithium and sodium.
    Type: Grant
    Filed: May 2, 2003
    Date of Patent: June 7, 2005
    Assignee: Hydro-Quebec
    Inventors: Paul-Etienne Harvey, Jean-Yves Sanchez, Fannie Alloin
  • Patent number: 6894143
    Abstract: A composition for solid polymer electrolyte which comprises a polyether polymer and an electrolyte salt compound soluble in the polyether polymer; wherein said polyether polymer is either (1) a polyether polymer having a toluene insoluble content of not larger than 5 weight %, or (2) a polyether polymer having a Mooney viscosity of 3 to 190, which has been prepared by applying a shearing force under heated conditions using an extruder to a polyether polymer having a Mooney viscosity of 10 to 200 so that the Mooney viscosity is reduced by 5 or more. This composition exhibits good film-forming property, and gives a solid polymer electrolyte exhibiting good and uniform ionic conductivity, and having high mechanical strength and surface smoothness. The solid polymer electrolyte is suitable for batteries and capacitors, especially for a lithium ion secondary battery.
    Type: Grant
    Filed: June 28, 2002
    Date of Patent: May 17, 2005
    Assignee: Zeon Corporation
    Inventors: Hideyuki Nishio, Hidenori Onishi, Yoshinori Fujii
  • Patent number: 6855788
    Abstract: The invention concerns a copolymer of ethylene oxide and at least one substituted oxirane carrying a cross-linkable function. The copolymer comprises ethylene oxide, —O—CH2—CHR— units in which R is a substituent containing a reactive function which is cross-linkable by free radical process, and possibly —O—CH2—CHR?— units in which R? is a substituent containing no reactive function which is cross-linkable by means of a free radical process, It is characterized by an excellent polydispersity index I=Mw/Mn and a random distribution of the different monomer units. The copolymer is prepared by an anionic copolymerization process. The copolymer is useful for preparing a solid electrolyte having good mechanical properties, a good cationic conductivity and a good chemical compatibility with the electrodes of a generator operating with alkali metals such as lithium and sodium.
    Type: Grant
    Filed: December 2, 2002
    Date of Patent: February 15, 2005
    Assignee: Hydro-Quebec
    Inventors: Paul-Etienne Harvey, Jean-Yves Sanchez, Fannie Alloin
  • Patent number: 6841654
    Abstract: An inexpensive polyimide-free alignment layer comprising a mixture of an epoxy and a reactive liquid crystal material is used for fabricating liquid crystal displays (LCDs). The alignment layer can be cast onto a previously aligned layer, without destroying the alignment of the underlying layer, thus allowing for monolithic fabrication of compensator stacks, without film transfer lamination.
    Type: Grant
    Filed: May 15, 2001
    Date of Patent: January 11, 2005
    Assignee: Rockwell Scientific Licensing, LLC
    Inventors: Dong-Feng Gu, Young Chung, Len Hale
  • Patent number: 6825315
    Abstract: A method of making a thermally-removable adhesive is provided where a bismaleimide compound, a monomeric furan compound, containing an oxirane group an amine curative are mixed together at an elevated temperature of greater than approximately 90° C. to form a homogeneous solution, which, when cooled to less than approximately 70° C., simultaneously initiates a Diels-Alder reaction between the furan and the bismaleimide and a epoxy curing reaction between the amine curative and the oxirane group to form a thermally-removable adhesive. Subsequent heating to a temperature greater than approximately 100° C. causes the adhesive to melt and allows separation of adhered pieces.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: November 30, 2004
    Assignee: Sandia Corporation
    Inventor: James H. Aubert
  • Publication number: 20040039136
    Abstract: A curable composition includes an unsaturated polyester and an unsaturated monomer copolymerisable with the unsaturated polyester in the presence of polymerisation accelerators and initiators. The unsaturated polyester is an epoxidised unsaturated polyester obtainable by reaction between unsaturated polyester obtainable by reaction between the carboxy end groups of a polyester having unsaturated monomer units and the epoxy groups of an epoxy resin.
    Type: Application
    Filed: June 5, 2003
    Publication date: February 26, 2004
    Inventors: Alessandro Godi, Pierpaolo Tassaone
  • Publication number: 20040038132
    Abstract: The invention concerns a copolymer of ethylene oxide and at least one substituted oxirane carrying a cross-linkable function. The copolymer comprises ethylene oxide, —O—CH2—CHR— units in which R is a substituent containing a reactive function which is cross-linkable by free radical process, R may be different from one unit to the other, and possibly —O—CH2—CHR′— units in which R′ is a substituent containing no reactive function which is cross-linkable by means of a free radical process, R′ may be different from one unit to the other. It is characterized by an excellent polymolecularity index I=Mp/Mn and a statistical distribution of the different monomer units. The copolymer is prepared by an anionic copolymerization process.
    Type: Application
    Filed: May 2, 2003
    Publication date: February 26, 2004
    Applicant: HYDRO-QUEBEC
    Inventors: Paul-Etienne Harvey, Jean-Yves Sanchez, Fannie Alloin
  • Publication number: 20030199669
    Abstract: The present invention provides a diene rubber composition having excellent processability and being improved in both the balance between low rolling resistance and wet skid resistance, and strength properties. The composition according to the invention is a diene polymer rubber composition comprising (A) 100 parts by weight of a raw material rubber comprising (A-1) a diene rubbery polymer which is a conjugated diene rubbery polymer or a conjugated diene-styrene rubbery copolymer (1) containing a modified component in an amount exceeding 60 wt. %, which modified component is obtained by reacting an active end of the rubbery polymer with a polyfunctional compound having, in its molecule thereof, at least two epoxy groups, (2) having a molecular weight distribution Mw/Mn of 1.05 to 3.
    Type: Application
    Filed: March 10, 2003
    Publication date: October 23, 2003
    Applicant: Asahi Kasei Kabushiki Kaisha
    Inventors: Akira Saito, Haruo Yamada, Yasunobu Nakafutami, Hiromi Nakafutami
  • Patent number: 6525169
    Abstract: Polycationic polyquaternary products as defined in Claim 1 are useful as adjuvants in paper-making, especially as fixatives in the production of paper from coated broke.
    Type: Grant
    Filed: December 21, 2000
    Date of Patent: February 25, 2003
    Assignee: Clariant Finance (BVI) Limited
    Inventor: John Farrar
  • Patent number: 6369188
    Abstract: Polyfunctional polymerizable urethane- or urea-containing oligomers allow the design, adjustment, and regulation of chemical and physical properties of the described oligomers. The invention discloses the formulas and compositions of these oligomers, methods of their synthesis, and methods of converting the described oligomers into useful polymeric products. The described oligomers can be used for many purposes, both directly and in combination with other chemicals in multiple applications such as adhesives, sealants, coatings, composites, etc., as well as in castable and moldable materials.
    Type: Grant
    Filed: March 27, 1999
    Date of Patent: April 9, 2002
    Assignee: Polymeright, Inc.
    Inventors: Leonid Rappoport, Alex Vainer, Aleksandr Yam
  • Patent number: 6346330
    Abstract: A non-silicone, form-in-place gasket produced using automated placement followed by curing of a pattern of an extrudable thixotropic material comprising a liquid polyolefin oligomer a reactive diluent a thixotropic filler and a curative. The form-in-place gasket, after curing, has a compression set of about 7% to about 20%, a level of outgassing components of about 10 &mgr;g/g to about 45 &mgr;g/g and a Shore A hardness from about 45 to about 65.
    Type: Grant
    Filed: December 14, 2000
    Date of Patent: February 12, 2002
    Assignee: 3M Innovative Properties Company
    Inventors: Mitchell Huang, William B. Stockton
  • Patent number: 6337384
    Abstract: A method of making a thermally-removable epoxy by mixing a bis(maleimide) compound to a monomeric furan compound containing an oxirane group to form a di-epoxy mixture and then adding a curing agent at temperatures from approximately room temperature to less than approximately 90° C. to form a thermally-removable epoxy. The thermally-removable epoxy can be easily removed within approximately an hour by heating to temperatures greater than approximately 90° C. in a polar solvent. The epoxy material can be used in protecting electronic components that may require subsequent removal of the solid material for component repair, modification or quality control.
    Type: Grant
    Filed: January 18, 2000
    Date of Patent: January 8, 2002
    Assignee: Sandia Corporation
    Inventors: Douglas A. Loy, David R. Wheeler, Edward M. Russick, James R. McElhanon, Randall S. Saunders
  • Patent number: 6288208
    Abstract: The present invention relates to a highly branched polyamide oligomer of the general formula (I) as hereinabove defined, to the process for preparing and branched oligomers and to different uses thereof. As well known to the man skilled in the art, the implementations and efficacy of the different polyamide oligomers may vary, depending on their structure and valency (reactive groups composition). Polyamide oligomers may be used, for example, as epoxy hardeners in the preparation of thermosetting compositions, as thermoplastic hot melt adhesives, as adhesion promoters and many other suitable applications. The highly branched oligomers disclosed have been shown to be highly efficient, for example, as epoxy hardeners, inter alia, in the formation of glue, lacquer, enamel or sealant mixtures.
    Type: Grant
    Filed: April 20, 1999
    Date of Patent: September 11, 2001
    Assignee: Epox, Ltd.
    Inventor: Leonid Moshinsky
  • Patent number: 6262127
    Abstract: This invention provides pharmaceutical compositions comprising polymeric matrices, especially those comprising IL-6 as an active ingredient. Specific novel poly(ethylene carbomate) polymers are also provided for more general use as matrix materials in sustained release compositions containing pharmacologically active compounds, as are methods of using of IL-6 for treatment of conditions mediated by IL-1 and/or TNF&agr;, e.g., certain autoimmune and inflammatory conditions, as well as septic shock.
    Type: Grant
    Filed: July 20, 1999
    Date of Patent: July 17, 2001
    Assignee: Novartis AG
    Inventors: Murat Acemoglu, Siegfried Bantle, David Bodmer, Salvatore Cammisuli, Peter Hiestand, Fritz Nimmerfall, Georg Stoll
  • Patent number: 6255446
    Abstract: The invention provides a rubber composition comprising 100 parts by weight of a diene rubber (i) and 0.1 to 25 parts by weight of a polyether-based polymer (ii).
    Type: Grant
    Filed: April 10, 2000
    Date of Patent: July 3, 2001
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Masao Nakamura, Yukio Takagishi, Katsumi Inagaki
  • Patent number: 6245827
    Abstract: This invention is of a resin composition including an additive of one or more organic peroxide thermal imitators to cationic photoinitiators, that are sensitized with alpha-hydroxy-ketones, which composition provides a self-propagating thermal curing reaction first activated by a short duration of surface ultraviolet radiation. The thermal reaction is non-directional, thus eliminating the line of sight limitation of current radiation curing processes. Complete curing can be achieved of the composition in a very short time; often after only a few minutes or less. The activation period can be provided by only a few seconds of ultraviolet light using a wide variety of commercial ultraviolet light sources.
    Type: Grant
    Filed: October 12, 1999
    Date of Patent: June 12, 2001
    Assignee: Elementis Specialties, Inc.
    Inventor: Scott Gregory
  • Patent number: 6235813
    Abstract: The invention relates to block-polymethacrylate-block-polyalkylene oxide copolymers with terminal carboxylic acids, of the general formula I and to their use as a dispersing additive in aqueous pigment preparations and as a compatibilizer in SMC or BMC formulations.
    Type: Grant
    Filed: August 9, 1999
    Date of Patent: May 22, 2001
    Assignee: Th. GoldSchmidt AG
    Inventors: Petra Brandt, Eberhard Esselborn, Hans-Leo Karminski, Arno Knebelkamp, Christian Psiorz, Stefan Silber, Ellen Wallhorn
  • Patent number: 6150437
    Abstract: Flow improving agents for binder suspensions containing cement are described, which consist of:a) Graft polymers which have been prepared by radical grafting of a polyalkylene oxide of the general formula (I) with an ethylenically unsaturated mono- or dicarboxylic acid or the anhydride thereof, and then by derivatizing with a primary or secondary amine and/or alcohol, and also ofb) Casein.These flow improving agents have the advantage that the ability to flow is considerably improved in comparison, for example, with casein alone, and the improved ability to flow is preserved over a longer period of time.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: November 21, 2000
    Assignee: SKW Trostberg Aktiengesellschaft
    Inventors: Konrad Wutz, Alfred Kern, Josef Weichmann
  • Patent number: 6107362
    Abstract: A mixture of acrylic or methacrylic compounds, containing from 40 to 95% by weight, based on the total amount of the acrylic or methacrylic compounds, of epoxide (meth)acrylates, is obtainable by a process comprising the process stepsa) esterification of hydroxy compounds with acrylic acid or methacrylic acid,b) if required, subsequent addition of further acrylic acid or methacrylic acid andc) subsequent reaction of the excess acrylic or methacrylic acid with epoxides in the presence of the esterification product of a).
    Type: Grant
    Filed: November 2, 1998
    Date of Patent: August 22, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Koniger, Wolfgang Paulus, Wolfgang Reich, Erich Beck, Lothar Wolf
  • Patent number: 5989627
    Abstract: The specification describes processes for synthesizing vinyl ether functionalized oligomers or polymers, and methods for coating optical fibers with formulations containing these oligomers or polymers. Optical fibers coated with these formulations can be highly transparent to radiation used to write optical gratings in the optical fibers.
    Type: Grant
    Filed: September 28, 1998
    Date of Patent: November 23, 1999
    Assignee: Lucent Technologies Inc.
    Inventors: Lee Landis Blyler, Jr., Mark Anthony Paczkowski, Debra Ann Simoff, Ulrike Varlemann, Nanze Patrick Wang
  • Patent number: 5945504
    Abstract: An episulfide which has an alicyclic, aromatic or heterocyclic skeleton and has two or more moieties represented by the formula ##STR1## wherein X is S or O, and S is in an amount of 50% or more, on the average, of the total of S and O constituting a three-membered ring. A cured material obtained by polymerizing this episulfide compound is a desirable optical material for various uses, particularly as a lens material for spectacles.
    Type: Grant
    Filed: January 13, 1997
    Date of Patent: August 31, 1999
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akikazu Amagi, Nobuyuki Uemura, Motoharu Takeuchi, Kenichi Takahashi, Minoru Ohashi, Hiroshi Horikoshi, Masanori Shimuta
  • Patent number: 5855961
    Abstract: This invention relates to coating compositions including one or more resins having amino-reactive groups; one or more polyamine curing agents; and one or more aminourethanes. The aminourethanes can be reaction products of (i) oligomeric or polymeric compounds which contain at least one, preferably two or more terminal 2-oxo-1,3-dioxolane groups (cyclic carbonate groups), and (ii) amines containing at least one primary, preferably two or more primary and, if desired, also secondary and tertiary amino groups. The ratios of equivalents of C1):C2) typically is from 1:1 to 1:10, preferably from 1:1.05 to 1:5 and particularly preferably from 1:1.1 to 1:2, and the end product preferably contains one or more free primary amino groups. The composition further may contain, if desired, pigments, fillers, one or more organic solvents, water and conventional additives.
    Type: Grant
    Filed: May 12, 1997
    Date of Patent: January 5, 1999
    Assignee: Vianova Resins GmbH
    Inventors: Michael Hoenel, Armin Pfeil, Thomas Budnick, Heiner Schwan
  • Patent number: 5817885
    Abstract: The present invention relates to novel derivatives of terpene origin which consist of cycloalkenyls or cycloalkyls having at least seven carbon atoms and possessing surfactant and/or fragrant properties. According to one embodiment, the invention relates to compounds of the formula ##STR1## in which p and q are integers or decimal numbers and are not equal to zero, 0.ltoreq.p.ltoreq.20, preferably, 0.ltoreq.p.ltoreq.5, and 0.ltoreq.q.ltoreq.100, preferably 1.ltoreq.q.ltoreq.20. The invention further relates to the surfactant and/or fragrant compositions based on the above-mentioned compounds. The invention has particular applicability in detergent and perfume formulations.
    Type: Grant
    Filed: June 18, 1997
    Date of Patent: October 6, 1998
    Assignee: Rhone-Poulenc Chimie
    Inventors: Jean-Marc Ricca, Paul-Noel Derian, Jean-Pierre Hecaen, Jean-Michel Mercier
  • Patent number: 5760142
    Abstract: Epoxide-amine dendrimers synthesized by a repetitive and step-wise addition reaction of epoxides comprising functional moieties which are available for conversion into amino groups followed by a reaction of these groups to primary amino moieties. The amino terminated dendrimers are reacted with (2,3-epoxypropoxy) methacrylate, a monoepoxide and/or a monoisocyante. The methacrylate terminated dendrimers are polymerizable using redox initiators and/or photoinitiators. The resulting dendrimers show a very low volume shrinkage from that of the starting materials, on the order of less than about 5 percent by volume.
    Type: Grant
    Filed: December 4, 1996
    Date of Patent: June 2, 1998
    Assignee: Dentsply DeTrey G.m.b.H.
    Inventor: Joachim E. Klee
  • Patent number: 5739212
    Abstract: Water-soluble graft polymers are described which have been produced bya) radical grafting of a polyalkylene oxide of the general formula I ##STR1## in which R.sup.1 =--H, --C.sub.n H.sub.2n+1, --C.sub.6 H.sub.4 --C.sub.n H.sub.2n+1, ##STR2## --(CH--R.sup.2).sub.m NHR.sup.2, --(CH--R.sup.2).sub.m OH, --(CH--R.sup.2).sub.m --COOH, --CO--R.sup.5R.sup.2 =--H, --CH.sub.3, --C.sub.2 H.sub.5R.sup.3 =--H, --C.sub.n H.sub.2n+1, --C.sub.m H.sub.2m --SO.sub.3 Na, --(CH--R.sup.2).sub.m NHR.sup.2, --(CH--R.sup.2).sub.m OH, --(CH--R.sup.2).sub.m --COOH, --CO--R.sup.5R.sup.4 =--H, --(CH--R.sup.2).sub.m --COOH, --CO--R.sup.5R.sup.5 =--C.sub.m H.sub.2m+1, --C.sub.6 H.sub.5, --(CH--R.sup.2).sub.m --COOH, --C.sub.6 H.sub.4 --COOHn denotes 1-18, m denotes 1-5, x denotes 2-200, y denotes 0 or 1with an ethylenically unsaturated mono or dicarboxylic acid or their anhydride and subsequentlyb) derivatising with a primary or secondary amine and/or alcohol.
    Type: Grant
    Filed: October 19, 1995
    Date of Patent: April 14, 1998
    Assignee: SKW Trostberg Aktiengesellschaft
    Inventors: Konrad Wutz, Josef Weichmann, Alfred Kern, Hans-Gunter Rosenbauer
  • Patent number: 5674823
    Abstract: The present invention relates to novel derivatives of terpene origin which consist of cycloalkenyls or cycloalkyls having at least seven carbon atoms and possessing surfactant and/or fragrant properties. According to one embodiment, the invention relates to compounds of the formula ##STR1## in which p and q are integers or decimal numbers and are not equal to zero, O<P<20, preferably, O<P<5, and O<q<100, preferably 1<q<20. The invention further relates to the surfactant and/or fragrant compositions based on the above-mentioned compounds. The invention has particular applicability in detergent and perfume formulations.
    Type: Grant
    Filed: July 3, 1995
    Date of Patent: October 7, 1997
    Assignee: Rhone-Poulenc Chimie
    Inventors: Jean-Marc Ricca, Paul-Joel Derian, Jean-Pierre Hecaen, Jean-Michel Mercier
  • Patent number: 5663265
    Abstract: Low-viscosity copolymers useful in coating compositions, containing hydroxyl and carboxyl groups are obtained by free-radical polymerization of A) from 3 to 50% by weight of one or more glycidyl esters of aliphatic saturated monocarboxylic acids having a tertiary or quaternary .alpha. carbon atom, and B) from 97 to 50% by weight of at least two olefinically unsaturated copolymerizable monomers of which at least one contains at least one COOH group and at least one is sterically hindered, the quantity of COOH groups in component B exceeding the quantity of epoxy groups in component A to such an extent that the resulting copolymer has an acid number of at least 15 mg of KOH/g.
    Type: Grant
    Filed: April 19, 1995
    Date of Patent: September 2, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Ulrich Epple, Uwe Kubillus, Holger Schmidt
  • Patent number: 5646240
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: March 21, 1996
    Date of Patent: July 8, 1997
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Jin Suzuki, Kouhei Ohkawa, Hiroshi Ono
  • Patent number: 5612445
    Abstract: The epoxidation of alkyds containing anhydrides or diacids with cycloaliphatic unsaturation results in epoxy resins which cure rapidly in UV light to produce uniform films without the use of flow modifiers. The fatty acid portion of the alkyd functions as an internal plasticizer. Crosslinking occurs through oxirane rings in both the anhydride and fatty acid moieties of the alkyd to produce hard, but not brittle films. Excellent water resistance is obtained without thermal post curing.
    Type: Grant
    Filed: February 15, 1995
    Date of Patent: March 18, 1997
    Assignee: Arizona Chemical Co.
    Inventor: Raymond H. Jones
  • Patent number: 5552486
    Abstract: Propoxylated allyl alcohol homopolymers and copolymers of allyl alcohol and propoxylated allyl alcohol are disclosed. The polymers are soluble in many organic solvents, making them useful in a variety of applications, including polyesters, polyurethanes, alkyds, uralkyds, polyamines, acrylates, crosslinked polymeric resins, and polymer blends.
    Type: Grant
    Filed: May 25, 1995
    Date of Patent: September 3, 1996
    Assignee: ARCO Chemical Technology, L.P.
    Inventors: Shao-Hua Guo, Robert G. Gastinger
  • Patent number: 5539022
    Abstract: Water-dilutable dispersions of acrylate copolymers having a hydroxyl number of from 40 to 200 mg KOH/g and an acid number of from 15 to 50 mg of KOH/g, obtained by free-radical copolymerization ofa) from 5 to 40 parts by weight of at least one glycidyl ester of an .alpha.-branched aliphatic saturated monocarboxylic acid,b) from 0 to 30 parts by weight of at least one diester of an .alpha.,.beta.-olefinically unsaturated dicarboxylic acid,c) from 0 to 70 parts by weight of at least one vinyl aromatic hydrocarbon, the molar quantity of component c) always being greater than or equal to the molar quantity of component b),d) from 0 to 60 parts by weight of an alkyl ester of an .alpha.,.beta.-olefinically unsaturated carboxylic acid,e) from 2 to 40 parts by weight of at least one .alpha.,.beta.-olefinically unsaturated carboxylic acid, the molar quantity of component e) always being greater than the molar quantity of component a),f) from 5 to 40 parts by weight of at least one hydroxyalkyl ester of an .alpha.,.
    Type: Grant
    Filed: April 4, 1994
    Date of Patent: July 23, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Holger Schmidt, Tanja R. Brueck, Uwe Kubillus, Harald Oswald, Petra Schaub, Andrea Travers-Hemmer
  • Patent number: 5536809
    Abstract: Disclosed are novel polyether compounds obtained by the reaction or polymerization of 3,4-epoxy-1-butene in the presence of tetrahydrofuran, an acidic catalyst and a nucleophilic initiator compound. The polyether compounds comprise m units of residue (1), n units of residue (2), and p units of residue (3) wherein (i) residues (1), (2) and (3) have the structures: ##STR1## (ii) the total value of m+n+p is 5 to 70; (iii) the value of n/(m+n+p) is in the range of 0.2 to 0.4, i.e.
    Type: Grant
    Filed: November 13, 1995
    Date of Patent: July 16, 1996
    Assignee: Eastman Chemical Company
    Inventors: James C. Matayabas, Jr., Peter B. MacKenzie, John A. Hyatt
  • Patent number: 5502137
    Abstract: Disclosed are novel polyether compounds obtained by the reaction or polymerization of 3,4-epoxy-1-butene in the presence of tetrahydrofuran, an acidic catalyst and a nucleophilic initiator compound. The polyether compounds comprise m units of residue (1), n units of residue (2), and p units of residue (3) wherein (i) residues (1), (2) and (3) have the structures: ##STR1## (ii) the total value of m+n+p is 5 to 70; (iii) the value of n/(m+n+p) is in the range of 0.2 to 0.4, i.e.
    Type: Grant
    Filed: November 25, 1994
    Date of Patent: March 26, 1996
    Assignee: Eastman Chemical Company
    Inventors: James C. Matayabas, Jr., Peter B. MacKenzie, John A. Hyatt
  • Patent number: 5496907
    Abstract: Compounds containing a ureido group which are useful in preparing dispersions of polymers having good wet adhesion properties and low volatility. Compounds having the formula: ##STR1## where R.sup.1 is H or an alkyl group, R.sup.2 is alkylene optionally interrupted with one or more ether oxygen atoms and A is H or a residue of an active hydrogen reactive compound are useful for incorporating ureido and optionally nitrile functionality into polymers and as precursors to amino compounds prepared by reduction of the nitrile group thereof. Compounds having the formula: ##STR2## where B is defined as for A and the same or different than A are also disclosed. The disclosed compounds have use as chain extending or terminating monomers for polyurethane dispersions when one or both of A and B are H and, when one of A and has ethylenic unsaturation, as wet adhesion monomers in dispersions of free radically polymerized polymers of unsaturated monomers.
    Type: Grant
    Filed: September 2, 1994
    Date of Patent: March 5, 1996
    Assignee: H. B. Fuller Licensing & Financing, Inc.
    Inventor: Michael J. Dochniak
  • Patent number: 5420172
    Abstract: Cross-linked epoxy resins having nonlinear optical properties may be used in nonlinear optical media. These cross-linked epoxy resins may have the following structure: ##STR1## Z.sup.1 and Z.sup.2 being NLO-chromophores.
    Type: Grant
    Filed: August 23, 1993
    Date of Patent: May 30, 1995
    Assignee: Siemens Aktiengesellschaft
    Inventors: Jens Nordmann, Rainer Puehl