At Least One Reactant Contains A Three-membered Heterocyclic Ring Having Two Carbon And One Oxygen Atoms, E.g., Oxirane, Etc. Patents (Class 528/393)
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Publication number: 20090099301Abstract: The present invention relates to crosslinked polymeric nanospheres having a star-shaped structure of the core-branch type, in which the branches are of a hydrophilic nature and the core is of a polymeric, crosslinked, hydrophobic nature and forms the imprint of all or at least part of a target molecule and to a process for preparing them.Type: ApplicationFiled: March 22, 2007Publication date: April 16, 2009Applicant: POLYINTELLInventors: Kaynoush Naraghi, Sami Bayoudh, Michel Arotcarena
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Publication number: 20090036614Abstract: Process for production of post-crosslinkable thermoplastic resins by bulk-polymerizing a polymerizable composition (A) comprising (I) a monomer fluid containing a cyclic olefin (?) having two or more metathetical ring-opening reaction sites in the molecule in an amount 10 wt % or above based on the total amount of the monomers or a monomer fluid containing a norbornene monomer and a crosslinking agent, (II) a metathetical polymerization catalyst, and (III) a chain transfer agent; thermoplastic resins obtained by this process. These thermoplastic resins are free from odor due to residual monomers and are excellent in storage stability. Process for producing crosslinked resins and composite materials which comprises laminating the thermoplastic resin to a substrate and then crosslinking the thermoplastic resin.Type: ApplicationFiled: September 24, 2008Publication date: February 5, 2009Inventor: Tomoo SUGAWARA
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Patent number: 7476716Abstract: The invention relates to a process for the production of post-crosslinkable thermoplastic resins by bulk-polymerizing a polymerizable composition (A) comprising (I) a monomer fluid containing a cyclic olefin (?) having two or more metathetical ring-opening reaction sites in the molecule in an amount 10 wt % or above based on the total amount of the monomers or a monomer fluid containing a norbornene monomer and a crosslinking agent, (II) a metathetical polymerization catalyst, and (III) a chain transfer agent; thermoplastic resins obtained by this process; and a process for producing crosslinked resins or crosslinked resin composite materials which comprises laminating such a thermoplastic resin with a substrate at need and then crosslinking the thermoplastic resin. According to the invention, thermoplastic resins which are free from odor due to residual monomers and excellent in storage stability can be efficiently obtained by a simple process of bulk-polymerizing the composition (A).Type: GrantFiled: June 26, 2003Date of Patent: January 13, 2009Assignee: Zeon CorporationInventor: Tomoo Sugawara
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Publication number: 20080221292Abstract: The invention provides a process for preparing vinyl chloride-vinyl acetate copolymers in the form of their solid resins by means of free-radically initiated suspension polymerization in aqueous medium of 70% to 90% by weight of vinyl chloride, 10% to 30% by weight of vinyl acetate and, if desired, further comonomers copolymerizable therewith, characterized in that 0.1% to 5% by weight of a vinyl acetate-vinyl chloride copolymer soluble in ethyl acetate is introduced as an initial charge, the amounts in % by weight being based in each case on the total weight of the comonomers.Type: ApplicationFiled: August 9, 2006Publication date: September 11, 2008Applicant: WACKER POLYMER SYSTEMS GMBH & CO. KGInventors: Stephan Kaiser, Claudia Strohmeier, Franz Zenk
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Publication number: 20080188638Abstract: The present invention provides bifunctional polymers, methods of preparing the same, and intermediates thereto. These compounds are useful in a variety of applications including the PEGylation of biologically active molecules. The invention also provides methods of using said compounds and compositions thereof.Type: ApplicationFiled: April 27, 2007Publication date: August 7, 2008Applicant: Intezyne TechnologiesInventors: Kurt Breitenkamp, Kevin N. Sill, Habib Skaff
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Publication number: 20080172937Abstract: The invention provides compounds having the general structure: wherein R and R? are independently selected from the group consisting of H, C1-24 alkyl, aryl, C1-24 alkylaryl, aryl(C1-24)alkyl, —C(?O)—R1 (esters), C(?O)—NHR1 (urethanes), or C(?O)—O—R1 (carbonates) wherein R1 is selected from the group consisting of C1-24 alkyl, aryl, C1-24 alkylaryl, C1-24 arylalkyl; A is an organic moiety derived from the group consisting of alkylene oxides having 4-12 carbon atoms and aryl epoxides having 8-12 carbon atoms; x=1-300; y=0-200; z=0-200; and with the proviso that R and R? can not be H or ether functionality at the same time. The compounds are useful for improving the water transport characteristics of hydrophobic surfaces.Type: ApplicationFiled: January 23, 2008Publication date: July 24, 2008Inventors: Charles Francis Palmer, Calvin M. Wicker
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Patent number: 7365147Abstract: In the technical field where a difunctional epoxy resin having increased molecular weight is used to impart flexibility or improving dielectric properties, the present invention has remarkably improved moisture resistance and water resistance when used to produce a cured epoxy resin article. The epoxy resin composition comprises a difunctional epoxy resin (A) having a structure wherein an aromatic hydrocarbon group (a1) having a bonding site in an aromatic nucleus and a hydrocarbon group (a2) having an ether bond or the other hydrocarbon group (a3) are bonded via an acetal bond (a4), and also has a structure wherein a glycidyloxy group is bonded to the aromatic hydrocarbon group (a1); and a curing agent (B) as essential component.Type: GrantFiled: June 19, 2006Date of Patent: April 29, 2008Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Ichiro Ogura, Nobuya Nakamura, Tomoyuki Imada
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Publication number: 20080047648Abstract: The present invention provides a rubber composition for a sidewall or a rubber composition for a clinch apex capable of reducing rolling resistance and electric resistance and improving crack resistance, and a tire prepared by using the rubber compositions. The rubber composition for a sidewall and the rubber composition for a clinch apex of the present invention comprise 1.0 to 7.5 parts by weight of a compound having oxyethylene units based on 100 parts by weight of a diene rubber. The tire of the present invention is prepared by using the rubber compositions.Type: ApplicationFiled: July 23, 2007Publication date: February 28, 2008Inventor: Yoichi Mizuno
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Patent number: 7321008Abstract: Star polymers of soft segment forming monomers are useful in forming surgical devices. The star polymers can be endcapped with diketene acetals, mixed with a filler and/or cross-linked. The polymer compositions are useful, for example, as fiber coatings, surgical adhesives or bone putty, or tissue growth substrate.Type: GrantFiled: August 28, 2006Date of Patent: January 22, 2008Assignee: United States Surgical CorporationInventors: Steven L. Bennett, Kevin Connolly, Elliott Gruskin, Ying Jiang
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Patent number: 7291682Abstract: The present invention provides a method of forming comb or star copolymers. The comb or star copolymers are useful in surface modification of thermoplastic materials or as surfactants. The method is aimed at attaching a polymeric side chain differing in polarity and chemical structure from the backbone and forming a comb or star copolymer structure. In particular the process comprises polymerizing in a first step a polymer backbone from epoxy and nitroxylether group containing monomers and in a second step polymerizing under controlled radical conditions a comb or star structure onto this backbone.Type: GrantFiled: August 26, 2003Date of Patent: November 6, 2007Assignee: Ciba Specialty Chemicals Corp.Inventors: Wiebke Wunderlich-Wippert, Rudolf Pfaendner, Francesco Fuso, Jochen Fink
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Patent number: 7112650Abstract: A process for preparing thermoplastic poly(3-hydroxyalkanoates) with a molar mass greater than 6 000 g/mol and a melting point in the range from 70 to 170° C., by reacting an oxirane compound with carbon monoxide in the presence of a transition metal catalyst which has rhodium(0), nickel(0), iron(0), cobalt(0) or palladium(0) as central metal and has been chelated with neutral Lewis bases, and also in the presence of diisocyanates, ortho esters, acetals, anhydrides, P2O5, MgO, MgCl2, MgSO4, zeolites, or a mixture of these, at a pressure in the range from 1 to 250 bar and at from room temperature to 150° C.Type: GrantFiled: July 17, 2002Date of Patent: September 26, 2006Assignee: BASF AktiengesellschaftInventors: Michael Slany, Gerrit Luinstra, Xavier Sava
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Patent number: 7087702Abstract: In the technical field where a difunctional epoxy resin having increased molecular weight is used to impart flexibility or improving dielectric properties, the present invention has remarkably improved moisture resistance and water resistance when used to produce a cured epoxy resin article. The epoxy resin composition comprises a difunctional epoxy resin (A) having a structure wherein an aromatic hydrocarbon group (a1) having a bonding site in an aromatic nucleus and a hydrocarbon group (a2) having an ether bond or the other hydrocarbon group (a3) are bonded via an acetal bond (a4), and also has a structure wherein a glycidyloxy group is bonded to the aromatic hydrocarbon group (a1); and a curing agent (B) as essential component.Type: GrantFiled: October 14, 2003Date of Patent: August 8, 2006Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Ichiro Ogura, Nobuya Nakamura, Tomoyuki Imada
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Patent number: 7019107Abstract: The invention relates to a catalytical process for preparing poly(3-hydroxyalkanoates) by copolymerizing an oxirane compound with carbon monoxide in the presence of a) at least one single- or multicenter neutral transition metal complex (A) based on a metal of groups 5 to 11 of the Periodic Table of the Elements, in which the metal center(s) is/are present in the formal oxidation state 0, and/or b) at least one single- or multicenter anionic transition metal complex (B) based on a metal of groups 5 to 11 of the Periodic Table of the Elements, where multicenter transition metal complexes have metal centers which, without exception, are of the same transition metal, which comprises carrying out the copolymerization in the presence of at least one nucleophile other than hydroxy-substituted pyridine compounds.Type: GrantFiled: February 26, 2003Date of Patent: March 28, 2006Assignee: BASF AktiengesellschaftInventors: Gerrit Luinstra, Markus Allmendinger, Bernhard Rieger
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Patent number: 6974856Abstract: Disclosed are block copolymers represented by the following general formula (I) wherein AI represents a hydroxyl group or an organic residue derived from an anionic polymerization initiator, R represents a hydrogen atom or an acyl group, NP represents a residue derived from a nucleophilic reagent, m is an integer of 2 to 20,000, and n is an integer of 1 to 20,000.Type: GrantFiled: June 27, 2000Date of Patent: December 13, 2005Assignee: Nanocarrier Co., Ltd.Inventors: Kazunori Kataoka, Yukio Nagasaki, Yoshitsugu Akiyama
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Patent number: 6933361Abstract: Thermally re-mendable cross-linked polymeric materials that can be repeatedly mended or repaired by simple thermal treatment. The polymeric materials are made by polymerizing furan monomers and maleimide monomers via the Diels-Alder (DA) reaction wherein the furan monomers have at least three furan moieties and the maleimide monomers have at least three maleimide moieties. The intermonomer linkages that form between the furan and maleimide monomers are thermally reversible and do not require the addition of catalysts, additional monomer or special surface treatments.Type: GrantFiled: July 12, 2002Date of Patent: August 23, 2005Assignee: The Regents of the University of CaliforniaInventors: Fred Wudl, Xiangxu Chen
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Patent number: 6903174Abstract: The invention concerns a copolymer of ethylene oxide and at least one substituted oxirane carrying a cross-linkable function. The copolymer comprises ethylene oxide, —O—CH2—CHR— units in which R is a substituent containing a reactive function which is cross-linkable by free radical process, R may be different from one unit to the other, and possibly —O—CH2—CHR?— units in which R? is a substituent containing no reactive function which is cross-linkable by means of a free radical process, R? may be different from one unit to the other. It is characterized by an excellent polymolecularity index I=Mw/Mn and a statistical distribution of the different monomer units. The copolymer is prepared by an anionic copolymerization process. The copolymer is useful for preparing a solid electrolyte having good mechanical properties, a good cationic conductivity and a good chemical compatibility with the electrodes of a generator operating with alkali metals such as lithium and sodium.Type: GrantFiled: May 2, 2003Date of Patent: June 7, 2005Assignee: Hydro-QuebecInventors: Paul-Etienne Harvey, Jean-Yves Sanchez, Fannie Alloin
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Patent number: 6894143Abstract: A composition for solid polymer electrolyte which comprises a polyether polymer and an electrolyte salt compound soluble in the polyether polymer; wherein said polyether polymer is either (1) a polyether polymer having a toluene insoluble content of not larger than 5 weight %, or (2) a polyether polymer having a Mooney viscosity of 3 to 190, which has been prepared by applying a shearing force under heated conditions using an extruder to a polyether polymer having a Mooney viscosity of 10 to 200 so that the Mooney viscosity is reduced by 5 or more. This composition exhibits good film-forming property, and gives a solid polymer electrolyte exhibiting good and uniform ionic conductivity, and having high mechanical strength and surface smoothness. The solid polymer electrolyte is suitable for batteries and capacitors, especially for a lithium ion secondary battery.Type: GrantFiled: June 28, 2002Date of Patent: May 17, 2005Assignee: Zeon CorporationInventors: Hideyuki Nishio, Hidenori Onishi, Yoshinori Fujii
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Patent number: 6855788Abstract: The invention concerns a copolymer of ethylene oxide and at least one substituted oxirane carrying a cross-linkable function. The copolymer comprises ethylene oxide, —O—CH2—CHR— units in which R is a substituent containing a reactive function which is cross-linkable by free radical process, and possibly —O—CH2—CHR?— units in which R? is a substituent containing no reactive function which is cross-linkable by means of a free radical process, It is characterized by an excellent polydispersity index I=Mw/Mn and a random distribution of the different monomer units. The copolymer is prepared by an anionic copolymerization process. The copolymer is useful for preparing a solid electrolyte having good mechanical properties, a good cationic conductivity and a good chemical compatibility with the electrodes of a generator operating with alkali metals such as lithium and sodium.Type: GrantFiled: December 2, 2002Date of Patent: February 15, 2005Assignee: Hydro-QuebecInventors: Paul-Etienne Harvey, Jean-Yves Sanchez, Fannie Alloin
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Patent number: 6841654Abstract: An inexpensive polyimide-free alignment layer comprising a mixture of an epoxy and a reactive liquid crystal material is used for fabricating liquid crystal displays (LCDs). The alignment layer can be cast onto a previously aligned layer, without destroying the alignment of the underlying layer, thus allowing for monolithic fabrication of compensator stacks, without film transfer lamination.Type: GrantFiled: May 15, 2001Date of Patent: January 11, 2005Assignee: Rockwell Scientific Licensing, LLCInventors: Dong-Feng Gu, Young Chung, Len Hale
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Patent number: 6825315Abstract: A method of making a thermally-removable adhesive is provided where a bismaleimide compound, a monomeric furan compound, containing an oxirane group an amine curative are mixed together at an elevated temperature of greater than approximately 90° C. to form a homogeneous solution, which, when cooled to less than approximately 70° C., simultaneously initiates a Diels-Alder reaction between the furan and the bismaleimide and a epoxy curing reaction between the amine curative and the oxirane group to form a thermally-removable adhesive. Subsequent heating to a temperature greater than approximately 100° C. causes the adhesive to melt and allows separation of adhered pieces.Type: GrantFiled: December 21, 2001Date of Patent: November 30, 2004Assignee: Sandia CorporationInventor: James H. Aubert
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Publication number: 20040039136Abstract: A curable composition includes an unsaturated polyester and an unsaturated monomer copolymerisable with the unsaturated polyester in the presence of polymerisation accelerators and initiators. The unsaturated polyester is an epoxidised unsaturated polyester obtainable by reaction between unsaturated polyester obtainable by reaction between the carboxy end groups of a polyester having unsaturated monomer units and the epoxy groups of an epoxy resin.Type: ApplicationFiled: June 5, 2003Publication date: February 26, 2004Inventors: Alessandro Godi, Pierpaolo Tassaone
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Publication number: 20040038132Abstract: The invention concerns a copolymer of ethylene oxide and at least one substituted oxirane carrying a cross-linkable function. The copolymer comprises ethylene oxide, —O—CH2—CHR— units in which R is a substituent containing a reactive function which is cross-linkable by free radical process, R may be different from one unit to the other, and possibly —O—CH2—CHR′— units in which R′ is a substituent containing no reactive function which is cross-linkable by means of a free radical process, R′ may be different from one unit to the other. It is characterized by an excellent polymolecularity index I=Mp/Mn and a statistical distribution of the different monomer units. The copolymer is prepared by an anionic copolymerization process.Type: ApplicationFiled: May 2, 2003Publication date: February 26, 2004Applicant: HYDRO-QUEBECInventors: Paul-Etienne Harvey, Jean-Yves Sanchez, Fannie Alloin
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Publication number: 20030199669Abstract: The present invention provides a diene rubber composition having excellent processability and being improved in both the balance between low rolling resistance and wet skid resistance, and strength properties. The composition according to the invention is a diene polymer rubber composition comprising (A) 100 parts by weight of a raw material rubber comprising (A-1) a diene rubbery polymer which is a conjugated diene rubbery polymer or a conjugated diene-styrene rubbery copolymer (1) containing a modified component in an amount exceeding 60 wt. %, which modified component is obtained by reacting an active end of the rubbery polymer with a polyfunctional compound having, in its molecule thereof, at least two epoxy groups, (2) having a molecular weight distribution Mw/Mn of 1.05 to 3.Type: ApplicationFiled: March 10, 2003Publication date: October 23, 2003Applicant: Asahi Kasei Kabushiki KaishaInventors: Akira Saito, Haruo Yamada, Yasunobu Nakafutami, Hiromi Nakafutami
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Patent number: 6525169Abstract: Polycationic polyquaternary products as defined in Claim 1 are useful as adjuvants in paper-making, especially as fixatives in the production of paper from coated broke.Type: GrantFiled: December 21, 2000Date of Patent: February 25, 2003Assignee: Clariant Finance (BVI) LimitedInventor: John Farrar
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Patent number: 6369188Abstract: Polyfunctional polymerizable urethane- or urea-containing oligomers allow the design, adjustment, and regulation of chemical and physical properties of the described oligomers. The invention discloses the formulas and compositions of these oligomers, methods of their synthesis, and methods of converting the described oligomers into useful polymeric products. The described oligomers can be used for many purposes, both directly and in combination with other chemicals in multiple applications such as adhesives, sealants, coatings, composites, etc., as well as in castable and moldable materials.Type: GrantFiled: March 27, 1999Date of Patent: April 9, 2002Assignee: Polymeright, Inc.Inventors: Leonid Rappoport, Alex Vainer, Aleksandr Yam
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Patent number: 6346330Abstract: A non-silicone, form-in-place gasket produced using automated placement followed by curing of a pattern of an extrudable thixotropic material comprising a liquid polyolefin oligomer a reactive diluent a thixotropic filler and a curative. The form-in-place gasket, after curing, has a compression set of about 7% to about 20%, a level of outgassing components of about 10 &mgr;g/g to about 45 &mgr;g/g and a Shore A hardness from about 45 to about 65.Type: GrantFiled: December 14, 2000Date of Patent: February 12, 2002Assignee: 3M Innovative Properties CompanyInventors: Mitchell Huang, William B. Stockton
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Patent number: 6337384Abstract: A method of making a thermally-removable epoxy by mixing a bis(maleimide) compound to a monomeric furan compound containing an oxirane group to form a di-epoxy mixture and then adding a curing agent at temperatures from approximately room temperature to less than approximately 90° C. to form a thermally-removable epoxy. The thermally-removable epoxy can be easily removed within approximately an hour by heating to temperatures greater than approximately 90° C. in a polar solvent. The epoxy material can be used in protecting electronic components that may require subsequent removal of the solid material for component repair, modification or quality control.Type: GrantFiled: January 18, 2000Date of Patent: January 8, 2002Assignee: Sandia CorporationInventors: Douglas A. Loy, David R. Wheeler, Edward M. Russick, James R. McElhanon, Randall S. Saunders
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Patent number: 6288208Abstract: The present invention relates to a highly branched polyamide oligomer of the general formula (I) as hereinabove defined, to the process for preparing and branched oligomers and to different uses thereof. As well known to the man skilled in the art, the implementations and efficacy of the different polyamide oligomers may vary, depending on their structure and valency (reactive groups composition). Polyamide oligomers may be used, for example, as epoxy hardeners in the preparation of thermosetting compositions, as thermoplastic hot melt adhesives, as adhesion promoters and many other suitable applications. The highly branched oligomers disclosed have been shown to be highly efficient, for example, as epoxy hardeners, inter alia, in the formation of glue, lacquer, enamel or sealant mixtures.Type: GrantFiled: April 20, 1999Date of Patent: September 11, 2001Assignee: Epox, Ltd.Inventor: Leonid Moshinsky
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Patent number: 6262127Abstract: This invention provides pharmaceutical compositions comprising polymeric matrices, especially those comprising IL-6 as an active ingredient. Specific novel poly(ethylene carbomate) polymers are also provided for more general use as matrix materials in sustained release compositions containing pharmacologically active compounds, as are methods of using of IL-6 for treatment of conditions mediated by IL-1 and/or TNF&agr;, e.g., certain autoimmune and inflammatory conditions, as well as septic shock.Type: GrantFiled: July 20, 1999Date of Patent: July 17, 2001Assignee: Novartis AGInventors: Murat Acemoglu, Siegfried Bantle, David Bodmer, Salvatore Cammisuli, Peter Hiestand, Fritz Nimmerfall, Georg Stoll
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Patent number: 6255446Abstract: The invention provides a rubber composition comprising 100 parts by weight of a diene rubber (i) and 0.1 to 25 parts by weight of a polyether-based polymer (ii).Type: GrantFiled: April 10, 2000Date of Patent: July 3, 2001Assignee: Nippon Zeon Co., Ltd.Inventors: Masao Nakamura, Yukio Takagishi, Katsumi Inagaki
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Patent number: 6245827Abstract: This invention is of a resin composition including an additive of one or more organic peroxide thermal imitators to cationic photoinitiators, that are sensitized with alpha-hydroxy-ketones, which composition provides a self-propagating thermal curing reaction first activated by a short duration of surface ultraviolet radiation. The thermal reaction is non-directional, thus eliminating the line of sight limitation of current radiation curing processes. Complete curing can be achieved of the composition in a very short time; often after only a few minutes or less. The activation period can be provided by only a few seconds of ultraviolet light using a wide variety of commercial ultraviolet light sources.Type: GrantFiled: October 12, 1999Date of Patent: June 12, 2001Assignee: Elementis Specialties, Inc.Inventor: Scott Gregory
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Patent number: 6235813Abstract: The invention relates to block-polymethacrylate-block-polyalkylene oxide copolymers with terminal carboxylic acids, of the general formula I and to their use as a dispersing additive in aqueous pigment preparations and as a compatibilizer in SMC or BMC formulations.Type: GrantFiled: August 9, 1999Date of Patent: May 22, 2001Assignee: Th. GoldSchmidt AGInventors: Petra Brandt, Eberhard Esselborn, Hans-Leo Karminski, Arno Knebelkamp, Christian Psiorz, Stefan Silber, Ellen Wallhorn
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Patent number: 6150437Abstract: Flow improving agents for binder suspensions containing cement are described, which consist of:a) Graft polymers which have been prepared by radical grafting of a polyalkylene oxide of the general formula (I) with an ethylenically unsaturated mono- or dicarboxylic acid or the anhydride thereof, and then by derivatizing with a primary or secondary amine and/or alcohol, and also ofb) Casein.These flow improving agents have the advantage that the ability to flow is considerably improved in comparison, for example, with casein alone, and the improved ability to flow is preserved over a longer period of time.Type: GrantFiled: June 7, 1995Date of Patent: November 21, 2000Assignee: SKW Trostberg AktiengesellschaftInventors: Konrad Wutz, Alfred Kern, Josef Weichmann
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Patent number: 6107362Abstract: A mixture of acrylic or methacrylic compounds, containing from 40 to 95% by weight, based on the total amount of the acrylic or methacrylic compounds, of epoxide (meth)acrylates, is obtainable by a process comprising the process stepsa) esterification of hydroxy compounds with acrylic acid or methacrylic acid,b) if required, subsequent addition of further acrylic acid or methacrylic acid andc) subsequent reaction of the excess acrylic or methacrylic acid with epoxides in the presence of the esterification product of a).Type: GrantFiled: November 2, 1998Date of Patent: August 22, 2000Assignee: BASF AktiengesellschaftInventors: Rainer Koniger, Wolfgang Paulus, Wolfgang Reich, Erich Beck, Lothar Wolf
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Patent number: 5989627Abstract: The specification describes processes for synthesizing vinyl ether functionalized oligomers or polymers, and methods for coating optical fibers with formulations containing these oligomers or polymers. Optical fibers coated with these formulations can be highly transparent to radiation used to write optical gratings in the optical fibers.Type: GrantFiled: September 28, 1998Date of Patent: November 23, 1999Assignee: Lucent Technologies Inc.Inventors: Lee Landis Blyler, Jr., Mark Anthony Paczkowski, Debra Ann Simoff, Ulrike Varlemann, Nanze Patrick Wang
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Patent number: 5945504Abstract: An episulfide which has an alicyclic, aromatic or heterocyclic skeleton and has two or more moieties represented by the formula ##STR1## wherein X is S or O, and S is in an amount of 50% or more, on the average, of the total of S and O constituting a three-membered ring. A cured material obtained by polymerizing this episulfide compound is a desirable optical material for various uses, particularly as a lens material for spectacles.Type: GrantFiled: January 13, 1997Date of Patent: August 31, 1999Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Akikazu Amagi, Nobuyuki Uemura, Motoharu Takeuchi, Kenichi Takahashi, Minoru Ohashi, Hiroshi Horikoshi, Masanori Shimuta
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Patent number: 5855961Abstract: This invention relates to coating compositions including one or more resins having amino-reactive groups; one or more polyamine curing agents; and one or more aminourethanes. The aminourethanes can be reaction products of (i) oligomeric or polymeric compounds which contain at least one, preferably two or more terminal 2-oxo-1,3-dioxolane groups (cyclic carbonate groups), and (ii) amines containing at least one primary, preferably two or more primary and, if desired, also secondary and tertiary amino groups. The ratios of equivalents of C1):C2) typically is from 1:1 to 1:10, preferably from 1:1.05 to 1:5 and particularly preferably from 1:1.1 to 1:2, and the end product preferably contains one or more free primary amino groups. The composition further may contain, if desired, pigments, fillers, one or more organic solvents, water and conventional additives.Type: GrantFiled: May 12, 1997Date of Patent: January 5, 1999Assignee: Vianova Resins GmbHInventors: Michael Hoenel, Armin Pfeil, Thomas Budnick, Heiner Schwan
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Patent number: 5817885Abstract: The present invention relates to novel derivatives of terpene origin which consist of cycloalkenyls or cycloalkyls having at least seven carbon atoms and possessing surfactant and/or fragrant properties. According to one embodiment, the invention relates to compounds of the formula ##STR1## in which p and q are integers or decimal numbers and are not equal to zero, 0.ltoreq.p.ltoreq.20, preferably, 0.ltoreq.p.ltoreq.5, and 0.ltoreq.q.ltoreq.100, preferably 1.ltoreq.q.ltoreq.20. The invention further relates to the surfactant and/or fragrant compositions based on the above-mentioned compounds. The invention has particular applicability in detergent and perfume formulations.Type: GrantFiled: June 18, 1997Date of Patent: October 6, 1998Assignee: Rhone-Poulenc ChimieInventors: Jean-Marc Ricca, Paul-Noel Derian, Jean-Pierre Hecaen, Jean-Michel Mercier
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Patent number: 5760142Abstract: Epoxide-amine dendrimers synthesized by a repetitive and step-wise addition reaction of epoxides comprising functional moieties which are available for conversion into amino groups followed by a reaction of these groups to primary amino moieties. The amino terminated dendrimers are reacted with (2,3-epoxypropoxy) methacrylate, a monoepoxide and/or a monoisocyante. The methacrylate terminated dendrimers are polymerizable using redox initiators and/or photoinitiators. The resulting dendrimers show a very low volume shrinkage from that of the starting materials, on the order of less than about 5 percent by volume.Type: GrantFiled: December 4, 1996Date of Patent: June 2, 1998Assignee: Dentsply DeTrey G.m.b.H.Inventor: Joachim E. Klee
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Patent number: 5739212Abstract: Water-soluble graft polymers are described which have been produced bya) radical grafting of a polyalkylene oxide of the general formula I ##STR1## in which R.sup.1 =--H, --C.sub.n H.sub.2n+1, --C.sub.6 H.sub.4 --C.sub.n H.sub.2n+1, ##STR2## --(CH--R.sup.2).sub.m NHR.sup.2, --(CH--R.sup.2).sub.m OH, --(CH--R.sup.2).sub.m --COOH, --CO--R.sup.5R.sup.2 =--H, --CH.sub.3, --C.sub.2 H.sub.5R.sup.3 =--H, --C.sub.n H.sub.2n+1, --C.sub.m H.sub.2m --SO.sub.3 Na, --(CH--R.sup.2).sub.m NHR.sup.2, --(CH--R.sup.2).sub.m OH, --(CH--R.sup.2).sub.m --COOH, --CO--R.sup.5R.sup.4 =--H, --(CH--R.sup.2).sub.m --COOH, --CO--R.sup.5R.sup.5 =--C.sub.m H.sub.2m+1, --C.sub.6 H.sub.5, --(CH--R.sup.2).sub.m --COOH, --C.sub.6 H.sub.4 --COOHn denotes 1-18, m denotes 1-5, x denotes 2-200, y denotes 0 or 1with an ethylenically unsaturated mono or dicarboxylic acid or their anhydride and subsequentlyb) derivatising with a primary or secondary amine and/or alcohol.Type: GrantFiled: October 19, 1995Date of Patent: April 14, 1998Assignee: SKW Trostberg AktiengesellschaftInventors: Konrad Wutz, Josef Weichmann, Alfred Kern, Hans-Gunter Rosenbauer
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Patent number: 5674823Abstract: The present invention relates to novel derivatives of terpene origin which consist of cycloalkenyls or cycloalkyls having at least seven carbon atoms and possessing surfactant and/or fragrant properties. According to one embodiment, the invention relates to compounds of the formula ##STR1## in which p and q are integers or decimal numbers and are not equal to zero, O<P<20, preferably, O<P<5, and O<q<100, preferably 1<q<20. The invention further relates to the surfactant and/or fragrant compositions based on the above-mentioned compounds. The invention has particular applicability in detergent and perfume formulations.Type: GrantFiled: July 3, 1995Date of Patent: October 7, 1997Assignee: Rhone-Poulenc ChimieInventors: Jean-Marc Ricca, Paul-Joel Derian, Jean-Pierre Hecaen, Jean-Michel Mercier
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Copolymers containing hydroxyl and carboxyl groups by reacting glycidyl esters and carboxyl monomers
Patent number: 5663265Abstract: Low-viscosity copolymers useful in coating compositions, containing hydroxyl and carboxyl groups are obtained by free-radical polymerization of A) from 3 to 50% by weight of one or more glycidyl esters of aliphatic saturated monocarboxylic acids having a tertiary or quaternary .alpha. carbon atom, and B) from 97 to 50% by weight of at least two olefinically unsaturated copolymerizable monomers of which at least one contains at least one COOH group and at least one is sterically hindered, the quantity of COOH groups in component B exceeding the quantity of epoxy groups in component A to such an extent that the resulting copolymer has an acid number of at least 15 mg of KOH/g.Type: GrantFiled: April 19, 1995Date of Patent: September 2, 1997Assignee: Hoechst AktiengesellschaftInventors: Ulrich Epple, Uwe Kubillus, Holger Schmidt -
Patent number: 5646240Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.Type: GrantFiled: March 21, 1996Date of Patent: July 8, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Tetsuya Oishi, Jin Suzuki, Kouhei Ohkawa, Hiroshi Ono
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Patent number: 5612445Abstract: The epoxidation of alkyds containing anhydrides or diacids with cycloaliphatic unsaturation results in epoxy resins which cure rapidly in UV light to produce uniform films without the use of flow modifiers. The fatty acid portion of the alkyd functions as an internal plasticizer. Crosslinking occurs through oxirane rings in both the anhydride and fatty acid moieties of the alkyd to produce hard, but not brittle films. Excellent water resistance is obtained without thermal post curing.Type: GrantFiled: February 15, 1995Date of Patent: March 18, 1997Assignee: Arizona Chemical Co.Inventor: Raymond H. Jones
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Patent number: 5552486Abstract: Propoxylated allyl alcohol homopolymers and copolymers of allyl alcohol and propoxylated allyl alcohol are disclosed. The polymers are soluble in many organic solvents, making them useful in a variety of applications, including polyesters, polyurethanes, alkyds, uralkyds, polyamines, acrylates, crosslinked polymeric resins, and polymer blends.Type: GrantFiled: May 25, 1995Date of Patent: September 3, 1996Assignee: ARCO Chemical Technology, L.P.Inventors: Shao-Hua Guo, Robert G. Gastinger
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Patent number: 5539022Abstract: Water-dilutable dispersions of acrylate copolymers having a hydroxyl number of from 40 to 200 mg KOH/g and an acid number of from 15 to 50 mg of KOH/g, obtained by free-radical copolymerization ofa) from 5 to 40 parts by weight of at least one glycidyl ester of an .alpha.-branched aliphatic saturated monocarboxylic acid,b) from 0 to 30 parts by weight of at least one diester of an .alpha.,.beta.-olefinically unsaturated dicarboxylic acid,c) from 0 to 70 parts by weight of at least one vinyl aromatic hydrocarbon, the molar quantity of component c) always being greater than or equal to the molar quantity of component b),d) from 0 to 60 parts by weight of an alkyl ester of an .alpha.,.beta.-olefinically unsaturated carboxylic acid,e) from 2 to 40 parts by weight of at least one .alpha.,.beta.-olefinically unsaturated carboxylic acid, the molar quantity of component e) always being greater than the molar quantity of component a),f) from 5 to 40 parts by weight of at least one hydroxyalkyl ester of an .alpha.,.Type: GrantFiled: April 4, 1994Date of Patent: July 23, 1996Assignee: Hoechst AktiengesellschaftInventors: Holger Schmidt, Tanja R. Brueck, Uwe Kubillus, Harald Oswald, Petra Schaub, Andrea Travers-Hemmer
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Patent number: 5536809Abstract: Disclosed are novel polyether compounds obtained by the reaction or polymerization of 3,4-epoxy-1-butene in the presence of tetrahydrofuran, an acidic catalyst and a nucleophilic initiator compound. The polyether compounds comprise m units of residue (1), n units of residue (2), and p units of residue (3) wherein (i) residues (1), (2) and (3) have the structures: ##STR1## (ii) the total value of m+n+p is 5 to 70; (iii) the value of n/(m+n+p) is in the range of 0.2 to 0.4, i.e.Type: GrantFiled: November 13, 1995Date of Patent: July 16, 1996Assignee: Eastman Chemical CompanyInventors: James C. Matayabas, Jr., Peter B. MacKenzie, John A. Hyatt
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Patent number: 5502137Abstract: Disclosed are novel polyether compounds obtained by the reaction or polymerization of 3,4-epoxy-1-butene in the presence of tetrahydrofuran, an acidic catalyst and a nucleophilic initiator compound. The polyether compounds comprise m units of residue (1), n units of residue (2), and p units of residue (3) wherein (i) residues (1), (2) and (3) have the structures: ##STR1## (ii) the total value of m+n+p is 5 to 70; (iii) the value of n/(m+n+p) is in the range of 0.2 to 0.4, i.e.Type: GrantFiled: November 25, 1994Date of Patent: March 26, 1996Assignee: Eastman Chemical CompanyInventors: James C. Matayabas, Jr., Peter B. MacKenzie, John A. Hyatt
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Patent number: 5496907Abstract: Compounds containing a ureido group which are useful in preparing dispersions of polymers having good wet adhesion properties and low volatility. Compounds having the formula: ##STR1## where R.sup.1 is H or an alkyl group, R.sup.2 is alkylene optionally interrupted with one or more ether oxygen atoms and A is H or a residue of an active hydrogen reactive compound are useful for incorporating ureido and optionally nitrile functionality into polymers and as precursors to amino compounds prepared by reduction of the nitrile group thereof. Compounds having the formula: ##STR2## where B is defined as for A and the same or different than A are also disclosed. The disclosed compounds have use as chain extending or terminating monomers for polyurethane dispersions when one or both of A and B are H and, when one of A and has ethylenic unsaturation, as wet adhesion monomers in dispersions of free radically polymerized polymers of unsaturated monomers.Type: GrantFiled: September 2, 1994Date of Patent: March 5, 1996Assignee: H. B. Fuller Licensing & Financing, Inc.Inventor: Michael J. Dochniak
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Patent number: 5420172Abstract: Cross-linked epoxy resins having nonlinear optical properties may be used in nonlinear optical media. These cross-linked epoxy resins may have the following structure: ##STR1## Z.sup.1 and Z.sup.2 being NLO-chromophores.Type: GrantFiled: August 23, 1993Date of Patent: May 30, 1995Assignee: Siemens AktiengesellschaftInventors: Jens Nordmann, Rainer Puehl