From Hydrocarbon Reactant Patents (Class 528/396)
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Patent number: 6770736Abstract: The present invention relates to a novel polymer as binder for producing activated carbon filters. The polymer of the invention is a polyethylene homopolymer and/or copolymer having a melt flow index (MFI 190/15) of from 1.2 g/10 min to 10 g/10 min, a polydispersity Mw/Mn of from 3 to 30, a bulk density of from 0.05 g/cm3 to 0.5 g/cm3 and a particle size from 5 &mgr;m to 300 &mgr;m.Type: GrantFiled: July 12, 2001Date of Patent: August 3, 2004Assignee: Ticona GmbHInventors: Stanislaw Haftka, Jens Ehlers, Christiane Barth, Louis Wang
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Publication number: 20040116650Abstract: The present invention generally relates to stable emissive aggregates of polymers. The aggregates are composed of various polymer molecules arranged in such a way as to allow extended electronic couplings between nearby polymer molecules, enhancing exciton transport, while minimizing the effects of quenching due to interchain interactions. For example, the polymer molecules may be arranged in a non-aligned, electronically-communicative manner (for example, at an oblique angle), stabilized by various methods such as chemical linkages or physical interactions. Within the aggregate, electronic interactions along the polymer molecule may extend to nearby polymer molecules, which may be observed as a shift in the absorption spectra relative to a random dispersion. Light emitted from the aggregate may be polarized in some cases, for example, linearly or circularly, which may be caused by chiral arrangements of polymers within the aggregate (the polymers themselves may or may not be chiral).Type: ApplicationFiled: July 15, 2003Publication date: June 17, 2004Inventors: Timothy M. Swager, Steffen Zahn
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Method for the processing of a liquid reaction discharge of the cationic polymerization of isobutene
Publication number: 20040092707Abstract: A process for working up a liquid reaction discharge of the cationic polymerization of isobutene, which substantially comprises polyisobutene, unconverted isobutene and an inert diluent, in which the reaction discharge is heated and is let down into a flash container, is described, the reaction discharge separating, as a result of the flashing, into a polyisobutene-containing liquid phase and a gas phase containing the main amount of the isobutene contained in the reaction discharge and of the diluent.Type: ApplicationFiled: October 9, 2003Publication date: May 13, 2004Inventors: Thomas Wettling, Dirk Borchers, Heinz Auer -
Publication number: 20040087676Abstract: The invention provides a film formation method in which a film containing an acene compound can be formed by a liquid-phase process. A film formation method includes: applying light and/or heat to an acene compound to cause a cycloaddition reaction to produce a cyclized compound which is soluble in a solvent, placing a liquid layer containing the cyclized compound and a solvent which can dissolve the cyclized compound on a substrate, and applying light and/or heat to the liquid layer to produce a solid composed of the acene compound.Type: ApplicationFiled: September 12, 2003Publication date: May 6, 2004Applicant: Seiko Epson CorporationInventor: Tomoyuki Okuyama
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Patent number: 6716947Abstract: Disclosed is a method for preparing dimethyl dipropargylmalonate polymer containing exclusively six-membered ring structure by using supercritical or sub-critical carbon dioxide as a solvent with a transition metal chloride catalyst.Type: GrantFiled: October 15, 2002Date of Patent: April 6, 2004Assignee: Korea Institute of Science and TechnologyInventors: Youn-Woo Lee, Hyun-Nam Cho, Jong Sung Lim, Young-Jae Hur
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Publication number: 20040048984Abstract: A polyolefin product is provided which comprises a branched olefin copolymer having an isotactic polypropylene backbone, polyethylene branches and, optionally, one or more comonomers. The total comonomer content of the branched olefin copolymer is from 0 to 20 mole percent. Also, the mass ratio of the isotactic polypropylene to the polyethylene ranges from 99.9:0.1 to 50:50.Type: ApplicationFiled: August 13, 2003Publication date: March 11, 2004Inventors: Weiging Weng, Armen Dekmezian, Eric J. Markel, Avinash Gadkari, Jean-Marc Dekoninck
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Patent number: 6699955Abstract: Ethylene, dienes and optionally &agr;-olefins are copolym-erized by selected iron complexes of 2,6-pyridinecarbox-aldehydebis(imines) and 2,6-diacylpyridinebis(imines). The resulting copolymers contain residual olefinic unsaturation from the diene monomers, and some of these copolymers contain cyclic units in the main chain.Type: GrantFiled: November 14, 2000Date of Patent: March 2, 2004Assignee: E. I. du Pont de Nemours and CompanyInventors: Alison Margaret Anne Bennett, Elizabeth Forrester McCord
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Patent number: 6586563Abstract: Processes for synthesizing borohydride compounds with reduced energy requirements and high efficiency are disclosed. The processes include the reaction of a base with a borane complex or diborane to produce a borohydride compound of formula YBH4, where Y is a monovalent cationic moiety.Type: GrantFiled: December 18, 2001Date of Patent: July 1, 2003Assignee: Millennium Cell, Inc.Inventors: Jeffrey V. Ortega, Ying Wu, Steven C. Amendola, Michael T. Kelly
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Patent number: 6583260Abstract: Functionalized monomers and polymerized functionalized monomers selected from the group consisting of 2-(N,N-dimethylaminomethyl)-1,3-butadiene, 2-(N,N-diethylaminomethyl)-1,3-butadiene, 2-(N,N-di-n-propylaminomethyl)-1,3-butadiene, 2-(cyanomethyl)-1,3-butadiene, 2-(aminomethyl)-1,3-butadiene, 2-(hydroxymethyl)-1,3-butadiene, 2-(carboxymethy)-1,3-butadiene, 2-(acetoxymethyl)-1,3-butadiene, 2-(2-alkoxy-2-oxoethyl)-1,3-butadiene, 2,3-bis(cyanomethyl)-1,3-butadiene, 2,3-bis(dialkylaminomethyl)-1,3-butadiene, 2,3-bis(4-ethoxy-4-4-oxobutyl)-1,3-butadiene and 2,3-bis(3-cyanopropyl)-1,3-butadiene, and methods for preparing such functionalized diene monomers and polymers.Type: GrantFiled: December 7, 2001Date of Patent: June 24, 2003Assignee: Iowa State University Research Foundation, Inc.Inventor: Valerie V. Sheares
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Publication number: 20030114638Abstract: This invention describes a process for covalently coupling organic compounds which comprises reacting an olefinic compound having a halogen or halogen-like substituent at a coupling position with a diboron derivative in the presence of a Group VIII metal catalyst and a suitable base.Type: ApplicationFiled: November 19, 2002Publication date: June 19, 2003Applicant: Commonwealth Scientific and Industrial Research OrganisationInventors: Sebastian Mario Marcuccio, Mary Rodopoulos, Helmut Weigold
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Patent number: 6573412Abstract: The invention provides chain-coupled polymeric alkoxide compounds for use as the elastomeric component in vulcanizable elastomeric compositions comprising silica, carbon black or mixtures thereof. In particular, the invention provides anionically polymerized polymers having polymer chain living ends that are functionalized with alkoxide groups and coupled together by a metal or nonmetal atom. The polymeric alkoxide compounds have an initial high viscosity for ease of handling prior to compounding, a stable viscosity during storage, and a decreased compound viscosity for better filler dispersion and improved mixing efficiency. The invention further provides a pneumatic tire having at least one component produced from the vulcanizable elastomeric composition of the invention.Type: GrantFiled: May 12, 2000Date of Patent: June 3, 2003Assignee: Bridgestone CorporationInventors: Terrence E. Hogan, William L. Hergenrother, James E. Hall
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Patent number: 6552101Abstract: A precursor polymer that can be electrochemically polymerized to form an electrically conducting polymer. A precursor according to the present invention includes a plurality of electrochemical polymerizable monomers, each monomer having first and second polymer-forming active sites that can be joined by electrochemical polymerization. The monomers also include third and fourth polymer-forming active sites that can be joined chemically in solution. The monomers in the precursor polymer are linked by the third and fourth polymer-forming active sites. The monomers are chosen such the precursor polymer is soluble in a predetermined solvent while the polymer resulting from the electrochemical polymerization of the precursor polymers via the first and second polymer-forming sites is electrically conducting and insoluble in the solvent. The monomers can be synthesized from fluorene, triophene, pyrrol, biphenyl, poly(vinyl carbazole) or poly (vinyl oxy thiophene).Type: GrantFiled: September 22, 1999Date of Patent: April 22, 2003Assignee: Agilent Technologies, Inc.Inventors: Daniel B. Roitman, Seiji Inaoka, Riogoberto C. Advincula
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Patent number: 6547985Abstract: A 2-cyanoacrylate composition useful as an adhesive contains a Lewis acid metal salt which comprises a specific metal such as aluminum, gallium, indium or thallium, and the conjugate base of an acid having oxygen such as a monohalo-, dihalo or trihaloacetate, wherein the metal is bonded to the conjugate base through an oxygen atom, and a compound having clathrating ability such as a crown ether.Type: GrantFiled: April 7, 2000Date of Patent: April 15, 2003Assignee: Togosei Co., Ltd.Inventors: Seitaro Tajima, Mitsuyoshi Sato
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Publication number: 20020161173Abstract: a composition for film formation which can be cured in a short time period and give a film having a low dielectric constant and excellent in heat resistance, adhesion and cracking resistance, a polymer for use in the composition and a process for producing the polymer. The composition prepared by dissolving the polymer having specific repeating units in a solvent has excellent film-forming properties.Type: ApplicationFiled: April 24, 2002Publication date: October 31, 2002Applicant: JSR CORPORATIONInventors: Takashi Okada, Noriyasu Sinohara, Kaori Shirato, Masahiko Ebisawa, Michinori Nishikawa, Kinji Yamada
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Patent number: 6440321Abstract: A fluorochemical composition to impart water repellency and/or oil repellency to a substrate, the composition comprising one or more condensates of (i) a methylolated amine or a C1-C4 alkoxylated derivative thereof, (ii) a hydrocarbon compound represented by formula (II) and (iii) a fluorinated compound represented by formula (I): Rf—(X1)n—Z1 (I) wherein: Rf is a fluorinated aliphatic group; X1 is an organic divalent linking group; Z1 is selected from the group consisting of hydroxy, thiol, amide or acid groups; and n is 0 or 1; and Rh—Z2 (II) wherein: Rh is a hydrocarbon group having at least 6 carbon atoms and optionally being substituted with 1 to 3 subsituents; Z2 is selected from the group consisting of hydroxy, thiol, amide or acid groups. The invention further provides a method of treatment of a substrate with the fluorochemical composition and a treated substrate.Type: GrantFiled: September 17, 1999Date of Patent: August 27, 2002Assignee: 3M Innovative Properties CompanyInventors: Frans A. Audenaert, Dirk M. Coppens, Rudolf J. Dams
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Patent number: 6433129Abstract: The present invention relates to compositions and processes for producing borohydride compounds. In particular, the present invention provides efficient processes and compositions for the large-scale production of borohydride compounds.Type: GrantFiled: November 8, 2000Date of Patent: August 13, 2002Assignee: Millennium Cell, Inc.Inventors: Steven C. Amendola, Michael T. Kelly
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Patent number: 6344538Abstract: Functionalized monomers and polymerized functionalized monomers selected from the group consisting of 2-(N,N-dimethylaminomethyl)-1,3-butadiene, 2-(N,N-diethylaminomethyl)-1,3-butadiene, 2-(N,N-di-n-propylaminomethyl)-1,3-butadiene, 2-(cyanomethyl)-1,3-butadiene, 2-(aminomethyl)-1,3-butadiene, 2-(hydroxymethyl)-1,3-butadiene, 2-(carboxymethy)-1,3-butadiene, 2-(acetoxymethyl)-1,3-butadiene, 2-(2-alkoxy-2-oxoethyl)-1,3-butadiene, 2,3-bis(cyanomethyl)-1,3-butadiene, 2,3-bis(dialkylaminomethyl)-1,3-butadiene, 2,3-bis(4-ethoxy-4-4-oxobutyl)-1,3-butadiene and 2,3-bis(3-cyanopropyl)-1,3-butadiene, and methods for preparing such functionalized diene monomers and polymers.Type: GrantFiled: May 2, 2000Date of Patent: February 5, 2002Assignee: Iowa State University Research Foundation, Inc.Inventor: Valerie V. Sheares
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Publication number: 20020007043Abstract: A process for the manufacture of polytrimethylene ether glycol comprising the steps of: (a) providing (1) 1,3-propanediol reactant selected from the group consisting of 1,3-propanediol and/or oligomers or prepolymers of 1,3-propanediol having a degree of polymerization of 2-9 and mixtures thereof, and (2) a polycondensation catalyst; and (b) polycondensing the 1,3-propanediol reactant to form a polytrimethylene ether glycol at less than one atmosphere pressure, and the product of the process. In addition, polytrimethylene ether glycol has a number average molecular weight greater than 1,500, an APHA color of less than 120, an unsaturation of less than 20 meq/kg, and a content of cyclic ether oligomers of less than 2%.Type: ApplicationFiled: December 15, 2000Publication date: January 17, 2002Inventors: Hari B. Sunkara, Leo E. Manzer
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Patent number: 6294245Abstract: A method for depositing an electrically conducting film on an electrode and the film resulting from that method. An electrically conducting film according to the present invention is deposited by immersing the electrode in a solution of a precursor polymer in a predetermined solvent. The precursor polymer includes a plurality of electrochemical polymerizable monomers. Each monomer has first and second polymer-forming active sites that can be joined by electrochemical polymerization and third and fourth polymer-forming active sites that can be joined chemically in solution. The precursor polymer is constructed from the monomers joined by the third and fourth polymer-forming active sites. The precursor polymer is soluble in the solvent whereas a polymer formed by electrochemical polymerization of the first and second polymer-forming active sites is insoluble in the solvent.Type: GrantFiled: September 22, 1999Date of Patent: September 25, 2001Assignee: Agilent Technologies, Inc.Inventors: Daniel B. Roitman, Seiji Inaoka, Riogoberto C. Advincula
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Patent number: 6193909Abstract: Cross-linked electrically conductive polymers, in particular electrically conductive, polyaniline are described. Dopants and substituents having pendant cross-linkable functionality are used which form a cross-linked conducting polymer network. The cross-linking functionality can be hydrogen-bonding as well as chemically polymerizable or cross-linkable. A conjugated path between chains can also be incorporated. The resulting cross-linked conducting polymers have enhanced thermal and environmental stability. The dopant cannot readily be washed out with solvents or diffuse out upon exposure to heat. In addition, the cross-linked polymers have enhanced electrical conductivity.Type: GrantFiled: February 2, 1996Date of Patent: February 27, 2001Assignee: International Business Machines CorporationInventors: Marie Angelopoulos, Jeffrey D. Gelorme, Yun Hsin Liao, Jane M. Shaw
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Patent number: 6156872Abstract: The invention is related to non-linear, paraffin-soluble olefin/carbon monoxide and olefin/acetylene/carbon monoxide copolymers. The invention is also related to a method for preparing olefin/carbon monoxide copolymers by heating a feed of at least one olefin, carbon monoxide, carbon dioxide, hydrogen, and methane in the presence of a free radical polymerization initiator. More particularly, the feed comprises at least one olefin, the total olefin amount ranging from about 5 to about 40 mole %, carbon monoxide in an amount ranging from about 1 to about 40 mole %, hydrogen in an amount ranging from about 4 to about 55 mole %, carbon dioxide in an amount ranging from about 3 to about 10 mole %, and methane in an amount ranging from about 4 to about 85 mole %. The feed may also include acetylene in an amount ranging up to about mole %.Type: GrantFiled: January 19, 1999Date of Patent: December 5, 2000Assignee: Exxon Research and Engineering Co.Inventors: Abhimanyu O. Patil, Donald N. Schulz, Raymond A. Cook, Michael G. Matturro
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Patent number: 6127516Abstract: The oxidation of 7,14-diphenylacenaphtho[1,2-.kappa.]fluoranthene (1) at platinum or indium tin-oxide electrodes leads to deposition of a polymer film on the electrode surface that displays many interesting properties including electroactivity, fluorescence, and electrochromism. Thin films of this polymer appear deep blue in the neutral state, but become pale grey upon oxidation and light green or orange upon reduction, depending upon the voltage applied. Soluble oligomers of poly(3,10-(7,14-diphenylacenaphtho[1,2-.kappa.]fluoranthene)) are formed during oxidation of the monomer (1) via radical cation-radical cation coupling reactions and are identical to those chemically synthesized by the Ni(0)-catalyzed coupling of the 3,10-dibromo derivative of 1. Further oxidation of these oligomers leads to intramolecular coupling reactions to form ladder structures within the chains and the eventual precipitation of insoluble polymer onto the electrode.Type: GrantFiled: December 30, 1998Date of Patent: October 3, 2000Assignee: Board of Regents, The University of Texas SystemInventors: Allen J. Bard, Jeff D. Debad
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Patent number: 6126867Abstract: The invention relates to nonlinear-optically active copolymers, to crosslinked NLO polymer materials produced from them and having high orientation stability, and to electrooptical and photonic components comprising these polymer materials. The copolymers of the invention are of the general formula 1 ##STR1## in which W is preferably a chromophoric group of the general formula 2: ##STR2## The chromophores employed in accordance with the invention exhibit high thermal stability and so can be processed at elevated temperatures while retaining the optical activity.Type: GrantFiled: March 9, 1999Date of Patent: October 3, 2000Assignee: Siemens AktiengesellschaftInventors: Andreas Kanitz, Christian Fricke
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Patent number: 6080835Abstract: A functionialized polymer according to the invention includes a polymer molecule having the general formula AYLi where A is a cyclic amine-containing radical having the general formula ##STR1## wherein R.sub.1 is a divalent alkylene, an oxy- or amino-alkylene, or substituted alkylene having from 6 to about 20 carbon atoms; R.sub.2 is a linear-, branched-, or cyclo-alkylene having from about 2 to about 20 carbon atoms; and Y is a divalent polymer radical and Li is a lithium atom bonded to a carbon atom of Y.Type: GrantFiled: September 24, 1997Date of Patent: June 27, 2000Assignee: Bridgestone CorporationInventors: David F. Lawson, Thomas A. Antkowiak, James E. Hall, Mark L. Stayer, Jr., John R. Schreffler
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Patent number: 6030550Abstract: Cross-linked electrically conductive polymers, in particular electrically conductive, polyaniline are described. Dopants and substituents having pendant cross-linkable functionality are used which form a cross-linked conducting polymer network. The cross-linking functionality can be hydrogen-bonding as well as chemically polymerizable or cross-linkable. A conjugated path between chains can also be incorporated. The resulting cross-linked conducting polymers have enhanced thermal and environmental stability. The dopant cannot readily be washed out with solvents or diffuse out upon exposure to heat. In addition, the cross-linked polymers have enhanced electrical conductivity.Type: GrantFiled: February 2, 1996Date of Patent: February 29, 2000Assignee: International Business Machines CorporationInventors: Marie Angelopoulos, Jeffrey D. Gelorme, Yun Hsin Liao, Jane M. Shaw
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Patent number: 6030668Abstract: Compounds of formula ##STR1## are provided which may be used in a variety of devices including liquid crystal devices, piezoelectric devices, pyroelectric devices and in optical recording media, where m=at least 5; and R.sub.x, R.sub.y and R.sub.z are independently from formula (IA), ##STR2## where Y is selected from COO, OCO, O, S, CHOH, CHF, CH.sub.2 ; Q=(CH.sub.2).sub.n wherein one or more non-adjacent methylenes may be replaced by O and n=1-20; Z is selected from O, S, a single covalent bond, COO, a OCO; when Y is CH.sub.2 then n may also be 0; formula (IB) is ##STR3## and represents any mesogenic group; and R.sub.x, R.sub.y and R.sub.z are also independently selected from H, OH, OCOR.sup.1, COOH, CO.sub.2 R.sup.1 (CH.sub.2).sub.p OH, (CH.sub.2).sub.p CO.sub.2 H, --(CH.sub.2).sub.p OR.sup.1 or --(CH.sub.2).sub.p CO.sub.2 R.sup.1 and p=1-20, R.sup.1 =H or C.sub.1-16 alkyl, when R.sup.1 =C.sub.2-16 alkyl the terminal CH.sub.3 group may be replaced by Br or Cl; provided that at least one of and R.sub.x, R.Type: GrantFiled: May 26, 1998Date of Patent: February 29, 2000Assignee: The Secretary of State for Defence, in Her Britannic Majesty's Government of the United Kingdom of Great Britain and Northern IrelandInventors: Alan W Hall, David Lacey, Ian C Sage, Keith M Blackwood, Michelle Jones
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Patent number: 5968411Abstract: Liquid crystal polymer materials used in liquid crystal devices, piezoelectric devices, pyroelectric devices and recording media are described.Type: GrantFiled: April 29, 1998Date of Patent: October 19, 1999Assignee: The Secretary of State for Defence in Her Britannic Majesty's Government of the United Kingdom of Great Britain and Northern IrelandInventors: Alan William Hall, David Lacey, Ian Charles Sage, Keith Moray Blackwood, Michelle Jones
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Patent number: 5925494Abstract: The invention provides a method for vapor-depositing a polymer film having constituents that are synthesized during the deposition and that can therefore be customized by time-dependent process control during the deposition. In the vapor-deposition process, a hydrocarbon precursor is reacted with an oxygen-containing precursor in a plasma environment. The plasma reaction synthesizes O--H bonds and forms a polymer having O--H bonds, C--C bonds, and C--H.sub.x bonds. Preferably, the hydrocarbon and oxygen-containing precursors are employed in a ratio selected such that the resulting polymer film has a selected level of oxygen constituency providing a corresponding selected ratio of O--H bond concentration to C--H.sub.x bond concentration. The precursor ratio is preferably varied as a function of time during the plasma reaction to result in a corresponding distribution, e.g., a depth-dependent distribution, of O--H bonds in the film.Type: GrantFiled: February 16, 1996Date of Patent: July 20, 1999Assignee: Massachusetts Institute of TechnologyInventor: Mark W. Horn
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Patent number: 5904990Abstract: Until recently, conducting polymers have been used as protective coatings. lthough these types of polymers appear to be effective in most cases, problems have resulted when attempting to bind these polymers to an aluminum surface. The polymers of this invention adhere extremely well to aluminum and aluminum alloys and thus, provide a very effective form of corrosion protection.Type: GrantFiled: March 13, 1998Date of Patent: May 18, 1999Assignee: The United States of America as represented by the Secretary of the NavyInventors: John D. Stenger-Smith, Melvin H. Miles, William P. Norris, John Nelson, Peter Zarras, John W. Fischer, Andrew P. Chafin
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Patent number: 5807970Abstract: Formulations including a high density polyester and a density reducing component. The formulations are useful for facilitating the separation of blood serum or plasma from the cellular portion of blood in blood collection applications.Type: GrantFiled: April 29, 1997Date of Patent: September 15, 1998Assignee: Becton, Dickinson and CompanyInventor: Rhyta S. Rounds
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Patent number: 5804100Abstract: Deaggregated substituted and unsubstituted polyparaphenylenes, polyparaphenylevevinyles, polyanilines, polyazines, polythiophenes, poly-p-phenylene sulfides, polyfuranes, polypyrroles, polyselenophene, polyacetylenes formed from soluble precursors and combinations thereof and copolymers thereof and methods of fabrication are described. The deaggregated polymer molecules when subsequently doped show higher electrical conductivity. Agents such as lithium chloride, m-cresol and nonylphenol are used to deaggregate the polymer molecules. The deaggregating agents can be added prior to or during doping the molecules.Type: GrantFiled: January 9, 1995Date of Patent: September 8, 1998Assignee: International Business Machines CorporationInventors: Marie Angelopoulos, Bruce K. Furman
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Patent number: 5756653Abstract: A novel zerovalent zinc species and an organozinc reagent are disclosed. The zerovalent zinc species is directly produced by reaction of a reducing agent on a zinc salt, preferably Zn(CN).sub.2. The organozinc reagent results from the reaction of the zerovalent zinc species and an organic compound having one or more stable anionic leaving groups. These organozinc reagents include a wide spectrum of functional groups in the organic radical, and are useful in a variety of reactions schemes.Type: GrantFiled: May 2, 1995Date of Patent: May 26, 1998Assignee: Board of Regents of the University of NebraskaInventor: Reuben D. Rieke
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Patent number: 5750585Abstract: A water swellable foam matrix formed as a macroporous solid comprising a foam stabilizing agent and a polymer or copolymer of a free radical polymerizable hydrophilic olefin monomer crosslinked with about 0.1 to about 10% by weight of a multiolefin-functional crosslinking agent is described. The foam matrix is characterized by rapid swelling and high water swelling ratios.Type: GrantFiled: April 4, 1995Date of Patent: May 12, 1998Assignee: Purdue Research FoundationInventors: Kinam Park, Haesun Park
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Patent number: 5684123Abstract: A process for the preparation of a solution of a catalyst system, suitable for use in a process for copolymerizing carbon monoxide and one or more ethylenically unsaturated compounds, which comprises (a) combining a palladium compound, a bisphosphine of the general formula R.sup.1 R.sup.2 P--R--PR.sup.3 R.sup.4 (I) wherein each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently represents an aromatic hydrocarbyl group which is substituted with an alkoxy group and R represents a bivalent bridging group containing at least two carbon atoms in the bridge, and a lower alcohol as solvent, and (b) admixing the obtained combination after a generation period G, during which a temperature T in the range of 0.degree.-70.degree. C. is maintained, with an acid having a pKa of less than 2, whereby the said generation period G is selected such that the value for G (in hours) and the temperature T in .degree.C.Type: GrantFiled: January 15, 1997Date of Patent: November 4, 1997Assignee: Shell Oil CompanyInventors: Frits Van Der Veer, Rudolf Jacobus Wijngaarden
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Patent number: 5679760Abstract: The present invention relates to polymers with an extended system of conjugated double bonds constructed as homo and/or heterocyclic rings which are interlinked in pairs so that one ring is joined to the neighboring one at two adjacent atoms in the ring, in which one of these connections is made by a chemical bond to a ring atom of the neighboring ring and the other via a carbon, nitrogen, oxygen or sulphur atom to an atom of the neighboring ring adjacent said ring atom, their production and use in electrical, electronic and opto-electronic components.Type: GrantFiled: March 21, 1995Date of Patent: October 21, 1997Assignee: Hoechst AktiengesellschaftInventors: Klaus Mullen, Ullrich Scherf
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Patent number: 5663285Abstract: Formulations including a high density polyester and a density reducing component. The formulations are useful for facilitating the separation of blood serum or plasma from the cellular portion of blood in blood collection applications.Type: GrantFiled: August 16, 1996Date of Patent: September 2, 1997Assignee: Becton Dickinson and CompanyInventor: Rhyta S. Rounds
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Patent number: 5604292Abstract: Novel conjugated amino substituted phenylene polymers are disclosed having on-linear optical properties, and which can be converted to electrically conductive polymers. Such polymers are produced by reacting a novel bis-cycloalkylene sulfonium salt of 2,5,N,N-tetramethylaniline hydrochloride, such as 2,5-(N,N-dimethyl)aniline hydrochloride dimethylene bis-(tetramethylene sulfonium chloride) with alkali metal hydroxide to form a cycloalkylene sulfonium salt precursor polymer, and then heating the precursor polymer under conditions to produce the amino substituted phenylene vinylene polymer, such as poly(2-(N,N-dimethylamino) phenylene vinylene). The polymers can also be made directly by treatment of the bis chlormethyl dimethyl aniline hydrochloride derivative with alkali metal alkoxide.Type: GrantFiled: May 31, 1994Date of Patent: February 18, 1997Assignee: The Untied States of America as represented by the Secretary of the NavyInventors: John D. Stenger-Smith, William P. Norris, Andrew P. Chafin, Scott T. Sackinger
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Patent number: 5578699Abstract: A process for synthesizing novel conjugated amino substituted phenylene pmers is disclosed. The process results in polymers having non-linear optical properties, and the polymers can be converted to electrically conductive polymers. The process involves reacting a novel bis-cycloalkylene sulfonium salt of 2,5,N,N-tetramethylaniline hydrochloride, such as 2,5-(N,N-dimethyl)aniline hydrochloride dimethylene bis-(tetramethylene sulfonium chloride) with alkali metal hydroxide to form a cycloalkylene sulfonium salt precursor polymer, and then heating the precursor polymer under conditions to produce the amino substituted phenylene vinylene polymer, such as poly(2-(N,N-dimethylamino) phenylene vinylene). Another process involves treatment of the bis chlormethyl dimethyl aniline hydrochloride derivative with alkali metal alkoxide.Type: GrantFiled: May 18, 1995Date of Patent: November 26, 1996Assignee: The United States of America as represented by the Secretary of the NavyInventors: John D. Stenger-Smith, William P. Norris, Andrew P. Chafin, Scott T. Sackinger
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Patent number: 5565543Abstract: High-performance polymers having a rigid-rod backbone comprising a chain length of at least 25 organic monomer units joined together by covalent bonds wherein at least about 95% of the bonds are substantially parallel; and solubilizing organic groups attached to at least 1% of the monomer units. The polymers are prepared in a solvent system which is a solvent for both the monomer starting materials and the rigid-rod polymer product.Type: GrantFiled: August 11, 1994Date of Patent: October 15, 1996Assignee: Maxdem IncorporatedInventors: Matthew L. Marrocco, III, Robert R. Gagne, Mark S. Trimmer
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Patent number: 5484883Abstract: Poly(phenylene) that is substantially free of insoluble material is prepared by the polymerization of a lithioarylhalide compound in the presence of a polar aprotic compound such as hexamethylphosphoramide, N,N,N',N'-tetramethylethylenediamine or hexamethylphosphorous triamide. The preferred reaction involves the polymerization of 1-bromo-4-lithiobenzene in the presence of hexamethylphosphoramide. The 1-bromo-4-1ithiobenzene may be synthesized by reacting 1,4-dibromobenzene with t-butyllithium. These same types of reactions can also be used to synthesis other benzenoid polymers.Type: GrantFiled: August 16, 1994Date of Patent: January 16, 1996Assignee: University of South CarolinaInventors: James M. Tour, Eric B. Stephens
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Patent number: 5401827Abstract: A semiconductive conjugated copolymer comprises at least two chemically different monomer units which, when existing in their individual homopolymer forms, have different semiconductor bandgaps. The proportion of said at least two chemically different monomer units in the copolymer is selected to control the semiconductor bandgap of the copolymer so as to control the optical properties of the copolymer. The copolymer is formed in a manner enabling it to be laid down as a film without substantially affecting the luminescent characteristics of the copolymer and is stable at operational temperature.The semiconductor bandgap may be spatially modulated so as to increase the quantum efficiency of the copolymer when excited to luminesce, to select the wavelength of radiation omitted during luminescence or to select the refractive index of the copolymer.Type: GrantFiled: August 22, 1991Date of Patent: March 28, 1995Assignee: Cambridge Display Technology LimitedInventors: Andrew Holmes, Donal D. Bradley, Richard H. Friend, Arno Kraft, Paul Burn, Adam Brown
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Patent number: 5374681Abstract: Polyacetals useful as reduced-phosphate or phosphate-free detergent and cleaner additives are obtainable by cationically initiated polyaddition of(a) divinyl ethers and(b) dihydroxy compounds and also, optionally,(c) monohydroxy compoundsand have K values of from 8 to 100.Type: GrantFiled: January 5, 1994Date of Patent: December 20, 1994Assignee: BASF AktiengesellschaftInventors: Matthias Kroner, Heinrich Hartmann, Richard Baur, Volker Schwendemann, Hans-Ulrich Jaeger, Johannes Perner
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Patent number: 5354929Abstract: The invention is a bis-BCB compound of the structure: ##STR1## a method for making same and polymers made therefrom. The novel compounds of this invention are useful in preparing polymers that can form thin film coatings for multichip midules (MCMs) and integrated circuits (ICs). These compounds can be isolated as liquids at room temperature, and can form polymers that are hydrophobic and have low dielectrical and dissipative properties.Type: GrantFiled: September 28, 1993Date of Patent: October 11, 1994Assignee: The Dow Chemical CompanyInventors: Robert A. Kirchhoff, P. J. Thomas, R. Garth Pews
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Patent number: 5310858Abstract: The invention relates to a process for preparing compounds of the formula (I) ##STR1## by pyrolysis, where n is the degree of polymerization and is.gtoreq.2. For this purposes compounds of the formula (II)--R--CO--O--CH.sub.2 --Ar--CH.sub.2 --O--CO--R (II)are pyrolyzed in one stage under conditions resulting in cleavage of the ester bonds under a partial pressure of the esters of p.ltoreq.10 mbar at temperatures T.gtoreq.500.degree. C., with the formation of the corresponding derivatives of 1,4-dimethylene-2,5-cyclohexadiene, but without the latter being cleaved further in subsequent reactions. The polymers of p-xylylene formed by spontaneous polycondensation of the derivatives of 1,4-dimethylene-2,5-cyclohexadiene were then cooled, Ar and R have the following meanings:--Ar-- is a 1,4-phenylene radical or another C.sub.6 -C.sub.12 aromatic or heteroaromatic radical in which the bonds are in the para position or a comparable coaxial or antiparallel position;R-- is preferably branched or unbranched C.sub.1 -C.Type: GrantFiled: January 28, 1993Date of Patent: May 10, 1994Assignee: Hoechst AktiengesellschaftInventors: Andreas Greiner, Peter Simon
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Patent number: 5281644Abstract: There are disclosed methods and compositions for retarding the ambient temperature hardening of a phenolic resole resin alone or with an aggregate when such resin is contacted with a nitroalkane and a hardening agent such as lightburned magnesium oxide, an organic ester functional hardening agent, and mixtures of lightburned magnesium oxide and an organic ester functional hardening agent in an alkaline medium. There is also disclosed a hardener composition for phenolic resole resins wherein the hardener composition consists essentially of a solution of a nitroalkane in an organic ester functional hardening agent.Type: GrantFiled: November 4, 1992Date of Patent: January 25, 1994Assignee: Borden, Inc.Inventors: S. Raja Iyer, David R. Armbruster, Arthur H. Gerber
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Patent number: 5247054Abstract: An organic polymer ferromagnetic material characterized in that the material comprises a polymer obtained by subjecting to plasma polymerization or oxidation polymerization a methane derivative having two substituents and represented by the formula ##STR1## wherein A is an electron accepting group, and B is an electron donating group, or by copolymerizing the methane derivative with a diarylmethane derivative represented by the formula ##STR2## wherein R.sup.1 is a substituted or unsubstituted phenyl group by plasma polymerization or oxidation polymerization.Type: GrantFiled: August 1, 1990Date of Patent: September 21, 1993Assignee: Otsuka Kagaku Kabushiki KaishaInventors: Hitoshi Tanaka, Tsuneyuki Sato, Todatoshi Ota, deceased, Michio Sasaoka
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Patent number: 5241044Abstract: A process for preparing poly(p-phenylene)s comprises reacting dihydroxy aromatic compounds such as orthoquinone and bisphenols with halogen-substituted aliphatic sulfonic acids, halogen sulfonic acid, or their anhydrides. The monomers thus formed are subsequently polymerized with Ni(0) catalysts to yield the desired polymers. The monomers or polymers may be functionalized with reactive groups.Type: GrantFiled: March 20, 1992Date of Patent: August 31, 1993Assignee: Edison Polymer Innovation CorporationInventor: Virgil Percec
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Patent number: 5124240Abstract: An optical recording medium consists essentially of a base material and a light-absorbing layer which contains a thermoplastic binder and at least one dye, wherein the thermoplastic binder is a polycyclic hydrocarbon which has a glass transition temperature Tg of greater than 150.degree. C. and is soluble to more than 3% by weight in an aliphatic or aromatic hydrocarbon.Type: GrantFiled: March 16, 1990Date of Patent: June 23, 1992Inventors: Sibylle Brosius, Bernhard Albert, Michael Schmitt, Klaus D. Schomann, Harald Kuppelmaier, Ulrich Harten
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Patent number: 5095057Abstract: A new class of compounds, is disclosed, defined by the formula:R'.sub.2 N(CH.sub.2 CH.sub.2 NR").sub.y Rwhere R, R' and R" are equal or different and are ##STR1## wherein x is bromine or chlorine, n is an integer from 3 to 5 inclusive and y is an integer equal to or greater than 1.The compounds of the invention are useful as fire retardant agents.Type: GrantFiled: December 15, 1989Date of Patent: March 10, 1992Assignee: Bromine Compounds LimitedInventors: Leonard M. Shorr, Many Ravey
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Patent number: 5066779Abstract: The present invention discloses a process for producing a raw material pitch for carbon materials containing a slight amount of ash, the comprising steps of adding aluminum chloride to naphthalene or its derivative as a catalyst; polymerizing said naphthalene or its derivative at a temperature of 100.degree. to 330.degree. C., adding water to the polymer, under stirring if necessary; maintaining the mixture in an emulsified state for a predetermined time under stirring, breaking an emulsion, removing a water layer from the polymer.Type: GrantFiled: January 30, 1990Date of Patent: November 19, 1991Assignee: Kureha Kagaku Kogyo Kabushiki KaishaInventors: Ikuo Seo, Tooru Oono, Yosinobu Murakami