From Hydrocarbon Reactant Patents (Class 528/396)
  • Patent number: 6770736
    Abstract: The present invention relates to a novel polymer as binder for producing activated carbon filters. The polymer of the invention is a polyethylene homopolymer and/or copolymer having a melt flow index (MFI 190/15) of from 1.2 g/10 min to 10 g/10 min, a polydispersity Mw/Mn of from 3 to 30, a bulk density of from 0.05 g/cm3 to 0.5 g/cm3 and a particle size from 5 &mgr;m to 300 &mgr;m.
    Type: Grant
    Filed: July 12, 2001
    Date of Patent: August 3, 2004
    Assignee: Ticona GmbH
    Inventors: Stanislaw Haftka, Jens Ehlers, Christiane Barth, Louis Wang
  • Publication number: 20040116650
    Abstract: The present invention generally relates to stable emissive aggregates of polymers. The aggregates are composed of various polymer molecules arranged in such a way as to allow extended electronic couplings between nearby polymer molecules, enhancing exciton transport, while minimizing the effects of quenching due to interchain interactions. For example, the polymer molecules may be arranged in a non-aligned, electronically-communicative manner (for example, at an oblique angle), stabilized by various methods such as chemical linkages or physical interactions. Within the aggregate, electronic interactions along the polymer molecule may extend to nearby polymer molecules, which may be observed as a shift in the absorption spectra relative to a random dispersion. Light emitted from the aggregate may be polarized in some cases, for example, linearly or circularly, which may be caused by chiral arrangements of polymers within the aggregate (the polymers themselves may or may not be chiral).
    Type: Application
    Filed: July 15, 2003
    Publication date: June 17, 2004
    Inventors: Timothy M. Swager, Steffen Zahn
  • Publication number: 20040092707
    Abstract: A process for working up a liquid reaction discharge of the cationic polymerization of isobutene, which substantially comprises polyisobutene, unconverted isobutene and an inert diluent, in which the reaction discharge is heated and is let down into a flash container, is described, the reaction discharge separating, as a result of the flashing, into a polyisobutene-containing liquid phase and a gas phase containing the main amount of the isobutene contained in the reaction discharge and of the diluent.
    Type: Application
    Filed: October 9, 2003
    Publication date: May 13, 2004
    Inventors: Thomas Wettling, Dirk Borchers, Heinz Auer
  • Publication number: 20040087676
    Abstract: The invention provides a film formation method in which a film containing an acene compound can be formed by a liquid-phase process. A film formation method includes: applying light and/or heat to an acene compound to cause a cycloaddition reaction to produce a cyclized compound which is soluble in a solvent, placing a liquid layer containing the cyclized compound and a solvent which can dissolve the cyclized compound on a substrate, and applying light and/or heat to the liquid layer to produce a solid composed of the acene compound.
    Type: Application
    Filed: September 12, 2003
    Publication date: May 6, 2004
    Applicant: Seiko Epson Corporation
    Inventor: Tomoyuki Okuyama
  • Patent number: 6716947
    Abstract: Disclosed is a method for preparing dimethyl dipropargylmalonate polymer containing exclusively six-membered ring structure by using supercritical or sub-critical carbon dioxide as a solvent with a transition metal chloride catalyst.
    Type: Grant
    Filed: October 15, 2002
    Date of Patent: April 6, 2004
    Assignee: Korea Institute of Science and Technology
    Inventors: Youn-Woo Lee, Hyun-Nam Cho, Jong Sung Lim, Young-Jae Hur
  • Publication number: 20040048984
    Abstract: A polyolefin product is provided which comprises a branched olefin copolymer having an isotactic polypropylene backbone, polyethylene branches and, optionally, one or more comonomers. The total comonomer content of the branched olefin copolymer is from 0 to 20 mole percent. Also, the mass ratio of the isotactic polypropylene to the polyethylene ranges from 99.9:0.1 to 50:50.
    Type: Application
    Filed: August 13, 2003
    Publication date: March 11, 2004
    Inventors: Weiging Weng, Armen Dekmezian, Eric J. Markel, Avinash Gadkari, Jean-Marc Dekoninck
  • Patent number: 6699955
    Abstract: Ethylene, dienes and optionally &agr;-olefins are copolym-erized by selected iron complexes of 2,6-pyridinecarbox-aldehydebis(imines) and 2,6-diacylpyridinebis(imines). The resulting copolymers contain residual olefinic unsaturation from the diene monomers, and some of these copolymers contain cyclic units in the main chain.
    Type: Grant
    Filed: November 14, 2000
    Date of Patent: March 2, 2004
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Alison Margaret Anne Bennett, Elizabeth Forrester McCord
  • Patent number: 6586563
    Abstract: Processes for synthesizing borohydride compounds with reduced energy requirements and high efficiency are disclosed. The processes include the reaction of a base with a borane complex or diborane to produce a borohydride compound of formula YBH4, where Y is a monovalent cationic moiety.
    Type: Grant
    Filed: December 18, 2001
    Date of Patent: July 1, 2003
    Assignee: Millennium Cell, Inc.
    Inventors: Jeffrey V. Ortega, Ying Wu, Steven C. Amendola, Michael T. Kelly
  • Patent number: 6583260
    Abstract: Functionalized monomers and polymerized functionalized monomers selected from the group consisting of 2-(N,N-dimethylaminomethyl)-1,3-butadiene, 2-(N,N-diethylaminomethyl)-1,3-butadiene, 2-(N,N-di-n-propylaminomethyl)-1,3-butadiene, 2-(cyanomethyl)-1,3-butadiene, 2-(aminomethyl)-1,3-butadiene, 2-(hydroxymethyl)-1,3-butadiene, 2-(carboxymethy)-1,3-butadiene, 2-(acetoxymethyl)-1,3-butadiene, 2-(2-alkoxy-2-oxoethyl)-1,3-butadiene, 2,3-bis(cyanomethyl)-1,3-butadiene, 2,3-bis(dialkylaminomethyl)-1,3-butadiene, 2,3-bis(4-ethoxy-4-4-oxobutyl)-1,3-butadiene and 2,3-bis(3-cyanopropyl)-1,3-butadiene, and methods for preparing such functionalized diene monomers and polymers.
    Type: Grant
    Filed: December 7, 2001
    Date of Patent: June 24, 2003
    Assignee: Iowa State University Research Foundation, Inc.
    Inventor: Valerie V. Sheares
  • Publication number: 20030114638
    Abstract: This invention describes a process for covalently coupling organic compounds which comprises reacting an olefinic compound having a halogen or halogen-like substituent at a coupling position with a diboron derivative in the presence of a Group VIII metal catalyst and a suitable base.
    Type: Application
    Filed: November 19, 2002
    Publication date: June 19, 2003
    Applicant: Commonwealth Scientific and Industrial Research Organisation
    Inventors: Sebastian Mario Marcuccio, Mary Rodopoulos, Helmut Weigold
  • Patent number: 6573412
    Abstract: The invention provides chain-coupled polymeric alkoxide compounds for use as the elastomeric component in vulcanizable elastomeric compositions comprising silica, carbon black or mixtures thereof. In particular, the invention provides anionically polymerized polymers having polymer chain living ends that are functionalized with alkoxide groups and coupled together by a metal or nonmetal atom. The polymeric alkoxide compounds have an initial high viscosity for ease of handling prior to compounding, a stable viscosity during storage, and a decreased compound viscosity for better filler dispersion and improved mixing efficiency. The invention further provides a pneumatic tire having at least one component produced from the vulcanizable elastomeric composition of the invention.
    Type: Grant
    Filed: May 12, 2000
    Date of Patent: June 3, 2003
    Assignee: Bridgestone Corporation
    Inventors: Terrence E. Hogan, William L. Hergenrother, James E. Hall
  • Patent number: 6552101
    Abstract: A precursor polymer that can be electrochemically polymerized to form an electrically conducting polymer. A precursor according to the present invention includes a plurality of electrochemical polymerizable monomers, each monomer having first and second polymer-forming active sites that can be joined by electrochemical polymerization. The monomers also include third and fourth polymer-forming active sites that can be joined chemically in solution. The monomers in the precursor polymer are linked by the third and fourth polymer-forming active sites. The monomers are chosen such the precursor polymer is soluble in a predetermined solvent while the polymer resulting from the electrochemical polymerization of the precursor polymers via the first and second polymer-forming sites is electrically conducting and insoluble in the solvent. The monomers can be synthesized from fluorene, triophene, pyrrol, biphenyl, poly(vinyl carbazole) or poly (vinyl oxy thiophene).
    Type: Grant
    Filed: September 22, 1999
    Date of Patent: April 22, 2003
    Assignee: Agilent Technologies, Inc.
    Inventors: Daniel B. Roitman, Seiji Inaoka, Riogoberto C. Advincula
  • Patent number: 6547985
    Abstract: A 2-cyanoacrylate composition useful as an adhesive contains a Lewis acid metal salt which comprises a specific metal such as aluminum, gallium, indium or thallium, and the conjugate base of an acid having oxygen such as a monohalo-, dihalo or trihaloacetate, wherein the metal is bonded to the conjugate base through an oxygen atom, and a compound having clathrating ability such as a crown ether.
    Type: Grant
    Filed: April 7, 2000
    Date of Patent: April 15, 2003
    Assignee: Togosei Co., Ltd.
    Inventors: Seitaro Tajima, Mitsuyoshi Sato
  • Publication number: 20020161173
    Abstract: a composition for film formation which can be cured in a short time period and give a film having a low dielectric constant and excellent in heat resistance, adhesion and cracking resistance, a polymer for use in the composition and a process for producing the polymer. The composition prepared by dissolving the polymer having specific repeating units in a solvent has excellent film-forming properties.
    Type: Application
    Filed: April 24, 2002
    Publication date: October 31, 2002
    Applicant: JSR CORPORATION
    Inventors: Takashi Okada, Noriyasu Sinohara, Kaori Shirato, Masahiko Ebisawa, Michinori Nishikawa, Kinji Yamada
  • Patent number: 6440321
    Abstract: A fluorochemical composition to impart water repellency and/or oil repellency to a substrate, the composition comprising one or more condensates of (i) a methylolated amine or a C1-C4 alkoxylated derivative thereof, (ii) a hydrocarbon compound represented by formula (II) and (iii) a fluorinated compound represented by formula (I): Rf—(X1)n—Z1  (I) wherein: Rf is a fluorinated aliphatic group; X1 is an organic divalent linking group; Z1 is selected from the group consisting of hydroxy, thiol, amide or acid groups; and n is 0 or 1; and Rh—Z2  (II)  wherein: Rh is a hydrocarbon group having at least 6 carbon atoms and optionally being substituted with 1 to 3 subsituents; Z2 is selected from the group consisting of hydroxy, thiol, amide or acid groups. The invention further provides a method of treatment of a substrate with the fluorochemical composition and a treated substrate.
    Type: Grant
    Filed: September 17, 1999
    Date of Patent: August 27, 2002
    Assignee: 3M Innovative Properties Company
    Inventors: Frans A. Audenaert, Dirk M. Coppens, Rudolf J. Dams
  • Patent number: 6433129
    Abstract: The present invention relates to compositions and processes for producing borohydride compounds. In particular, the present invention provides efficient processes and compositions for the large-scale production of borohydride compounds.
    Type: Grant
    Filed: November 8, 2000
    Date of Patent: August 13, 2002
    Assignee: Millennium Cell, Inc.
    Inventors: Steven C. Amendola, Michael T. Kelly
  • Patent number: 6344538
    Abstract: Functionalized monomers and polymerized functionalized monomers selected from the group consisting of 2-(N,N-dimethylaminomethyl)-1,3-butadiene, 2-(N,N-diethylaminomethyl)-1,3-butadiene, 2-(N,N-di-n-propylaminomethyl)-1,3-butadiene, 2-(cyanomethyl)-1,3-butadiene, 2-(aminomethyl)-1,3-butadiene, 2-(hydroxymethyl)-1,3-butadiene, 2-(carboxymethy)-1,3-butadiene, 2-(acetoxymethyl)-1,3-butadiene, 2-(2-alkoxy-2-oxoethyl)-1,3-butadiene, 2,3-bis(cyanomethyl)-1,3-butadiene, 2,3-bis(dialkylaminomethyl)-1,3-butadiene, 2,3-bis(4-ethoxy-4-4-oxobutyl)-1,3-butadiene and 2,3-bis(3-cyanopropyl)-1,3-butadiene, and methods for preparing such functionalized diene monomers and polymers.
    Type: Grant
    Filed: May 2, 2000
    Date of Patent: February 5, 2002
    Assignee: Iowa State University Research Foundation, Inc.
    Inventor: Valerie V. Sheares
  • Publication number: 20020007043
    Abstract: A process for the manufacture of polytrimethylene ether glycol comprising the steps of: (a) providing (1) 1,3-propanediol reactant selected from the group consisting of 1,3-propanediol and/or oligomers or prepolymers of 1,3-propanediol having a degree of polymerization of 2-9 and mixtures thereof, and (2) a polycondensation catalyst; and (b) polycondensing the 1,3-propanediol reactant to form a polytrimethylene ether glycol at less than one atmosphere pressure, and the product of the process. In addition, polytrimethylene ether glycol has a number average molecular weight greater than 1,500, an APHA color of less than 120, an unsaturation of less than 20 meq/kg, and a content of cyclic ether oligomers of less than 2%.
    Type: Application
    Filed: December 15, 2000
    Publication date: January 17, 2002
    Inventors: Hari B. Sunkara, Leo E. Manzer
  • Patent number: 6294245
    Abstract: A method for depositing an electrically conducting film on an electrode and the film resulting from that method. An electrically conducting film according to the present invention is deposited by immersing the electrode in a solution of a precursor polymer in a predetermined solvent. The precursor polymer includes a plurality of electrochemical polymerizable monomers. Each monomer has first and second polymer-forming active sites that can be joined by electrochemical polymerization and third and fourth polymer-forming active sites that can be joined chemically in solution. The precursor polymer is constructed from the monomers joined by the third and fourth polymer-forming active sites. The precursor polymer is soluble in the solvent whereas a polymer formed by electrochemical polymerization of the first and second polymer-forming active sites is insoluble in the solvent.
    Type: Grant
    Filed: September 22, 1999
    Date of Patent: September 25, 2001
    Assignee: Agilent Technologies, Inc.
    Inventors: Daniel B. Roitman, Seiji Inaoka, Riogoberto C. Advincula
  • Patent number: 6193909
    Abstract: Cross-linked electrically conductive polymers, in particular electrically conductive, polyaniline are described. Dopants and substituents having pendant cross-linkable functionality are used which form a cross-linked conducting polymer network. The cross-linking functionality can be hydrogen-bonding as well as chemically polymerizable or cross-linkable. A conjugated path between chains can also be incorporated. The resulting cross-linked conducting polymers have enhanced thermal and environmental stability. The dopant cannot readily be washed out with solvents or diffuse out upon exposure to heat. In addition, the cross-linked polymers have enhanced electrical conductivity.
    Type: Grant
    Filed: February 2, 1996
    Date of Patent: February 27, 2001
    Assignee: International Business Machines Corporation
    Inventors: Marie Angelopoulos, Jeffrey D. Gelorme, Yun Hsin Liao, Jane M. Shaw
  • Patent number: 6156872
    Abstract: The invention is related to non-linear, paraffin-soluble olefin/carbon monoxide and olefin/acetylene/carbon monoxide copolymers. The invention is also related to a method for preparing olefin/carbon monoxide copolymers by heating a feed of at least one olefin, carbon monoxide, carbon dioxide, hydrogen, and methane in the presence of a free radical polymerization initiator. More particularly, the feed comprises at least one olefin, the total olefin amount ranging from about 5 to about 40 mole %, carbon monoxide in an amount ranging from about 1 to about 40 mole %, hydrogen in an amount ranging from about 4 to about 55 mole %, carbon dioxide in an amount ranging from about 3 to about 10 mole %, and methane in an amount ranging from about 4 to about 85 mole %. The feed may also include acetylene in an amount ranging up to about mole %.
    Type: Grant
    Filed: January 19, 1999
    Date of Patent: December 5, 2000
    Assignee: Exxon Research and Engineering Co.
    Inventors: Abhimanyu O. Patil, Donald N. Schulz, Raymond A. Cook, Michael G. Matturro
  • Patent number: 6127516
    Abstract: The oxidation of 7,14-diphenylacenaphtho[1,2-.kappa.]fluoranthene (1) at platinum or indium tin-oxide electrodes leads to deposition of a polymer film on the electrode surface that displays many interesting properties including electroactivity, fluorescence, and electrochromism. Thin films of this polymer appear deep blue in the neutral state, but become pale grey upon oxidation and light green or orange upon reduction, depending upon the voltage applied. Soluble oligomers of poly(3,10-(7,14-diphenylacenaphtho[1,2-.kappa.]fluoranthene)) are formed during oxidation of the monomer (1) via radical cation-radical cation coupling reactions and are identical to those chemically synthesized by the Ni(0)-catalyzed coupling of the 3,10-dibromo derivative of 1. Further oxidation of these oligomers leads to intramolecular coupling reactions to form ladder structures within the chains and the eventual precipitation of insoluble polymer onto the electrode.
    Type: Grant
    Filed: December 30, 1998
    Date of Patent: October 3, 2000
    Assignee: Board of Regents, The University of Texas System
    Inventors: Allen J. Bard, Jeff D. Debad
  • Patent number: 6126867
    Abstract: The invention relates to nonlinear-optically active copolymers, to crosslinked NLO polymer materials produced from them and having high orientation stability, and to electrooptical and photonic components comprising these polymer materials. The copolymers of the invention are of the general formula 1 ##STR1## in which W is preferably a chromophoric group of the general formula 2: ##STR2## The chromophores employed in accordance with the invention exhibit high thermal stability and so can be processed at elevated temperatures while retaining the optical activity.
    Type: Grant
    Filed: March 9, 1999
    Date of Patent: October 3, 2000
    Assignee: Siemens Aktiengesellschaft
    Inventors: Andreas Kanitz, Christian Fricke
  • Patent number: 6080835
    Abstract: A functionialized polymer according to the invention includes a polymer molecule having the general formula AYLi where A is a cyclic amine-containing radical having the general formula ##STR1## wherein R.sub.1 is a divalent alkylene, an oxy- or amino-alkylene, or substituted alkylene having from 6 to about 20 carbon atoms; R.sub.2 is a linear-, branched-, or cyclo-alkylene having from about 2 to about 20 carbon atoms; and Y is a divalent polymer radical and Li is a lithium atom bonded to a carbon atom of Y.
    Type: Grant
    Filed: September 24, 1997
    Date of Patent: June 27, 2000
    Assignee: Bridgestone Corporation
    Inventors: David F. Lawson, Thomas A. Antkowiak, James E. Hall, Mark L. Stayer, Jr., John R. Schreffler
  • Patent number: 6030550
    Abstract: Cross-linked electrically conductive polymers, in particular electrically conductive, polyaniline are described. Dopants and substituents having pendant cross-linkable functionality are used which form a cross-linked conducting polymer network. The cross-linking functionality can be hydrogen-bonding as well as chemically polymerizable or cross-linkable. A conjugated path between chains can also be incorporated. The resulting cross-linked conducting polymers have enhanced thermal and environmental stability. The dopant cannot readily be washed out with solvents or diffuse out upon exposure to heat. In addition, the cross-linked polymers have enhanced electrical conductivity.
    Type: Grant
    Filed: February 2, 1996
    Date of Patent: February 29, 2000
    Assignee: International Business Machines Corporation
    Inventors: Marie Angelopoulos, Jeffrey D. Gelorme, Yun Hsin Liao, Jane M. Shaw
  • Patent number: 6030668
    Abstract: Compounds of formula ##STR1## are provided which may be used in a variety of devices including liquid crystal devices, piezoelectric devices, pyroelectric devices and in optical recording media, where m=at least 5; and R.sub.x, R.sub.y and R.sub.z are independently from formula (IA), ##STR2## where Y is selected from COO, OCO, O, S, CHOH, CHF, CH.sub.2 ; Q=(CH.sub.2).sub.n wherein one or more non-adjacent methylenes may be replaced by O and n=1-20; Z is selected from O, S, a single covalent bond, COO, a OCO; when Y is CH.sub.2 then n may also be 0; formula (IB) is ##STR3## and represents any mesogenic group; and R.sub.x, R.sub.y and R.sub.z are also independently selected from H, OH, OCOR.sup.1, COOH, CO.sub.2 R.sup.1 (CH.sub.2).sub.p OH, (CH.sub.2).sub.p CO.sub.2 H, --(CH.sub.2).sub.p OR.sup.1 or --(CH.sub.2).sub.p CO.sub.2 R.sup.1 and p=1-20, R.sup.1 =H or C.sub.1-16 alkyl, when R.sup.1 =C.sub.2-16 alkyl the terminal CH.sub.3 group may be replaced by Br or Cl; provided that at least one of and R.sub.x, R.
    Type: Grant
    Filed: May 26, 1998
    Date of Patent: February 29, 2000
    Assignee: The Secretary of State for Defence, in Her Britannic Majesty's Government of the United Kingdom of Great Britain and Northern Ireland
    Inventors: Alan W Hall, David Lacey, Ian C Sage, Keith M Blackwood, Michelle Jones
  • Patent number: 5968411
    Abstract: Liquid crystal polymer materials used in liquid crystal devices, piezoelectric devices, pyroelectric devices and recording media are described.
    Type: Grant
    Filed: April 29, 1998
    Date of Patent: October 19, 1999
    Assignee: The Secretary of State for Defence in Her Britannic Majesty's Government of the United Kingdom of Great Britain and Northern Ireland
    Inventors: Alan William Hall, David Lacey, Ian Charles Sage, Keith Moray Blackwood, Michelle Jones
  • Patent number: 5925494
    Abstract: The invention provides a method for vapor-depositing a polymer film having constituents that are synthesized during the deposition and that can therefore be customized by time-dependent process control during the deposition. In the vapor-deposition process, a hydrocarbon precursor is reacted with an oxygen-containing precursor in a plasma environment. The plasma reaction synthesizes O--H bonds and forms a polymer having O--H bonds, C--C bonds, and C--H.sub.x bonds. Preferably, the hydrocarbon and oxygen-containing precursors are employed in a ratio selected such that the resulting polymer film has a selected level of oxygen constituency providing a corresponding selected ratio of O--H bond concentration to C--H.sub.x bond concentration. The precursor ratio is preferably varied as a function of time during the plasma reaction to result in a corresponding distribution, e.g., a depth-dependent distribution, of O--H bonds in the film.
    Type: Grant
    Filed: February 16, 1996
    Date of Patent: July 20, 1999
    Assignee: Massachusetts Institute of Technology
    Inventor: Mark W. Horn
  • Patent number: 5904990
    Abstract: Until recently, conducting polymers have been used as protective coatings. lthough these types of polymers appear to be effective in most cases, problems have resulted when attempting to bind these polymers to an aluminum surface. The polymers of this invention adhere extremely well to aluminum and aluminum alloys and thus, provide a very effective form of corrosion protection.
    Type: Grant
    Filed: March 13, 1998
    Date of Patent: May 18, 1999
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: John D. Stenger-Smith, Melvin H. Miles, William P. Norris, John Nelson, Peter Zarras, John W. Fischer, Andrew P. Chafin
  • Patent number: 5807970
    Abstract: Formulations including a high density polyester and a density reducing component. The formulations are useful for facilitating the separation of blood serum or plasma from the cellular portion of blood in blood collection applications.
    Type: Grant
    Filed: April 29, 1997
    Date of Patent: September 15, 1998
    Assignee: Becton, Dickinson and Company
    Inventor: Rhyta S. Rounds
  • Patent number: 5804100
    Abstract: Deaggregated substituted and unsubstituted polyparaphenylenes, polyparaphenylevevinyles, polyanilines, polyazines, polythiophenes, poly-p-phenylene sulfides, polyfuranes, polypyrroles, polyselenophene, polyacetylenes formed from soluble precursors and combinations thereof and copolymers thereof and methods of fabrication are described. The deaggregated polymer molecules when subsequently doped show higher electrical conductivity. Agents such as lithium chloride, m-cresol and nonylphenol are used to deaggregate the polymer molecules. The deaggregating agents can be added prior to or during doping the molecules.
    Type: Grant
    Filed: January 9, 1995
    Date of Patent: September 8, 1998
    Assignee: International Business Machines Corporation
    Inventors: Marie Angelopoulos, Bruce K. Furman
  • Patent number: 5756653
    Abstract: A novel zerovalent zinc species and an organozinc reagent are disclosed. The zerovalent zinc species is directly produced by reaction of a reducing agent on a zinc salt, preferably Zn(CN).sub.2. The organozinc reagent results from the reaction of the zerovalent zinc species and an organic compound having one or more stable anionic leaving groups. These organozinc reagents include a wide spectrum of functional groups in the organic radical, and are useful in a variety of reactions schemes.
    Type: Grant
    Filed: May 2, 1995
    Date of Patent: May 26, 1998
    Assignee: Board of Regents of the University of Nebraska
    Inventor: Reuben D. Rieke
  • Patent number: 5750585
    Abstract: A water swellable foam matrix formed as a macroporous solid comprising a foam stabilizing agent and a polymer or copolymer of a free radical polymerizable hydrophilic olefin monomer crosslinked with about 0.1 to about 10% by weight of a multiolefin-functional crosslinking agent is described. The foam matrix is characterized by rapid swelling and high water swelling ratios.
    Type: Grant
    Filed: April 4, 1995
    Date of Patent: May 12, 1998
    Assignee: Purdue Research Foundation
    Inventors: Kinam Park, Haesun Park
  • Patent number: 5684123
    Abstract: A process for the preparation of a solution of a catalyst system, suitable for use in a process for copolymerizing carbon monoxide and one or more ethylenically unsaturated compounds, which comprises (a) combining a palladium compound, a bisphosphine of the general formula R.sup.1 R.sup.2 P--R--PR.sup.3 R.sup.4 (I) wherein each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently represents an aromatic hydrocarbyl group which is substituted with an alkoxy group and R represents a bivalent bridging group containing at least two carbon atoms in the bridge, and a lower alcohol as solvent, and (b) admixing the obtained combination after a generation period G, during which a temperature T in the range of 0.degree.-70.degree. C. is maintained, with an acid having a pKa of less than 2, whereby the said generation period G is selected such that the value for G (in hours) and the temperature T in .degree.C.
    Type: Grant
    Filed: January 15, 1997
    Date of Patent: November 4, 1997
    Assignee: Shell Oil Company
    Inventors: Frits Van Der Veer, Rudolf Jacobus Wijngaarden
  • Patent number: 5679760
    Abstract: The present invention relates to polymers with an extended system of conjugated double bonds constructed as homo and/or heterocyclic rings which are interlinked in pairs so that one ring is joined to the neighboring one at two adjacent atoms in the ring, in which one of these connections is made by a chemical bond to a ring atom of the neighboring ring and the other via a carbon, nitrogen, oxygen or sulphur atom to an atom of the neighboring ring adjacent said ring atom, their production and use in electrical, electronic and opto-electronic components.
    Type: Grant
    Filed: March 21, 1995
    Date of Patent: October 21, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Klaus Mullen, Ullrich Scherf
  • Patent number: 5663285
    Abstract: Formulations including a high density polyester and a density reducing component. The formulations are useful for facilitating the separation of blood serum or plasma from the cellular portion of blood in blood collection applications.
    Type: Grant
    Filed: August 16, 1996
    Date of Patent: September 2, 1997
    Assignee: Becton Dickinson and Company
    Inventor: Rhyta S. Rounds
  • Patent number: 5604292
    Abstract: Novel conjugated amino substituted phenylene polymers are disclosed having on-linear optical properties, and which can be converted to electrically conductive polymers. Such polymers are produced by reacting a novel bis-cycloalkylene sulfonium salt of 2,5,N,N-tetramethylaniline hydrochloride, such as 2,5-(N,N-dimethyl)aniline hydrochloride dimethylene bis-(tetramethylene sulfonium chloride) with alkali metal hydroxide to form a cycloalkylene sulfonium salt precursor polymer, and then heating the precursor polymer under conditions to produce the amino substituted phenylene vinylene polymer, such as poly(2-(N,N-dimethylamino) phenylene vinylene). The polymers can also be made directly by treatment of the bis chlormethyl dimethyl aniline hydrochloride derivative with alkali metal alkoxide.
    Type: Grant
    Filed: May 31, 1994
    Date of Patent: February 18, 1997
    Assignee: The Untied States of America as represented by the Secretary of the Navy
    Inventors: John D. Stenger-Smith, William P. Norris, Andrew P. Chafin, Scott T. Sackinger
  • Patent number: 5578699
    Abstract: A process for synthesizing novel conjugated amino substituted phenylene pmers is disclosed. The process results in polymers having non-linear optical properties, and the polymers can be converted to electrically conductive polymers. The process involves reacting a novel bis-cycloalkylene sulfonium salt of 2,5,N,N-tetramethylaniline hydrochloride, such as 2,5-(N,N-dimethyl)aniline hydrochloride dimethylene bis-(tetramethylene sulfonium chloride) with alkali metal hydroxide to form a cycloalkylene sulfonium salt precursor polymer, and then heating the precursor polymer under conditions to produce the amino substituted phenylene vinylene polymer, such as poly(2-(N,N-dimethylamino) phenylene vinylene). Another process involves treatment of the bis chlormethyl dimethyl aniline hydrochloride derivative with alkali metal alkoxide.
    Type: Grant
    Filed: May 18, 1995
    Date of Patent: November 26, 1996
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: John D. Stenger-Smith, William P. Norris, Andrew P. Chafin, Scott T. Sackinger
  • Patent number: 5565543
    Abstract: High-performance polymers having a rigid-rod backbone comprising a chain length of at least 25 organic monomer units joined together by covalent bonds wherein at least about 95% of the bonds are substantially parallel; and solubilizing organic groups attached to at least 1% of the monomer units. The polymers are prepared in a solvent system which is a solvent for both the monomer starting materials and the rigid-rod polymer product.
    Type: Grant
    Filed: August 11, 1994
    Date of Patent: October 15, 1996
    Assignee: Maxdem Incorporated
    Inventors: Matthew L. Marrocco, III, Robert R. Gagne, Mark S. Trimmer
  • Patent number: 5484883
    Abstract: Poly(phenylene) that is substantially free of insoluble material is prepared by the polymerization of a lithioarylhalide compound in the presence of a polar aprotic compound such as hexamethylphosphoramide, N,N,N',N'-tetramethylethylenediamine or hexamethylphosphorous triamide. The preferred reaction involves the polymerization of 1-bromo-4-lithiobenzene in the presence of hexamethylphosphoramide. The 1-bromo-4-1ithiobenzene may be synthesized by reacting 1,4-dibromobenzene with t-butyllithium. These same types of reactions can also be used to synthesis other benzenoid polymers.
    Type: Grant
    Filed: August 16, 1994
    Date of Patent: January 16, 1996
    Assignee: University of South Carolina
    Inventors: James M. Tour, Eric B. Stephens
  • Patent number: 5401827
    Abstract: A semiconductive conjugated copolymer comprises at least two chemically different monomer units which, when existing in their individual homopolymer forms, have different semiconductor bandgaps. The proportion of said at least two chemically different monomer units in the copolymer is selected to control the semiconductor bandgap of the copolymer so as to control the optical properties of the copolymer. The copolymer is formed in a manner enabling it to be laid down as a film without substantially affecting the luminescent characteristics of the copolymer and is stable at operational temperature.The semiconductor bandgap may be spatially modulated so as to increase the quantum efficiency of the copolymer when excited to luminesce, to select the wavelength of radiation omitted during luminescence or to select the refractive index of the copolymer.
    Type: Grant
    Filed: August 22, 1991
    Date of Patent: March 28, 1995
    Assignee: Cambridge Display Technology Limited
    Inventors: Andrew Holmes, Donal D. Bradley, Richard H. Friend, Arno Kraft, Paul Burn, Adam Brown
  • Patent number: 5374681
    Abstract: Polyacetals useful as reduced-phosphate or phosphate-free detergent and cleaner additives are obtainable by cationically initiated polyaddition of(a) divinyl ethers and(b) dihydroxy compounds and also, optionally,(c) monohydroxy compoundsand have K values of from 8 to 100.
    Type: Grant
    Filed: January 5, 1994
    Date of Patent: December 20, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Heinrich Hartmann, Richard Baur, Volker Schwendemann, Hans-Ulrich Jaeger, Johannes Perner
  • Patent number: 5354929
    Abstract: The invention is a bis-BCB compound of the structure: ##STR1## a method for making same and polymers made therefrom. The novel compounds of this invention are useful in preparing polymers that can form thin film coatings for multichip midules (MCMs) and integrated circuits (ICs). These compounds can be isolated as liquids at room temperature, and can form polymers that are hydrophobic and have low dielectrical and dissipative properties.
    Type: Grant
    Filed: September 28, 1993
    Date of Patent: October 11, 1994
    Assignee: The Dow Chemical Company
    Inventors: Robert A. Kirchhoff, P. J. Thomas, R. Garth Pews
  • Patent number: 5310858
    Abstract: The invention relates to a process for preparing compounds of the formula (I) ##STR1## by pyrolysis, where n is the degree of polymerization and is.gtoreq.2. For this purposes compounds of the formula (II)--R--CO--O--CH.sub.2 --Ar--CH.sub.2 --O--CO--R (II)are pyrolyzed in one stage under conditions resulting in cleavage of the ester bonds under a partial pressure of the esters of p.ltoreq.10 mbar at temperatures T.gtoreq.500.degree. C., with the formation of the corresponding derivatives of 1,4-dimethylene-2,5-cyclohexadiene, but without the latter being cleaved further in subsequent reactions. The polymers of p-xylylene formed by spontaneous polycondensation of the derivatives of 1,4-dimethylene-2,5-cyclohexadiene were then cooled, Ar and R have the following meanings:--Ar-- is a 1,4-phenylene radical or another C.sub.6 -C.sub.12 aromatic or heteroaromatic radical in which the bonds are in the para position or a comparable coaxial or antiparallel position;R-- is preferably branched or unbranched C.sub.1 -C.
    Type: Grant
    Filed: January 28, 1993
    Date of Patent: May 10, 1994
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Andreas Greiner, Peter Simon
  • Patent number: 5281644
    Abstract: There are disclosed methods and compositions for retarding the ambient temperature hardening of a phenolic resole resin alone or with an aggregate when such resin is contacted with a nitroalkane and a hardening agent such as lightburned magnesium oxide, an organic ester functional hardening agent, and mixtures of lightburned magnesium oxide and an organic ester functional hardening agent in an alkaline medium. There is also disclosed a hardener composition for phenolic resole resins wherein the hardener composition consists essentially of a solution of a nitroalkane in an organic ester functional hardening agent.
    Type: Grant
    Filed: November 4, 1992
    Date of Patent: January 25, 1994
    Assignee: Borden, Inc.
    Inventors: S. Raja Iyer, David R. Armbruster, Arthur H. Gerber
  • Patent number: 5247054
    Abstract: An organic polymer ferromagnetic material characterized in that the material comprises a polymer obtained by subjecting to plasma polymerization or oxidation polymerization a methane derivative having two substituents and represented by the formula ##STR1## wherein A is an electron accepting group, and B is an electron donating group, or by copolymerizing the methane derivative with a diarylmethane derivative represented by the formula ##STR2## wherein R.sup.1 is a substituted or unsubstituted phenyl group by plasma polymerization or oxidation polymerization.
    Type: Grant
    Filed: August 1, 1990
    Date of Patent: September 21, 1993
    Assignee: Otsuka Kagaku Kabushiki Kaisha
    Inventors: Hitoshi Tanaka, Tsuneyuki Sato, Todatoshi Ota, deceased, Michio Sasaoka
  • Patent number: 5241044
    Abstract: A process for preparing poly(p-phenylene)s comprises reacting dihydroxy aromatic compounds such as orthoquinone and bisphenols with halogen-substituted aliphatic sulfonic acids, halogen sulfonic acid, or their anhydrides. The monomers thus formed are subsequently polymerized with Ni(0) catalysts to yield the desired polymers. The monomers or polymers may be functionalized with reactive groups.
    Type: Grant
    Filed: March 20, 1992
    Date of Patent: August 31, 1993
    Assignee: Edison Polymer Innovation Corporation
    Inventor: Virgil Percec
  • Patent number: 5124240
    Abstract: An optical recording medium consists essentially of a base material and a light-absorbing layer which contains a thermoplastic binder and at least one dye, wherein the thermoplastic binder is a polycyclic hydrocarbon which has a glass transition temperature Tg of greater than 150.degree. C. and is soluble to more than 3% by weight in an aliphatic or aromatic hydrocarbon.
    Type: Grant
    Filed: March 16, 1990
    Date of Patent: June 23, 1992
    Inventors: Sibylle Brosius, Bernhard Albert, Michael Schmitt, Klaus D. Schomann, Harald Kuppelmaier, Ulrich Harten
  • Patent number: 5095057
    Abstract: A new class of compounds, is disclosed, defined by the formula:R'.sub.2 N(CH.sub.2 CH.sub.2 NR").sub.y Rwhere R, R' and R" are equal or different and are ##STR1## wherein x is bromine or chlorine, n is an integer from 3 to 5 inclusive and y is an integer equal to or greater than 1.The compounds of the invention are useful as fire retardant agents.
    Type: Grant
    Filed: December 15, 1989
    Date of Patent: March 10, 1992
    Assignee: Bromine Compounds Limited
    Inventors: Leonard M. Shorr, Many Ravey
  • Patent number: 5066779
    Abstract: The present invention discloses a process for producing a raw material pitch for carbon materials containing a slight amount of ash, the comprising steps of adding aluminum chloride to naphthalene or its derivative as a catalyst; polymerizing said naphthalene or its derivative at a temperature of 100.degree. to 330.degree. C., adding water to the polymer, under stirring if necessary; maintaining the mixture in an emulsified state for a predetermined time under stirring, breaking an emulsion, removing a water layer from the polymer.
    Type: Grant
    Filed: January 30, 1990
    Date of Patent: November 19, 1991
    Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Ikuo Seo, Tooru Oono, Yosinobu Murakami