Two Or More Heterocyclic Reactants Containing Rings Of One Oxygen And Two Carbon Atoms Patents (Class 528/419)
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Patent number: 6133211Abstract: Block copolyethers having general formula (I):RX--(CH.sub.2 --CHR.sub.1 --O--).sub.x --(--CH.sub.2 CHR.sub.2 --O--).sub.y --(--CH.sub.2 --CHR.sub.3 --O--).sub.z --R.sub.4wherein:R is selected from H, alkyl, alkylaryl;X is selected from O, S and N;R.sub.1, R.sub.2 and R.sub.3 are selected from H, CH.sub.3, and C.sub.2 -C.sub.10 alkyl radicals;R.sub.4 is selected from H, alkyl, acyl;x,y,z represent the number of ether units and are integers which have such values that the molecular weight of the compound having general formula (I) is between 600 and 4000, and in addition (x+z)/y is between 1.5 and 5.0; with the proviso that:a) either R.sub.1 and R.sub.3 are selected from H and CH.sub.3, in which case R.sub.2 is selected from C.sub.2 to C.sub.10 alkyl radicals,b) or R.sub.1 and R.sub.3 are selected from C.sub.2 -C.sub.10 alkyl radicals, in which case R.sub.2 is selected from H and CH.sub.3.Type: GrantFiled: October 30, 1997Date of Patent: October 17, 2000Assignee: Agip Petroli S.p.A.Inventors: Sandra Cobianco, Alessandro Lezzi, Alberto Forlini, Emilio Gatti
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Patent number: 6124418Abstract: The invention provides a method for making a curable epoxysilicone composition through the hydrosilation reaction between an ethylenically unsaturated epoxide and an SiH-containing silicone to produce an epoxysilicone product, and catalyzed by a quaternary ammonium, phosphonium or arsonium hexahaloplatinate which does not promote the oxirane ring-opening reaction of either the ethylenically unsaturated epoxide starting material or the epoxysilicone product. The invention also provides for a curable epoxysilicone composition made by the above method.Type: GrantFiled: February 14, 1994Date of Patent: September 26, 2000Assignee: General Electric CompanyInventors: James Vincent Crivello, Mingxin Fan
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Patent number: 6103850Abstract: There is provided an sealant made with an isocyanate or hydroxyl terminated prepolymer made by reacting a stoichiometric excess of an organic polyisocyanate with polyols made of at least a polyoxyalkylene polyether triol or a mixture thereof with a polyoxyalkylene polyether diol. The triol or diol has within its structure the nucleus of an initiator compound, an internal blocks of oxypropylene groups, and external blocks of oxyalkylene groups, wherein the internal blocks of oxypropylene are between said nucleus and said external blocks, said external blocks are made of oxyalkylene groups derived from a C.sub.4 or higher alkylene oxide. The amount of the internal blocks of oxypropylene groups is from 25 weight percent to 80 weight percent based on the weight of all oxyalkylene groups and initiator in the prepolymer The triol or diol has a compatibility index of 25.degree. C. or less, and may be part of a two component or a one component moisture cured sealant.Type: GrantFiled: November 21, 1996Date of Patent: August 15, 2000Assignee: BASF CorporationInventors: Curtis J. Reichel, Thomas L. Fishback, Gladys M. Aviles
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Patent number: 6069210Abstract: A composition comprising a particulate solid and a dispersant which is a phosphate ester of a compound of formula 1: ##STR1## wherein Y is methoxy or H--(EO).sub.q, m and q are each independently from 5 to 50 and n is from 5 to 70. When Y is a methoxy, n is preferably 20 and m is preferably 10. When Y is H--(EO).sub.q, m and q are preferably 13 and n is preferably 30.Type: GrantFiled: November 4, 1998Date of Patent: May 30, 2000Assignee: Zeneca LimitedInventors: David John Cartridge, Dean Thetford
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Patent number: 6051627Abstract: A dispersant which is a phosphate ester of a polyalkylene ether block copolymer of formula MeO(C.sub.2 H.sub.4 O).sub.m (C.sub.3 H.sub.6 O).sub.n --H wherein m and n are each, independently, 2 to 60 and use in aqueous based paints and printing inks.Type: GrantFiled: June 1, 1998Date of Patent: April 18, 2000Assignee: Zeneca LimitedInventors: Dean Thetford, Mark Holbrook
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Patent number: 6034208Abstract: Unique, well defined macromonomers containing hydroxyl-functionality, unsaturation-functionality, and polyoxyalkylene segments are prepared by oxyalkylating an unsaturated initiator molecule having at least one oxyalkylatable hydrogen in the presence of an effective amount of a double metal cyanide complex catalyst, optionally, when necessary, in the presence of a free radical polymerization inhibitor. The resulting unsaturated macromonomers are eminently suitable for such uses as copolymerization with ethylenically unsaturated monomers containing carboxylic acid-based groups such as acrylic acid to form effective superplasticizers and water reducers for cement and concrete applications.Type: GrantFiled: May 8, 1998Date of Patent: March 7, 2000Assignee: Arco Chemical Technology, L.P.Inventors: Kenneth G. McDaniel, Edward T. Shawl, Xinhau Zhou
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Patent number: 5998574Abstract: Thus, there is provided according to the present invention polyol compositions comprising(A) a polytetramethylene ether glycol, and(B) a difunctional active hydrogen compound-initiated polyoxyalkylene polyether polyol having a degree of unsaturation of not greater than 0.04 milliequivalents per gram of said polyether polyol.Type: GrantFiled: July 10, 1996Date of Patent: December 7, 1999Assignee: BASF CorporationInventors: Thomas L. Fishback, Curtis J. Reichel, Thomas B. Lee
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Patent number: 5998559Abstract: A single-ion electrolyte achieves conductivity greater than 10.sup.-3 S/cm at 20.degree. C. by employing repeating mer units which are functionalized by fluoroalkylsulfonate groups. Preferred backbones for the electrolyte include polysiloxanes, polymethacrylates and poly(alkylene oxides). More preferred backbones have the structure ##STR1## wherein A is selected from the group consisting of C and Si such that when A is C then R.sup.4 is (CH.sub.2).sub.1-100' and when A is Si then R.sup.4 is O; R.sup.1 and R.sup.2 are independently selected from the group consisting of hydrogen, lower alkyl, lower alkoxy, fluorinated lower alkyl, fluorinated lower alkoxy, and fluoroalkylsulfonate; and R.sup.3 is null or selected from the group consisting of O, (O).sub.1-100, O--CH.sub.2, (O).sub.1-100 --(CH.sub.2).sub.1-100.Type: GrantFiled: August 15, 1996Date of Patent: December 7, 1999Assignee: SRI InternationalInventors: Subhash C. Narang, Susanna C. Ventura
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Patent number: 5981624Abstract: A reduced shade paint or ink comprising(a) a base paint or ink comprising a base pigment such as titanium dioxide, a film-forming resin and a non-polar liquid such as white spirits;(b) one or more dispersant which is a phosphate ester of a compound of formula 1 ##STR1## wherein Y is a group RO-- or a group H--(EO).sub.q --;R is C.sub.1-10 -alkyl;m and q are each, independently, from 5 to 50;n is from 5 to 70; and(c) a tinter composition comprising a colored pigment, water and/or a water-miscible solvent such as ethyleneglycol.Type: GrantFiled: November 4, 1997Date of Patent: November 9, 1999Inventors: Dean Thetford, David J. Cartridge
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Patent number: 5891960Abstract: Coating compositions comprised of a film forming polymer which is the reaction product of (a) a compound containing pendant and/or terminal hydroxyl or epoxy functional groups and (b) citric acid or citric acid anhydride. The coating compositions have enhanced adhesion to galvanized and galvanealed steel substrates without the use of a chrome containing wash primer.Type: GrantFiled: September 12, 1997Date of Patent: April 6, 1999Assignee: PPG Industries, Inc.Inventors: James A. Claar, Karl F. Schimmel, Shanti Swarup, Bruce A. Connelly
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Patent number: 5854386Abstract: Unique, well defined polyethers containing both hydroxyl-functionality and unsaturation-functionality are prepared by oxyalkylating an unsaturated monomer having at least one oxyalkylatable hydrogen in the presence of an effective amount of a double metal cyanide complex catalyst, optionally, when necessary, in the presence of a free radical polymerization inhibitor. The resulting polyethers are eminently suitable for such uses as polymer polyol stabilizers or stabilizer precursors, and both in situ and ex situ impact modifiers for thermoplastics.Type: GrantFiled: August 25, 1997Date of Patent: December 29, 1998Assignee: ARCO Chemical Technology, L.P.Inventors: Jianzhong Shen, Kenneth G. McDaniel, John E. Hayes, Uli B. Holeschovsky, Harry R. Hinney
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Patent number: 5792829Abstract: Polyurethane elastomers exhibiting improved green strength while maintaining short demold times are prepared from ultra-low unsaturation polyoxypropylene polyols containing up to 20 weight percent internal random oxyethylene moieties. The elastomers adsorb less than 10 weight percent water at 0.degree. C. The internal polyoxyethylene moiety-containing polyoxypropylene polyols may be used to prepare ultra-low unsaturation polyoxyethylene capped polyols which are haze-free and which may be used to prepare haze-free 4,4'-MDI prepolymers. Multidisperse blends of monodisperse internal oxyethylene moiety-containing polyoxypropylene polyols of ultra-low unsaturation provide yet further improvements in elastomer processing.Type: GrantFiled: June 3, 1997Date of Patent: August 11, 1998Assignee: ARCO Chemical Technology, L.P.Inventors: Gary L. Allen, Nigel Barksby, Bruce H. Isaacs, Leah J. Langsdorf, Stephen D. Seneker
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Patent number: 5789626Abstract: Highly active double metal cyanide (DMC) catalysts are disclosed. The catalysts comprise a DMC complex, and organic complexing agent, and from about 5 to about 80 wt. %, based on the amount of catalyst, of a polyether having a number average molecular weight less than about 500. The catalysts polymerize propylene oxide at a rate in excess of about 1 kg PO/g Co/min. at 100 ppm catalyst, based on the weight of finished polyether, at 105.degree. C. The catalysts, which are easy to prepare, give polyether polyols with exceptionally low unsaturation levels.Type: GrantFiled: January 8, 1997Date of Patent: August 4, 1998Assignee: Arco Chemical Technology, L.P.Inventor: Bi Le-Khac
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Patent number: 5731407Abstract: Improved double metal cyanide catalysts are disclosed. The substantially amorphous catalysts of the invention are more active for polymerizing epoxides than conventional DMC catalysts, which have a substantial crystalline component. Polyol products made with the catalysts are unusually clear, have exceptionally low unsaturations, and contain no detectable amount of low molecular weight polyol impurities. A method of making the improved DMC catalysts, which involves intimately combining the reactants, is also disclosed.Type: GrantFiled: June 7, 1995Date of Patent: March 24, 1998Assignee: Arco Chemical Technology, L.P.Inventor: Bi Le-Khac
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Patent number: 5719257Abstract: The invention relates to polyethers of the formula I ##STR1## in which m is 0 or 1; n is an integer in the range from 3 to 100; R.sup.1, in the case where m is 0 or 1, is C.sub.1 -C.sub.36 alkyl or C.sub.7 -C.sub.36 aralkyl, each of which is unsubstituted or substituted by C.sub.5 -C.sub.8 cycloalkyl, is interrupted in the aliphatic part by C.sub.5 -C.sub.8 cycloalkylene or by oxygen or sulfur or --NR.sup.11 -- or is substituted in the aromatic part by 1 to 3 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; C.sub.3 -C.sub.36 alkenyl; C.sub.5 -C.sub.12 cycloalkyl which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; C.sub.6 -C.sub.10 aryl which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; and R.sup.1, in the case where m is 0, can alternatively be hydrogen; C.sub.1 -C.sub.36 alkoxy or C.sub.7 -C.sub.36 aralkoxy, each of which is unsubstituted or substituted by C.sub.5 -C.sub.Type: GrantFiled: October 2, 1996Date of Patent: February 17, 1998Assignee: Ciba Specialty Chemicals CorporationInventor: Alfred Steinmann
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Patent number: 5670612Abstract: An aqueous self-emulsifiable epoxy resin curing agent which is produced by reacting, with each other, an (A) polyamine (meta-xylylenediamine, etc), a (B) epoxy group-containing alkoxypolyethylene polyether compound (methoxypolyethyleneglycol glycidyl ether, etc.) having 500 to 5000 average molecular weight, at least one (C) hydrophobic epoxy compound having at least one epoxy group in the molecule (butyl glycidyl ether, epoxy resin of type bisphenol A or F, etc.) and optionally, a (D) unsaturated compound capable of addition reaction (acrylonitrile, methyl methacrylate, etc.), in a molar quantity of the epoxy group in (B) of 0.001 to 0.1 mol and in a molar quantity of the sum of the epoxy group in (C) and the unsaturated group in (D) of 0.2 to 0.5 mol, each based on 1 mol of a hydrogen atom bonded to a nitrogen atom in (A) which is capable of reacting with an epoxy group or a unsaturated group.Type: GrantFiled: October 10, 1995Date of Patent: September 23, 1997Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Shuta Kihara, Shinichi Yonehama, Kiichiro Seki
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Patent number: 5616637Abstract: The invention relates to polyethers of the formula I ##STR1## in which m is 0 or 1; n is an integer in the range from 3 to 100; R.sup.1, in the case where m is 0 or 1, is C.sub.1 -C.sub.36 alkyl or C.sub.7 -C.sub.36 aralkyl, each of which is unsubstituted or substituted by C.sub.5 -C.sub.8 cycloalkyl, is interrupted in the aliphatic part by C.sub.5 -C.sub.8 cycloalkylene or by oxygen or sulfur or --NR.sup.11 -- or is substituted in the aromatic part by 1 to 3 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; C.sub.3 -C.sub.36 alkenyl; C.sub.5 -C.sub.12 cycloalkyl which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; C.sub.6 -C.sub.10 aryl which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; and R.sup.1, in the case where m is 0, can alternatively be hydrogen; C.sub.1 -C.sub.36 alkoxy or C.sub.7 -C.sub.36 aralkoxy, each of which is unsubstituted or substituted by C.sub.5 -C.sub.Type: GrantFiled: March 13, 1996Date of Patent: April 1, 1997Assignee: Ciba-Geigy CorporationInventor: Alfred Steinmann
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Patent number: 5594097Abstract: Polyether polyol comprising as alkylene oxide units ethylene oxide and propylene oxide units, said polyol having a nominal average hydroxyl functionality of 2-6, an hydroxyl value of 16-45 mg KOH/g, a primary hydroxyl content of at least 50% calculated on the total amount of hydroxyl groups and an amount of ethylene oxide units, calculated on the weight of the alkylene oxide units in the polyol, of 21-49% by weight these polyols are useful for making flexible foam.Type: GrantFiled: June 7, 1995Date of Patent: January 14, 1997Assignee: Imperial Chemical Industries PLCInventors: Pierre G. Chaffanjon, Peter F. Stroobants, Gerhard J. Bleys
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Patent number: 5563221Abstract: A process for making high-primary, low-unsaturation polyols is disclosed. A polyol made by double metal cyanide (DMC) catalysis is blended with a polyol made by basic catalysis, and the polyol blend is reacted with ethylene oxide to produce an ethylene oxide-capped potyol. The process overcomes problems of the conventional recatalysis approach to making EO-capped polyols from DMC-catalyzed polyols.Type: GrantFiled: June 21, 1995Date of Patent: October 8, 1996Assignee: ARCO Chemical Technology, L.P.Inventor: Jos e F. Pazos
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Patent number: 5534618Abstract: The invention relates to polyethers containing recurring units of the formula I ##STR1## in which A is --CH.sub.2 -- or --CO--, and, when A is methylene, E is ##STR2## and when A is carbonyl, E is ##STR3## R.sup.1 is hydrogen, and R.sup.2 is likewise hydrogen or an aromatic, aliphatic or araliphatic carbonyloxy radical or a corresponding radical of an ether or tertiary amine, or R.sup.1 and R.sup.2 together are a.dbd.O substituent or together with the carbon atom to which they are bonded are a five- or six-membered, substituted, oxygen- and/or nitrogen-containing heterocyclic ring, andR.sup.17 is a hydrocarbon radical having a maximum of 18 carbon atoms.The polyethers according to the invention can advantageously be employed for the stabilization of organic material against the harmful effect of light, oxygen and/or heat.Type: GrantFiled: July 7, 1994Date of Patent: July 9, 1996Assignee: Ciba-Geigy CorporationInventor: Alfred Steinmann
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Patent number: 5521282Abstract: The invention relates to polyethers of the formula I ##STR1## in which m is 0 or 1; n is an integer in the range from 3 to 100; R.sup.1, in the case where m is 0 or 1, is C.sub.1 -C.sub.36 alkyl or C.sub.7 -C.sub.36 aralkyl, each of which is unsubstituted or substituted by C.sub.5 -C.sub.8 cycloalkyl, is interrupted in the aliphatic part by C.sub.5 -C.sub.8 cycloalkylene or by oxygen or sulfur or --NR.sup.11 -- or is substituted in the aromatic part by 1 to 3 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; C.sub.3 -C.sub.36 alkenyl; C.sub.5 -C.sub.12 cycloalkyl which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; C.sub.6 -C.sub.10 aryl which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub. alkoxy radicals; and R.sup.1, in the case where m is 0, can alternatively be hydrogen; C.sub.1 -C.sub.36 alkoxy or C.sub.7 -C.sub. 36 aralkoxy, each of which is unsubstituted or substituted by C.sub.5 -C.sub.Type: GrantFiled: July 7, 1994Date of Patent: May 28, 1996Assignee: Ciba-Geigy CorporationInventor: Alfred Steinmann
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Patent number: 5506309Abstract: This invention pertains to perfluoropolyethers and perhalogenated chlorofluoropolyethers that can be prepared by fluorinating addition polymers made by polymerizing epoxides.Type: GrantFiled: June 6, 1995Date of Patent: April 9, 1996Assignee: Exfluor Research CorporationInventors: Thomas R. Bierschenk, Timothy Juhulke, Hajimu Kawa, Richard J. Lagow
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Patent number: 5426174Abstract: Hydroxy-functionalized polyoxybutylene ether compositions having improved thermal and oxidative stability are prepared by the polymerization of a mixture of C.sub.4 epoxides in the presence of an organic initiator containing hydroxy groups.Type: GrantFiled: June 10, 1994Date of Patent: June 20, 1995Assignee: ARCO Chemical Technology, L.P.Inventors: Daniel B. Pourreau, Thomas P. Farrell, Michael J. Cannarsa
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Patent number: 5340916Abstract: The present invention relates to a process for the preparation of a hard foam containing urethane groups or urethane and isocyanurate groups by the polyisocyanate polyaddition process, by reactinga) a polyoxypropylene- or polyoxyethylene-polyoxypropylene-polyol containing secondary hydroxyl groups, having a functionality of from 3.5 to 4.3, a hydroxyl number of from 350 to 650 and a viscosity of from 500 to 2,500 mPa.multidot.s at 23.degree. C.Type: GrantFiled: October 26, 1992Date of Patent: August 23, 1994Assignee: BASF AktiengesellschaftInventors: Rolf Henn, Werner Hinz, Ludwig Schuster, Klaus Vorspohl
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Patent number: 5290912Abstract: The present invention has an object of producing a polyoxyalkylene compound by ring-opening polymerization of an alkylene oxide to a certain specific highly hydrophobic initiator. The present invention provides a process for producing a polyoxyalkylene compound, characterized in that the polyoxyalkylene compound is produced by ring-opening polymerization of an alkylene oxide, in the presence of a plural metal cyanide complex catalyst, with an initiator selected from an organopolysiloxane compound having an active hydrogen-containing functional group to which an alkylene oxide is reactive, and a fluorine-containing compound having such an active hydrogen-containing functional group and a fluorinated hydrocarbon group.Type: GrantFiled: January 10, 1992Date of Patent: March 1, 1994Assignee: Asahi Glass Company Ltd.Inventors: Takashi Watabe, Hiromitsu Takeyasu, Shigeyuki Kozawa
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Patent number: 5077033Abstract: Balanced pH, thermo-irreversible gels are ideal vehicles for drug delivery to the eye of a mammal.Type: GrantFiled: August 7, 1990Date of Patent: December 31, 1991Assignee: Mediventures Inc.Inventors: Tacey X. Viegas, Lorraine E. Reeve, Raymond L. Henry
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Patent number: 4931506Abstract: An antistatic additive for PVC, or other chlorine containing polymers, or polystyrene and/or other styrene containing polymers, including but not limited to polymers of styrene and acrylonitrile, such as ABS (acrylonitrile-butadiene-styrene) or mixtures thereof and blends of any of these, wherein the antistatic additive includes, at least in part, ethylene oxide and epihalohydrin. The antistatic additive is semicrystalline, and the ethylene oxide component is in a range of from about 60% to 95% by weight, preferably 80% to 95% by weight, and the epihalohydrin component is in a range of from about 5% to about 40% by weight, preferably 5% to 20% by weight. Optionally, up to 25% of the additive can include, as a replacement for epihalohydrin, one or more 1,2-epoxides.Type: GrantFiled: July 15, 1988Date of Patent: June 5, 1990Assignee: The B. F. Goodrich CompanyInventor: Simon H. Yu
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Patent number: 4855403Abstract: Capped connected branch copolymers are provided comprising a core segment, branched polymer segments attached to the core segment, linear polymer segments attached to the terminals of the branched polymer segments, and cap segments, which comprise residues of an alkylene oxide containing at least 4 carbon atoms and which are attached to the free terminals of the linear polymer segments. These capped copolymers are less water-soluble than the uncapped connected branched copolymers from which they are derived, and are useful in carbonless copying systems as carriers for the color precursor microcapsules. The microcapsules can be applied to the carbonless copying sheet by dispersing the microcapsules in the capped copolymer, heating the copolymer above its transition temperature and spreading the melted copolymer over the sheet. After cooling, the copolymer forms a coherent layer on the sheet.Type: GrantFiled: August 22, 1985Date of Patent: August 8, 1989Assignee: Union Carbide CorporationInventors: Debra J. Meschke, Kenneth L. Hoy
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Patent number: 4799980Abstract: An improved multifunctional polyalkylene oxide binder is obtained by tailoring the cross-linking with a multifunctional polyol having a functionality of 3 or more and a molecular weight from about 12,000 to about 27,000 daltons. The binder is useful in forming castable propellants and plastic-bonded explosive compositions having high tensile strength and elongation and low volume dilatation.Type: GrantFiled: January 28, 1988Date of Patent: January 24, 1989Inventor: Russell Reed, Jr.
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Patent number: 4658011Abstract: A process for the polymerization of oxazolines and copolymerization of oxazolines with epoxy resins in the presence of catalytic amounts of cationic complexes of alkali metals and alkaline earth metals is disclosed.Type: GrantFiled: August 15, 1985Date of Patent: April 14, 1987Assignee: Ashland Oil, Inc.Inventor: Anil B. Goel
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Patent number: 4622349Abstract: Described herein are compositions suitable for photocopolymerization comprising (a) an epoxide containing two or more epoxy groups, and (b) a hydroxyl substituted cycloaliphatic monoepoxide. The composition may additionally contain a poly (active hydrogen) organic compound and/or a photoinitiator. A coating produced from such a composition has a good combination of properties. Especially preferred are compositions further containing a vinyl cycloaliphatic monoepoxide and diazonium or onium photoinitiator.Type: GrantFiled: February 7, 1983Date of Patent: November 11, 1986Assignee: Union Carbide CorporationInventors: Joseph V. Koleske, Neil J. McCarthy, Jr.
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Patent number: 4618442Abstract: Protection of plants against freeze damage by treatment with about 0.05 to about 2.5 wt. % aqueous solution of water soluble nonionic surface active polyoxyethylenated polyoxypropylene block copolymers, optionally also containing urea.Type: GrantFiled: October 7, 1985Date of Patent: October 21, 1986Inventors: Robert J. Geary, Robert J. Geary, III
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Patent number: 4388209Abstract: The present invention describes the production of high molecular weight polyglycidyl ethers.Type: GrantFiled: March 27, 1981Date of Patent: June 14, 1983Assignee: Henkel CorporationInventor: Edgar R. Rogier
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Patent number: 4339389Abstract: The present invention describes the production of high molecular weight polyglycidyl ethers.Type: GrantFiled: October 4, 1979Date of Patent: July 13, 1982Assignee: Henkel CorporationInventor: Edgar R. Rogier
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Patent number: 4315830Abstract: A method for altering the characteristics of liquid telechelic polymers by means of reducing the reactive group content and adjusting the viscosity of a given liquid telechelic polymer. This is accomplished by means of a two stage process which comprises reacting some of the polymer's available reactive groups with a difunctional reactant and adding a diluent to produce a final composition of desired viscosity and reactive group content.Type: GrantFiled: January 19, 1972Date of Patent: February 16, 1982Assignee: The United States of America as represented by the Secretary of the NavyInventors: David M. French, J. T. L. Rosborough, Clyde J. Swedenberg
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Patent number: 4304902Abstract: Disclosed are copolymers of ethylene oxide and epoxy-n-alkane of 12 to 25 carbon atoms. These copolymers exhibit greater viscosity in water or in aqueous acid solutions than do ethylene oxide homopolymers of comparable molecular weight and this greater viscosity is more stable to mechanical shear.Type: GrantFiled: December 19, 1980Date of Patent: December 8, 1981Assignee: Hercules IncorporatedInventor: Leo M. Landoll
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Patent number: 4293675Abstract: The complex formed between a tri-or pentavalent antimony halide and an organic phosphate ester has been found to be an effective catalyst for cationic polymerization reactions.Type: GrantFiled: February 26, 1980Date of Patent: October 6, 1981Assignee: Minnesota Mining and Manufacturing CompanyInventors: Robert J. Blachunis, Stephen W. Bany
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Patent number: 4284745Abstract: A saturated cross-linkable binder composition adapted for preparing coatings having a non-glossy surface is disclosed which comprises:(a) at least one cross-linkable resin selected from the group consisting of saturated polyester resins and epoxide resins;(b) a cross-linking agent wherein the functional groups are selected from the group consisting of acid groups and acid anhydride groups and, in case the cross-linkable resin is a saturated polyester resin, also masked isocyanate groups; and,(c) having associated therewith a salt of an at least bivalent metal ion and an organic acid anion selected from the group consisting of carboxylic anions and acetylacetonate.These binder compositions are particularly useful as binding agents in powderous paint compositions which yield a paint coating having a non-glossy and textured surface.Type: GrantFiled: March 26, 1979Date of Patent: August 18, 1981Assignee: Rhone-Poulenc IndustriesInventors: Jacques Meyer, Daniel Bernelin
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Patent number: 4275244Abstract: Linear polypropylene ether glycols of high molecular weight are made by reacting a linear polypropylene ether glycol of lower molecular weight first with an alkaline agent such as sodium hydroxide or other suitable base to form an alcoholate, and then coupling the alcoholate with a suitable difunctional coupling agent, such as the benzene-sulfonic acid diester of ethylene glycol or with some other suitable arylsulfonic acid diester of a C.sub.2 to C.sub.6 alcohol, thereby obtaining a 100 percent linear polypropylene ether glycol of a desirably higher molecular weight. Materials so produced find use in an aqueous medium as defoaming agents, thickeners, or emulsifiers, and use as protective colloids to improve the low-temperature stability of polyurethane and other latices.Type: GrantFiled: July 13, 1979Date of Patent: June 23, 1981Assignee: BASF Wyandotte CorporationInventors: Herbert Helfert, Pauls Davis
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Patent number: 4259474Abstract: The sulfur-containing polyoxyalkylenes having the formula: ##STR1## wherein E is --SW or a halogen atom; W is hydrogen, phenyl, alkyl of 1 to 4 carbon atoms, an alkali metal or ammonium ion, or a heterocyclic radical containing from 2 to 4 hetero atoms in a 5-or 6-membered ring which may be monocyclic or may be fused to an aromatic ring; A, C and D represent lower alkylene of 2 to 4 carbon atoms; B is alkylene of 2 to 8 carbon atoms; y and z are each integers having a value of 0 to 50; x is an integer having a value of from 2 to 50; and n is an integer having a value of from 1 to 30; and intermixtures of said polyoxyalkylenes.The above compounds display a wide variety of uses; however, all are active metal working lubricants.Type: GrantFiled: September 25, 1979Date of Patent: March 31, 1981Assignee: GAF CorporationInventors: Paritosh M. Chakrabarti, Lindley S. Wood, David J. Tracy
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Patent number: 4256904Abstract: Terminally unsaturated liquid epihalohydrin polymers are produced by polymerizing at least one epihalohydrin using acrylic acid or methacrylic acid as a modifier. The polymerization is conducted in the presence of a catalytic amount of a trialkyl oxonium salt of an HMF.sub.6 acid wherein M is an element selected from the group consisting of phosphorus, arsenic and antimony. The polymers are useful as tougheners for unsaturated polyester resin systems.Type: GrantFiled: September 6, 1979Date of Patent: March 17, 1981Assignee: The B. F. Goodrich CompanyInventor: Changkiu K. Riew
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Patent number: 4256910Abstract: Terminally unsaturated liquid epihalohydrin polymers are produced by polymerizing at least one epihalohydrin using hydroxyalkyl acrylate or methacrylates as a modifier. The polymerization is conducted in the presence of a catalytic amount of a trialkyl oxonium salt of an HMF.sub.6 acid wherein M is an element selected from the group consisting of phosphorus, arsenic and antimony. The polymers are useful as tougheners for unsaturated polyester resin systems.Type: GrantFiled: September 6, 1979Date of Patent: March 17, 1981Assignee: The B. F. Goodrich CompanyInventor: Chin C. Hsu
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Patent number: 4255561Abstract: The sulfide polymers of polyoxyalkylenes having the formula: ##STR1## wherein M is alkyl of from 1 to 4 carbon atoms, benzyl, phenyl, hydrogen or an alkali metal or ammonium ion; A, C and D represent lower alkylene of 2 to 4 carbon atoms; B is alkylene of 2 to 8 carbon atoms; y and z are each integers having a value of 0 to 50; x is an integer having a value of from 1 to 50; n is an integer having a value of 1 to 30; and m has a value of from 2 to 10; and intermixtures of said polyoxyalkylene sulfide polymers.The above polymers have excellent antioxidating properties and are useful as synthetic metal working lubricants, antistatic agents and antioxidants for various other types of applications. They can also be used as crosslinking agents to impart oxidation resistance and static elimination.Type: GrantFiled: September 25, 1979Date of Patent: March 10, 1981Assignee: GAF CorporationInventors: Lindley S. Wood, David J. Tracy, Paritosh M. Chakrabarti
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Patent number: 4230827Abstract: Impact resistance of PVC is shown to be improved by blending therewith polymers derived from monomer systems comprised of at least about 80 percent by weight ethylene oxide. Polymers of at least about 80 percent ethylene oxide and about 0.1 to 2 percent of a symmetrical diepoxide as crosslinking agent are also disclosed.Type: GrantFiled: December 6, 1978Date of Patent: October 28, 1980Assignee: Rohm and Haas CompanyInventor: Robert M. Myers
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Patent number: 4230612Abstract: A lubricant for use in the processing of plastics is disclosed. The lubricant comprises a polyalkylene oxide made from a monomer selected from the group consisting of aliphatic, non-substituted, 1,2-alkylene oxides containing from about six to about 40 carbon atoms, and mixtures thereof, said polyalkylene oxide having an average molecular weight from about 1,000 to about 6,000. Also disclosed is a process for using such lubricants in the shaping of thermoplastic polymers.Type: GrantFiled: January 11, 1979Date of Patent: October 28, 1980Assignee: Akzona IncorporatedInventors: Heinz Praetorius, Karl Seibert, Werner Holtvoigt
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Patent number: 4200701Abstract: A polymeric material which comprises an amorphous solid solution formed between a metallic compound and a polymer by virtue of ether, thioether or urethane linkages contained therein, the metal of the metallic compound being selected from the group consisting of Be, Mg, Sr, Ba, Sc, Y, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, In, Sn, Sb, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Tl, Pb, Bi, Al, La and the other lanthanides.Type: GrantFiled: August 29, 1977Date of Patent: April 29, 1980Assignee: National Research Development CorporationInventors: Raymond E. Wetton, David B. James
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Patent number: 4195167Abstract: Polymers which comprise polymer chains along which the proportion of mer units provided by a first heterocyclic monomer gradually increases in a given chain length as the proportion of mer units provided by a second heterocyclic monomer gradually decreases along said chain length. In one form, the portions of the polymers adjacent one end of the given chain lengths have about 100% of mer units provided by the first monomer and about 0% of mer units provided by the second monomer and the portions adjacent the other end of the given chain lengths have about 0% of mer units provided by the first monomer and about 100% of mer units provided by the second monomer. Additional forms of polymers are disclosed.Type: GrantFiled: November 9, 1978Date of Patent: March 25, 1980Assignee: Union Carbide CorporationInventors: Robert J. Knopf, Kenneth L. Hoy
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Patent number: 4159975Abstract: A lubricant for use in the processing of plastics is disclosed. The lubricant comprises a polyalkylene oxide made from a monomer selected from the group consisting of aliphatic, non-substituted, 1,2-alkylene oxides containing from about six to about 40 carbon atoms, and mixtures thereof, said polyalkylene oxide having an average molecular weight from about 1,000 to about 6,000. Also disclosed is a process for using such lubricants in the shaping of thermoplastic polymers.Type: GrantFiled: December 14, 1977Date of Patent: July 3, 1979Assignee: Akzona IncorporatedInventors: Heinz Praetorius, Karl Seibert, Werner Holtvoigt
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Patent number: RE31468Abstract: Terminally unsaturated liquid epihalohydrin polymers are produced by polymerizing at least one epihalohydrin using hydroxyalkyl acrylate or methacrylates as a modifier. The polymerization is conducted in the presence of a catalytic amount of a trialkyl oxonium salt of an HMF.sub.6 acid wherein M is an element selected from the group consisting of phosphorus, arsenic and antimony. The polymers are useful as tougheners for unsaturated polyester resin systems.Type: GrantFiled: March 15, 1983Date of Patent: December 20, 1983Assignee: The B. F. Goodrich CompanyInventor: Chin C. Hsu
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Patent number: RE31469Abstract: Terminally unsaturated liquid epihalohydrin polymers are produced by polymerizing at least one epihalohydrin using acrylic acid or methacrylic acid as a modifier. The polymerization is conducted in the presence of a catalytic amount of a trialkyl oxonium salt of an HMF.sub.6 acid wherein M is an element selected from the group consisting of phosphorus, arsenic and antimony. The polymers are useful as tougheners for unsaturated polyester resin systems.Type: GrantFiled: March 15, 1983Date of Patent: December 20, 1983Assignee: The B. F. Goodrich CompanyInventor: Changkiu K. Riew