Two Or More Heterocyclic Reactants Containing Rings Of One Oxygen And Two Carbon Atoms Patents (Class 528/419)
  • Patent number: 6133211
    Abstract: Block copolyethers having general formula (I):RX--(CH.sub.2 --CHR.sub.1 --O--).sub.x --(--CH.sub.2 CHR.sub.2 --O--).sub.y --(--CH.sub.2 --CHR.sub.3 --O--).sub.z --R.sub.4wherein:R is selected from H, alkyl, alkylaryl;X is selected from O, S and N;R.sub.1, R.sub.2 and R.sub.3 are selected from H, CH.sub.3, and C.sub.2 -C.sub.10 alkyl radicals;R.sub.4 is selected from H, alkyl, acyl;x,y,z represent the number of ether units and are integers which have such values that the molecular weight of the compound having general formula (I) is between 600 and 4000, and in addition (x+z)/y is between 1.5 and 5.0; with the proviso that:a) either R.sub.1 and R.sub.3 are selected from H and CH.sub.3, in which case R.sub.2 is selected from C.sub.2 to C.sub.10 alkyl radicals,b) or R.sub.1 and R.sub.3 are selected from C.sub.2 -C.sub.10 alkyl radicals, in which case R.sub.2 is selected from H and CH.sub.3.
    Type: Grant
    Filed: October 30, 1997
    Date of Patent: October 17, 2000
    Assignee: Agip Petroli S.p.A.
    Inventors: Sandra Cobianco, Alessandro Lezzi, Alberto Forlini, Emilio Gatti
  • Patent number: 6124418
    Abstract: The invention provides a method for making a curable epoxysilicone composition through the hydrosilation reaction between an ethylenically unsaturated epoxide and an SiH-containing silicone to produce an epoxysilicone product, and catalyzed by a quaternary ammonium, phosphonium or arsonium hexahaloplatinate which does not promote the oxirane ring-opening reaction of either the ethylenically unsaturated epoxide starting material or the epoxysilicone product. The invention also provides for a curable epoxysilicone composition made by the above method.
    Type: Grant
    Filed: February 14, 1994
    Date of Patent: September 26, 2000
    Assignee: General Electric Company
    Inventors: James Vincent Crivello, Mingxin Fan
  • Patent number: 6103850
    Abstract: There is provided an sealant made with an isocyanate or hydroxyl terminated prepolymer made by reacting a stoichiometric excess of an organic polyisocyanate with polyols made of at least a polyoxyalkylene polyether triol or a mixture thereof with a polyoxyalkylene polyether diol. The triol or diol has within its structure the nucleus of an initiator compound, an internal blocks of oxypropylene groups, and external blocks of oxyalkylene groups, wherein the internal blocks of oxypropylene are between said nucleus and said external blocks, said external blocks are made of oxyalkylene groups derived from a C.sub.4 or higher alkylene oxide. The amount of the internal blocks of oxypropylene groups is from 25 weight percent to 80 weight percent based on the weight of all oxyalkylene groups and initiator in the prepolymer The triol or diol has a compatibility index of 25.degree. C. or less, and may be part of a two component or a one component moisture cured sealant.
    Type: Grant
    Filed: November 21, 1996
    Date of Patent: August 15, 2000
    Assignee: BASF Corporation
    Inventors: Curtis J. Reichel, Thomas L. Fishback, Gladys M. Aviles
  • Patent number: 6069210
    Abstract: A composition comprising a particulate solid and a dispersant which is a phosphate ester of a compound of formula 1: ##STR1## wherein Y is methoxy or H--(EO).sub.q, m and q are each independently from 5 to 50 and n is from 5 to 70. When Y is a methoxy, n is preferably 20 and m is preferably 10. When Y is H--(EO).sub.q, m and q are preferably 13 and n is preferably 30.
    Type: Grant
    Filed: November 4, 1998
    Date of Patent: May 30, 2000
    Assignee: Zeneca Limited
    Inventors: David John Cartridge, Dean Thetford
  • Patent number: 6051627
    Abstract: A dispersant which is a phosphate ester of a polyalkylene ether block copolymer of formula MeO(C.sub.2 H.sub.4 O).sub.m (C.sub.3 H.sub.6 O).sub.n --H wherein m and n are each, independently, 2 to 60 and use in aqueous based paints and printing inks.
    Type: Grant
    Filed: June 1, 1998
    Date of Patent: April 18, 2000
    Assignee: Zeneca Limited
    Inventors: Dean Thetford, Mark Holbrook
  • Patent number: 6034208
    Abstract: Unique, well defined macromonomers containing hydroxyl-functionality, unsaturation-functionality, and polyoxyalkylene segments are prepared by oxyalkylating an unsaturated initiator molecule having at least one oxyalkylatable hydrogen in the presence of an effective amount of a double metal cyanide complex catalyst, optionally, when necessary, in the presence of a free radical polymerization inhibitor. The resulting unsaturated macromonomers are eminently suitable for such uses as copolymerization with ethylenically unsaturated monomers containing carboxylic acid-based groups such as acrylic acid to form effective superplasticizers and water reducers for cement and concrete applications.
    Type: Grant
    Filed: May 8, 1998
    Date of Patent: March 7, 2000
    Assignee: Arco Chemical Technology, L.P.
    Inventors: Kenneth G. McDaniel, Edward T. Shawl, Xinhau Zhou
  • Patent number: 5998574
    Abstract: Thus, there is provided according to the present invention polyol compositions comprising(A) a polytetramethylene ether glycol, and(B) a difunctional active hydrogen compound-initiated polyoxyalkylene polyether polyol having a degree of unsaturation of not greater than 0.04 milliequivalents per gram of said polyether polyol.
    Type: Grant
    Filed: July 10, 1996
    Date of Patent: December 7, 1999
    Assignee: BASF Corporation
    Inventors: Thomas L. Fishback, Curtis J. Reichel, Thomas B. Lee
  • Patent number: 5998559
    Abstract: A single-ion electrolyte achieves conductivity greater than 10.sup.-3 S/cm at 20.degree. C. by employing repeating mer units which are functionalized by fluoroalkylsulfonate groups. Preferred backbones for the electrolyte include polysiloxanes, polymethacrylates and poly(alkylene oxides). More preferred backbones have the structure ##STR1## wherein A is selected from the group consisting of C and Si such that when A is C then R.sup.4 is (CH.sub.2).sub.1-100' and when A is Si then R.sup.4 is O; R.sup.1 and R.sup.2 are independently selected from the group consisting of hydrogen, lower alkyl, lower alkoxy, fluorinated lower alkyl, fluorinated lower alkoxy, and fluoroalkylsulfonate; and R.sup.3 is null or selected from the group consisting of O, (O).sub.1-100, O--CH.sub.2, (O).sub.1-100 --(CH.sub.2).sub.1-100.
    Type: Grant
    Filed: August 15, 1996
    Date of Patent: December 7, 1999
    Assignee: SRI International
    Inventors: Subhash C. Narang, Susanna C. Ventura
  • Patent number: 5981624
    Abstract: A reduced shade paint or ink comprising(a) a base paint or ink comprising a base pigment such as titanium dioxide, a film-forming resin and a non-polar liquid such as white spirits;(b) one or more dispersant which is a phosphate ester of a compound of formula 1 ##STR1## wherein Y is a group RO-- or a group H--(EO).sub.q --;R is C.sub.1-10 -alkyl;m and q are each, independently, from 5 to 50;n is from 5 to 70; and(c) a tinter composition comprising a colored pigment, water and/or a water-miscible solvent such as ethyleneglycol.
    Type: Grant
    Filed: November 4, 1997
    Date of Patent: November 9, 1999
    Inventors: Dean Thetford, David J. Cartridge
  • Patent number: 5891960
    Abstract: Coating compositions comprised of a film forming polymer which is the reaction product of (a) a compound containing pendant and/or terminal hydroxyl or epoxy functional groups and (b) citric acid or citric acid anhydride. The coating compositions have enhanced adhesion to galvanized and galvanealed steel substrates without the use of a chrome containing wash primer.
    Type: Grant
    Filed: September 12, 1997
    Date of Patent: April 6, 1999
    Assignee: PPG Industries, Inc.
    Inventors: James A. Claar, Karl F. Schimmel, Shanti Swarup, Bruce A. Connelly
  • Patent number: 5854386
    Abstract: Unique, well defined polyethers containing both hydroxyl-functionality and unsaturation-functionality are prepared by oxyalkylating an unsaturated monomer having at least one oxyalkylatable hydrogen in the presence of an effective amount of a double metal cyanide complex catalyst, optionally, when necessary, in the presence of a free radical polymerization inhibitor. The resulting polyethers are eminently suitable for such uses as polymer polyol stabilizers or stabilizer precursors, and both in situ and ex situ impact modifiers for thermoplastics.
    Type: Grant
    Filed: August 25, 1997
    Date of Patent: December 29, 1998
    Assignee: ARCO Chemical Technology, L.P.
    Inventors: Jianzhong Shen, Kenneth G. McDaniel, John E. Hayes, Uli B. Holeschovsky, Harry R. Hinney
  • Patent number: 5792829
    Abstract: Polyurethane elastomers exhibiting improved green strength while maintaining short demold times are prepared from ultra-low unsaturation polyoxypropylene polyols containing up to 20 weight percent internal random oxyethylene moieties. The elastomers adsorb less than 10 weight percent water at 0.degree. C. The internal polyoxyethylene moiety-containing polyoxypropylene polyols may be used to prepare ultra-low unsaturation polyoxyethylene capped polyols which are haze-free and which may be used to prepare haze-free 4,4'-MDI prepolymers. Multidisperse blends of monodisperse internal oxyethylene moiety-containing polyoxypropylene polyols of ultra-low unsaturation provide yet further improvements in elastomer processing.
    Type: Grant
    Filed: June 3, 1997
    Date of Patent: August 11, 1998
    Assignee: ARCO Chemical Technology, L.P.
    Inventors: Gary L. Allen, Nigel Barksby, Bruce H. Isaacs, Leah J. Langsdorf, Stephen D. Seneker
  • Patent number: 5789626
    Abstract: Highly active double metal cyanide (DMC) catalysts are disclosed. The catalysts comprise a DMC complex, and organic complexing agent, and from about 5 to about 80 wt. %, based on the amount of catalyst, of a polyether having a number average molecular weight less than about 500. The catalysts polymerize propylene oxide at a rate in excess of about 1 kg PO/g Co/min. at 100 ppm catalyst, based on the weight of finished polyether, at 105.degree. C. The catalysts, which are easy to prepare, give polyether polyols with exceptionally low unsaturation levels.
    Type: Grant
    Filed: January 8, 1997
    Date of Patent: August 4, 1998
    Assignee: Arco Chemical Technology, L.P.
    Inventor: Bi Le-Khac
  • Patent number: 5731407
    Abstract: Improved double metal cyanide catalysts are disclosed. The substantially amorphous catalysts of the invention are more active for polymerizing epoxides than conventional DMC catalysts, which have a substantial crystalline component. Polyol products made with the catalysts are unusually clear, have exceptionally low unsaturations, and contain no detectable amount of low molecular weight polyol impurities. A method of making the improved DMC catalysts, which involves intimately combining the reactants, is also disclosed.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 24, 1998
    Assignee: Arco Chemical Technology, L.P.
    Inventor: Bi Le-Khac
  • Patent number: 5719257
    Abstract: The invention relates to polyethers of the formula I ##STR1## in which m is 0 or 1; n is an integer in the range from 3 to 100; R.sup.1, in the case where m is 0 or 1, is C.sub.1 -C.sub.36 alkyl or C.sub.7 -C.sub.36 aralkyl, each of which is unsubstituted or substituted by C.sub.5 -C.sub.8 cycloalkyl, is interrupted in the aliphatic part by C.sub.5 -C.sub.8 cycloalkylene or by oxygen or sulfur or --NR.sup.11 -- or is substituted in the aromatic part by 1 to 3 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; C.sub.3 -C.sub.36 alkenyl; C.sub.5 -C.sub.12 cycloalkyl which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; C.sub.6 -C.sub.10 aryl which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; and R.sup.1, in the case where m is 0, can alternatively be hydrogen; C.sub.1 -C.sub.36 alkoxy or C.sub.7 -C.sub.36 aralkoxy, each of which is unsubstituted or substituted by C.sub.5 -C.sub.
    Type: Grant
    Filed: October 2, 1996
    Date of Patent: February 17, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Alfred Steinmann
  • Patent number: 5670612
    Abstract: An aqueous self-emulsifiable epoxy resin curing agent which is produced by reacting, with each other, an (A) polyamine (meta-xylylenediamine, etc), a (B) epoxy group-containing alkoxypolyethylene polyether compound (methoxypolyethyleneglycol glycidyl ether, etc.) having 500 to 5000 average molecular weight, at least one (C) hydrophobic epoxy compound having at least one epoxy group in the molecule (butyl glycidyl ether, epoxy resin of type bisphenol A or F, etc.) and optionally, a (D) unsaturated compound capable of addition reaction (acrylonitrile, methyl methacrylate, etc.), in a molar quantity of the epoxy group in (B) of 0.001 to 0.1 mol and in a molar quantity of the sum of the epoxy group in (C) and the unsaturated group in (D) of 0.2 to 0.5 mol, each based on 1 mol of a hydrogen atom bonded to a nitrogen atom in (A) which is capable of reacting with an epoxy group or a unsaturated group.
    Type: Grant
    Filed: October 10, 1995
    Date of Patent: September 23, 1997
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Shuta Kihara, Shinichi Yonehama, Kiichiro Seki
  • Patent number: 5616637
    Abstract: The invention relates to polyethers of the formula I ##STR1## in which m is 0 or 1; n is an integer in the range from 3 to 100; R.sup.1, in the case where m is 0 or 1, is C.sub.1 -C.sub.36 alkyl or C.sub.7 -C.sub.36 aralkyl, each of which is unsubstituted or substituted by C.sub.5 -C.sub.8 cycloalkyl, is interrupted in the aliphatic part by C.sub.5 -C.sub.8 cycloalkylene or by oxygen or sulfur or --NR.sup.11 -- or is substituted in the aromatic part by 1 to 3 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; C.sub.3 -C.sub.36 alkenyl; C.sub.5 -C.sub.12 cycloalkyl which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; C.sub.6 -C.sub.10 aryl which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; and R.sup.1, in the case where m is 0, can alternatively be hydrogen; C.sub.1 -C.sub.36 alkoxy or C.sub.7 -C.sub.36 aralkoxy, each of which is unsubstituted or substituted by C.sub.5 -C.sub.
    Type: Grant
    Filed: March 13, 1996
    Date of Patent: April 1, 1997
    Assignee: Ciba-Geigy Corporation
    Inventor: Alfred Steinmann
  • Patent number: 5594097
    Abstract: Polyether polyol comprising as alkylene oxide units ethylene oxide and propylene oxide units, said polyol having a nominal average hydroxyl functionality of 2-6, an hydroxyl value of 16-45 mg KOH/g, a primary hydroxyl content of at least 50% calculated on the total amount of hydroxyl groups and an amount of ethylene oxide units, calculated on the weight of the alkylene oxide units in the polyol, of 21-49% by weight these polyols are useful for making flexible foam.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: January 14, 1997
    Assignee: Imperial Chemical Industries PLC
    Inventors: Pierre G. Chaffanjon, Peter F. Stroobants, Gerhard J. Bleys
  • Patent number: 5563221
    Abstract: A process for making high-primary, low-unsaturation polyols is disclosed. A polyol made by double metal cyanide (DMC) catalysis is blended with a polyol made by basic catalysis, and the polyol blend is reacted with ethylene oxide to produce an ethylene oxide-capped potyol. The process overcomes problems of the conventional recatalysis approach to making EO-capped polyols from DMC-catalyzed polyols.
    Type: Grant
    Filed: June 21, 1995
    Date of Patent: October 8, 1996
    Assignee: ARCO Chemical Technology, L.P.
    Inventor: Jos e F. Pazos
  • Patent number: 5534618
    Abstract: The invention relates to polyethers containing recurring units of the formula I ##STR1## in which A is --CH.sub.2 -- or --CO--, and, when A is methylene, E is ##STR2## and when A is carbonyl, E is ##STR3## R.sup.1 is hydrogen, and R.sup.2 is likewise hydrogen or an aromatic, aliphatic or araliphatic carbonyloxy radical or a corresponding radical of an ether or tertiary amine, or R.sup.1 and R.sup.2 together are a.dbd.O substituent or together with the carbon atom to which they are bonded are a five- or six-membered, substituted, oxygen- and/or nitrogen-containing heterocyclic ring, andR.sup.17 is a hydrocarbon radical having a maximum of 18 carbon atoms.The polyethers according to the invention can advantageously be employed for the stabilization of organic material against the harmful effect of light, oxygen and/or heat.
    Type: Grant
    Filed: July 7, 1994
    Date of Patent: July 9, 1996
    Assignee: Ciba-Geigy Corporation
    Inventor: Alfred Steinmann
  • Patent number: 5521282
    Abstract: The invention relates to polyethers of the formula I ##STR1## in which m is 0 or 1; n is an integer in the range from 3 to 100; R.sup.1, in the case where m is 0 or 1, is C.sub.1 -C.sub.36 alkyl or C.sub.7 -C.sub.36 aralkyl, each of which is unsubstituted or substituted by C.sub.5 -C.sub.8 cycloalkyl, is interrupted in the aliphatic part by C.sub.5 -C.sub.8 cycloalkylene or by oxygen or sulfur or --NR.sup.11 -- or is substituted in the aromatic part by 1 to 3 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; C.sub.3 -C.sub.36 alkenyl; C.sub.5 -C.sub.12 cycloalkyl which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; C.sub.6 -C.sub.10 aryl which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub. alkoxy radicals; and R.sup.1, in the case where m is 0, can alternatively be hydrogen; C.sub.1 -C.sub.36 alkoxy or C.sub.7 -C.sub. 36 aralkoxy, each of which is unsubstituted or substituted by C.sub.5 -C.sub.
    Type: Grant
    Filed: July 7, 1994
    Date of Patent: May 28, 1996
    Assignee: Ciba-Geigy Corporation
    Inventor: Alfred Steinmann
  • Patent number: 5506309
    Abstract: This invention pertains to perfluoropolyethers and perhalogenated chlorofluoropolyethers that can be prepared by fluorinating addition polymers made by polymerizing epoxides.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: April 9, 1996
    Assignee: Exfluor Research Corporation
    Inventors: Thomas R. Bierschenk, Timothy Juhulke, Hajimu Kawa, Richard J. Lagow
  • Patent number: 5426174
    Abstract: Hydroxy-functionalized polyoxybutylene ether compositions having improved thermal and oxidative stability are prepared by the polymerization of a mixture of C.sub.4 epoxides in the presence of an organic initiator containing hydroxy groups.
    Type: Grant
    Filed: June 10, 1994
    Date of Patent: June 20, 1995
    Assignee: ARCO Chemical Technology, L.P.
    Inventors: Daniel B. Pourreau, Thomas P. Farrell, Michael J. Cannarsa
  • Patent number: 5340916
    Abstract: The present invention relates to a process for the preparation of a hard foam containing urethane groups or urethane and isocyanurate groups by the polyisocyanate polyaddition process, by reactinga) a polyoxypropylene- or polyoxyethylene-polyoxypropylene-polyol containing secondary hydroxyl groups, having a functionality of from 3.5 to 4.3, a hydroxyl number of from 350 to 650 and a viscosity of from 500 to 2,500 mPa.multidot.s at 23.degree. C.
    Type: Grant
    Filed: October 26, 1992
    Date of Patent: August 23, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Rolf Henn, Werner Hinz, Ludwig Schuster, Klaus Vorspohl
  • Patent number: 5290912
    Abstract: The present invention has an object of producing a polyoxyalkylene compound by ring-opening polymerization of an alkylene oxide to a certain specific highly hydrophobic initiator. The present invention provides a process for producing a polyoxyalkylene compound, characterized in that the polyoxyalkylene compound is produced by ring-opening polymerization of an alkylene oxide, in the presence of a plural metal cyanide complex catalyst, with an initiator selected from an organopolysiloxane compound having an active hydrogen-containing functional group to which an alkylene oxide is reactive, and a fluorine-containing compound having such an active hydrogen-containing functional group and a fluorinated hydrocarbon group.
    Type: Grant
    Filed: January 10, 1992
    Date of Patent: March 1, 1994
    Assignee: Asahi Glass Company Ltd.
    Inventors: Takashi Watabe, Hiromitsu Takeyasu, Shigeyuki Kozawa
  • Patent number: 5077033
    Abstract: Balanced pH, thermo-irreversible gels are ideal vehicles for drug delivery to the eye of a mammal.
    Type: Grant
    Filed: August 7, 1990
    Date of Patent: December 31, 1991
    Assignee: Mediventures Inc.
    Inventors: Tacey X. Viegas, Lorraine E. Reeve, Raymond L. Henry
  • Patent number: 4931506
    Abstract: An antistatic additive for PVC, or other chlorine containing polymers, or polystyrene and/or other styrene containing polymers, including but not limited to polymers of styrene and acrylonitrile, such as ABS (acrylonitrile-butadiene-styrene) or mixtures thereof and blends of any of these, wherein the antistatic additive includes, at least in part, ethylene oxide and epihalohydrin. The antistatic additive is semicrystalline, and the ethylene oxide component is in a range of from about 60% to 95% by weight, preferably 80% to 95% by weight, and the epihalohydrin component is in a range of from about 5% to about 40% by weight, preferably 5% to 20% by weight. Optionally, up to 25% of the additive can include, as a replacement for epihalohydrin, one or more 1,2-epoxides.
    Type: Grant
    Filed: July 15, 1988
    Date of Patent: June 5, 1990
    Assignee: The B. F. Goodrich Company
    Inventor: Simon H. Yu
  • Patent number: 4855403
    Abstract: Capped connected branch copolymers are provided comprising a core segment, branched polymer segments attached to the core segment, linear polymer segments attached to the terminals of the branched polymer segments, and cap segments, which comprise residues of an alkylene oxide containing at least 4 carbon atoms and which are attached to the free terminals of the linear polymer segments. These capped copolymers are less water-soluble than the uncapped connected branched copolymers from which they are derived, and are useful in carbonless copying systems as carriers for the color precursor microcapsules. The microcapsules can be applied to the carbonless copying sheet by dispersing the microcapsules in the capped copolymer, heating the copolymer above its transition temperature and spreading the melted copolymer over the sheet. After cooling, the copolymer forms a coherent layer on the sheet.
    Type: Grant
    Filed: August 22, 1985
    Date of Patent: August 8, 1989
    Assignee: Union Carbide Corporation
    Inventors: Debra J. Meschke, Kenneth L. Hoy
  • Patent number: 4799980
    Abstract: An improved multifunctional polyalkylene oxide binder is obtained by tailoring the cross-linking with a multifunctional polyol having a functionality of 3 or more and a molecular weight from about 12,000 to about 27,000 daltons. The binder is useful in forming castable propellants and plastic-bonded explosive compositions having high tensile strength and elongation and low volume dilatation.
    Type: Grant
    Filed: January 28, 1988
    Date of Patent: January 24, 1989
    Inventor: Russell Reed, Jr.
  • Patent number: 4658011
    Abstract: A process for the polymerization of oxazolines and copolymerization of oxazolines with epoxy resins in the presence of catalytic amounts of cationic complexes of alkali metals and alkaline earth metals is disclosed.
    Type: Grant
    Filed: August 15, 1985
    Date of Patent: April 14, 1987
    Assignee: Ashland Oil, Inc.
    Inventor: Anil B. Goel
  • Patent number: 4622349
    Abstract: Described herein are compositions suitable for photocopolymerization comprising (a) an epoxide containing two or more epoxy groups, and (b) a hydroxyl substituted cycloaliphatic monoepoxide. The composition may additionally contain a poly (active hydrogen) organic compound and/or a photoinitiator. A coating produced from such a composition has a good combination of properties. Especially preferred are compositions further containing a vinyl cycloaliphatic monoepoxide and diazonium or onium photoinitiator.
    Type: Grant
    Filed: February 7, 1983
    Date of Patent: November 11, 1986
    Assignee: Union Carbide Corporation
    Inventors: Joseph V. Koleske, Neil J. McCarthy, Jr.
  • Patent number: 4618442
    Abstract: Protection of plants against freeze damage by treatment with about 0.05 to about 2.5 wt. % aqueous solution of water soluble nonionic surface active polyoxyethylenated polyoxypropylene block copolymers, optionally also containing urea.
    Type: Grant
    Filed: October 7, 1985
    Date of Patent: October 21, 1986
    Inventors: Robert J. Geary, Robert J. Geary, III
  • Patent number: 4388209
    Abstract: The present invention describes the production of high molecular weight polyglycidyl ethers.
    Type: Grant
    Filed: March 27, 1981
    Date of Patent: June 14, 1983
    Assignee: Henkel Corporation
    Inventor: Edgar R. Rogier
  • Patent number: 4339389
    Abstract: The present invention describes the production of high molecular weight polyglycidyl ethers.
    Type: Grant
    Filed: October 4, 1979
    Date of Patent: July 13, 1982
    Assignee: Henkel Corporation
    Inventor: Edgar R. Rogier
  • Patent number: 4315830
    Abstract: A method for altering the characteristics of liquid telechelic polymers by means of reducing the reactive group content and adjusting the viscosity of a given liquid telechelic polymer. This is accomplished by means of a two stage process which comprises reacting some of the polymer's available reactive groups with a difunctional reactant and adding a diluent to produce a final composition of desired viscosity and reactive group content.
    Type: Grant
    Filed: January 19, 1972
    Date of Patent: February 16, 1982
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: David M. French, J. T. L. Rosborough, Clyde J. Swedenberg
  • Patent number: 4304902
    Abstract: Disclosed are copolymers of ethylene oxide and epoxy-n-alkane of 12 to 25 carbon atoms. These copolymers exhibit greater viscosity in water or in aqueous acid solutions than do ethylene oxide homopolymers of comparable molecular weight and this greater viscosity is more stable to mechanical shear.
    Type: Grant
    Filed: December 19, 1980
    Date of Patent: December 8, 1981
    Assignee: Hercules Incorporated
    Inventor: Leo M. Landoll
  • Patent number: 4293675
    Abstract: The complex formed between a tri-or pentavalent antimony halide and an organic phosphate ester has been found to be an effective catalyst for cationic polymerization reactions.
    Type: Grant
    Filed: February 26, 1980
    Date of Patent: October 6, 1981
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Robert J. Blachunis, Stephen W. Bany
  • Patent number: 4284745
    Abstract: A saturated cross-linkable binder composition adapted for preparing coatings having a non-glossy surface is disclosed which comprises:(a) at least one cross-linkable resin selected from the group consisting of saturated polyester resins and epoxide resins;(b) a cross-linking agent wherein the functional groups are selected from the group consisting of acid groups and acid anhydride groups and, in case the cross-linkable resin is a saturated polyester resin, also masked isocyanate groups; and,(c) having associated therewith a salt of an at least bivalent metal ion and an organic acid anion selected from the group consisting of carboxylic anions and acetylacetonate.These binder compositions are particularly useful as binding agents in powderous paint compositions which yield a paint coating having a non-glossy and textured surface.
    Type: Grant
    Filed: March 26, 1979
    Date of Patent: August 18, 1981
    Assignee: Rhone-Poulenc Industries
    Inventors: Jacques Meyer, Daniel Bernelin
  • Patent number: 4275244
    Abstract: Linear polypropylene ether glycols of high molecular weight are made by reacting a linear polypropylene ether glycol of lower molecular weight first with an alkaline agent such as sodium hydroxide or other suitable base to form an alcoholate, and then coupling the alcoholate with a suitable difunctional coupling agent, such as the benzene-sulfonic acid diester of ethylene glycol or with some other suitable arylsulfonic acid diester of a C.sub.2 to C.sub.6 alcohol, thereby obtaining a 100 percent linear polypropylene ether glycol of a desirably higher molecular weight. Materials so produced find use in an aqueous medium as defoaming agents, thickeners, or emulsifiers, and use as protective colloids to improve the low-temperature stability of polyurethane and other latices.
    Type: Grant
    Filed: July 13, 1979
    Date of Patent: June 23, 1981
    Assignee: BASF Wyandotte Corporation
    Inventors: Herbert Helfert, Pauls Davis
  • Patent number: 4259474
    Abstract: The sulfur-containing polyoxyalkylenes having the formula: ##STR1## wherein E is --SW or a halogen atom; W is hydrogen, phenyl, alkyl of 1 to 4 carbon atoms, an alkali metal or ammonium ion, or a heterocyclic radical containing from 2 to 4 hetero atoms in a 5-or 6-membered ring which may be monocyclic or may be fused to an aromatic ring; A, C and D represent lower alkylene of 2 to 4 carbon atoms; B is alkylene of 2 to 8 carbon atoms; y and z are each integers having a value of 0 to 50; x is an integer having a value of from 2 to 50; and n is an integer having a value of from 1 to 30; and intermixtures of said polyoxyalkylenes.The above compounds display a wide variety of uses; however, all are active metal working lubricants.
    Type: Grant
    Filed: September 25, 1979
    Date of Patent: March 31, 1981
    Assignee: GAF Corporation
    Inventors: Paritosh M. Chakrabarti, Lindley S. Wood, David J. Tracy
  • Patent number: 4256910
    Abstract: Terminally unsaturated liquid epihalohydrin polymers are produced by polymerizing at least one epihalohydrin using hydroxyalkyl acrylate or methacrylates as a modifier. The polymerization is conducted in the presence of a catalytic amount of a trialkyl oxonium salt of an HMF.sub.6 acid wherein M is an element selected from the group consisting of phosphorus, arsenic and antimony. The polymers are useful as tougheners for unsaturated polyester resin systems.
    Type: Grant
    Filed: September 6, 1979
    Date of Patent: March 17, 1981
    Assignee: The B. F. Goodrich Company
    Inventor: Chin C. Hsu
  • Patent number: 4256904
    Abstract: Terminally unsaturated liquid epihalohydrin polymers are produced by polymerizing at least one epihalohydrin using acrylic acid or methacrylic acid as a modifier. The polymerization is conducted in the presence of a catalytic amount of a trialkyl oxonium salt of an HMF.sub.6 acid wherein M is an element selected from the group consisting of phosphorus, arsenic and antimony. The polymers are useful as tougheners for unsaturated polyester resin systems.
    Type: Grant
    Filed: September 6, 1979
    Date of Patent: March 17, 1981
    Assignee: The B. F. Goodrich Company
    Inventor: Changkiu K. Riew
  • Patent number: 4255561
    Abstract: The sulfide polymers of polyoxyalkylenes having the formula: ##STR1## wherein M is alkyl of from 1 to 4 carbon atoms, benzyl, phenyl, hydrogen or an alkali metal or ammonium ion; A, C and D represent lower alkylene of 2 to 4 carbon atoms; B is alkylene of 2 to 8 carbon atoms; y and z are each integers having a value of 0 to 50; x is an integer having a value of from 1 to 50; n is an integer having a value of 1 to 30; and m has a value of from 2 to 10; and intermixtures of said polyoxyalkylene sulfide polymers.The above polymers have excellent antioxidating properties and are useful as synthetic metal working lubricants, antistatic agents and antioxidants for various other types of applications. They can also be used as crosslinking agents to impart oxidation resistance and static elimination.
    Type: Grant
    Filed: September 25, 1979
    Date of Patent: March 10, 1981
    Assignee: GAF Corporation
    Inventors: Lindley S. Wood, David J. Tracy, Paritosh M. Chakrabarti
  • Patent number: 4230612
    Abstract: A lubricant for use in the processing of plastics is disclosed. The lubricant comprises a polyalkylene oxide made from a monomer selected from the group consisting of aliphatic, non-substituted, 1,2-alkylene oxides containing from about six to about 40 carbon atoms, and mixtures thereof, said polyalkylene oxide having an average molecular weight from about 1,000 to about 6,000. Also disclosed is a process for using such lubricants in the shaping of thermoplastic polymers.
    Type: Grant
    Filed: January 11, 1979
    Date of Patent: October 28, 1980
    Assignee: Akzona Incorporated
    Inventors: Heinz Praetorius, Karl Seibert, Werner Holtvoigt
  • Patent number: 4230827
    Abstract: Impact resistance of PVC is shown to be improved by blending therewith polymers derived from monomer systems comprised of at least about 80 percent by weight ethylene oxide. Polymers of at least about 80 percent ethylene oxide and about 0.1 to 2 percent of a symmetrical diepoxide as crosslinking agent are also disclosed.
    Type: Grant
    Filed: December 6, 1978
    Date of Patent: October 28, 1980
    Assignee: Rohm and Haas Company
    Inventor: Robert M. Myers
  • Patent number: 4200701
    Abstract: A polymeric material which comprises an amorphous solid solution formed between a metallic compound and a polymer by virtue of ether, thioether or urethane linkages contained therein, the metal of the metallic compound being selected from the group consisting of Be, Mg, Sr, Ba, Sc, Y, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, In, Sn, Sb, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Tl, Pb, Bi, Al, La and the other lanthanides.
    Type: Grant
    Filed: August 29, 1977
    Date of Patent: April 29, 1980
    Assignee: National Research Development Corporation
    Inventors: Raymond E. Wetton, David B. James
  • Patent number: 4195167
    Abstract: Polymers which comprise polymer chains along which the proportion of mer units provided by a first heterocyclic monomer gradually increases in a given chain length as the proportion of mer units provided by a second heterocyclic monomer gradually decreases along said chain length. In one form, the portions of the polymers adjacent one end of the given chain lengths have about 100% of mer units provided by the first monomer and about 0% of mer units provided by the second monomer and the portions adjacent the other end of the given chain lengths have about 0% of mer units provided by the first monomer and about 100% of mer units provided by the second monomer. Additional forms of polymers are disclosed.
    Type: Grant
    Filed: November 9, 1978
    Date of Patent: March 25, 1980
    Assignee: Union Carbide Corporation
    Inventors: Robert J. Knopf, Kenneth L. Hoy
  • Patent number: 4159975
    Abstract: A lubricant for use in the processing of plastics is disclosed. The lubricant comprises a polyalkylene oxide made from a monomer selected from the group consisting of aliphatic, non-substituted, 1,2-alkylene oxides containing from about six to about 40 carbon atoms, and mixtures thereof, said polyalkylene oxide having an average molecular weight from about 1,000 to about 6,000. Also disclosed is a process for using such lubricants in the shaping of thermoplastic polymers.
    Type: Grant
    Filed: December 14, 1977
    Date of Patent: July 3, 1979
    Assignee: Akzona Incorporated
    Inventors: Heinz Praetorius, Karl Seibert, Werner Holtvoigt
  • Patent number: RE31468
    Abstract: Terminally unsaturated liquid epihalohydrin polymers are produced by polymerizing at least one epihalohydrin using hydroxyalkyl acrylate or methacrylates as a modifier. The polymerization is conducted in the presence of a catalytic amount of a trialkyl oxonium salt of an HMF.sub.6 acid wherein M is an element selected from the group consisting of phosphorus, arsenic and antimony. The polymers are useful as tougheners for unsaturated polyester resin systems.
    Type: Grant
    Filed: March 15, 1983
    Date of Patent: December 20, 1983
    Assignee: The B. F. Goodrich Company
    Inventor: Chin C. Hsu
  • Patent number: RE31469
    Abstract: Terminally unsaturated liquid epihalohydrin polymers are produced by polymerizing at least one epihalohydrin using acrylic acid or methacrylic acid as a modifier. The polymerization is conducted in the presence of a catalytic amount of a trialkyl oxonium salt of an HMF.sub.6 acid wherein M is an element selected from the group consisting of phosphorus, arsenic and antimony. The polymers are useful as tougheners for unsaturated polyester resin systems.
    Type: Grant
    Filed: March 15, 1983
    Date of Patent: December 20, 1983
    Assignee: The B. F. Goodrich Company
    Inventor: Changkiu K. Riew