From At Least One Blocked -n=c=x Group Patents (Class 528/45)
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Patent number: 12234315Abstract: A molded product of the present invention includes a polythiourethane, in which an SH group concentration according to an IR analysis method is 0.30 wt % to 3.0 wt %.Type: GrantFiled: March 13, 2020Date of Patent: February 25, 2025Assignee: MITSUI CHEMICALS, INC.Inventors: Yusuke Matsui, Masayuki Furuya, Shinsuke Ito
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Patent number: 12168741Abstract: The present invention relates to a urethane prepolymer having an isocyanate group, a viscosity at 100° C. of 30 to 600 dPa·s, and a thermal softening temperature after moisture curing of 75 to 155° C.Type: GrantFiled: August 24, 2020Date of Patent: December 17, 2024Assignee: DAINICHISEIKA COLOR & CHEMICALS MFG. CO., LTD.Inventors: Ryo Kawamura, Toshiki Yamada, Kazuya Sasaki
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Patent number: 12163047Abstract: The present invention provides an electron beam curable coating composition comprising: an electron beam curable component (A) which contains 10% by mass or more of a multifunctional (meth)acrylate; and a room temperature curable component (B) which contains 1 to 15% by mass of an isocyanate group and is not cured by electron beam irradiation, wherein a solid content mass ratio of the component (B) to a total amount of the components (A) and (B) is 20 to 55% by mass.Type: GrantFiled: October 5, 2021Date of Patent: December 10, 2024Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Kanji Mori, Shuji Yomo, Keiji Ambo, Mamoru Kouzaki, Atsuo Nabeshima, Eiichi Okazaki
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Patent number: 12152103Abstract: The present invention relates to a copolymerized saturated polyester resin and a coating composition containing same. Provided are a copolymerized saturated polyester resin and a coating composition having excellent hot water resistance, chemical resistance and processability when formed into a coating film, and showing excellent adhesiveness to a metal base, and thus particularly useful for coating a can and pre-coated metal (PCM).Type: GrantFiled: January 31, 2019Date of Patent: November 26, 2024Assignee: SK CHEMICALS CO., LTD.Inventors: Hyung-Gon Kim, Jong-Ki Sim, Soon-Ki Kim
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Patent number: 11939437Abstract: A method for producing a fiber for reinforcing rubber, comprising applying an adhesion treatment liquid containing a thermoplastic elastomer, a blocked polyisocyanate, and a rubber latex to a fiber cord to obtain a fiber for reinforcing rubber, wherein the thermoplastic elastomer is incorporated in the form of a water dispersion into the adhesion treatment liquid, wherein the thermoplastic elastomer particles in the water dispersion have an average particle diameter of 0.01 to 1.0 ?m.Type: GrantFiled: December 17, 2019Date of Patent: March 26, 2024Assignee: TEIJIN FRONTIER CO., LTD.Inventor: Yoshifumi Suzuki
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Patent number: 11732083Abstract: A polyisocyanate resin can include from 25 wt % to 50 wt % of a first cycloaliphatic polyisocyanate and from 50 wt % to 75 wt % of a flexibilizing component based on a total weight of the polyisocyanate resin. The first cycloaliphatic polyisocyanate can have an NCO % of from 12 wt % to 20 wt % based on ISO 11909:2007. The flexibilizing component can include a linear aliphatic polyisocyanate having a number average isocyanate functionality of from 2 to 3 based on gel permeation chromatography and an isocyanate-terminated reaction product of a second cycloaliphatic polyisocyanate and an isocyanate-reactive material, the reaction product having a Tg of less than ?30° C. based on a Differential Scanning Calorimetry (2nd Heating) temperature scan from ?100° C. to 150° C. using 20° C./min heating and cooling ramps. The isocyanate-terminated reaction product and the linear aliphatic polyisocyanate can be present at a weight ratio of from 0.5 to 2.5.Type: GrantFiled: November 19, 2020Date of Patent: August 22, 2023Assignee: Covestro LLCInventors: Kurt E. Best, Daniel P. Wang, Joseph Kleer
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Patent number: 11697704Abstract: A novel primer composition contains aldimine and/or epoxy resins, a process of making such primer to be used in glass bonding adhesive kit.Type: GrantFiled: October 27, 2020Date of Patent: July 11, 2023Assignee: DDP Specialty Electronic Materials US, LLCInventors: Niranjan Malvadkar, Daniel P. Sophiea, Jamie M. Weishuhn
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Patent number: 11629218Abstract: The present invention provides a coating film having a structure represented by the following general formula (1) (in the formula, R11 is a residue formed by removing one isocyanate group from a polyisocyanate, and R12 is an alkyl group or an alkoxy group having 2 to 12 carbon atoms, R13 is a residue formed by removing one hydroxyl group from a polyol), wherein a König hardness of the coating film is 20 or more, in an SS curve measurement of a tensile test, the coating film has an elastic deformation region and a plastic deformation region, and in the SS curve measurement, a stress at an inflection point stress between the elastic deformation region and the plastic deformation region is 5 MPa or more.Type: GrantFiled: October 31, 2019Date of Patent: April 18, 2023Assignee: ASAHI KASEI KABUSHIKI KAISHAInventors: Eiko Tanaka, Koichiro Azuma
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Patent number: 11597142Abstract: The present disclosure provides for making annealed additive manufacturing powder, where the powder can be used to make structures using additive manufacturing processes. The additive manufacturing powder can be annealed to improve the flowability of the powder. Once annealed, the powder can be used in the additive manufacturing process and structures can be formed by affixing the powder particles to one another (e.g., by reflowing and re-solidifying a material present in the powder particles). The annealed additive manufacturing powder can be formed in a layer-by-layer additive process to produce articles such as a component of an article of sporting equipment, apparel or footwear (10), including a sole structure (30) for footwear (10).Type: GrantFiled: January 14, 2019Date of Patent: March 7, 2023Assignee: NIKE, INC.Inventors: John Cross, Luis Folgar, Ryan R. Larson
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Patent number: 11535694Abstract: A compound of formula (I) having advantageous properties when used as a latent curing agent for compositions containing isocyanate groups, and to compositions containing the compound of formula (I). The compound of formula (I) is odourless, is liquid and has comparatively low viscosity at room temperature and is stable in storage together with isocyanates. It makes possible odourless single-component polyurethane compositions which have good stability in storage, do not produce bubbles when cured in the presence of moisture, and cause no problematic odour emissions, giving a cured elastic material having good mechanical properties, good heat stability, a surprisingly non-adhesive surface and little tendency towards plasticizer migration.Type: GrantFiled: June 19, 2018Date of Patent: December 27, 2022Assignee: SIKA TECHNOLOGY AGInventors: Urs Burckhardt, Andreas Kramer
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Patent number: 11465473Abstract: An interfacing element of a lock zone of a door of a motor vehicle. The interfacing element comprises: includes a support made of plastic material, intended to be attached to a lining of the door, the lining being made of plastic material and a reinforcing plate of the lock zone onto which a lock is intended to be fastened, the plate being integrated to the support by overmolding. The support is made of a material having a Young's modulus lower than that of the plastic material of the lining of the door, and a coefficient of elongation at break greater than that of the plastic material of the lining of the door. A sub-assembly of motor vehicle includes a lining of tailgate and an interfacing element fastened onto an outer face of the lining.Type: GrantFiled: December 20, 2019Date of Patent: October 11, 2022Assignee: Compagnie Plastic OmniumInventor: Philippe Coudron
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Patent number: 11406732Abstract: A process forms an implantable product including poly(glycerol sebacate) urethane (PGSU) loaded with an active pharmaceutical ingredient (API). The process includes homogeneously mixing a flowable poly(glycerol sebacate) (PGS) resin with the API and a catalyst to form a resin blend. The process also includes homogeneously combining the resin blend with an isocyanate to form a reaction mixture and injecting the reaction mixture to form the PGSU loaded with the API. An implantable product includes a PGSU loaded with an API. In some embodiments, the implantable product includes at least 40% w/w of the API, and the implantable product releases the API by surface degradation of the PGSU at a predetermined release rate for at least three months under physiological conditions. In some embodiments, the PGSU is formed from a PGS reacted with an isocyanate at an isocyanate-to-hydroxyl stoichiometric (crosslinking) ratio in the range of 1:0.25 to 1:1.25.Type: GrantFiled: January 13, 2021Date of Patent: August 9, 2022Assignee: THE SECANT GROUP, LLCInventors: Stephanie Reed, Carissa Smoot, Dennis Shull, Todd Crumbling, John D'Ottavio, Peter D. Gabriele, Jeremy J. Harris, Charles Brendan Nicholson, Jared Ely
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Patent number: 11365327Abstract: A method for applying a multilayer coating comprising a basecoat and a clearcoat is disclosed. The basecoat is a curable aqueous composition comprising (1) polymeric particles containing carboxylic acid functionality and prepared from ethylenically unsaturated compounds including a multi-ethylenically unsaturated monomer, and (2) a polycarbodiimide. Also provided is a multilayer coated substrate.Type: GrantFiled: May 14, 2019Date of Patent: June 21, 2022Assignee: PPG Industries Ohio, Inc.Inventors: Shanti Swarup, Xiangling Xu, Richard J. Sadvary, Anthony M. Chasser
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Patent number: 11339244Abstract: The present invention provides a blocked polyisocyanate composition comprising a blocked polyisocyanate formed through blocking at least a part of isocyanate groups possessed by a polyisocyanate derived from one or two or more diisocyanates selected from the group consisting of an aliphatic diisocyanate and an alicyclic diisocyanate with an active methylene-based compound comprising a malonic acid diester, wherein a specific molar ratio calculated from contents (mol %) of isocyanurate groups, iminooxadiazinedione groups, uretdione groups, and allophanate groups is 0.05 or more and 0.60 or less.Type: GrantFiled: July 24, 2020Date of Patent: May 24, 2022Assignee: ASAHI KASEI KABUSHIKI KAISHAInventors: Masakazu Yamauchi, Satoshi Takeno
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Patent number: 11279790Abstract: The present invention relates to process for producing polyisocyanurate plastics, comprising the following steps: a) providing a polyisocyanate composition A) which comprises oligomeric polyisocyanates and is low in monomeric diisocyanates, “low in monomeric diisocyanates” meaning that the polyisocyanate composition A) has a content of monomeric diisocyanates of not more than 20% by weight, b) catalytically trimerizing the polyisocyanate composition A) using at least one tertiary organic phosphine catalyst B). The invention further relates to polyisocyanurate plastics obtainable by the process according to the invention, to coatings, films, semifinished products and mouldings comprising or consisting of the polyisocyanurate plastic according to the invention, and to the use of the polyisocyanurate plastics according to the invention for production of coatings, films, semifinished products and mouldings.Type: GrantFiled: August 29, 2017Date of Patent: March 22, 2022Assignee: Covestro Deutschland AGInventors: Dieter Mager, Hans-Josef Laas, Mathias Matner, Dirk Achten, Heiko Hocke
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Patent number: 11214649Abstract: A method for producing a shaped body, containing: producing the shaped body from a composition by a powder-based layer construction process, wherein the composition contains a thermoplastic polyurethane, obtained by reacting a polyisocyanate composition and a polyol composition, the thermoplastic polyurethane is solid at least in a temperature region below 50° C. and has end groups selected from the group consisting of first end groups and second end groups, wherein the first end groups are optionally eliminated at a first temperature, and the second end groups are optionally eliminated at a second temperature, to form reactive groups on the thermoplastic polyurethane that optionally enter into a reaction with functional groups of the thermoplastic polyurethane or functional groups of a further component of the composition, and wherein the first temperature and the second temperature are each greater than or equal to 60° C.Type: GrantFiled: February 16, 2018Date of Patent: January 4, 2022Assignee: BASF SEInventors: Rajan Hollmann, Sebastian Richter, Martin Hufnagel, Hendrik Wagner
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Patent number: 11091584Abstract: The present invention relates to a polyisocyanate composition comprising a formation component having isocyanate groups, the isocyanate groups having been reacted to an extent of ?98% with at least one CH-acidic compound, characterized in that the formation component consists to an extent of ?51% by weight of at least one polyisocyanate based on pentamethylene 1,5-diisocyanate having a content of isocyanurate trimer of ?60 area %, based on the total weight of the polyisocyanates based on pentamethylene 1,5-diisocyanate, and the remaining proportion up to 100% by weight of the total amount of polyisocyanates present in the formation component consists of at least one aliphatic or cycloaliphatic polyisocyanate. The present invention further provides a one-component system comprising the polyisocyanate composition, a process for producing a coating on a substrate, and the coatings obtainable from the one-component system.Type: GrantFiled: July 20, 2016Date of Patent: August 17, 2021Assignee: Covestro Deutschland AGInventors: Andreas Hecking, Florian Johannes Stempfle, Christoph Eggert, Michael Grahl, Dorota Greszta-Franz
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Patent number: 11081747Abstract: A packaging material for a power storage device includes a base material layer which has at least a first adhesive layer, a metal foil layer, a corrosion prevention-treated layer, a second adhesive layer, and a sealant layer, sequentially laminated on the side of the first surface thereof; and a base material protective layer formed from at least one selected from the group consisting of a polyester polyol and an acrylic polyol, each containing a group having a hydroxyl group in a side chain thereof, and an aliphatic isocyanate curing agent, laminated on the side of the second surface of in the base material layer.Type: GrantFiled: May 1, 2014Date of Patent: August 3, 2021Assignee: TOPPAN PRINTING CO., LTD.Inventors: Naoto Oono, Kazuki Nishijima, Koji Murata
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Patent number: 11053345Abstract: The present invention relates to the technical field of polymer materials, and in particular, relates to a polyurethane polymer and a method for preparing the same and use thereof. The present invention discloses use of aminoimidazolinone-based compound in preparing an end-capped polyurethane polymer product, by which the polyurethane polymer capable of achieving repeated self-healing for multiple times without adding any self-healing agent and any external stimulation can be prepared. The present invention further provides a polyurethane polymer capable of achieving repeated self-healing for multiple times without any external stimulation and having a compressive strength restored to at most 96% of the one before compression, and a method for preparing the same.Type: GrantFiled: December 27, 2017Date of Patent: July 6, 2021Assignee: ELECTRIC POWER RESEARCH INSTITUTE OF GUANGDONG POWER GRID CO., LTD.Inventors: Musong Lin, Tiansheng Chen, Qiang Fu, Shengping Fan, Lei Peng
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Patent number: 10787765Abstract: Provided is a coating composition for the elastic coating of textile materials, comprising at least one blocked, isocyanate-terminated prepolymer (component A), the isocyanate-terminated prepolymer A) being prepared from a polyol component a) IN and an isocyanate component b), and the terminal isocyanate groups being blocked with dialkyl malonate and/or 3,5-dimethylpyrazole, and the isocyanate component b) containing ?70 wt % of at least one aliphatic polyisocyanate and ?30 wt % of at least one N aromatic polyisocyanate, based on the total weight of component b), at least one polyamine (component B) and ?30 wt %, based on the total mass of the coating composition, of at least one organic solvent. Further provided are a method for coating substrates with the coating composition, and also the substrate obtainable in such a method, and, further, the use of the coating composition for producing elastic coatings or elastic films.Type: GrantFiled: December 22, 2015Date of Patent: September 29, 2020Assignee: Covestro Deutschalnd AGInventors: Rolf Irnich, Jürgen Köcher, Rafael Langer
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Patent number: 10752728Abstract: The invention relates to a polyisocyanate which is based on tolylene 2,4-diisocyanate, tolylene 2,6-diisocyanate or a mixture of tolylene 2,4- and 2,6-diisocyanate and has isocyanurate groups, wherein the polyisocyanate has a) a weight average molecular weight of from ?350 to ?800 g/mol, determined by means of gel permeation chromatography using a polystyrene standard and tetrahydrofuran as eluent in accordance with DIN 55672-1:2016-03, b) a polydispersity D of from >1 to ?1.5, where the polydispersity D is the ratio of weight average and number average molecular weight of the polyisocyanate and the weight average and number average molecular weight are in each case determined by means of gel permeation chromatography using a polystyrene standard and tetrahydrofuran as eluent in accordance with DIN 55672-1:2016-03, and c) a content of monomeric tolylene diisocyanate of ?1% by weight, based on the total weight of the polyisocyanate.Type: GrantFiled: October 18, 2017Date of Patent: August 25, 2020Assignee: Covestro Deutschland AGInventors: Christoph Irle, Stefan Groth, Ruiwen Wu, Antonio Midolo, Robert Maleika, Hongchao Li, Hao Liu
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Patent number: 9957347Abstract: The present invention relates to a process for producing a polyurethane, comprising at least the following steps (A) bringing at least one polymer polyol into contact with an amount of from 0.1 to 20 mol %, based on the entire amount of polyisocyanate, of at least one first polyisocyanate, in order to obtain a prepolymer which in essence has terminal hydroxy groups, and (B) bringing the prepolymer from step (A) into contact with at least one second polyisocyanate and optionally with further additives, in order to obtain the polyurethane, to a polyurethane obtainable via said process, and also to the use of this polyurethane as cladding in automobiles, coatings, cables, plug connectors, solar modules, foils, moldings, shoe soles and shoe components, balls and ball components, rollers, fibers, profiles, laminates and wiper blades, hoses, cable plugs, bellows, drag cables, cable sheathing, gaskets, nonwoven fabrics, drive belts, or damping elements.Type: GrantFiled: February 24, 2014Date of Patent: May 1, 2018Assignee: BASF SEInventors: Frank Prissok, Henning Wettach
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Patent number: 9920159Abstract: The present invention relates to a process for producing a polyurethane, comprising at least the following steps (A) bringing at least one polymer polyol into contact with an amount of from 0.1 to 20 mol %, based on the entire amount of polyisocyanate, of at least one first polyisocyanate, in order to obtain a prepolymer which in essence has terminal hydroxy groups, and (B) bringing the prepolymer from step (A) into contact with at least one second polyisocyanate and optionally with further additives, in order to obtain the polyurethane, to a polyurethane obtainable via said process, and also to the use of this polyurethane as cladding in automobiles, coatings, cables, plug connectors, solar modules, foils, moldings, shoe soles and shoe components, balls and ball components, rollers, fibers, profiles, laminates and wiper blades, hoses, cable plugs, bellows, drag cables, cable sheathing, gaskets, nonwoven fabrics, drive belts, or damping elements.Type: GrantFiled: February 24, 2014Date of Patent: March 20, 2018Assignee: BASF SEInventors: Frank Prissok, Henning Wettach
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Patent number: 9657206Abstract: The present invention relates to adhesive formulations based on uretdione-group-comprising polyaddition compounds that are free of isocyanate groups and monomeric polyisocyanates, and to the use thereof for the production of adhesive bonds between substrates, in particular for the production of flexible film composites.Type: GrantFiled: July 24, 2013Date of Patent: May 23, 2017Assignee: Covestro Deutschland AGInventors: Dorota Greszta-Franz, Berta Vega Sanchez, Beate Baumbach, Hans-Josef Laas, Mathias Matner
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Patent number: 9464160Abstract: The present invention comprises fluorinated ethoxylated polyurethanes of formula [Rf—(X)n—(CH2CHR1—O)m—CH2CH2—O—C(O)—NH]p-A, wherein Rf is a C1 to C6 perfluoroalkyl; X is a divalent radical; n is 0 or 1; R1 is H or C1 to C4 alkyl; m is 1 to 20; p is a positive integer of at least 2; and A is the residue of a polyisocyanate, and methods for altering surface behavior of liquids using such compounds.Type: GrantFiled: August 27, 2010Date of Patent: October 11, 2016Assignee: THE CHEMOURS COMPANY FC, LLCInventors: Michael Henry Ober, Kathleen L. Kanetsky, Allison Mary Yake
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Patent number: 9334392Abstract: Provided is a cellulose resin composition wherein roll contamination during processing and reduction in the productivity caused by roll contamination are inhibited. The cellulose resin composition is obtained by adding a polyester-based plasticizer to a cellulose resin, the cellulose resin composition being characterized in that the polyester-based plasticizer is produced from a polybasic acid, a polyhydric acid and, as required, a stopper, in which polyester-based plasticizer, components having a molecular weight of 430 or less are removed to an amount of 5 wt % or less.Type: GrantFiled: May 7, 2013Date of Patent: May 10, 2016Assignee: ADEKA CORPORATIONInventors: Masashi Harada, Yuji Yamazaki, Satoshi Kamimura, Yuki Tanaka
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Patent number: 9309218Abstract: The present invention suggests 2-oxo-1,3-dioxolane-4-carboxamides of formula (I), in which R2 can be, inter alia, an n-valent radical (n>1) which is substituted with n?1 further 2-oxo-1,3-dioxolane-4-carboxamide groups of general formula (II), to processes for the preparation of these 2-oxo-1,3-dioxolane-4-carboxamides, to processes for the preparation of the 2-oxo-1,3-dioxolane-4-carboxylic acids of formula (III), which are suitable starting materials for the above processes, and to the use of said 2-oxo-1,3-dioxolane-4-carboxamides for the preparation of (poly)hydroxyurethanes, -hydroxycarbonates and -hydroxysulfanylformates, and also as end groups for the blocking of amines.Type: GrantFiled: November 14, 2012Date of Patent: April 12, 2016Assignee: Construction Research & Technology GmbHInventors: Heimo Woelfle, Burkhard Walther, Maximilian Köhler, Sophie Putzien
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Patent number: 9296927Abstract: A pressure-sensitive adhesive polymeric composition comprising: (a) a butyl rubber; (b) a polyurethane; (c) an olefinic polymer component; and (d) a filler that includes titanium dioxide.Type: GrantFiled: November 12, 2011Date of Patent: March 29, 2016Assignee: Firestone Building Products Co., LLCInventors: Jiansheng Tang, Brandon Ward
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Patent number: 9193874Abstract: Hydrophilic coating compositions and methods to make and use the compositions are disclosed. The compositions include a polymer comprising a plurality of isocyanate groups and a blocking agent contacting at least one of the plurality of isocyanate groups.Type: GrantFiled: July 16, 2012Date of Patent: November 24, 2015Assignee: EMPIRE TECHNOLOGY DEVELOPMENT LLCInventors: William Brenden Carlson, Georgius Abidal Adam, Angele Sjong, Feng Wan, Timothy Londergan
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Patent number: 9186851Abstract: Systems and methods for the reduction of volatile component content from shaped prepregs and prepreg layups and the layups and composites formed therefrom are disclosed. One or more shaped prepregs or prepreg layups are placed within an enclosure and a flow of a non-condensing gas is introduced adjacent at least one surface of the shaped prepregs or prepreg layups, accelerating the rate and/or the completeness of removal of volatile components from the shaped prepregs or prepreg layups. The shaped prepregs or prepreg layups may be further subjected to heat, vacuum, and external pressure to facilitate removal of the volatile components. Shaped prepregs and prepreg layups with volatiles reduced in this manner may be further consolidated with heat, external pressure and/or vacuum. Beneficially, reduced matrix bleed and reduced fiber movement may be achieved during processing, reducing manufacturing time and improving part quality.Type: GrantFiled: October 21, 2009Date of Patent: November 17, 2015Assignee: Cytec Technology Corp.Inventors: Jack Douglas Boyd, Spencer Donald Jacobs
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Patent number: 9115292Abstract: The instant invention provides a crosslinkable aqueous composition, method of producing the same, crosslinked compositions, and method of producing the same. The crosslinkable composition comprising: an aqueous dispersion comprising; (a) water; (b) a polycarbamate comprising at least an average of 2.0 carbamate functional groups; (c) a polyaldehyde comprising at least two aldehyde groups; (d) an acid catalyst; and (e) optionally one or more surfactants; wherein said aqueous dispersion has a pH in the range of less than 7; and wherein said composition is capable of being crosslinked at a temperature in range of less than 80° C. upon substantial removal of water.Type: GrantFiled: April 14, 2014Date of Patent: August 25, 2015Assignees: Dow Global Technologies LLC, Rohm and Haas CompanyInventors: Eric Greyson, John N. Argyropoulos, Paul Foley, Andrew Swartz, Nahrain E. Kamber, Caroline Slone, Manesh N. Sekharan
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Patent number: 9074080Abstract: The invention relates to the use of polymers on the basis of renewable resources as LPA, characterized in that the polymers on the basis of renewable resources can be obtained by the radically initiated polymerization of one or more ethylenically unsaturated monomers in the presence of one or more renewable resources selected from the group consisting of carbohydrates and natural rubbers.Type: GrantFiled: May 9, 2011Date of Patent: July 7, 2015Assignee: Wacker Chemie AGInventors: Florian Bauers, Michael Tobias Zarka
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Patent number: 9011630Abstract: The present invention relates to curable compositions comprising at least one specific blocked amine, at least one surface-deactivated polyisocyanate that is solid at ambient temperature and optionally water or a water-producing substance. Compositions of this type are characterized by an extremely high storage stability as long as they are not heated. Hot curing compositions that cure with the action of heat can thus be produced. Heat-activated compositions can also be produced. When heat is applied the latter compositions are not cured but are activated so that they are able to cure under the influence of moisture. The curable compositions are particularly suitable for use as adhesives.Type: GrantFiled: March 31, 2010Date of Patent: April 21, 2015Assignee: Sika Technologies AGInventors: Urs Burckhardt, Peter Gimmnich
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Patent number: 8980970Abstract: The invention relates to a process for preparing binders which contain 1) allophanate groups, 2) groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups) and 3) optionally NCO-reactive groups, by reacting at temperatures ?130° C. A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds that contain isocyanate-reactive groups and groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups), and then C) with one or more saturated, hydroxyl-containing compounds other than B), at least one of these compounds having an OH functionality of ?2, in the presence of D) a catalyst containing one or more zinc compounds, the reaction with compounds C) taking place at least proportionally with the formation of allophanate groups. The present invention also relates to the binders obtained by the process of the invention.Type: GrantFiled: September 1, 2005Date of Patent: March 17, 2015Assignee: ALLNEX IP S.a.r.L.Inventors: Jan Weikard, Dorota Greszta-Franz, Wolfgang Fischer, Jörg Schmitz, Holger Mundstock, Christophe Detrembleur
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Publication number: 20150051365Abstract: The present invention suggests 2-oxo-1,3-dioxolane-4-carboxamides of formula (I), in which R2 can be, inter alia, an n-valent radical (n>1) which is substituted with n?1 further 2-oxo-1,3-dioxolane-4-carboxamide groups of general formula (II), to processes for the preparation of these 2-oxo-1,3-dioxolane-4-carboxamides, to processes for the preparation of the 2-oxo-1,3-dioxolane-4-carboxylic acids of formula (III), which are suitable starting materials for the above processes, and to the use of said 2-oxo-1,3-dioxolane-4-carboxamides for the preparation of (poly)hydroxyurethanes, -hydroxycarbonates and -hydroxysulfanylformates, and also as end groups for the blocking of amines.Type: ApplicationFiled: November 14, 2012Publication date: February 19, 2015Inventors: Heimo Woelfle, Burkhard Walther, Maximilian Köhler, Sophie Putzien
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Patent number: 8957176Abstract: The invention provides innovative blocked polyisocyanates whose crosslinking is initiated thermally and photochemically. The polyisocyanates comprise at least one thermally reversibly blocked NCO group whose blocking agent contains at least one group which on exposure to actinic radiation reacts, with polymerization, with ethylenically unsaturated compounds. A process for preparing the polyisocyanates, and their use in binders, is also provided.Type: GrantFiled: September 2, 2005Date of Patent: February 17, 2015Assignee: ALLNEX IP S.à.r.L.Inventors: Thomas Fäcke, Jan Weikard, Wolfgang Fischer
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Patent number: 8940853Abstract: Blocked polyisocyanates, obtained by using a polyisocyanate derived from an aliphatic and/or an alicyclic diisocyanate monomer, as a precursor, and including both of a blocked isocyanate group blocked with a pyrazole compound and a cationic group neutralized with an anion, in one molecule thereof; methods for making and using such blocked polyisocyanates; and compositions of matter including such blocked polyisocyanates.Type: GrantFiled: March 16, 2011Date of Patent: January 27, 2015Assignee: Asahi Kasei Chemicals CorporationInventors: Yoshiyuki Asahina, Michiaki Sasahira
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Patent number: 8933138Abstract: The present invention provides photolatent Ti-chelate catalyst compounds of formula (I), wherein R1 is for example C6-C14 aryl which is substituted by one or more R?2, R?3 or R?4; or the two R1 together are unsubstituted linear or branched C1-C12alkylene; R2, R3, R4, R?2, R?3, and R?4 independently of each other are for example hydrogen, halogen or linear or branched C1-C20alkyl; R5, R6 and R7 independently of each other are hydrogen, linear or branched C1-C20alkyl, C6-C14aryl, Br or Cl, provided that not more than one of R5, R6 and R7 is hydrogen; as well as formulations comprising said compounds and defined 1,3-diketones.Type: GrantFiled: September 1, 2010Date of Patent: January 13, 2015Assignee: BASF SEInventors: Tobias Hintermann, Didier Bauer, Antoine Carroy, Caroline Lordelot, Rachel Kohli Steck
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Patent number: 8853295Abstract: The present invention relates to a process for the preparation of particularly reactive and low-viscosity reaction products of polyisocyanates which contain activated ethylenically unsaturated groups which react by polymerization under the action of actinic radiation, and the use of these reaction products in coating compositions, and particularly scratch-resistant coatings obtainable therefrom.Type: GrantFiled: February 12, 2010Date of Patent: October 7, 2014Assignee: ALLNEX IP S.a.r.L.Inventors: Michael Ludewig, Wolfgang Fischer, Helmut Kuczewski
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Patent number: 8828098Abstract: Non-fluorinated blocked polyurethanes are described as extenders and, particularly as textile auxiliaries, for use with fluorochemical polymers in treating substrates, for example fibrous substrates, such as textile fabrics or yarns. The polyurethane is prepared by reacting a polyisocyanate, a blocking agent, and a non-fluorinated isocyanate reactive compound having an average alkyl chain length of 24 to 50 carbon atoms.Type: GrantFiled: December 18, 2007Date of Patent: September 9, 2014Assignee: 3M Innovative Properties CompanyInventors: Stewart H. Corn, Chetan P. Jariwala
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Patent number: 8802770Abstract: The present invention discloses a semicrystalline, thermoplastic polyurethane which is comprised of the reaction product of (1) a hydrophobic polyol, (2) a polyisocyanate, and (3) a linear chain extender containing 5 carbon atoms or 7 to 12 carbon atoms; wherein the hydrophobic polyol has a number average molecular weight which is within the range of about 1,000 to about 4,000; wherein the semicrystalline, thermoplastic polyurethane has a weight average molecular weight which is within the range of 50,000 to 1,000,000; and wherein the semicrystalline, thermoplastic polyurethane has a melting point which is within the range of 80° C. to 150° C. This hydrophobic thermoplastic polyurethane offers a unique array of characteristics that are highly desirable for utilization in manufacturing a variety of products. For instance, it can be used in overmolding soft grips onto consumer products, in adhesives, and in protective coatings.Type: GrantFiled: January 21, 2009Date of Patent: August 12, 2014Assignee: Lubrizol Advanced Materials, Inc.Inventors: Donald A. Meltzer, Jacques P. E. J. Horrion
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Patent number: 8795831Abstract: The invention relates to addition compounds and their salts, characterized in that the addition compounds are obtainable by reacting (a) one or more polyisocyanates having at least two isocyanate groups per molecule with (b) one or more compounds of the formula Y—(XH)n and (c) one or more compounds from the group consisting of (c1) compounds M-Q, (c2) a blocking agent for isocyanate groups, and (c3) optionally compounds of the general formula Z-Q. The invention further relates to the preparation of the addition compounds and to their use as dispersants, wetting agents and dispersion stabilizers, and also to solids coated with the addition compounds.Type: GrantFiled: January 9, 2009Date of Patent: August 5, 2014Assignee: BYK-Chemie GmbHInventors: Wolfgang Pritschins, Karlheinz Haubennestel, Hans-Josef Teuwsen
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Patent number: 8779055Abstract: The present invention relates to a composition comprising a hydrophobically modified alkylene oxide urethane polymer with pendant or end-capping tertiary amine groups, the conjugate acids of which have a pKa in the range of about 4.5 to about 6.5. The composition of the present invention is useful as a rheology modifier for paint formulations formulated over a wide pH range and is more stable to heat aging than higher pKa amine-modified HEURs.Type: GrantFiled: November 14, 2011Date of Patent: July 15, 2014Assignee: Rohm and Haas CompanyInventors: John J Rabasco, Barrett R Bobsein
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Patent number: 8742053Abstract: The invention relates to novel polyamide-polysiloxane compounds, processes for their preparation, their use, precursors for their preparation and reactive compositions which contain the precursors.Type: GrantFiled: March 19, 2008Date of Patent: June 3, 2014Assignee: Momentive Performance Materials GmbHInventors: Horst Lange, Karl-Heinz Sockel, Roland Wagner, Gunnar Hoffmüller
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Patent number: 8703896Abstract: A two part non-sag polyurethane construction sealant or adhesive is provided with the properties of low modulus, high elongation, good paint adhesion, and primerless adhesion to concrete surfaces. The sealant or adhesive is prepared using a polyol, and optionally an epoxy silane and/or a melamine compound, in the base component of the formulation; and a prepolymer reaction product including the residues of xylenol or xylenol and an additional polyol, and a polymeric isocyanate, an aromatic diisocyanate, or a polymeric isocyanate and an aromatic diisocyanate, and optionally an epoxy silane and/or a melamine compound, in the activator component of the formulation.Type: GrantFiled: July 26, 2012Date of Patent: April 22, 2014Assignee: Construction Research & Technology GmbHInventors: Chia L. Wang, John M. Davis, Bryan Lienke
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Patent number: 8680176Abstract: The present invention provides a nanocapsule of a blocked isocyanate encapsulated within a polymeric nanosphere. In one aspect, the polymeric nanosphere is functionalized. Free isocyanate functionality is released upon thermal annealing or UV exposure of the nanospheres containing the blocked isocyanate. This present invention also provides a novel method for encapsulating isocyanates in aqueous media. In one aspect, the method comprises miniemulsion polymerization. The thermally or UV deblocked isocyanate can be used as an active functional group for many potential applications.Type: GrantFiled: March 13, 2008Date of Patent: March 25, 2014Assignee: The University of Southern MississippiInventors: James W. Rawlins, Huaxiang Yang, Sharathkumar K. Mendon
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Publication number: 20140031484Abstract: It is an object of the invention to provide a block polyisocyanate compound with excellent storage stability. The block polyisocyanate compound of the invention has the following construction. A block polyisocyanate compound having at least one block isocyanate group selected from the group consisting of a block isocyanate group represented by formula (I), block isocyanate group represented by formula (II) and block isocyanate group represented by formula (III), and a hydrophilic group.Type: ApplicationFiled: April 5, 2012Publication date: January 30, 2014Applicant: KANSAI PAINT CO., LTD.Inventors: Masami Kobata, Hiroshi Kitagawa, Kazuaki Kitazono
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Patent number: 8629231Abstract: An oligomer is made by capping a uretdione compound of structure with a compound (II) having an active hydrogen and a carbamate or cyclic carbonate group under conditions in which the isocyanate groups but not the uretdione group react. The product (III) is either reacted with a reactant having at least two active hydrogens under reaction conditions that cleave the uretdione ring, after which any cyclic carbonate groups may be converted to carbamate groups, or a product (III) having cyclic carbonate groups is reacted with ammonia or primary amine to provide uretdione with a hydroxy carbamate group that is then self-condensed under uretdione ring-opening conditions. A curable coating composition comprises the oligomer; a coated article is prepared by applying a layer of the curable coating composition and curing the applied layer.Type: GrantFiled: May 20, 2009Date of Patent: January 14, 2014Assignee: BASF Coatings GmbHInventors: Nicholas Caiozzo, Walter H Ohrbom, David C Cranfill
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Patent number: 8604097Abstract: The present invention relates to a process for preparing radiation-curing binders containing allophanate groups by reacting, at temperatures of ?130° C., A) one or more compounds containing uretdione groups with B) one or more OH-functional compounds which contain groups which react, with polymerization, with ethylenically unsaturated compounds on exposure to actinic radiation (radiation-curing groups), C) optionally NCO-reactive compounds other than B), in the presence of D) a catalyst containing at least one zinc compound, to form allophanate groups by opening the uretdione ring. The present invention also relates to the binders obtained by the process of the invention and to coating compositions containing these binders.Type: GrantFiled: January 27, 2011Date of Patent: December 10, 2013Assignee: Bayer MaterialScience AGInventors: Jan Weikard, Christophe Detrembleur, Dorota Greszta-Franz, Frank Richter, Wolfgang Fischer, Jörg Schmitz, Holger Mundstock
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Patent number: RE46368Abstract: A material for electroluminescent devices which comprises a compound in which a heterocyclic group having nitrogen is bonded to carbazolyl group and an organic electroluminescent device having at least one organic thin film layer which is sandwiched between the cathode and the anode and contains the above material in at least one layer, are provided. The material can provide organic electroluminescent devices emitting bluish light with a high purity of color. The organic electroluminescence device uses the material.Type: GrantFiled: September 9, 2015Date of Patent: April 18, 2017Assignee: Idemitsu Kosan Co., Ltd.Inventors: Toshihiro Iwakuma, Chishio Hosokawa, Hidetsugu Ikeda, Seiji Tomita, Takashi Arakane