Contacting With Alkali (li, Na, K, Rb, Cs, Fr) Or Alkaline Earth (be, Mg, Ca, Sr, Ba) Metal Or Compound Thereof Patents (Class 528/488)
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Patent number: 11950999Abstract: Described embodiments are directed toward centrally-opening, leaflet valve devices and systems for transcatheter delivery having a two-piece valve body as well as methods of making and delivering the two-piece valve devices. A transcatheter valve includes a collapsed configuration and an expanded configuration. The transcatheter valve can further include an everted configuration and a non-everted configuration.Type: GrantFiled: October 6, 2021Date of Patent: April 9, 2024Assignee: EDWARDS LIFESCIENCES CORPORATIONInventors: William C. Bruchman, Cody L. Hartman
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Patent number: 10011673Abstract: The present invention relates to thermoplastic compositions comprising as impact modifier a rubber containing graft polymer prepared by the process of emulsion polymerization and recovered by a special process controlling and adjusting the pH value, the use of the thermoplastic compositions in the production of molded bodies, and to the molded, bodies themselves. The present invention relates also to thermoplastic compositions comprising a polymeric impact modifier with a core-shell structure made by a multistage process and recovered by a special process controlling and adjusting the pH value comprising at least one gradient polymer the use of the thermoplastic compositions in the production of molded bodies, and to the molded, bodies themselves.Type: GrantFiled: December 14, 2011Date of Patent: July 3, 2018Assignee: Arkema FranceInventors: Christophe Navarro, Stephane Girois, Elisabeth Bay, Jean-Claude Saint-Martin, Magali Bergeret-Richaud
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Patent number: 9221032Abstract: A method of improving the efficiency of a diesel engine provided with a source of diesel fuel includes the steps of: a) adding to the diesel fuel a reverse-micellar composition having an aqueous first disperse phase that includes a free radical initiator and a first continuous phase that includes a first hydrocarbon liquid, a first surfactant, and optionally a co-surfactant, thereby producing a modified diesel fuel, and b) operating the engine, thereby combusting the modified diesel fuel. The efficiency of a diesel engine provided with a source of diesel fuel and a source of lubricating oil can also be improved by modifying the lubricating oil by the addition of a stabilized nanoparticulate composition of cerium dioxide. The efficiency of a diesel engine can also be improved by adding to the diesel fuel a reverse-micellar composition that includes an aqueous disperse phase containing boric acid or a borate salt.Type: GrantFiled: April 18, 2013Date of Patent: December 29, 2015Assignee: CERION, LLCInventors: Kenneth Reed, Albert Gary DiFrancesco
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Patent number: 9190215Abstract: There is provided an electrolytic capacitor which includes a capacitance portion that includes an anode and a cathode foils wound around, a separator being provided between the foils, a first conductor bar connected to the anode foil, a second conductor bar to the cathode foil, a casing that houses the capacitance portion, the first conductor bar, and the second conductor bar and is provided with an opening, a sealing material fitted to the opening, the sealing material including a first and a second holes, a first lead welded to the first conductor bar within the first hole, a second lead to the second conductor bar the second holed, a first insulating filler filled between the first hole and the first lead and filler being formed in a porous state, and a second insulating filler filled between the second hole and the second lead and being formed in a porous state.Type: GrantFiled: September 13, 2013Date of Patent: November 17, 2015Assignee: FUJITSU LIMITEDInventors: Tomokazu Nakasima, Masayuki Itoh
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Patent number: 9034992Abstract: An improved polymerization and process method allows the production of special nitrile rubbers which are characterized by a specific anion content and an excellent storage stability and allow a particularly good vulcanization rate and moreover result in vulcanized materials that have advantageous properties, especially with regard to the contact with metal components of molded parts based on said vulcanized materials.Type: GrantFiled: September 10, 2013Date of Patent: May 19, 2015Assignee: LANXESS Deutschland GmbHInventors: Werner Obrecht, Rolf Josten, Michael Klimpel
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Patent number: 9012598Abstract: A new and efficient method of functionalizing high molecular weight polymers through alkylation using a metal amide base is described. This novel procedure can also be used to synthesize polymer-based macro-initiators containing radical initiating groups at the chain-ends for synthesis of block copolymers.Type: GrantFiled: July 19, 2013Date of Patent: April 21, 2015Assignee: Seeo, Inc.Inventors: Kulandaivelu Sivanandan, Hany Basam Eitouni, Yan Li, Russell Clayton Pratt
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Patent number: 8993687Abstract: There is provided a method for production of a high-purity biodegradable polyoxyethylene derivative on an industrial scale using a polyoxyethylene compound containing polylactic acid at the terminal thereof. A biodegradable polyoxyethylene compound represented by formula (1) and a compound represented by formula (I) are caused to react with each other at 60° C. to 120° C. using toluene as a solvent in the presence of sodium acetate to obtain a biodegradable polyoxyethylene derivative represented by formula (2).Type: GrantFiled: March 12, 2014Date of Patent: March 31, 2015Assignee: NOF CorporationInventors: Kosuke Nishiguchi, Tsuyoshi Takehana, Yuji Yamamoto
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Patent number: 8962792Abstract: A process for preparing an aliphatic or cycloaliphatic epoxy resin including the steps of: (I) reacting a mixture of (a) an aliphatic or cycloaliphatic hydroxyl containing material, (b) an epihalohydrin, (c) a basic acting substance, (d) a non-Lewis acid catalyst, and (e) optionally, a solvent, forming an epoxy resin composition; (II) subjecting the epoxy resin composition produced in step (I) to a separation process to remove (A) “light” components such as, for example, solvent used in the epoxidation reaction, if any, unreacted epihalohydrin, and co-products such as di(epoxypropyl)ether; (B) unreacted aliphatic or cycloaliphatic hydroxyl containing material, if any; (C) partially epoxidized aliphatic or cycloaliphatic hydroxyl containing material, such as, for example, MGE; (D) fully epoxidized aliphatic or cycloaliphatic hydroxyl containing material, such as, for example, DGE, such that the (E) aliphatic or cycloaliphatic polyfunctional epoxy resin product remaining contains no more than 50% by weight of sType: GrantFiled: September 7, 2011Date of Patent: February 24, 2015Assignee: Dow Global Technologies LLCInventor: Robert E. Hefner, Jr.
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Patent number: 8937149Abstract: The present invention provides nano-sized particles of melanin, and the method for formation of the melanin particles comprise the following steps: adding a base to a dopamine.H+X?-containing solution (wherein H+X? is an acid) and allowing an acid-base neutralization reaction; and forming nano-sized particles of melanin by controlling the addition of nucleic dopamine.H+X? (a) to base (b) at a ratio of a:b=1:0.1-1, and allow concurrent or consecutive formation of melanin by oxidation curing of the dopamine in air (polymerization). The manufacturing method according to the present invention can produce nano-sized melanin particles in a short period of time. Furthermore, the nano-sized melanin particles made according to the present invention are distinctive from conventional solvents containing dispersions of natural melanin and synthetic melanin, and have excellent application in various fields.Type: GrantFiled: October 22, 2010Date of Patent: January 20, 2015Assignee: SNU R&DB FoundationInventors: Jin Kyu Lee, Kuk Youn Ju
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Patent number: 8883959Abstract: A method for producing a polyarylene sulfide resin, comprising: producing a slurry (I) containing a solid alkali metal sulfide by allowing a hydrous alkali metal sulfide, or a hydrous alkali metal hydrosulfide and an alkali metal hydroxide, and an aliphatic cyclic compound (c1) that can be ring-opened by hydrolysis to react with each other while conducting dehydration in the presence of a non-hydrolyzable organic solvent; adding an aprotic polar organic solvent after the production of the slurry (I) and distilling off water to conduct dehydration; and conducting polymerization by allowing a polyhaloaromatic compound (a), an alkali metal hydrosulfide (b), and an alkali metal salt (c2) of a hydrolysate of the compound (c1) to react with each other in the slurry (I) in a state where the amount of water existing in the reaction system is 0.02 moles or less relative to 1 mole of the aprotic polar organic solvent.Type: GrantFiled: January 9, 2014Date of Patent: November 11, 2014Assignee: DIC CorporationInventor: Toshio Hinokimori
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Patent number: 8853351Abstract: Disclosed are a highly pure amphiphilic block copolymer including a hydrophobic polymer block of a poly(?-hydroxy acid), and a method for preparing the same. The method for preparing a highly pure amphiphilic block copolymer including a hydrophobic polymer block of a poly(?-hydroxy acid) includes removing ?-hydroxy acid, lactone monomers thereof, oligomers thereof and an organometal catalyst in polymerizing the amphiphilic block copolymer.Type: GrantFiled: December 31, 2008Date of Patent: October 7, 2014Assignee: Samyang Biopharmaceuticals CorporationInventors: Bong Oh Kim, Myung Seob Shim, Min-Hyo Seo
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Patent number: 8846857Abstract: Provided are methods for obtaining modified polyarylene sulfide compositions having improved thermal and thermo-oxidative stability, the compositions so obtained, and articles comprising the compositions. The method comprises the steps of contacting, in the presence of a suitable solvent, a polyarylene sulfide with at least one reducing agent and at least base to form a first mixture. The reducing agent comprises zinc(0), tin(0), tin(II), bismuth (0), bismuth(III), or a combination thereof. The first mixture is heated to form a second mixture in which the polyarylene sulfide is dissolved. The polyarylene sulfide is then precipitated to obtain a modified polyarylene sulfide.Type: GrantFiled: October 4, 2012Date of Patent: September 30, 2014Assignee: E I du Pont de Nemours and CompanyInventors: Robert John Duff, Zheng-Zheng Huang, Joachim C Ritter, Joel M Pollino
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Patent number: 8809489Abstract: Methods for preparing active carbonate esters of water-soluble polymers are provided. Also provided are other methods related to the active carbonate esters of water-soluble polymers, as well as corresponding compositions.Type: GrantFiled: May 15, 2013Date of Patent: August 19, 2014Assignee: Nektar TherapeuticsInventors: Antoni Kozlowski, Jon McKannan, Samuel P. McManus
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Patent number: 8809486Abstract: Disclosed is a method for producing a purified 2-aryl-3,3-bis(4-hydroxyaryl)phthalimidine of formula (I) wherein R1 is hydrogen or a C1-25 hydrocarbyl group and R2 is a hydrogen, a C1-25 hydrocarbyl group, or a halogen, and wherein the method comprises dissolving a crude phthalimidine compound in an aqueous base solution; precipitating the dissolved, crude phthalimidine compound from the aqueous base solution by adding an acid in an amount effective to lower the pH of the solution to 9.0 to 12.0, to provide a semicrude phthalimidine compound; and isolating the semicrude phthalimidine compound from the aqueous base solution, to provide the purified 2-aryl-3,3-bis(4-hydroxyaryl)phthalimidine of formula (I), and having a phenolphthalein compound content of less than 2,500 ppm, based on the weight of the purified 2-aryl-3,3-bis(4-hydroxyaryl)phthalimidine.Type: GrantFiled: July 13, 2012Date of Patent: August 19, 2014Assignee: Sabic Innovative Plastics IP B.V.Inventors: Venkata Rama Narayanan Ganapathy Bhotla, Balakrishnan Ganesan, Kishan Gurram, Salkod Parameshwar Mallika, Kumar Arun Satyanarayana, Swaminathan Shubashree
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Patent number: 8742061Abstract: It is aimed to provide a polyarylene sulfide film for an acoustic instrument vibrating plate excellent in heat resistance, molding processability, acoustic properties, and also heat moldability. Provided is a polyarylene sulfide film wherein the elongation at break in either a longitudinal direction or a width direction of the film is 100% or more and 250% or less, and the Young's modulus in either a longitudinal direction or a width direction of the film is 1.5 GPa or more and less than 4 GPa.Type: GrantFiled: December 19, 2012Date of Patent: June 3, 2014Assignee: Toray Industries, Inc.Inventors: Tetsuya Machida, Yasuyuki Imanishi, Masatoshi Ohkura, Takuji Higashioji
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Patent number: 8735537Abstract: The present application provides methods of producing polyanthracene including polymerization of anthracene monomers in the presence of oxidants and reaction solvents. The present application further provides polyanthracene produced by methods described herein that has higher solubility in organic solvents and better thermal stability and ablation resistance.Type: GrantFiled: June 4, 2010Date of Patent: May 27, 2014Assignee: Tongji UniversityInventors: Mei-rong Huang, Xin-gui Li, Shao-Jun Huang
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Patent number: 8691936Abstract: An initiator for cationic polymerization comprises a salt of a protic acid as well as a protic add. The molar ratio of protic acid to salt is in the range from 1:0.01 to 1:2000. The initiator is used for example for cationic homo- or copolymerization of trioxane, and permits stable and flexible operation of the polymerization.Type: GrantFiled: June 19, 2012Date of Patent: April 8, 2014Assignee: Ticona GmbHInventors: Michael Hoffmockel, Michael Haubs, Horst Röschert
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Patent number: 8686104Abstract: A polymer of formula (I): where: n is an integer from 10 to 5,000; m is an integer from 10 to 5,000; Ar1 and Ar3 are the same or different and are residues derived from a tetra-hydroxy aromatic monomer, the tetra-hydroxy aromatic monomer being wherein R is the same or different and is H or a C1-C8 alkyl, C2-C8 alkenyl or C3-C8 cycloalkyl group; and, Ar2 and Ar4 are the same or different and are residues derived from a tetra-halogenated aromatic monomer, the tetra-halogenated aromatic monomer being wherein X is F, Cl or Br, and R1 and R2 are the same or different and are wherein y is an integer from 1 to 8; with the proviso that when Ar1 is the same as Ar3 and Ar2 is the same as Ar4, R1 and R2 are not both —CN is useful as a material for gas separation, vapor separation, adsorbents or catalysis.Type: GrantFiled: October 16, 2009Date of Patent: April 1, 2014Assignee: National Research Council of CanadaInventors: Naiying Du, Michael D. Guiver, Gilles P. Robertson
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Patent number: 8680200Abstract: Novel polyglycerol aldehyde polymers are described. The polymers comprise glycerol monomers connected by ether linkages and have 3 to about 170 aldehyde groups per molecule. The polyglycerol aldehydes may be reacted with various amine-containing polymers to form hydrogel tissue adhesives and sealants that may be useful for medical applications such as wound closure, supplementing or replacing sutures or staples in internal surgical procedures such as intestinal anastomosis and vascular anastomosis, tissue repair, preventing leakage of fluids such as blood, bile, gastrointestinal fluid and cerebrospinal fluid, ophthalmic procedures, drug delivery, and preventing post-surgical adhesions.Type: GrantFiled: March 26, 2010Date of Patent: March 25, 2014Assignee: Actamax Surgical Materials LLCInventor: Henry Keith Chenault
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Production process of poly(arylene sulfide) whose content of terminal halogen group has been reduced
Patent number: 8680230Abstract: The invention provides a production process of a poly(arylene sulfide) which contains a step of polymerizing a sulfur source and a dihalo-aromatic compound in an organic amide solvent, said polymerization step containing a phase-separation polymerization step that the polymerization reaction is continued in the presence of a phase separation agent in a phase-separated state, wherein a monohalo-organic compound is added in a proportion of 0.005 to 20 mol per 100 mol of the charged sulfur source into the polymerization reaction system at the time a conversion of the dihalo-aromatic compound has reached 80 to 99% after initiation of the polymerization reaction and before the liquid phase becomes the phase-separated state to be reacted with a formed polymer, and the liquid phase within the polymerization reaction system is then converted to the phase-separated state to continue the polymerization reaction.Type: GrantFiled: June 10, 2009Date of Patent: March 25, 2014Assignee: Kureha CorporationInventors: Akihiro Konno, Ken-ichi Takaki, Hiroshi Sakabe -
Patent number: 8653232Abstract: A manufacturing method of polyethylene terephthalate including a step of melt polycondensation in presence of polycondensation catalyst represented by general Formula (I), wherein R1 represents an alkyl group having from 2 to 12 carbon atoms, and melt polycondensed polyethylene terephthalate has an intrinsic viscosity of from 0.48 to 0.53 dL/g and a terminal carboxyl number of from 14 to 22 mmol/kg; and a step of solid phase polycondensation to obtain solid phase polycondensed polyethylene terephthalate having an intrinsic viscosity of from 0.70 to 0.86 dL/g, and a terminal carboxyl number of less than 15 mmol/kg, followed by a step of applying an aqueous solution of at least one salt selected from the group consisting of acetate, carbonate, and sulfate of sodium, potassium, or cesium to the solid phase polycondensed polyethylene terephthalate, and then drying the polyethylene terephthalate, wherein the final content of sodium, potassium or cesium atom in dried polyethylene terephthalate is from 2 to 25 ppm.Type: GrantFiled: April 5, 2007Date of Patent: February 18, 2014Assignee: Teijin Fibers LimitedInventor: Shinya Konuma
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Patent number: 8653150Abstract: The present invention relates to a method for decomposing, in the presence of subcritical water, a thermosetting resin comprising a polyester moiety and a crosslinking moiety therewith to provide a compound comprising an acid residue derived from the polyester moiety and a residue derived from the crosslinking moiety, and collecting the compound in an efficient yield, specifically, which comprises steps of: (I) decomposing the thermosetting resin in the presence of subcritical water to provide a solid comprising a compound comprising an acid residue derived from the polyester moiety and a residue derived from the crosslinking moiety, (II) subjecting the solid to an organic solvent to dissolve the compound into the organic solvent, wherein the organic solvent has a higher solubility which can dissolve the compound than that of water, and (III) collecting, separating or isolating the compound from the organic solvent.Type: GrantFiled: March 26, 2009Date of Patent: February 18, 2014Assignees: Panasonic Corporation, International Center for Environmental Technology TransferInventors: Takumi Izumitani, Takaharu Nakagawa, Masaru Hidaka, Keishi Shibata, Junko Matsui
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Patent number: 8653229Abstract: Process for the oligomerization of hexafluoropropylene oxide (HFPO) in which the sum of the dimers, trimers, tetramers, pentamers and hexamers represents less than 20% of the weight of the polymerized HFPO, the oligomers other than the dimers, trimers, tetramers, pentamers and hexamers (the remaining oligomers) having an average molecular weight ranging between 1100 and 4000 g/mol, characterized in that the process comprises the steps of contacting hexafluoropropylene oxide (HFPO) at a temperature between ?30° C. to +50° C.Type: GrantFiled: March 25, 2009Date of Patent: February 18, 2014Assignee: Clariant Finance (BVI) LimitedInventor: Bernard Danner
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Patent number: 8642722Abstract: Disclosed is a method of preparing porous polybenzimidazole. The method includes providing polyaminoimide by reacting aromatic amine including at least two ortho-positioned amino groups and acid dianhydride, obtaining polypyrrolone from the polyaminoimide, subjecting the polypyrrolone to alkaline treatment, and subjecting the alkaline-treated polypyrrolone to heat treatment. The polybenzimidazole shows permeability and selectivity for various gases due to a fractional free volume and well-connected picopores.Type: GrantFiled: May 15, 2009Date of Patent: February 4, 2014Assignee: IUCF-HYU (Industry-University Cooperation Foundation Hanyang University)Inventors: Chul-Ho Jung, Sang-Hoon Han, Jae-Eun Lee, Young-Moo Lee, Ho-Bum Park
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Patent number: 8623981Abstract: An improved polymerization and process method allows the production of special nitrile rubbers which are characterized by a specific anion content and an excellent storage stability and allow a particularly good vulcanization rate and moreover result in vulcanized materials that have advantageous properties, especially with regard to the contact with metal components of molded parts based on said vulcanized materials.Type: GrantFiled: January 16, 2009Date of Patent: January 7, 2014Assignee: LANXESS Deutschland GmbHInventors: Werner Obrecht, Rolf Josten, Michael Klimpel
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Patent number: 8618246Abstract: A manufacturing method of polyethylene terephthalate including a step of melt polycondensation in presence of polycondensation catalyst represented by general Formula (I), wherein R1 represents an alkyl group having from 2 to 12 carbon atoms, and melt polycondensed polyethylene terephthalate has an intrinsic viscosity of from 0.48 to 0.53 dL/g and a terminal carboxyl number of from 14 to 22 mmol/kg; and a step of solid phase polycondensation to obtain solid phase polycondensed polyethylene terephthalate having an intrinsic viscosity of from 0.70 to 0.86 dL/g, and a terminal carboxyl number of less than 15 mmol/kg, followed by a step of applying an aqueous solution of at least one salt selected from the group consisting of acetate, carbonate, and sulfate of sodium, potassium, or cesium to the solid phase polycondensed polyethylene terephthalate, and then drying the polyethylene terephthalate, wherein the final content of sodium, potassium or cesium atom in dried polyethylene terephthalate is from 2 to 25 ppm.Type: GrantFiled: April 5, 2007Date of Patent: December 31, 2013Assignee: Teijin Fibers LimitedInventor: Shinya Konuma
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Patent number: 8569444Abstract: A process for producing a polyalkylene glycol derivative having such high molecular weight and purity that the derivative can be used in pharmaceutical applications, which produces a polyalkylene glycol derivative of the formula (X) by steps (A), (B), (C) and (D), wherein R is as defined: R—(OA)nOH??(X) (step (A)) 5 to 50% by mol of an alkali catalyst is added to a compound represented by the formula (Y), wherein R is as defined: R—OH??(Y) (step (B)) an alkylene oxide having 2 to 4 carbon atoms is reacted under a condition of 50 to 130° C. until the average number of moles of an oxyalkylene group OA added reaches the range of 5 to 500 to obtain a polyalkylene glycol derivative; (step (C)) 10 to 5000% by mass of a hydrocarbon solvent is added to the derivative of the step (B) to dilute it, and remaining water is removed by azeotropy; and (step (D)) the derivative of the step (B) is reacted with an alkylene oxide having 2 to 4 carbon atoms under a condition of 50 to 130° C.Type: GrantFiled: November 11, 2009Date of Patent: October 29, 2013Assignee: NOF CorporationInventors: Ken-ichiro Nakamoto, Chika Itoh, Shuichi Yoshimura, Tsuyoshi Takehana
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Patent number: 8557929Abstract: A method for producing a biodegradable polyoxyalkylene derivative, includes: reacting a biodegradable polyoxyalkylene compound represented by the formula (1) as defined herein with a compound represented by one of the formulae (I) to (IV) as defined herein in a presence of an alkaline solid salt, the biodegradable polyoxyalkylene derivative being represented by the formula (2) as defined herein.Type: GrantFiled: September 28, 2007Date of Patent: October 15, 2013Assignee: NOF CorporationInventors: Kazuhiro Kubo, Shigeru Kitano, Chika Ito
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Patent number: 8546518Abstract: A method is provided for producing a polyarylene sulfide by reacting a sulfidizing agent with a dihalogenated aromatic compound in an organic polar solvent in the presence of an alkali metal hydroxide, the method includes <Step 1>: carrying out the reaction in such a manner that the polymerization time in a temperature range of 230° C. to less than 245° C. (T1a) is not less than 30 minutes and less than 3.5 hours and that the conversion ratio of the dihalogenated aromatic compound at the end of the step is 70 to 98 mol. % and <Step 2>: carrying out the reaction in such a manner that the polymerization time in a temperature range of 245° C. to less than 280° C. (T2) is not less than 5 minutes and less than 1 hour.Type: GrantFiled: August 26, 2010Date of Patent: October 1, 2013Assignee: Toray Industries, Inc.Inventors: Takeshi Unohara, Hiroyuki Isago, Toru Nishimura, Masahiro Inohara
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Patent number: 8546520Abstract: The present invention relates to a method of reducing allergenicity of natural rubber latex products caused by allergens by reducing extractable protein levels found for said products, said method comprising the steps of: subjecting said products to a wash in a strong alkaline solution to deteriorate the allergens, and a system for reducing allergenicity of natural rubber latex products caused by allergens by reducing extractable protein levels found for said products, and a product, such as a glover or condom, manufactured from natural rubber latex.Type: GrantFiled: September 3, 2009Date of Patent: October 1, 2013Assignee: Budev B.V.Inventors: Herman Feil, Mark Domselaar
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Patent number: 8530554Abstract: A polymer assisted deposition process for deposition of metal oxide films is presented. The process includes solutions of one or more metal precursor and soluble polymers having binding properties for the one or more metal precursor. After a coating operation, the resultant coating is heated at high temperatures to yield metal oxide films. Such films can be epitaxial in structure and can be of optical quality. The process can be organic solvent-free.Type: GrantFiled: April 29, 2008Date of Patent: September 10, 2013Assignee: Los Alamos National Security, LLCInventors: Thomas M. McCleskey, Anthony K. Burrell, Quanxi Jia, Yuan Lin
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Patent number: 8530531Abstract: Method for the recycling of polyvinyl butyral based on obtaining recycled polyvinyl butyral (PVB) from laminated glass which is shattered and the polyvinyl butyral (PVB) is separated. The sheet obtained is cut into pieces and cleaned to eliminate dirt and foreign matter. The solid state PVB is subjected to a first polyvinyl butyral (PVB) purification stage with a chemical treatment with a first reagent and a final chemical treatment with a second reagent. The obtained purified polyvinyl butyral is suitable to be used in the manufacture of laminated glass.Type: GrantFiled: March 27, 2008Date of Patent: September 10, 2013Assignee: L'Urederra Fundacion para el Desarrollo Technologico y SocialInventors: Claudio Fernández Acevedo, Luis Martínez de Morentín Osaba, Edurne Osés Arteta, Germán Medina Herrera, María Antonia Fernández Fernández
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Patent number: 8507644Abstract: Methods of making metal-terephthalate polymers from a polyester ethylene terephthalate or terephthalic acid produces high yield and high purity reaction products for a range of metals. Among the preferred metal compounds employed in the processes are metal oxides and metal hydroxides. The methods are preferably carried out at a low pressure and can produce metal-terephthalate polymer powders containing small crystals which can be employed to enhance properties of polymers or disperse metals in specific applications by thermal decomposition of metal-terephthalate polymers.Type: GrantFiled: March 29, 2011Date of Patent: August 13, 2013Assignee: Chem Engineering EnergyInventors: Daniel Eric Steinmeyer, Jonathan Lyle Wistrom
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Patent number: 8501904Abstract: A process for the preparation of a polyol which includes reacting an amino-group-containing starter compound with an alkylene oxide in the presence of a catalyst to form a polyol, wherein the catalyst is based on a compound selected from the group consisting of alkali metal hydroxides, alkali, alkaline earth metal hydrides, alkaline earth metal carboxylates, and alkaline earth hydroxides, and wherein the catalyst is present in an amount of from 0.004 to 0.1 wt. % based on the amount of polyol; and neutralizing the polyol with from 0.75 to 1 mol of sulfuric acid per mol of catalyst used.Type: GrantFiled: April 6, 2009Date of Patent: August 6, 2013Assignee: Bayer MaterialScience AGInventors: Klaus Lorenz, Arnulf Werner, Marcus Eichmann
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Patent number: 8492513Abstract: The present invention provides a method for producing a silicone hydrogel having a high water content. The method comprises the following steps: (a) polymerizing a monomer mixture to form the silicone hydrogel, wherein the monomer mixture comprises at least one silicon-containing monomer and at least one ionic monomer; and (b) placing the silicone hydrogel in an alkaline solution for at least 20 minutes, wherein the alkaline solution has a pH not less than 7.5 and the ionic monomer is present in an amount not less than 0.7 wt % based on the total dry weight of the silicone hydrogel.Type: GrantFiled: October 14, 2011Date of Patent: July 23, 2013Assignee: Far Eastern New Century CorporationInventors: Chih-Ta Lee, Ching-Ping Huang, Yi-Hsuan Chang, Ken-Yuan Chang
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Patent number: 8487049Abstract: A process is described for recycling superabsorbent polymer fines into a process that includes treating the superabsorbent polymer fines with caustic and a polymerization step for making the superabsorbent polymer gel. The process requires treating the superabsorbent polymer fines with a caustic, followed by mixture with polymerizable monomer solution, and polymerizing the mixture of the superabsorbent polymer fines and monomer to form the aqueous fluid absorbent polymer. In the process, the fines are incorporated into the new polymer gel and become indistinguishable there from. The gel may then be comminuted into a particulate dried and then separated into a portion having a desired minimum particle size in a fines portion having less than the desired size. The particulate may then be coated with a surface crosslinking agent and surface additives and heated for surface conversion.Type: GrantFiled: November 9, 2012Date of Patent: July 16, 2013Assignee: Evonik Stockhausen, LLCInventors: Gonglu Tian, Scott J. Smith, Janet Pate-Linton
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Patent number: 8445629Abstract: A method for producing an acid group-containing polyarylene sulfide of the present invention includes a reaction step of reacting a polyhaloaromatic compound (a), an alkali metal hydrosulfide (b), and an alkali metal carboxylate (c) in the presence of a solid alkali metal sulfide and a lithium ion.Type: GrantFiled: August 7, 2007Date of Patent: May 21, 2013Assignee: DIC CorporationInventors: Toshio Hinokimori, Nobuhiko Yamauchi, Takashi Furusawa
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Patent number: 8445631Abstract: The present disclosure relates to a process for neutralizing a sulfonated block copolymer with a metal compound, to metal-neutralized block copolymers, and to various articles comprising the metal-neutralized block copolymers, e.g., in form of a water vapor permeable membrane which comprises the metal-neutralized block copolymers. The present disclosure further relates to a means and a method for storing and stabilizing a polar component such as a metal compound in a non-polar liquid phase by immuring the polar component in micelles of the sulfonated block copolymer in the non-polar liquid phase.Type: GrantFiled: October 13, 2009Date of Patent: May 21, 2013Assignee: Kraton Polymers U.S. LLCInventor: Carl Lesley Willis
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Patent number: 8436058Abstract: Embodiments of the present disclosure include a method for separating a product comprising a super absorbent polymer, a fiber and a plastic to separate the product into components thereof, the method comprising adding water to the product, and pressing the product in order to separate the product into components comprising a plastics component and a super absorbent polymer and fiber component. Other methods of the present disclosure include a method for producing a reusable plastic, reusable paper fiber stream and a reusable super absorbent polymer from the treatment of a product comprising a super absorbent polymer, a fiber and a plastic. Still other embodiments of the present disclosure include a method for the treatment of wet super absorbent polymer, comprising salt assisted dehydration.Type: GrantFiled: May 14, 2010Date of Patent: May 7, 2013Assignee: Knowaste International, LLCInventor: David Grimes
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Patent number: 8426552Abstract: A method for producing an acid group-containing polyarylene sulfide of the present invention includes a reaction step of reacting a polyhaloaromatic compound (a), an alkali metal hydrosulfide (b), an alkali metal carboxylate (c), and an aromatic compound (d) having an elimination group and an acid group, which function in a nucleophilic reaction, in the presence of a solid alkali metal sulfide.Type: GrantFiled: August 7, 2007Date of Patent: April 23, 2013Assignee: DIC CorporationInventors: Toshio Hinokimori, Nobuhiko Yamauchi, Takashi Furusawa
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Patent number: 8404754Abstract: A process for recycling a coloured thermoplastic material comprising an absorbed disperse dye comprises contacting the optionally comminuted coloured thermoplastic material with a caustic wash and recovering an at least partly colour-modified thermoplastic composition from the caustic wash.Type: GrantFiled: December 5, 2005Date of Patent: March 26, 2013Assignee: Colormatrix Europe LimitedInventors: Mark Frost, Fuquan Zeng, Victoria Sayer
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Patent number: 8399608Abstract: A process for the preparation of polyether alcohols by reacting at least one alkylene oxide with at least one unsaturated starter having at least one active hydrogen atom per molecule under basic catalysis, that the alkoxylation is carried out in at least two stages, in stage (I) the alkoxylation of the starter or starters being carried out with not more than 10 mol of alkylene oxide per mole of starter with a catalyst concentration of not more than 0.0085 mol of basic catalyst per mole and in stage (II) and the optionally following stages, the alkoxylated starter or starters from stage (I) being reacted with further alkylene oxide at a catalyst concentration of at least 0.01 mol of basic catalyst per mole of starter.Type: GrantFiled: October 25, 2007Date of Patent: March 19, 2013Assignee: BASF AktiengesellschaftInventors: Georg Heinrich Grosch, Matthias Zipplies, Thomas Ostrowski, Ulrich Annen, Markus Klumpe
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Patent number: 8349974Abstract: A biaxially oriented polyarylene sulfide film which has an excellent elongation at break and flatness is provided. The biaxially oriented film may be a biaxially oriented polyarylene sulfide film which is substantially composed of a polyarylene sulfide resin (A), wherein one of the elongations at break in the machine direction and in the transverse direction of the film is not lower than 110%; one of the breaking stresses in the machine direction and in the transverse direction of the film of the film is not higher than 200 MPa; and both of the heat shrinkage ratio in the machine direction of the film and that in the transverse direction of the film at 260° C. for 10 minutes are not less than 0% and not more than 10%.Type: GrantFiled: May 7, 2008Date of Patent: January 8, 2013Assignee: Toray Industries, Inc.Inventors: Tetsuya Machida, Masatoshi Ohkura, Yasuyuki Imanishi
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Patent number: 8344094Abstract: An optical material is provided that has a high transmittance, a high refractive index, a low Abbe constant, a high secondary dispersion property, and a low water absorption rate. The optical material includes a polymer of a mixture which contains: a sulfur-containing compound represented by the following general formula (1): a sulfur-containing compound represented by the following general formula (2): and an energy polymerization initiator, in which a content of the sulfur-containing compound represented by the chemical formula (2) is 10% by weight or more to 60% by weight or less, an Abbe constant (?d) of the polymer of the mixture satisfies 18<?d<23, and a secondary dispersion property (?g,F) thereof satisfies 0.68<?g,F<0.69.Type: GrantFiled: September 8, 2009Date of Patent: January 1, 2013Assignee: Canon Kabushiki KaishaInventors: Hidefumi Iwasa, Shigeo Kiso, Terunobu Saitoh, Toshiji Nishiguchi
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Patent number: 8329832Abstract: A method for producing a cyclic polyarylene sulfide, wherein a cyclic polyarylene sulfide is produced by heating a reaction mixture which is composed of at least a linear polyarylene sulfide (a), a sulfidizing agent (b), a dihalogenated aromatic compound (c) and an organic polar solvent (d). This method for producing a cyclic polyarylene sulfide is characterized in that not less than 1.25 liters of the organic polar solvent is used per 1 mole of the sulfur content in the reaction mixture. This method enables to efficiently produce a cyclic polyarylene sulfide, more specifically cyclic oligoarylene sulfide by an economical and simple process in short time.Type: GrantFiled: February 27, 2008Date of Patent: December 11, 2012Assignee: Toray Industries, Inc.Inventors: Shunsuke Horiuchi, Kohei Yamashita, Kayo Tsuchiya, Koji Yamauchi
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Patent number: 8318895Abstract: A process is described for recycling superabsorbent polymer fines into a process that includes treating the superabsorbent polymer fines with caustic and a polymerization step for making the superabsorbent polymer gel. The process requires treating the superabsorbent polymer fines with a caustic, followed by mixture with polymerizable monomer solution, and polymerizing the mixture of the superabsorbent polymer fines and monomer to form the aqueous fluid absorbent polymer. In the process, the fines are incorporated into the new polymer gel and become indistinguishable there from. The gel may then be comminuted into a particulate dried and then separated into a portion having a desired minimum particle size in a fines portion having less than the desired size. The particulate may then be coated with a surface crosslinking agent and surface additives and heated for surface conversion.Type: GrantFiled: August 2, 2012Date of Patent: November 27, 2012Assignee: Evonik Stockhausen, LLCInventors: Gonglu Tian, Scott J. Smith, Janet Pate-Linton
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Patent number: 8309682Abstract: A process is described for recycling superabsorbent polymer fines into a process that includes treating the superabsorbent polymer fines with caustic and a polymerization step for making the superabsorbent polymer gel. The process requires treating the superabsorbent polymer fines with a caustic, followed by mixture with polymerizable monomer solution, and polymerizing the mixture of the superabsorbent polymer fines and monomer to form the aqueous fluid absorbent polymer. In the process, the fines are incorporated into the new polymer gel and become indistinguishable there from. The gel may then be comminuted into a particulate dried and then separated into a portion having a desired minimum particle size in a fines portion having less than the desired size. The particulate may then be coated with a surface crosslinking agent and surface additives and heated for surface conversion.Type: GrantFiled: February 4, 2011Date of Patent: November 13, 2012Assignee: Evonik Stockhausen, LLCInventors: Gonglu Tian, Scott J. Smith, Janet Pate-Linton
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Patent number: 8304464Abstract: The invention relates to a method for mixing a polyester with caustic material including providing a polyester, preferably PET, mixing the polyester with the caustic material; and heating the mixture in temperature stages defined as a function of a reaction sequence of the reaction between the PET and the caustic material.Type: GrantFiled: November 25, 2009Date of Patent: November 6, 2012Assignee: Cleanaway PET International GmbHInventor: Ulrich Schmidt
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Patent number: 8263734Abstract: The techniques provide a system and a method of producing polyphenylene sulfide (PPS) polymer. The PPS polymer is produced by reacting a sulfur source and a dihaloaromatic compound in the presence of a polar organic compound in a polymerization mixture in a polymerization vessel. The PPS polymer is washed with a base to lower the oligomer content of the PPS polymer and thus the off-gassing during processing.Type: GrantFiled: February 13, 2009Date of Patent: September 11, 2012Assignee: Chevron Phillips Chemical Company LPInventors: Jeffrey S. Fodor, Aubrey South, Jr.
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Patent number: 8247523Abstract: Disclosed herein is a method for producing a purified 2-aryl-3,3-bis(4-hydroxyaryl) phthalimidine of formula (I) wherein R1 is hydrogen or a C1-25 hydrocarbyl group and R2 is a hydrogen, a C1-25 hydrocarbyl group, or a halogen, and wherein the method comprises dissolving a crude phthalimidine compound in an aqueous base solution; precipitating the dissolved, crude phthalimidine compound from the aqueous base solution by adding an acid in an amount effective to lower the pH of the solution to 9.0 to 12.0, to provide a semicrude phthalimidine compound; and isolating the semicrude phthalimidine compound from the aqueous base solution, to provide the purified 2-aryl-3,3-bis(4-hydroxyaryl)phthalimidine of formula (I), and having a phenolphthalein compound content of less than 2,500 ppm, based on the weight of the purified 2-aryl-3,3-bis(4-hydroxyaryl)phthalimidine.Type: GrantFiled: December 12, 2008Date of Patent: August 21, 2012Assignee: Sabic Innovative Plastics IP B.V.Inventors: Venkata Rama Narayanan Ganapathy Bhotla, Balakrishnan Ganesan, Kishan Gurram, Salkod Parameshwar Mallika, Kumar Arun Satyanarayana, Swaminathan Shubashree